Concept Recapitulation Test I/Advanced/PAPER-1/Answer/Answer

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ANSWERS, HINTS & SOLUTIONS

CRT-I(Set-I)

PAPER -1

PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
C D A
2.
C B B
3.
B B B
4.
C C D
5.
A C D
6.
B B A
7.
D A C
8.
C D B
9.
A B D
10.
D D A
11.
D D B
12.
C C B
13.
D A A
14.
B D B
15.
C B C
16.
A B B
17.
C B B
18.
A A B
19.
B C B
1.
(A) (q, s)
(B) (p, q, r, s)
(C) (p, q, s)
(D) (p, s)
A (p)
B (s, t)
C (r, t)
D (q, t)
(A) (q)
(B) (p)
(C) (s)
(D) (r)
2.
(A) (p, r)
(B) (q)
(C) (q, s)
(D) (q)
A (a)
B (p)
C (r)
D (q)
(A) (r)
(B) (p)
(C) (s)
(D) (q)
3.
(A) (p, r)
(B) (p, q)
(C) (s)
(D) (t, p)
A (p)
B (q)
C (s)
D (r)
(A) (q)
(B) (s)
(C) (p)
(D) (r)

A
L
L

I
N
D
I
A

T
E
S
T

S
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S

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AITS-CRT(Set-I)-Paper-1-PCM(S)-JEE(Adv)/13
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2
P Ph hy ys si ic cs s PART I

SECTION A

1. ( ) ( )
d
g L x gL xu
dt
+ =

2.
x
p
v 5 = ,
y
p
v 5 =
5 2 = 7.1 m/s approx.

3. Solve the problem using as the coefficient of kinetic friction. Linear velocity radius to zero
before angular velocity becomes zero.

4. II and IV quadrant field will be added.

5. Conceptual.

6. Leftward Force =
2I P
C t

7. Conceptual, torque of pseudo force.

8. Effective length = (r
2
+ r
1
)

14.
t
0
I I 1 e

( =

0
E
I
R
= and =
2L
3R

3Rt
2L
E
I 1 e
R

| |
| =
|
\ .

2L L
I 2
I and I I
3 3
= =

15. Magnetic energy stored at t = t
0
is given by
2
LI
U
2
= , where I is value of I
L
at t = t
0
;
3Rt
2L
L
2 2 E
I I 1 e
3 3 R

| |
| = =
|
\ .

0
2
3Rt 2
2L
2
2E L
U 1 e
9R
(
=
(

16. Zero current since no path for current is available.

17. dQ = 0, dW = 0

18. For constant temperature T, dW nRTln2 =

19. dQ = dU + dW = dW,
dU = 0 as T = constant

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3
SECTION B

2. V
i
for C
1
=
2
4V
9
, V
i
for C
2
=
2
2V
9

V
f
for C
1
=
2
8V
25
, V
f
for C
2
=
2
2V
25

C Ch he em mi is st tr ry y PART II

SECTION A

1. Energy of photon corresponding to second line of Balmer series of Li
2+
ion.

2
2 2
1 1 27
13.6 3 13.6
16 2 4
| |
= =
|
\ .

Energy needed to eject electron from n = 2 level in H-atom =
2
2 2
1 1 13.6
13.6 1
4 2
| |
=
|
\ .

KE of ejected electron =
9 3 13.6
13.6 19.55 eV
16 4
=

2.
3
6 2 2
3
] ) O H ( Cr [ O H 6 Cr
+ +
+ (violet)
) blue ( ] ) O H ( Cr [ O H 6 Cr
2
6 2 2
2 + +
+
3
3 2 3 4
grey blue
Cr 3NH 3H O Cr(OH) 3NH
+ +
+ + +
( ) ( )
3 3 3
3 6
grey blue
Cr(OH) 6NH Cr NH OH
(
+

3 2 2 2
2 8 2 4 4
2Cr 3S O 8H O 2CrO 16H 6SO
+ +
+ + + +
2
4 2 2 5 2
CrO 2H H O CrO 3H O
+
+ + +
3.
A
A
4 Mx
N V
= when V volume of fcc unit cell.

y
A x
B
A B y
M
M 30
8 , 0.3
N V 2M 2 50
= = = =

Total density
A B
4.33 + = g/cc

7.
Ph
OH
Ph
H
+
Ph
Ph
Friedal Craft
Acylation

Ph
Ph
8.
CN
CN
CN
CN
COOH
COOH
COOH
COOH
O
O
O
3
H O
+
4

9.
7 7 2
2
6 10 6 10 100 1000 6 10
H 1000 1.2 10
0.05 5 5

+

( = = = =

10. O=C=C=C=O

11. Group reagent for V group is (NH
4
)
2
CO
3
in presence of NH
4
Cl and because of NH
4
OH, pH of
solution is maintained.

12. Lighter nuclei dont have so high binding energy.

14. MnO
2
form solution when performing titration of KMnO
4
in alkaline medium.

17. In expansion of CO
2
gas molecule, entropy of system
( )
sys
S increases and
surr
S decreases.

18. Work done = q = nRT
2
1
V 30
n 3 8.314 288.15 n
V 10
| |
=
|
\ .

1
q q
S 27.4 JK
T 288.15

= = =

19.
uni
S will be zero for all reversible process.
SECTION-B
2. ( )
3 3 2 2
2
4Zn 10HNO 4Zn NO NO 5H O + + +
( )
3 3 2
2
Mg 2HNO Mg NO H + +
( )
3 3 4 3 2
2
4Sn 10HNO 4Sn NO NH NO 3H O + + +
( )
3 3 2
2
3Pb 8HNO 3b NO 2NO 4H O + + +

M Ma at th he em ma at ti ic cs s PART III

SECTION A
1. I
1
=
( )( )
101
2 2 4x
100
dx
5 2x 2x 1 e

+ +
=
( ) ( ) ( )
( )
( )
101
2
2 4 1 x
100
dx
5 2 1 x 2 1 x 1 e

+ +

= 2I
1
=
101
2
100
dx
5 2x 2x
= I
2

1
2
I
I
=
1
2
.

2. Since incident ray is perpendicular to the line
mirror y x = 1 so after refection reflected ray
goes back and intersect x axis at A
A (1, 0)
Whose equation is x y = 1.

A
45
(1, 0)
B (0, 1)
(0, 1)
45
C
5
3. Let OA
= a
, OB b =

and OC c =

, then AB b a =

and
1
OP a
3
=

,
1
OQ b
2
=

,
1
OR c
3
=

Since P, Q, R and S are coplanar, then
PS PQ PR = +

( PS
can be written as a linear combination of PQ
and PR
)
=
( ) ( )
OQ OP OR OP +

i.e., ( )
a
OS OP b c
3 2 3

= + + +

( )
a
OS 1 b c
3 2 3

= + + +

.. (1)
Given OS AB =

=
( )
b a

.. (2)
From (1) and (2), = 0,
1
3

= and
2
= 2 = 1 + 3 = 1

4. Let the numbers be x and y
| x y | 10 No. of ways
If x = 1 1 y 11 11
x = 2 1 y 12 12
x = 3 1 y 13 13
: :
: :
: :
: :
x = 11 1 y 21 21
x = 12 2 y 22 21
x = 13 3 y 23 21
: :
: :
x = 25 15 y 25 21
Now of ways = (11 + 12 +.. + 20) + 21 15
20 10
k 1 k 1
k k 315
= =
= +

=
20 21 10 11
315
2 2

+
= 210 55 + 315 = 470.

5.
( )
( )
( ) ( )
f x
1 lnf x x c.lnf 0 c c 0
f x
= = + = =
f(x) = e
x

( ) ( )
1 1 1
2
x 2 x 2 x x
0 0 0
e x e dx x e dx e dx =

=
( )
1
2
x
2
2 x x x
0
e
e 1
x e 2xe 2e e 2e 2e 2
2 2 2
(
(
+ = + +
(
(

=
2
e 3
e
2 2

6.
( )
2n 1
3 3 5
+
+ = +

( )
2n 1
1
3 3 5 1
+
= <
( ) ( )
2n 2n 2
2n 1 2n 1 3
1 1 3
2 C .5 3 3 C 5 3 3 .......
+ + | |
+ = + +
|
\ .

= even integer
1
= 0
( 1 <
1
< 0)
= even integer

6
7. cos = 1
4x
2
10x 6x + 15 < 0 (2x 3) (2x 5) < 0

(2x 3)

3/2
(2x 5)
5/2 ve +ve +ve

tan = 2
sin( + ) sin( ) = cos
2
cos
2
= 1
1 4
5 5
=

8. BOC = 2 ( + A)
= A
a
2
= R
2
+ R
2
2R
2
cos( A)
a
2
= 2R
2
(1 + cos A)

2
a a
R sec A/ 2
2
2.2cos A/ 2
= =

O
(B+C)/2
A
B C

9. ( ) ( )
n n
a b c a b c + + + + = ( ) ( ) ( )
( )
n n 2 0
n 0 n 2 n n
0 2 n
2. C .c . a b C .c a b ........ C .c a b
+ + + + + +
Number of term = ( ) ( ) ( ) n 1 n 1 n 3 ...... 3 1 + + + + + +
= ( )
( )( ) ( )
2
n 2 n 2 n 2
n 2
. 1 n 1
2 2 2
+ + +
+ | |
+ + = =
|
\ .

10. If n even
n
4
+ 4
n
even and n
4
+ 4
n
> 2
n
4
+ 4
n
is not a prime
if n odd, let n = 2k + 1
n
4
+ 4
n
= (2k + 1)
4
+ 4
2k + 4

= (2k + 1)
4
+ 4(2
k
)
4
+ 4(2
k
)
2
(2k + 1)
2
4(2
k
)
2
(2k + 1)
2

= ((2k + 1)
2
+ 2(2
k
)
2
)
2
(2(2
k
)(2k + 1))
2

= ((2k + 1)
2
+ 2(2
k
)
2
+ 2(2
k
)(2k + 1))((2k + 1)
2
+ 2(2
k
)
2
2(2
k
)(2k + 1)).

11. px
2
+ 4xy + qy
2
+ 4a(x + y + 1) = 0 represents pair of straight lines iff
4apq + 16a
2
4a
2
p 4a
2
q 16 a
2
= 0
4
2
4a + ap + aq pq = 0.
For real , 16a
2
4.4(ap + aq pq) 0
(a p)(a q) 0 a p or a q.

12. 2f(x) + f(x) = 2f(x) + f(x) f(x) = f(x)
f(x) =
1
3x
sin
1
x
x
| |
|
\ .

I =
e
1/ e
1 1
sin x dx
3x x
| |
|
\ .
=
e
1/ e
1 1
sin t dt
3t t
| |
|
\ .
= I
I = 0.

7
13. x
2
+ 8x 16 = 0
(x + 4)
2
= 32
x = 4 4 2
x = 4 + 4 2
x = 1, y = +2 2 , (1, 0) (1, 1) (1, 2) 5 integral
points
x = 2, y = 2 3 (2, 0) (2, 1, (2, 2),
(2, 3) 7 integral points
x = 3, y = 7 , (3, 0), (3, 1), (3, 2) 5 integral
points
P
Q

14. Area =
2
r
4
=

15. Area =
1
2
2 2 = 2

16. Area =
( )
3
2
1
x 2 dx
2
=
.

17. According to graph f (a + h) f (a h) > 0.

x = a
18. According to above graph if f(a) = 0
f(a) = 0 (it is point of inflection)
f() = 0
< (using Rolle s Theorem).

19. f(x) 0 f (x) = 0 has atmost one real.
f(x) = 0 has atmost one solution.

SECTION-B
1. (A)
sin1 sin5
sin2 sin6

take f(x) =
( )
sinx
sin x 1 +

f(x) =
( ) ( )
( )
2
sin x 1 cosx cos x 1 sinx
sin x 1
+ +
+
=
( )
2
sin1
0
sin x 1
>
+

f(x) is increasing.
f(1) < f(5).
(B) take f(x) = tanx x
2

f(x) = sec
2
x 2x
f(x) = 2 sec
2
x tanx 2
f(1) > 0 and f(x) > 0 for x > 1
8
f(x) is increasing in 1,
2
| |
|
\ .

3 9
tan
2 4
> .
(C)
x
x 0
e 1
lim
x
(
(

does not exist as left hand and right hand limits are not equal.
(D) f() = 0 and f(x) > 0 x R {}
f(x) = (x )
2n
g(x)
f() = 0.

2. (A) f
2
(x) = f
2
( x)
f(x) = f( x) or f(x) = f( x)
if f(x) is not continuous then f(x) may be neither even nor odd.
(B) f(x) = x[x
2
] +
2
1
1 x
domain of f(x) is ( 1, 1)
f(x) =
2
1
1 x
which is an even function
(C) f(x) =
3 2 2 3
x x 2x x
x 1 x 2
e e

+ =
2 2
x x
e e
+ but (x 1, 2)
f(x) is neither even nor odd.
(D) 2x f(x) = f(2x
2
1)
put x = x
2x f( x) = f(2x
2
1)
f(x) is odd.

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can be written as a linear combination of PQ

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