ENSIGN-BICKFORD COMPANY -- MILITARY PRIMADET -- 1680-00N019214

===================== Product Identification ===================== Product ID:MILITARY PRIMADET MSDS Date:06/27/1989 FSC:1680 NIIN:00N019214 MSDS Number: BLCSJ === Responsible Party === Company Name:ENSIGN-BICKFORD COMPANY Address:660 HOPMEADOW STREET City:SIMSBURY State:CT ZIP:06070 Country:US Info Phone Num:203-658-4411 Emergency Phone Num:203-658-4411 Preparer's Name:STEVE BARTHOLOMEW CAGE:0B1W4 === Contractor Identification === Company Name:ENSIGN-BICKFORD CO Address:660 HOPMEADOW ST Box:City:SIMSBURY State:CT ZIP:06070 Country:US Phone:(203) 658-4411 OR (203) 843-22 CAGE:0B1W4 Company Name:THE ENSIGN-BICKFORD CO Address:660 HOPMEADOW ST Box:City:SIMSBURY State:CT ZIP:06070 Phone:(203) 658-4411 CAGE:0B2N1 ============= Composition/Information on Ingredients =============

Ingred Name:CYCLONITE CAS:121-82-4 RTECS #:XY9450000 Fraction by Wt: 60-70% OSHA PEL:S, 1.5 MG/M3 ACGIH TLV:S, 1.5MG/M3; 9192 Ingred Name:LEAD AZIDE, (DEXTRINATED) CAS:13424-46-9 RTECS #:OF8650000 Fraction by Wt: 15-20% OSHA PEL:0.15 MG(PB)/M3 ACGIH TLV:0.15 MG(PB)/M3 Ingred Name:POTASSIUM PERCHLORATE CAS:7778-74-7 RTECS #:SC9700000 Fraction by Wt: 5-10% Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 5-10%

OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <1% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:OCTOGEN; (HMX) CAS:2691-41-0 RTECS #:XF7450000 Fraction by Wt: <1% ===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures =======================

First Aid:EYES: IMMEDIATELY FLUSH EYES WITH POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: IF DETONATION FUMES ARE I NHALED REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures =====================

Extinguishing Media:NONE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . DO NOT FIGHT FIRE. ISOLATE AREA. EVACUATE PERSONNEL TO A SAFE PLACE. Unusual Fire/Explosion Hazard:HAZARDOUS FUMES PRODUCED IN A FIRE ARE LEAD FUMES AND NOX. WILL DETONATE IN A FIRE. ================== Accidental Release Measures ==================

Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY PRECAUTIONS BEFORE PROCEEDING WITH CLEAN-UP, USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT DURING CLEAN-UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ======================

Handling and Storage Precautions:TRANSPORTATION AND STORAGE MUST BE IN ACCORDANCE WITH FEDERAL AND STATE REGULATIONS. Other Precautions:REFER TO MANUFACTURER'S INSTRUCTIONS AND WARNINGS SUPPLIED WITH PRODUCT. ============= Exposure Controls/Personal Protection =============

Ventilation:NOT APPLICABLE. Protective Gloves:NONE. Eye Protection:CHEMICAL WORKERS GOGGLES .

Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ==================

HCC:E1 Appearance and Odor:AL SHELL CONTAINING APPROX 940 MG RDX & 230 MG LEAD AZIDE W/PLASTIC TUBE ATTACH ================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH ACIDS, ALKALIES. Stability Condition to Avoid:BECOMES UNSTABLE WITH HEAT, SHOCK, FRICTION OR IMPACT. Hazardous Decomposition Products:HAZARDOUS GASES PRODUCED ARE NOX. ==================== Disposal Considerations ====================

Waste Disposal Methods:CONSULT AS EXPLOSIVE MANUFACTURER OR THE INSTITUTE OF MAKERS OF EXPLOSIVES FOR RECOMMENDED METHODS FOR DESTROYING EXPLOSIVE MATERIALS. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGU LATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.

=====================

Product Identification

=====================

MSDS NAME:PRIMADET NONELECTRIC DETONATORS NIIN:00N078332 MSDS Number: CGGDV === Responsible Party === Company:ENSIGN-BICKFORD CO Address:660 HOPMEADOW ST City:SIMSBURY State:CT ZIP:06070 Country:US Info Phone Num:203-658-4411 Emergency Phone Num:203-658-4411 Preparer's Name:E.L. STEARNS CAGE:96336

=== Contractor Identification === Company:ENSIGN-BICKFORD CO Address:660 HOPMEADOW STREET Box:483 City:SIMSBURY State:CT ZIP:06070-0483 Country:US Phone:1-801-798-8613 CAGE:96336 ============= Composition/Information on Ingredients =============

Name:PENTAERYTHRITOL TETRANITRATE CAS:78-11-5 RTECS #:RZ2620000 Fraction by Wt: 30-40% OSHA PEL:N/K ACGIH TLV:N/K Name:LEAD AZIDE CAS:13424-46-9 RTECS #:OF8650000 Fraction by Wt: 25% OSHA PEL:RULE IN PROCESS ACGIH TLV:0.15 MG/M3 PB Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 10-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Name:LEAD TETROXIDE; (RED LEAD) CAS:1314-41-6 RTECS #:OG5425000 Fraction by Wt: 10-15% OSHA PEL:N/K ACGIH TLV:N/K Name:BARIUM CHROMATE CAS:10294-40-3 RTECS #:CQ8760000 Fraction by Wt: 1-4% OSHA PEL:0.5 MG/M3 CR ACGIH TLV:0.5 MG/M3 CR Name:PERCHLORIC ACID, POTASSIUM SALT (1:1); (POTASSIUM PERCHLORATE) CAS:7778-74-7 RTECS #:SC9700000 Fraction by Wt: 1-2% OSHA PEL:N/K ACGIH TLV:N/K Name:SILICA; (OTTAWA SILICA) Fraction by Wt: 1-2% OSHA PEL:N/K ACGIH TLV:N/K

Name:CHROMIC ACID, (1:1), LEAD (2+) SALT (1:1); (LEAD CHROMATE) CAS:7758-97-6 RTECS #:GB2975000 Fraction by Wt: 1-4% OSHA PEL:N/K ACGIH TLV:N/K Name:SELENIUM (SARA 313) (CERCLA) CAS:7782-49-2 RTECS #:VS7700000 Fraction by Wt: <1% OSHA PEL:0.2 MG/M3 ACGIH TLV:0.2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 15-20% OSHA PEL:10 PPM ACGIH TLV:10 PPM Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 10-15% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 OSHA PEL:N/K ACGIH TLV:0.15 MG/M3 DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:LEAD APPEARS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION . EYE CONTACT/SKIN CONTACT/INHALATION/INGESTION: NOT LIKELY ROUTES OF EXPOSURE. Explanation of Carcinogenicity:BARIUM CHROMATE & LEAD CHROMATE: IARC MONOGRAPHS, VOL 49, PG 49, 1990:GROUP 1. NTP 7TH ANNUAL REPORT ON (SUPDAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

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First Aid Measures

=======================

First Aid:INGEST: CALL MD IMMEDIATELY . EYES: IMMEDIATELY FLUSH EYES WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEEK ASSISTANCE FROM MD . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: IF DETONATION FUMES ARE INHALED,REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT GIVE OXYGEN. CALL MD. ===================== Fire Fighting Measures =====================

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . DO NOT FIGHT FIRE. ISOLATE AREA. EVACUATE PERSONNEL TO A SAFE PLACE. Unusual Fire/Explosion Hazard:HAZARDOUS FUMES PRODUCED IN FIRE ARE LEAD FUMES AND NITROGEN OXIDES. WILL DETONATE IN A FIRE. ================== Accidental Release Measures ==================

Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY PRECAUTIONS BEFORE PROCEEDING WITH CLEAN UP. USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT DURING CLEAN UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ======================

Handling and Storage Precautions:TRANSPORTATION AND STORAGE MUST BE IN ACCORDANCE WITH FEDERAL AND STATE REGULATIONS. CLASS C STANDARD SHIPPING CONTAINER. Other Precautions:REFER TO MANUFACTURER'S INSTRUCTIONS AND WARNINGS SUPPLIED WITH PRODUCT. ============= Exposure Controls/Personal Protection =============

Respiratory Protection:NONE. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT APPLICABLE. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR: MG PENTAERYTHRITOL TETRANITRATE (PETN) WITH PLASTIC TUBE ATTACHED. EXPLAN OF CARCIN: CARCINOGENS, 1994:KNOWN TO BE CARCINOGEN. NOT ALL HAZARDOUS INGREDIENTS ARE PRESENT IN EVERY DETONATOR . ================== Physical/Chemical Properties ==================

Appearance and Odor:ALUMINUM SHELL CONTAINING APPROXIMATELY 100 ML LEAD AZIDE AND 400-800 (SUPDAT) ================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH ACIDS, ALKALIES. Stability Condition to Avoid:BECOMES UNSTABLE WITH HEAT, SHOCK, FRICTION OR IMPACT. AVOID BREATHING FUMES FROM DETONATION. Hazardous Decomposition Products:HAZARDOUS GASES PRODUCED ARE NITROGEN OXIDES.

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Disposal Considerations

====================

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . CONSULT AN EXPLOSIVE MANUFACTURER FOR RECOMMENDED METHODS FOR DESTROYING EXPLOSIVE MATERIALS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.