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EXOTHERMIC AND ENDOTHERMIC CHANGES
1. Changes of state
During the freezing of water, water changes to ice and heat energy is
given out to the surroundings.
Question 1
Classify freezing and condensation as either exothermic or endothermic.
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For example, during the boiling water, water changes to steam and heat is
absorbed.
Heat + H2O(l) H2O(g)
Question 2
Classify melting and boiling as either exothermic or endothermic.
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2. Dissolving of some salts in water.
Part a:
Put in sodium carbonate into the test tube and take note of the final
temperature.
Question 3
Classify dissolving sodium carbonate in water as either exothermic or
endothermic.
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Part b:
Put in ammonium chloride into the test tube and take note of the final
temperature.
Question 4
Classify dissolving ammonium chloride in water as either exothermic or
endothermic.
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3. Combustion reactions
4. Decomposition of compounds
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Heat + CuCO3(s) CuO(s) + CO2(g)
Question 6
Classify decomposition of compounds as either exothermic or endothermic.
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5. Neutralisation reactions
Put in hydrochloric acid into a test tube. Take note of the initial temperature
of the acid in the test tube.
Put in sodium hydroxide into the test tube and take note of the final
temperature.
H+(aq) + OH-(aq) H2O(aq) + heat
Question 7
Classify neutralization reactions as either exothermic or endothermic.
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For example, when zinc reacts with copper (II) sulphate solution in a test
tube, the reaction gives out heat and the test tube becomes warm.
Zn(s) + Cu2+(aq) Zn2+(aq) + Cu(s) + heat
Question 8
Classify metal displacement reactions as either exothermic or endothermic.
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For example, when some headache tablets ( a mixture of solid acids such
as citric acid and sodium hydrogencarbonate) are added to water, the
temperature of the solution decreases as the acid and hydrogencarbonate
react. The word equation for this reaction is:
Question 9
Classify reactions between acids and hydrogencarbonates as either
exothermic or endothermic.
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WORKSHEET 1
5
Please proceed to do exercise from:
WORKSHEET 2
So what will happen to the energy of the products and the reactants?
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BOND BREAKING AND BOND MAKING
1. Add up the bond energies for all the bonds in the products. This is the
heat given out in making bonds.
2. Add up the bond energies for all the bonds in the reactants. This is the
heat absorbed in breaking bonds.
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⇒ Using the bond energy from Table 1, calculate the overall heat change.
The energy level diagrams for exothermic and endothermic reactions are
compared below.
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Please proceed to do exercise from:
WORKSHEET 4
COMBUSTION OF FUELS
The most commonly used fuels are fossil fuels such as coal, petroleum
and natural gas.
They are formed from decayed plants and animals that lived millions of
years ago. They are carbon compounds.
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The properties and uses of some of the fractions are summarised in the
Table below.
Coal is mainly carbon. It burns in excess of air to give carbon dioxide and
energy.
Equation: carbon + oxygen carbon dioxide + heat energy
C(s) + O2(g) CO2(g) + heat energy
Most fuels contain carbon and hydrogen, when these fuels burn, carbon
dioxide, water and heat energy are produced.
Write the equation for the complete combustion of natural gas, which
contains mainly methane (CH4).
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If a limited supply of air is used, carbon particles (in the form of soot) and a
poisonous gas, carbon monoxide are produced. This is called incomplete
combustion.
Write the equation for the incomplete combustion of natural gas.
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HYDROGEN AS A FUEL
Hydrogen produces at least twice as much heat energy per gram when
burnt, than any other common fuels. This is why it is used as a fuel in
space shuttles and other big rockets.
Fuel Cells
A fuel cell is a chemical cell in which reactants (usually a fuel and oxygen)
are continuously supplied to produce electricity directly.
The best known example is the hydrogen-oxygen fuel call which is used as
a source of electrical power in space vehicles.
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Photosynthesis
Green plants absorb carbon dioxide and water, and convert them into
glucose and oxygen using sunlight as energy, which is absorbed by the
green pigment, chlorophyll.
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WORKSHEET 1
( )
3. Which statement is true for all examples of combustion?
A One product is carbon dioxide.
B It is an exothermic reaction.
C The combustion products have more energy than the original fuel and
oxygen.
D No bonds are broken in the reaction.
( )
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4.
5.
6.
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WORKSHEET 2
2. The equation for the extraction of iron in the blast furnace is:
Fe2O3 + 3CO 2Fe + 3CO2; ΔH=-27 kJ
What heat energy change takes place when 1 mole of iron is produced in the reaction?
A 27 kJ of heat energy absorbed.
B 13.5 kJ of heat energy is absorbed.
C 13.5 kJ of heat energy is given out.
D 27 kJ of heat is given out. ( )
3. The equation for the reaction of sulphuric acid with sodium hydroxide is:
H2SO4(aq) + 2NaOH(aq) Na2SO4(s) + 2H2O(l) ΔH=-114 kJ
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WORKSHEET 3
( )
3. The reaction between hydrogen and oxygen to form water occurs in three stages. In
which stages are the signs of energy changes correctly shown?
4.
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5. In each change, state whether it is endothermic or exothermic.
6. Hydrogen reacts with chlorine to produce hydrogen chloride. The equation for the
reaction is:
H2(g) + Cl2(g) 2HCl(g)
(a) (i) What type of energy change occurs when bonds are broken?
(ii) What type of energy change occurs when bonds are formed?
(iii) Which is the larger of the energy changes taking place in the reaction above,
bond breaking or bond forming? Explain your answer.
(b) When 1 mole of chlorine gas reacts, the energy change, ΔH, is -184 kJ.
Calculate the energy change when 14.2 g of chlorine reacts completely with
hydrogen.
(c) (i) In forming ionic bonds, electrons are transferred between atoms. How is a
covalent bond formed?
(ii) Draw a ‘dot and cross’ diagram to show the bonding in a molecule of
hydrogen chloride. You only need to draw the electrons in the outermost shells.
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WORKSHEET 4
Use the bond energy data in the table to calculate the energy change in each reaction
(make sure your sign is correct).
Draw an energy profile diagram to show the relative position of the reactants and
products in each one.
O O
1) 2 2 S
O S O + O O
1 O
1
)
H H + Cl Cl 2 H Cl
2)
ii
)
H H H
O
3) H C C C H + 5 O O 3 O C O + 4 H H
H H H
ii
i)
H
O
2 O O
4) 2 H H + O O
H
i
v
)
H H H H H H
H C C C H + Br Br H C C C H
5)
H H Br Br
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WORKSHEET 5
2. The bar chart compares the amounts of energy used by country Z in three years.
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3. Liquid hydrogen is used as a fuel in big rockets.
a) Suggest a reason why liquid hydrogen is carried on big rockets in tanks rather than
hydrogen gas.
b) i) Write the equation for the combustion of hydrogen.
ii) In terms of bonds broken and binds formed, explain why the burning of hydrogen
is exothermic.
iii) One mole of H2 releases 282 kJ of energy when burnt.
What is the amount of energy released when 10 kg of hydrogen burns?
c) It has been suggested that hydrogen could be developed as an alternative fuel to
replace hydrocarbon fuels in the future. Suggest one advantage hydrogen has over
fossil fuels.
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