MATERIAL SAFETY DATA SHEET

PRODUCT PAGE SYNONYMS / FIND PAGE NO. .................................................................................................................................. 7 AC -45-C .................................................................................................................................................................. 16 ACETALDEHYDE ..................................................................................................................................................... 18 ACETIC ACID (glacial) ............................................................................................................................................. 20 ACETIC ANHYDRIDE............................................................................................................................................... 23 ACETONE ................................................................................................................................................................ 27 ACETONE CAYANOHYDRIN ................................................................................................................................... 28 ACETONITRILE ....................................................................................................................................................... 32 ACRYLIC ACID ........................................................................................................................................................ 34 ACRYLONITRILE ..................................................................................................................................................... 37 ADIPONITRILE......................................................................................................................................................... 40 ALLYL ALCOHOL ..................................................................................................................................................... 42 ALLYL CHLORIDE ................................................................................................................................................... 45 alpha-METHYLSTYRENE......................................................................................................................................... 47 ALPHANOL -79 ........................................................................................................................................................ 50 AMINOETHYL ETHANOLAMINE.............................................................................................................................. 51 AMMONIA AQUEOUS.............................................................................................................................................. 53 iso-AMYL ACETATE ................................................................................................................................................. 55 n-AMYL ALCOHOL................................................................................................................................................... 58 ANILINE ................................................................................................................................................................... 60 ARKOPAL N130/N 150 ............................................................................................................................................. 63 AROMASOL H.......................................................................................................................................................... 65 BABASSU OIL.......................................................................................................................................................... 66 BENZENE ................................................................................................................................................................ 68 BRAKE FLUID .......................................................................................................................................................... 71 n-BUTYL ALCOHOL(Butanol) ................................................................................................................................... 73 n-BUTYL ACETATE ................................................................................................................................................. 75 n-BUTYL ACRYLATE ............................................................................................................................................... 78 sec- BUTYL ALCOHOL ............................................................................................................................................ 81 BUTYL BENZYL PHTHALATE ................................................................................................................................. 84 1,3-BUTYLENE GLYCOL ......................................................................................................................................... 85 n-BUTYL ETHER ...................................................................................................................................................... 87 BUTYL METHACRYLATE ........................................................................................................................................ 90 n-BUTYRALDEHYDE ............................................................................................................................................... 92 n-BUTYRIC ACID ..................................................................................................................................................... 94 CALCIUM CHLORINE LIQUEUR .............................................................................................................................. 97 CAMPHOR OIL ........................................................................................................................................................ 98 CARADOLS ............................................................................................................................................................ 101 CARBOLIC OIL ...................................................................................................................................................... 102 CARBON DISULFIDE ............................................................................................................................................. 104 CARBON TETRACHLORIDE ................................................................................................................................. 105 CARBOLIC OIL ...................................................................................................................................................... 108 CASHEW NUT OIL................................................................................................................................................. 110 CASTOR OIL.......................................................................................................................................................... 112 CAUSTIC SODA SOLUTION .................................................................................................................................. 114 CERECLORS ......................................................................................................................................................... 116 CHINA CLAY SLURRY ........................................................................................................................................... 117 CHLOROBENZENE ............................................................................................................................................... 119 CHLOROFORM ...................................................................................................................................................... 121 CHLOROPRENE .................................................................................................................................................... 124 CHLOROSULFONIC ACID ..................................................................................................................................... 126 CHOLINE CHLORIDE ............................................................................................................................................ 129 COCONUT OIL....................................................................................................................................................... 131

COD LIVER OIL ..................................................................................................................................................... 132 CORN OIL .............................................................................................................................................................. 133 CORN STEEP LIQUOR .......................................................................................................................................... 135 COTTON SEED OIL ............................................................................................................................................... 136 CRESYLIC ACID .................................................................................................................................................... 138 CROTONALDEHYDE ............................................................................................................................................. 140 CRUDE/ PALM OILS .............................................................................................................................................. 143 CUMENE ................................................................................................................................................................ 145 CYCLOHEPTANE .................................................................................................................................................. 147 CYCLOHEXANE..................................................................................................................................................... 149 CYCLOHEXANOL .................................................................................................................................................. 152 CYCLOHEXANONE ............................................................................................................................................... 154 CYCLOHEXYLAMINE ............................................................................................................................................ 157 1,1-DICHLOROETHANE ........................................................................................................................................ 160 1,3-DICHLOROPROPENE (DD Soil Fumigant) ...................................................................................................... 162 iso-DECALDEHYDE ............................................................................................................................................... 165 DECALIN ................................................................................................................................................................ 167 DECANE ................................................................................................................................................................ 169 n-DECYL ALCOHOL............................................................................................................................................... 171 iso-DECYL ACRYLATE .......................................................................................................................................... 173 DIACETONE ALCOHOL ......................................................................................................................................... 174 o-DICHLOROBENZENE ......................................................................................................................................... 177 1-2 DICHLOROETHYLENE .................................................................................................................................... 181 2,2-DICHLOROETHYL ETHER .............................................................................................................................. 182 DICHLOROMETHANE ........................................................................................................................................... 186 DICYCLOPENTADIENE ......................................................................................................................................... 188 DIETHANOLAMINE ................................................................................................................................................ 191 DIETHYLAMINE ..................................................................................................................................................... 193 DIETHYLBENZENE................................................................................................................................................ 196 DIETHYLENE GLYCOL .......................................................................................................................................... 199 DIETHYLENE GLYCOL BUTYL ETHER ................................................................................................................. 200 DIETHLENE GLYCOL ETHYL ETHER ................................................................................................................... 202 DIETHYLENE GLYCOL MONOMETHYL ETHER ................................................................................................... 204 DIETHYLENE TRIAMINE ....................................................................................................................................... 206 DIETHYL ETHER ................................................................................................................................................... 208 DIISOBUTYLENE ................................................................................................................................................... 210 DIISOBUTYL KETONE ........................................................................................................................................... 212 DIISOBUTYL PHTHALATE .................................................................................................................................... 215 DIISODECYL PHTHALATE .................................................................................................................................... 216 DIISONOYL PHTHALATE ...................................................................................................................................... 218 DIISOOCTYL PHTHALATE .................................................................................................................................... 220 DIISOPROPYLAMINE ............................................................................................................................................ 222 DIMETHYLAMINE SOLUTION,40 % ...................................................................................................................... 225 DIMETHYLETHANOLAMINE.................................................................................................................................. 228 DIMETHYLFORMAMIDE ........................................................................................................................................ 230 DIMETHYLPHENOL ............................................................................................................................................... 233 DIOCTYL PHTHALATE .......................................................................................................................................... 236 DIPENTENE ........................................................................................................................................................... 237 DIPHENYLMETHANE DIISOCYANATE(MDI)......................................................................................................... 239 DIPROPYLENE GLYCOL ....................................................................................................................................... 243 DIPROPYLENE GLYCOL MONOMETHYL ETHER ................................................................................................ 244 DOBANIC ............................................................................................................................................................... 245 DOBANOL 23 c12-c13 25 C12 -C15, 45 C14-C15 ................................................................................................ 246 DOBANOL 25-3 ...................................................................................................................................................... 248 DODECANOL ......................................................................................................................................................... 250 DODECYL BENZENE............................................................................................................................................. 252 DOWANOL P MIX .................................................................................................................................................. 254 DOWANOL TPM .................................................................................................................................................... 256 DOWFAX ............................................................................................................................................................... 257

DOWFROTH .......................................................................................................................................................... 258 DUTREX................................................................................................................................................................. 258 EPICHLROHYDRIN ................................................................................................................................................ 260 ETHYL ALCOHOL .................................................................................................................................................. 264 m-ETHANOLAMINE ............................................................................................................................................... 266 ETHYLENE GLYCOL ETHYL ETHER ACETATE ................................................................................................... 269 ETHYL ACETATE .................................................................................................................................................. 272 ETHYL ACRYLATE ................................................................................................................................................ 275 ETHYLAMINE......................................................................................................................................................... 278 ETHYL AMYL KETONE .......................................................................................................................................... 280 ETHYLBENZENE ................................................................................................................................................... 282 ETHYLCYCLOHEXANE ......................................................................................................................................... 285 ETHYLENE CHLOROHYRIN .................................................................................................................................. 286 ETHYLENE CYANOHYDRIN .................................................................................................................................. 289 ETHYLENE DIAMINE ............................................................................................................................................. 290 ETHYLENE DIBROMIDE ........................................................................................................................................ 293 ETHYLENE DICHLORIDE ...................................................................................................................................... 295 ETHYLENE GLYCOL ............................................................................................................................................. 298 ETHYLENE GLYCOL BUTYL ETHER .................................................................................................................... 300 ETHYLENE GLYCOL MONOBUTYL ETHER ACTATE .......................................................................................... 303 ETHYLENE GLYCOL ETHYL ETHER .................................................................................................................... 305 ETHYLENE GLYCOL METHYL ETHER ................................................................................................................. 307 ETHYLENE GLYCOL MONO PHENYL ETHER...................................................................................................... 310 ETHYLENEIMINE ................................................................................................................................................... 311 2-ETHYL HEXANOL ............................................................................................................................................... 314 2 ETHYL HEXYL ACETATE ................................................................................................................................... 315 2-ETHYLHEXYL ACRYLATE .................................................................................................................................. 317 2 ETHYL 3 PROPYL ACROLEIN ............................................................................................................................ 319 EUCALYPTUS OIL ................................................................................................................................................. 320 FISH OIL ................................................................................................................................................................ 321 FORMALDEHYDE SOLUTION (37~50%) ............................................................................................................... 323 FORMAMIDE ......................................................................................................................................................... 326 FORMIC ACID ........................................................................................................................................................ 327 FURFURAL ............................................................................................................................................................ 329 FURFURYL ALCOHOL........................................................................................................................................... 332 FUSEL OIL ............................................................................................................................................................. 336 GAS OIL ................................................................................................................................................................. 337 GENKLENE ............................................................................................................................................................ 339 GLYCERINE ........................................................................................................................................................... 340 GLYOXAL 40% SOLUTION .................................................................................................................................... 344 GROUNDNUT OIL.................................................................................................................................................. 345 HEPTANE .............................................................................................................................................................. 347 1-HEPTANOL ......................................................................................................................................................... 349 HEPTENE .............................................................................................................................................................. 350 HEXAMETHYLENEIMINE ...................................................................................................................................... 352 n-HEXANE.............................................................................................................................................................. 355 HEXANOL .............................................................................................................................................................. 358 HEXYLENE GLYCOL ............................................................................................................................................. 360 HYDROCHLORIC ACID ......................................................................................................................................... 362 HYDROFLUORIC ACID.......................................................................................................................................... 365 2- HYDROXY ETHYL ACRYLAE ............................................................................................................................ 367 ISO AMYL ACETATE ............................................................................................................................................. 369 ISO BUTANOL ....................................................................................................................................................... 371 HEPTENE .............................................................................................................................................................. 372 ISO BUTYL ACRYLATE ......................................................................................................................................... 374 ISO BUTYL AMINE ................................................................................................................................................ 377 ISO BUTYRALDEHYDE ......................................................................................................................................... 379 ISO DECANOL ....................................................................................................................................................... 381 ISODECYL METHACRYLATE ................................................................................................................................ 383

ISO DODECANE .................................................................................................................................................... 384 iso-OCTYL ALCOHOL ............................................................................................................................................ 386 ISOPHORONE ....................................................................................................................................................... 387 ISOPAR M SOLVENT C,E,G,H,K,L,M .................................................................................................................... 389 ISOPRENE ............................................................................................................................................................. 393 iso-PROPYL ALCOHOL ......................................................................................................................................... 396 ISOPROPENYL BENZENE .................................................................................................................................... 400 ISO PROPYL ACETATE ........................................................................................................................................ 401 ISO PROPYL AMINE.............................................................................................................................................. 403 ISO PROPYL ETHER ............................................................................................................................................. 405 JET FUEL............................................................................................................................................................... 407 JET FUEL ADDITIVE.............................................................................................................................................. 409 KEROSENE ........................................................................................................................................................... 411 LARD OIL ............................................................................................................................................................... 414 LATEX (NATURAL ) ............................................................................................................................................... 416 LATEX (SYNTHETIC) ............................................................................................................................................. 417 LAURIC ACID ......................................................................................................................................................... 419 LEMON OIL ............................................................................................................................................................ 420 LINEVOLS .............................................................................................................................................................. 421 LINSEED OIL ......................................................................................................................................................... 423 LISSAPOLS............................................................................................................................................................ 425 MESITYL OXIDE .................................................................................................................................................... 426 META CRESOL ...................................................................................................................................................... 429 META PARA CRESOL ........................................................................................................................................... 431 META XYLENE ...................................................................................................................................................... 433 METHYL ALCOHOL ............................................................................................................................................... 434 METHYL ACETATE................................................................................................................................................ 437 METHYL ACRYLATE ............................................................................................................................................. 440 METHYLAMYL ACETATE ...................................................................................................................................... 443 METHYLAMYL ALCOHOL...................................................................................................................................... 445 METHYL ETHYL KEYONE ..................................................................................................................................... 447 2-METHYL-5-ETHYL PYRIDINE ............................................................................................................................. 451 METHYL ISO AMYL KETONE ................................................................................................................................ 454 METHYL ISO BUTYL KETONE .............................................................................................................................. 456 METHYL METHACRYLATE MONOMER ................................................................................................................ 459 MOLASSES............................................................................................................................................................ 461 MONO METHYL ETHANOLAMINE ........................................................................................................................ 463 MORPHOLINE ....................................................................................................................................................... 464 iso-AMYL ACETATE ............................................................................................................................................... 467 NAPHTHA: stoddard solvent................................................................................................................................... 470 NAPHTHA , SOLVENT ........................................................................................................................................... 473 NAPTHENIC ACIDS ............................................................................................................................................... 475 NIAX POLYOL ........................................................................................................................................................ 478 NITRIC ACID (56~68%) .......................................................................................................................................... 480 NITROBENZENE ................................................................................................................................................... 483 NITROETHANE ...................................................................................................................................................... 486 1-NITROPROPANE ................................................................................................................................................ 487 2-NITROPROPANE ................................................................................................................................................ 490 NONANE ................................................................................................................................................................ 493 NONIDET NP40 ................................................................................................................................................... 496 NONYL ALCOHOL ................................................................................................................................................. 497 NONYL PHENOL.................................................................................................................................................... 499 PENTANE .............................................................................................................................................................. 500 n-PROPYL ACETATE ............................................................................................................................................ 503 NYLON 6:6 SALT ................................................................................................................................................... 506 iso-OCTYL ALCOHOL ............................................................................................................................................ 507 OCTENE ................................................................................................................................................................ 509 OLEFFINS .............................................................................................................................................................. 511 OLIVER OIL ........................................................................................................................................................... 514

ORANGE OIL OF TURPENTINE ............................................................................................................................ 516 ORTHO CRESOL ................................................................................................................................................... 518 OLEIC ACID ........................................................................................................................................................... 521 ORTHO NITROCHLOROBENZENE ....................................................................................................................... 522 ORTHONITROTOLUENE ....................................................................................................................................... 525 ORTHO-XYLENE ................................................................................................................................................... 527 PALM KERNEL OIL ................................................................................................................................................ 529 (PARA) CHLOROTOLUENE................................................................................................................................... 531 CRESOLS .............................................................................................................................................................. 534 p-CYMENE ............................................................................................................................................................. 537 PARAFFIN WAX .................................................................................................................................................... 539 PARALDEHYDE ..................................................................................................................................................... 541 para-XYLENE ......................................................................................................................................................... 544 PENTACHLOROETHANE ...................................................................................................................................... 547 iso-PENTANE ......................................................................................................................................................... 550 1-PENTENE ........................................................................................................................................................... 552 PERRILLA OIL ....................................................................................................................................................... 556 PHENOL................................................................................................................................................................. 561 PHOSPHORIC ACID .............................................................................................................................................. 564 PINE OIL ................................................................................................................................................................ 566 POLYETHYLENE GLYCOL .................................................................................................................................... 568 POLYPROPYLENE GLYCOL ................................................................................................................................. 570 POTASSIUM HYDROXIDE (SOLUTION) ............................................................................................................... 572 n-PROPYL ALCOHOL ............................................................................................................................................ 574 PROPIONALDEHYDE ............................................................................................................................................ 577 PORPIONIC ACID .................................................................................................................................................. 579 PROPIONIC ANHYDRIDE ...................................................................................................................................... 582 PROPYLAMINE ...................................................................................................................................................... 585 PROPYLENE DICHLORIDE ................................................................................................................................... 589 PROPYLENE GLYCOL .......................................................................................................................................... 590 PROPYLENE GLYCOL MONOMETHYL ETHER ................................................................................................... 592 PROPYLENE OXIDE .............................................................................................................................................. 594 PROPYLENE TETRAMER ..................................................................................................................................... 597 PROPYLENE TRIMER ........................................................................................................................................... 599 PYRIDINE .............................................................................................................................................................. 601 RAPE SEED OIL .................................................................................................................................................... 604 RESIN PLASTICIZER............................................................................................................................................. 606 SANDALWOOD OIL (EastIndian) ........................................................................................................................... 608 SESAME OIL.......................................................................................................................................................... 608 SHELLFLEX - VARIOUS GRADES(Duflex) ............................................................................................................ 610 SOFTANOL ............................................................................................................................................................ 614 SOLVESS 100/150 ................................................................................................................................................. 616 SORBITOL ............................................................................................................................................................. 618 SOYBEAN OIL ....................................................................................................................................................... 620 SPERM ,WHALE OIL ............................................................................................................................................. 622 STYRENE MONOMER ........................................................................................................................................... 624 SULFURIC ACID .................................................................................................................................................... 627 SULPHURIC ACID (FUMING ) ............................................................................................................................... 630 SAFFLOWER OIL .................................................................................................................................................. 632 SUNFLOWER SEED OIL ....................................................................................................................................... 633 SYNPERONICS ..................................................................................................................................................... 635 TALL OIL ................................................................................................................................................................ 637 TALLOW ................................................................................................................................................................ 639 TAR ACID............................................................................................................................................................... 641 TEE FROTH ........................................................................................................................................................... 643 TEEPOL ................................................................................................................................................................. 644 1,1,2,2-TETRACHLOROETHANE .......................................................................................................................... 645 TETRACHLOROETHYLENE .................................................................................................................................. 647 TETRAETHYLENE GLYCOL .................................................................................................................................. 650

TETRAHYDROFURAN ........................................................................................................................................... 652 TETRAHYDRONAPHTHALENE ............................................................................................................................. 655 TETRAPROPYLENE BENZENE............................................................................................................................. 658 TOLUENE .............................................................................................................................................................. 659 TOLUENE DIISOCYANATE (T.D.I) ........................................................................................................................ 662 TRIBUTUL PHOSPHATE ....................................................................................................................................... 665 1,1,1-TRICHLOROETHANE ................................................................................................................................... 667 1,1,2-TRICHLOROETHANE ................................................................................................................................... 669 TRICHLOROETHYLENE ........................................................................................................................................ 671 TRIDECANOL ........................................................................................................................................................ 674 TRIETHANOLAMINE.............................................................................................................................................. 676 TRIETHYLAMINE ................................................................................................................................................... 678 TRIETHYLBENZENE ............................................................................................................................................. 681 TRIETHYLENE GLYCOL........................................................................................................................................ 682 TRIETHYLENE TETRAMINE.................................................................................................................................. 684 TRICRESTYL PHOSPHATE................................................................................................................................... 687 TRIXYLYL PHOSPHATE ........................................................................................................................................ 690 TUNG OIL .............................................................................................................................................................. 692 TURPENTINE......................................................................................................................................................... 694 UNDECANE ........................................................................................................................................................... 696 UREA/ AMMONIA SOLUTION................................................................................................................................ 698 UREA-AMMONIUM NITRATE SOLUTION(more than 2% free ammonia)............................................................... 700 UREA/ FORMALDEHYDE SOLUTION ................................................................................................................... 702 n-VALERALDEHYDE.............................................................................................................................................. 704 VEOVA 10............................................................................................................................................................ 709 VERSATIC 911....................................................................................................................................................... 710 VINYL ACETATE MONOMER ................................................................................................................................ 711 VINYL ETHYL ETHER ............................................................................................................................................ 714 VINYLIDENE CHLORIDE ....................................................................................................................................... 717 VORANOL .............................................................................................................................................................. 720 WHITE SPIRIT ....................................................................................................................................................... 722 XYLENE ( MIXED ISOMERS) ................................................................................................................................. 723

APPENDIX-1 SPECIAL CARGO HANDLING MANUAL ...................................................................................... 725 ACRYLIC ACID (ESTER GRADE)................................................................................................................... 725 ACRYLONITRILE ............................................................................................................................................ 732 PROPYLENE OXIDE ...................................................................................................................................... 736 CAPROLACTAM ( PURE ) .............................................................................................................................. 744 FORMIC ACID ................................................................................................................................................ 751 HEXAMETHYLENE DIAMINE SOLUTION. ..................................................................................................... 756 ISOCYANATES (MDI, PAPI, TDI) ................................................................................................................... 762 NATURAL LATEX ........................................................................................................................................... 776 PHOSPHORIC ACID (75~85%/WET) ............................................................................................................. 780 SULFURIC ACID ............................................................................................................................................. 786 TALL OIL (CRUDE) ......................................................................................................................................... 791 APPENDIX-2 Wall Wash & Berth Information ................................................................................................... 795 WALL WASH SPECS: .................................................................................................................................... 795 ARGO WALLWASH SPECS ........................................................................................................................... 796

CARGO WALLWASH SPECS CONT.............................................................................................................. 797 ARCO CARGO WALLWASH SPECS** ........................................................................................................... 798 HOECHST CELANESE CARGO WALLWASH SPECS ................................................................................... 799 HISTORICAL PRE-WASH INFORMATION ..................................................................................................... 800 BERTH INFORMATION IN HOUSTON AREAS .............................................................................................. 801 APPENDIX 3 TANK PREPARATION TO WALL WASH SPECIFICATION .......................................................... 803 GENERAL GUIDELINE ................................................................................................................................... 803 METHANOL TESTING PROCEDURES- METHANOL TEST KIT .................................................................... 804 WALL WASH PROCEDURE ........................................................................................................................... 805 TESTING FOR HYDROCARBONS ................................................................................................................. 806 TESTING FOR CHLORIDES .......................................................................................................................... 806 PERMANGANATE TIME TEST ....................................................................................................................... 806 SUGGESTIONS .............................................................................................................................................. 807 METHANOL SPECIFICATIONS BY LOAD PORT AND SUPPLIER ................................................................ 807 METHANOL WALL WASH SPECIFICATION .................................................................................................. 808 SITRA (BARAIN) METHANOL ........................................................................................................................ 808 KITMAT B.C METHANOL ............................................................................................................................... 809 VANCOUVER BC METHANOL ....................................................................................................................... 810 CAPE HORN METHANOL .............................................................................................................................. 810 LABUAN METHANOL ..................................................................................................................................... 811 NEW PLYMOUTH METHANOL (FLETCHER CHALANGE/PETRALGAS) ...................................................... 811 POINT LISAS (TRINIDAD) METHANOL.......................................................................................................... 812 Guidance when preparing the tank for an Ultra violet spectrum Test ................................................ 812 Guidance When preparing the tank for a Nonvolatile Matter test ....................................................... 813 MECHANICAL DAMAGE FROM TANK CLEANING MACHINES..................................................................... 813 LINE CLEANING GUIDELINES ....................................................................................................................... 814 NON-DESTRUCTIVE PRESSURE TESTING OF HEATING COILS ............................................................... 815 CLEANING , HANDLING AND STORAGE OF CARGO HOSES ..................................................................... 817

SYNONYMS / FIND PAGE NO.

A A.A A.C A.C.H AC45C A.D.N A.M.STYRENE A.N ACETALDEHYDE ACETIC ACID ACETIC ACID ISOBUTYL ESTER ACETIC ALDEHYDE ACETIC ANHYDRIDE ACETIC ETHER ACETIC OXIDE ACETONE 44 47 30 17 42 50 39 19 22 394 19 25 288 25 28 ACETONE CYANOHYDRIN ACETONITRILE ACETYL OXIDE ACETYLENE DICHLORIDE ACETYLENE TETRACHLORIDE ACETYLENE TRICHLORIDE ACROLEIC ACID ACRYLIC ACID ACRYLIC ACID ETHYL ESTER ACRYLIC ACID METHYL ESTER ACRYLIC RESIN MONOMER ACRYLONITRILE ADIPONITRILE ADRONOL A-HYDROXYISOBUTYRONITRILE ALCOHOL C7 30 33 25 192 686 714 36 36 291 467 487 39 42 162 30 369

ALCOHOL C8 ALCOHOL C9 ALCOHOL C10 ALDEHYDE ALDEHYDE COLLIDENE ALDEHYDINE ALKANE ALKYLBENZENE ALKYL PHENOL POLYGLYCOL ETHER ALIZARIN OIL ALYL ALCOHOL ALLYL CHLORIDE ALPHA METHYL STYRENE ALPHA N AMYLENE ALPHA OCTENE ALPHA OLEFINS ALPHANOL 79 AMINO CYCLOHEXANE AMINOBENZENE AMINO ETHANE AMINOETHANOLAMINE 1 AMINOPROPANE 2 AMINOPROPANE AMMONIA AQUEOUS AMMONIA HYDRATES AMMONIA HYDROXIDE AMYL ACETATE AMYL ACETIC ESTER AMYLACETIC ESTER AMYL ALCOHOL AMYL ADEHYDE AMYL HIDRIDE ANILINE ANILINE OIL AQUA FORTIS ARACHIS OIL ARKOPAL N130#n150 AROMASOL H ARTIFICIAL ANT OIL AZACYCLOPROPANE AZIRIDENE B BABASSU OIL BANANA OIL BBP BENE OIL BENZAPHENOL BEZENE BENZOL BETA METHYL PROPYLETHANOATE BETA-N-AMYLENE B-HYDROXYPROPIONTRILE B-METHYL ACROLEIN B-TRICHLOROETHANE BISOFLEX 88 BOILED LINSEED OIL BRAZILIAN PALM OIL BUTALDEHYDE

539 518 182 19 479 479 267 267 67 119 44 47 50 588 541 553 53 167 64 297 64 623 427 56 56 56 58 496 58 61 749 532 64 64 510 365 67 69 349 330 330

BUTANAL BUTANOL 2 BUTANOL BUTAN-2-OL 1-3 BUTANEDIOL BUTANOIC ACID 2 BUTANONE 2 BUTENAL 2 BUTOXYETHANOL BUTYL ACETATE BUTYL ACRYLATE 2 BUTYL ALCOHOL BUTYL BENZYL PHTHALATE BUTYL CARBINOL BUTYL CELLOSOLVE BUTYL DIOXITAL BUTYL ETHANOATE BUTYL ETHER BUTYL METHACRYLATE BUTYL METHACRYLATE MONOMER 1-3-BUTYLENE GLYCOL BUTYL OXITOL BUTYRALDEHYDE BUTYRIC ACID BUTYRIC ALCOHOL BUTYRIC ALDEHYDE BRAKE FLUID C CAJEPUTOL CALCIUM CHLORIDE LIQUOR CAMPHOR OIL CARADATE 30 CARADOL CARBITOL SOLVENT CARBOLIC ACID CARBOLIC OIL CARBON BISULPHIDE CARBON DICHLORIDE CARBON DISULPHIDE CARBON TETRACHLORIDE CARDANOL CARDURA E CASHEW NUT OIL CASTOR OIL CASTOR OIL SULPHORATED CAUSIC POTACH LIQUOR CAUSTIC POTASH SOLUTION CAUSTIC SODA SOLUTION CERECLORS CELLOSOLVE ACETATE CELLOSOLVE SOLVENT CHINA CLAY SLURRY CHINA WOOD OIL CHINESE BEAN OIL CHLORINATED HYDROCHLORIC ETHER CHLOROBENZENE CHLOROBENZOL 2-CHLOROBUTADIENE

98 77 86 86 90 100 475 149 318 80 83 86 89 213 318 213 80 92 95 95 90 318 98 100 77 98 75

70 390 89 647 597 72 72 394 588 306 149 712 234 448 70 98

339 103 104 254 107 215 597 108 110 689 110 112 117 115 117 119 119 609 609 121 123 285 273 124 736 659 338 126 126 132

2-CHLOROETHANOL 2- CHLOROETHYL ALCOHOL CHLOROFORM CHLOROETHYLIDENE DICHLORIDE 4-CHLORO-1-METHYLBENZENE CHLOROMETHYL OXIRANE CHLOROPRENE 3-CHLOROPROPENE CHLOROPROPYLENE OXIDE CHLOROSULPHONIC ACID CHLOROSULPHURIC ACID CHLOROTHENE CHOLINE CHLORIDE CINENE CINEOL CINNAMENE CINANOL CIS-9-OCTADECENOIC ACID CITRUS FRUIT OILS COCONUT BUTTER COCONUT OIL COCONUT PALM OIL COD LIVER OIL COLAMINE COLZA OIL CORN OIL CORN STEEP LIQUOR COTTON OIL STEARIN COTTON SEED OIL CPO 4 CRESOL CRESYLIC ACID CROTONALDEHYDE CROTONIC ALDEHYDE CSO CTC CUMENE CUMOL 2 CYANOETHANOL CYANOMETHANE CYCLOHEPTANE CYCLOHEXANE CYCLOHEXANOL CYCLOHEXANONE CYCLOHEXYL ALCOHOL CYCLOHEXYLAMINE CYCLOTETRAMETHYLENE OXIDE D D.A.A. D.B.A D.B.P D.C.P.D D.D.B D.D.SOIL FUMIGANT D.D.S.F DEANOL DECAHYDRONAPTALENE DECALDEHYDE

303 303 129 712 565 276 132 47 276 134 134 709 137 252 339 663 663 558 445 139 139 139 141 282 642 142 144 145 145 152 568 147 149 149 145 112 154 154 306 33 157 159 162 164 162 167 694

DECANE DECANOL DECALIN DECYLACRYLATE DECYLACOHOL DECYLHYDRIDE D.E.G D.E.H.P DETERGENT ALKYLATE DIACETONE DIACETONE ALCOHOL 2,2 DIAMINO DIETHYLENE 1,2 DIAMINO ETHANE 1,2 DIAMINOETHYLAMINOETHANE 1,2 DIBROMETHANE DIBUTYL MALEATE DIBUTYL PHTHALATE DICHLORBUTADIENE DICHLORETHER DICHLOTOBENZENE 1,1 DICHLOROETHANE 1,2 DICHLOROETHANE 1,1 DICHLOROETHYLENE 1,2 DICHLOROETHYLENE DICHLORO ETHYL ETHER DICHLROROMETHANE 1,2, DICHLOROMETHANE DICYCLOPENTADIENE D.I.D.P DIETHANOLAMINE DIETHYLAMINE DIETHYL BENZENE DIETHYLENE GLYCOL

180 182 178 184 182 180 211 250

186 189 192 200 267 170 170 203 178 176

267 186 186 219 308 728 310 189 192 132 194 189 170 313 763 192 194 197 626 200 230 203 205 208 211 DIETHYLENE GLYCOL MONOBUTYL ETHER 213 DIETHYLENE GLYCOL MONOETHYL ETHER 215 DIETHYLENE GLYCOL MONOMETHYL ETHER 217 DIETHYLENE TRIAMINE 219 DIETHYLENIMIDE OXIDE 493 DIETHYLETHER 221 DIETHYLHEXYL PHTHALATE 250 1,4 DIEYANOBUTANE 42 2,2 DIHYDROXISOPROPYL ETHER 257 DIGLYCOL 211 DIGOL 211 DIISOBUTENE 223 DIISOBUTYLENE 223 DIISOBUTYL KETONE 225 DIISOBUTYL PHTHALATE 238 DIISODECYL PHTHALATE 230 DIISONONYL PHTHALATE 232 DIISOOCTYL PHTHALATE 234 DIISOPROPYLAMINE 236 DIISOPROPYLETHER 429 DIMETHYLAMINE AQUEOUS SOLUTION 239 DIMETHYLAMINOETHANOL 242 DIETHYL BENZENE 779 1,2 DIMETHYLBENZENE 560 1,3 DIMETHYLBENZENE 459 1,4 DIMEHTYLBENZENE 579

1,3 DIMETHYLBUTANOL DIMETHYLENIMINE DIMETHYLETHANOLAMINE DIMETHYLFORMAMIDE 2,6 DIMETHYL-H-HEPTANONE

472 330 242 245 225

2 E.H.A E.P.I EPICHLOROHYDRIN 1,2 EPOXYPROPANE ETHANAL 1,2 ETHANEDIAMINE ETHANEDIOL ETHANENITRILE ETHANOIC ACID ETHANOIC ANHYDRIDE ETHANOL ETHANOLAMINE ETHINYL TRICHLORIDE ETHOXOL ETHOXOL ACETATE EHTYL ACETATE ETHOXY ACETATE ETHYL ACETIC ACID ETHYL ACRYLATE ETHYL ALCOHOL ETHYL AMINE ETHYL AMYL KETONE ETHYL BEZENE ETHYL BENZOL EHTYL CARBINOL 258ETHYL CYCLOHEXANE EHTYL DIGLYCOL ETHYL DOGOL ETHYLENE ALCOHOL ETHYLENE CHLORIDE ETHYLENE CHLOROHYDRIN ETHYLENE CYANOHYDRIN ETHYLENE DIAMINE ETHYLENE DIBROMIDE ETHYLENE DICHLORIDE 2,2, THYLENE DIOXYDIETHANOL ETHYLENEIMINE ETHYLENE GLYCOL
ETHYLENE GLYCOL MONOBUTYL ETHER ETHYLENE Glycol Monoethyl Ether Acetate ETHYLENE Glycol Monobutyl ether acetate ETHYLENE GLYCOL MONOETHYL ETHER ETHYLENE GLYCOL MONOMETHYL ETHER ETHYLENE GLYCOL MONOPHENYL ETHER

336 276 276 632 363 308 316 33 22 25 279 282 714 323 285 288 285 100 291 279 297 299 299 302 302 215 217 316 313 303 306 308 310 313 726 330 316 318 285 321 323 326 329 689 714 288 288 323 332 334 336 332 338 86 475 282 221

DIMETHYLKEYTONE 28 DIMETHYLPHENOL 248 DIMETHYL PHENOL (FRACTIONS) 248 D.I.N.P 232 DIOCTYL PHTHALATE 250 D.I.O.P 234 DIOXITOL 215 DIPENTENE 252 DIPHENYL METHANE DIISOCYANATE 254 DIPROPYLENE GLYCOL 257 DIRPOPYLENE GLYCOL Monomethyl ether 259 DIPROPYLMETHANE 367 DISULPHURIC ACID 670 D-LIMONENE 549 D.M.A 239 D.M.F 245 D.M.K 28 DOBANE 267 DOBANIC 260 DOBANIC ACID 260 DOBANOL 23 261 DOBANOL 25 261 DOBANOL 25-3 263 DOBANOL 45 261 DODECANE 635 DODECANOIC ACID 444 DODECANOL 265 DODECYCLENE 635 DODECYL ALCOHOL 265 DODECYL BENZENE 267 D.O.P 250 DOWANOL DB 213 DOWANOL DE 215 DOWANOL DESG 215 DOWANOL DM 217 DOWANOL DPM 259 DOWANOL EB 318 DOWANOL EE 323 DOWANOL EM 326 DOWANOL PM 630 DOWANOL PMIX 269 DOWANOL TPM 271 DOWFAX 272 DOWFROTH 273 D.SORBITAL 657 D.SORBITLE 657 DUTCH OIL 313 DUTREX 274 E E.A.K E.C.H E.D.B E.D.C

297 276 310 313

EHTYLENE TETRACHLORIDE ETHYLENE TRICHLORIDE ETHYL ESTER ETHYL ETHANOATE ETHYL GLYCOL 2, ETHYL HEXANOL 2, ETHYL HEXYL ACETATE 2, ETHYL HEXYL ACRYLATE 2, EHTYL HEXYL ALCOHOL ETHYLIDENE CHLORIDE ETHYL METHYL CARBINOL ETHYL METHYL KETONE EHTYLOLAMINE ETHYL OXIDE

ETHYL OSYTOL 5, EHTYL 2 PICOLINE ETHYL PROPANOATE 2, EHTYL 2 PROPYL ACROLEIN ETHYL VINYL ETHER EUCALYPTUS OIL EUCAYPTOL E.V.E F FERMENTATION ALCOHOL FIR TREE OIL FISH OIL FLAXSEED OIL FLUORHYDRIC ACID FORMALDEHYDE AQUEOUS SOLUTION FORMALIN FORMAMIDE FORMDIMEHTYLAMIDE FORMIC ACID FURAL FURALDEHYDE FURALE DURFURALDEHYDE FURFURYL ALCOHOL FURURAL 2, FURYL CARBINOL FUSEL OIL GAS OIL GENKLENE GINGELLY OIL GLACIAL ACETIC ACID GLYCERENE GLYCEROL GLYCOL GLYCOL ALCOHOL GLYCOL BIS (HYDROXYETHYL) ETHER GLYCOL CHLOROHYDRIN GLYCOL DIBROMIDE GLYCOL ALCOHOL GLYOXAL 40% SOLUTION G-METHYL STYRENE GRAIN ALCOHOL GRAIN OIL GROUND NUT OIL GURJON OIL H H.E.A HEAVY AROMATIC NAPHTHA HENDECANE HEPTAMEHTYLENE HEPTANE HEPTANOL HEPTAN-1-OL HEPTENE HEPTYL ALCOHOL HEPTYLENE HEXAHYDRONILINE

323 479 291 339 760 339 339 760

276 603 340 448 386 342 342 345 245 346 349 349 349 349 352 349 352 355 357 359 647 22 360 360 360 316 726 303 310 360 363 423 279 355 365 736

HEXAHYDROBENZENE 159 HEXAHYDROBENZOIC ACID 504 HEXAHYRIC ALCOHOL 657 HEXALIN 162 HEXAMETHYLENE 159 HEXAMETHYLEN DIAMMONIUM ADIPATE 538 HEXAMETHYLENEIMINE 372 HEXANE 375 HEXANEDIOL 1-2 381 HEXANOL 378 1- HEXANOL 378 HEXAN -1-OL 378 HEXANON 164 HEXONE 484 HEXYLENE GLYCOL 381 HEXYL HYDRIDE 375 H.M.I 372 HUON -PINE OIL 603 HYDRACRYLONITRILE 306 HYDROGEN CARBOXYLIC ACID 346 HYDROGEN CHLORIDE SOLUTION 383 HYDROGEN NITRATE 510 HYDROFLOURIC ACID 386 1-HYDROMETHYL PROPANE 392 HYDROPHENOL 386 2-HYDROXY ETHYL ACRYLATE 388 HYDROXYETHYL ETHYLENE DIAMINE 54 2 Hydroxy Ethyl Trimethyl Ammonium Hydroxide 137 I I.D.A INDIAWOOD OIL I.P.A I.P.E ISOACETOPHENONE ISOAMYL ACETATE ISO BUTANAL ISO BUTANOL ISO BUTYL ACRYLATE ISO BUTYL ALCOHOL ISO BUTYL ALDEHYDE ISO BUTYL AMINE ISO BUTYL METHYL KETONE ISOBUTYRALDEHYDE ISOBYL CARBINOL ISO DECANOL ISO DECYL ACRYLATE ISO DECYL ALCOHOL ISO DECYL METHACRYLATE ISO DODECANE ISO OCTANOL ISO OCTYL ALCOHOL ISOPAR ISOPRENE ISOPROPANOL ISOPROPENYL BEZENE 2 ISOPROPOXYPROPANE ISO PROPYL ACETATE ISO PROPYL ALCOHOL

388 499 741 157 367 369 369 370 369 370 167

403 736 419 429 412 390 401 392 396 392 401 399 484 401 355 403 184 403 405 406 408 408 412 416 419 423 429 425 419

ISO PROPYLAMINE ISO PROPYL BENZENE ISO PROPYL CARBINOL ISO PROPYL ETHER ISO PROPYIDENE ACETONE ISO PROPYL TOLUENE ISO VALERONE ISO PHORONE J JET FUEL ADDITIVE JET FUEL (J.P) K KAOLIN SLURRY KEROSENE KEROSINE KETOHEXAMETHYLENE L LARD OIL LAREX LATEX (NATURAL) LATEX(SYNTHETIC) LAURIC ACID LAURYL ALCOHOL LEMON OIL LENNING SOLVENT N0.2 LENNING SOLVENT NO.13 LIGHT INDUSTRIAL DIESSEL OIL LOMONENE LIMONIS OIL LINSEED OIL LISSAPOL LIQUID CAMPHOR LIQUID RESIN LONNING SOLVENT NO.5 LUBADO L LUBE ADDITIVES LUBE OILS LYE LYE SOLUTION LINEVOLS M MAIZE OIL M-CRESOL M-CRESYLIC ACID M.D.I M- DIBUTYL ETHER M.E.A M.E.C M.E.G M.E.K M.E.P MESITYL OXIDE META CRESOL META PARA CRESOL META XYLENE METYL ACETATE METHANAMIDE

427 154 392 429 451 571 225 410 433 431

124 435 435 164

438 438 440 442 444 265 445 83 467 357 252 445 448 450 104 678 291 17 451 454 609 121 446 142 454 454 254 92 282 197 197 475 479 451 454 457 459 464 345

METHYL ACRYLATE METHANAL METHANE CARBOXYLIC METHANOIC ACID METHANOL METHYLACETIC ACID MEHTYL ALCOHOL METHYL ALDEHYDE METHYL AMYL ACETATE METHYL AMYL ALCOHOL MEHTYL BENZENE 3-METHYL-1-3-BUTADIENE METHYL CARBINOL METHYL CELLOSOLVE MEHTYL CYANIDE MEHTYL ETHYL KETONE 2 METHYL 5 ETHYL PYRIDENE METHYL GLYCOL 5 METHYL -3-HEPTANONE 5 MEHTYL -2-HEXANONE MEHTYL ISO AMYL KETONE METHYL ISO BUTYL CARBINOL

467 342 22 346 461 617 461 342 470 472 701 416 217 326 33 475 479 628 297 481 482 472 METHYL ISO BUTYL CARBINOL ACETATE 470 METHYL ISOBUTENE KETONE 451 METHYL ISO BUTYL KETONE 484 1-METHYL-4-Isopropenyl-1-CYCLOHEXENE 549 METHYL METHACRYLATE MONOMER 487 MEHTYLOXIRANE 632 METHYL OXITOL 326 4 METHYL PENTAL-2-OL 472 4 METHYL 2 PENTANONE 484 4 METHYL 3-PENTENE-2-ONE 451 2 MEHTYL PHENOL 551 3 METHYL PHENOL 454 4 METHYL PHENOL 568 M-MEHTYL PHENOL 454 2 METHYL PROPANOL 401 2 MEHTYL -1-PROPANOL 392 2 METHYLPROPYL ACRYLATE 396 MEHTYL PROPYLBENZENE 571 L-METHOXY-2-PROPANOL 630 METHYLENE Bis-Phenylene Diisocayanate 254 MEHTYLENE CHLORIDE 197 METHYLENE DICHLRIDE 197 MEHTYLENE OXIDE 342 MEHTYLETHYLENE GLYCOL 628 METYL CHLOROFORM 709 M.I.A.K M.I.B.C M.I.B.K MIDDLE OILS NERAL THINNERS M.M.M MOLASSES MONOCHLOROBENZENE MONOETHANOLAMINE MONOETHYLENE GLYCOL MONOHYDROXY BEZENE MONOETHYL ETHANOLAMINE 482 472 484 108 768 487 490 126 297 316 597 492

MONONITROBENZENE M.P CRESOL MORRHUAE MORRPHOLINE MURIATIC ACID N NAPTHA STANDARD SOLVENT N-AMYL ACETATE NAPTHA COAL TAR NAPTHA PETROLEUM NAPHTHA SOLVENT NAPHTHENIC ACIDS NAPTHENIC OIL RESIDUE N.B.A N-BUTANOL N- BUTYLACETATE N-BUTYLAMINE N-BUTYL ACRYLATE N-BUTYL ALCOHOL N-BUTYL CARBINOL N-BUTYL ESTER N-BUTYL METHACRYLATE N-BMM N-HEPTANE N-HEPTANOL N-HEXANE N-NONYL ALCOHOL N-PARAFFIN N-PROPANOL N-PROPYL ACETATE N-PROPYLAMINE N-PROPYL ESTER NEOFLEX NIAX POLYOL NITRATION BENZENE NITRIC ACID NITROBENZENE NITROBENZOL NITROETHANE 2 NITROPANE NITROPROPANE 1-NITROPROPANE N,N, DIMETHYLFORMAMIDE NONANE NONANOL NONIDET NP40 NONIDET SB NONYL CARBINOL NONYL HYDRIDE NONYL PHENOL N.UNDECANE N.VALERALDEHYDE NYLON SALT NYLON -6-6-SALT O O-CRESYLIC ACID O-CRESYLOL OCTANOL

513 457 141 493 383 499 496 502 499 502 504 504 77 77 80 508 83 77 61 83 95 95 367 369 375 528 435 532 535 623 535 446 508 72 510 513 513 516 521 521 518 245 524 528 527 518 182 524 530 741 749 538 538

OCTENE 1-OCTENE 2OCTENE OCTYL ACRYLATE OCTYL ALCOHOL OCTYL CARBINOL O.D.C.B. O-DICHLOROBENZOL O-HYDROXYTOLUENE OIL OF NIRBANE OLEFFINS OLEIC ACID OLEINE OLEUM OLIVE OIL O.N.C.B. O.N.T O-NITROTOLUOL ORANGE OIL OF TURPENTINE ORTHO CHLORO NITROBENZENE ORTHO CRESOL ORTHO NITROCHLOROBENZENE ORTHO NITROTOLUENE ORTHO-METHYLNITROBENZENE ORTHO PHOSPHORIC ACID ORTHO XYLENE OXALADEHYDE OXYISOBUTYRIC NITRILE O-XYLOL OXYTOL OXYTOL ACETATE P PALM ACID TREATED PALM KERNEL OIL PALM LOTOX PALM OIL (CRUDE) PALM OLEIN PALM STEARINE PARACERALDEHYDE PARACHLOROTOLUENE PARAFFIN PARAFFIN WAX PARAFFINIC PARACRESOL PARADEHYDE PARANONYL PHENOL PARA XYLENE P.B.S.Y P.CRESYLIC ACID P-CYMENE PEANUT OIL PEAR OIL P.E.E.G P.E.G. PENTACHLOROETHANE PENTALIN PENTA METHYL HEPTANE PENTANAL

541 541 541 336 539 528 189 189 538 513 543 553 558 670 547 555 558 558 549 555 551 555 558 558 600 560 363 30 560 323 285

152 2563 152 152 152 152 576 565 435 574 499 568 576 530 579 145 568 571 365 390 316 607 582 582 406 749

538 538 539

PENTANE (MIXED ISOMERS) 1PENTENE PENTANOL 1PENTANOL ACETATE 2PENTENE PERCHLOROETHYLENE PERCHLOROMETHANE PERILLA OIL PERKLONE PERSPIRIT PETROLEUM BENZENE PETROLEUM ETHER PETROLEUM SULPHONATES PETROLEUM THINNERS PHENOL PHENYLAMINE PHENYL CELLOSOLVE PHENYL CHLORIDE PHENYL ETHANE PHENYL ETHYLENE PHENYLIC ACID PHENYL METHANE 2 PHENYLOXYETHANOL 2 PHENYL PROPANE 2 PHENYL PROPENE PINE OIL PKO POLYSTER ETHYLENE GLYCOL POLYPROPYLENE GLYCOL POTASSIUM HYDRATE PHOSPHORIC ACID POLYETHLYLENE GLYCOL POTASSIUM HYDROXIDE SOLUTION POTATO OIL PPG PRIMARY AMYL ALCOHOL PROPANAL PROPANOIC ACID PROPANOIC ANHYDRIDE PROPANOL 1 PROPANOL 2 PRPANOL PROPANONE PROPENE DICHLORIDE PROPENE NITRILE PROPENE OXIDE PROPENOIC ACID PROPENOIC ACID NITRILE 2 PROPEN -1-OL PROPENYL ALCOHOL PRPION ALDEHYDE PROPIONIC ACID PROPIONIC ALDEHYDE PROPIONIC ANHYDRIDE PROPYLETHYLENE PROPYL ALCOHOL PROPYL ALDEHYDE PROPYLAMINE PROPYLAN

585 588 61 58 588 689 112 592 689 419 499 499 592 768 597 64 329 126 299 663 597 701 329 154 50 603 565 316 607 609 600 605 609 355 607 61 614 617 620 611 611 419 28 626 39 632 36 39 44 44 614 617 614 620 588 611 614 623 607

PROPYLENE ALDEHYDE PROPYLENE CHLORIDE PROPYLENE DICHLORIDE PROPYLENE GLYCOL PROPYLENE GLYCOL METHYL ETHER PROPYLENE Glycol Monoehtyl Ether PROPYLENE OXIDE PROPYLENE TETRAMAR PROPYLENE TRIGLYCOL ETHER PROPYLENE TRIMER PROPYFORMIC ACID PROPYLIC ALDEHYDE P-XYLENE P-XYLOL PYRIDINE PYROSULPHURIC ACID R RAPE SEED OIL RAPE OIL RAW LINSEED OIL RBD PALM OIL RED OIL REFINED WAX RESIN PLASTICIZER RICIRUS OIL S SAFETY SOLVENT SAFFLOWER OIL SANDAL OIL SANDALWOOD OIL SANTAL OIL SANTAL WOOD OIL SANTICIZER 160 S.B.O SEC BUTYL ALCOHOL SEC HEXYL ACETATE SEED OIL SESAME OIL SEXTONE SHELL NEOFLEX SHELL FLEX SHELLSOL SODIUM HYDRATE SODIUM HYDROXIDE SOLUTION SOFTANOL SOLUABLE CASTER OIL SOLVENT ETHER BP SOLVESSO 100 SOLVESSO 150 SORBITOL SOYA BEAN OIL SOYBEAN OIL SPERM OIL SPIRIT OF TURPENTINE STYRENE MONOMER SUBRENE SUBST. OF TURPENTINE SULFURIC CHLOROHYDRIN

149 626 626 628 630 630 632 635 107 637 100 614 579 579 639 670 642 642 448 152 558 574 644 119

768 672 646 646 646 646 89 659 86 470 145 647 164 446 649 649 121 121 653 119 221 655 655 657 659 659 661 714 663 157 738 134

SULPHURIC ACID FUMING SULPHURIC ETHER SUNFLOWER SEED OIL SUNFLOWER OIL SWEET OIL SYM-METHYETHYLENE SYNPERONICS SULFURIC ACID T TALLOW TALL OIL TALLOL TAR ACID T.D.I T.E.A. TEEFROTH A TEEFROTH D TEEL OIL TEEPOL T.E.G TETRACHLOROETHANE TETRACHLOROETHYLENE TETRACHLOROMETHANE TETRAETHYLENE GLYCOL TETRAHYDROFURAN TETRAHYDRONAPTHALENE TETRAHYDRO -1-4-OXAZINE TETRALIN TETRAMETHYLENE CYANIDE TETRAMETHYLENE OXIDE TETRAPROPYLENE TETRAPROPYLENE BENZENE T.H.F TOLUENE TOLUENE DIISOCYANATE TOLUOL TORIA OIL 1-2-4 TRETYLBENZENE TRIBUTYL PHOSPHATE 1-1-1 TRICHLOETHANE 1-1-2 TRICHLOROETHANE TRICHLROETHYLENE TRICHLOROMETHANE TRICRESYL PHOSPHATE TRIDECANOL TRIDECYL ALCOHOL TRI (DIMETHYLPHENOL) PHOSPHATE TRIETHANOLAMINE TRIETHYLAMINE TRIETHYL BENZENE TRIETHYLENE TETRAMINE TRI (2 HYDROXYETHYLAMINE) T.R.I TRIMETHYLAMINE TRIMETHYL CYCLOHEXENONE 2-4-6 TRIMETHYL 1-3-5 TIOXANE TRIPROPYLENE TRIPROPYLENE Glycol Monomethyl Ether

670 221 674 674 547 588 676 667 680 678 678 682 701 719 684 684 647 685 726 686 689 112 692 694 697 493 697 42 694 635 700 694 701 704 701 642 724 707 709 712 714 129 731 717 717 734 719 721 724 728 719 714 721 412 576 637 271

TRITOLYL PHOSPHATE TRIXYLENYL PHOSPHATE TRIXYLYL PHOSPHATE T.T.P TUNG OIL TURKEY RED OIL TRUPENTINE OIL TURPENTINE SUBST. TURPS OIL T.X.P U UNDECANE UNFINISHED NAPHTHA URAN UREA AMMONIA NITRATE SOLUTION UREA AMMONIA SOLUTION UREA FORMADEHYDE SOLUTION V VALERAL VALERALDEHYDE VALERIC ALDEHYDE V.A.M VARSOL V.C VEOVA 10 VERSATIC 9-II VINEGAR ACID VINEGAR NAPHTHA VINYL ACETATE MONOMER VINYL ACETATE MONOMER(INHIBITOR) VINYL BENZENE VINYL CYANIDE VINYL ETHYL ETHER VINYLIDENE CHLORIDE VINYL TRICHLORIDE VIRSIN VORANOL W WATER OF AMMONIA WHALE OIL WHITE SPIRIT WOOOD ALCOHOL WOOD OIL X X-METHYL STYRENE X MONO CHLORIPROPYLENE XYLENE XYLENOL XYLOL Y YELLOW SARSON OIL

731 734 734 731 736 119 738 768 738 734

741 499 745 745 743 747

749 749 749 757 749 763 754 756 22 288 757 757 663 39 760 763 712 499 766

56 661 768 461 736

50 47 770 147 770

642

AC -45-C
Synonyms : IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Correction factor Heating Range (Subject to Chart.Reg.) Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : LUBAD L N/A N/A Complex mixture 1/a 4.5% wt of super-basic calcium salt of alkyl salicylic acid in oil. Dark brown viscous liquid, Smell of heavy mineral Oils. 0.985/1.010 @ 20 C

20 ~30 C. 40 C.

General neutral Bondstrand , Compoflex or ships lines. No( Ensure Certificate obtained and Duration Checked) Purge : Blanket : Yes

: Stainless steel, Polyurethane or Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 160 C Draeger Tube No. Boiling Point : N/A Explosive Range : N/A Freeze Point : N/A Autoignition Point : N/A Operational Problems/Hazardous No serious hazardous, May require vent line desiccate for quality control. Forms emulsions with small amounts of water. Load via droplines for quality control. Personnel Protection; Boiler suit and rubber gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :A Vapor Return System Reg. : NO Dispose of residues to bunker tanks or shore reception facilities.

Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : N/A

Hot wash with chemical injection, Fresh water rinse or steam Educt and Mop NOTE : This is a persistent oil based cargo. Residues should be settled out in a slop tank and transferred to bunkers. (B) Cleaning to : (Beyond Solvent Standard) See index under Lube Additives for further information.

ACETALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Carriage Temp. Average Expected Load temp Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen (Subject to charteres Reg. ) Purge Blanket Tank Coating Fire & Explosion Hazard Data Grade- A Electrical Group : : : : : : : : : : : : : : : : : : : : : Acetic aldehyde; Aldehyde; Ethanal; Ethyl aldehyde 1089 AAD 3 CH CHO Colorless liquid, Pungent suffocating odor; fruity odor when diluted. 21C/ 70F -121C/ 186F 0.7846 Correction factor : 0.00132/C. Ambient Disch. : Ambient Ambient or below Aldehyde 755mmHg C C 25.6 O 36.0 Complete 1.52 Ships Lines or compoflex NOT Bondstrand. Yes (Ensure Certificate obtained and duration checked)

: Yes : Yes : Polyurethane with restrictions, Stainless steel

: Flammable liquid :C

General: Products irritating vapor when heated. if pressure is used to unload tank, nitrogen or other gas mist be used. Air pressure may cause explosive peroxides to form. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : -36(cc) 4.0 to 57% 365 Co2,dry chemical, alcohol form, water fog.

Special fire Procedures Avoid exposure to vapor. Wear self-contained breathing apparatus. use water fog on large fires. Use hose streams at maximum range to cool exposed tanks. fight fire from a safe distance or from a protected location. Health Hazard Data Health hazard Rating Odor Threshold(ppm)

: 3,1,2 : 2.3

PEL/TWA(ppm) TLV/TWA(ppm)

: 100 : 100

General Suspected carcinogen. Vapor irritating; liquid causes skin and eye burns. Symptoms Burning of eyes, nose and throat, headache, rapid heartbeat, possible drowsiness with prolonged exposure. Short Exposure Tolerance: 1,100ppm for 2 hours is severely irritating to mucous membrane; 11,000ppm for 1-2 hrs has been reported fatal. Exposure Procedure : Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15min. Get medical advice or attention. Reactivity : Dangerous reactions with oxidizing agents, halogens, amines, alcohols, Ketonnes, Acids anhydride, Phenols and Anhydrous ammonia. Stability: Highly reactive. can form explosive peroxides under air pressure. slowly polymerizes to paraldehyde. Can react vigorously with oxidizing materials. explodes when mixed with iodine. Compatibility: Material; negligible corrosion to mild steel. may dissolve rubber. Cargo : group 19 of compatibility Spill or Leak Procedure If possible, wear rubber gloves, self-contained breathing apparatus and protective clothing. Cover spill with sodium bisulfate (NaHSO3) add small amount of water and mix. scoop up. Wash site with soap solution. secure ignition sources. Operational Problems/hazards A very reactive compound which can form explosive oxides under air pressure. Must be carried refrigerated or under pressure. Gaseous at ambient temperature. Personnel Protection Chemical protective suit, gloves and goggles, Breathing apparatus available. Vapor Return System : Probable

Tank Cleaning: Cold water rinse to remove residues, Ventilate to gas and odor free, Fresh Water rinse, Educt and mop. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. POTENTIAL HAZARDS FIRE OR EXPLOSION

Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ACETIC ACID (glacial)

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Acetic acidglacial; Ethanoic acid, Glacial acetic acid; Methane carboxylic; Vinegar acid : 10% ~80% 2790 Glacial, >80% 2789 : AAC 3 : CH COOH : Colorless liquid; pungent vinegar like odor. : 118C/ 245F

Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Nitrogen (Subject to charterers Reg. ) Tank Coating Draeger Tube No. Temp Carriage Disch . Fire & Explosion Hazard Data Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

: 17C/ 62F : 1.05 : Organic acid. : 11.3 :D :D : 0.60 :O : 0.92 : Complete : 2.07 Solidifies at 17 C Load via ships line . Ensure lines absolutely dry , Highly corrosive. : Purge : Yes Blanket : Yes : Stainless steel only 321,316,318 grades. : 6722101 Acetic Acid 5/a : 20-35C : 20- 35C Average load temp : 35 C

: Combustible liquid :D Ignited by heat and by some oxidizing agents. Vapor may explode if ignited an enclosed area : 110 : 5.4 to 16% at 212F : 1050 2 : Co , dry chemical, alcohol form, water fog.

Special fire Procedures: Use personal protective equipment when contact with liquid is likely. Skin or clothing contact can cause serious burns. Wear self-contained breathing apparatus. Cool exposed tank with water. Health Hazard Data Health hazard Rating : 2,3,2 Odor Threshold(ppm) : 1.0 PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Vapor extremely Irritating. liquid causes severe burns. Symptoms: Burning of skin in contact with liquid. Irritation of eyes and respiratory system. Short Exposure Tolerance : 40ppm for 5 minutes. Exposure Procedure: Vapor-remove victim to fresh air; if breathing is stops, apply artificial respiratory. Skin or eye contact-remove contaminated clothing and gentle flush affected areas with water for 15 min. Get medical attention. Wash contaminated clothing, including shoes, before reuse Reactivity Stability: Can react vigorously with oxidizing materials. Reacts violently with potassium hydroxide caustic potash) and sodium hydroxide(Caustic soda). Compatibility: Material; highly corrosive to metals when dilute.316 and 318 stainless steels and aluminum are satisfactory construction

Materials. Cargo : Group 4 of compatibility chart. See also appendix 1- exceptions to the chart. Spill or Leak Procedure: Secure ignition source. if possible, wear rubber gloves, face shield, and protective clothing. Body shield and self-contained breathing apparatus should be available. Cover spill soda ash or sodium bicarbonate. mix, and add water if necessary for mixing. scoop up slurry. Wash site with soda ash solution. flush spills with large quantities of water. Usually a spill into a navigable waterway would quickly dilute to a harmless concentration for humans. Remarks: Below 62F the acid may freeze and expand enough to burst its container. Operational Problems /Hazards Keep away from adjacent heat where temperature above 35 C. Corrosive properties intensify with progressive dilution therefore keep tanks and line free of water vapor. Cover spillage with large quantities of water. Vapors very irritant and corrosive. Liquid causes severe burns and in highly corrosive. Line should be cleared with Nitrogen. Personnel Protection: Total protective suit and breathing apparatus required. Secure accommodation and Recirculation air, Minimum personnel on deck during operations Use Closed ullaging systems. Vapor Return System Reg. : Yes Is quickly diluted to a point where it presents no danger. However, should be discharged on passage under regulation control conditions. Tank Cleaning : Wash with cold salt water for minimum of 3 hours to completely flush tank, line and pump, to reduce acid value of product as quickly as possible 5 ft 40 minute drops minimum. On completion cold wash - Thoroughly Steam tank and lines. Allow to cool, Ventilate, Educt and mop. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas

Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ACETIC ANHYDRIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water : : : : : : : : : : : : : : : : Acetic acid anhydrine, acetic oxide, acetyl oxide, ethanoic anhydride 1715 ACA 3 2 (CH CO) O Colorless liquid, pungent, highly irritating odor. 140C/ 284F -73C/ -100F 1.08 Acid anhydride 4.0 D D 0.3 O 0.4 12% Appreciable.

Vapor Density(air = 1.0)

: 3.5

Handling : Use only ships lines which must be absolutely dry. Highly corrosive. May require desiccator. Do not use Bandstand Nitrogen (Subject to charteres Reg.) Purge : Yes Blanket : Yes Tank Coating : Stainless steel 316 Grade only. Draeger Tube No : 6722101 Acetic acid 5/a Fire & Explosion Hazard Data Grade- D Electrical Group

: Combustible liquid :D

General: React violently with water generating dangerous heat and press in confined spaces. Ignited by heat. Vapor may explode if ignited in an enclosed space. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 121(cc) 2.7~ 10% 734 CO2,alcohol foam, water fog or chemical.

Special fire Procedures : Cool outside of tanks with water spray. Apply water cautiously. Do not contaminate anhydride system with water. use self contained respiratory protection and clothing. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

3,3,3. 0.14 5 5

General : Vapor extremely irritating. Liquid causes severe burns. Symptoms: Coughing; burning sensation in nose and throat. severe eye and skin burns. warning properties are good because compound is highly irritating. Short Exposure Tolerance: Less than 40 ppm for 5 minutes. Exposure Procedure: Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- removes contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical attention. Reactivity Can explode when mixed with water. Gives off acetic. Dangerous with amines, Alkalis, acids, styrene and aniline Stability: Reacts with to form acetic acid and produces considerable heat. Reacts violently with potassium hydroxide(caustic potash) and sodium hydroxide(caustic soda). Compatibility: Material: Highly corrosive to iron and steel when moist. soften many plastics. Usually stored in aluminum or stainless steel tanks. Cargo: Group 11 of compatibility chart.

Spill or Leak Procedure Wear full protective clothing. body shield and self contained apparatus should be available. Secure ignition sources. if possible cover spill with soda ash or sodium bicarbonate. Mix and add water if necessary to effect good mixing. Scoop up slurry and wash site with soda ash solution. Usually a spill into a navigable waterway would quick dilute to a point where it would present little danger to humans. remarks: Avoid getting water into acetic anhydride tanks. Operational Problems/Hazards Highly flammable from adjacent heat, Although water causes reaction Any spill should be flushed off with copious quantities of water to dilute product. Highly corrosive both liquid and vapor cause severe burns. Liquid in eyes causes blindness. Personnel Protection : Total protection suit with breathing apparatus must be worn. Minimum personnel on deck. Secure accommodation and recirculate air during all operation. Use Close loading method of ullaging. Tank Cleaning Wash with cold salt water for minimum of 3 hours to flush completely tank, line and pump. On completion, thoroughly steam tank and lines, Ventilate to gas free, Educt and mop. lines and tank to be absolutely dry , Blow with Nitrogen. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. POTENTIAL HAZARDS HEALTH HAZARDS May be fatal if inhaled swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. May ignite other combustible materials (wood, paper, oil, etc) violent reaction with water. Flammable/poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. FIRE Do not get water inside container. 2 Small Fires: Dry chemical, Co Large Fires: Flood fire area with water from a distance do not get water inside container. Move container from fire area if you can do it without risk apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks.

SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor; do not put water directed on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Spills; Dike for later disposal; do not apply water unless directed to do so cleanup only under supervision of an expert. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature.

ACETONE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity : : : : : : : : : : : : : : Dimethyl Ketone (DMK) Propanone 1090 N/A 3 3 CH COCH 4 Ketone. Clear Colorless liquid, Sharp Odor - Smell of nail varnish remover 0.796 @ 15 C 0.00111 /C. Ambient . Ambient Ambient 18 Reacts with oxidizing agents, Nitric Sulfuric Acids and Alkalis.

Handling : Keep away from heat. Load over deck via droplines. Ensure thoroughly dry and grease free. Inhibitor : No (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge Blanket NO Tank Coating recommended : Zinc or Stainless steel. Exceptionally in Polyurethane but causes coating to soften. Must be vented for 24 hours prior to ballasting/reloading and last cargo has to be charterers acceptable. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : -18 C Draeger Tube No. : CH229 Acetone 100/b Boiling Point : 56 /C Explosive Range : 2 % to 13% Freeze Point : -95 C Autoignition Point : 538 Operational Problems/Hazardous Highly volatile and inflammable, Product will find any impurities and surveyors are very meticulous in inspection of tanks and lines. Loading via droplines preferred. Ensure all grease free- particularly joints and portable valves. On completion- lines to be blown clear with Nitrogen. Moderate irritant but vapor become unacceptable before high dangerous concentrations are encountered. Personnel Protection; Protective clothing , gloves and goggles . Breathing apparatus on standby, Accommodation doors closed. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Can be discharged over-side outside territorial waters. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Complete Educt residues (ensure lines and pump drained to tank) Protective clothing, breathing apparatus and emergency party standby, Gas free/ blow to dryness, Fresh water rinse, Educt and Mop (B) Cleaning to : (Beyond Solvent Standard)

Product is susceptible to : Smell/Moisture/Rust/Chlorides/Hydrocarbons After oils or fats - spray with toluene or neat chemical Hot wash - steam out thoroughly all lines and tanks. Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. Health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Fire / Small first Dry chemical,CO2,water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing , give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note.6 Cargoes such as alcohol and Ketone do not require extensive machine washing and can be cleaned by positioning a tank cleaning machine close to the pump well and giving a short fresh water wash. For coated tanks, it is necessary to consult the manufactures resistance list to ensure this method will not adversely affect the tank coating. When the coating can be affected, it is still necessary to flush the entire pump/line system with fresh water as much as possible to remove any remaining cargo form valves, drain cocks, low points on line system, etc.

ACETONE CAYANOHYDRIN
Synonyms UN. No ChrisCode Formula Appearance-Odor Boiling Point Alpha-hydroxyisobutronitrile; 2-hydroxy-2-methylpropanenitile, 2-methylacetonitrile, propanenitirile, 2-hydroxy-2methyl : 1541 : ACY : (CH3)2C(OH)CN : colorless to straw colored liquid, almond color. : *120C/ 248F

Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0)

: : : : : : : : : : :

-19C/ -2F 0.93 Cyanohydrin 0.8 A A 0.3 O 0.4 Complete 2.9

Fire & Explosion Hazard Data Grade- E : Combustible liquid Electrical Group :D General: Give off flammable and poisonous cyanide gas when heated. Vapor may explode if ignited in an enclosed area. Dilution with water causes decomposition with information of hydrogen cyanide. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 165(cc) 2.25 to 11% 1270 2 CO ,alcohol foam, water fog**

Special fire Procedures : DO NOT USE SODA-acid extinguisher! cool exposed tanks with water. Apply water cautiously. Do not contaminated cargo with water. Respiratory protection required for fire fighting personnel. Wear full protective, airtight clothing. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: 1,2,4 : Unavailable : Unavailable : "

General : Vapor very poisonous by inhalation. Liquid poisonous by absorption through the skin. Grade B poison. Symptoms: Headache, dizziness, nausea; bluenoses of lips and fingernails. Short Exposure Tolerance: Unavailable. Exposure Procedure : Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 min. keep victim at rest. Get prompt medical attention for liquid or vapor exposure. Wash contaminated clothing. including shoes, before reuse. See medical Kit information Appendix B. Reactivity : Dangerous with oxidizing agents and acids.

Decomposes with alkalis and water to form Hydrogen Cyanide and Acetone. High toxic and flammable. Stability: When heated, decomposes to form cyanide gas. Must be kept slightly acidified. Dilution with water causes decomposition with formation of hydrogen cyanide. Compatibility: Material: Aluminum and stainless steel are satisfactory, rubber will swell. Cargo: Group O of compatibility chart. See also appendix 1- exception to the chart. Spill or Leak Procedure If possible, wear long rubber gloves, self contained breathing apparatus, and protective clothing. Eliminate all sources of ignition personnel not equipped with respiratory protection. Do not flush spill where humans or animals may contact. Remarks:* Decomposes at the boiling point, ** Avoid getting water into cargo tanks Operational Problems/Hazards Stabilized with sulfuric Acid, Highly reactive Pump/lines must be dry. Keep away from heat - Temperature must not approach 120C. Wash away with copious water. Dont use Soda Acid extinguished. Give off Cyanide Gas, Vapor highly toxic. Do not use Bondstrand. ersonnel Protection : Total protection suit and breathing apparatus, restrict personnel on deck, Secure accommodation and recirculate air. Use Closed loading methods of ullaging. Tank Cleaning : Thoroughly wash cold salt water for minimum 3 hours, 5 ft, 40 minute drops to flush tank, lines and pump. Thereafter hot salt water with chemical (TC) injection, Ventilate, Fresh water Rinse. Educt and mop. Stolt Tanker cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo.

POTENTIAL HAZARDS HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE,

Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ACETONITRILE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling : : : : : : : : : : : : : : : : : Cyanomethane; ethanenitrile; ethyl nitrile methyl cyanide 1648 ATN 3 CH CN Colorless liquid, aromatic odor. 81C/ 178F -40c/ -40F 0.78 Nitrile 0.51 D III 0.02 O 0.03 Complete 1.41

Inhibitor Nitrogen Tank Coating : Stainless Steel only Exceptionally in Zinc Restricted to tanks with suitable venting system. Draeger Tube No. : CH257 Hydrocyanic Acid 2/a.

By ships lines only. Tank and lines must be dry Clear lines with Nitrogen. : Yes (Ensure certificate obtained and duration checked) : Purge : No Blanket : Possible

Fire & Explosion Hazard Data Grade-C : Flammable Liquid. Electrical Group :D General: Reacts with steam and acids to produce toxic and flammable vapors. Ignited by heat, sparks, or open flame. Flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 42 4.4 to 16.0% 975 2 CO , dry chemical, alcohol foam.

Special fire Procedures : Water may be ineffective. cool exposed tanks with water spray. Care must be taken not to expose fire fighters to the fumes of this material. Any who must enter a contaminated atmosphere must be provided with respiratory protection. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,1,3 40 40 40/skin

General: Highly toxic. Can be absorbed through skin and respiratory tract. Vapor irritating to eyes, nose and throat, liquid irritating to skin and eyes.

Symptoms: Dizziness, headache, nausea, and blueness of lips and fingernails. Inhalation will cause difficult breathing. Short Exposure Tolerance: Brief exposure to 500ppm has produced some nose and throat irritation. Exposure Procedure: Remove victim to fresh air. Apply artificial respiration if he stops breathing. Get medical attention. If liquid contacts skin, wash off with plenty of water. * Reactivity: Dangerous with oxidizing agents, Nitric acids, amines, alcohol, glycol and Phenol. Contact with water released highly Toxic and flammable vapor. Stability: Stable

Compatibility: Material: mild steel and stainless steel are compatible. Cargo : Group 37 of compatibility chart. Spill or Leak Procedure If possible, wear long rubber gloves, self contained breathing apparatus, and protective clothing. Avoid contact with liquid. Secure ignition source. small spills may be washed away with water. May add excess of strong calcium hypochlorite solution to spill and scoop up slurry. Wash site with soap solution containing some hypochlirute. Remarks: Odor threshold is not considered adequate warning of Potential dangerous vapor concentrations. High vapor concentration cause rapid death. Operational Problems/Hazards Is poisonous and flammable when mixed with water give off highly toxic and flammable vapor line should be cleared with Nitrogen. Personnel Protection: Total protection suits and breathing apparatus must be worn. Restrict personnel on deck. Secure accommodation and recirculate air, Use Closed Loading method of ullaging. Vapor Return System reg. : YES Tank Cleaning: Thoroughly flush tank, lines and pump with cold salt water, Minimum wash 5 ft. half -hour drops, 2 hour wash. Warm salt-water wash, Ventilate, Fresh water rinse, Educt and mop. Note : Tank will pass survey inspection prior to loading is strictly - similar AN. cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining. Wash water temperature(Code C); Hot water (55 degrees C up to the maximum allowed by the tank coating manufacturer) POTENTIAL HAZARDS HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames vapors may travel to a source of ignition and flash back container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. . FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Move container from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; Stop leak if you can do it without risk water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ACRYLIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Acroleic acid;ethylene carboxylic acid; 2-propenic acid;2-propenic Acid;propenic acid; vinyl formic acid. : 2218 : ACR 2 3 : C H COOH : Colorless liquid; acid odor. : 141C/ 286F : 8C/ 46F : 1.05 : Organic acid : 3.1

Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Fire & Explosion Hazard Data Grade-D Electrical Group

: : : : : : :

D 0.2 O 0.4 Complete 2.48

: Combustible liquid. :D

General: Presents no special fire or explosion hazard because of its relatively high flash point and low vapor pressure. Poisonous gases may be produced in a fire. Flash Point (F) : 130 Flammable Limits : Unavailable Auto igniting Temp.(F) : 835 2 Extinguishing Agents : Water, dry chemical, and alcohol foam, Co . Special fire Procedures: Use of CO2 where it could blanket the vapor space of a container is not recommended. A fire involving a spill outside of tanks could be extinguished with dry chemical. Wear full protective clothing, eye protection and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 3,3,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 10/skin TLV/TWA(ppm) : 10* General Acrylic acid, when in contact with skin or eyes, may result in a burn upon short contact. Vapor may present an inhalation hazard from single exposures; irritating to eyes, nose and throat. Symptoms: Vapors are capable of causing definite skin or eye irritation, nasal irritation and lachrymation. Short Exposure Tolerance: 0.5 ppm

Exposure Procedure : If contact with skin or eye occurs, immediately flush with plenty of water for at least 15 minutes. get medical attention promptly. immediately remove contaminated clothing and shoes. Reactivity Stability: Polymerizes readily. Should be inhibited to insure safety and stability during storage or handling. Compatibility: Material: Severely corrodes iron and steel, Glass, low carbon content stainless steel and high purity aluminum are Recommended for containment in order stated. Cargo: Group 4 of compatibility chart. See also appendix 1- exceptions to the chart. Spill or Leak Procedure If possible, wear rubber gloves, face shield, protective clothing, body shield and self-contained breathing apparatus should be available. If possible, cover contaminated surfaces and spill with large quantities of soda ash or sodium bicarbonate.

Mix and add water if needed for good mixing. scoop up slurry. Wash site with soda ash solution. remarks:* Proposed change in TLV to 2ppm , with "skin" notation. Operational Problem/Hazards High corrosive liquid, Highly irritant vapor. Product is unstable and compatibility with other products should be checked. Due to freezing point , Heating may be required. Keep away from excessive adjacent heat. Nitrogen blanket and/or vent line desiccator may be required Clear line with Nitrogen. Personnel Protection Total protection suits and breathing apparatus. Restrict personnel on deck. Secure accommodation and recirculate air. Use Closed method of ullaging. Vapor return system : YES Tank Cleaning Gas free or inert tank, Alternatively cold salt water flushed to remove residues. Cold salt water pre-wash for minimum 1.5 hours. Hot salt water wash, 5 ft. half hour drops. Ventilate Fresh water Rinse, Educt and Mop. Note : Heating : external heating only. Inhibitor amount/ brand must be made known to USCG. Remark; this is strictly and dangerous cargo if polymerizing takes place. Check double check before booking /carriage. 1. All tanks need to be stripped as per P & A manual. Shortly after discharge all tanks are to be rinsed with clean ambient fresh water (nor ship channel water) to dilute any remaining acid by a minimum of 10 parts water to 1 part acid. This mixture is to remain in the tank until it is cleaned at sea (salt water OK) as per MARPOL regulation. Alternatively this fresh water/acid mixture may be transferred into another SS tank or empty (rinsed) acid tank so the tank may be cleaned in port. Under no circumstances is the fresh water/acid mixture to be mixed with any other slop onboard (except for other Acrylic Acid slops). After initial rinsing and transfer of slops the Acrylic Acid tank may be cleaned in port with salt or channel water collecting slops onboard along with any other compatible slops. This cargo can polymerize violently if contaminated or if exposed to freezing (12-14C) or excessive heat(45C) so utmost care needs to be taken when handling or cleaning from this cargo. 2. If heating coils not been used for heating, remove blind and thoroughly flush the coils with fresh water. 3. Steam line systems ensure to flush at all drain cocks and plugs. 4. Dry tank and lines. POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ACRYLONITRILE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger tube No. Vapor Return Reg. : : : : : : : : : : : : : : : : : : : : : : : An;Cyanoethylene; propenenitrile; 2-propenenitrile;vinyl cyanide. 1093 ACN 2 CH CHCN Colorless liquid; resembles that of peach seed. 77C/ 171F 32 0.81 Nitrile 83 B B 3.5 O 5.0 Moderate 1.8 Load only through ships lines. YES Purge : NO Blanket : NO Stainless steel and Zinc. 6728591 Acrylonitrile 0.5/a Yes

Fire & Explosion Hazard Data Grade-C : Flammable liquid. Electrical Group :D General: When heated this material may evolve toxic cyanide gas, or explode, or both. Flashback along vapor trail may occur. fire may cause violent rupture of tank. Flash Point (F) : 32 Flammable Limits : 3.0 to 17.0% Auto igniting Temp.(F) : 898 Extinguishing Agents : CO2, dry chemical, alcohol foam. Special fire Procedures : Do Not use dry chemical for a large, confined fire. water or foam may cause frothing. fire parties must wear respiratory protection and full protective clothing include rubber boots. Keep tank cool with water spray. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

3,1,3 21.6* 29CFR 1910.1045 2/skin

General : Suspected carcinogen, harmful by inhalation and skin absorption. Penetrates leather, liquid in shoes cause delayed burns. Contaminated leather shoes and gloves should be destroyed. Symptoms: Eye irritation, headache, nausea, blueness of lips and fingertips, contact with skin may also cause dermatitis. Short Exposure Tolerance: 400 ppm for 30 minutes. Exposure Procedure : Remove victim to fresh air, if he is not breathing, apply artificial respiration. remove contaminated clothing and wash chemical from skin with a gentle flow of later. get medical attention. if patient is unconscious, administer vapor of amyl nitrile.* Reactivity Stability: Very reactive; may polymerize explosively in the presence of strong bases. Must be inhibited to prevent polymerization. Polymerization could be initiated by visible light. Compatibility: Material: copper alloys are attacked and should not be used. Attacks aluminum in high concentrations. Cargo: group 15 of compatibility chart. See also appendix 1- exceptions to the chart. Spill or Leak Procedure If possible, wear long rubber gloves, self-contained breathing apparatus, protective clothing. Avoid contact with liquid. Secure ignition sources. May add excess of strong calcium hypochlorite solution. Scoop up slurry. Wash site of spill with soap solution cautioning some hypochlorite. remarks: Note: Detectable odor is greater than the TLV. Exposure to potentially dangerous vapor concentrations can occur before the vapor is detected. Operational Problems/Hazards Protective clothing/gloves, etc. of leather or natural or nitrile rubbers are suitable for working this product, Odor threshold varies with individuals, but as vapors are toxic- breathing apparatus should be worn.

Possible carcinogen. Draeger tubes are unreliable and should only be used to check presence of Gas. A vapor is heavier than air. Polymerize with failure of inhibitor or contact with Alkalis. Keep away from heat, as inhibitor tends to degrade when subject to heating. Personnel Protection Use Closed Loading method of ullaging. Total protection and breathing apparatus should be used. Restrict Personnel on deck. Secure accommodation and recirculate air during loading, discharging and tank cleaning. Tank Cleaning Cold sea water flush and gas free- if con not inert (Note: Product is inhibited monomer) Cold sea water wash, 5 ft. half hour drops. thereafter hot salt water wash (similar drops) Ventilate, Fresh water rinse, Educt and mop. Alternatively Educt residues and gas free prior wash. tank may be washed over rich but LEL must be constantly monitored. Note : If inhibitor is Ammonia Zinc is no good. Be sure of checking inhibitor brand/amount. Very strictly tank inspection prior to loading -expensive stuff. Cleaning Code(4); Cargoes listed under this group are not or are only partially water-soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Extremely flammable; May be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural Firefighters protective clothing is not effective for these materials Isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE FIRE Small Fires: Dry chemical or Co2, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire.

Do not touch or walk through spilled material Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ADIPONITRILE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : : : : : : A.D.N, 1-4 Dieyanobutane, Tetramethylene Cyanide. 2205 3 2 4 NC (CH ) CN 7a Organic Nitrile Colorless mobile liquid with no identifiable smell. 0.956 @ 20 C 0.00072 15-20 C . 15- 20 C 10 C. 37 /C.

Reactivity: Violent with oxides and alkalis (caustic soda) possibly with acids. Handling : Is toxic by skin absorption Closed ullaging when burning gives off hydrogen cyanide fumes . Load only via ships lines. Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : No ( Ensure Certificate obtained and Duration Checked) : Purge possible Blanket : possible : Stainless steel or Zinc (preferably forward).

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 93 C Draeger Tube No. : Boiling Point : 295 /C Explosive Range : Freeze Point :2C Autoignition Point : Operational Problems/Hazardous Very little information available therefore treat as highly dangerous . Tank and lines to be dry. Blow with Nitrogen.

Personnel Protection; Total protection suits and breathing apparatus, Restricted personnel on deck. Secure accommodation and recirculate air . Use closed loading method of ullaging. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :D Vapor Return System Reg. : NO Discharge on passage. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial Gas free or inert. Followed by warm salt-water wash, 5 ft. half-hour drops, Ventilate, Fresh water rinse, Educt and mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/Hydrocarbons Note: This Nitrile is less hazardous to handle than AN . Tank inspection same as for AN. Cleaning Code(4); Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. Health Hazard:
Poisonous ; May be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from control or dilution water may give off poisonous gases and cause water pollution. Fire may produce irritating or poisonous gases. Fire or Explosion: Some of these materials may burn, but none of them ignites readily. Container may explode violently in heart of fire. Emergency Action: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low area, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus and chemical protective clothing which is specially recommended by the shipper or manufacturer may be worn, It may provide little or no thermal protection. Remove and isolate contaminated clothing at the site. Fire; Small fire: Dry chemical, water spray or regular foam. Large fire: Water spray, fig or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of material . Dike fire control water for later disposal ; do not scatter the material. Spill or Leak: Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapors. Small Spill : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills:

With clean shovel place material into clean , dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site. Keep victims quiet and maintain normal body temperature. Effects may be delayed; Keep victim under observation.

ALLYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Propenol;1-propenol-3, 1-propenol-3-ol; 2-propenol; 2-propen-1-ol; Ropenyl alcohol; vinyl carbinol. : 1098 : ALA 2 2 : CH = CHCH OH : Colorless liquid; pungent odor : 97C/ 206F : -129C/ -200F : 0.85 : Substituted allyl : 1.70 :B :B : 1.0 :O : 1.8 : Complete : 2.0

Handling : Can polymerize and may inhibited; load via ships lines preferably. Exceptionally may be loaded via portable lines to droplines. Inhibitor : YES Nitrogen : Purge : Possible Blanket : Possible Tank Coating : Stainless Steel, Zinc - max. 2months, Epoxy under restriction Draeger Tube No : CH254 Hydrocarbon 2 Operational Problems/Hazards Product liquid and vapor toxic Personnel Protection : Total protection suits and breathing apparatus. Secure accommodation and recirculate air. Use Closed Ullaging system. Fire & Explosion Hazard Data Grade- C: Flammable liquid Electrical Group : C General: Poisonous gases may be produced in a fire. readily ignited by heat, sparks, or open flame Flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) : 90(oc); 70(cc)

Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

: 2.5 ~ 18% : 713 2 : CO ,dry chemical, alcohol foam, water fog.

Special fire Procedures : Use respiratory, body and eye protective equipment and clothing. water may be ineffective. Cool exposed tanks with water. Health Hazard Data Health hazard Rating : 3,2,3 Odor Threshold(ppm) : 2~ 3 PEL/TWA(ppm) : 2/skin TLV/TWA(ppm) : 2/skin General : Vapor poisonous if inhaled or if skin is exposed. liquid is poisonous if swallowed or if skin is exposed. Vapor extremely irritating. Lung and eye injury may be delayed. Liquid causes severe burns. Grade B poison. Symptoms: Vapor exposure- irritation to respiratory tract. liquid splashed in the skin causes "deep bone ache" If not removed promptly. Disabling irritation and corneal injury to eye may be delayed. Short Exposure Tolerance: 1000ppm has been reported as fatal (exposure time not reported); 5 ppm can be tolerated for 30 min. Exposure Procedure : Vapor- Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact immediately flood affected areas gently with water for at least 15 min. remove contaminated clothing and shoes at once. Keep patient at rest and under observation for 24-48hr. effects may be delayed. Wash contaminated clothing before reuse, destroys shoes. Get medical help. Reactivity Stability: Chemically stable. Compatibility: Material : swells rubber. Not corrosive to steel. Cargo: group 15 of compatibility chart. See Appendix 1- Exceptions to the chart. Spill or Leak Procedure If possible, wear rubber gloves, face shield and protective clothing. Secure ignition sources. Use respiratory protection. Keep unprotected personnel upwind of contaminated area. Flush spill with water. may absorb very small spills with absorbent material(sand etc.,) Tank Cleaning : Cold salt water pre-wash, minimum 2 hours to clear residues , Hot salt water wash, 5 ft. half hour drops. (Check LEL) Ventilate to gas/ odor free. Fresh water rinse, Educt and Mop. Uses : Perfumes , flavorings, denaturing alcohol. Note :Hazardous to health , handle with Utmost care . Study all safety information available. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ;

Ambient temperature water or at least 10 degree C above the melting point of the cargo.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ALLYL CHLORIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Chlorallylene; 1-chloro-2-propene 3-chloropropen; 3-chloro-1-propene; 3-chloropropylene; alpha-chloropropylene. : 1100 : ALC : CH2 = CHCH2CI : Clear to strawberry colored liquid : 45c/ 113F : -134c/ 209F : 0.94 : Substituted allyl : 294.3 :C :B : 10.3 :O : 10.6 : 0.30% : 2.64

Handling : Load via ships lines _ Keep dry and cool. Use spray on deck if high outside temperature. Tank must be Nitrogen purge before loading, then carried under nitrogen pressure. Low boil/flash point makes this cargo hazardous in more ways than one. Inhibitor Nitrogen Tank Coating Zinc : a slight amount of water/moisture will Fire & Explosion Hazard Data Grade- B Electrical Group : No : Purge : Possible Blanket : YES : Stainless Steel, Zinc. strip tank of coating. Phenoline is O.K.

: Flammable liquid :D

General: Corrosive hydrogen chloride gas formed upon combustion. becomes more reactive and corrosive when wet. ignited by heat, sparks, or open flame. Flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) : -20(cc) Flammable Limits : 3.3 to 11.9% Auto igniting Temp.(F) : 737 Extinguishing Agents : CO2, dry chemical, alcohol foam. Special fire Procedures : Water may be ineffective on fire. cool exposed tanks with water spray. Fire fighting personnel should be protected against hydrochloric acid fumes by wearing self contained breathing Apparatus and full protective clothing. Health Hazard Data Health hazard Rating : 3,2,3 Odor Threshold(ppm) : above 1 PEL/TWA(ppm) :1 TLV/TWA(ppm) :1 General :

Suspected carcinogen. poisonous if inhaled. if swallowed, or if skin is exposed. vapor extremely irritating. liquid causes burns. Grade B Poison. Symptoms: Vapors are irritating to eyes and respiratory tract. the liquid irritates the skin. short Exposure Tolerance: Inhalation of 100 ppm for 60 min. has been reported as fatal. Exposure Procedure : Vapor-remove victim to fresh air. if breathing is difficult, administer oxygen; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with for 15 min. get medical help. Reactivity Stability: Chemically stable. Compatibility: Material: Highly corrosive to steel and aluminum. Nickel and monel are suitable materials of construction. Cargo : Group 15 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self-contained breathing apparatus and protective clothing. Avoid contact with liquid. Secure ignition sources. Do not flush spill into confined spaces where flammable Vapors can accumulate. If spill occurs, call National response Center, 800-424-8802 Operational Problems/Hazards Decomposes with water to yellow ... 100ppm for 1 hour is fatal , Vent line desiccate may be required. Product causes severe irritation at smallest concentrations and personnel should be restricted during operation. Personnel Protection Total protection suits and breathing apparatus. Secure accommodation and recirculate air. Use Closed ullaging system. Tank Cleaning: Gas free or inert tank, Alternatively cold flush to remove residues Check LEL. Cold salt water wash 5ft. half hours drops. Ventilate to gas and odor free (See TLV) Steam tank and line, ventilate. Educt and Mop. Uses : Setting resins and varnishes, plastics and adhesives. Cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining. Wash water temperature Code (A); Ambient temperature water of at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained

breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

alpha-METHYLSTYRENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA AMS; Isopropenylbenzene; 1-methyl-1- phenylethylene; phenylpropylene. : 2303 : MSR 6 5 3 2 : C H C(CH )=CH : Clear yellow liquid; characteristic aromatic odor. : 167~170c/ 333~338 F : -23c/ -9 F : 0.89 : Olefin : 4.08 :

IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0)

: : : : : :

A 0.23 O 0.40 Insoluble 4.08

Handling : Portable lines via droplines, Vapor unpleasant and lines must be dry. Product soften Coatings. Inhibitor : YES Nitrogen : Purge : NO Blanket : Possible. Tank Coating : Any Coating, But consult coating compatibility lists for time restrictions, particularly in zinc. Fire & Explosion Hazard Data Grade- D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : : : : :

Combustible liquid D Moderate fire hazard when exposed to heat or flame. 125~ 135 1.9~ 6.1% 1066 Dry chemical, foam, co2, water fog.

: Water may be ineffective on fire.

: : : :

Unavailable Less than 10 50 50

General : Avoid skin contact. Not known to be absorbed. Symptoms: Will cause skin irritation if not removed promptly. Breathing considerable quantities may cause headache and /or dizziness. Short Exposure Tolerance: Unavailable Exposure Procedure: Skin contact- flush body splashes with plenty of water. Inhalation- remove victim to fresh air. Administer artificial respiration if necessary. Reactivity Data Stability: Stable. Can react with oxidizing materials. Compatibility: Material : May cause rubber to swell. Cargo : Group 30 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, and protection clothing. Have all purpose canister mask available. Secure all sources of ignition.

Operational Problems /hazards As product will polymerize in contact with heat and for water, and the reaction is self sustaining, care must be taken to kept away adjacent heat. Tank ,line etc. must be dry. Heating coils should be blown dry and blanket and a check kept on temperature variation. Avoid contact with liquid and breathing vapor. Personnel Protection Chemical protection clothing, gloves, goggles. Breathing apparatus or air line sets on standby in working area. Tank Cleaning: Cold S.W wash, (Product contains inhibitor) 10 ft. half-hour drops. Thereafter hot S.W wash, 5 ft. half hour drops. With chemical injection. Drain tank, pump and lines. - Educt, Ventilate to gas free odorless condition. Fresh water Rinse - Educt and mop. Styrene odor lingers and warm air blowing may be beneficial. If possible tank should be left empty for maximum 3 days prior to ballasting /reloading to allow coating to harden. To free the tank and lines of odor it may be necessary to steam the tank, but only after the tank has been completely gas freed and 24 hours allowed for coating recovery. Some authorities may require vapor return system to be rigged. Do not allow draining to lie in P/R bilge unless well diluted with water. Uses : Polyesters and resins. Cleaning Code(4); Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference Note 15 Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires:

Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

ALPHANOL -79
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating : : ; : : : : : : : : : : : : : : : TBA 3 A mixture of C7-C9 Primary aliphatic alcohols. 10 Alcohol Colorless slightly viscous liquid. 0.835 @ 20 C 0.00075/C. Ambient . Ambient Ambient N/A Reacts with oxidizing agents, and mineral acids . Ships or portable lines. No ( Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Any.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 73 C Draeger Tube No. : Boiling Point : 177-202 /C

Explosive Range Freeze Point Autoignition Point

: : :

Operational Problems/Hazardous Non-hazardous, but wash eyes affected skin areas. Personnel Protection; Boiler suit and gloves.. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Retain on board and dispose of at sea. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Negligible Cold wash, Fresh water rinse Educt and mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/Hydrocarbons Important: These alcohols must be confused with Phthalates or Santicizer which belong in USCG group 34.ESTERS

AMINOETHYL ETHANOLAMINE
Synonyms 2-{(2-Aminoethyl)amino}ethanol, N-(aminoehtyl)ethano, N-(2aminoethyl)ethanolamine, Hydroxyethylenediamine, N-B ydroxyethylenediamine, N-hydroxyethyl-1,2-ethylenediamine. : ++ : AEE : NH2CH2CH2NHCH2CH2OH : Clear, colorless liquid with mild ammonia odor. : 243c/ 469F : -78c/ -108F : 1.03 : Amine : Low : :D : Low :O : Low : Complete : 3.59 : Stainless Steel. Some epoxy or polyurethane but subject to restriction.

UN.No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits

: : : : :

Combustible liquid C No smoking or Open light. 275 15.0 ~ 27.0%

Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: 695 : Carbon dioxide, dry chemical or alcohol foam. : Cool exposed tanks with water. or foam may cause frothing.

Health Hazard Data Health hazard Rating : 1,3,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Causes severe eye irritation. Symptoms: Liquid causes skin irritation with possibility of burns or prolonged contact. vapor causes mild respiratory irritation. Short Exposure Tolerance: Unavailable. Exposure Procedure : In case of eye contact, immediately flush eyes with plenty of low pressure water for 15 min. if discomfort persists or reappears, see a physician. Reactivity Stability: Compatibility:

Stable.

Material: Incompatible with copper, copper alloys, aluminum and zinc. Cargo : Group 8 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid, if possible, wear butyl rubber gloves, face shield, and protective clothing, cover spill with sodium bisulfite. Spray with water and wash with large excess of water. If a spill occurs, call National response Center, 800-424-8802. Remarks :++ Unassigned. Operational Problems/Hazardous Liquid and vapor irritating eyes and skin. Personnel protection: Boiler suit, gloves and goggles. Tank cleaning Warm salt water wash, minimum 3 hour Check LEL. Ventilate to gas and odor free Fresh water rinse Educt and Mop. Note : Amines rapidly absorb water. Check vacuum does not foam in tank while washing. This Amine looks OK to me see no problems. Cleaning code 1; Cargoes listed under this group are completely soluble or miscible. Some are water reactive; however, such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature (A) ; Ambient temperature water or at least 10 degree C above the melting point of the cargo.

AMMONIA AQUEOUS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Ammonia Hydrate, Ammonia Hydroxide, Aqua Ammonia, Water of ammonia. : 1005 :3 4 : NH OH : -2 : Amine. : Colorless liquid, Characteristic sharp smell. : 0.90 @ 15 C : : : : : 0.0002 /C. Ambient . Ambient Ambient 6

Reactivity: Violent with chlorine and acids, halogens and mercury. Possible reaction with alcohol, glycol, esters, aldehydes, Ketone and phenols. Handling : If large parcel then via ships lines. Ensure lines dry and grease free. Very gaseous and on discharging pumps will be liable to gas up if too high a rate attempted. Inhibitor Nitrogen (Subject to chaterers Reg. ) : No (Ensure Certificate obtained and Duration Checked) : Purge Blanket : NO

Tank Coating recommended: Polyurethane , Epoxy or stainless steel , but coating lists should be checked according to grade concentration. Aggressive in Zinc. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 50 ppm TLV 25 ppm Flash point :C Draeger Tube No. : CH205 Ammonia 5/a Boiling Point : various Explosive Range : 16 % to 25 %

Freeze Point Autoignition Point

: -97 C : 600 C

Operational Problems/Hazardous Various concentrations from 20% to 35% with water . Possibility of boil off in hot climates. Deck spraying should be considered. Keep away from adjacent heat. Considered non-flammable, but within explosive range will burn, Both liquid and vapor very irritant and cause severe burns to eyes and lungs. Can cause coating breakdown and coating softening. See cleaning guide. Personnel Protection; During loading, ,discharging , cleaning and gas freeing Chemical suits , gloves, and breathing apparatus or air line. Restrict personnel on deck. Secure accommodation and recirculate air. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : Possible Retain slops on board until on passage , where discharge under control. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete Drying oil : NO

On completion of discharge tank must be ventilated by forced air means to complete dryness . Thereafter flush tanks and lines with Cold S.W then cold S.W wash, 10 ft. 40 minute drops. Ventilate to gas Free. Fresh water rinse, Educt and mop. Ventilate for further 24 hours before ballast/next cargo, To an odorless condition may take 72 hours. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture Product is high alkaline, SG and correction factor will vary in the concentrations. Check locally.
health hazards Contact cause burns to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away, isolate hazard area and deny entry, Stay upwind; Keep out of low areas. Positive pressure self contained apparatus and structural firefighters protective clothing will provide limited protection. Fire Some of these materials may react violently with water. Small fires: Dry chemical, CO2, water spray or regular foam. Large fire : Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Spill or leak: Do not touch or walk through spilled materials ;stop leak if you can do it without risk. Small spill : Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Small dry Spill : With clean shovel place materials into clean, dry container and cover loosely; move containers from spill area.

Large Spill: Dike far ahead of liquid spill for later disposal. First AID Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site. Keep victim quite and maintain normal body temperature.

iso-AMYL ACETATE
Synonyms Amyl acetate;sec-amyl acetate, amylacetic ester,banana oil; isoamyl acetate, isoamyl ethanoate, isopentyl acetate, 1- methyl-1-butanol acetate; 2-methylbutyl ethanoate; pear oil. : 1104 : IAT 3 2 2 3 2 : CH COO(CH ) CH(CH ) : colorless liquid; pleasant fruity banana-like odor. : 149C/ 300F : -70c/ 094F : 0.88 : Ester : 4.0 :D :C : 0.1 : D.O : 0.34 : Slight : 4.5 : Compoflex, Bondstrand or ships Lines : Purge : NO Blanket : NO : NO : Stainless Steel, Limitation on Epoxy, Zinc, and Polyurethane.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Nitrogen Inhibitor Tank Coating Fire & Explosion Hazard Data Grade- D Electrical Group

: Combustible liquid :D

General: No smoking or open flames, flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed space. Precautions should be taken to prevent the accumulation of static electricity. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : 100 1.1 ~ 7.5% 714 CO2, dry chemical, alcohol foam, water fog Water may be ineffective.

Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,0,1 7 ~ 10 100 100

General : Little hazard from inhalation below 500 ppm. it may dry and defeat skin. Symptoms: Headache, dizziness, nausea; irritation of mucous membranes of eyes and respiratory tract, coughing. Short Exposure Tolerance: 500 ~ 1000 ppm for 30~60 min. Will produce definite irritation of eyes, throat, and trachea. Exposure Procedure : Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contactRemove contaminated clothing and gently flush affected areas with for 15 min. Get medical attention. Reactivity Stability: Chemically stable. Compatibility: Material : this compound will soften, then dissolve, a great many plastic material, and rubber. Attacks asbestos. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available avoid contact with liquid. Secure ignition sources. Flush minor spill away with water. Remarks:
Operational Problems/Hazards

Moderate fire hazards, Avoid exposure of skin or eyes to liquids. Personal Protection Boiler suit, gloves and goggles Tank Cleaning Cold salt water wash, minimum 3 hours Fresh water rinse, Educt and mop. Ventilation may be prolonged as odor is persistent. May be necessary to steam tank and lines. Cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining. Wash water temperature (B): Warm Water (38 to 55 degree C). Refer Notes 7: Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank cleaning program.

POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

n-AMYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No Alcohol C-5;1-amyl alcohol; primary-n-amyl alcohol; n-butylcarbinol; 1-pentanol; Pentyl alcohol. : 1105 : AAN 3 2 : CH (CH )4OH : Colorless liquid; mild odor : 138C/ 280F : -79c/ -110F : 0.82 : Alcohol : Low : :D : 0.2 :D : 0.3 : Slight : 3.04 : Portable lines to droplines or ships lines to check/Center tanks. : NO : Purge: NO Blanket : NO : Any Coating subject to coating guide. : CH297 Alcohol 100/a

Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General: Moderate fire hazard when exposed to heat or flame. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. When heated, it emits acrid fumes; can react with oxidizing materials. Flash Point (F) Flammable Limits Auto igniting Temp.(F) : 118 : 1.2 ~ 10.0% : 572

Extinguishing Agents : Carbon dioxide, dry chemical or alcohol foam. Special fire Procedures : Water may be ineffective on fire. Cool exposed tanks with water spray. Wear self-contained breathing apparatus. Health Hazard Data Health hazard Rating : 1,0,2 Odor Threshold(ppm) : 0.12 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : Unavailable General : Vapor may be irritant to the eyes and the upper respiratory tract. Symptoms:

Vapor inhalation causes psychic stimulation, insomnia, palpitation of heart, headache, and vertigo. Short Exposure Tolerance: 150 ppm for 30 min. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops or is very weak, apply artificial respiration. Skin or eyes contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity May react with oxidizing agents and acids , Check other cargo. Stability: Very Stable. Compatibility: Material: Can be stored in copper, aluminum, or plain steel tanks. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. avoid contact with liquid. Secure ignition sources. If a spill occurs, call the national response Center, 800-424-8802 remarks: Operational Problems/Hazards Product is flammable. Both liquid and vapor cause intense irritation, High vapor concentrations have narcotic effect. Stow away from adjacent heat. Personnel Protection Chemical protective clothing goggles, gloves, Breathing apparatus on standby. Vapor return : NO Tank Cleaning: Warm seawater wash, Minimum 2.5 hours (Check LEL) Ventilate to gas and odor free. Fresh water rinses, Educt and Mop. Alternatively, tank may be inerted prior to wash. Cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Water wash temperature code (D); Ambient water followed by warm waters.

POTENTIAL HAZARDS FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard.

HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ANILINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Aminobenzene; aminophen;aniline oil; Benenamine; benzenamine; blue oil; phenylamine. : 1547 : ANL 6 5 2 : C H NH : Oily colorless-to-brown liquid odor not unpleasant : 184c/ 364F : -6c/ 21F : 1.02

Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0)

: : : : : : : : :

Amine 2.4 D C 0.02 O 0.04 3.0% 3.22

Handling : Via ships lines- tank and lines to be dry and air excluded as far as possible. Closed ullaging. NOT suitable with Bondstrand. Nitrogen Inhibitor Tank Coating Draeger Tube No Fire & Explosion Hazard Data Grade- E Electrical Group : Purge : Possible Blanket : YES : NO Stainless Steel, Occasionally Zinc but coating compatibility must be ascertained. : CH204 Aniline 5/a

: Combustible liquid :D

General: Poisonous gas is produced when heated. vapor may explode if ignited in an enclosed area Flash Point (F) : 158C Flammable Limits : LEL=1.3%, UEL= 11% Auto igniting Temp.(F) : 1143 Extinguishing Agents : CO2,dry chemical, alcohol foam, water spray. Special fire Procedures : Protect personnel against exposure to either the vapor or liquid; wear full protective clothing and self-contained breathing apparatus. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,1,3 0.5 2/skin 2/skin

General : Suspected carcinogen, poisonous by inhalation or skin absorption. it will cause cyanosis a serious blood condition. Class B Poison. Symptoms: Headache, weakness, irritability, dizziness, bluish discoloration of lips and fingernails, drowsiness, and unconsciousness. Short Exposure Tolerance: 50~100 ppm probably can be tolerated for 60 min. Exposure Procedure : Remove victim to fresh air. Apply artificial respiration if needed. remove any clothing wet with aniline. flush exposed skin area thoroughly with water. Get medical attention as soon as possible. Administer oxygen if available. keep patient at rest.

Wash clothing thoroughly with strong soap solution before reuse, or destroy. Reactivity Stability: Stable. Reacts dangerously with oxidizing agents and inorganic acids. Compatibility: Material : Corrosive to copper and copper alloys. Not corrosive to iron or steel. Cargo : Group 9 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid . wear butyl rubber gloves, plastic protective apron and self contained breathing apparatus. Secure ignition sources. May mix with sand and soda ash mixture(90-100), scoop up into cardboard boxes and pack with excess crumpled paper. then burn in open pit. Operational Problems/Hazards Liquid is particularly dangerous in contact with skin. Hoses and lines must be secured against leakage and any spill sanded immediately. Should be kept away from adjacent heat and carried under Nitrogen blanket to exclude air . Use Closed loading method of ullaging. Personnel Protection Total protection suit and Breathing apparatus must be worn. Restrict personnel on deck. Secure accommodation and recirculate air. Vapor return system : YES Tank Cleaning Warm salt water wash (50C Max.) 5 ft half hour drops Ventilate to gas free Fresh water rinse, Educt and Mop. Ensure tank, lines and pump dried a Nitrogen purge may be required or necessary to reduce oxygen level and dry the system. This product attacks nitrile rubbers, therefore nitrile chemical gloves are not suitable. As Anile attacks blood cells personnel subject to anaemia or heavy drinking should not work this product. Cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining. Wash water temperature (B): Warm Water (38 to 55 degree C). HEALTH HAZARDS Poisonous; may be fatal if inhaled or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION May be ignited by heat, sparks or flames contact may cause burns to skin and eyes. Vapor explosion and poison hazard indoors, outdoors or sewers EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Cool container with water using unmanned device until well after fire is out fight fire from maximum distance.

Stay away from ends of tanks. Dike fire- control water for later disposal do not scatter the material. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; stop leak if you can do it without risk. Water spray may reduce vapor; but it may nit prevent ignition in closed space. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature Effect may be delayed; keep victim under observation.

ARKOPAL N130/N 150

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor : No : : : : : : : : : : : : : : : ALKYL PHENOL POLYGLYCOL ETHER. 2430 -

Viscous Yellow Liquid. 1.062 @20 C TBA /C. 25-35 C . 25- 50 C 50 C. 40 Neutral. Bondstrand, Compoflex and Ships Lines.

( Ensure Certificate obtained and Duration Checked) : Purge Blanket :

Nitrogen (Subject to chaterers Reg. )

Tank Coating Recommended

: Polyurethane and Epoxy , Restrictions on Zinc.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 216 C Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point :5C Autoignition Point : Operational Problems/Hazardous Non toxic. No significant hazards. obtain specific information for grade shipped. Personnel Protection; Boiler suit and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Retain slops on board and discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : YES Hot wash with chemical injection . Fresh water rinse, Educt and Mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/Hydrocarbons Cleaning code (2) ; Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining. Wash water temperature (D): Ambient water followed by warm water. Health Hazard: Poisonous ; May be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from control or dilution water may give off poisonous gases and cause water pollution. Fire may produce irritating or poisonous gases. Fire or Explosion: Some of these materials may burn, but none of them ignites readily. Container may explode violently in heart of fire. Emergency Action: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low area, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus and chemical protective clothing which is specially recommended by the shipper or manufacturer may be worn, It may provide little or no thermal protection. Remove and isolate contaminated clothing at the site. Fire; Small fire:

Dry chemical, water spray or regular foam. Large fire: Water spray, fig or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of material . Dike fire control water for later disposal ; do not scatter the material. Spill or Leak: Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapors. Small Spill : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel place material into clean , dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; Keep victim under observation.

AROMASOL H
Synonyms : Manufactured Largely by ICI(UK). IMO No : IMO TYPE :3 Formula : Mixture of Aromatic Hydrocarbons. ICS Guide Page No. : 20 Family : Aromatic Hydrocarbon Appearance and character : Clear colorless mobile liquid with mild distinctive smell. Specific Gravity : 0.8804 @ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.0008 /C. Carriage : Ambient.. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : Reactivity : Can react with oxidizing agents and acids. Handling Fairly innocuous product, load via dropline for quality control reasons. Inhibitor : No ( Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Any Coating , but some restrictions in some Epoxies Check Coating lists.

Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A ppm TLV N/A ppm Flash point : 47 C

Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: : : : :

CH254 Hydrocarbon 2 168 /C N/A % to % -50C 600C

Operational Problems/Hazardous An artificial solvent with similar characteristics to xylene a mixture of hydrocarbons (but not Benzene) draeger tube testes should not be regarded as definitive and will only indicate the presence of gas. Contact with liquid causes defeating and vapors cause irritation. Personnel Protection; Chemical protective clothing goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Retain slops on board and discharge on passage Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight Hot salt water wash, 5 ft. half hour drops, with chemical. Ventilate to gas free. , Fresh water rinse, Educt and mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank and line must be smell and grease free..

BABASSU OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : : : : : : Brazilian Palm Oil N/A 3 N/A Esters. Reddish yellow oil or grease has butter like consistency. 0.890 @ C /C. 30-35/C. 49-55 C. 50 C. 34

Reactivity: Possibility of dangerous reaction with Nitric Acid. Heat evolved in certain circumstances with Sulphuric Acids. Handling : No specialized handling requirements Portable lines to droplines or ships lines to deck tanks. Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : No (nsure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Polyurethane, Epoxy, Stainless Steel Not normally carried in Zinc Silicate (FFA 2.5% Maximum)

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A Flash point : N/A Draeger Tube No. : Boiling Point : N/A

Explosive Range Freeze Point Autoignition Point

: N/A : 27-43 C : N/A

Operational Problems/Hazardous Starts to solidify at ambient temperature, Tanks normally required to be swept therefore oxygen content and tank entry procedures to be strictly observed. Slops liable to purity giving Hydrogen Sulphide and also deoxidize the tank. Personnel Protection; Boiler suit, normal working gear, gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge at sea according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO After discharge, steam down tank, Hot salt water wash, minimum 3 hours, with chemical injection Ventilate Fresh water rinse or steam tank and lines. Educt and mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/ Tank and line must be dry. Note : Zinc The FFA is usual below 2.5%. Check! Handle same way as Coconut oil - No problem. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code C Hot water (55 degree C up to the maximum allowed by the tank coating manufacture).

BENZENE
Appearance : Colorless, Clear liquid, or white crystalline solid. Odor : Characteristic aromatic. Emergency Procedure Fire Use foam, dry Powder or CO2, Fire fighters should wear breathing apparatus. Liquid in Eye : Flood the eye gentle with clean sea or clean fresh water. continue washing for at least 15 minutes. Liquid on skin : Flood with water and remove contaminated clothing. Continue washing for at least 10 minutes. Vapor inhaled : Remove victim to fresh air. If breathing has stopped or is weak or irregular, give mouth to mouth or mouth to nose resuscitation. Spillage : Avoid contact with liquid. Extinguish sources of ignition. Wash away with water. Inform port authorities if a major spillage occurs, as this will result in the formation of a cloud of explosive vapor. Fire and Explosion Data Flash point : -11C Closed cup Auto-igniting Temp. : 538C Flammable limit : 1.4% ~ 8.0%(in air) Explosion Hazard : Moderate in an enclosed space in the presence of a source of igniting. Chemical Data Formula : C6h6 Chemical Family : Hydrocarbon(aromatic) is not hygroscopic A stable compound. Reactivity With Oxidizing Agents : some reaction, possibly dangerous. Acids: Conc. Nitric acids: some reaction, possibly Dangerous. Sulphuric acids: Mixture may became very warm under certain conditions. Other acids: no dangerous reaction. Alkalis : No dangerous reaction. Salt or fresh Water : No reaction. Air : " Other Chemicals No dangerous in general, but for confirmatory information consult the data sheet for the other cargo in question. Health Data

TLV : 5 ppm Odor Threshold : Greater than 25 ppm. Effect of Liquid On Eyes : Very irritation. On Skin : slight Irritation. Continuous contact will lead to defatting and possibly secondary infection. By skin Aborption : Small amounts are absorbed, but it is unlikely that systemic poisoning can arise from immersing hands in benzene. By Ingestion : Moderate systemic effect. Effective of Vapor On eyes : Irritates in high concentrations. On Skin : Nil When inhaled(acute effect) : Slight irritation and moderate systemic effect causing dizziness, headache and drowsiness. When Inhaled(chronic-effect) : Can have severe systemic effect- a definite cumulative action causing headache, dizziness, fatigue, loss of appetite, irritability, nervousness, and it can cause blood disorders. Physical Data Specific Gravity : 0.8790 (20/4C) Boiling Point : 79.8 ~ 81.0C Freezing Point : 5.5C Vapor Pressure : 70mmHg at 20C Coefficient of Cubic expansion : 0.001215/C @ 20C Vapor Density : 2.7 Solubility in water : Negligible. Viscosity : 0.74cS @ 20C Electrostatic Generation : Likely. Handling and Storage Materials Normal Carriage Temp. : 7C ~ 30C Normal Carriage pressure : Atmospheric. Filling Ratio : See 1.6.4 Handling and Storage Recommendations Unsuitable : Certain rubbers. Suitable : Mild steel, Stainless steel, Most metals. Operational Problems/Hazards Highly inflammable and compound produced is highly toxic Vapors are toxic. Contact can result in blood cancer. As far as possible keep away from adjacent heated cargoes; However, product freezes at approximately 5 C and Charterer must be consulted reference heating of products, depending on climatic conditions. Use Closed Loading method of ullaging. Clear lines with Nitrogen. Personnel Protection Total protection suit and breathing apparatus or air lines required. Restrict personnel on deck , secure accommodation and recirculate air during all load/discharge cleaning and gas freeing operation. Tank cleaning : I) Can be washed directly in over-rich condition if necessary. II)Gas free or inert before washing, Hot salt water wash, 5 ft. half hour drops. Ventilate to gas free, Educt and mop. To Gas free 1) Using protective clothing and breathing apparatus Educt residues before ventilating. or 2) Salt water ballast the tank overflowing. Ensure accommodation sealed while gas freeing, Beware possibility of product being in fact Crude Benzene. Product should be quoted as Pure . To ascertain which type ask for details of distillation range. If tight -i.e. 70.5-80.5C product is good. if 76-180C then it is crude and will cause irreparable damage to coating.

Vapor return system : Possible

IMO Pollution Cat. : C

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Code (D)Ambient water followed by warm water. Reference Code 14. Lube oils with low viscosity can be extremely hard to remove, especially form inorganic(zinc) coatings. Generally if the viscosity is less than 100cst and the subsequent cargo is of high specification, it is necessary to toluene float the tank. Obtain the viscosity at the port to assist in cleaning the tank after discharge. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

BRAKE FLUID
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : Depends on Manufacturer 1118 3,2 N/A 108/1 Compound Colorless slightly viscous liquid. 1.0/1.116 @ C

: TBA /C. : Ambient. : Ambient. : Ambient : 40 : NIL Compoflex, Bondstrand or Ships Lines. Load via droplines for quality control. : No (Ensure Certificate obtained and Duration Checked) : Purge YES Blanket : YES : ANY Coating.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : above 100C Draeger Tube No. Boiling Point : above 180C Explosive Range : Freeze Point : Below -10C Autoignition Point : 400 Operational Problems/Hazardous Exclusion of moisture essential. Very hygroscopic. Ensure tanks/lines Completely dry. Maintain nitrogen blanket. Use vent line dessicators. Shippers can be very particular with these products. Personnel Protection; Boiler suit, normal working gear, gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Retain slops on board and discharge on passage. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial.

Hot salt water wash with chemical injection minimum 3 hours , Ventilate, Thoroughly steam tank and lines. Educt and mop.

(B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/ Pay particular attention to dryness of tanks and lines. Note : USCG/IMO Product is not cleared AS: UCON Zinc : PH ranges 10.7 to 11.5 making zinc a risky tank lining.

Phenoline- OK.

Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames vapors may travel to a source of ignition and flash back. Vapor explosion hazard indoors, outdoors, or in sewers. Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus and structural firefighting protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, or rail car or tank truck is involved in fire. Fire Small fire Dry chemical , Co2, water spray or regular foam. Large Fires : Water spray, fog or regular foam. Move container from sire area if you can do it without risk. Apply cooling water to sides of containers that are exploded to flames until well after fire out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Spill or Leak Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Leak Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Large Spill Dike far ahead of liquid spill for later disposal. First Aids Move victims to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

n-BUTYL ALCOHOL(Butanol)
Synonyms Alcohol C-4, butanol,1-butanol,n-butanol butyl alcohol, butyric alcohol, 1-hydroxybutane, NBA, propyl carbinol, n-propyl carbinol UN. No : 1120 CHris Code : BAN 3 2 3 Formula : CH (CH ) OH Appearance-Odor : Colorless liquid, pungent alcohol odor Boiling Point : 117c/ 243F Freezing Point : -84c/ 0129F Specific Gravity : 0.81 Chemical Family : Alcohol Vapor Pressure(20C) : 8.8 Pollution Category USEPA :D IMO : III Reid Vapor Pressure(psia) : 0.3 Applicable Bulk reg.46 Subchapter :D Vapor pressure 46C(psia) : 0.5 Solubility in water : Moderate Vapor Density(air = 1.0) : 2.6 Handling : Normally through portable lines to droplines, unless to deck tanks. Nitrogen : Purge : NO Blanket : NO Inhibitor : NO Tank Coating : Any Coating subject to coating guides. Zinc, Epoxy and Polyurethane must be ventilated for 24 hours after discharge/ cleaning. Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General: Ignited by heated, sparks, or open flame. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 103 Flammable Limits : 1.4~ 11.2% Auto igniting Temp.(F) : 690 Extinguishing Agents : Dry chemical, CO2, foam, water fog. Special fire Procedures : Water and alcohol foam may be ineffective on fire. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 25 PEL/TWA(ppm) : 50/skin TLV/TWA(ppm) : 50/skin General : Causes significant injury to the eye. Repeated skin contact may have a defatting action on the skin and may produce dermatitis from daily contact. Avoid prolonged and repeated breathing of vapors. Symptoms: Headache, dizziness, and respiratory irritation. Short Exposure Tolerance: 150 ppm Exposure Procedure :

Vapor-victim to fresh air. if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Stability: Stable. Compatibility: Material: Recommended carbon steel tanks, valves, and piping. water free n-butanol reacts with aluminum at temp. above 120F. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact with liquid. secure ignition source. Operational Problems / Hazards Exposure to vapors will diminish ability to smell vapors , Liquid on skin causes defatting and is irritating in eyes. Vapors can cause dermatitis, particularly on fingers and nails. Otherwise is highly flammable. Desiccators may be required. Personnel Protection Protective clothing , goggles and gloves. Tank cleaning Cold slat water wash for minimum 1.5 hours (to avoid fixing odor in coating). Hot salt water wash, 5 ft. halt hour drops. Ventilate to gas free. Fresh water rinse, Educt and mop. It may be necessary to ventilate to below LEL after cold pre-wash. It is not sufficient to evaporate residues. Tank must be odor free and dry. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C ) Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. Health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Fire /Small first Dry chemical,CO2, water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk.

Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

n-BUTYL ACETATE
Synonyms UN. No CHris Code Formula Acetic acids, butyl ester,butyl acetate normal butyl acetate, Butyl ethanoate : 1123 : BCN 3 4 5 : CH COOC H

Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0)

: : : : : : : : : : : : :

colorless liquid, pleasant, fruity odor 127c/ 260F -77c/ -107F 0.88 Ester 8.7 D C 0.5 D,O 0.8 slight 4.0

Handling : Portable lines to droplines or ships lines to deck/poison tank Ensure all lines absolutely dry. Inhibitor : NO Nitrogen : Purge : No Blanket : Possible Tank Coating : Any coating, subject to coating guide. Epoxy, polyurethane and Zinc must be ventilated minimum 24hours prior to ballast or next cargo. Fire & Explosion Hazard Data Grade- D: Combustible liquid Electrical Group : D General: Volatile, with a low flash point. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed space. Flash Point (F) : 90 Flammable Limits : 1.4~ 7.6% Auto igniting Temp.(F) : 790 2 Extinguishing Agents : CO , dry chemical, alcohol foam, water fog. Special fire Procedures : Use of dry chemical where it can get into a tank of n-butyl acetate is not recommended. Fires involving spills outside of tanks can be get extinguished with dry chemicals. Water may be ineffective. cool exposed tanks with water spray. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm)

: 1,1,2 : 10 : 150

TLV/TWA(ppm) : 150 General : Low level of toxicity. vapor irritating to eyes, nose and throat. liquid irritating to skin and eyes. Symptoms: Headache, irritation of respiratory passage and eyes, dizziness, and nausea. Short Exposure Tolerance: 200~300 ppm produces some nose and eye irritation upon brief exposure.

Exposure Procedure : Vapor-remove victim to fresh air, if breathing stops, apply artificial respiration. Skin or eye contacts- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Stability: Stable, however, will hydrolyze (react with water) on standing to form acetic acid and n-butyl alcohol. Compatibility: Material: softens and dissolves rubber and many plastics. Spill or Leak Procedure Wear rubber gloves, face shield protective clothing. have all-purpose canister mask available. Avoid contact with liquid. Secure igniting sources. Operational Problems/Hazards Reactions with contaminates accelerated if product in contact with heat. Keep away from adjacent heat. Highly flammable. Liquid and vapor are irritant to eyes and skin. NOTE :Polyurethane compoflex hoses NOT suitable with this product. Clear lines with Nitrogen, Use Closed ullage system. Personnel protective Protective clothing goggles and gloves. Tank cleaning Cold sea water wash for minimum 1.5 hours, followed by Hot sea water wash, 5 ft. half-hour drops. Ventilate to odor free. Fresh water rinse, Educt and mop Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C ) Reference note 7 Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program. Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. Health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Fire /

small first Dry chemical,CO2,water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing , give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

n-BUTYL ACRYLATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Acrylic acid, n-butyl ester, n-butyl -2-propenoate, 2-propenoic acid, Butyl ester. : 2348 : BTC : CH2=CHCOOC4H9 : colorless liquid, sharp, biting ester-like odor. : 149c/ 300F : -64c/ -83F : 0.90 : Acrylate : 3.2 : :B : 0.2 :O

Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0)

: 0.4 : Negligible : 4.4

Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General: The main hazard is its very easy polymerization, ignited by heat and open flame. fire may cause violent rupture of tank. Flash Point (F) : 120 Flammable Limits : 1.5~ 9.9% Auto igniting Temp.(F) : 567 Extinguishing Agents : Carbon dioxide, dry chemical, alcohol foam, water spray. Special fire Procedures : Provide fire fighters with breathing apparatus. Keep tank cool with water spray. Handling : Use only ships lines, which must be maintained dry. Bondstrand NOT suitable. Inhibitor : YES Nitrogen : Purge : NO Blanket : NO Tank Coating : Zinc or Stainless Steel. Draeger Tube No : 6728171 Methyl Methacrylate 50/a Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Vapor and liquid are irritating. Symptoms: Eye irritation; watering of eyes and salivation when inhaled. Short Exposure Tolerance: Unavailable. Exposure Procedure : Skin contact should be washed thoroughly with soap and water. In case of eye contact, flush with water for 15 min. Get medical attention or advice. Reactivity Stability: polymerizes readily on heating. Must be inhaled. Compatibility: Material: Compatible with steel, stainless steel or aluminum. Cargo : Group 14 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, full protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems/Hazards When using Draeger Tubes - divide range by two and divide reading by 2. Highly flammable liquid and vapors is toxic. Odors is particularly persistent and care must be taken to ensure all connections are secure and closed Ullaging/loading procedures are followed. Vapor return systems may obtain bubbling gases. Through a special chemical, rather than shore direct return. Use closed loading Method of ullaging. Personnel Protection Total protection suit and breathing apparatus required. Restrict personnel on deck. Secure accommodation and recirculate air during all loading/discharging/cleaning

and gas freeing operations. Tank Cleaning Cold sea water wash ( to clear inhibitor and residues) for 1.5 hours minimum. Then hot salt water wash, 5 ft. half hours drops, Ventilate to gas free and odorless(which may take 24 hour) Fresh water rinse - Educt and mop. Tank should be further ventilated for 24 hours before next cargo to harden coating,. Smell is very persistent and odor -sensitive cargoes will not accept ex Acrylate stowage. -Absolutely dryness is required. Nitrogen blanket may be required, but reduces oxygen to inhibitor which may tend to degrade. Desiccators in vent line may be required . Due to pungent and persistent odor, most Authorities have stringent regulations on vapor control. This grade need some heat- obtain exact heating instruction . Coating softens if cargo is heated by coils or by adjacent heat-void. Remarks All 3 grades are good cargoes. No problems, exact strong odor. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9,15 After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. Health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Fire / small first Dry chemical,CO2,water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing , give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

sec- BUTYL ALCOHOL

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade- C Electrical Group AlcoholC-4, 2-butanol,sec-butanol, butylene hydrate, Ethyl methyl carbinol,2-hydroxybutane, methyl ethyl carbinol. : 1120 : BAS 3 2 3 : CH CH CHOHCH : colorless liquid strong pleasant odor. : 99c/ 211F : -109c/ 165F : 0.81 : Alcohol :* : : III : 0.2 :D : 1.3 : Moderate : 2.6 : Compoflex and Ships Lines. : NO : Purge : Possible Blanket : Possible : Any Coating.

: Flammable liquid :D

General: Dangerous when exposed to heat or flame. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 74 Flammable Limits : 1.7 ~ 9.8% at 212 F Auto igniting Temp.(F) : 763 2 Extinguishing Agents : CO , dry chemical, alcohol foam, water fog. Special fire Procedures : Water may be ineffective on fire. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,0,1 Unavailable 100 100

General : Avoid inhalation of high vapor concentrations. prolonged or repeated skin contact may cause defatting of the skin and may produce dermatitis from daily contact. Symptoms: Headache, and dizziness. short Exposure Tolerance: 150 ppm for 30 min. Exposure Procedure : Vapor-remove victim to fresh air ,. give artificial respiration if breathing stops. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical help. Reactivity Stability: Stable Compatibility: Material: usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. See appendix 1- exception to the chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. secure ignition sources. Operational Problems/ Hazards Moderately Toxic Irritant to eyes and skin. Dangerous fire risk. Personnel Protective Boiler suit, gloves and goggles. Tank Cleaning : Cold salt water wash to dispose residues. Hot salt water wash 5 ft. half-hours drops (Check LEL) Fresh water rinse, Educt and mops. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product.

Wash water temperature Code (B)-

Warm water (38 to 55 degree C )

Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Fire / small first Dry chemical,CO2,water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing , give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

BUTYL BENZYL PHTHALATE

Synonyms : BBP, Santicizer 160 IMO No : TBA IMO TYPE :3 4 9 6 4 2 6 5 Formula : C H COOC H COOH C H ICS Guide Page No. : 36 Family : Ester. Appearance and character : Clear and oily with characteristic odor. Specific Gravity : Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 34 Reactivity : No violent reactions Handling : Preferably portable lines via droplines. Inhibitor : No (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge NO Blanket : Possible Tank Coating recommended : ANY Coating. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 190 C Draeger Tube No. : Boiling Point : 370 C Explosive Range : Freeze Point : Below -10C Autoignition Point : Operational Problems/Hazardous Hazards are negligible, although liquid in eyes will cause irritation. Vapor pressure is Low. Personnel Protection; Normal protective clothing goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A Vapor Return System Reg. : NO Retain slops on board and discharge on passage.

Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NIL Hot salt water wash, 5 ft. half-hour drops with chemicals injection Ventilate to odor free. Fresh water rinses, Educt and mop. (B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/Chlorides/ Ensure tank is dry, odor and gases free.
Make sue lines/tank/pump is clean and dry before loading/discharging. Nitrogen blanket for stack tanks. Un-compliance cargo.

Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

1,3-BUTYLENE GLYCOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade- E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating : : : : : : : : Combustible liquid. D Slight fire hazard when exposed to heated or flame. 250 Unavailable 710 Water, carbon dioxide or dry chemical, alcohol foam. Cool exposed tanks with water. Butane-1,3-diol, 1,3-butanediol, Beta-Butyleneglycol, 1,3dihydroxybutane, Methyltrimethylene Glycol. : ++ : BUG : CH2OHCH2CH(OH)CH3. : Practically colorless, odorless liquid : 207C/ 406 F : 23C/ 74 F : 1.01 : Glycol : 0.06 : :D : LOW :D : LOW : Complete : 3.10 : Compoflex or ships lines. : NO : Purge : NO Blanket : YES : Stainless Steel , Epoxy or polyurethane, Restrictions on Zinc.

: 0,0,0

Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance

: Unavailable : Unavailable : " : Not considered toxic under ordinary conditions of handling. : Unavailable. : Unavailable.

Exposure Procedure : Vapor- remove victim to fresh air. skin or eye contact- gently flush contaminated areas with water for 15 Min. Reactivity Stability: Stable. Can react with oxidizing materials. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. See also appendix 1 - Exceptions to the chart. Spill or Leak Procedure Avoid contact with liquid. remarks: ++ Unassigned. Operational Problems/hazards Check if technical or food grade. Low toxicity. Nitrogen blanket and/or vent line dessicator may be required. Some shippers may require product to be heated. Check locally. Personnel Protection Boiler suit and gloves. Tank Cleaning Hot salt water wash 5ft. .5 hour drops Ventilate. Thoroughly steam tank and lines. Ventilate Educt and mop. Both grade are fine Glycols needing good tanks. It is a good cargo, No Problem. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

n-BUTYL ETHER
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure (20C) Pollution Category USEPA IMO Reid Vapor Pressure (psia) Applicable Bulk reg.46 Subchapter Vapors pressure 46C(psia) Solubility in water Vapor Density (air = 1.0) Handling Inhibitor Nitrogen Tank Coating 1-butoxy butane,butyl ether, dibutyl ether di-n-butyl ether, n-dibutyl ether, dibutyl ether, dibutyl oxide,1,1-oxybis(butane) : 1149 : DBE 4 9 2 : (C H ) O : Colorless liquid; mild, pleasant ether like odor : 142c/ 288F : -95c/ -140 F : 0.767 : Ether : 4.8 : :C :+ :O : 0.4 : Negligible : 4.5 : Compoflex or ships lines : NO : Purge : NO Blanket : NO : Stainless Steel. Epoxy, or polyurethane Zinc not Recommended.

Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :C General: Flammable, irritating vapors are produced. flashback long vapor trail may occur. Vapor may explode if ignited in an enclosed areas. Ground all equipment and personnel! Flash Point (F) : 92 Flammable Limits : 1.5~ 7.6% Auto igniting Temp.(F) : 382 Extinguishing Agents : Dry chemical, alcohol foam,co2. Special fire Procedures: containers may explode in fire. Water may be ineffective. Cool exposed containers with water. secure ignition sources. Wear goggles or face shield, rubber gloves. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: Unavailable : Unavailable : " : "

General : Vapor irritating causes irritation of nose and throat. Liquid irritates eyes and irritates skin or prolonged contact. Symptoms: Inhalation causes irritation of nose and throat. Liquid irritates eyes and irritates skin or prolonged contact. Short Exposure Tolerance: Data not available. Exposure Procedure: Remove to fresh air, administer artificial respiration or oxygen as necessary remove contaminated clothing. Flush areas with large amounts of water. If conscious, induce vomiting. Get medical attention. Speed is of primary Importance. Reactivity Stability: Stable. However, when anhydrous(dry), tends to from explosive peroxides in air. Compatibility: Material: Iron, aluminum, stainless steel, tin, polyethylene, porcelain, glass, and enamel are suitable for containers. Spill or Leak Procedure Mechanically contain material and remove. stay upwind. Wear face shield and rubber gloves, protective clothing, Beware of flashback along vapor trail. Secure ignition sources. Ground all equipment and personnel ! remarks: + unavailable. Operational Problems/Hazards Dangerous fire hazard. May form explosive petroxides. Personnel Protection Boiler suit and gloves. Tank Cleaning Cold salt water pre-wash, Hot salt water minimum 3 hours. Ventilate. Steam tank and lines. Ventilate , Educt and mop. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection.

Fire /small first Dry chemical,CO2,water spray or alcohol -resistant foam. Largest first Water spray fog or alcohol-resistant foam. do not use dry chemical extinguishers to control fires involving nitromethans or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and left fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL or LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills : Take up with sand or other noncombustible absorbent material and place into containers for later disposal. First Aid: Move victim to fresh air and call emergency medical care; if not breathing , give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

BUTYL METHACRYLATE
Synonyms Butyl 2-methacrylate,n-butyl methacrylate, n-butyl alpha-methacrylate,butyl 2-methyl-2-propenoate, metharylic acid, butyl ester. : 2227 : BMN 2 3 4 9 : CH =C(CH )COOC H : Clear, colorless liquid with typical acrylate odor. : 155c/ 311F : -33c/ -29 F : 0.88 : Acrylate(monomer) : 3.5 : :D : Low :O : 0.29 : 0.4% : 4.9 : Portable lines to dropline or ships lines to Deck/poison tanks. Note : Compoflex hoses NOT suitable with this product. : YES : Purge : NO Blanket : NO Any Coating, but subject to coating guide. Ventilate prior to next cargo. : : : : : : : : Combustible liquid D Heat will increase generation of toxic fumes. 105 2 ~ 8% (estimated) 562 Carbon dioxide, dry chemical or foam Use water spray to cool fire exposed tanks.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Recommended Fire & Explosion Hazard Data Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,1,2 less than 50 Unavailable Unavailable

General : Mild skin irritant. Can be absorbed through skin and lungs. Ingestion Amy cause serious permanent damage or death. Symptoms: Skin- mild irritation and reddening of skin. Inhalation-irritation of mucous membranes and respiratory tract.

Short Exposure Tolerance: 1100 ppm for 1 hour. Exposure Procedure : Skin- wash affected areas with plenty of water. Eyes- wash cool water for 15 min. Inhalation- remove victim to fresh air.

Administer artificial respiration if necessary, and then oxygen. In all cases call a doctor. Reactivity Stability: Butyl methacrylate is relatively stable if properly inhibited. exposure to oxidizers will initiate polymerization. Compatibility: Material : stainless steel is acceptable. Cargo :Group 14 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all-purpose canister mask available. secure all ignition sources. Clean up liquid with paper towels and burn under hood. Operational Problem/Hazards Will polymerize unless inhibitor Assist action of inhibitor, therefore no Nitrogen blanket (see remark) Keep away from adjacent heat. Liquid and vapor cause irritation of eyes and skin. Odor is very persistent. Some shippers will not accept this product as last cargo Clear lines with Nitrogen. Personnel Protection Protective clothing, goggles, gloves. Tank Cleaning Cold salt water wash for minimum 1.5 hour(to prevent polymerization) as soon as possible after discharge. Followed by hot salt water wash, 5 ft. half -hour drops, Ventilate to odor free. Fresh water rinse, Educt and mop Subsequent ventilation/warm air blow may be required prior to next cargo. Tank must be dry. Note : As some manufacturers use different inhibitors, occasionally a Nitrogen blanket may be required. Consult Shipper if in doubt. USCG/IMO Inhibitor brand and amount must be reported. Vapor return line used for loading and transfer. Handling : No foreign material such as water/residue/previous cargo must not come in contact with this readily polymerizing product Tank/line/pumps valves must be 100% clean and dry before loading. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9,15 After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire.

Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind; keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection.

n-BUTYRALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Butaldehyde, butanal, n-butanal, butyl aldehyde, n-butyl aldehyde, butyraldehyde,butyric aldehyde. : 1129 : BTR 3 2 2 :CH CH CH CHO : Colorless liquid, pungent odor. : 76c/ 169 F : -99c/ -146F : 0.82 : Aldehyde : 91.5

Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade- C Electrical Group

: : : : : : : : : : :

B 4.8 O 8.0 6.5% 2.48 Ships lines to deck/poison tanks, or portable lines to droplines. NO Purge : NO Blanket : YES Stainless Steel or zinc, Preferably.

: Flammable liquid :C

General: Fire are difficult to control because of the ease with which the vapors re-ignited. These vapors are readily ignited by static sparks of relatively low energy. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 20(cc) 2.47 ~10.6% 446 Co2, dry chemical, water fog and alcohol foam.

Special fire Procedures : fire parties should wear body and respiratory protection to guard against both inhalation and liquid contact. Keep tank cool with water spray. fight fire from a safe distance or from a protected location. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

2,1,2 0.0046 Unavailable Unavailable.

General : Irritation and burns of the skin and eyes follow contact of short duration. Symptoms: Coughing, watering of eyes, and burning sensation in throat and nose. Short Exposure Tolerance: Animal experiments have shown that large doses produce depression of the central nervous system and anesthesia. Exposure Procedure: Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. Oxygen, when administered by trained personnel, is helpful. Skin or eyes contact- remove contaminated clothing and gently flush affected area with water for 15 min. Get medical advice or attention. Reactivity Stability: Oxidizes to butyric acid readily. Compatibility: Material : mild steel is corroded by butyric formed in presence of air. Cargo : Group 19 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self-contained breathing apparatus, protective clothing. Secure ignition sources.

If possible, cover spill with sodium bisulfate. Add small amount of water and mix. Scoop up. Wash the site with soap solution. Rags used to wipe up small spills should be immersed in water or removed to a safe area without delay Otherwise they may ignite spontaneously. Operational Problems/Hazards Liquid is inflammable and can cause eye damage. Vapor is irritating to eyes, skin and Lungs. Product tends to react with air, therefore a Nitrogen blanket will be required. Also a dessicator in the vent line may be required. Personnel Protection Protective clothing, goggles, gloves, Breathing apparatus on standby. Note : Product must be carried under nitrogen/inert gas pressure(Constant) . Wash tank immediately after discharge. Tank cleaning Thorough cold salt water wash, 2 hour minimum. Followed by Hot salt water wash, 5 ft. half-hour drops with chemical injection. Ventilate to ensure tank drained , When slops drained out steam tank and lines. Ventilate to odor free, Fresh water rinse-Educt and mop. Odor is persistent. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.
Fire or Explosion: Flammable /combustible material; may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard in doors, outdoors or in hazard. Runoff to sewer may create fire or explosion hazard. health hazard: may be poisonous if inhaled or absorbed through skin. vapors may cause dizziness or suffocating. Contact may produce irritating or poisonous gases. Runoff from fire or dilution water may cause pollution. Emergency action: Keep unnecessary people away; isolate hazard area and deny entry. stay upwind;keep out of low area. Positive pressure self contained breathing apparatus and structural fire fighting protective clothing will provide limited protection.

n-BUTYRIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water : Butanic acid,butanoic acid, butyric acid ethylacetic acid, propanecarboxylic acid, propylformic acid. : 2820 : BRA 3 2 2 : CH CH CH COOH : Colorless liquid, pungent putrid odor : 164c/ 327 F : -5c/ 23 F : 0.96 : Organic acid :0 :D :D : Low :O : 0.07 : Complete

Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade- E Electrical Group General: Moderate fire hazard when exposed to heat Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

: : : : :

3.04 Compoflex, Bondstrand and Stainless steel line. NO Purge: NO Blanket : NO Stainless Only.

: Combustible liquid :D

or flame. Yield flammable vapors which form explosive mixtures. : 175 : 2~10% : 846 : Dry chemical, alcohol, foam or foam or carbon dioxide.

Special fire Procedures : Water may be ineffective. wear eye protection and protection clothing. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

2,3,0 0.001 Unavailable Unavailable

General : Skin contact may be severely irritating or may cause moderate burns. Eyes are seriously injured by liquid contact. Symptoms: Vapor-eye, throat, skin irritation. liquid contact; severely irritating with moderate burns. Short Exposure Tolerance: Eyes are seriously injured by a five- percent solution of the acid. Exposure Procedure: Contact with skin or eyes; immediately flush with plenty of clear running water. Wash eyes for 15 min. and get medical care; remove contaminated clothing. Inhalation; Move to fresh air; if breathing is difficult, give oxygen. Get medical attention. Reactivity Stability: Can react with oxidizing material. Compatibility: Material storage tanks and piping can be of stainless steel or aluminum. Cargo: Group 4 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Body shield and self-contained breathing apparatus should be available. Eliminate all sources of ignition. if possible, cover spill with large quantities of soda ash or sodium bicarbonate. Mix and add water if needed for good mixing. Scoop up slurry. Wash site with soda ash solution. Operational Problems/Hazards

Combustible, Low toxicity, Corrosive to most metals. Penetrating odor, Vapor causes eye, throat and skin irritation. Avoid contact with liquid. Personnel Protection Chemical suit gloves and goggles. Tank Cleaning Hot salt water wash (check LEL) Ventilate to gas and odor free, Thoroughly steam tank and line. Ventilate Educt and mop. Grade: Edible, Synthetic, Reagent and Technical. Use in pharmaceuticals, delimiting agent, and disinfectants. Emulsifying agents and sweetening gasoline. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Health hazards Contact cause burns to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away, isolate hazard area and deny entry, Stay upwind; Keep out of low areas. Positive pressure self contained apparatus and structural firefighters protective clothing will provide limited protection. Fire/ Some of these materials may react violently with water. Small fires: Dry chemical, CO2, water spray or regular foam. Large fire : Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Spill or leak: Do not touch or walk through spilled materials ;stop leak if you can do it without risk. Small spill : Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Small dry Spill : With clean shovel place materials into clean, dry container and cover loosely; move containers from spill area. Large Spill: Dike far ahead of liquid spill for later disposal. First AID Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site. Keep victim quite and maintain normal body

temperature.

CALCIUM CHLORINE LIQUEUR

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : TBA C22 C12 Solution in water 40A Inorganic salt in water. Clear pale yellow liquid odorless. 1.35 @ 20 C

: /C. : Ambient. : Ambient. : Ambient :

Reactivity: Reacts with hydroxides to form insoluble calcium hydroxide, also with concentrated mineral acids, giving off heat. Handling Inhibitor Nitrogen (Subject to chaterers Reg.) Tank Coating recommended : : : : Portable lines via droplines. No (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO ANY Coating.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Non-Flammable Draeger Tube No. : Boiling Point : 115 C Explosive Range : % to % Freeze Point : -10C Autoignition Point :

Operational Problems/Hazardous Personnel Protection; Normal protective clothing goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Retain slops on board and discharge on passage. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete Hot salt water wash, Ventilate to gas and odor free. Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Uses : De-icer. Drying oil : NO

CAMPHOR OIL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Gum camphor, impure camphor, light camphor oil, liquid camphor, White camphor oil : 1130 : CPO : C10H16O : Oily liquid, colorless, brown or blue penetrating camphor odor. : ~200c ~392F : : 0.87~1.04 : Ketone : 392 : :B :+ :O :+ : Slight : NP : No specific handling regulations, : NO : Purge: NO Blanket : NO : Epoxy, Polyurethane, and Stainless Steel.

Fire & Explosion Hazard Data Grade- D : Combustible Liquid Electrical Group :D General: Moderate fire hazard when exposed to heat. the solid often evaporates without first melting. Flash Point (F) : 117(cc) Flammable Limits : Unavailable Auto igniting Temp.(F) : 466 Extinguishing Agents : foam, carbon dioxide or dry chemical

Special fire Procedures

: Cool exposed tanks with water.

Health Hazard Data Health hazard Rating : 0,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapors are non-irritating to the eyes and throat. if spilled on clothing and allowed to remain, smarting and Redding of the skin may result. Symptoms: after swallowing, nausea and vomiting, headache, confusion, jerk movements. Short Exposure Tolerance: Reliable data unavailable. Exposure Procedure : In case of contact, flush skin or eyes with plenty of low-pressure water. get medical attention for eye contact. Reactivity Stability: Stable. Can react with oxidizing materials. Compatibility: Material: Cargo : Group 18 of compatibility chart. Spill or Leak Procedure Wear rubber, face shield, protective clothing. avoid contact with liquid. secure ignition sources. shut off leak. flush area with water. remarks: + Unavailable. Operational Problems/Hazards Relatively non-hazardous, Avoid contact with liquid. Get medicine attention for eye contact. A moderate irritant locally, Causes nausea, vomiting, dizziness, excitation and convulsions, non-volatile therefore vapor hazard is not high. Check locally for possible heating instructions dependent on shipper. Personnel Protection Boiler suit , rubber gloves, goggles. Tank Cleaning Hot salt-water wash, minimum 3 hours, with chemical injection Ventilate, Fresh water rinse, Educt and mop Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water Reference note The temperature of the wash water should not exceed 10-20 degree C above the discharge temperature of the product. Higher temperatures can cause to stick on the bulkheads. Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames vapors may travel to a source of ignition

and flash back. Vapor explosion hazard indoors, outdoors, or in sewers. Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus and structural fire fighting protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, or rail car or tank truck is involved in fire. Fire Small fire Dry chemical , Co2, water spray or regular foam. Large Fires : Water spray, fog or regular foam. Move container from sire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Spill or Leak Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Leak Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Large Spill Dike far ahead of liquid spill for later disposal. First Aids Move victims to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

CARADOLS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Prpylene Triglycol ether with a Molecular weight Greater than 3800 TBA [CH2(OCH2 C2 H4)OH]n where n=150 40A Polypylene Triglycol Ethers. Colorless viscous liquid mild odor. 1.02 @ 20 C 0.00068 /C. 30 C 30 C. 30 C Reacts with organic Isocyanates to give large volume of foam. Portable lines via droplines. No (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO ANY Coating.
3

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Above 205 C Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : 390 C Operational Problems/Hazardous Low vapor pressure therefore fire and toxic hazards negligible. Liquid in eyes causes mild irritation. Personnel Protection; Normal protective clothing goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Retain slops on board and discharge on passage. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NIL Cold salt water wash to disperse residues Warm salt water wash minimum 3 hour, Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank and line to be thoroughly dry. Trade name for polyether polyol blends used as a rigid polyurethane foam component. Cleaning code 2.

Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

CARBOLIC OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : Middle Oils TBA 2 Complex mixture. 40A
A mixture or hydrocarbons, phenol and mono, Di and Tri Alkylated Phenols.

Brown mobile liquid Characteristic , coal tar type smell. 0.99 @ 15 C 0.0001/C. Ambient. Ambient. Ambient 21 NO significant Reactions. Compoflex or ships line Not Bondstrand No ( Ensure Certificate obtained and Duration Checked)

: Purge NO Blanket : NO : Stainless Steel, Not Zinc, Epoxy or polyurethane.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 70 C Draeger Tube No. : Boiling Point : 200- 300 C Explosive Range : Freeze Point : Below 0 Autoignition Point : N/A Operational Problems/Hazardous Fire hazard. Avoid contact with skin. Phenol and cresol content can be absorbed causing poisoning, particularly liver and Kidneys. Destroyed contamination footwear. Personnel Protection; Chemical suit, gloves and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A Vapor Return System Reg. : NO Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Negligible Hot salt water wash, Ensure all residues removed Steam tank and lines ,

Ventilate to gas and odor free. Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust
Obtained from distillation of coal Tar ( Boiling range 190C -250C) and containing Naphthalene, Phenol and Cresols.

Note : Avoid and contact with this health hazardous product . Handle same as Phenol. Use protective clothing and mask when loading/ Discharge. Cleaning code 4 Cargoes listed under this group are not or are only partially water-soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture). Reference note. 9 After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach)

CARBON DISULFIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating : Depending on manufacturer See coating lists, Dangerous reaction with Zinc. Carbon bisulfide,carbon bisulphide, Carbon disulphide, Dithiocarbonic anhydride. : 1131 : CBB : CS2 : Colorless liquid, strong Disagreeable odor. : 46c/ 115F : -111c/ -167F : 1.26 : Sulfide : 297 :B :B : 10.3 :O : 10.5 : 0.22% : 2.64 : : NO : Purge : YES Blanket : YES

Fire & Explosion Hazard Data Grade- B : Flammable liquid Electrical Group : No electrical equipment allowed. General: highly flammable liquid with unusually low auto ignition temp. contact with steam line or hot. bare electric light bulb can cause ignition. burning releases irritating and toxic sulfur dioxide gas (SO2). Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : -22(cc) 1.3 ~ 44% 212 2 CO , or dry chemical

Special fire Procedures: a self contained breathing apparatus is recommended. when burning, carbon disulfide produces sulfur dioxide, Which is toxic and highly irrigating. Wear protection clothing. Fight fire from a safe distance or from a protected location. Health Hazard Data Health hazard Rating : 2,2,3 Odor Threshold(ppm) : 0.21 PEL/TWA(ppm) : 4/skin TLV/TWA(ppm) : 10/skin General : Vapor harmful, avoid skin contact with liquid. Symptoms: Light-headaches, dizziness, prolonged contact with skin may cause burns. Short Exposure Tolerance: 1100 ppm for 1/2 hour may cause severe symptoms and Unconsciousness 4815 ppm for 1 hour has been reported as fatal.

Exposure Procedure : Remove to fresh air, give artificial respiration if unconscious. Get medical attention as soon as possible. if breathing is difficult, administer oxygen. Reactivity Stability: Cargo tanks should be isolate from high temperature fluids. Under conditions encountered on tank-ship and barges, carton disulfide is not dangerously reactive. Must be slipped with pad of inert gas. Compatibility: Material: May be slightly corrosive to metals of construction due to impurities. Softens rubber and many plastics. Cargo: Group 38 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, safety glasses, protective clothing and self-contained breathing apparatus. Have carbon dioxide fire extinguisher available. Eliminate flammable and all sources of ignition. Note the low auto ignition temp (212F) Operational Problems/Hazards Very low Autoignition temperature. Severe fire hazards/ Avoid contact with heated steam line etc., steam away from heat. Avoid contact with either liquid or vapor, which can cause blistering of skin. Carried under water pad and nitrogen blanket. See special carriage requirements for this cargo: IMO chapter IV,4.1,4.9, 4.14. Use Closed loading system. Personnel Protection Total protection suit. Breathing apparatus. Restrict personnel on deck. Secure accommodation and recirculate air during all operations. Tank cleaning Discharge procedure includes flushing all lines/pumps to shore ex water pad over cargo therefore negligible slops remain on board. Cold wash, Fresh water rinse. Educt and mop.
Health Hazards Poisonous may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from control or dilution water may cause pollution. First Aids Move victim to fresh air and call emergency medical care; if not breathing give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site.Keep victim quite and maintain normal body temperature. Effects may be delayed; Keep victim under observation. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus and chemicals protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection . Structural firefighters protective clothing is not effective for these materials. Isolate for 1/2 miles in all directions if tank, rail car, or tank truck is involved in fire.

CARBON TETRACHLORIDE
Synonyms UN. No CHris Code Formula Family Benzinoform, carbon tet, methane tet Necatornia, perchloromethane, Tetrachloromethane. : 1846 : CBT : CCI4 : Halocarbon (Aliphatic)

Appearance-Odor : colorless liquid, sweetish odor. Boiling Point : 76C/ 168F Freezing Point : -23c/ -9 F Specific Gravity : 1.59 Chemical Family : Halogenated Hydrocarbon Vapor Pressure(20C) : 90.9 Pollution Category USEPA :A IMO :B Reid Vapor Pressure(psia) : 3.8 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 5.4 Solubility in water : Insoluble Vapor Density(air = 1.0) : 5.49 Handling : Portable lines to droplines Inhibitor : NO Nitrogen : Purge : Possible Blanket : Possible Tank Coating : Stainless steel or zinc, epoxy, polyurethane, but these coating restricted on time and moisture content , Consult coating guide. Normally. Fire & Explosion Hazard Data Grade: Nonflammable, hazardous liquid Electrical Group : NA General : Does not burn. liquid or vapor in contact with hot metal can form poisonous phosgene gas. Flash Point (F) : Flammable Limits : Auto igniting Temp.(F) : Extinguishing Agents : Special fire Procedures : Wear self-contained breathing apparatus. Cool tanks near fire with water. Health Hazard Data Health hazard Rating : 2,1,4 Odor Threshold(ppm) : 50* PEL/TWA(ppm) :2 TLV/TWA(ppm) : 5/skin General : Suspect carcinogen. Breathing vapor in closed space can cause serious illness. The odor threshold is not considered adequate warning of potentially dangerous vapor concentration. Prolonged or repeated skin contact may cause defeating of the skin. Symptoms: Drowsiness followed by unconsciousness and by respiratory failure if exposure is prolonged. Short Exposure Tolerance: Little or no injury from single exposure to 300 ppm for one hour,90 ppm for 4 hour, or 2000 ppm for 6 hour. Exposure Procedure : Vapor- removes victim to fresh air. if breathing is difficult administer oxygen, if breathing stops, Apply artificial respiration. Skin or eye contact- removes contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. DO NOT give victim any preparation containing alcohol because it could be fatal. Reactivity Stability: Stable Compatibility: Material: becomes corrosive when in contact with water.

corrosive to most iron and copper base alloys, aluminum and rubber. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self-contained breathing apparatus, and protective clothing. Avoid contact with liquid. Operational Problems/Hazards Product is non-flammable; however, vapor when inhaled are highly toxic. TLV figure include absorption via mucous membranes. Contact with liquid causes irritation and possible infection and contributes to exposure to vapors. Keep away from heat as possible involvement of phosgene gas Tanks, lines, pumps, etc, must be absolutely dry. Nitrogen blankets may be required to reduce ingress of moisture. Unless tank strengthened, most tonnage allowed is that equal to tank total capacity of SW(1.025). Personnel Protection Total protection suit and breathing apparatus, Restrict personnel on deck, Secure accommodation and recirculate air. Use Closed Loading methods of ullaging. Tank Cleaning Using protective clothing and breathing apparatus Educt residues and ventilate to gas free. Fresh water wash to flushing pump and lines. Thoroughly steam tank and line, Ventilate- Educt and mop. Alternatively cold salt water wash to remove residues, then fresh water rinse. However, in some coating product may have to be ventilated to dryness prior to washing. Vapor is up to 5 times heavier than air and will tend to lie on vessel in still conditions. May make gas-freeing operations prolonged. Exercise caution when entering tanks, checking tank bottom for gas carefully. Hazards both vapors and liquids is very dangerous to health Handle with mask and protective clothing. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing, ventilation etc.) to protect the coating. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE,

Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CARBOLIC OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling : : : : : : : : : : : : : : : TBA TBA Complex . 43A Glycidyl Ester. Clear colorless highly mobile liquid with mild odor. 0.9745 @ 15 C 0.00078 /C. Ambient 40 C . 20 -40 C 34 NO reactions , but absorbs water. Portable lines to droplines Ensure all lines and tanks absolutely dry.

Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

: No (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible : Stainless Steel, Epoxy or polyurethane consult coating guides.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 120/248 C Draeger Tube No. : Boiling Point : 275 C Explosive Range : Freeze Point : - 60 C Autoignition Point : N/A Vapor pressure very low. Operational Problems/Hazardous Non-toxic, liquid causes irritation and may cause mild conjunctivitis in eyes. Vapor apparently has no effects. Product absorbs water and Nitrogen blanket and vent line dessiccator usually required to reduce ingress of moisture. A shell product, shipper should be consulted on heating requirements as these vary. Personnel Protection; Chemical suit, gloves and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water: Negligible Drying oil : NO

Hot salt water wash, 5 ft. half-hours drops. Ventilate to odor free. Fresh water rinse , Educt and mop. Ensure pump and line are thoroughly flushed Steaming may be required. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust
Tank and line must be dry

Product is very color sensitive. Always use nitrogen blanket. Load & discharge overhead . Use portable MP on old line system. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture). Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach)

CASHEW NUT OIL

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : Cardanoll * N/A 3 Contains approx. 90% Anacardic acids. 19 N/A. Dark, viscous, sticky liquid. 0.96 @ C

Ambient. Ambient. Ambient 34 Forms condensation products with Aldehydes No specific handling regulations. Ships or shore lines. No (Ensure Certificate obtained and Duration Checked)

: Purge NO Blanket : NO : Stainless Steel, Polyurethane Epoxy and Zinc Silicate are unsuitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point :

Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: : 180- 230 C : : :

Operational Problems/Hazardous In untreated form is highly. strong irritant , causing blisters similar to that of poison ivy. Polymerizes on heating, therefore should be kept away from heated cargo. Personnel Protection; Chemical suit, gloves and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Retain on board -discharge on passage as per regulation Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Drying oil : NO

Cold wash to remove residues, then drain tank Hot wash with chemical injection Fresh water rinse or steam Ventilate, Educt and mop. NOTE: This product may cause discoloration of tank coating and cleaning may be difficult and subsequent contamination of susceptible products may occur. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Product is toxic and a strong irritate especially to light skinned people. Ask for literature dealing with prevention and remedies. NY barges havent handled this product in years, Be sure to check barging before booking. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

CASTOR OIL
Synonyms Ricirus Oil, Turkey red oil, Castor oil sulphorated, Soluable castor oil, Alizarin Asst. Alizarin Oil. IMO No : N/A IMO TYPE :3 Formula : N/A ICS Guide Page No. : 19 Family : Ester. Appearance and character : Water white to pale yellow liquid. Viscous, slightly turbid, having slight sediment. Free from rancid odor. Specific Gravity : 0.95@ 25 C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 34 Reactivity : Basically non-reactive. Handling : No specific handling regulations ship or shore lines. Inhibitor : No ( Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg.) Tank Coating recommended : Purge NO Blanket : NO : Stainless Steel, Epoxy or polyurethane.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 204-260 C Draeger Tube No. : Boiling Point : 313 C Explosive Range : Freeze Point : Below 0 Autoignition Point :

Operational Problems/Hazardous A non-drying oil which is made drying by dehydrating. Should therefore be washed as soon as possible. May required food grade tank before being acceptable to load this product. Personnel Protection; Boiler suit , normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Pre-Clean with Cold water to remove residues. Clean with hot water and chemical injection Spot clean as necessary. Ventilate If residues disposed - thoroughly steam tank and line Ventilate, Educt and Mop B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank must dry No heat needed in warm climate seasons. Zinc - the FFA is usual around 1 % - but check before stow in Zinc tanks, Grades - Medicinal is same as Grades#1 - No problem. Product is expensive so be sure to have tanks/ line and pumps clean and dry. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. Drying oil : NO

CAUSTIC SODA SOLUTION

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Sodium Hydroxide Solution, Lye solution, Sodium hydrate solution, Sodium hypochlorate solution. : 1824 :3 : NaOH. : 192 : Alkali. : Colorless or gray, syrupy liquid, slow-moving Characteristic odor. : 1.53 @ 15 C : : : : : 0.00072/C. Above 10 C 15 - 30 C 15- 30 C 5

Reactivity: Violent with acids, acetaldehyde, Caroline, acrylonitrile, halocarbons, aldehydes, phenols, nitriles, ketones, esters and anhydrides. Handling : Product is highly corrosive and should be loaded via manifold line only. Inhibitor : No (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Stainless Steel, Epoxy, Polyurethane Some coatings may require 3 days ventilation before next loading. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : None Draeger Tube No. : Boiling Point : 140 C Explosive Range : Freeze Point :8C Autoignition Point : Vapor pressure Low Operational Problems/Hazardous Product is non-flammable but highly corrosive and should be treated with great respect, both liquid and frozen crystals will cause severe burns with contact. Ensure system does not leak, especially in pump-rooms.

Heat may or may not be required and charterer should be consulted. TLV is 2mg/m3 based on a fine spray. Vapor not normally a hazard. Ensure pumps and lines thoroughly flushed as product can be difficult to remove due to high SG. Personnel Protection; Protective clothing, goggles and gloves, While tank cleaning ensure washings are discharged through sea valves, or over-side hoses with ends below waterline to prevent product - spray over decks and accommodation. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water: Complete

Drying oil : NO

Warm sea water wash, 5 ft. half hour drops. Ventilate - Educt and mop. Thoroughly flush all lines and pumps to ensure all products removed, particularly in way of Recirculation lines and gate valves. Ensure tank and lines dry. Further ventilation for 24 hours prior to loading or ballasting is recommended. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to: Smell/Moisture/Rust Ensure all previous residues are removed, especially molasses or vegoils. Lines and pumps and heating coils to be thoroughly cleaned. Various grades of caustic soda are shipped; from use as cleaning agent to manufacture of batteries. Surveyor takes inspections very seriously and may require foot sample. Do not leave lines charged with Caustic soda, as it will attack the steel. After loading flushed lines clean. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (B)Warm water (38 to 55 degree C ) Health hazards Contact causes burns to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Fire or explosion Some of these materials may burn, but none of them ignites readily. Flammable poisonous gases may accumulate in tanks and hoppers cars. Some of these materials may ignite combustibles (wood, paper, oil, etc) Emergency Action Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind keep out of low areas. Positive pressure self contained breathing apparatus and structural firefighters protective clothing will provide limited protection. Call chemtrec at 1-800-424-9300 for emergency assistance. If water pollution occurs, notify the appropriate authorities. Fire Some of these materials may react violently with water. Small fire : Dry chemical .CO2, water spray or regular foam. Large fire Water spray, fog or regular foam. Move container from fire area if can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after this is out. Stay away from ends of tanks. Spill or leak

Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills Take up with sand or other noncombustible absorbent material and place into containers from spill area. Small dry spill With clean shovel place material into clean, dry container and cover loosely; move containers from spill area Large spill: Dike far ahead of liquid spill for later disposal First aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

CERECLORS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : TBA : : Chlorinated Paraffin C22-C26 : : TBA. : Colorless/yellow liquid mild odor. : 1.15-1.55 C : : : : : : : : : :

20- 30 C 30 C . 30 C 36 Check Locally. Compoflex or ships line No (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible See Manufacturers lists for restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Below 0 Autoignition Point : Operational Problems/Hazardous Non- toxic, Non- flammable. Information on this product should be obtained locally, Personnel Protection; Boiler suit and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water: Nil Hot salt-water wash, with chemical injection. Fresh water rinse. Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard)

NO

Drying oil : NO

Product is susceptible to : Smell/Moisture/Rust Trade name for a series of secondary plasticizers manufactured from chlorinated waxes. % Chlorine indicated by product number- e.g. Cerclor 70. Heating: Steam coils inside tanks are unsuitable too hot. If when heat is needed, a little heat on the right kind of adjacent cargo, will do.

CHINA CLAY SLURRY

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : Kaolin Slurry : : : : : : Resembles weak white emulsion paint with kaolin-type odor. : 1.71 - 1.76 @ C : /C. : Ambient. : Ambient. : Ambient :

Reactivity : NO significant Reactions. Handling : Via manifold ships lines. Avoid splash loading due high SG. If dropline loading, load slowly to provide good bottom Cushion before increasing load rate. Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : YES (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible : Polyurethane, Epoxy: consult coating guides.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : C Explosive Range : Freeze Point : 3C Autoignition Point : Operational Problems/Hazardous Product is occasionally heated in severe weather consult Charterer. Product is Inhibited in the sense that biocides are added to prevent fumgicidal growth in the product in transit. Product is solids in suspension - i.e. 70% China clay, 30% fresh water. To obviate settling out, it may be necessary to recirculate the product using ships pumps. A supply of biocide is carried and may be added to product on charterers instruction. May require pudding. As temperature affects growth of fungus stow away from adjacent heat. Personnel Protection; Protective clothing goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. :

NO

Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete

Drying oil : NO

Although not a Dying oil Kaolin when dry is very difficult to remove. Immediately after discharge tanks to be cold salt water washed down, lines and pumps to be flushed and blown clear Therefore warm slat water wash 5 ft half hours drops. Ventilate. Fresh water rinse. Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Highly susceptible to smell and rust and tanks and lines must be thoroughly hot washed, steamed, blown dry, prior loading and ventilated odor free. Uses : High grade crockery and papers. Not unlike stomach mixture !.

CHLOROBENZENE
Synonyms Benzene chloride, Benzene chlorobenzol MCB, Monochlorobenzene, Phenyl chloride UN. No : 1134 CHris Code : CRB Formula : C6H5CI Appearance-Odor : Colorless liquid, almond like odor Boiling Point : 132C/ 270 F Freezing Point : -45C/ -48F Specific Gravity : 1.11 Chemical Family : Halogenated hydrocarbon Vapor Pressure(20C) : 10.0 Pollution Category USEPA :B IMO :B Reid Vapor Pressure(psia) : 0.5 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.8 Solubility in water : Negligible Vapor Density(air= 1.0) : 3.88 Handling : Portable lines to droplines, or ships lines NOTE : Compoflex notes may be used but should be flushed clean immediately after use. Inhibitor : NO Nitrogen : Purge : NO Blanket : Possible Tank Coating : Stainless Steel, Zinc, Polyurethane, Epoxy may be used with restriction on moisture and drying ventilation prior to next cargo. Consult coating lists. Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General Burning releases toxic and irritating gases of phosgene and hydrogen chloride. Ignited by heat or open flames. Flashback along vapor trail may occur. Vapor may explode in an enclosed area. Flash Point (F Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : 90(cc) 1.3 ~ 7.1 % 1180 Co2,dry chemical, water fog, foam. Supply respiratory protection to fire fighting personnel.

Health Hazard Data Health hazard Rating : 0,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 75* TLV/TWA(ppm) : 75* General : Vapor irritating to skin, eyes and mucous membranes. Symptoms: Drowsiness, twitching of extremities, and deep, rapid respiration. Short Exposure Tolerance: Exposure for 0.5 hours to 6500 ppm or 1 hour to 2000 ppm would not be expected to cause death. Exposure Procedure: Remove victim to fresh air, if breathing stops, apply artificial respiration.

skin or eye contact- Remove contaminated clothing and gently flush affected area with for 15 min. Get medical advice or attention. Reactivity Stability: Reacts vigorously with oxides. if heated to decomposition, toxic chlorine compounds will be given off. Compatibility: Material : Relatively non-corrosive. Attacks rubber. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, and protective clothing. avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards No particular hazard, although liquid and vapor cause irritation and high concentrations of vapor can cause unconsciousness and possible liver or kidney damage. Tanks and lines must be dry and desiccator may be required in vent line. Also some charterers may require a Nitrogen blanket to reduce moisture ingress. Personnel Protection Protective clothing goggles and gloves Breathing apparatus on standby. Tank Cleaning Cold slat water pre-wash minimum 1 hour Followed by hot salt water wash, 5 ft. half hour drops Ventilate to odor free Fresh water rinse Educt and Mop Tank must be ventilated for further 24 hours prior to next cargo if Epoxy or polyurethane - to allow coating to reharden. Individual tank tonnage must not exceed tonnage equal to total capacity of tank in SW (1.025) Use protective clothing and mask when working with this cargo. both vapor and liquid is very harmful to health. It is otherwise an easy cargo to handle. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS

May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

CHLOROFORM
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Formal trichloride, methane, trichloro, Methenyl trichloride, trichloromethane : 1888 : CRF 3 : CHCI : Colorless liquid, sweet odor : 61C/ 142F : -63C/ -82F : 1.48

Chemical Family : Halogenated hydrocarbon Vapor Pressure(20C) : 153 Pollution Category USEPA :A IMO :B Reid Vapor Pressure(psia) : 6.39 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 9.00 Solubility in water : Slight Vapor Density(air= 1.0) : 4.25 Handling : Ships lines to poison tanks or portable lines to droplines. Load slowly to cover tank bottom before increasing rate. NOTE: Compoflex hoses may be used but must be flushed clean immediately after use. Inhibitor : YES Nitrogen : Purge : Possible Blanket : Possible Tank Coating : Stainless Steel or Zinc. Draeger Tube No. : Ch244 Trichloroethylene 10/a Fire & Explosion Hazard Data Grade- E : Combustible liquid Electrical Group :D General Will burn only after prolonged exposure to flame or high temp. when heated or exposed to a flame, chloroform decomposes to form phosgene, which is highly poisonous Flash Point (F) : Flammable Limits : Auto igniting Temp.(F) : Extinguishing Agents : Special fire Procedures : Keep fire exposed tanks cool with water spray. wear eye protection, self contained breathing apparatus and protective clothing. Health Hazard Data Health hazard Rating : 2,1,1 Odor Threshold(ppm) : 200~300 PEL/TWA(ppm) :2 TLV/TWA(ppm) : 10 General Suspected carcinogen. breathing vapor in enclosed area can cause loss of consciousness. Odor threshold is higher than the TLV. Exposure to potentially dangerous vapor concentrations can occur before the product can be detected by smell. Symptoms Irritation of mucous membranes and skin; drowsiness. Short Exposure Tolerance: Inhalation of 400~600 ppm for 30 min. or less can prove fatal. Exposure Procedure : Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eyes contact; remove Contaminated clothing and gently affected areas with water for 15 min. get medical advice or attention. Reactivity Stability: Decomposes in the presence of excess water or a high temp. to give phosgene and hydrogen chloride, which are very toxic, can become explosive in the presence of strong alkalis and water. Compatibility: Non corrosive at normal atmospheric temp. when free of moisture. in contact with water and at high temp. it becomes corrosive. Corrodes iron and certain other metals.

Cargo :

Group 36 of compatibility chart.

Spill or Leak Procedure Wear rubber gloves, self-contained breathing apparatus, and protective clothing. Avoid contact with Liquid. Operational Problems/ Hazards For Practical purposes product is considered non-flammable Both liquid and vapor cause irritation skin and eyes anesthetic effect. Contact with water increases acidity which is aggressive to coatings. Nitrogen blanket and vent line desiccator may be required. Vapor return system may be required by some charterers. * Note: Do not Bondstrand lines. Personnel Protection Protective clothing gloves and breathing apparatus. Secure accommodation and recirculate air while gas freeing. Use Closed Loading system for ullaging. Tank Cleaning Cold sea water pre-wash, minimum 1 hour, then Hot sea water wash, 5 ft. half hour drops. Ventilate, Educt and mop After carriage in Zinc it is preferable to Educt residues (full protective clothing , breathing apparatus , etc.,) and ventilate or evaporate tank gas free and dry prior to washing. Due to low vapor pressure and high SG ventilating may be prolonged. Ensure tank and lines are absolutely dry and odor-free. Tank inspection before loading very strictly. It is customary to purge tank- ensuring dryness. Nitrogen blankets all the times. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks.

Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CHLOROPRENE
Synonyms : 2- Chlorobutadiene, See also Latex IMO No : 1991 IMO TYPE :2 2 2 Formula : CH = CCI - CH = CH ICS Guide Page No. : Family : Appearance and character : Colorless liquid. Specific Gravity : 0.9583@ 20 C Heating Range (Subject to Chart.Reg.) Correction factor : /C. Carriage : Ambient. Disch. : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 36 Reactivity : Contains :- Butadiene, Acrylonitrile, Toluene- Consult relevant materials. Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : As for LATEX. : YES (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : YES : Stainless Steel or Epoxy, NOT ZINC.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : TLV 25ppm Flash point : -20C Draeger Tube No. : 67189 Chloroprene 5/a Boiling Point : 59C Explosive Range : 4 % to 20% Freeze Point : C Autoignition Point : Operational Problems/Hazardous Highly inflammable , Toxic, Reactive monomer. Keep away from adjacent heat. Personnel Protection; Chemical protection suit and Breathing Apparatus. In case of contact flush thoroughly with fresh water : Consult physician. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : Possible Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight See remarks Cold wash ,Warm wash, Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust A similar product to Latex: Very little information available - Spraying may be required. USCG- Product is classified but ungrouped. Stow GR.36 until hearing differently. Handling- Low boil/ flash point plus being toxic makes this product a hazardous cargo. Handling with caution. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Extremely flammable; May be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural Firefighters protective clothing is not effective for these materials Isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE FIRE 2 Small Fires: Dry chemical or Co , water spray or regular foam.

Large Fires: Water spray, fog or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CHLOROSULFONIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Chlorosulfuric acid, chlorsulfonic acid, chlorsulfuric acid, Sulfuric chlorohydrine. : 1754 : CSA 2 2 : HOSO CI, or SO .HCI : Colorless to light liquid, pungent odor. : 152C/ 305 F : -80C/ -112 F : 1.79 : Inorganic acid : <1.0 :C :C : 0.03 :O : 0.08 :* : 4.0 : Compoflex and ships lines - flush after use : NO : Purge : Possible Blanket : Possible : Stainless Steel (Must be dry)

Fire & Explosion Hazard Data Grade : Non- flammable. classified as corrosive liquid. Electrical Group :B (based upon possible hydrogen gas (H2) generation should a leak occur.)

General: Non- flammable. but it may cause ignition by contact with combustible materials. Dangerously reactive. explosive concentrations of hydrogen gas can accumulate inside tanks containing this acid spill in confined space may produce explosive concentration of hydrogen. See data sheet for hydrogen. Flash Point (F) : Non- flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : " Special fire Procedures DO NOT USE WATER. wear full protective clothing. including self contained breathing apparatus. cool adjacent tanks with water spray from a distance. Health Hazard Data Health hazard Rating : 4,4,4 Odor Threshold(ppm) :3 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) :1 General Vapor inhalation may cause loss of consciousness with serious damage to lung tissue. Liquid causes severe irritation and watering of the eyes. Symptoms: Contact of liquid with the skin can cause severe burns. breathing the vapor will cause severe Irritation and watering of the eyes. Short Exposure Tolerance: 30 ppm for 10 min., 10 ppm for 60 min.. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. Oxygen, administered by trained personnel, is often helpful. skin or eyes contact- Remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Violently reacts with water forming sulfuric and hydrochloric acids. Compatibility: Material: Dangerously reactive. In addition to attacking many metals, the acid is a strong oxidizing agent and will react with water and organic Materials with evolution of heat and large quantities of dense fumes. Cargo : chlorosulfonic acid is unassigned in the compatibility chart for compatibility assistance, Call-G-MTH-1(202-267-1577). Spill or Leak Procedure Wear rubber gloves, self-contained breathing apparatus, protective clothing. Avoid contact with spilled liquid. From a distance carefully flush the spill away with water. Great care must be taken as water and chlorosulfonic acid react violently forming toxic HCI fumes and sulfuric acid. Consequently, clean up personnel should work with the wind at their backs. If water is not available or if inversion conditions prevail, apply dry sand, vermiculite ashes or powdered clay to absorb the spill. Operational Problems/Hazards Highly toxic Strong irritant to eyes and skin. Liquid causes severe burns , Evolves hydrogen on contact with most metals, especially when diluted. Nitrogen blanket and/or vent line desiccator will be required. Clear lines with Nitrogen. Use Closed Ullaging system.

Personnel Protection Total protection suit, breathing apparatus. Restrict personnel on deck. Secure accommodation and recirculate air during all operations. Tank Cleaning Cold salt water wash, 5 ft. half-hour drops Steam tank and lines Ventilate Educt and mop Decomposes in water to Sulfuric and hydrochloric Acids.

HEALTH HAZARDS May be fatal if inhaled swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. May ignite other combustible materials (wood, paper, oil, etc) violent reaction with water. Flammable/poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. FIRE Do not get water inside container. Small Fires: Dry chemical, Co2 Large Fires: Flood fire area with water from a distance do not get water inside container. Move container from fire area if you can do it without risk apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor; do not put water directed on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Spills; Dike for later disposal; do not apply water unless directed to do so cleanup only under supervision of an expert. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature.

CHOLINE CHLORIDE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor : : : : : : : : 2- Hydroxy-Ethyl, Trimethyl Ammonium, Hydroxide. N/A N/A 3 3 2 2 (CH ) N (CL) CH CH OH N/A Practically Colorless liquid with faint chlorine type odor. 1.104 @ 15 C

:. : Ambient. : Ambient. : Ambient : 20 : Neutral. : Compoflex , Bondstrand or ships lines. :- (Ensure Certificate obtained and Duration Checked)

Nitrogen (Subject to chaterers Reg. ) : Purge: Blanket : Tank Coating recommended : Stainless Steel Preferred Zinc unsuitable Epoxy and polyurethane subject to manufacturers. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : N/A Draeger Tube No. : Boiling Point : 247C Explosive Range : Freeze Point : -12 C Autoignition Point : Operational Problems/Hazardous General low toxicity but liquid and vapor will cause irritation. Product contains trimethylamine. Personnel Protection; Boiler suit and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO

Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete Warm wash F.W rinse ,Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust

Drying oil : NO

Group B vitamins used in animal foodstuffs made by ICI petrochem wilton . 75% aqueous solution. Product must not come in contact with hot surfaces. S.Steel - This is very corrosive cargo needing 316L/ 317 SUS tank in perfect condition. Inspect tank before & After loading . Phenoline- This is safe tank lining. Carriage with no problem in this coating. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

COCONUT OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity : : : : : : : : : : : : : Coconut Palm oil, Coconut Butter. N/A 3 N/A Ester White , semi-solid, lard-like fat with characteristic odor. 0.91 @ 20 C 0.00068/C. 24 C. 49 C 30 C 34

: Basically- non-reactive

Handling : NO specific handling regulations Portable lines to droplines and shore lines. Inhibitor Nitrogen (Subject to chaterers Reg.) : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO

Tank Coating recommended : Epoxy, polyurethane, Stainless Steel Not normally carried in Zinc Silicate copper and its alloys as tank fittings unsuitable. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 286C Draeger Tube No. : Boiling Point : 280C Explosive Range : Freeze Point : 28C Autoignition Point : Operational Problems/Hazardous Has been shown that vapor from hot coconut oil either excludes or absorbs oxygen, therefore entry into tank should be prohibited until tank has been well vented and oxygen content checked. Temperature rise on heating should not exceed 3 C/day to be at discharge temperature 3 days prior to discharge High standard of cleanliness required. Tank may have to be swept on discharge dependent on grade some shippers prefer to splash load product over deck. Personnel Protection; Boiler suit, normal working gears Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO

Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Warm /hot salt water wash, minimum 3 hours, with chemical injection. Spot clean as required Fresh water rinse Educt and mop. NOTE: Too much heat and chemical may result in a white powder deposit on surfaces which is difficult to remove. Do not ballast tank ex coconut oil if it can be avoided. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank must be dry and grease free Coconut : FFA always below 1% Zinc O.K. Make sure blowers are supplying sufficient air to men doing the sweeping (squeezing) Start blowers . 5 hour before men enter tanks. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture). Reference note 10. The temperature of the wash water should not exceed 10-20 degree C above the discharge temperature of the product. Higher temperatures can cause to stick on the bulkheads.

COD LIVER OIL

Synonyms : Morrhuae

IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. )

: : : : : : :

N/A 3 N/A Ester Pale yellow liquid with slight fishy odor. 0.92 @ C

:. : Ambient. : Ambient. : Ambient : : Combustible ( non- toxic) : No specific handling regulations . Portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO

Tank Coating recommended : Subject to FFA restrictions Epoxy preferred (polyurethane or SUS ) Copper alloys unsuitable as tank fittings Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Could possibly absorb or exclude oxygen for tanks therefore before tank entry oxygen content should be checked. Product may be Food Grades and tank must have high cleanliness standard and good coating. Heat product as per shippers instructions. Product will be discolored by excessive heat or sharp increase in temperature. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Hot salt water wash, minimum 3 hours, with chemical injection, Spot cleaning as required. Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust

CORN OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : Maize Oil N/A 3 N/A 19

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor

: Ester : Pale yellow liquid with characteristic odor. : 0.914-0.921 :. : Ambient. : Ambient. : Ambient : 34 : Basically non-reactive : No specific handling regulations . Portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked)

Nitrogen (Subject to chaterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Subject to FFA restrictions Epoxy preferred (polyurethane or SUS ) Copper alloys unsuitable as tank fittings Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 321C Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : -10C Autoignition Point : Operational Problems/Hazardous Could be absorb or exclude oxygen for tanks therefore before tank entry oxygen content should be checked and maintain. May require sweeping subject to charterers requirement. Some shippers may require product heated, Nitrogen blanket and/or vent line dissector. check locally. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Cold pre-wash as soon as possible after discharge, Hot salt water wash, minimum 3 hours, with chemical injection, Ventilate and inspect. Fresh water rinse or steam tank and lines Ventilate, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank must be dry Heat- product is best handle at 60~80F Only in very cold climate is heat needed. Zinc- The FFA is usually low. but check to be sure. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the

composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

CORN STEEP LIQUOR

Synonyms : IMO No : TBA IMO TYPE :3 Formula : TBA ICS Guide Page No. : Family : Ester Appearance and character : A Dilute aqueous solution obtained form soaking corn jernels in warm 0.2% sulfur dioxide solution. Specific Gravity : 0.75 ~0.89 C Heating Range (Subject to Chart.Reg.) Correction factor : /C. Carriage : Ambient. Disch . : Ambient.

Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

: : : : : : :

Ambient

No specific handling regulations . NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Polyurethane, Stainless Steel, Epoxy Preferred.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous

Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Drying oil : NO

Hot salt water wash, with chemical injection , minimum 2 hours Ventilate to gas and odor free. Fresh water rinse. Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust

COTTON SEED OIL

Synonyms : Cotton oil Streine, Seed oil, C.S.O., PBSY IMO No : N/A IMO TYPE :3 CHris Code : OCS Formula : N/A ICS Guide Page No. : Family : Ester Appearance and character : Pale yellow oil (dark if crude ) which deposits sterine on standing, particularly at low temperatures. Pure oil is odorless and has a bland taste. Specific Gravity : 0.915 - 0.921 @ 25C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00068 /C. Carriage : Ambient. Disch . : 20 ~ 25 C Average Expected Load Temp. : 20 C. USCG Compatibility chart Group No : 34

Reactivity : Basically non- hazardous Handling : No specific handling regulations . Portable lines to droplines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge NO Blanket : Possible Tank Coating recommended : Epoxy, Polyurethane, Stainless Steel, Zinc Silicate ( with FFA below 5%) Subject to coating compatibility Lists Consult USCG Compatibility Chart Operational Problems/Hazardous A semi -drying oil which request pre-wash wash immediately after discharge. May require sweeping subject to charterers requirements In the event of this oxygen content of tank to be checked and maintained. Temperature to be increased as per shippers instruction. Personnel Protection; Boiler suit, normal working gear. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Drying oil : YES

Solubility in water : NO Cold salt water pre-wash immediately after discharge to remove residues. Cotton seed oil may harden at high temperature and scorch firmly to the steel. Hot salt water wash, minimum 3 hours , with chemical injection . Spot cleaning as required. Ventilate, If residues removed, thoroughly steam tank and line, Ventilate Fresh water rinse, Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Heat- For a good out-turn apply Heat (80F) max. if ambient temperature is below 50F. Zinc- FFA is low -less than 1% - check to be sure. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 10. The temperature of the wash water should not exceed 10-20 degree C above the discharge temperature of the product. Higher temperatures can cause to stick on the bulkheads. Reference note 22. These cargoes are drying or semi-drying oils which require cold(ambient) washing immediately after discharging. Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) : : : : : : : : : ~0c/ ~32 F 0.92 Ester 2.0 D 0.1 D 0.15

Solubility in water Vapor Density(air= 1.0) Fire & Explosion Hazard Data Grade- E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: Negligible :+

: : : : : : : :

Combustible liquid D Slight fire hazard when exposed to heat or flame. 486(cc) Unavailable 650 Dry chemical, foam, or carbon dioxide. Water may be ineffective on fire. Cool exposed tanks with water.

Health Hazard Data Health hazard Rating : 0,1,0 Odor Threshold(ppm) : None PEL/TWA(ppm) : None TLV/TWA(ppm) : " General : Non-toxic. Symptoms : Non-toxic. Short Exposure Tolerance : Non- toxic. Exposure Procedure : Non-toxic. if accidentally splashed into eyes, wash yes thoroughly with copious Maoist of water. Reactivity Stability: Stable Compatibility: Material : usual materials of construction are suitable. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves and face shield. clean up excess amounts and wash residue away with water.

CRESYLIC ACID
Synonyms : Xylenol, 2- Methyl Phenol IMO No : 2022 IMO TYPE :3 Formula : (CH3)2 C6 H3 OH ICS Guide Page No. : 51 Family : Phenol Appearance and character : May be Colourless or dark brown with a sharp disinfectant-like odor. Specific Gravity : 1.05 @ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00073 /C. Carriage : 0~ 30C . Disch . : 0 ~ 50 C. Average Expected Load Temp. : 0 ~ 50 C USCG Compatibility chart Group No : 21 Reactivity : Reacts with oxidizing agents, acids, amines and alkalis. Handling : Ships lines poison/deck tanks. Bondstrand type portable lines are NOT suitable,. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge Possible Blanket : Possible Tank Coating recommended : Stainless Steel Maybe Zinc, dependent on coating guide. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 80 C Draeger Tube No. : CH315 Phenol 5/a

Boiling Point Explosive Range Freeze Point Autoignition Point

: 190 C : 1 % to : 0-30 C : 590 C

Operational Problems/Hazardous Product is composed of phenol Cresols BP and temperature requirements, As high phenolic content, product must be treated with care. Product is toxic and corrosive, and subject to polymerization if not heated, subject to specific mixture. Must be well segregated from any product susceptible to smell. Personnel Protection; Total protection suit and breathing apparatus Restrict personnel on deck. Accommodation secured and air on Recirculation. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : Possible Ideally discharge slops to shore facility , otherwise retain on board and discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Slight Drying oil : NO

Hot salt water wash, 5 ft. half hour drops (check LEL) Ensure pump and line system thoroughly flushed clear. Ventilate to gas and odor free Thoroughly steaming tank and lines Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Treat for phenol. USCG- If product contains more than 5% phenol, the carriage requirement of phenol shall apply -Check. Grade- Specification vary a great deal- each shipper differ on color & heat . Clear colored stuff should be carried under nitrogen pressure, to remain clear- Check !. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X Wash water temperature Code (B)Warm water (38 to 55 degree C)
HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires: . Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; W ith clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CROTONALDEHYDE
Synonyms U.N No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating 2-Butenal,trans-2-butenal,crotenaldehyde, stabilized,crotonic aldehyde,betamethylacroein,propylene aldehyde. : 1143 : CTA : CH3CH=CHCHO : Water white to yellow liquid suffocating tarry odor. : 102c/ 216 F : -74c/ -102 F : 0.85 : Aldehyde : 30 :B :B : 1.5 :O : 2.0 : Slight : 2.41 : Stainless Steel Lines Do Not Compoflex or Bondstrand : YES : Purge : NO Blanket : Possible : Stainless Steel

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :C General : At elevated temp. polymerization occurs. if the polymerization takes place in a closed container, violent rupture is possible. Flash Point (F) : 55

Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : Cool hot containers surfaces with water.

: 2.1% ~ 15.5% : 450 : Alcohol foam, carbon dioxide or dry chemical.

Health Hazard Data Health hazard Rating : 3,3,3 Odor Threshold(ppm) : 0.13 PEL/TWA(ppm) :2 TLV/TWA(ppm) :2 General : Suspected carcinogen. vapor extremely irrupting. Liquid causes severe burns. A lachrymator. Symptoms: Vapor causes eye irritation and burning skin irritation at high concentrations, and inhalation results in coughing, watering of eyes and burning of nose and throat. liquid causes severe irritation to eyes and skin. Short Exposure Tolerance: Unavailable. Exposure Procedure : In case of skin contact, wash thoroughly with soap and water for at least 15 min. In case of eye contact flush with water then obtain medical aid. Reactivity Stability: May polymerize when mixed acids or brass Compatibility: Material : compatible with aluminum and stainless steel. Cargo : Group 19 of compatibility chart. See also appendix 1- exception to the chart. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, protective clothing. Avoid contact with liquid. Secure ignition sources. cover with sodium bisulfate(NaHSO3). Ad small amount of water and mix. Scoop up. Wash site with soap solution. Operational Problems/ Hazards Flammable, Dangerous fire risk, Highly toxic, especially irritating to eye and skin , Water inhibits polymerization, Clear lines with Nitrogen. Use Closed Ullaging system. Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection Chemical suit, gloves and goggles, Breathing apparatus. Tank cleaning Cold salt water Pre-wash to disperse residues Hot sea water wash, minimum 3 hours ( check LEL ) Steam tank and line. Ventilate Educt and mop. Handling -carrying it under Nitrogen pressure. Cleaning- Wash tank immediately after discharge. Deodorize with blowers/nil odor or polycomplex - it sticks . Use protective clothing mask.

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames vapors may travel to a source of ignition and flash back container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. . FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Move container from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; Stop leak if you can do it without risk water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CRUDE/ PALM OILS

Synonyms : CPO, * For variations see remarks IMO No : NIL IMO TYPE :3 Formula : ICS Guide Page No. : Family : Ester Appearance and character : Deep red yellow oil, with buttery consistency and characteristic odor. Normally solid at ambient temperatures. Specific Gravity : 0.892 @ 49 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00061/C. Carriage : 32~48C . Disch . : 49~ 55 C. Average Expected Load Temp. : Approx. 45C USCG Compatibility chart Group No : Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg.) Tank Coating recommended : When mixed with caustic forms cudes form of soap. : No specific handling regulations. Ship or shore lines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Epoxy, Polyurethane, Stainless Steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Requires strict adherence with charterers heating instructions . Surveyor is becoming increasing temperature when passing tanks as suitable for palm Oil, especially in Fareast. Temperatures should not increase more than 5 C/day. Tanks have to be carefully swept. Before entry into tanks oxygen content should be checked and maintained. Crag lines usually required to be steamed ashore, also advisable to steam back to tank after passed as dry, to prevent blockage of lines. Most shippers will provide on depends a table of SG. Personnel Protection; Boiler suit, gloves, normal working gear.

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : Possible Classed as residual oil Discharge possibly ashore - otherwise discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Drying oil : NO

Steam down Very hot wash with chemical injection ( temperature maximum compatible with coating) 5 ft. half hour drops Extensive spot cleaning may be required. Fresh water rinse or steam Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Remarks ( N.B. Ensure all other publications held on board are consulted in conjunction with this guide including company manuals on safety Before any tank entry CHECK oxygen content of tank Note : Variations acid-treated, palm-olein, palm lotox, RDB palm or palm stearin may be carried. These differ only in heating requirements and FFA content. Minor SG Check locally when loading these products. Palm acid oil- Heat ; all shippers except Plamco agree to our recommended heating. Plamco no heat during voyage. start heating 7 to 10 day before arrival at discharge port. maximum temp. for discharge is 135F Adive; bring temp. up to 135F- two days before arrival at port of discharge. recirculate cargo for 6hours if heavy bottom-Helpful. Palm fatty acid- Heat; heating instruction from Palmco is the same as for palm acid oil- above. this grade handles better at 135F, so heat according to palmco. Phenoline- Make sure to get exact phosphoric acid contain before stow. carboline (SL) confirm 50 ppm as being OK . Palm kernel oil- Heat maintain 100F during voyage, if a short trip. for loger voyages start heating 7 to 10 days before arrival ar discharge port. Palm kernel sterine- Heat ; If needed, no heat during voyage is OK but be sure to heat cargo very slowly for discharge . Do not raise temp. mor than 5 F per day. Palm olein- Heat- both olein grades be carried discharged without heat when in warm climate not exceed 95F for discharge. FFA/Zinc at 0.25% good cargo -no problems. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

CUMENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating Fire & Explosion Hazard Data Grade- D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Benzene,1-methylethyl,cumol,isopropyl Benzene, (1-methylethyl)benzene,2-phenyl propane : 1918 : CUM 6 5 3 2 : C H CH(CH ) : Colorless liquid, sharp, penetrating aromatic odor. : 152c/ 306F : -96c/ -141 F : 0.86 : Aromatic hydrocarbon :8 :D :B : 0.5 : D,O : 0.6 : Negligible : 4.2 : Compoflex or Ships lines : NO : Purge : No Blanket : NO : Stainless Steel , Zinc, Epoxy or polyurethane

: : : : : : : :

Combustible liquid D Vapor forms explosive mixture with air. 102(cc) 0.9~6.5% 795 Co2,dry chemical, foam, water fog. Use water to keep fire exposed containers cool.

: : : : : :

1,1,1 1.2 50/skin 50/skin Vapor and liquid irritation. Irritation of nose and throat; drowsiness

Short Exposure Tolerance : Occasional short exposure to concentration of 400 ppm probable would not be harmful. Exposure Procedure Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or irritation.

Reactivity Stability: Stable. it can react with oxidizing materials. Compatibility: Material : attacks rubber. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. avoid contact with liquid. secure ignition sources. small spills may be washed away with water. Operational Problems/Hazards Highly toxic by inhalation, Moderate fire risk Keep away from adjacent heat. Personnel Protection Chemical suit, gloves and goggles Breathing apparatus available, Restrict personnel on deck. Vapor return system : NO Tank cleaning : Cold salt water pre-wash, minimum 1 hour to clear residues Hot salt water wash, 5 ft half hour drops ( Check LEL) Steam tank and lines Ventilate Educt and mop ADJ./HEAT : MSK -Japan went along with heat to 130F when it was need. Handling: No problem cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes.

Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames vapors may travel to a source of ignition and flash back container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. . FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Move container from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; Stop leak if you can do it without risk water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

CYCLOHEPTANE
Synonyms IMO No IMO TYPE Formula : : : : Heptamethylene, Suberane. 2241 N/A C7 H14

ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

: : : :

N/A Saturated Hydrocarbon Colorless liquid Pungent odor. 0.809 @ C

: /C. : Ambient. : Ambient. : Ambient : : Dangerous , Reaction with Nitric Acid. : : : : Bondstrand, compoflex or ships Lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel, Zinc, Epoxy or polyurethane.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A Flash point : Below 38C Draeger Tube No. : Boiling Point : 117 C Explosive Range : Freeze Point : -12 C Autoignition Point : Operational Problems/Hazardous Very flammable Narcotic Stow away from adjacent heat - Maximum 40 C. Personnel Protection; Boiler suit , gloves, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : Possible Discharge slops at sea.

Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Nil

Drying oil : NO

Cold salt water pre-wash, minimum 1.5 hour to disperse residues. Hot salt water wash, 5 ft half hour drops ( check gas level) Steam tank and lines Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/ Cleaning code 2.

Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.
Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames vapors may travel to a source of ignition and flash back. Vapor explosion hazard indoors, outdoors, or in sewers. Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus and structural firefighting protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, or rail car or tank truck is involved in fire. Fire Small fire Dry chemical , Co2, water spray or regular foam. Large Fires : Water spray, fog or regular foam. Move container from sire area if you can do it without risk. Apply cooling water to sides of containers that are explored to flames until well after fire out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Spill or Leak Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Leak Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Large Spill Dike far ahead of liquid spill for later disposal. First Aids Move victims to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

CYCLOHEXANE
Synonyms Benzene, hexahydride; benzene, hexahydro, Hexahydrobenzene; hexamethylene, Hexanaphthene} UN. No : 1145 CHris Code : CHX 2 2 4 2 Formula : CH (CH ) CH Appearance-Odor : Colorless mobile liquid, sweetish odor when highly pure, pungent odor otherwise. Boiling Point : 81C/ 177 F Freezing Point : 7C/ 44F Specific Gravity : 0.78

Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0)

: : : : : : : : :

Saturated hydrocarbon ** C C* 3.3 D,O 4.5 Insoluble 2.9

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : When exposed to heat or flame it can react with oxidizing materials. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : -4 Flammable Limits : 1.3~ 8.4% Auto igniting Temp.(F) : 500 Extinguishing Agents : Foam, carbon dioxide or dry chemical. Special fire Procedures : In unconfined fires, solid hose steams tend to scatter the liquid and spread the fire. Use water spray or high pressure fog to cool a bring surface and exclude air to control or extinguish fire. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 300 PEL/TWA(ppm) : 300 TLV/TWA(ppm) : 300 General : Undesirable effects may occur from the inhalation of excessive concentrations of cyclohexane vapor, prolonged or repeated skin contact with liquid, and from liquid contamination of eyes. Symptoms: Dizziness, nausea, vomiting, unconsciousness. Short Exposure Tolerance: No chronic effects have been observed to occur in workers exposed to vapor, concentrations in the range of 600~700 ppm. Exposure Procedure : If cyclohexane is splashed into the eyes it should be flushed out immediately with copious amount of water. For over-exposure by inhalation to high vapor concentrations, remove patient to fresh air, Administer oxygen therapy or artificial respiration if necessary. Reactivity Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. secure ignition sources. Operational Problems/ Hazards

Highly flammable Causes nausea if vapor inhaled, and liquid and vapors cause irritation Personnel Protection Boiler suit , gloves and goggles breathing apparatus on standby. Tank cleaning Gas free or inerted tank or cold SW flush to remove residues then ventilate. Hot sea water wash, 5 ft half hour drops ( CHECK LEL) Ventilate to gas free Thoroughly steam and lines Ventilate Educt and mop M.S : Only an excellent tank , Tank will pass inspection for loading Avoid . Good cargo - small problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE.

If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

CYCLOHEXANOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : : : : cyclohexyl alcohol, hexahydrophenol hydroxyxlohexane. CHN 2 2 CH (CH )CHOH Colorless to pale yellow oily liquid camphor-like odor. 161c/ 322 F 24c / 27F 0.94 Alcohol 1.0 C 0.1 D,O 0.2 Slight 3.5 Portable lines via dropline NO Purge : NO Blanket : Yes Any Coating, but polyurethane and Epoxy are restricted.

Check coating lists. Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Moderate fire hazard. when exposed to heat or flame it can react with oxidizing materials Flash Point (F) : 154(cc) Flammable Limits : Unavailable Auto igniting Temp.(F) : 572 Extinguishing Agents : Alcohol foam, carbon dioxide, dry chemical. Special fire Procedures : Cool exposed tanks with water. Wear self-contained breathing apparatus. Health Hazard Data Health hazard Rating : 1,2,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 50/skin TLV/TWA(ppm) : 50/skin General : Vapor and liquid irritation. systematic effects produced. Symptoms : Vapor-irritating of mucous membranes, headache. Liquid- ulceration, thicking of skin. Short Exposure Tolerance: 3~5 min. exposure to 100 ppm was objectionable producing nose ,eye, and throat irritation. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. 20 to 30 min. for eye contact. Get medical attention. Reactivity Data Stability: Stable Compatibility: Material : Usual materials of construction are suitable. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all-purpose canister mask available. avoid contact with liquid. Operational Problems/ Hazards Highly flammable Product may have up to 20% water content to lower freezing point. Required heat may vary with shipper. Liquid on skin may cause ulceration and vapor causes irritation Keep away from adjacent heat. Shipper may required Nitrogen blanket for safety and quality control reasons. Personnel Protection Protective clothing, gloves, goggles, Breathing apparatus on standby. Tank cleaning Cold Salt water wash for minimum 1 hour, then Hot salt water wash, 5 ft half hour drops Ventilate to gas free Steam tank and line Ventilate, Educt and Mop dry.

Product will pick up impurities very easily. Tank must be grease free and dry. Melt Point- Specs., shown here is grade we carried with no problems Other (Purer) grade may need heat. Check melting point and if heat would be necessary. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

CYCLOHEXANONE
Synonyms : Cycloheyl ketone, ketone,ketohexamethylene pimelic ketone UN. No : 1915 CHris Code : OCH Formula : CH2(CH2)4CO Appearance-Odor : Water white to pale yellow liquid odor reminiscent of peppermint and acetone. Boiling Point : 156C/ 313F Freezing Point : -31C/ -24F Specific Gravity : 0.95 Chemical Family : Ketone Vapor Pressure(20C) :2 Pollution Category USEPA :D IMO :D Reid Vapor Pressure(psia) : 0.8 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.20 Solubility in water : Slight Vapor Density(air= 1.0) : 3.4 Handling : Portable lines via droplines Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank Coating : Stainless Steel or Zinc Product will attack Polyurethane and Epoxy coatings. Fire & Explosion Hazard Data Grade- D Electrical Group General Flash Point (F)

: : : :

Combustible liquid. D Moderate fire hazard, when exposed to heat or flame. 129

Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : :

1.1~8.1% 788 Alcohol foam, dry chemical, co2 Wear full protective, self contained breathing apparatus.

Health Hazard Data Health hazard Rating : 3,2,1 Odor Threshold(ppm) : 0.12 PEL/TWA(ppm) : 25/skin TLV/TWA(ppm) : 25/skin General : Vapor inhalation irritating to mucous membranes. Symptoms : Eye, nose, and throat irritation; narcosis, salivator; depression of body temp. respiratory rates, heart rates. Short Exposure Tolerance: 50 ppm for 3~5 min. was uncomfortably irritating, particularly to the throat. definite eye, nose and throat irritation was reported at 75 ppm. Exposure Procedure : Vapor-remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. will attack most paints. Cargo : Group 18 of compatibility chart. Spill or Leak Procedure If possible, wear rubber gloves, face shield, and protective clothing. secure ignition sources. Have all purpose canister mask available. Keep unprotected personnel upwind of contaminated area. flush spill with water. Operational Problems/ Hazards Highly flammable Liquid and vapor will cause irritation and possible damage to eyes. Personnel Protection Boiler suits, Goggles and gloves Vapour return system : NO Tank Cleaning Cold salt water wash for minimum 1 hour, then warm salt water 5 ft. half hour drops. Ventilate to gas free Steam tank and line Educt and mop Tank must be grease free. ADJACENT: Try to avoid any heat adjacent to this particular Ketone - it is shippers wish. MS: There is nothing wrong with good M.S tanks. Handling - Product is toxic and skin irritant. Use gloves and face mask- when handling.

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is

difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

CYCLOHEXYLAMINE
Synonyms : Amiocyclohexane,oychlohexanamine. Hexahydroaniline. UN. No : 2357 CHris Code : CHA 2 5 2 Formula : (CH ) CHNH Appearance-Odor : Colorless liquid, strong ammonia odor Boiling Point : 135C/ 274F Freezing Point : 18C/ 64 F Specific Gravity : 0.865 Chemical Family : Aliphatic amine Vapor Pressure(20C) : 0.177 Pollution Category USEPA : IMO :C Reid Vapor Pressure(psia) :+ Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.619 Solubility in water : Soluble Vapor Density(air = 1.0) : 3.42 Handling : Restrictions on zinc. NOT Compatible with Epoxy or Polyurethane, compoflex or ships lines. Inhibitor : NO Nitrogen : Purge : Possible Blanket : YES Tank Coating : Zinc with restrictions, Epoxy and polyurethane NOT Recommended. Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General: Dangerous when exposed to heat or fire, gives of toxic, fumes. flashback along vapor trail may occur. vapor may explode if ignited in an enclosed space. Flash Point (F) : 90 Flammable Limits : Unavailable Auto igniting Temp.(F) : 560 Extinguishing Agents : Foam, CO2,dry chemical Special fire Procedures : Wear goggles and self contained breathing apparatus. cool exposed tanks with water. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm)

: 3,4,2 : Unavailable : 10

TLV/TWA(ppm) : 10 General : Strongly caustic. Symptoms: Inhalation of vapors, and skin and eyes contact with liquid will cause severe burns. Short Exposure Tolerance: Unavailable. acute exposure causes nausea, anxiety, apprehension, slurred speech, papillary dilation. Exposure Procedure : Ingestion- do not induce vomiting. Eyes- flush with water for at least 15 min. Get medical attention immediately. Skin- remove contaminated clothing and flush skin with large amounts of waters. Reactivity Stability: Stable. Compatibility: Material : Corrosive to copper and its alloys. Cargo : Group 7 of compatibility chart.

Spill or Leak Procedure Avoid contact with liquid. Keep people away. Wear full protective clothing, self contained breathing apparatus and rubber over clothing. Try to contain. for large spills disperse and flush. Secure ignition sources. Operational Problems/ Hazards Flammable, dangerous fire risk. Highly toxic by ingestion, inhalation and skin absorption. Keep away from adjacent heat. Personnel Protection Chemical suit, gloves and goggles breathing apparatus on standby. Vapor return system : NO Tank Cleaning : Cold salt water pre-wash, minimum 1.5 hours to clear residues Hot salt water wash minimum 3 hours Ventilate Thoroughly steam tank and lines Ventilate, Educt and mop M.Steel - If carried in MS tank discoloration can be expected. Nitrogen blanket recommended. Strong organic base with 0.01% water pH of solution 10.5 Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

1,1-DICHLOROETHANE
Synonyms Asymmetrical dichloroethane; Chlorinated hydrochloric ether; Ethane,1,1-dichloro; ethylidene chloride; ethylidene dichloride, 1,1-ethylidene chloride. : 2362 : DCH 2 4 2 : C H CI : Colorless oily liquid, Chloroform : 57C/ 135 F : -97C/ -143 F : 1.18 : Halogenated compound : 182 :C :B : 7.35 :O : 9.9 : Negligible : 3.41 : Ships lines to deck/center tanks, or portable lines to droplines : NO : Purge : NO Blanket : Possible : Stainless steel, Zinc, polyurethane and Epoxy with restrictions.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

Fire & Explosion Hazard Data Grade- C : Flammable liquid Electrical Group :D General : When heated, toxic and highly flammable vapors are given off. Flash Point (F) : 17 Flammable Limits : 6~ 16 % Auto igniting Temp.(F) : 856 Extinguishing Agents : Dry chemical, foam, CO2 Special fire Procedures : Water may ineffective on fire. keep exposed tanks cool with water spray. provide fire fighters with protective clothing and self contained breathing apparatus. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Liquid causes slight irritation.

: : : : : :

1,1,2 Unavailable 100 200 Vapor irritating. liquid slightly irritating. Vapor causes eye irritation, dizziness, intoxication.

Short Exposure Tolerance : 4000 ppm in 30 min. Exposure Procedure : Remove victim to fresh air, if breathing stops, apply artificial respiration Skin or eye contact- flush areas immediately with water for 15 min. Reactivity Stability: Generally stable, but decomposes when heated forming toxic and flammable vapors.

Incompatible with strong oxidizers and caustics. Compatibility: Material : Usual materials of construction are suitable. Spill or Leak Procedure Wear protective clothing. face shield, goggles, respiratory protection. Secure ignition sources Water spray may be used to spills away. remarks: This compound is a teratogen;1,2-dichloroethane is a suspected carcinogen. Operational Problems/ Hazards Product is flammable Liquid and vapor will cause irritation and slight burns Nitrogen blanket and/or vent line desiccator may be required. Product becomes corrosive if in contact with moisture Keep away from adjacent heat, Clear lines with Nitrogen. Personnel Protection Chemical protective clothing Breathing apparatus on standby Tank Cleaning Cold sea water pre-wash to remove residues Ventilate to gas free ( or inert ) Hot sea water wash minimum 3 hours ( Check LEL) Ventilate to gas and odor free, Fresh water rinse Educt and mop, Tank must be dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard.

HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

1,3-DICHLOROPROPENE (DD Soil Fumigant)

Synonyms Alpha chloroalllyl chloride; gamma chloroallyl chloride, Dichloropropene,1,3-dichloropylene,alpha gamma dichloropylene, 1-propene, 1,3-dichloro, Telone : 2047 : DPU 2 : CICH=CHCH CI : White or yellow liquid, sweet penetrating odor. : 104C/ 219 F

UN. No CHris Code Formula Appearance-Odor Boiling Point

Freezing Point : -60C/ -76 F Specific Gravity : 1.23 Chemical Family : Substituted allyls Vapor Pressure(20C) : 103 Pollution Category USEPA :B IMO :B Reid Vapor Pressure(psia) : 4.0 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 5.5 Solubility in water : 0.1 % Vapor Density(air = 1.0) : 3.84 Handling : Center tank ships lines only. Center tank Stainless steel portable lines only. Flexibles and Bondstrand NOT suitable. Inhibitor : NO Nitrogen : Purge : Possible Blanket : Possible Tank Coating : Stainless Steel or Zinc Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General : Combustible produces toxic vapors of hydrogen chloride, phosgene, and carbon monoxide fire may cause violent rupture of tanks. Flash Point (F) : 95 Flammable Limits : 5.3 ~ 14,5% Auto igniting Temp.(F) : Unavailable Extinguishing Agents : Co2, dry chemical, foam, water fog. Special fire Procedures : fire parties must wear full respiratory protection and, where danger of skin contact exists, full protection as well. Health Hazard Data Health hazard Rating : 2,2,3 Odor Threshold(ppm) : 1~3 PEL/TWA(ppm) : 1/skin TLV/TWA(ppm) : 1/skin General : Suspected carcinogen. liquid is severely irritating to eyes. Vapor is a severe irritant. Symptoms: Blisters and burns when in contact with skin. breathing the vapors causes irritation to nose and eyes. Short Exposure Tolerance: Unavailable. However, it should be noted that the commercial product is a mixture of isomers. The physical properties will vary somewhat depending upon the proportion of each isomer present. The mixture should be handled in the same manner as a class B poison. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : will cause corrosion of steel if wet or at elevated temp. also, attacks aluminum and rubber. Cargo : Group 15 of compatibility chart.

Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, protective clothing, avoid contact with liquid. secure ignition sources. Operational Problems/Hazards Product is a mixture and there is insufficient information available Mixture with water will increase corrosive Properties Liquid in contact with eyes will cause damage Contact with liquid and vapor may be harmful Shipper will probably require desiccator fitted to vent lines. Personnel Protection Total protection suit with breathing apparatus Restrict personnel on deck and secure accommodation. Tank Cleaning Warm salt water wash for minimum of 3 hours to ensure pump lines are thoroughly flushed. Ventilate to odor and gas free. Thoroughly steam tank and lines Allow to cool and ventilate Educt and mop. Tank must be absolutely dry. USCG : Product is to be referred to as : Dichloropane Mixed Documents to show same. IMO : Vessel must have L.O.C certificate reading :Dicloropropene Zinc - When product analyzed it contained 500 PPM of water , no go Zinc. If Dry (150ppm) Zinc is O.K. Handling - Use protective mask and closing when handling this poisonous cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE.

If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

iso-DECALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor : : : : : : : : : : : : : : : : : : : isodecaldehyde, mixed isomers, trimethylheptanols ++ IDA 9 19 C H CHO,mixture of isomers Colorless liquid with a pleasant fruity odor. 197C/ 387F -80C/ -112 F 0.83 Aldehyde 0.22 @C 0.03 D,O 0.06 Insoluble 5.38 Portable lines to droplines or ships lines to center deck tanks, NO

Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: Purge : NO Blanket : Possible : Stainless steel Possibly Zinc, but restricted.

: : : : : : : :

Combustible liquid C This materials is more of a health hazard than a fire hazard. 185 Unavailable 375 Carbon dioxide, foam and dry chemical. Cool container surfaces with water.

Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapor irritating to mucous membranes. Symptoms : Coughing and sneezing, burning and tearing of eyes, salivation. signs of irritation of the mucous membranes. short Exposure Tolerance: Unavailable. Exposure Procedure : Strong concentration on the skin will produce burns. Obtain medical treatment. weaker solution may cause discoloration, roughening and hardening. spills on skin should be washed immediately with soap and water. Reactivity Stability: Stable. Compatibility: Material: compatible with aluminum, steel, stainless steel, not compatible with galvanized iron. Cargo : Group 19 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self contained apparatus, protective clothing. avoid contact with liquid. cover spill with sodium bissulfite(NaHSO3). Add small amount of water and mix. scoop up. wash site with soap solution. Operational Problems/Hazards Product is flammable Vent line desiccator may be required. Liquid will cause burns Vapor causes irritations at quite low concentrations. Personnel Protection Chemical protective clothing , goggles , gloves breathing apparatus on standby. Vapor return System : Possible Tank Cleaning Cold sea water pre-wash Hot sea water wash, 5 ft half hour drops ( check LEL) Ventilate to gas and odor free Steam tank and lines Ventilate, Educt and mop. Cleaning code 2.

Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

DECALIN
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : Decahydronaphthalene. 1147 TBA 10 18 C H 57B Hydrogenated Hydrocarbon Clear Colourless liquid with sharp menthol like odor 0.87 to 0.89 @ 20 C /C. Ambient. Ambient. Ambient 32 May React with oxides and acids. Portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked)

: Purge NO Blanket : Possible : Any coating but some linings subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : N/A Flash point : 57 C. Draeger Tube No. :Boiling Point : 188 C Explosive Range : 4.9 % to 6.7 % Freeze Point : -35 C Autoignition Point : 250 C

Operational Problems/Hazardous Flammable liquid. Effects of liquid and vapor largely unknown Explosive range is for product at 212C. Personnel Protection; Chemical protective clothing . Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : Possible Discharge on passage as per regulations Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Drying oil : NO

Solubility in water : Nil Warm sea water wash, half-hour drops , Ventilate to gas and odor free. Steam tank and lines Ventilate Educt and mop B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.
Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames vapors may travel to a source of ignition and flash back. Vapor explosion hazard indoors, outdoors, or in sewers. Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure selfcontained breathing apparatus and structural firefighting protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, or rail car or tank truck is involved in fire. Fire Small fire Dry chemical , Co2, water spray or regular foam. Large Fires : Water spray, fog or regular foam. Move container from sire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Spill or Leak Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Leak Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Large Spill Dike far ahead of liquid spill for later disposal. First Aids

Move victims to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DECANE
Synonyms : Decyl Hydride. IMO No : 2247 IMO TYPE : TBA Formula : CH3 (CH2)8 CH3 ICS Guide Page No. : Family : Saturated Hydrocarbon Appearance and character : Colorless liquid with mild sweet odor. Specific Gravity : 0.7298 @C Heating Range (Subject to Chart.Reg.) Correction factor : /C. Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 31 Reactivity : May react with oxides and acids should be checked against other products. Handling Inhibitor Nitrogen (Subject to chaterers Reg.) Tank Coating recommended : Portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless Steel, Zinc, Epoxy .

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A Flash point : 44 C Draeger Tube No. :Boiling Point : 174 C Explosive Range : Freeze Point : -30 C Autoignition Point : 200 C Operational Problems/Hazardous Product is flammable and liquid and vapor cause irritation. Vapor is narcotic and high concentrations. Personnel Protection; Chemical protective clothing , goggles gloves.

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Nil Drying oil : NO

Warm sea water wash for minimum 2.5 hours Ventilate to gas and odor free Fresh water rinse Educt and mop B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/ Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes Wash water temperature Code (D)Ambient water followed by warm water.
Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames vapors may travel to a source of ignition and flash back. Vapor explosion hazard indoors, outdoors, or in sewers. Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. Emergency Action Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure selfcontained breathing apparatus and structural firefighting protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, or rail car or tank truck is involved in fire. Fire Small fire Dry chemical , Co2, water spray or regular foam. Large Fires : Water spray, fog or regular foam. Move container from sire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Spill or Leak Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Leak Take up with sand or other noncombustible absorbent materials and place into containers for later disposal. Large Spill Dike far ahead of liquid spill for later disposal. First Aids Move victims to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

n-DECYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating Draeger Tube No. : : : : : : : : : : : : : : : : : : : : : : Alcohol C-10,capric alcohol,1-decanol nonylcarbinol ++ DAN/ DAX(all isomers) 3 2 8 2 CH (CH ) CH OH Colorless, water white liquid, sour odor. 233C/ 451 F 7C/ 45 F 0.83 Alcohol V.Low B V.Low D,O " Insoluble 5.3 Portable lines to droplines NO Purge : NO Blanket : NO ANY Coating Ch297 Alcohol 100/a

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Moderate hazard, when exposed to heat or flame, can react with oxidizing materials. Flash Point (F) : 180 Flammable Limits : Unavailable Auto igniting Temp.(F) : 550 Extinguishing Agents : Alcohol foam, carbon dioxide, dry chemical, water spray. Special fire Procedures : Not pertinent Health Hazard Data Health hazard Rating : 0,0,0 Odor Threshold(ppm) : Unavailable. PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Practically non-toxic. Handle as a detergent. Main hazard is liquid contact with eyes.

Symptoms: Skin and eye contact- considerable pain and irritation to eyes; skin irritation. Short Exposure Tolerance: Unavailable. Exposure Procedure : Eye contact- flood gently with clean water for at least 15 min. Skin contact- remove contaminated clothing and wash affected areas with plenty of water. Reactivity Stability: Stable. Compatibility: Material : Mild steel is suitable for tanks, pipes, valves. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. remarks: ++ Unassigned Operational Problems/ Hazards Due to high point, loading carriage and discharge temperatures will vary with different shippers, but in any event temperature must be maintained above 7 C. If climatic conditions allow, then product will be carried ambient product is generally non-hazardous, but eyes must be protected from liquid. Personnel Protection Boiler suit, gloves and goggles Tank Cleaning Warm salt water wash, 5 ft half-hour drops, using chemical injection at second drop and penulate drop. Ventilate to odor and gas free. Fresh water rinse Educt and mop. M.Steel - A good MS tank can be used for synthetic. Natural need coated/SS tank. Good cargo - No headache.

iso-DECYL ACRYLATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) : : : : : : : : : : : : : : : : : Acrylic acid, isodecyl ester ,isodecyl acrylate, isodecyl propenoate. ++ IAI 2 10 21 CH =CHCOOC H Water white liquid; pungent odor 121C/250 F -100c/ -148 F 0.89 Acrylate <0.01 A Low O O Negligible 7.3

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : May polymerize to gummy solid. reaction is not violent. Flash Point (F) : May polymerize to gummy solid. Reaction is not violent. Flammable Limits : Unavailable Auto igniting Temp.(F) : " Extinguishing Agents : Foam, dry chemical.co2 Special fire Procedures : Water might be ineffective. Cool exposed tanks with water. Handling : Portable lines to droplines Ships lines to center tank. NOTE: Bondstrand Not suitable for this product. Inhibitor : YES Nitrogen : Purge : Possible Blanket : Possible Tank Coating : Stainless Steel Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid causes swelling and redness after 10 min. Symptoms : Skin contact: Swelling and redness. Short Exposure Tolerance: 8 hour exposure of rats to concentrated vapors approaching saturation in air was not fatal. Inhalation causes mild irritation of nose and throat; vapor mildly irritates eyes. Exposure Procedure : Vapor- remove victim to resh air. Give artificial respiration if breathing stops,

skin or eyes contact- remove contaminated clothing and gently flush affected areas with after for 15 min. Get medical advice or attention. Reactivity Stability: Stable if inhibited. Compatibility: Material: will swell and soften certain rubbers and soften and remove certain paints Cargo : Group 14 of compatibility chart. Spill or Leak Procedure If possible wear rubber gloves, face shield, and protective clothing. have all purpose canister mask available. Secure ignition sources. flush away with water. Do not flush into confined space (such as a sewer) because of the danger of explosion. remarks:++ Unassigned Operational Problems/ Hazards Product is flammable Liquid and vapor cause irritation and swelling Atmosphere will be untenable before dangerous concentrations reached. Product must be kept dry and away from adjacent heat Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection Total protection suit , Secure accommodation and Recirculation air during all operations Use Closed ullaging system Tank Cleaning Cold sea water pre-wash, minimum 1 hour Hot sea water wash, 5 ft half hour drops Ventilate to odor and gas free. Thoroughly steam tanks and line ( Odor may be persistent) Educt and mop Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided.

DIACETONE ALCOHOL
Synonyms Diacetone; 4-hydroxy-4-methyl-2-pentone, 4-hydroxy-4methyl

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No

Pentanone-2; 2-methyl-2-petanol-4-one : 1148 : DAA 3 2 3 2 : CH COCH C(CH ) OH : Colorless to light yellow liquid faint, pleasant odor. : 164C/ 328 F : -50C/ -58 F : 0.94 : Ketone/alcohol : 1.0 : :D : 0.07 :D : 0.1 : Complete : 4.0 : Portable lines via droplines : NO : Purge : NO Blanket : Possible : Any Coating, but restrictions on Polyurethane and Epoxy. : CH297 Alcohol 100/a

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 126(cc) Flammable Limits : 1.8 ~ 6.9% Auto igniting Temp.(F) : 1118 Extinguishing Agents : Co2,dry chemical, water fog, alcohol foam. Special fire Procedures : fire parties should be provided with respiratory protection. Health Hazard Data Health hazard Rating : 1,2,0 Odor Threshold(ppm) : 25 PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 50 General : Irritating to eyes and mucous membranes. Narcotic in high concentration, experimentally has caused anemia and damage to kidneys and liver. Symptoms: Burning of eyes and nasal passages, dizziness, drowsiness. Short Exposure Tolerance: 150 ppm for 30 min. Exposure Procedure : Vapors- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently affected areas with water for 15 min. Get medical advice or attention. Reactivity Stability: Relatively stable. can react with oxidizing materials. Compatibility: Material : dissolves or softens many plastics.

Cargo :

Group 20 of compatibility chart.

Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all-purpose canister mask available. Operational Problems/Hazards Highly flammable and vapor may be harmful; however, the irritant properties will affect personnel before inhalation becomes harmful . Personnel protection Boiler suit, gloves and goggles, Breathing apparatus available on standby Tank cleaning Cold salt water wash for minimum of 2 hours Ventilate to gas and odor free Thoroughly steam tank and line Ventilate Educt and mop NOTE : Check coating guide lists prior to cleaning for any special requirements. Remarks; Flash point - The acetone content vary in these 3 grades- and so does the flash - check grade. Handling - It is a strong solvent, needing good clean/dry tanks. No big problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases.

Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

o-DICHLOROBENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Benzene,1,2-dichloro; 1,2-dichrolobenzene o-dichlorobenzol, Dowtherm E, Orthodichlorobenzene : 1591 : DBO : C6H4CI2 : Colorless liquid, Pleasant aromatic : 181C/ 357 F : -18C/ -1 F : 1.30 : Halogenated compound :1 :B :B

Reid Vapor Pressure(psia) : 0.06 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.1 Solubility in water : Negligible Vapor Density(air = 1.0) : 5.07 Handling : Portable lines via droplines NOTE: Compoflex flexible should be used only if no alternative and cleaned a soon as possible. Inhibitor : NO Nitrogen : Purge : Possible Blanket : YES Tank Coating : Zinc preferred. Some epoxy linings are suitable but severely restricted and guide lists should be consulted . Draeger Tube No : CH244 Trichloroethylene 10/a Fire & Explosion Hazard Data Grade- E : Combustible liquid Electrical Group :D General : Dangerous. when heated to decomposition, emits highly toxic chloride fumes. Flash Point (F) : 151 Flammable Limits : 2~9 % Auto igniting Temp.(F) : 1198 Extinguishing Agents : Water spray, dry chemical, Co2, foam. Special fire Procedures : Wear full protective clothing and self confined breathing apparatus. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms

: : : : : :

2,1,1 4 50 50/skin Vapor inhalation causes moderate local irritation of nose and airway. Drowsiness, unsteadiness, eye irritation, difficulty in breathing.

Short Exposure Tolerance: Painful to some at 60~100 ppm for more than a few min. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Stability: Stable. Compatibility: Material: Most rubbers are not compatible. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure If possible, wear butyl rubber gloves, self breathing apparatus, protective clothing. if possible absorb or mix with vermiculite,sodium bicarbonate or sand. This may be package in cardboard cartons and burned in an open pit. wash site thoroughly with strong soap solution. Operational Problems/ Hazards Product is mixed isomers- that quoted is Ortho. The Meta and Para isomers differ only slightly. Personnel should be warned that the odor of this product can be tolerated for longer periods,

the longer personnel are exposed, causing damage before awareness of the danger. Liquid causes only slight irritation but vapor are toxic System of closed ullaging should be used. Tends to become corrosive when in contact with water nitrogen blanket and vent line desiccator may be required. Personnel Protection Protective clothing , gloves and breathing apparatus Ensure accommodation secured during cleaning, loading, gas freeing operations. Tank Cleaning Cold salt water flush of tank bottom and pump and lines. Warm salt water wash, 5 ft half hour drops Ventilate to gas and odor free Thoroughly steam tank and line Ventilate Educt and mop. Tank must be absolutely dry and grease free. Epoxy- Coating is Only OK. non-heated grades up to 30 degree avoid. Phenoline - Carrying heated grades (140F) - No problem not stow product as first cargo in newly coated tanks . When cargo cured after 3/6 month service coating 100% OK No a difficult cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program. HEALTH HAZARDS Inhalation of vapor or dust is extremely irritating. May cause burning of eyes flow of waters. May cause coughing, difficult breathing and nausea. Brief exposure effects last any a minutes. Exposure in an enclosed area may be very harmful. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or regular foam. Large Fires: Water spray ,fog or regular foam. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Small spills:

Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature.

1-2 DICHLOROETHYLENE
Synonyms : Acethylene Dichloride IMO No : TBA IMO TYPE : N/A 1 1 Formula : C HC CHC ICS Guide Page No. : Family : TBA Appearance and character : Colorless liquid with mild pleasant odor. Specific Gravity : 1.257 @ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : TBA /C. Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : Reactivity : May react with acids, Alkalis and water .Check other cargo. Handling : Ships lines to center tanks Exceptionally portable Stainless Steel lines to droplines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg.) Tank Coating recommended : Purge NO Blanket : Possible : Stainless steel, Zinc or Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : N/A Flash point : 5C Draeger Tube No. : Boiling Point : 47 to 49 C Explosive Range : Freeze Point : -80 C Autoignition Point : N/A C Operational Problems/Hazardous Product is flammable and considered dangerous fire hazard. Liquid and vapor are irritant and narcotic at high concentrations . Can be absorbed via skin. As product used as base solvent, tank cleanliness must be high standard. Vent line desiccator may be required. Clear lines with Nitrogen Product degrades in contact with moisture , light or excessive heat. Personnel Protection; Chemical protective clothing, goggles gloves, breathing apparatus on standby. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Slight Cold sea water pre-wash to disperse residues. Gas free wash ( minimum 3 hour) Ventilate Drying oil : NO

Fresh water rinse Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust Tank and line must be dry Note : Product exists in cis and trans forms. SG differs slightly.

2,2-DICHLOROETHYL ETHER
Synonyms Chlorex; chroloethyl ether, bis ether bis beta chloroethyl ether, DCEE,2,2-dichlorodiethyl ether,dichloroether, sym-dichloroethyl ether, dichloroethyl oxide, ethane,1,1-oxybis (2-chloro;1-1 oxybis(2-chloro;1-1'oxybis(2-chloroethane) : 1916 : DEE

UN. No CHris Code

Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

: : : : : : : : : : : : : : : : : :

CICH CH OCH CI Colorless liquid; chloroform like odor 178C/ 352 F -50C/ -58 F 1.22 Ether 1.2 A B + O 0.04 Negligible 4.9 Ships line to center tanks NO Purge : Possible Blanket : YES Stainless Steel or Zinc

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General : When heated to decomposition, it emits highly toxic fumes, it reacts with water or steam to evolve toxic or corrosive fumes. Flash Point (F) : 131(cc) Flammable Limits : Unavailable Auto igniting Temp.(F) : 696 Extinguishing Agents : Foam, Co2, dry chemical Special fire Procedures : Wear full protective clothing and respiratory protection. Health Hazard Data Health hazard Rating : 3,2,3 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 5/skin TLV/TWA(ppm) : 5/skin General : Vapor is irritant to mucous of eyes and nose. it affected kidneys and liver in varying degrees, and is a mild narcotic. Symptoms : Nausea, irritation of eyes and skin. Short Exposure Tolerance: 500~1000 ppm causes severe irritation of the eyes and nose after brief exposure. 100 ppm produces slight nausea and irritation. Exposure Procedure : Remove victim to fresh air. Skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable until heated to decomposition. Will react with water or steam, and can react vigorously with oxidizing materials. Compatibility: Materials : Unavailable.

Cargo : Group 41 of compatibility chart Spill or Leak Procedure Wear rubber gloves, large heavy face shield, self contained breathing apparatus. secure ignition sources. flush with large quantities of water. remarks: + unavailable. Operational Problems/ Hazards Product is flammable and both liquid and vapor are toxic, particularly via skin and inhalation of vapor. Product becomes corrosive in contact with water and nitrogen blanket/ purge and or vent line desiccator may be required. Keep away from excessive adjacent heat due to possible vapor release Clear lines with Nitrogen. Personnel Protection Total protection suit Secure accommodation and Recirculation air Restrict personnel on deck during all operations Use Closed Ullaging system. Tank Cleaning Cold sea water wash to remove residues Ventilate to gas free Warm sea water wash, minimum 2.5 hours Ventilate, Fresh water rinse Educt and mop. Tank must be dry and chloride/ Hydrocarbon free. S.S/Zinc - Product carried from Japan checked and found O.K. for these tank linings. S.S -tanks should be inspected for pittings before and after carriages. Handling- Use protective clothing and mask when working this hazardous cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available.

FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature delayed; keep victim under observation.

DICHLOROMETHANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Note : Compoflex hoses are not suitable for Inhibitor Nitrogen Tank Coating Draeger Tube No : Methylene bichloride, methylene chloride Methylene dichloride : 1593 : DCM : CH2CI2 : Colorless liquid a chloroform odor. : 40C/ 104 F : -97C/ -143 F : 1.34 : Halogenated hydrocarbons. : 350 : :D : 13.9 :O : 19.0 : 1.3% : 3.0 : Portable lines to droplines, or ships lines to deck tanks. prolonged use and should be cleaned as soon as possible. : : Purge : No Blanket : Possible : Stainless steel or Zinc : 672469 Ethylene Chloride 100/a

Fire & Explosion Hazard Data Grade: Non-flammable Electrical Group :D General : No flash point by conventional methods, but forms flammable vapor-air mixture at 212 deg F higher. evolves phosgene, a poisonous gas, and hydrogen chloride gas when heated. Flash Point (F) : None. Flammable Limits : 12~19% Auto igniting Temp.(F) : 1033 Extinguishing Agents : Water, foam, dry chemical, CO2. Special fire Procedures : Wear self contained breathing apparatus. cool exposed tanks with water. Health Hazard Data Health hazard Rating : 2,1,2 Odor Threshold(ppm) : 214 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : 50 General : Suspected carcinogen. vapor causes anesthetic effects at high concentrations. Liquid causes skin and eye irritation. prolonged or repeated skin contact may causes defatting of the skin and may produce dermatitis from daily contact. Symptoms: Light headdress, mental confusion, nausea, vomiting, and headache. Short Exposure Tolerance: Not well established, possibly in the range 10000~20000 ppm by volume in air. However, in coordination, dizziness and slight nausea begin after a half hour exposure to approx. 1000 ppm. Exposure Procedure :

Give artificial respiration if breathing has stops, if the eyes are involved, flush and then irrigate with large amount of water for at least 15 min. if ingestion has occurred, obtain medical attention. Reactivity Data Stability: Stable. but contact with open flame causes decomposition. Compatibility: Material : corrosive to aluminum and magnesium, corrosive to steel when wet. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. Operational Problems/ Hazards Product is non-flammable but vapors may become flammable with air and other flammable mixtures. Odor threshold varies with individuals, as odor can be tolerated by adaptation Product becomes acidic in contact with water and nitrogen blanket and/or vent line desiccators may be required. Both liquid and vapor cause irritation and vapors can cause unconsciousness. Keep away from adjacent heat. Due low BP water spray on deck may be necessary. Personnel Protection Chemical protective clothing and breathing apparatus as required. USCG- Uses the Synonym; Dichloromethane Tank Cleaning Cold sea water flush of tank bottom, lines and pump Hot slat water wash minimum 2 hours Ventilate to gas and odor free Thoroughly steam tank and lines Ventilate Educt and mop. Note : Smell can be difficult to remove and prolonged steaming may be required. Ensure tank is steamed to reduce chlorides, and is dry and grease free. Test for chlorides and hydrocarbons if in doubt If particle a Methane spray may be beneficial. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program. HEALTH HAZARDS Vapors may cause dizziness or suffocation Exposure in on enclosed area may be very harmful. Contact may irritate burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials but none of them ignites readily. Most vapors heavier than air Air/vapor mixtures may explode when ignited. Container may explode in heat of fire.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co . Large Fires: Water spray ,fog or regular foam apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Small Liquid spills: Take up with sand, earth or other noncombustible absorbent Material Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; \ if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Use first aid treatment according to the nature of the injury

DICYCLOPENTADIENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Cyclopentadiene;1,3-cyclopentadiene 1,3-cyclopentadiene dimer, dicy,3a,4,7,7a, dicyclo-1,4-pentadiene, tetrahydro-4,7-methanoindence. : 2048 : DPT 10 12 :C H : Colorless liquid or molten liquid camphor-like odor. : 166C/ 331 F : 33C/ 91 F : 0.98 : Olefin : 1.5

Pollution Category USEPA : IMO :B Reid Vapor Pressure(psia) : 0.16 Applicable Bulk reg.46 Subchapter : D,O Vapor pressure 46C(psia) : 0.25 Solubility in water : Insoluble Vapor Density(air = 1.0) : 4.55 Handling : Portable lines to droplines or ships lines to deck/center tanks Lines and tank must be maintained dry and may required Nitrogen purge. Inhibitor : YES Nitrogen : Purge : Possible Blanket : YES Tank Coating : Stainless Steel or Zinc, Some Epoxy or Polyurethane linings are acceptable but restricted. Draeger Tube No : 67189 Chloroprene 5/a Fire & Explosion Hazard Data Grade- D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : :

Combustible C Keep away from heat, sparks and fire. 80~ 100 0.8 ~ 6.3 % Above 500 Foam, carbon dioxide, dry chemical, water spray. Water may be ineffective. Keep exposed tanks cool with water spray.

Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : less than 0.003 PEL/TWA(ppm) :5 TLV/TWA(ppm) :5 General : Liquid causes skin and eye irritation. avoid prolonged or repeated breathing of vapor. Possibility of thermal burns from hot liquid. Symptoms: Inhalation-dizziness, drowsiness, skin contact- dermatitis following prolonged contact. Short Exposure Tolerance: 1 ppm caused slight eye and throat irritation after 7 min. eye irritation resulted after 10 min. at 5.5 ppm. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material: Usual materials of construction are suitable. Cargo : Group 30 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all-purpose canister mask available. secure ignition sources. Operational Problems/ Hazards Product is flammable and both liquid and vapor cause irritation Prolonged exposure to liquid may cause dermatitis Product will polymerize in contact with heat above 40 C and may discolor and polymerize in contact with air.

Product temperature must be rigidly controlled. Nitrogen purge and blanket and vent line desiccator may be required. Chaterer may require the O2 content of the tank to be less than 2%. Clear lines with Nitrogen. Personnel Protection Total protection suit, Secure accommodation and re-circulate air. Restrict personnel on deck during all operations Use Closed ullaging system. Tank Cleaning Cold sea water wash to remove residues Ventilate to gas free Warm sea water , Minimum 2.5 hours, Ventilate Fresh water rinse, Educt and mop Tank must be dry and chloride/ Hydrocarbon free. These specs are from MSK Japan. It differs from chemical dictionary re melt point. MS- Avoid if possible - hard to deodorize after discharge. In lined Tanks - No problem. Cleaning- if spot cleaning is necessary ,Use same cleaner as for lube oil. Use Nitrogen Blanket always. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 18. These cargoes leave an odor that in very difficult to remove especially in zinc coated tanks Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIETHANOLAMINE
Synonyms Diethyloamine,2,2-dihydroxydiethylamine. di(2-hydroxyethyl)amine, bis(hydroxyethyl)amine, bis(2-hydroxyethyl)amine,2,2-iminobisethanol 2,2-Iminodiethanol. UN. No : ++ CHris Code : DEA 2 2 2 Formula : (HOCH CH ) NH Appearance-Odor : Thick, colorless liquid, ammonia Boiling Point : 268C/ 514 F Freezing Point : 28C/ 82 F Specific Gravity : 1.09 Chemical Family : Amine Vapor Pressure(20C) : <0.1 Pollution Category USEPA : IMO : III Reid Vapor Pressure(psia) : 0.97 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : V.Low Solubility in water : Complete Vapor Density(air = 1.0) : 3.65 Handling : Ships lines or portable lines to droplines Bondstrand lines are NOT suitable with this product. Inhibitor : NO

Nitrogen : Purge : Possible Blanket : Probable Tank Coating : Stainless Steel or Epoxy, although Epoxy linings subject to restrictions which check Zinc and polyurethane are Not suitable. Draeger Tube NO : CH318 Hydrazine 0.25/a Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Slight fire hazard when exposed to heat or flame. irritating vapor are generated when heated. Flash Point (F) : 280 Flammable Limits : 1.6%(calculated) ~9.8%(estimated) Auto igniting Temp.(F) : 1224 Extinguishing Agents : CO2,dry chemical, water fog, alcohol foam. Special fire Procedures : Water or foam may cause frothing. provide fire fighters with self contained breathing apparatus and protective clothing. Health Hazard Data Health hazard Rating : 2,2,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) :3 TLV/TWA(ppm) :3 General : Liquid is irritating to skin and highly corrosive to eyes. avoid inhalation of high vapor concentrations. Symptoms : Itching or burning at point of contact. Short Exposure Tolerance : Unavailable. Exposure Procedure : Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material: Avoid copper and its alloys. Cargo : Group 8 of compatibility chart. Spill or Leak Procedure Wear butyl rubber gloves, face shield, or all purpose canister respiratory, protective clothing, may cover with sodium bisulfate, spray with large excess of water and wash up. remarks:Since the pure material is solid at ambient temperatures, deethanolamine may be carried in aqueous solution or elevated temp. to keep it liquid. ++ Unassigned Operational Problems/ Hazards Product is generally water-white, but may be shipped as a pale yellow color. Consult locally to establish colour as product can become discolored and off-spec. under certain conditions. Avoid adjacent heat. A nitrogen blanket and/or vent line desiccator may be required. Due low pressure beware of vapour lying. Liquid can be harmful by absorption, and may burn in eyes Both liquid and vapors cause irritation. Product may be mixed with water to depress the freeze point Thus SG may vary. Personnel Protection

Protective clothing , goggles and gloves Breathing apparatus on standby Vapor return system : NO Tank Cleaning Warm sea water wash for minimum 2 hours Ventilate to odor and gas free Steaming tank and lines Ventilate Educt and mop NOTE: Amines absorb water very rapidly , Ensure sufficient opening in tank to prevent vacuum forming while washing. Zinc - Test show a Zinc pick-up of 5000 ppm -making coating unsuitable. Phenoline- Coating is most likely resistant - need test. Handling- This amine is giving us no trouble. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

DIETHYLAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density (air = 1.0) Handling Ships lines to deck center tanks Compoflex Inhibitor Nitrogen Tank Coating : DEN;N-ethylethanamine : 1154 : DEN 2 5 2 : (C H ) NH : Colorless liquid, ammonia odor : 56C/ 132 F : -50c/ -58 F : 0.71 : Amine : 20.4 :B :C : 0.7 :O : 1.0 : Complete : 2.5 : hoses may be used if necessary. : NO : Purge : NO Blanket : NO : Stainless Steel

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :C General : Extremely flammable. dangerous when exposed to heat or flame. vapors are heavier than air and may travel considerable distance to an ignition sources and flashback. Irritating vapors are generated when heated.

Flash Point (F) : -24 Flammable Limits : 1.8~10.1 % Auto igniting Temp.(F) : 594 Extinguishing Agents : CO2,dry chemical or alcohol foam. Special fire Procedures : Provide fire fighters with self contained breathing apparatus and protective clothing. Health Hazard Data Health hazard Rating : 3,2,2 Odor Threshold(ppm) : 0.14 PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Liquid very irritating on contact and is toxic by skin absorption. vapor causes severe irritation of nose and respiratory passages. Symptoms: Liquid cause eye injury and skin irritation. Short Exposure Tolerance: 100 ppm for 30 min. Exposure Procedure : In case of contact with eyes or skin, immediately flush with plenty of water for at least 15 min. for eyes get medical attention. Remove contaminated clothing and shoes at once. Reactivity Data Stability: Stable. Compatibility: Material: Steel and stainless steel are compatible. copper and its alloys should not be used. Cargo : Group 7 of compatibility chart. Spill or Leak Procedure Wear butyl rubber gloves, face shield or all purpose canister respirator, protective clothing secure ignition sources. cover with sodium bisulfate and clean up. flush spill with large quantities of water. Operational Problems/ Hazards Product is flammable and effect of liquid and vapor is harmful Ensure tank and lines are moisture free Blow with Nitrogen Amines absorbed water very rapidly . When cleaning ensure vacuum does not form in tank. Personnel Protection Protective clothing, gloves, and breathing apparatus Tank Cleaning Cold sea water wash, minimum 2 hours to clear residues, Hot sea water wash, 3 hours ( check LEL) Ventilate Thoroughly steam tank and line Ventilate Educt and mop Note : Alternatively inert or gas free tank prior to hot wash Zinc - Coating is OK at temperatures of 70F and lower cooling beneficial . Handling - At this writing shipper demand P.V valves set at 5 psig or cooled down in hot. Climate Cooling recommended Nitrogen Blanket needed . This cargo is hard to handle at high ambient temperature. Cleaning code 1.

Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

DIETHYLBENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) : : : : : : : : : : : : : : : : : Diethylbenzene(1,2-1,3-1,4) diethylbenzene, m or o- isomers 2049 DEB 6 4 2 5 2 C H (C H ) Colorless liquid, benzene like odor 182C/ 360 F -43C/ -45F 0.87 Aromatic hydrocarbon 1 C 0.05 D,O 0.08 Negligible 4.62

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 133 Flammable Limits : Unavailable Auto igniting Temp.(F) : 806 Extinguishing Agents : CO2, dry chemical, foam, water fog. Special fire Procedures : Fight in the same manner as any grade D petroleum product fire. Firefighter should wear respiratory protection. Handling : Little data available -action as for Benzene. Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank Coating : ANY Coating suitable Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance

: : : : : : :

1,1,1 Unavailable Unavailable " Vapor harmful Headache, dizziness, nausea. Unavailable

Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. the effects of inhalation may be delayed. Reactivity Data Stability: Stable. Compatibility: Material : rubber, on long immersion, will first swell, then soften. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. secure ignition sources. remarks: Usually shipped as a mixture of isomers; the ortho and para form will predominate. Operational Problems / Hazards As for Benzene Personnel Protection Chemical Protective clothing Breathing Apparatus Tank Cleaning Cold salt water pre-wash Ventilate to gas and odor free Hot salt water wash Educt and mop dry Tank must be dry and grease free. 64/66 : Ventilate tank for 24 hours after discharge coating may be soft. Handling - See no problems with this cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas

Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

DIETHYLENE GLYCOL
Synonyms DEG,diglycol,dihydroxydiethyl ether, 2,2-dihydroxythyl ether, bis(2-hydroxyethyl)ether,3-Oxa-1,5-pentanediol,2,2-oxybisethanol, 2,2-oxydiethanol. UN. No : ++ CHris Code : DEG 2 2 2 Formula : (CH CH OH) O Appearance-Odor : Colorless, syrup liquid, slight odor Boiling Point : 244C/ 472 F Freezing Point : -6C/ 21 F Specific Gravity : 1.12 Chemical Family : Glycol ethers Vapor Pressure(20C) : Very Low Pollution Category USEPA : IMO : III Reid Vapor Pressure(psia) : Very Low Applicable Bulk reg.46 Subchapter :D Vapor pressure 46C(psia) :" Solubility in water : Complete Vapor Density(air = 1.0) : 3.66 Handling : Portable lines to droplines or ships lines to deck /center tanks Ensure lines absolutely clean and dry. Inhibitor : NO Nitrogen : Purge : Possible Blanket : Probable Tank Coating : Any Coating , but some Zincs and Epoxy linings are restricted. Check coating guide. Fire & Explosion Hazard Data Grade- E : Combustible liquid Electrical Group :C General : Slight hazard, when exposed to heat or flame; can react with oxidizing materials. Flash Point (F) : 255 Flammable Limits : 1.6 ~ 10.8% Auto igniting Temp.(F) : 444 Extinguishing Agents : CO2,dry chemical, alcohol foam, water spray. Special fire Procedures: Water or foam may cause frothing. DO not direct water directly into fire. Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Under ordinary conditions of handling, not considered toxic. Symptoms : Skin which has come into contact with the liquid may burn or itch. Short Exposure Tolerance : Unavailable. Exposure Procedure : Eye or skin contact- flush affected area gently with water for 15 min. for eye contact, or if skin is blistered or peeled, get medical attention. Reactivity

Stability: Stable. Compatibility: Material: compatible with most materials of construction. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing, avoid contact with liquid. Operational Problems/ Hazards Product is practically non- hazardous Product highly susceptible to contamination, especially rust, chlorides and hydrocarbons, and easily put off specification. Several grades shipped, highest grade generally termed fibregrade Nitrogen blanket/purge and vent line desiccator may be required. Tank coatings must be in good condition and tank s and lines absolutely dry. Liquid and vapor will cause irritation. Personnel Protection Boiler suit and gloves and goggles. Tank Cleaning Hot sea water wash, 5 ft. half hour drops Ventilate Steam tank and lines Ventilate Educt and mop Thoroughly steaming tank and line to clear chlorides Tank may be chemically sprayed (when cool) to remove hydrocarbons an washed with distilled waters. Test for Chloride and Hydrocarbons M.S- It is next to impossible to get a perfect M.S tank past surveyor s - Avoid product discolor easily. Handling - Nitrogen Blanket is recommended especially for slack loaded tanks. Excellent cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

DIETHYLENE GLYCOL BUTYL ETHER

Synonyms Butyldiethylene glycol,2-(2-butoxyethoxy)ethanol, 2(2-butoxy ethoxy)ethanol, butyl carbitol,butyl diglycol,butyl dioxitol, Diglycol monobutyl ether,dowanol DB,ektasolve DB solvent.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : : : : : : : : : : : : : :

++ DME 4 9 2 2 2 2 C H OCH CH )CH CH OH Colorless liquid, Pleasant odor. 231C/ 448 F -68C/ -90 F 0.95 Glycol ether Very Low III " D " Complete 5.5 Portable lines to droplines or ships lines to deck / Center tanks. NO Purge : Possible Blanket : Probable Stainless Steel or Zinc

: : : : : : : :

Combustible liquid C Moderate fire hazard when exposed to heat or flame. 172 Unavailable 442 Confined area-co2,dry chemical, open area-polar solvent foam Water spray may cause frothing.

Health Hazard Data Health hazard Rating : 1,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Slight eye irritation. low toxicity. Symptoms: Liquid-slightly painful and irritating to eyes, repeated skin contact causes slight irritation. Vapor-eye irritation. Short Exposure Tolerance: Unavailable Exposure Procedure : Liquid- flush with water. Vapor inhalation- remove victim to fresh air. Reactivity Stability:

Stable.

Compatibility: Material: mild steel and stainless steel are suitable. Certain rubbers and plastics are unsuitable. Cargo : Group 40 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. Secure ignition sources. absorb on paper towel and vermiculite.

remarks: ++ Unassigned

Operational Problems/ Hazards Product has no significant hazards, although liquid and vapor may cause irritation. Product is highly susceptible to contamination, particularly from water, rust and excessive heat. Exposure to excessive adjacent heat may cause discoloration Product shipped by DOW chemicals will almost certainly require Nitrogen blanket and/or vent line desiccator Maximum adjacent heat tolerable 40 C. product will attack rubber. Personnel Protection Boiler suit, gloves , goggles Tank Cleaning Warm sea water wash, 5 ft. half -hour drops Ventilate to odor free Thoroughly steaming tank and line Ventilate Educt and mop Note : Check coating guide as some coating require drying by ventilation of the product before washing the tank. Tank and line must be dry and grease free Coating showing minimal breakdown. Handling - This is a good cargo with no problems. a good clean tank/ lines is all thats needed.

DIETHLENE GLYCOL ETHYL ETHER

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Carbitol solvent, dowanol DE,ektasolve DE solvent, Ethoxy diglycol,2(2-ethoxyethoxy)ethanol. : ++ : DGE 2 2 2 2 2 3 : HOCH CH OCH CH OC H : Colorless liquid, mild pleasant odor : 202C/ 396 F : -76C/ -105 F : 1.03 : Glycol ether

Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : : : : : :

Low III Low D 0.01 Complete 4.62 Portable lines to droplines or ships lines to deck/ center tanks. NO Purge : Possible Blanket : Probable Stainless Steel or Zinc

: : : : : : : :

Combustible liquid C Moderate hazard when exposed to heat 205 LEL=1.2% UEL=8.55(est.) 400 dry chemical, alcohol foam, or carbon dioxide. Coal exposed tanks with water.

Health Hazard Data Health hazard Rating : 0,0,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Strong ingesstive toxin. mild local irritant. under ordinary conditions of handling not considered toxic. Symptoms : None expected with normal use. short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove victim to fresh air, Skin or eye contact- remove contaminated clothing and gently flush affected area with water for 15 min. Get medical advice for eye contact. Reactivity Data Stability: Stable. can react with oxidizing materials. Compatibility: Material: Usual materials of construction are suitable. Cargo : Group 40 of compatibility chart. Spill or Leak Procedure avoid contact with liquid. secure ignition sources. absorb on paper towel and vermiculite. remarks:++ Unassigned. Operational Problems/ Hazards Normally a DOW Chemical product where Nitrogen blanket and/or vent line dessicator required SG may vary from 0.9 to 1.03 with shipper. Product susceptible to moisture, rust and chlorides Liquid and vapor may cause irritation and liquid is toxic by ingestion, otherwise practically non-hazardous . Avoid excessive adjacent heat, as product may discolor. Product will attack rubber. Personnel Protection Boiler suit, gloves, goggles

Tank Cleaning Warm/ hot sea water wash, 5 ft half-hour drops Ventilate to gas/ odor free Thoroughly steam tank and line. Ventilate - Educt and mop Ensure gas checked at bottom of tank as vapor pressure low Note : Check coating guide as some coatings require drying by ventilation of the product before washing the tank. Tank must be dry ,odor and grease free. Handling - USCG/Shell request (Demand) Nitrogen Blanket. No big problems with this cargo. MS- Tank will pass for loading if in good shape.

DIETHYLENE GLYCOL MONOMETHYL ETHER

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Dowanol DM, ektasolve DM solvent, 2(2-methyoxyethoxy)ethanol, Methyl carbitol. : ++ : DGM 3 2 2 2 2 : CH OCH CH OCH CH OH : Colorless liquid with a mild pleasant odor. : 193C/ 379 F : -84C/ -120 F : 1.03 : Glycol ether : 0.2 : :C : 0.01 : D,O : 0.02 : Complete : 4.14

Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : : : : : :

Combustible liquid C Moderate fire hazard when exposed to heat or flame. 200 LEL = 1.2%, UEL = unavailable Unavailable Water, Carbon dioxide, Dry chemical, or alcohol foam. Cool exposed tanks with water.

: 0,0,0 : Unavailable : Unavailable : "

General : Not considered toxic under ordinary conditions of handling. Symptoms : Liquid may irritate Short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove victim to fresh air. Skin or eye contact- remove contaminated clothing and gently flush affected area with water for 15 min. Get medical advice for eye contact. Reactivity Data Stability: Stable. can react with oxidizing materials. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 40 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. remarks: ++ Unassigned. Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : Portable lines to droplines or ships lines to deck /center tanks. NO (Ensure Certificate obtained and Duration Checked) Purge possible Blanket : Probable Stainless steel, Zinc .

Operational Problems/Hazardous A Dow chemical product. Will require Nitrogen blanket and/or vent line desiccator. Product is practically non-hazardous, although liquid and vapor may cause irritation. Product is susceptible to moisture, rust and chlorides and may be adversely affected by excessive adjacent heat . Product will attack rubber. Personnel Protection; Boiler suit , gloves goggles. Tank Cleaning Warm sea water wash with chemical injection . Ventilate to gas/odor free Thoroughly steaming tank and lines Ventilate. Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust

Tank should be well steamed and odor grease free.

DIETHYLENE TRIAMINE
Synonyms : 2.2 Diaminodiethylene IMO No : 2079 IMO TYPE :3 2 2 2 2 2 2 Formula : H N Ch CH NH CH CH NH ICS Guide Page No. : 79 Family : Amine ( poly aliphatic ) Appearance and character : Clear colorless to yellow straw color with strong ammonia type odor. Specific Gravity : 0.9474 @ 25 C Heating Range (Subject to Chart.Reg.) Correction factor : TBA /C. Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No :7 Reactivity : reacts with oxidizing agent and acids Increased vapor release in contact with water and contact with air can cause discoloration . Handling : Portable lines to droplines or ships lines to deck /center tanks. Note: Bondstrand lines are Not suitable for this products Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : NO (Ensure Certificate obtained and Duration Checked) : Purge possible Blanket : Probable : Stainless steel, Zinc

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : N/A ppm TLV ppm

Flash point Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: : : : : :

102 C 67184 Triethylamine 193C % to % -35 C 399 C

Operational Problems/Hazardous Product will react with halocarbon type solvents, Allyl chloride, Acrilonitrile, Aldehydes and Ketones. Consult other cargoes before slopping to common tanks. Charterer may require Nitrogen blanket and/or vent line desiccator . Liquid and vapor can be harmful Vapor is very strong irritant and atmosphere will be untenable before TLV is reached . Product is strong alkaline. Avoid adjacent heat. Personnel Protection; Chemical protective clothing, goggles gloves, breathing apparatus on standby. Secure accommodation and re-circulate air Restrict personnel on deck Employ closed ullaging system Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete Warm sea water wash for minimum of 2.5 hours Ventilate to odor and gas free Steaming tanks and lines Ventilate Educt and mop. Drying oil : NO

B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited

protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

DIETHYL ETHER
Synonyms : Ether, Ethyl Oxide, Solvent Ether BP, Sulphuric Ether. IMO No : 1155 IMO TYPE :2 2 5 2 5 Formula : C H OC H ICS Guide Page No. : 80 Family : Ether Appearance and character : Clear colorless highly mobile liquid with strong sweet odor. Specific Gravity : 0.7193 @ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00114 Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 41 Reactivity : Reacts with oxidizing agent and acids Forms explosive peroxides in contact with air. Handling : Ships lines to deck/center tanks. Inhibitor : YES (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chaterers Reg. ) : Purge probable Blanket : YES Tank Coating recommended : Stainless steel, Zinc Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : LOW ppm TLV 400 ppm Flash point : -40 C Draeger Tube No. : 67305 Diethyl Ether 100/a Boiling Point : 34C Explosive Range : 1.85 % to 36.5% Freeze Point : -123 C Autoignition Point : 180 C Operational Problems/Hazardous Product may have to be cooled if climatic temperatures approach 30 C to prevent boil-off. Nitrogen purge/blanket may be required, also vent line desiccator, as product reacts with air. Liquid and vapor cause irritation and vapor can be fatal at high concentrations, although atmosphere becomes

unacceptable before TLV is reached. Product is highly flammable and explosion risk is severe and Nitrogen blanket is recommended in all circumstances. Clear lines with Nitrogen. Personnel Protection; Chemical protective clothing, goggles gloves, breathing apparatus on standby. Secure accommodation and re-circulate air Restrict personnel on deck Employ closed ullaging system Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial Cold sea water flush of tank and line to remove residues Ventilate to odor and gas free (or below LEL) Hot sea water wash, minimum 2 hours Ventilate to gas and odor free Steam tank and line Educt and mop Note : Attempts to evaporate residues by heating coils or air blowing will cause dangerous risk of formation of explosive peroxides. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank to be dry and grease rust free. Reference note 19. The tank must be filed with water prior to any machine washing. Check with ship operator for further cleaning instructions.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out.

Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor fire burn.

nozzles; if this is impossible, withdraw from area and let

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIISOBUTYLENE
Synonyms : Diisobutene. IMO No : 2050 IMO TYPE :3 Formula : Mixed Isomers C8 H16 ICS Guide Page No. : 61 Family : Hydrocarbon (Olefins) Appearance and character : Clear colorless liquid with strong sweet odor. Specific Gravity : 0.72 @ 20 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00082 Carriage : Ambient. Disch . : Ambient. Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 30 Reactivity : Reacts with oxidizing agent and acids Handling : Portable lines to droplines or ships lines to deck/center tanks Note : Compoflex flexible hoses are NOT suitable for this products. Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : YES (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible : Any Coating , but some restricted. Check Coating guides

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : N/A ppm TLV N/A ppm Flash point :-7C Draeger Tube No. : N/A Boiling Point : 97C Explosive Range : 1 % to unknown % Freeze Point : -101 C Autoignition Point : N/A C Operational Problems/Hazardous Product is flammable Liquid and vapor may cause irritation in eyes but are largely non-hazardous. Product should be kept away from adjacent heat. As a mixed isomer product tends to polymerize and while inhibited, Charterer may require Nitrogen blanket and/or vent line desiccator. Personnel Protection;

Boiler suit, goggles, and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NIL Cold sea water wash for minimum of 2 hours Warm sea water wash, 5 ft half hours drops Ventilate to odor and gas free Thoroughly Steaming tanks and lines Ventilate Educt and mop Drying oil : NO

B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank should be thoroughly steaming . Dry and grease free. This is not a difficult cargo. All thats needed is a good clean tank. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let

fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIISOBUTYL KETONE
Synonyms DIBK,sym-diisopropylacetone, sym-5 diisopropylacetone, 2,6-dimethyl-4-heptanone,Isovalerone,Valerone UN. No : 1157 CHris Code : DIK Formula : [(CH3)2CHCH2]CO Appearance-Odor : Colorless liquid, mild odor Boiling Point : 168C/ 334 F Freezing Point : -41C/ -42 F Specific Gravity : 0.81 Chemical Family : Ketone Vapor Pressure(20C) :1 Pollution Category USEPA : IMO :D Reid Vapor Pressure(psia) : 0.21 Applicable Bulk reg.46 Subchapter :D Vapor pressure 46C(psia) : 0.48 Solubility in water : Negligible Vapor Density(air = 1.0) : 4.9 Handling : Portable lines to droplines or ships lines to center /deck tanks. Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank Coating : Stainless Steel, Zinc Epoxy and polyurethane acceptable but restricted. Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Moderate fire hazard when exposed to heat or flame. Flash Point (F) : 140 Flammable Limits : 0.8~6.2 % Auto igniting Temp.(F) : 745 Extinguishing Agents : Carbon dioxide, dry chemical, alcohol foam. Special fire Procedures : Wear self-contained breathing apparatus. cool fire exposed tanks with water. Water may be ineffective on fire. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms

: : : : : :

2,1,1, Unavailable 25 25 Fairly toxic if inhaled, minor skin irritation. Redness or irritation of skin, irritation of eye, nose and throat.

Short Exposure Tolerance: Animal tests show minor skin irritation, traces of eye injury. inhalation resulted in 33% death rate in 8 hours, on test. Exposure Procedure : Inhalation: remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact: flush affected areas for 15 min. with water. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material: mild steel can be used. Cargo : Group 18 of compatibility chart. Spill or Leak Procedure If possible, wear rubber gloves, face shield, and protective clothing. secure ignition sources. Have all purpose canister mask available. Keep unprotected personnel upwind of contaminated area. flush with water. Operational Problems/ Hazards Product if flammable Liquid on skin can cause dermatitis, otherwise product practically non-hazardous, although irritation and systemic effects may result from prolonged exposure Odors is irritant and will create untenable atmosphere before exposure would be harmful. Personnel Protection Boiler suit , gloves, goggles Tank Cleaning Cold sea water wash for minimum 2 hours Warm sea water wash, 5 ft half hour drops Ventilate to gas and odor free Thoroughly Steaming tank and lines Ventilate Educt and mop 64/66 - OK with no heat adjacent Ventilate / Dry tank for at least 24 hours before re-loading. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIISOBUTYL PHTHALATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended : : : : : : : : TBA 3 C6 H4 (CO2 C4 H9) 2 64 Ester Clear colorless to gray liquid with almost no odor. 1.04 @ 20C

: : : : : 34 : Reacts with oxidizing agent and acids : Portable lines to droplines or ships lines to deck/center tanks : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible : Stainless steel, Polyurethane Some Zinc but restricted.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : No odor ppm TLV N/A ppm Flash point : 160C Draeger Tube No. : N/A Boiling Point : 327C Explosive Range : % to % Freeze Point : - 50 C Autoignition Point : N/A C Vapor pressure LOW Operational Problems/Hazardous Product is Practically non-hazardous Product must be dry Nitrogen blanket and/or vent line desiccator may be required. Lines should be cleared with Nitrogen. Personnel Protection; Boiler suit, goggles, and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NIL Drying oil : NO

Hot sea water wash, 5 ft. half hour drops with chemical injection. Ventilate to gas and odor free. Steam tank and line only after inspection to ensure no residues

Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

DIISODECYL PHTHALATE
Synonyms IMO No IMO TYPE Formula : : : : DIDP TBA TBA 6 4 10 21 2 C H (COOC H )

ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

: : : : : : : : : : : :

N/A Ester Clear colorless liquid with mild pleasant odor. 0.966@ 20 C

10-20 C 20-40 C 10-40 C 34 May Reacts with oxidizing agent and acids Check other cargo. Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked)

: Purge Possible Blanket : Possible : Stainless steel, Zinc, or Epoxy possibly some restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 190 C Draeger Tube No. : N/A Boiling Point : 250 C Explosive Range : Freeze Point : - 50 C Autoignition Point : N/A C Operational Problems/Hazardous Product is flammable Liquid and vapor cause irritation and may be toxic at high concentrations. Product may be heated or ambient Possible only heated for case of discharge Check locally. Nitrogen blanket and/or vent line desiccator may be required for quality control. Personnel Protection Boiler suit, goggles, and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Slight Drying oil : NO

Hot sea water wash, Minimum 3 hours chemical injection may be required. Ventilate When all residues removed thoroughly steam tank and line, Ventilate to gas and odor free. Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry and odor free. Color - Nitrogen blanket with protect color: especially on slack tank. Tank and lines must be completely dry for loading and discharge. No other problems Good cargoes.

Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

DIISONOYL PHTHALATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage : : : : : : : : DINP TBA 3 (C9 H19 COO)2 C6 H4 TBA Ester Colorless viscous liquid with mild pleasant odor. 0.972@ 20 C

: : Ambient

Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chaterers Reg. ) Tank Coating recommended

: 20 -40 C : 10- 40C : 34 : : Portable lines to droplines . : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible Stainless steel, Zinc, Epoxy. All with restriction on acid value and dryness.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 221 C Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous

Personnel Protection; Boiler suit, goggles, and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NIL Hot sea water wash, 5 ft. half hour drops . Ventilate to gas and odor free. Steam tank and line Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank and line must be dry. Color : Nitrogen blanket will protect color; especially on slack tank completely dry for loading and discharge No other problems Good cargo. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Drying oil : NO

Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

DIISOOCTYL PHTHALATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) : : : : : : : : : : : : : : : : : DIOP, BISOFLEX TBA 3 6 4 8 17 2 C H (COOC H ) 86 Ester Clear viscous Liquid with no odor. 0.98 @ 20 C 0.00072 Ambient Ambient 34 Reacts with oxidizing agent and acids Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible

Tank Coating recommended

: Any Coating.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : No odor ppm TLV N/A ppm Flash point : 204 C Draeger Tube No. : N/A Boiling Point : 370C Explosive Range : Freeze Point : - 50 C Autoignition Point : 500 C Vapor pressure LOW Operational Problems/Hazardous Product is Practically non-hazardous Product is susceptible to smell and Charterer may require Nitrogen blanket and/or vent line desiccator Although vapor is non-hazardous, due to low vapor pressure , caution should be employed in tank bottoms where Oxygen may be deficient. Personnel Protection; Boiler suit, goggles, and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NIL Cold Sea water wash, minimum 2 hours Hot sea water wash, 5 ft. half hour drops. Ventilate to gas and odor free. Steam tank and line Ventilate Educt and mop. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. Drying oil : NO

DIISOPROPYLAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Dareger Tube No Carriage : : : : : : : : : : : : : : : : : : : : : : : DIPA,N-(1-methyletyhl)-2-propamine 1158 DIA 3 2 2 [(CH ) CH] NH Colorless liquid, amine odor. 84C/ 183 F -96C/ -92 F 0.72 Amine 70 C 2.5 O 3.7 Complete 3.5 Ships lines to center/deck tanks NO Purge ; possible Blanket : YES Stainless Steel, Possible Zinc, but severely restricted. CH318 Hydrazine 0.25/a Ambient

Disch Average expected load Temp.

: Ambient : Ambient

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :C General : Dangerous. Keep away from heat and open flame. Toxic of nitrogen may form in fires. Flashback along vapor trail may occur. Vapor may explode ignited in an enclosed area. Flash Point (F) : 30 Flammable Limits : Unavailable. Auto igniting Temp.(F) : 600 Extinguishing Agents : Alcohol foam, co2,dry chemical. Special fire Procedures : Water may be ineffective. Wear eye protection and self contained breathing apparatus. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Liquid irritating to skin and eyes on contact. Symptoms:

: 3,2,4 : Unavailable : 5/skin : 5/skin : Inhalation of fumes can cause pulmonary edema.

eye, skin, and respiratory irritation.

Short Exposure Tolerance: Death results at 2200 ppm, or from repeated exposures of 260 ppm, nausea and impairment of vision occur between 25 and 50 ppm. Exposure Procedure : Remove victim to fresh air. Apply artificial respiration, if breathing stops, Skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable Compatibility: Material : Avoid copper and copper alloys. Cargo : Group 7 of compatibility chart. Spill or Leak Procedure If possible, wear butyl rubber gloves, face shield or all purpose canister respiratory protection, protective clothing. Secure ignition sources. Cover with sodium bisulfate and clean up. flush spill with large quantities of water. Operational Problems/Hazards Product used as catalyst and may react with several other products. Liquid and vapor harmful. Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection Chemical protective clothing, gloves, goggles, breathing apparatus ,Secure accommodation and re-circulate air. Use Closed Ullaging system. Tank Cleaning Warm sea water wash (check LEL) minimum 3 hours

Ventilate to odor and gas free Steam tank and line Ventilate Educt and mop NOTE: Amines absorb water very rapidly . Ensure vacuum does not form in tank while washing. Handling - Use protective clothing/mask when handling. Do not come in contact with liquid .Its bad irritation. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration.

All of the cargoes can be cleaned using only water and all can be considered as good last cargoes.
Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

DIMETHYLAMINE SOLUTION,40 %
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Dareger Tube No : : : : : : : : : : : : : : : : : : : : : : Methanamaine, N-methyl,N-methyl Methanamaine 40% 1160 DMG 3 2 (CH ) NH Clear, colorless liquid, ammoniacal fishy odor. 54C/ 129 F -37C/ -35 F 0.892 Aliphatic amines 170 C C 6.9 O 9.2 Appreciable 1.55 Ships lines to center/deck tanks only NO Purge : NO Blanket : Possible Stainless Steel only. CH318 Hydrazine 0.25/a

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :B General: Vapor is extremely flammable. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : -1 (cc) Flammable Limits : 2.8 ~14.4% Auto igniting Temp.(F) : 752(anhydrous) Extinguishing Agents : Water fog, co2, dry chemical, alcohol foam. Special fire Procedures :

Use water fog to protect personnel and cool containers. wear protective clothing and self-contained breathing apparatus. Health Hazard Data Health hazard Rating : 3,2,3 Odor Threshold(ppm) : 0.6 PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Vapor very irritating, liquid causes burns. Symptoms : Vapor causes sneezing. coughing, preumonitis edema. liquid burns skin, eyes, mouth, throat. Short Exposure Tolerance: Vapor very irritating above 10 ppm Exposure Procedure : Get medical attention. Inhalation; remove to fresh air, rest give mouth to mouth resuscitation or oxygen if needed. Ingestion; do not induce vomiting. skin contact; flush skin and eyes for at least 15 min. Reactivity Data Stability: Generally stable; reacts with acids, strong oxidizers. can explode in contact with mercury if ammonia present, so keep mercury thermometers and similar instruments away. Compatibility: Material : suitable; stainless steel, mild steel, iron, unsuitable; (corrosive) aluminum, copper, zinc, brass, bronze. Cargo : Group 7 of compatibility chart. Spill or Leak Procedure Avoid contact, do not breath vapor, wear protective clothing( face shield, hard hat, goggles, rubber gauntlet gloves, apron, boots). Use self contained breathing apparatus if needed. do not flush into sewers; dike and remove. then flush spill area with water. secure all ignition sources. Operational Problems/ Hazards Product will tend to boil off and tank must be capable of withstanding increased pressure and maintaining product at 3 below Boiling point. As product is toxic and harmful to eyes, Closed loading system should be employed. Vapor return, Nitrogen blanket and vent line desiccator may be required. As product reacts with mercury do not mercury thermometers. Odor is strong and will be unacceptable before TLV is reached . Product may have to be cooled by water spray Heating coils must blown dry and blanked off. Personnel Protection Total protection suit and breathing apparatus Secure accommodation and re-circulate air Restrict personnel on deck Use Closed Ullaging system Tank Cleaning Amines tend to absorb water very rapidly and all tank opening should be open to prevent vacuum forming in tank .. Flush tank with Cold sea water through small bore hose to clear residues. Ventilate to gas free Warm sea water wash for minimum 2.5 hours Ventilate to odor free Fresh water rinse - Educt and mop. tank to be steamed thoroughly and absolutely dry. Product is quote for 60% solution . Also shipped is a 40% solution ; SG 0.898 BP 51C FR.pt. -10C. Otherwise information applied to both solution.

USCG/IMO 40% DMA is the maximum concentration permitted as of 1/1/77. Heat Adj. No heat ever. Cool Down the deck on hot days- it will reduce loss due to evaporation . Handling - Vapor return line in use during loading/ discharge. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIMETHYLETHANOLAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No Carriage Disch. Average load temp. Deanol;2-(dimethylamino)ethanol; beta-dimethylaminoethyl alcohol; N,N-dimethyl-N-(2-hydroxyethyl) amine : 2051 : DMB 3 2 2 4 : (CH ) NC H OH : Colorless liquid; ammonia like odor : 136C/ 277 F : -59C/ -74 F : 0.89 : Alkanolamines : 4.2 : :D :+ :O :+ : Complete : 3.03 : Ship-lines to deck/center tanks : NO : Purge : NO Blanket : NO : Stainless Steel : N/A : Ambient : Ambient : Ambient

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General : Moderate hazard, when exposed to heat or flame; can react vigorously with oxidizing materials Flash Point (F) : 105 Flammable Limits : Unavailable Auto igniting Temp.(F) : " Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Water may be ineffective. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms

: : : : : :

Unavailable Unavailable " " Skin contact extremely dangerous Irritation of nose and throat

Short Exposure Tolerance Exposure Procedure :

: Unavailable

Vapor- remove victim to fresh air if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability This is a relatively reactive substance which can react with many other chemicals. Compatibility: Copper and copper alloys, and zinc and galvanized iron are corroded readily and should be avoided. Spill or Leak Procedure Wear rubber gloves, full protective clothing. Avoid contact with liquid. secure ignition sources. Operational Problems/ Hazards Liquid may cause severe damage to eyes Vapor cause vomiting and nausea. Personnel Protection Chemical protective clothing , goggles and gloves Keep accommodation sealed while gas freeing. Tank Cleaning Cold SW wash for minimum 1 hour to dispose residues. Check LEL. Ventilate to gas free ( or inert tank) Hot SW wash 5 ft. .5 hour drops. Ventilate FW rinse Educt and mop Tank must be dry and grease free. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames.

Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

DIMETHYLFORMAMIDE
Synonyms UN. No CHris Code : N,N-dimethylformamide; DMF; DMFA : 2265 : DMF

Formula : HCON(CH ) Appearance-Odor : Colorless liquid; unpleasant and fishy odor. Boiling Point : 153C/ 307 F Freezing Point : -58C/ -73 F Specific Gravity : 0.95 Chemical Family : Amide Vapor Pressure(20C) :* Pollution Category USEPA : IMO :D Reid Vapor Pressure(psia) : 0.16 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.30 Solubility in water : Complete Vapor Density(air = 1.0) : 2.51 Handling : Portable line to droplines or ships lines to deck/center tanks Inhibitor : NO Nitrogen : Purge : NO Blanket : Possible Tank Coating : Stainless Steel or Zinc Zinc is restricted and coating guide should be checked. Carriage : Ambient Disch. : Ambient Average load temp. : Ambient Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General: Moderate hazard, when exposed to heat or flame; can react with oxidizing materials, vapors are irritation. Flash Point (F) : 136 Flammable Limits : 2.2 ~ 15.2 % Auto igniting Temp.(F) : 833 Extinguishing Agents : Alcohol foam, Co2, or dry chemical. Special fire Procedures : Provide fire-fighters with self contained breathing apparatus and protective clothing. Health Hazard Data Health hazard Rating : 2,2,3 Odor Threshold(ppm) : 100 PEL/TWA(ppm) : 10/skin TLV/TWA(ppm) : 10/skin General : Moderate hazard, May be absorbed through skin, experimental evidence of liver and kidney damage. may defeat skin. highly irritating. Symptoms: Nausea, vomiting; skin irritation form liquid contact. Short Exposure Tolerance: Prolonged inhalation of 100 ppm has produced liver damage in experimental animals. Exposure Procedure : Wash contaminated skin with copious amounts of water, Irrigate eyes with water for at least 15 min. Reactivity Data Stability: Stable

3 2

Compatibility: Material : Compatible with all common metals except copper and copper alloys. Cargo : Group 10 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, safety glasses, protective clothing. Avoid contact with liquid. Secure ignition sources. Scoop up, add alcohol and burn a safe place outside. remarks: Vapor pressure: 3.7 mmHg at 25C Operational Problems/Hazards Product is hazardous, particularly by skin absorption Vapor when inhaled can cause liver and kidney damage Product must be dry and Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection Chemical protective clothing and breathing apparatus Secure accommodation and re-circulate air. Tank Cleaning Cold sea water pre-wash to clear residues Ventilate to gas free Hot sea water wash, 5 ft. half hour drops Fresh water rinse - Educt and mop Prolonged steaming may be required in order to disperse odor which has a tendency to linger. Tank and line to be absolutely dry. Zinc - If product contain less than 15 ppm of water Zinc is OK. S.S- No restriction. Handling - Prepare tank for loading same as for methanol, Strict Inspection . Use Nitrogen Blanket at all time. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIMETHYLPHENOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : 2.4/2.5 Diemethylphenol fractions See also resylic acid and xylenol. 2261 3 Complex Phenol A corrosive amber liquid with a distinctive carbolic odor. 1.02 @ 15 C

: 0.00073 : 45-65 C : : 45-65 C :

Reactivity: Can react with oxidizing agents, some acids, also reacts dangerously with ethylene oxide, acetaldehyde and formaldehyde. Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended Deck tanks. : : : : Portable lines to droplines or ships lines to deck lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel, Zinc, Silicate and polyurethane with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 92 C Draeger Tube No. : CH315 Phenol 5/a Boiling Point : 203 C Explosive Range : Freeze Point : 20 C Autoignition Point : TBA C Operational Problems/Hazardous Health hazards are similar to that of phenol. very corrosive and toxic vapor and liquid . Avoid all contact. Overall exposure can kill. High freezing point, will require careful monitoring of temperature. Treat otherwise same as phenol. Personnel Protection; Total protection suit and B/A. Restrict personnel on deck . Accommodation secured and A/C on Recirculation during all cargo operation. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO Discharge Slops ashore where facilities exist, or retain on board well diluted and discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Very Slightly Drying oil : NO

Hot SW wash with chemical injection ( 0.5 hour. 5 ft. drops) Fresh water rinse or steam. Ventilate to gas and odor free (odor may be persistent and required extra steaming) Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (B)-

Warm water (38 to 55 degree C )

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires: . Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; W ith clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

DIOCTYL PHTHALATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube NO Di-(2-ethylhexyl) phthalate; DOP ; bis(2-ethylhexyl)phthalate; Octoil; phthalic acid, bis(2-ethylhexyl)ester. : ++ : DOP 6 4 8 17 2 : C H (COOC H ) : Colorless oily liquid, mild odor. : 386C/ 726 F : -55C/ -67F : 0.99 : Ester : 0.01 : : III : LOW :D : Very Low : Insoluble : 13.45 : Portable lines to dropline or Ships lines to deck/ Center tanks : NO : Purge : NO Blanket : Possible : Stainless Steel, Epoxy, Polyurethane, Zinc with restriction. : N/A

Fire & Explosion Hazard Data

Grade- E: Combustible liquid Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : : : D Slight hazard, when exposed to heat or flame. 425 Unavailable 770 Carbon dioxide, dry chemical, foam, water spray.

Special fire Procedures : Water or foam may cause frothing. Do not direct water directly into fire . Use water to keep fire exposed containers cool.

Health Hazard Data

Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : " TLV/TWA(ppm) : " General : Suspected carcinogen. produces no ill effects at normal temperatures but may give off irritating vapors at high temperatures. Symptoms: After repeated exposure to skin, liquid causes reddening and scaling of the skin. Short Exposure Tolerance: Unavailable Exposure Procedure : Skin contact- wash affected parts as soon as possible. Eye contact- flood eye gently with clean water. Continue washing for at least 15 Min.

Reactivity Data
Stability: Stable Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 34 of compatibility chart.

Spill or Leak Procedure

Avoid contact with liquid. remarks: ++ Unassigned. Operational Problems/Hazards Liquid and vapor practically non-hazardous Low vapor pressure may result in layering and Oxygen deficiency in tank bottoms. Product must be dry and is highly susceptible to odor Charterer may require Nitrogen blanket and/or vent line desiccator. Personnel Protection Boiler suit Tank Cleaning Warm water wash, 5 ft half hour drops Ventilate to gas free and odor free. Steam tank and lines Ventilate Educt and mop Tank must be dry and odor -free. Color : Water /Moisture in product will change the color to milky white . Be sure to load/ discharge through dry and clean lines. Good cargo with no major problems.

DIPENTENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : CINENE, LIMONENE. 2052 3 10 16 C H 87

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No

: Olefin : Clear colorless liquid with lemon-like odor. : 0.847@ 15 C : : : : : TBA Ambient Ambient Ambient 30

Reactivity : May react with oxides. Will react with acids May discolor with moisture or excessive. Handling : Portable lines to droplines . Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg.) : Purge NO Blanket : NO Tank Coating recommended : Any Coating. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 45 C Draeger Tube No. : N/A Boiling Point : 175 C Explosive Range : Freeze Point : -97 C Autoignition Point : 160 C Operational Problems/Hazardous Product is flammable and liquid and vapor cause irritation and may be toxic in high concentrations. Product does not normally polymerize, but may be inhibited by some shippers. Nitrogen blanket and/or vent line desiccator may be required for quality control Product derived from wood oils and supplied in one of two grades ( high and normal quality). Personnel Protection; boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Nil Hot SW wash, 5 ft. half hours drops, with chemical injection Ventilate to gas and odor free Thoroughly steam tank and lines Ventilate Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. Minimum chlorides and hydrocarbons. HEAT ADJ. Heat next to Oil grade O.K. if grade is similar to turpentine. deliver from wood - no heat. Cleaning - For oil just Butterworthing hot or cold. For wood derived #3. Good cargo - No problems. Cleaning code 5.

Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

DIPHENYLMETHANE DIISOCYANATE(MDI)
Synonyms 4,4-Diisocyanodiphenylmethane; 4,4-diphenylmethane diisocyanate diphenylmethane-4,4-diisocyanate; MDI; Methylene bis(4-phenyl isocyanate); methylene bis-phenylisocyanate. : 2489 : DPM 6 4 2 2 : (OCNC H ) CH : Light yellow solid(at room temp) or molten liquid; slightly musty odor. : 392C/ 738 F : 37C/ 99 F : 1.19 @ 77 F(25C)

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity

Chemical Family : Isocyanate Vapor Pressure(20C) : V.LOW Pollution Category USEPA : IMO :B Reid Vapor Pressure(psia) :" Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) :" Solubility in water :* Vapor Density(air = 1.0) : 8.5 Handling : Ships lines to poison bank or deck tanks only. Probably only a deck tank stowage. Inhibitor : Possibly Nitrogen : Purge : YES Blanket : YES Tank Coating : Stainless Steel or Zinc(Product may be compatible with other coatings) Carriage : 15-20 C Disch. : 15-20 C Average Expected Load Temp. : 15-20 C Fire & Explosion Hazard Data Grade-E : Combustible Electrical Group : NA General : Light yellow solid. flammable at high temp. Toxic vapors of carbon monoxide, oxides of nitrogen, hydrogen cyanate are generated when heated. fire may cause polymerization and decomposition leading to violent rupture of containers or tanks. Flash Point (F) : 374 Flammable Limits : Unavailable Auto igniting Temp.(F) : 465 Extinguishing Agents : Water spray, Co2, dry chemical, water spray. Special fire Procedures : wear self- contained breathing apparatus and protective clothing. cool exposed tanks with water. Health Hazard Data Health hazard Rating : 3,2,4 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 0.01 TLV/TWA(ppm) : 0.005 General : Vapor is strong irritation to eyes and throat; can cause eye and lung injury. cannot be tolerated even at low concentrations. Symptoms: Watering or reddening of eyes. diarrhea, and loss of weight. breathlessness, chest discomfort, and reduced pulmonary function. Short Exposure Tolerance: animal tests have shown slight eye damage in 50 % solution; oral lethal dose is in excess of 21.6g/kg of body weight ; no primary skin irritation; no deaths by inhalation in 5~6 hrs. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and immediately flush affected areas with water for 15 min. call a doctor. Reactivity Data Stability:

Material must be blanketed with dry nitrogen; unstable in traces of moisture, slowly forming carbon dioxide gas. Compatibility: Material : do not have in direct contact with wood. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing and self contained breathing apparatus. Avoid contact with liquid. Secure ignition sources. remarks: Negligible; reacts slowly Operational Problems/Hazards A toxic product, dangerous in most forms of contact When in contact with moisture the product gives off carbon Dioxide which could form dangerously high pressures within closed containers. Heat is also evolved. Prior to loading the atmosphere in the tank must be completely dry and maintained at a dew point of less than - 40C , this being done with shore dry nitrogen. Stow away from adjacent heat ( above 40C concentration of toxic vapor will be dangerously high and may self-react ) Product will require a vent line desicccator. Personnel Protection Total protection suit Restrict personnel on deck Secure accommodation and recirculate air. Vapor return system : YES Tank Cleaning Maintain Nitrogen in tank and clean with suitable solvent ( Toluene Acetone) Do not Use water When all trace of product gone, clean as for solvent used above. Tank must be completely dry and purged with dry Nitrogen until dew point - 40C or less. Melt point-Heat : Check it varies - different shippers Coating - If cleaning fail all coating lost . Handling - Special instruction and equipment will be supplied if and when booked /carried. Refer to Special cargoes handling booklet appendix.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material.

SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

DIPROPYLENE GLYCOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating Carriage Disch. Average loading Temp. Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : 2,2-dihydroxydipropyl ether; 2,2'-dihydroxyisopropyl ether; 1,1'-oxydi-2-propanol : ++ : DPG 3 2 2 : (CH CHOHCH ) O : Colorless, Slightly viscous liquid odorless. : 232C/ 449 F : : 1.03 : Glycol ether : V.LOW : : III :" :D : 0.07 : Complete : 4.63 : Portable lines to droplines : NO : Purge : No Blanket : Possible : Stainless Steel, Zinc, polyurethane and Epoxy with restrictions. : Ambient : Ambient : Ambient

: : : : : : : :

Combustible liquid C Slight hazard when exposed to heat or flame 280 LEL=2.2%, UEL -Unavailable Unavailable Water, CO2, dry chemical, alcohol foam. Water or foam may cause frothing.

Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Not considered toxic under ordinary conditions or handling. Symptoms : Minor eye irritant short Exposure Tolerance : Unavailable. Exposure Procedure : Skin or eye contact- remove contaminated clothing and gently flush with water for 15 min. Get medical advice for eye contact. Reactivity Data Stability: Stable Compatibility: Material : usual materials of construction are suitable.

Cargo :

Group 40 of compatibility chart.

Spill or Leak Procedure Avoid contact with liquid. remarks: ++ Unassigned Operational Problems/ Hazards Product practically non- hazardous Liquid may cause irritation Easily contaminated, particularly by water, rust , or excessive adjacent heat, which may cause discoloration. Charterer may require Nitrogen blanket and/or vent line desiccator for quality control. For sea reason lines should be cleared with Nitrogen Surveyors will be very particular over coating condition. Personnel protection Boiler suit, gloves, goggles Vapor return system Discharge on passage as per regulation Tank Cleaning Hot sea water wash, minimum 2.5 hours, Ventilate Steam tank and line, Educt and mop Tank must be dry and odor free This is a fine Glycol needing a good tank with clean lines. GOOD Cargo - No problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

DIPROPYLENE GLYCOL MONOMETHYL ETHER

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family : : : : : : Dowanol DPM. TBA 3 3 3 3 CH OC OO OH Glycol Ether

Appearance and character : Clear colorless liquid with Mild pleasant odor. Specific Gravity : 0.95to 1.0@ 20 C Heating Range (Subject to Chart.Reg.) Correction factor : TBA Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : Ambient USCG Compatibility chart Group No :40 Reactivity : May react with oxides, acids and some amines Discolored by excessive heat. Handling : Portable lines to droplines . Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : YES Tank Coating recommended : Stainless Steel Zinc and Polyurethane with some restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 100 ppm Flash point : 85 C Draeger Tube No. : N/A Boiling Point : 188C Explosive Range : Freeze Point : -83 C Autoignition Point : C Low Vapor Pressure. Operational Problems/Hazardous Product practically non- hazardous Liquid may cause defatting and irritation Normally a Dow chemicals product Nitrogen blanket and/or vent line desiccator may be required. Surveyors will be particular about coating condition Normally carried ambient , but some shippers may request heating for discharge. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Complete Hot SW wash, 5 ft. half hours drops, Ventilate to gas and odor free Thoroughly steam tank and lines Ventilate ,Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry and odor free.

DOBANIC
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : : : : : : : : Dobanic Acid. N/A N/A Cn H2 n+1 So3 H where n=8 to 14 89a Alkyl Benzene Sulphonic Acids Dark viscous liquid Slight odor of sulfuric dioxide. 1.058@ 20 C

: 0.00071

Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : :

20/25 C

N/A Not established forms emulsions with water Stainless steel ships lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : YES Stainless Steel

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : N/A Boiling Point : Explosive Range : Freeze Point : Autoignition Point : C Operational Problems/Hazardous Mildly corrosive, non-flammable Mild irritant to eyes and skin. Must not exceed 40 C - use hot water circulated through heating coils - Excessive heating causes discoloration. Ensure tank /line completely dry. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : form emulsions with water. Hot SW wash, Steam Educt and mop dry Drying oil : NO

B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides/hydrocarbons. Tank must be absolutely dry.

DOBANOL 23 c12-c13 25 C12 -C15, 45 C14-C15

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . : : TBA : TBA : CNH(2N+1)OH where C is from 12-15 : : Primary Fatty Alcohol : Clear colorless liquid with mild odor. : 0.834@ 25 C : TBA : 20-55 C : 30-55 C

Average Expected Load Temp. : 20- 40 C USCG Compatibility chart Group No : 20 Reactivity : Reactions not established. Check other cargo. Product will absorb water and discolor in contact with air or excessive heat. Handling : Portable lines to droplines . Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge Possible Blanket : Probably Tank Coating recommended : Stainless steel, Zinc, Polyurethane or Epoxy with some restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 140 C Draeger Tube No. : Alcohol may be suitable Boiling Point : 270-285C Explosive Range : Freeze Point : 17-31 C Autoignition Point : C Operational Problems/Hazardous Product non-hazardous, although liquid may cause irritation. Product easily contaminated, particularly by water or rust Heat must be applied at low pressure- sudden increases in temperature or excessive heat will discolor product. As product absorbed water Nitrogen blanket and/or vent line desiccator may be required for quality control. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight Hot SW wash, minimum 2.5 hours, Ventilate to gas and odor free, Thoroughly steam tank and lines Ventilate , Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. These synthetic primary fatty are also called detergent alcohols Heat/color : Do not raise temperature more than 5 degree per day Too fast heating may scorch color. All grades are color sensitive No other problems. Exthoylated: These fine grades are similar to above grades, But for different uses. Heating : Be sure and obtain exact heating instructions. It is Imperative that these instruction be followed to the letter. Tanks : Only good coated tanks will be accepted. Check coating condition before stow . Good cargoes. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water.

For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

DOBANOL 25-3
Synonyms : NONIDET SB. IMO No : TBA IMO TYPE :3 Formula : RO (CH2 CH2 O)3 H ICS Guide Page No. : 89C Family : Primary Alcohol Ethoxylate Appearance and character : Clear colorless liquid with mild odor. Specific Gravity : 0.925@ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00066 Carriage : 30-40 C Disch . : Average Expected Load Temp. : 20-40 C USCG Compatibility chart Group No : Reactivity : May react with oxides. acids and amines is contaminated and discolored by moisture and excessive heat. Handling : Portable lines to droplines . Inhibitor : NO ( Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge Possible Blanket : YES Tank Coating recommended : Stainless steel Zinc, Epoxy and

Polyurethane are subject to restrictions Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 204 C Draeger Tube No. : N/A Boiling Point : N/A C Explosive Range : Freeze Point : 5C Autoignition Point : C Vapor pressure Low Operational Problems/Hazardous Product is Practically non-hazardous , although liquid may cause irritation and some defatting Product is susceptible to contamination, particularly by water , rust and excessive heat. Charterer may be require Nitrogen blanket and/or vent line desiccator Do not heat above 50 C unless specific instructions issued Surveyors particular about coating condition. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Nil Hot SW wash, 5 ft. half hours drops, Ventilate to gas and odor free, Fresh water rinse ( Steaming may be required to disperse odor) Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. These synthetic primary fatty are also called detergent alcohols Heat/color : Do not raise temperature more than 5 degree per day Too fast heating may scorch color. All grades are color sensitive No other problems. Exthoylated: These fine grades are similar to above grades, But for different uses. Heating : Be sure and obtain exact heating instructions. It is Imperative that these instruction be followed to the letter. Tanks : Only good coated tanks will be accepted. Check coating condition before stow . Good cargoes. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 8. Drying oil : NO

Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated

DODECANOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : : : : : : Dodecyl Alcohol, Lauryl Alcohol, Dobanol 23 TBA 3 3 2 2 CH (CH ) 10 CH OH Alcohol Clear colorless oily liquid mild perfume-like odor. 0.830@ 20 C TBA 27-32 C 30-38 C 30- 38 C 20

Reactivity: May react with oxides. acids caustic soda and alkalis contaminated by water at excessive heat. Handling : Portable lines to droplines . Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg.) : Purge NO Blanket : Possible Tank Coating recommended : ANY Coating but check possible restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 127 C Draeger Tube No. : N/A Boiling Point : 259 C Explosive Range : Freeze Point : 24 C

Autoignition Point

Operational Problems/Hazardous Product is Practically non-hazardous, Susceptible to moisture , rust and excessive heat. Do not heat above 38C unless specific instructions and all heat should be applied gently, otherwise product may discolor. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B

Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight Hot SW wash, Minimum 2.5 hours. Ventilate to gas and odor free Steaming tank and lines Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. These synthetic primary fatty are also called detergent alcohols Heat/color : Do not raise temperature more than 5 degree per day Too fast heating may scorch color. All grades are color sensitive No other problems. Exthoylated: These fine grades are similar to above grades, But for different uses. Heating : Be sure and obtain exact heating instructions. It is Imperative that these instruction be followed to the letter. Tanks : Only good coated tanks will be accepted. Check coating condition before stow . Good cargoes. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

DODECYL BENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Alkyl benzene; detergent alkylate #2; n-Dodecylbenzene; laurylbenzene, 1-phenyldodcane : ++ : DDB : C12H25C6H5 : Water-white liquid; kerosene odor : 246 C/ 475 F : 4C/ 40 F : 0.86 : Aromatic hydrocarbon : 0.01 : : III : 4.1 :D : 4.7 : Negligible : 8.4 : Portable lines to droplines, or ships lines to deck /center tanks. : NO : Purge : NO Blanket : Possible : ANY COATING : CH261 Hydrocarbons 0.1%, CH254 Hydrocarbons 2

: : : : : : : :

Combustible liquid D CO and CO2 fumes produced on combustion. 235 Unavailable " Confined area- Co2, dry chemical, open area foam, water spray. Water or foam may cause frothing

Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance

: : : : : : :

0,0,0 Unavailable Unavailable " Very low toxicity " Very low toxicity

Exposure Procedure : Skin contact- wash well with soap and water. Eye contact- flush with portable water. Reactivity Data Stability: Stable Compatibility: Material : usual materials of construction are suitable. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. remarks: ++ unassigned Operational Problems/ Hazards Product is practically non-hazardous and evolves little or no vapor at normal handling temperatures. Charterers may require Nitrogen blanket and/or vent line desiccator. Personnel Protection Boiler suit , gloves Tank Cleaning Hot sea water wash for minimum 2.5 hour with chemical injection : If residues persistent ( Check LEL) Ventilate to gas and odor free. Fresh water rinse Educt and mop. These base detergents are sometimes called soft and Hard detergents, alkyl benzene; Detergent Alkylate and Ucane are Soft ones Dob is almost problem free - Good cargoes. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

DOWANOL P MIX
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended Check restrictions Epoxy NOT suitable. : : : : : : : : : : : : : : : : : : TBA 3 Mixture : See ICS 91/4 91 Glycol Ether Colorless liquid mild odor. 0.944@ 25 C TBA Ambient Ambient Ambient 40 May react with oxides. acids .Check other cargo. Portable lines to droplines . or ships lines to deck center tanks. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Probable Stainless Steel, Zinc or polyurethane .

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 49 C Draeger Tube No. : N/A Boiling Point : 132-286C Explosive Range : Freeze Point : - 84C Autoignition Point : C Operational Problems/Hazardous Product is Practically non-hazardous, Liquid and Vapor will cause irritation Nitrogen blanket and/or vent line desiccator may be required. Keep away from adjacent heat Heating may be required by some shippers Product susceptible to contamination Surveyor particular about odor and coating condition. Personnel Protection; Chemical protective clothing, Goggles and gloves Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO

(A) Cleaning from Solubility in water : Complete NOTE : Check coating list as some coatings require product dried by ventilation before washing. Hot sea water wash, minimum 2.5 hours ( check LEL) Ventilate, Fresh water rinse Ventilate - Educt and mop Some coating may require further ventilation prior to ballasting or next cargo. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry. Product is a mixture of : Dipropylene Glycol Monomethyl Ether, Propylene Glycol Monomethyl Ether, Tripropylene Glycol Monomethyl Ether. Adj/Heat ; DOW will not load this product if cargoes in adjacent tanks are under heating. Handling - This is not a difficult cargoes A good lined tank with clean lines/pumps will do these similar product Cellosol.

DOWANOL TPM
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Tripropylene Glycol , Monomethyl Ether. TBA HO(C3 H6O)2 C3 H6 OCH3 219 Glycol Ether Colorless liquid with mild odor. 0.965@ 25 C TBA Ambient Ambient Ambient 40 May react with oxides. acids check with other cargo. Portable lines to droplines or ships lines to center/deck tanks. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible Stainless Steel, Zinc Epoxy, polyurethane subject to coating restrictions

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 121 C Draeger Tube No. : N/A Boiling Point : 242 C Explosive Range : Freeze Point : -78 C Autoignition Point : C Operational Problems/Hazardous Product is Practically non-hazardous, Liquid and vapor may cause irritation Vent line desiccator may be required Product susceptible to water, rust or excessive heat Surveyors particular about coating condition Keep away from adjacent heat- although shipper may require heating. Check locally. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Complete Note : Check any coating restriction before washing Hot sea water wash, minimum 2.5 hours. Ventilate to gas and odor free Fresh water rinse. Educt and mop Ventilate for 24 hours prior to ballast or next cargo. B) Cleaning to : (Beyond Solvent Standard)

Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry.

DOWFAX
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : TBA 3 Mixture TBA TBA Clear liquid . 1.040@ 25 C TBA Ambient Ambient Ambient N/A React with oxidizing agents, acids and alkalis. Portable lines to droplines . NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible ANY Coating but if undiluted.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : +4 ~40C Autoignition Point : C Operational Problems/Hazardous Low oral toxicity. Undiluted and 10% aqueous solutions are moderately irritating to the eyes. Prolonged skin contact may produce burns or blisters Some grades may require heating - check locally Product may discolor in contact with air, water or excessive heat. Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial Hot SW wash, Minimum 3 hours. Ventilate to gas and odor free Fresh water rinse tank and line , Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry, Grease -free, and good coating condition SS/Phenol - These linings are recommended by DOW Carried in S.Steel with no problems.

DOWFROTH
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : TBA Mixture Clear, Slightly oily, liquid with a mild odor. 0.996@ 15 C TBA Ambient Ambient Ambient May react with oxides. acids Check other cargo. Portable lines to droplines . NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Epoxy, polyurethane Some Zinc, but restricted.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 120 C Draeger Tube No. : N/A Boiling Point : 250 C Explosive Range : Freeze Point : N/A Autoignition Point : C Operational Problems/Hazardous Effectively of little hazard, although liquid and vapor will cause irritation and may cause deffating. Considered of high specification, product is degraded by contact with adjacent heat, moisture or rusting. Nitrogen blanket and vent line desiccator may be required Surveyor will expect minimal coating breakdown. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial Hot SW wash, with chemical injection (Some frothing may occur- this should be flushed off prior to tank entry) Ventilate to gas/odor free, Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Tank must be absolutely dry.

DUTREX
Synonyms IMO No Trademark for a series of aromatic hydrocarbons derived from petroleum. : TBA

IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : : : : : : : :

3 Hydrocarbon Mixture 92 Aromatic Lube oil Extract Light amber to black viscous liquid characteristics odor. See List TBA See list N/A N/A 33 Generally no reaction except with Nitric Acid. Portable lines to droplines . NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Zinc or Stainless Steel- check Manufacturer lists.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : See lists Draeger Tube No. : N/A Boiling Point : 280~ 555C Explosive Range : Freeze Point : Below 0 C Autoignition Point : C Operational Problems/Hazardous Probably flammable but very Low volatilitys May be carcinogenic Avoid Skin Contact. Personnel Protection; Boiler suit , goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A Vapor Return System Reg. : NO Persistent oil - residues to bunkers. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NIL Hot SW wash, with chemical injection - 5 ft. half hour drops Steam tank and lines Ventilate Educt and mop dry. B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides See attached list for typical SG, flash points and carriage temperatures for Various grades. Grade 217UK 479UK 718NC 719UK SG 60/60F 0.971 1.023 1.022 F.P /C 145 193 215 + 229 Pour Pt C Carriage Temp. -32 Ambient -1 -1 to 17 50 7 -

726 726HP 726UK 729AG 729HP 729UK 739UK 766 766HP 766UK 915AG RT

0.96 0.96 0.99 1.00 1.00 1.025 1.027 1.00 1.00 0.99 1.00 1.020

215 + 215 + 226 215 + 215 + 215 249 215 + 215 + 249 215 + 204

-1 to 17 -1 to 17 15 -1 to 17 -1 to 17 7 2- 1 to 17 - 1 to 17 16 -1 to 17 4

50 50 50 50 50 65 65 -

These oils are also called Extended Oils Heat: Temperatures given are maximum for discharge. Handle and clean as for Lube Oils . No Problems.

EPICHLROHYDRIN
Synonyms 1-chloro-2,3-epoxypropane, 3-chloro-1,2 epoxypropane, chloromethyloxirane, 2-chloropropylene oxide, gamma-chloropropylene oxide; oxirane, (chloromethyl)-; propane, 1-chloro-2,3-epoxy, ECH, EPI. : 2023 : EPC 2 2 : CH CHCH CI : Colorless liquid; sweetish-like odor . : 116C/ 240 F

UN. No CHris Code Formula Appearance-Odor Boiling Point

Freezing Point : -58C/ -73 F Specific Gravity : 1.18 Chemical Family : Epichlorohydrin Vapor Pressure(20C) : 12.5 Pollution Category USEPA :B IMO :C Reid Vapor Pressure(psia) : 0.67 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 1.0 Solubility in water : 6% Vapor Density(air = 1.0) : 3.19 Handling : Ships lines to center /deck tanks. Inhibitor : YES Nitrogen : Purge : Possible Blanket : probable Tank Coating : Stainless Steel, some Zinc with restrictions Exceptionally some Epoxies and Polyurethane, but check coating guide. Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General: One of the products of combustion is hydrochloric acid gas, which is both toxic and corrosive. Ignited by heat and open flame. This product can decompose to form highly toxic phosgene gas. Flash Point (F) : 105 Flammable Limits : 3.8~ 21% Auto igniting Temp.(F) : 804 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Keep exposed tank cool with water spray, provided respiratory and body protection to fire fighting personnel. Health Hazard Data Health hazard Rating : 3,3,4 Odor Threshold(ppm) : 10~25 PEL/TWA(ppm) : 2/skin TLV/TWA(ppm) : 2/skin General : Suspected carcinogen. vapor extremely irritating. Lung injury may be delayed. liquid causes severe burns; absorbed by leather and causes delayed burns. class B poison. Symptoms The liquid blisters skin on contact. :

The vapor causes eye and respiratory irritation It may also cause vomiting, convulsions, rapid pulse, and respiratory paralysis. Short Exposure Tolerance: Concentrations exceeding 40 ppm rapidly produce irritation to nose and eye Exposure Procedure : Vapor-remove victim to fresh air, if breathing stops, apply artificial respiration. Skin or eye contact - remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical attention as soon as possible. Reactivity Data Stability: Stable under usual handling conditions, however, it will polymerize at elevated temp. or in the presence of certain catalysts; acids, alkalis and metallic halides are known to be

effective catalysts for polymerization and should be avoided. Compatibility: Material : Usually carried in steel tanks; however, the wet product will pit steel. Cargo : Group 17 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, protective clothing. Evacuate personnel not equipped with protective clothing and respiratory protection. Secure ignition sources. Operational Problems/ Hazards Product is flammable, Liquid and vapor cause irritation and may be toxic Keep away from adjacent heat As product can polymerize in contact with heat shipper may inhibit the product. Check Locally. Nitrogen blanket and/or vent line desiccator may be required for quality control and to reduce water vapor, as product can become corrosive to metals and tank lining in contact with water. Clear lines with Nitrogen. Personnel Protection Total protection suit Secure accommodation and recirculate air and restrict personnel on deck during all operation. Tank Cleaning Cold sea water wash for minimum 2 hours Ensure all residues removed and pump and line thoroughly flushed, Ventilate to gas and odor free. Hot sea water wash, 5 ft half hour drops ( Chemical injection may be required), Ventilate Thoroughly steam tank and line ( to remove odor) Ventilate, Educt and Mop. Note : Some coatings may require 24 hours ventilation prior to washing or prior to loading next cargo, or ballast. Handle this poisonous cargo with utmost care . Use protective clothing and mask when working around this cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Extremely flammable; May be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural Firefighters protective clothing is not effective for these materials Isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances.

If you find the ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE FIRE 2 Small Fires: Dry chemical or Co , water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ETHYL ALCOHOL
Synonyms Alcohol; alcohol anhydrous; alcohol C-2; Cologne spirit; denatured alcohol; ethanol; ethyl hydroxide; fermentation alcohol; Grain alcohol; methyl alcohol. : 1170 : EAL 2 5 : C H OH : Colorless liquid, smells like wine or shellac thinner. : 78C/ 173 F : -114C/ -173 F : 0.79 : Alcohol : 44 : : III : 2.3 :D : 3.5 : Complete : 1.6 : Portable lines to droplines or ships lines to center. deck tanks. : NO : Purge : Possible Blanket : Probable : Stainless Steel, Zinc, Epoxy, polyurethane Subject to restrictions.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Dangerous when exposed to heat or flame. flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) : 65 Flammable Limits : 3.3 ~ 19% Auto igniting Temp.(F) : 793 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Water may not be effective unless large quantities are used. Health Hazard Data Health hazard Rating : 1,0,1 Odor Threshold(ppm) : 10 PEL/TWA(ppm) : 1000 TLV/TWA(ppm) : 1000 General : One of the least hazardous industrial organic solvents. Symptoms: Dizziness, double vision, and other classic alcohol intoxication symptoms. these may be accompanied by symptoms such as vomiting. attributable to the denaturant. Short Exposure Tolerance: 5000~ 10000 ppm irritates eyes and upper respiratory tract; stupor and drowsiness may result after an hour at this concentration. more than 1000 ppm may cause headache and eye irritation. Exposure Procedure : Vapor- remove victim for fresh air; if breathing stops; apply artificial respiration. Eye contact- gently flush with water for 15 min. Get medical advice or attention. Reactivity Data

Stability: Stable Compatibility: Materials : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. See also Appendix 1- exceptions to the chart. Spill or Leak Procedure Secure ignition sources. Spills may be flushed away with water, but should not flushed into a confined space because of the explosion hazard. Operational Problems/ Hazards Alcohol may be derived from fermentation ( i.e. Natural) Processes or from chemical (i.e. artificial) processes. This sheet will apply in general terms to all products. Product is flammable. Liquid and vapor cause intoxication and high concentrations cause damage and can be fatal . Product is easily contaminated; Nitrogen blanket and/or vent line desiccator may be required. Tank openings to be sealed. Surveyors very particular about cleanliness and coating condition and generally a very high standard is required. Product occasionally shipped in diluted form. Check Locally. Personnel Protection Boiler suit, goggles , gloves. Tank cleaning If reloading a high quality product, particularly an alcohol, then tank should be educted of residues (observe all safety precautions) and ventilated dry, and gas/odor free. Alternatively hot sea water wash (check LEL) , Ventilate to gas/odor free Fresh water rinse - Educt and mop. NOTE : With some linings product must be ventilated dry before washing . Also tank must be ventilated before ballasting or next cargo. Check coating guides,. Although product is termed Ethanol, this sheet will apply to Alcohol in general, including Pure Grain Alcohol. Some difference will be found in SG FP etc. but the general treatment of the product will remain the same. Grades/MS- Industrial grade could be carried in an excellent M.S tanks . Other grades need S.S or good coated tanks 64/66 : Coating softens badly if heat adjacent - Avoid ventilate tank for 48 hours after discharge - Hardening. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 6. Cargoes such as alcohol and Ketone do not require extensive machine washing and can be cleaned by positioning a tank cleaning machine close to the pump well and giving a short fresh water wash. For coated tanks, it is necessary to consult the manufactures resistance list to ensure this method will not adversely affect the tank coating. When the coating can be affected, it is still necessary to flush the entire pump/line system with fresh water as much as possible to remove any remaining cargo form valves, drain cocks, low points on line system, etc. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard.

HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

m-ETHANOLAMINE
Synonyms Aminoethanol;2-aminoethanol; beta-amino-ethyl alcohol, collamine;ethyloamine,2-hydroxethylamine, beta-hydroxethylamine, monoethanolamine. : 2491 : MEA 2 2 2 : HOCH CH NH : Colorless liquid; Ammonia like-odor : 172C/ 342 F : 10C/ 50F

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point

Specific Gravity : 1.02 Chemical Family : Amine Vapor Pressure(20C) : 0.48 Pollution Category USEPA : IMO :D Reid Vapor Pressure(psia) : 0.01 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.03 Solubility in water : Complete Vapor Density(air = 1.0) : 2.10 Handling : Ships lines to center or deck tanks or portable lines to droplines. Inhibitor : NO Nitrogen : Purge : Possible Blanket : Possible Tank Cleaning : Stainless Steel , Exceptionally some Zinc , Epoxy or polyurethane, but subject to restrictions. Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Moderate hazard, when exposed to heat or flame, irritating vapors generated when heated. Flash Point (F) : 200 Flammable Limits : Unavailable Auto igniting Temp.(F) : Greater than 500 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Respiratory and body protection should be worn by fire parties. Health Hazard Data Health hazard Rating : 2,2,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) :3 TLV/TWA(ppm) :3 General : Liquid contact causes severe eye irritation, vapor inhalation causes respiratory irritation. Symptoms: Respiratory irritation will range from itching to severe burning depending upon concentration. Short Exposure Tolerance: 50 ppm for 30 minutes. Exposure Procedure : Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen, administered by trained personnel, is often helpful. skin or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: It will oxidize in the presence of air, so is often shipped under a pad of inert gas. ethanolamine is a reactive material confining chemically with many other substances. Compatibility: Material : Corrosive to copper and its alloys; also, attacks rubber. Spill or Leak Procedure Wear butyl rubber gloves, face shield or all purpose canister respirator, protective clothing. avoid contact with liquid. cover spill with sodium bisulfate. Wash with excess of water. Operational Problems/ Hazards Products is flammable. Liquid particularly harmful to eyes Vapor causes irritation. Product may react with air and Nitrogen blanket and/or vent desiccator may be required.

Heating requirements very with Shipper and conditions check locally May be necessary to keep away from adjacent heat. Clear lines with Nitrogen. Personnel Protection Chemical protective clothing, gloves, goggles and breathing apparatus. Secure accommodation and recirculate air during all operations. Tank Cleaning Tank should be washed down with cold sea water directly after discharge to reduce oxidizing process. Thereafter warm sea water wash, minimum 3 hours. Ventilate to gas and odor free , Fresh water rinse Steaming may be required to reduce odor if persistent Ventilate Educt and mop. Tank must be dry Carried with no problems Handling : Use mask and protective clothing. Both vapor and liquid harmful. Vapor return system : Possible. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

HEALTH HAZARDS Contact cause burns to skin and eyes If inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out.

Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ETHYLENE GLYCOL ETHYL ETHER ACETATE

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Cellosolve acetate; ethanol, 2-ethoxy- acetate; 2-ethoxyethylacetate; Glycol monoethyl ether acetate : 1172 : EGA 3 2 4 2 5 : CH COOC H OC H : Colorless liquid; Pleasant fruity odor . : 156C/ 313 F : -62C/ -79 F : 0.97 : Ester : 1.2 : :C : 0.1 : D,O : 0.2 : 23% Appreciable : 4.72 : Portable lines to droplines or ships lines to Center/deck tanks.

Inhibitor Nitrogen Tank Coating

: NO : Purge : NO Blanket : Possible : Stainless steel , Polyurethane Limited in Epoxy and Zinc

Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :C General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 135 Flammable Limits : LEL = 1.7%, UEL= Unavailable Auto igniting Temp.(F) : 715 Extinguishing Agents : CO2,dry chemical, alcohol foam, water fog. Special fire Procedures : The same techniques used for igniting fire involving combustible petroleum products are applicable. Cool fire exposed tanks with water. Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 0.056 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : 5/skin General : Slight skin irritation. more of a chronic systemic hazard from inhalation. Symptoms: Irritation from skin contact. Vapor- irritation of nose and throat. Short Exposure Tolerance: High vapor concentrations can cause nose and throat irritation. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity data Stability: This is a relatively stable compound. Compatibility: Material : softens many plastics. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. secure ignition sources. Operational Problems/ Hazards Product is flammable. practically non-hazardous. although irritation may be caused. Vapor when inhaled in sufficient concentrations any be harmful to nervous system, lungs and kidney, but is not normally encountered in such concentrations as vapor pressure is low. Should vapor irritate then safe concentrations have been exceeded Product should be kept dry and shipper may require Nitrogen blanket. Clear lines with Nitrogen. Personnel Protection Chemical protective clothing , goggles, gloves and breathing apparatus. Secure accommodation and re-circulate air. during all operations. Vapor return system : Possible Tank Cleaning

cold sea water pre-wash to remove residues, Ventilate to gas free ( alternatively inert tank) Warm was water wash, minimum 3 hours, Ventilate Steam tank and line, Ventilate Educt and mop Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYL ACETATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Acetic acid, ethyl ester;acetic ester; acetic ether,ethyl ethanoate; Vinegar naphtha. : 1173 : ETA : CH3COOC2H6 : Colorless liquid; pleasant fruity odor : 77C/ 171 F : -83C/ -117F : 0.90 : Ester :* :D :D : 3.27 :D : 4.5 : 8.7% : 3.04 : Ships lines to deck or center tanks, or portable lines to droplines : NO : Purge : Possible Blanket : Probably : Stainless steel, some Zinc and polyurethane but with restrictions.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Ethyl acetate is highly flammable and its vapors form explosive mixture with air. flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) : 24(cc)

Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

: 2.2~ 11.5 % : 800 : CO2, alcohol foam, water fog, dry chemical.

Special fire Procedures : Use of dry chemical where it can get into a tank of ethyl acetate is not recommended. Fire involving spills outside of tanks can be extinguished with dry chemical. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 100 PEL/TWA(ppm) : 400 TLV/TWA(ppm) : 400 General : Vapor cause some irritation. Absorption is chiefly by inhalation. continued skin contact will dry and crack skin with chance of dermatitis and infection. Symptoms: Headache, irritation of respiratory passages and eyes. Short Exposure Tolerance: 100 ppm for 5 minutes. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops; apply artificial respiration skin or eye contact- remove contaminated clothing and gently flushed with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Stable will hydrolyze(react with water) on standing to form acetic acid and ethyl alcohol. This reaction is greatly accelerated by bases(alkalis). Can react vigorously with oxidizing materials Compatibility: Material: softens and dissolves rubber and many plastics. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield. protective clothing. have all purpose canister mask available. avoid contact with liquid. secure ignition sources. remarks: Vapor pressure : 100 mmHg at 27C.

Operational Problems/Hazards Product is flammable Liquid and vapor cause irritation and may cause defatting Product can hydrolyse to form ethanol and acetic acid. However process is slow and unlikely during carriage Product must be kept dry and Nitrogen may be required also vent line desiccator. Keep way from adjacent heat. Clear lines with Nitrogen. Personnel Protection Chemical protective clothing , goggles, gloves Breathing apparatus. Tank Cleaning If a coated tank check coating guide as residues may have to be ventilated dry prior to washing Cold sea water wash ( Explosive range is for 20 C) for minimum 3 hour. Ventilate to gas free and odor free. Steam tank and lines Ventilate - Educt and mop Tank may require further ventilation to disperse odor or for coating control prior to ballast or next cargo. Tank must be absolutely dry. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system.

The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYL ACRYLATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Acrylic acid, ethyl ester; ethyl propenoate Ethyl2-propenoate; 2-propenoic acid, ethyl ester. : 1917 : EAC 2 2 5 : CH =CHCOOC H : Colorless liquid ;pungent odor : 99C/ 211 F : -39C/ -103 F : 0.93 : Acrylate : 29.3 :D :A : 1.4 :O : 2.0 : 1.5% : 3.5 : Ships lines to deck/center tanks : YES : Purge : Possible Blanket : YES : Stainless steel, Exceptionally Zinc or Epoxy, but with restrictions.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General: Ignited by heat, sparks, or open flame. flashback along vapor trail may occur, vapor may explode if ignited in an enclosed area. fire may cause violent rupture of tank. toxic and irritating vapors generated when heated. Flash Point (F) : 60(cc); 48F (TCC) Flammable Limits : 1.8 ~ 9.5 % (calculated) Auto igniting Temp.(F) : 700 Extinguishing Agents : CO2, dry chemical, water fog, alcohol foam. Special fire Procedures : Keep tank cool with a water spray to prevent polymerization. wear chemical protective clothing, eye protection and self contained breathing apparatus. Health Hazard Data Health hazard Rating Odor Threshold(ppm)

: 3,2,3 : 0.00047

PEL/TWA(ppm) : 5/skin TLV/TWA(ppm) :5 General : Suspected carcinogen, vapor irritating. Symptoms : Eye and throat irritation, shortness of breath, and convulsions. Short Exposure Tolerance: 50 ppm for 15 min. 2000 ppm vapor killed rats in 4 hours with death attributable to severe pulmonary irritation. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Will polymerize spontaneously if not inhaled. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 14 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing, all purpose canister mask available. avoid contact with liquid. secure ignition sources. Operational Problems/ Hazards Product in flammable. Liquid can be harmful and vapor irritating. Contact can dull ability to detect vapor. Product can polymerize when heated, giving off toxic Fumes; also in contact with heat or light. Keep away from adjacent heat. Nitrogen blanket and/or vent line desiccator may be required Product reacts dangerously with several other families Check ICS Guide 100/5 Rust may also affect polymerization possibilities. Personnel Protection Total Protection suit , Breathing apparatus Use Closed Ullaging system Secure accommodation and re-circulate air during all operation. Restrict personnel on deck. Vapor return System : YES Tank Cleaning Tank should be gas freed or inerted if possible ,Cold sea water wash for minimum 3 hours Ventilate to gas and odor free, Steaming may be required to disperse odor Fresh water rinse, Educt and mop Tank may require further ventilation prior to next cargo Tank must be dry Odor is very persistent and most Authorities have stringent regulations on vapor control. Some shippers object to Nitrogen on quality control Check Locally Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining.

Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : : : : Aminoethane; ethylamine, anhydrous; Monoethylamine 1036 EAM 3 2 2 CH CH NH Colorless liquid or gas strong ammonia like odor. 17C/ 62 F -81C/ -114F 0.80 Amine 880 B C 29.8 O 40.8 Complete 1.55 Ships lines to center /deck tanks NO Purge : Possible Blanket : YES Stainless Steel

Fire & Explosion Hazard Data Grade-A : Flammable liquid Electrical Group :C General: Toxic oxides of nitrogen may form in fire. dangerous. keep away from heat and open flame flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : Less than 0 3.5~ 14.0% 725 Alcohol foam, carbon dioxide, or dry chemical. Keep burning tank and tanks adjacent to it cool with a water spray.

Health Hazard Data Health hazard Rating : 3,2,3 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Direct contact can cause burns. Symptoms : Liquid causes eye injury and skin irritation. short Exposure Tolerance : Unavailable. Exposure Procedure : In case of contact with eyes or skin, immediately flush with plenty of water for at least 15 min. for eyes get medical attention. Remove contaminated clothing and shoes at once. Reactivity Data Stability: Stable. Compatibility: Material : Steel, stainless steel, and nickel are compatible. aluminum and copper should not be used. Cargo : Group 7 of compatibility chart. See also Appendix 1 -Exceptions to the chart.

Spill or Leak Procedure If possible, wear butyl rubber gloves, face shield or all purpose canister respirator, and protective clothing. Secure ignition sources. cover with sodium bisulfate. clean up. do not flush spill into confined spaces where flammable vapors can accumulate. Operational Problems/ Hazards Product is highly flammable Liquid and vapor harmful, cause severe burns Product shipped in aqueous solution. Check data locally according to dilution. Vapor heavier than air and will layer at deck or lowest levels in still air . Clear lines with Nitrogen. Nitrogen blanket and/or vent line desiccator may be required Employ Closed Ullaging. Personnel Protection Total protection suit, Breathing apparatus. Secure accommodation and re-circulate air during all operation Restrict personnel on deck. Vapor return System : YES Tank Cleaning Cold sea water pre-wash, minimum 2 hours, to remove all residues Ventilate to gas free ( or inert tanks) Warm sea water wash, 5 ft half- hour drops ( Check LEL) Ventilate to gas and odor free Thoroughly steam tank and lines Ventilate Educt and mop Tank must be dry and grease free. Note : Amines absorb water very rapidly Ensure vacuum does not form in tank while washing. Solutions; Maximum is 70% in our vessels. Be sure to check S.G and boiling point. Handling:- Because of low boil/flash points. Flush deck with sea water on warm days climate. It will reduce evaporation and make carrying safer. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration.

All of the cargoes can be cleaned using only water and all can be considered as good last cargoes.
Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases.

Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ETHYL AMYL KETONE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage : E.A.K, 5-Methyl-3-Heptanone : 2271 : TBA 3 2 2 4 3 : CH CH CO (CH ) CH : : Mixture : Clear colorless liquid with sharp pungent odor. : 0.819 to 0.824 C : TBA : Ambient

Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : :

Ambient Ambient May react with oxides and acids Check other cargo. Portable lines to droplines . NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel or zinc some epoxy or polyurethane, with restrictions

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 25 ppm Flash point : 59 C Draeger Tube No. : CH229 Acetone 100/b Boiling Point : N/A C Explosive Range : % to % Freeze Point : below 0 C Autoignition Point : C Operational Problems/Hazardous Product is toxic and flammable, Liquid and vapor cause irritation, Vent line desiccator may be required. Personnel Protection; Chemical protective clothing, goggles, gloves, breathing apparatus. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO Discharge on passage as per regulation Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

NIL

Gas free or inerted tank, Warm sea water wash ( Minimum 3 hours) Ventilate, Fresh water rinse Educt and mop dry. Tank must be grease free B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin.

Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLBENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling : : : : : : : : : : : : : : : : : : EB; Ethylbenzol, phenylethane 1175 ETB C6H5C2H5 Colorless liquid; aromatic odor 136C/ 277 F -95C/ -136 F 0.87 Aromatic hydrocarbon 15.3 C C* 0.4 D,O 0.6 Negligible 3.66 Portable lines to droplines or ships lines to center/ deck tanks.

Inhibitor Nitrogen Tank Coating

: NO : Purge : NO Blanket : NO : Stainless Steel, Zinc, Epoxy, Polyurethane with restrictions

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Irritating vapors are generated when heated. vapors may travel considerable distances from a source in a flammable concentration. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 59 1.0~6.7% 810 CO2, dry chemical, foam, water fog.

Special fire Procedures : fight in the same manner as any grade C petroleum fire. firefighter should wear self contained breathing apparatus, protective clothing and eye protection. Health Hazard Data Health hazard Rating : 2,2,2 Odor Threshold(ppm) : 140 PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Vapors-cause eye irritation, Dizziness, narcosis(paralysis). burns of the skin, sensation of chest construction. irritation of respiratory tract, conjunctivitis, dermatitis. exfoliation of large patches of skin and chapped appliance result. Symptoms: Irritation to eyes and throat, dizziness and a feeling of chest construction. Short Exposure Tolerance: 200 ppm for 30min. 1000 ppm irritates skin and mucous membranes. 2000 ppm extremely irritating. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : Rubber in prolonged exposure to Ethylbenzene first swell, then softens. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. avoid contact with liquid. secure ignition sources. remarks: *Pollution category C Oil -like 33 CFR 151.49. Operational Problems/ Hazards Product if flammable, Liquid and vapor cause irritation and information Personnel Protection Chemical protective clothing, gloves, goggles, Breathing apparatus

Tank Cleaning Cold sea water pre-wash to remove residues Ventilate to gas and odor free ( Alternatively inert tank or Educt residues and gas free) Some coatings require ventilation to dryness prior to washing Warm sea water wash, 5 ft half hour drops (Check LEL) Ventilate, Thoroughly steam tank and lines, Ventilate - Educt and mop Do not confuse this product with Benzene and its associated health hazards. 64/66 - Ventilate tank for 24 hours after discharge Good cargo - small problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from

area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLCYCLOHEXANE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : C2 H5 C6 H11 : : : Colorless liquid . : 0.788 @ 20C : : : : : : : : : : TBA Ambient Ambient Ambient

NO (Ensure Certificate obtained and Duration Checked) Purge Blanket : Most Coating suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : 35 C Draeger Tube No. : Boiling Point : 132C Explosive Range : 0.9% to 6.6% Freeze Point : -111 C Autoignition Point : 200 C Operational Problems/Hazardous Product is highly flammable Stow away from adjacent.

Personnel Protection; Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Discharge on passage as per regulation Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides

ETHYLENE CHLOROHYRIN
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating 2-chlorethanol; 2-chloroethanol; 2-chloroethyl alcohol; Ethylene chlorhydrin; Glycol chlorohydrin : 1135 : ECH : CICH2CH2OH : Colorless liquid; faint alcohol-ether-like odor. : 128C/ 262F : -69C/ -92 F : 1.21 : Alcohol : * : :C :+ :O : 0.44 : Complete : 2.78 : Ships lines to center deck tanks. : NO : Purge : Possible Blanket : Possible : Stainless Steel

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General: Moderate fire hazard when exposed to heat or flame. dangerous; when heated to decomposition, emits highly toxic fumes of phosgene. Flash Point (F) : 140 Flammable Limits : 4.9~ 15.9% Auto igniting Temp.(F) : 797 Extinguishing Agents : Water, Co2, alcohol foam and dry chemical Special fire Procedures :

Wear self contained breathing apparatus and full protective clothing. cool exposed tanks with water. Health Hazard Data Health hazard Rating : 3,2,0 Odor Threshold(ppm) : High PEL/TWA(ppm) : 1/skin TLV/TWA(ppm) : 1/skin General : Little margin of safety between early reversible symptoms and fatal intoxication. fatal amounts may be absorbed by skin. Symptoms: Vapor- causes nausea, vomiting, vertigo, in coordination, numbness. Short Exposure Tolerance: Absorption by inhalation or skin may cause death. Inhalation- 240ppm lethal to rats in four hours. Human fatally at 350 ppm for two and half hours. Exposure Procedure : Vapor- remove victim from vapor and administer oxygen if available. administer artificial respiration if necessary. if swallowed, induce vomiting. Call a doctor. Reactivity Data Stability: Dangerously decomposes at high temperatures. Compatibility: Material : Steel is satisfactory. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear neoprene gloves, plastic protective clothing and self contained breathing apparatus. provide good ventilation. secure all ignition sources. Wash skin immediately with water. remarks: Vapor pressure : 6.8 mmHg at 25 C + Unavailable. Operational Problems/ Hazards Product is flammable, Liquid and vapor poisonous At high concentrations vapor will penetrate some rubbers Check suit compatibility, Odor is not easily detectable and there is no satisfactory warning of vapors. Nitrogen blanket and/or vent line desiccator may be required Clear lines with Nitrogen Employ Closed system. Personnel Protection Total Protection suit and breathing apparatus, Secure accommodation and recirculate air during all operations Restrict personnel on deck. Vapor return System : Possible Tank Cleaning Cold sea water pre-wash to remove all residues, Hot sea water wash with chemical injection Ventilate to gas and odor free, Thoroughly steam tank and line Ventilate - Extensive ventilation will be required, Educt and mop Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution.

Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature delayed; keep victim under observation.

ETHYLENE CYANOHYDRIN
Synonyms 2-cyanoethanol; glycol cyanohydrin; hydracrylonitrile; 1-hydroxy-2-cyanoethane; 3-hydroxypropanenitrile, 2-hydroxypropionitrile; beta-hydroxypropionitrile. : ++ : ETC 2 2 : HOCH CH CN : Straw colored liquid not unpleasant odor. : 227C/ 440 F : -46C/ -50 F : 1.04 : Alcohol : V.Low : :D :" :O :" : Complete : 2.45 : Ships lines to center/deck line : NO : Purge : Possible Blanket : Possible : Stainless steel some Epoxy and Zinc but with restrictions.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : When heated, ethylene cyanohydrin gives off poisonous fumes of cyanides. Reacts with water to produce cyanide gas, which is highly poisonous and flammable vapor. Flash Point (F) : 265 Flammable Limits : 2.3~ 12.1% Auto igniting Temp.(F) : 922 Extinguishing Agents : CO2, Dry chemical, Alcohol foam. Special fire Procedures : Firefighters should wear self contained breathing apparatus and full protective clothing. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms short Exposure Tolerance

: : : : : : :

0,0,2 Unavailable. Unavailable " Toxic by ingestion, avoid high vapor concentrations. Headache, dizziness, blueness of lips and fingernails. Unavailable.

Exposure Procedure : If Ingested, induce vomiting at once; vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eyes contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. See Medical kit Information, Appendix B Reactivity Data

Stability: Avid basic contamination to prevent polymerization. stable or prolonged storage. Reacts with water. Reacts vigorously with oxidizing materials, chlorsulfonic acid, oleum, sodium hydroxide, sulfuric acid. Compatibility: Material : Corrosive to mild steel Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Avoid all contact with liquid or vapor. Wear rubber gloves, face shield, full protective clothing. secure ignition sources. flood with copious amounts of water. Operational Problems/ Hazards Product is flammable, Liquid and vapor are toxic, causing cyanide poisoning Product must be kept dry. Contact with water or steam causes dangerous reaction. Keep away from adjacent heat, Clear lines with Nitrogen. Nitrogen blanket may be required for safety/ quality control. Personnel Protection Total Protection suit and breathing apparatus, Restrict personnel on deck Secure accommodation and recirculate air during all operations Vapor Return System: YES Tank Cleaning Cold sea water wash, minimum 3 hours, to remove and dilute, Hot sea water wash, 5 ft half hour drops Thoroughly steam tank and line, Ventilate for at least 24 hours to ensure vapor dispersed Educt and mop, Tank must be dry. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

ETHYLENE DIAMINE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : 1-2 Diaminoethane, 1-2 Ethanediamine 1604 2 H2 N CH2 CH2 NH2 105

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Amine (Aliphatic ) : Colorless liquid with ammonia -like unpleasant odor. Liquid may fine. : 0.900@ C : : : : : : 0.00094 12-38 C 20-38 C 12-38 C 7 Reacts with oxides, acids, aldehydes, allyl chloride and acrylonitrile. Will discolor in air at excessive temperatures. Check other cargoes. : Ships lines to deck center tanks : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : YES : Stainless Steel , Some Zinc with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 10 ppm Flash point : 34 C Draeger Tube No. 67184 : Triethylamine 5/a Boiling Point : 115C Explosive Range : 4% to 20 % Freeze Point : 11 C Autoignition Point : 400 C Operational Problems/Hazardous Product is highly flammable, Liquid and vapor highly corrosive and liquid will cause serious burns. Heating instructions may vary with shipper . Check locally . Nitrogen blanket and/or vent line desiccator may be required to exclude air. Clear lines with Nitrogen, Use Closed Ullaging systems. Do not expose product to temperatures in excess of 38C, Do not rely on odor to warm of gas concentrations. Personnel Protection; Total protection suit, breathing apparatus Secure accommodation and recirculate air and restrict personnel on deck during all operations. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage as per regulation Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Complete Drying oil : NO

Cold sea water wash for minimum 3 hours, Ventilate to gas and odor free Thoroughly steam tank and line, Ventilate Educt and mop NOTE: It may be necessary to pre-wash tank using water at 20C to 30C to remove residues Amines absorb water very rapidly Ensure vacuum does not form while washing tank B) Cleaning to : (Beyond Solvent Standard) Product is susceptible to : Smell/Moisture/Rust/chlorides

Personnel with asthmatic tendencies should be kept away from this product Destroy contaminated leather gloves or footwear Wear contamination will lower the freezing point of the product Heating - In cold areas apply heat 70 -80 F. M.S if color of no consequence M.S-O.K Handling - Avoid contact with liquid . Use gloves and protective clothing . No other problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.
HEALTH HAZARDS Poison; extremely hazardous May be fatal if inhaled or absorbed through skin. Initial odor may be irritating, foul or absent and may deaden your dense of smell. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials are extremely flammable. May be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Cylinder may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural Firefighters protective clothing is not effective for these materials isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find The ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Cool container with water using unmanned device until well after fire is out. Isolate area until gas has dispersed. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Shutoff ignition sources; no flares, smoking or flames in hazard area. Use water spray to reduce vapor; do not put water directly on leak or spill Area. Isolate area until gas has dispersed. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Keep victim quiet and maintain normal body temperature Effect may be delayed; Keep victim under observation.

ETHYLENE DIBROMIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No. Bromofume,1,2-dibromoethane; sym-Dibromoethane; EDB; Ethane, 1,2-dibromo; ethylene bromide; glycol dibromide : 1605 : EDB 2 2 : BrCH CH Br : Colorless liquid; sweet odor : 131C/ 268 F : 8C/ 48 F : 2.17@ 60F : Halogenated hydrocarbon : 9.0 :X :B : 0.4 :O : 0.7 : Slight : 6.5 : Ships lines to center deck tanks : NO : Purge : Possible Blanket : YES : Stainless Steel some Zinc but restricted. : CH244 Trichloroethylene 10/a

Fire & Explosion Hazard Data Grade: N/A Electrical Group :D General : Ethylene dibromide is difficulty flammable. Dangerous, when heated to decomposition, it emits highly toxic fumes of bromides. Flash Point (F) : None. Flammable Limits : None Auto igniting Temp.(F) : 960 Extinguishing Agents : Water spray, dry chemical, foam or CO2. Special fire Procedures : Fire fighters should wear full-protective clothing and respiratory protection. Health Hazard Data Health hazard Rating : 1,1,3 Odor Threshold(ppm) : 22 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : Skin General : Suspected carcinogen. prolonged contact with skin should be avoided. Toxic by inhalation, skin contact and ingestion. Symptoms : Blistering of skin; destruction of tissue. Short Exposure Tolerance: 200 ppm for one hour; 500 ppm for several minutes might be fatal. Exposure Procedure : Contaminated shoes and clothing should be removed at once and the skin should be thoroughly cleaned with soap and water. if eyes are accidentally contaminated they should be flushed thoroughly with flowing water for 15 min. A physician should be consulted. Reactivity Data

Stability: Stable. has no oxidizing or polymerization characteristics will not react with air, water vapor, fresh or salt water at temp. below 115F. Compatibility: Reacts vigorously with aluminum and magnesium. No appreciable attack on steel, wood, or cloth. Softens and deteriorates rubber and paint. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, protective clothing. wash away with water. Operational Problems/ Hazards Product non-flammable, Liquid and vapor can cause injury Heating instructions will vary. Normally carried ambient unless climatic conditions require heating to keep product above freezing point. Vapor may Layer in tank bottom and deck Separate pump and line , and individual vent line required Due to high SG tanks may only be filled to 47% volumes. Deck tanks also limited. Personnel Protection Total protection suit and breathing apparatus. Secure accommodation and recirculate air during all operations. Vapor Return System : YES Tank Cleaning Thoroughly pre-wash with cold sea water to remove residues. Warm sea water wash, minimum 3 hours, with chemical injection Ventilate to gas and odor free, Thoroughly steam tank and lines Ventilate ( May be prolonged to ensure vapor dispersed) Educt and mop, Tank Must be dry. NOTE : Although non-flammable, product may certain ethylene, creating explosive vapor above product level. Excessive heat may produce explosive conditions. When vapor is detectable , toxic conditions exist. S.GR:- Check elevation to shore tank- booster pump might be needed. Vessels with piston pumps- unsuitable . Deepwell pump are O.K Handling - Avoid vapor avoid contact. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C ) Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ETHYLENE DICHLORIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity 1,2-dichloroethane;sym-dichloroethane; Dutch liquid; Dutch oil; ethane,1,2-dichloroethylene chloride; glycol dichloride : 1184 : EDC 2 2 : CICH CH CI : Colorless oily liquid; chloroform like odor. : 84C/ 183 F : -36C/ -33 F : 1.26

Chemical Family : Halogenated hydrocarbon Vapor Pressure(20C) :* Pollution Category USEPA :B IMO :B Reid Vapor Pressure(psia) : 2.7 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 4.0 Solubility in water : Slight Vapor Density(air = 1.0) : 3.42 Handling : Ships lines to deck center tanks portable lines to droplines with caution Inhibitor : NO Nitrogen : Purge : Possible Blanket : Probably Tank Coating : Stainless Steel, Zinc, and polyurethane with restrictions , Epoxy not generally Acceptable. Draeger Tube No : CH244 Trichloriethylene 10/a Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General: The vapors are irritating. In contact with a hot surface. ethylene dichloride decomposes into phosgene, which is highly poisonous. Ignited by heat, sparks or open flame. Flash Point (F) : 65 Flammable Limits : 6.2~ 16% Auto igniting Temp.(F) : 775 Extinguishing Agents : CO2, Dry chemical, foam, water fog. Special fire Procedures : Keep exposed tanks cool with water spray. Water may be ineffected on fire. Supply respiratory protection and full protective clothing for fire parties. Health Hazard Data Health hazard Rating : 2,2,3 Odor Threshold(ppm) : 200* PEL/TWA(ppm) :1 TLV/TWA(ppm) : 10 General : Suspected carcinogen. Vapor harmful; causes systemic poisoning through inhalation. Liquid contact with on skin may cause dermatitis or a burn. Toxic by inhalation, skin contact and ingestion. Symptoms: Irritation, dizziness, nausea, rapid pulse, blueness of lips and fingernails. Short Exposure Tolerance: 200 ppm for one hour. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration . skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. * NOTE: Detectable odor is greater than the TLV. Exposure to potentially dangerous vapor concentration can occur before the vapor is detected by smell. Reactivity Data Stability: Relatively stable. Compatibility: Material : Non- corrosive at normal atmospheric temp. when dry. when contaminated with water at elevated temp. it corrosive iron. Cargo : Group 36 of compatibility chart. Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus, protective clothing. avoid contact with liquid . Secure ignition sources. remarks: Vapor pressure: 100 mmHg @ 29.4 C. Operational Problems/ Hazards Product if flammable ,Liquid and vapor harmful and vapor is toxic Many port authorities insist on vapor return and stringent operational precautions. Nitrogen blanket and/or vent line desiccator may be required Keep away from adjacent heat Use Closed Ullaging system, Clear lines with Nitrogen Vapor caused irritation occurs after dangerous high concentrations have been exceeded. Personnel Protection Total protection suit and breathing apparatus Secure accommodation and recirculate air and restrict personnel on deck during all operations. Vapor Return system : YES Tank Cleaning Check coating for ventilation to dryness prior to washing Cold sea water pre-wash to remove residues, Ventilate to gas/ odor free, Hot sea water wash, minimum 3 hours ( Check LEL), Ventilate, Steam tank and line, Educt and mop Ventilate for 24 hors prior to ballast next cargo if zinc /polyurethane Tank must be absolutely dry. If product impure it will attack Epoxy coatings. Ensure that linings other than stainless steel have been cleared as acceptable. Acid content of product may vary with some coatings product temperature must not exceed 25C and must have no water content. Phenolic- After 6 months in our service having carried heated cargoes. Coating O.K. When coating is improperly applied it will blister in all areas where coatings exceeds 20 mils(500 MIC) Handling - very strict tank inspection prior to loading . Use protective clothing and face mask when working around this cargo. DO NOT INHALE VAPOR !. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will

provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLENE GLYCOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor 1,2-Dihydroxyethane; 1,2-Ethanediol; ethylene alcohol; Ethylene dihydrate; glycol; glycol alcohol; Monoethylene glycol : ++ : EGL 2 2 : HOCH CH OH : Colorless, Syrupy liquid; Slight odor. : 197C/ 387F. : -12C/ 10 F . : 1.13 : Glycol : 0.05 : :D : 0.008 :D : 0.01 : Complete : 2.21 : Portable lines to droplines : NO

Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: Purge : Possible Blanket : Probable : Any coating, but some restrictions

: : : : : : : :

Combustible liquid D Slight hazard when exposed to heat or flame. 240 LEL=3.2% UEL= Unavailable 775 (antifreeze grade); 752(pure) CO2, Dry chemical, Alcohol foam, Water fog. Water may be ineffective on fire. cool fire exposed tanks with water.

Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 50 General : Relatively non-toxic unless ingested. If ingested, serious injury or death may result from as little as 60 ml (approx. 2 OZ) Symptoms: Headache, nausea, and dizziness. Short Exposure Tolerance: Inhalation is no hazard at normal room temp. Exposure Procedure : Ingestion; induce vomiting and call a physician. Never give fluids or induce vomiting if victim is unconscious or having convulsions. skin and eyes; flush with water for 10 Min. Reactivity Data Stability: Stable. Compatibility: Material : most materials of construction are suitable. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. avoid contact with liquid. remarks: Data are for the "pure" grade, not the "anti-freeze" grade. ++ Unassigned Operational Problems/ Hazards Shipper may require Nitrogen blanket and/or vent line desiccator for quality control. Lines should be cleared with Nitrogen Product can be corrosive to metals, Surveyors will be particular about coating condition. Shipped in two grades :- commercial and fiber grade. IG is very high specification and require high standard of cleanliness. Stow away from pungent cargoes and adjacent heat The liquid will cause irritation of the eyes and skin But ingestion may be fatal. Personnel Protection Boiler suit, gloves and goggles, Breathing apparatus on standby Steps should be taken to avoid Ingestion Tank Cleaning Hot seawater wash, 5 ft half hour drops, Ventilate to gas free Fresh water rinse or steam, Educt and mop. * Alternatively; Lot of fresh water flushing and steaming.

Requires high standard of cleanliness Tank should be completely dry and grease free. Fiber grade of this product is known as polyester Ethylene Glycol (P.E.E.G) in some areas (USG). Requires high coating/ cleanliness standard. Methanol spray and bulkhead tests for chlorides/hydrocarbons recommended prior to survey. SG may vary slightly. Fiber Grade/Zinc;- This fine grade will pick up Zinc. especially in warm climate No GO . zinc coating are O.K. for all other grade. MS;- Hard to get past surveyor for loading. Handling - All grades need good tanks, but it is the fiber grade that needs special attention. Use nitrogen for this grades. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

ETHYLENE GLYCOL BUTYL ETHER

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Nitrogen Tank coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits 2-butyl ethanol; Butyl cellosolve, Butyl oxitol; Dowanol EB; ektasolve EB solvent, ethanol, 2-butoxy: 2369 : EGM 2 2 4 9 : HOCH CH OC H : Colorless oily liquid; Mild rancid odor. : 171C/ 340 F : -87C/ -125 F : 0.90 : Glycol ether : 0.76 : : III : 2.2 :D : 3.2 : Complete : 4.07 : Bondstrand , compoflex and ships lines : Purge : NO Blanket : NO : Stainless Steel , Zinc and Epoxy with restrictions.

: : : : :

Combustible liquid C Moderate hazard, when exposed to heat or flame. 141(cc) 1.1~ 10.6%

Auto igniting Temp.(F) : 472 Extinguishing Agents : Water, alcohol foam, carbon dioxide or dry chemical. Special fire Procedures : The same techniques used for fighting fire involving combustible petroleum products are applicable. Cool fire exposed tanks with water. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Eye and respiratory tract irritation, narcosis, blood, kidney, and to a lesser degree liver damage can be produced in animals from a single or repeated exposures at concentrations less than saturation. Symptoms Short Exposure Tolerance Exposure Procedure : Eye, nose, and throat irritation. : 200 ppm for approx. one hour. : prevent repeated skin contact by wearing protective clothing.

Reactivity Data Stability: In general, an inert solvent. Compatibility: Material : compatible with usual materials of construction. Plastic materials and rubber are not recommended. Cargo : Group 40 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. avoid personnel contact with liquid and vapor. Secure all sources of ignition. Operational Problems/ Hazards Slightly irritating to skin and eyes, Combustible Low toxicity. Personnel Protection Chemical suit, gloves and goggles Tank Cleaning Note: Tank must be educted and ventilated to dry before washing or steaming. Check coating guide. Hot sea water wash, Ventilate Fresh water rinse, Educt and mop, Ventilate 24 hours if Epoxy tank. Mild steel- An excellent MS tank is suitable for both these Glycol Ethers, but shippers request lined tank, most of the time. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is

difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLENE GLYCOL MONOBUTYL ETHER ACTATE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : Butyl Cellosolve Acetate. TBA 3 C4 H9 OCH2 CH2 OOC CH3 110 Ester/Ester ( Aliphatic) Clear colorless liquid with pleasant fruity odor. 0.9424@20 C

: : : : : : : : : :

TBA Ambient Ambient Ambient 34 May react with oxidizing agents. Check other cargo. Ships lines or portable line to droplines NO(Ensure Certificate obtained and Duration Checked) Purge NO Blanket : POSSIBLE ANY COATING, Subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 150 ppm Flash point : 88 C Draeger Tube No. : Boiling Point : 192C Explosive Range : Freeze Point : -63C Autoignition Point : C Operational Problems/Hazardous Product virtually non-hazards, Product must be dry. Vent line desiccator may be required. Personnel Protection; Boiler suit , goggles , gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO Discharge on passage as per regulation

Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Slight

Drying oil : NO

Hot sea water wash for minimum 3 hours with chemical injection, Ventilate to gas and odor free Thoroughly steam tank and line, Ventilate, Educt and mop NOTE : In some coatings it may necessary to ventilate prior to washing Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

ETHYLENE GLYCOL ETHYL ETHER

Synonyms Cellosolve solvent; dowanol EE;EE solvent Ethanol,2-ethoxy-; 2-ethoxyethanol; ethylene glycol monoethyl ether, Glycol monoethy ether : 1171 : EGE 3 2 2 2 : CH CH OCH CH OH : Colorless liquid; ether like odor practically odorless. : 135C/ 275F : -76C/ -94 F : 0.93 : Glycol ethers : 4.0 :C :D : 0.1 :D : 0.17 : Complete : 3.1 : Portable lines to droplines or ships lines to center/deck tanks. : NO : Purge : NO Blanket : Possible : Stainless steel, zinc , Limited polyurethane and Epoxy.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 120 Flammable Limits : 1.7 ~15.6% Auto igniting Temp.(F) : 460 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : The same techniques used for fighting fire involving combustible petroleum products are applicable. cool fire exposed tanks with water. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms

: : : : : :

1,1,2 Unavailable Unavailable 5/skin Low hazard for acute inhalation; moderate for chronic inhalation. Headache , nausea, eye irritation.

Short Exposure Tolerance: Exposure to air saturated with cellosolve vapor(0.6%) for a few seconds resulted in irritation of the eyes.

Exposure Procedure : Vapor- remove victim to fresh air; breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: This is relatively stable compound Compatibility: Material : softens rubber and many plastics. avoid aluminum and its alloys. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. avoid contact with liquid. secure ignition sources. Operational Problems /Hazards Product if flammable, Liquid and vapor highly irritation and liquid is easily absorbed. Nitrogen blanket and/or vent line desiccator may be required for quality control. Keep away from adjacent heat. Coatings may soften with this product Product is susceptible to contamination and high standard tank cleaning and coating and coating required. Personnel protection Chemical protective clothing gloves and goggles Tank Cleaning Note : Check coating list before washing Hot sea water wash for minimum 2.5 hours ( Check LEL) Ventilate to gas and odor free Fresh water rinse Educt and mop NOTE : Ventilate for 24 hours after cargo- before ballasting or next cargo . With some coating this product must be educted and the coating dried by ventilation, before washing the tank. Mild steel - If scale free and well cleaned- O.K. Handling - Nitrogen blanket recommended for all slack loaded tanks. Good Cargo- Small problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION

Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLENE GLYCOL METHYL ETHER

Synonyms IMO No Dowanol EM; ethanol,2-methoxy; glycol monomethyl ether, 2-methoxyethanol; methyl cellosolve; methyl oxitol : 1188

CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : : : : : : : : : : : : : :

EME 3 2 2 CH OCH CH OH Colorless liquid, mild agreeable odor. 124C/ 255 F -85C/ -121 F 0.97 Glycol ether 6.2 D 0.39 D 0.6 Complete 2.62 Portable lines to droplines or ships lines to center /lines NO Purge : NO Blanket : Possible Stainless steel, Zinc, Epoxy and Polyurethane subject to restrictions

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 115(cc) Flammable Limits : 2.5 ~ 19.8% Auto igniting Temp.(F) : 551 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : The same techniques used for fighting fires involving combustible petroleum products are applicable. Cool fire exposed tanks with water. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 0.9 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : 5/skin General : Harmful vapor; liquid absorption through the skin may be harmful. Symptoms : Drowsiness, confusion, loss of metal ability, headache. Short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove the victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity data Stability: This is a relatively stable compound Compatibility: Material : softens many plastics. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. secure ignition sources. Operational Problems/ hazards

Product is flammable and liquid and vapor will cause irritation. Liquid on skin may cause dermatitis Nitrogen blanket and/or vent line desiccator may be required for quality control. Product is susceptible to moisture , rust and excessive heat. Surveyor will be particular about coating condition Personnel Protection Chemical protective clothing, goggles and gloves. Tank Cleaning Note : Check coating list before washing Hot sea water wash for 2.5 hours minimum ( Check LEL) Ventilate to gas and odor free Fresh water rinse Educt and mop Note : Ventilation for 24 hours may be required before ballast or next cargo. With some coatings product must be educted and coating dried by ventilation before washing tank. Trade marks ; UCC- Methyl cellosive, UCC- Jet Fuel Additive Shell- Methyl Oxitol Mild Steel- It is next to impossible even for a short voyage to arrive with product ON-Spec. Handling - This is the most Sensitive of all Glycol Ethers we carry. Tank and lines must be cleaned to perfection. No other problems/ Hazards. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ETHYLENE GLYCOL MONO PHENYL ETHER

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling : : : : : : : : : : : : : : : 2- Phenoxyethanol, Phenyl cellosolve TBA TBA 6 5 2 2 C H OCH CH OH Phenolic Ether Colorless liquid with faint aromatic odor. 1.1094 @20 C TBA Ambient Ambient Ambient

Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO :

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 171 C Draeger Tube No. : Boiling Point : 244C Explosive Range : % to % Freeze Point : 14C Autoignition Point : C Operational Problems/Hazardous In climate regions may require gentle heat to prevent freezing but obtain local information as regards heating instructions. Personnel Protection;

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Discharge on passage as per regulation Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Partials Drying oil : NO

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

ETHYLENEIMINE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : Azacyclopropane, Aziridene, Dimethylenimine. 1185 3 NHCH2 CH2 112 Amine. Colorless oily liquid with a sharp pungent ammonia - like odor. 0.8320@20 C

: TBA : : : :

Reactivity: Highly reactive with groups and specific families. No USCG grouping Slops separately and obtain advice for stowage and pumping.

Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : :

Ships lines or portable line to droplines YES (Ensure Certificate obtained and Duration Checked) Purge POSSIBLE Blanket : YES Stainless Steel, some Zinc with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 2 ppm TLV 0.5 ppm Flash point : -11 C Draeger Tube No. : CH318 Hydrazine 0.25/a Boiling Point : 57C Explosive Range : 3.6% to 54% Freeze Point : -78C Autoignition Point : 322 C Operational Problems/Hazardous Product is Flammable, Liquid and vapor highly toxic Product highly reactive, Information very scarce and advice should be sought locally. Nitrogen blanket required ( Will discolor in contact with air) Keep away from adjacent heat ( Inhibitor may degrade) Clear line with Nitrogen Use Closed Ullaging system Personnel Protection; Total Protection suit and breathing apparatus Secure accommodation and recirculate air and restrict personnel on deck during all operations. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : YES Retain on board , well -diluted, and discharge on passage as per regulations. Keep separate. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO

(A) Cleaning from Solubility in water : Complete Cold sea water pre-wash to remove residues Ventilate to gas free ( or inert) Hot sea water wash, 5 ft half hour drops Ventilate to gas and odor free, Steam tank and lines, Ventilate Educt and mop Tank must be dry Note : Amines absorb water very rapidly . Ensure vacuum does not form in tanks while washing.
HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Extremely flammable; May be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical Protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no

thermal protection. Structural Firefighters protective clothing is not effective for these materials Isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE FIRE 2 Small Fires: Dry chemical or Co , water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

2-ETHYL HEXANOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Alcohol C-8; 2-ethyl-1-hexanol; 2-ethylhexyl alcohol; Octanol; octyl alcohol : ++ : EHX 3 2 3 2 5 2 : CH (CH ) CH(C H )CH OH : Colorless, Slightly viscous liquid Alcoholic odor. : 183C/ 362 F : < -76c/ < -105 F : 0.83 : Alcohol : 0.36 : : : 0.01 : D,O : 0.015 : Slight : 4.5 : Portable lines to droplines or ships lines to deck center tanks. : NO : Purge : NO Blanket : NO : ANY COATING

: : : : : : : :

Combustible liquid D Moderate hazard, when exposed to heat or flame. 179 Unavailable 581 Alcohol foam, CO2, Dry chemical, water spray Cool exposed tanks with water.

Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Practically non-hazardous. slight effect from absorption of liquid through skin. Symptoms : Mild skin irritation. Short Exposure Tolerance : Not pertinent Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing. Flush affected areas gently with water for 15 min. 20~30 min. for eye contact. Get medical attention. Reactivity Data Stability: Will undergo self reaction if contaminated. does not require stabilizer. Compatibility:

Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. Operational Problems / Hazards Product is flammable, otherwise practically non-hazards Liquid and vapor may cause temporary irritation Odor is detectable before dangerous concentrations reached Nitrogen blanket and/or vent line desiccator may be required for quality control. Clear lines with nitrogen Due low vapor pressure beware Gas Layer in tank bottom. Personnel Protection Boiler suit , goggles, gloves Tank Cleaning Warm sea water wash with chemical injection, minimum 3 hours (check gas concentration) Ventilate to gas and odor Steaming may be required to disperse odor. Ventilate Educt and mop. Tank to be dry and grease free. Mild Steel - Celanece reject M.S tanks - others accept a good tank. Handling - See No big problem, It is the odor deodorize with polycomplex or Nil-odor. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

2 ETHYL HEXYL ACETATE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family : : : : : : Octyl Acetate, B-Ethyl Hexyl Acetate. TBA TBA 3 2 2 5 4 9 CH COOCH CHC H C H Unknown ( but Possibly an Ester)

Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Water white liquid. : 0.8733 @20 C : : : : : : : : : : TBA

Reacts with Oxidizing agents acids and alkalis. Portable lines to drop lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible Stainless Steel, or zinc.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 82 C Draeger Tube No. : Boiling Point : 198 C Explosive Range : Freeze Point : -93C Autoignition Point : C Operational Problems/Hazardous Product is slightly toxic and an irritant to skin and eyes. Stow away from adjacent heat. Clear lines with Nitrogen Usually a high spec. cargo. Personnel Protection; Chemical protective clothing, gloves goggles, B/A on standby . Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : YES Discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

NIL

Coating may required ventilation to dryness before washing. Cold sea water wash, minimum 2.5 hours Ventilate to gas free. F.W rinse , Educt and mop Prolonged ventilation may be required as odor may persist. USCG- Stow as Octyl Acetate which is listed. Use Nitrogen Blanket for slack tanks. Good cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product.

Wash water temperature Code (D)Ambient water followed by warm water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

2-ETHYLHEXYL ACRYLATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA Acrylic acid, 2-ethylhexyl ester; 2-ethylhexyl, 2-propenoate; Octyl acrylate : ++ : EAI 2 2 2 2 5 4 9 : CH =CHCO CH CH(C H )C H : Colorless liquid pleasant odor : 215~218C/ 418~425 F : -85C/ -130 F : 0.89 : Acrylate : 0.1 :

IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Cleaning

: : : : : : : : : :

B 0.01 O 0.015 Negligible 6.35 Portable lines to drop lines or ships lines to center deck tanks. YES Purge : NO Blanket : Possible Stainless Steel, Epoxy, Polyurethane some restrictions.

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General: Moderate hazard, when exposed to heat or flame; will polymerize on heating. Flash Point (F) : 188(cc) Flammable Limits : LEL = 0.8% UEL=6.4% Auto igniting Temp.(F) : 485 Extinguishing Agents : Dry chemical, CO2, foam, water. Special fire Procedures : Water or foam may cause frothing. cool exposed tanks with water. Health Hazard Data Health hazard Rating : 0,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid irritating to skin on contact Symptoms : Skin irritation. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. Skin or eyes contact- remove contaminated clothing and gently flush with water. Reactivity Data Stability Compatibility: Material : Non- corrosive to carbon steel.

: Unstable; polymerize easily unless inhibited.

Spill or Leak Procedure If possible, wear rubber gloves, face shield, and protective clothing. have all purpose canister mask available. secure ignition sources. flush away with water. Operational Problems /Hazards Product is flammable Liquid and vapor cause irritation and can be absorbed via skin. TLV is not internationally accepted. Product shipped inhibited and can polymerize in contact with excessive heat ( Which degrades inhibitor) or water which will dilute inhibitor. Nitrogen blanket and/or vent line desiccator may be required. clear lines with Nitrogen. Personnel Protection Chemical protective clothing, goggles, gloves, breathing apparatus. Use Closed ullaging system.

Vapor return system : Possible Tank Cleaning Cold sea water pre-wash ( to remove residues and inhibitor) Hot sea water wash, minimum 3 hours, with chemical injection Ventilate to gag and odor free Fresh water rinse Educt and mop ( Steaming may be required to disperse odor ) Tank must be dry Note : 2EHA is the term generally used for this product. However some authorities use it to describe 2 Ethyl Hexyl Alcohol or 2 Ethyl Hexyl Acetate. Ensure, if 2EHA is encountered, that actual product is clarified. Mild Steel- From the takes MS tanks have been accepted from the US.GULF -NO. Handling - This product is O.K. no problems noted. A good clean/dry tank and lines will do. Reacts dangerously with oxidizing agents and acids can react if water or air degrades inhibitor Check other cargo. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided.

2 ETHYL 3 PROPYL ACROLEIN

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : 2-Ethylhexenal. TBA 3 3 7 2 5 C H CH : C(C H )CH0 Aldehyde Yellow liquid with strong pungent odor. 0.8518@20 C TBA Ambient Ambient 19 Reacts with Oxidizing agents NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible

Subject to coating compatibility Lists Consult USCG Compatibility Chart

Odor threshold Flash point Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: : 68 C : CH264 Formaldehyde 0.002 : 79C : : C : C

Operational Problems/Hazardous Product is flammable, Keep away from adjacent heat. Moderately Toxic causing irritation of skin eyes and respiratory tract. Personnel Protection; Chemical protective clothing, gloves goggles, B/A on standby . Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : YES Discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NIL

Drying oil : NO

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

EUCALYPTUS OIL
Synonyms : Eucalyptol, Cineol, Cajeputol. IMO No : N/A IMO TYPE :3 10 18 Formula :C H O ICS Guide Page No. : 19 Family : Unessential oil. Appearance and character : Colorless or faintly yellow oil with aromatic odor which is pungent and spicy. Specific Gravity : 0.905-0.925@20 C Heating Range (Subject to Chart.Reg.) Correction factor : TBA Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : N/A Reactivity : Moderately combustible. Handling : No specialized handling regulation. Portable lines to drop lines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Stainless Steel, Epoxy , Polyurethane. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV ppm Flash point : C Draeger Tube No. :

Boiling Point Explosive Range Freeze Point Autoignition Point

: C : : -15.4C : C

Operational Problems/Hazardous Moderately toxic vapors Some shippers may require product heated for discharge - check locally. Vent line desiccator may be required, High standard of coating required. Personnel Protection; Boiler suit, normal working gear gloves goggles, B/A on standby . Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :TBA Vapor Return System Reg. : YES Discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight Hot salt water wash, minimum 3 hours, with chemical injection Ventilate to gas/odor free.If require dispersed, thoroughly steam tank and line Ventilate, Educt and mop Note : Further steaming or ventilation may required to disperse odor. Due to fact slightly soluble in water, therefore alcohol type foam may be required for fire fighting.

FISH OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character oil. Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : See Remarks. N/A 3 N/A 19 Ester Pale yellow/dark red, with characteristic odor, dependent on quality of

: 0.92@15 C : : : : : : : : : : 0.00068 Ambient 27-32 C 20-30 C 34 Basically non-hazardous. NO specialized handling requirements. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Polyurethane, Epoxy, Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : C Autoignition Point : C

Operational Problems/Hazardous Can remove or exclude oxygen from tanks, therefore before entry into tank oxygen content to be checked and maintained. May require sweeping subject to charterers requirements To be at discharge temperature 10 days prior to discharge Daily maximum rise of temperature permissible is 3C/day May require food grade tank dependent on quality of oil May be subject to spontaneous heating SG may vary with shipper. Personnel Protection; Boiler suit , normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : YES Discharge on passage as per regulation. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Pre-wash with cold salt water , minimum 2 hour to remove residues , immediately following discharge Hot salt water wash, minimum 3 hours, with chemical injection Spot clean as required Fresh water rinse, Educt and mop. The following come under the general title of Fish Oils: Pilchard, sardine, herring, cod, menhaden and Mombunker oil. Heating- In warm climate no heat needed during voyage. For crude grade 95F (35C) is on the low side, winter time in Rotterdam- Try for 40C (104F) . Mild steel- O.K for crude and semi refined Zinc- Semi and fully refined are usually very low RE FFA - but check each time . Handling - Wear masks when squeeze (sweeping). Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 22. These cargoes are drying or semi-drying oils which require cold(ambient) washing immediately after discharging. Drying oil : YES

FORMALDEHYDE SOLUTION (37~50%)

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Check carefully coating lists. Formalin; Formalith, formic aldehyde solution formol; fyde; Methanal solution; methylene oxide; morbicid : 1198 : FMS : HCHO : Colorless liquid; Pungent, Irritating odor. : 97C/ 206 F : : 1.11~1.13 : Aldehyde : 1.39 : :C : 0.09 :O : 0.15 : Complete : 1.03 : Portable lines to droplines : YES : Purge : Possible Blanket : Possibly : Stainless steel , polyurethane with restrictions.

Fire & Explosion Hazard Data Grade-D,E : Combustible liquid (grade depends on concentrations) Electrical Group :B General : When the solution is heated, highly flammable vapors are given off. Flash Point (F) : 122~ 185 Flammable Limits : 7.0~73% (formaldehyde vapor in air) Auto igniting Temp.(F) : 806 Extinguishing Agents : CO2, Dry chemical, Alcohol foam, Water fog. Special fire Procedures : The vapors are highly irritating. so fire parties should wear respiratory protection.

Health Hazard Data Health hazard Rating : 3,2,2 Odor Threshold(ppm) : Below 1 PEL/TWA(ppm) :3 TLV/TWA(ppm) : 1* General : Suspected carcinogen. Major effect is local irritation of eyes, nose, and throat. strong formaldehyde solutions cause a hardening effect and primary skin irritation upon direct contact. Symptoms: Coughing, copious watering of eyes, severe respiratory irritation. Short Exposure Tolerance: At a vapor concentration of 10~20 ppm breathing becomes difficult. exposure to 650 ppm for a few minutes may cause death. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops apply artificial respiration skin or eyes contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Solution are often shipped at elevated temp. to prevent polymer formation. Compatibility: Material : corrosive to steel and to copper and its alloys. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus. protective clothing. avoid contact with liquid. secure ignition sources. if possible, cover large spills with sodium bisulfate (NaHSO3). add small amount of water and mix. scoop up. wash site with soap solution. remarks: The commercial material is shipped as water solution of from about 37~50% concentration. Methanol is often used to inhibit polymerization. *Propose change in TLV to 0.3 ppm. + Unavailable Operational Problems/ hazards Formaldehyde solution tends to form insoluble polymeric compounds, unless inhibited with alcohol. If polymerization does occur it is not usually violent or dangerous. Liquid causes severe burns to eyes and along with vapor is highly irritating. All contact to be avoided . Use full protective clothing and breathing apparatus. Any spillage to be washed away with copious quantities of water. Highly toxic by inhalation and ingestion Fire risk increases with Methanol content As water soluble , use alcohol type foam. Personnel Protection Full chemical protective clothing and Breathing Apparatus. Tank Cleaning Cold sea water wash to remove residues ( 2hours ) (Check coating compatibility when strong slops or discharge directly overboard) Hot sea water wash with chemical injection , 5 ft. half hour drops Ventilate to gas and odor free ( Odor may be difficult to remove ) Educt and mop dry, Tank must be dry USCG - O.K. to 50%, IMO- O.K. to 45% Mild steel - For a short voyage MS is O.K. but iron pick up can be expected. Dont try. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes Wash water temperature Code (D)-

Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

FORMAMIDE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity CHeating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Methanamide TBA 3 2 HCONH

A Colorless Hydroscopic oily liquid. 1.1376@15 0.00085 Normally Ambient Normally Ambient 10.* Ships lines to deck tanks only. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel only.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 20 ppm Flash point : 154 C Draeger Tube No. : TBA Boiling Point : 210-212 C Explosive Range : % to % Freeze Point : 2.5C Autoignition Point : C Operational Problems/Hazardous A moderately toxic and corrosive liquid, therefore avoid all contact. Start to decompose before boiling point is reached emitting very toxic fumes. May require Heating to improve discharge viscosity, check Locally. Personnel Protection; Chemical suit, Gloves, Goggles, B/A set for topping off. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : YES Retain on board slops well diluted. Discharge slops on passage according to regulation. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Hot SW wash with chemical injection ( 1/2 Hr 5 ft drops) Fresh water rinse or steam.

Ventilate to gas and odor free, Educt and mop dry. Tank must be dry USCG- Cleared but un-groped. 10 will do.

FORMIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling However compoflex can be used. Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : Formylic acid; Hydrogencarboxylic acid; Methanoic acid 1779 FMA HCOOH Colorless liquid; Sharp, penetrating 101C/ 213 F 8C/ 47 F 1.22 Organic acid 0.6 D D 1.5 O 2.1 Complete 1.6 Shore hose connected to deck tank manifolds.

: Possible : Purge : YES Blanket : YES : Stainless Steel

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Formic acid is a corrosive, combustible liquid. Toxic vapors are generated in fire. Flash Point (F) : 156(cc) Flammable Limits : 18~57% Auto igniting Temp.(F) : 1114 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Fire fighting parties should wear rubber boots and gauntlets and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 3,3,3 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) :5 TLV/TWA(ppm) :5 General : Natural, slow decomposition yields carbon monoxide(CO), a chemical asphyxiate, and water enclosed spaces must be tested for oxygen content(19.5% Min.) before entering. Vapor irritating. Liquid causes burns. Symptoms: Choking, respiratory irritation, watering of the eyes; skin contact will cause severe itching or burning. Short Exposure Tolerance: Unavailable. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and immediately flush affected areas gently with water for 15 min.

Get medical attention. Use protective clothing to prevent personal contact. Reactivity Data Stability: Reacts will bases(alkalis) to produces heat. It is also a reducing agent. Compatibility: Material : Type 316, stainless steel or lead lined tanks are satisfactory. Cargo : Group 4 of compatibility chart . See also Appendix 1 -Exceptions to the chart. Spill or Leak Procedure Avoid contact with liquid. use respiratory protection and protective clothing. Eliminate all sources of ignition. Cover contaminated surfaces and spill with large quantity of soda ash or sodium bicarbonate. Mix and add water if necessary for good mixing. Scoop up slurry. Wash site with soda ash solution. Operational Problems /Hazards An extreme corrosive, with which all contact should be avoided. Being hydroscopic a vent line desiccator is required. Concentrations of less than 96% are stable, but higher concentrations are unstable and will decompose to give off carbon Monoxide. Although in tanks where P/V valve is working properly a dangerous pressure should not develop. Lines used to load cargo should be flushed with copious after use. Personnel Protection Full protective clothing and breathing apparatus Vapor return System : Possible Tank Cleaning Cold sea water wash ( 2hours) to remove residues (due to incompatibility of coatings to formic acid, slops should preferably be washed over-side or stored in stainless steel) Hot sea water wash, half hour 5 ft . drops, Ventilate to gas and odor free Fresh water rinse or steam, Educt and mop dry Tank must be completely dry and moisture free. Heat - Melt point 47F heat might be needed if in severe cold area. Suggest external heat, if ever needed. carried numbers times - no problems as long as the S.S tank is perfect SUS : 316-317 is rated excellent while 304 is rated Good . Be sure to check steel condition before loading. 1. 2. 3. 4. 5. 6. 7. 8. Wash the tank with ambient temperature seawater for 2 hour. The following must be washed/steamed simultaneously when washing the cargo tank Cargo line, valves, drain cocks and removal of blinds if fitted on valves. Vent line system including P/V valve and riser Heating coils or heat exchanger, cargo pump cofferdam. Restricted gauge pipe, if fitted. Housing for tank level gauging On completion washing fill the tank with sea water until it is overflowing(allow air pockets to escape from B/W hatches. Level the ballast water in the tank for 12 hours and then empty the tank) Mechanically ventilate the tank as follows: 1. Stop the tank ventilation and the tank atmosphere from hatches in the after part and fore part using portable equipment. Provided tests show no traces of formic acid vapors or carbon monoxide, and the oxygen is showing 21%, then the following may be carried out. 2. Before the tank is considered safe to enter a person equipped with self-contained breathing apparatus, and vapor resting equipment should enter the tank for testing. Vapor tests should be taken from pumpwell, all corners of the tank, and any other pocket such as behind web frames where product gases may accumulate. 3. The tank entry can be made according tot he tank entry procedure. 4. At every re-entry, up to the next loading, this tank must be rested for traces of formic acid vapor or carbon monoxide.

HEALTH HAZARDS Contact cause burns to skin and eyes

If inhaled, may be harmful.

Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical or Co2 Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

FURFURAL
Synonyms Ant oil; artificial oil of ants; fural; 2-furaldehyde; 2-furancarbonal; 2-furancarboxaldehyde; furfuran carboxylic aldehyde; Furfurole; pyromucic aldehyde. : 1199 : FFA 4 3 : C H OCHO

UN. No CHris Code Formula

Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

: Colorless to reddish-brown liquid penetrating almond-like odor. : 161C/ 322 F : -37C/ -34 F : 1.20 : Aldehyde : 1.53 :D :C : 0.1 :O : 0.15 : 8.3% : 3.31 Portable lines to droplines compoflex suitable Product NOT recommended for bondstrand. : NO : Purge : Probably Blanket : Probably Stainless Steel, Polyurethane with Restrictions, Consult coating guides

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :C General: Moderate hazard, when exposed to heat or flame. Furfural can explode on contact with strong mineral acids and alkalis(caustics). Irritating vapors are generated with heated. Flash Point (F) : 155 Flammable Limits : 2.1~ 19.3% Auto igniting Temp.(F) : 743 Extinguishing Agents : CO2, Dry chemical, Alcohol foam, Water fog. Special fire Procedures : Wear eye protection, self contained breathing apparatus and protective clothing. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

2,2,3 0.4 2/skin 2/skin

General : Liquid is irritating to skin and eyes on contact. Vapor is respiratory irritant. Symptoms: Irritation of respiratory passages. Short Exposure Tolerance: 15 ppm for 15min. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Furfural can explode on contact with strong mineral acids and alkalis. Reacts with numerous organic materials.

Compatibility: Material : Dissolves or softens many plastics and rubber formulations. Cargo : Group 19 of compatibility chart. Spill or Leak Procedure Wear rubber gloves and protective clothing. Have self contained breathing apparatus available. avoid contact with liquid. small spills may be washed away with water. Cover large spills with sodium bisulfite(NaHSO3). Add small amount of water and mix. Scoop up. Wash site with soap solution. Operational Problems/ Hazards Do not carry at temperature greater than 50 C. Vapor harmful to respiratory system , therefore Avoid Contact. Slightly hygroscopic, therefore may require vent line desiccator. Personnel Protection Goggles, Gloves, Breathing apparatus or chemical suit. Tank Cleaning Cold sea water wash to remove residues ( 2 hours) Hot sea water wash with chemical injection, 5 ft half-hour drop. Fresh water rinse or steam Ventilate to gas and odor free ( smell may be difficult to remove) Educt and mop dry. Tank Must be dry and moisture free. Zinc - From USA the acid content is usually below 0.10% , but from Sugar Cane ( Foreign) it is too high -Check. Handling - The odor from Sugar Cane derived is strong and lingering . Deodorize with cold water- Nil odor or Polycomplex. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 18. These cargoes leave an odor that in very difficult to remove especially in zinc coated tanks. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection.

Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

FURFURYL ALCOHOL
Synonyms 2-furancarbinol; 2-furanmethanol; furfuralcohol; furylcarbinol; 2-furylcarbinol; Alpha-furylcarbinol; 2-furylmethanol; 2-hydroxymethylfuran : 2874 : FAL 4 3 2 : C H OCH OH Colorless amber liquid turning to dark red brown when exposed to light and air. slight brine-like odor. : 171C/ 340 F : -31c/ -24 F : 1.29 : Alcohol :1 : :C : 0.07 : D,O

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter

Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

: 0.1 : Complete : 3.37 Portable lines to deck tanks or poison bank Bondstrand is NOT recommended. : Possibly : Purge : NO Blanket : NO : Stainless Steel, Zinc Silicate with restriction.

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :C General: Slight explosion hazard when exposed to heat or flame. however it will react with explosive violence in contact with mineral acids or their vapors, or with strong organic acids or vapors. Flash Point (F) : 167 Flammable Limits : 1.8~ 16.3% Auto igniting Temp.(F) : 916 Extinguishing Agents : Confined area- Co2, dry chemical. Open area- polar solvent foam, water spray. Special fire Procedures : Wear eye protection, clothing resistant to furfuryl alcohol, respiratory protection. Health Hazard Data Health hazard Rating : 2,1,2 Odor Threshold(ppm) :8 PEL/TWA(ppm) : 10/skin TLV/TWA(ppm) : 10/skin General : Skin absorption may cause toxic effects. Harmful if swallowed. toxic concentrations of vapors may be present at temp. above room temp. Symptoms: Headache, watering eyes, irritated skin. Short Exposure Tolerance: Vapor exposures- Rats show 8 percent mortality after one six hour exposure to 47 ppm and 100 percent mortality at 243 and above. Absorption through skin is very rapid. Exposure Procedure : Eyes-wash with water for 10 min. Remove contaminated clothing and wash. Skin- wash with soap and water. Ingestion- induce vomiting. Inhalation- move to fresh air. Get medical advice or attention. Reactivity Data Stability: Stable. Reactive with organic or mineral acids. Compatibility: Material : do not use near lacquers, vanish, or resins. Can ship in ordinary steel. Cargo : Group 20 of compatibility chart. See also Appendix 1- Exceptions to the chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid Contact with liquid. Secure ignition sources. spill area may be washed with water. remarks: Ground storage drums or tanks to prevent accumulation of static electricity. Operational Problems/ Hazards Very high standard of tank cleanliness required; tank requires complete absence of moisture

A fairly reactive product; segregated stowage advised Vapor and liquid are dangerous - Avoid all contact Wash any spillage away with copious quantities of water. However, stable under normal conditions of sea transport As slightly hygroscopic may require vent line desiccator check local regulations Deteriorates at temperatures above 49 C. Personnel Protection Chemical suit, Breathing apparatus Tank Cleaning Cold sea water wash ( 2 hour ) to remove residues Hot sea water wash, 5 ft. half hour drops, with chemical injection Fresh water rinse or steam Ventilate to gas and odor free ( Smell may be difficult to disperse odor) Educt and mop dry ,Tank must be dry and moisture free. Color-If product is Clear upon loading, Nitrogen Blanket is a must. Pale colored grade can go without Nitro/Blanket. M.Steel- A good scale free MS tank is suitable. Handling - It is a fine Alcohol with no problems if carried in good tanks. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 18. These cargoes leave an odor that in very difficult to remove especially in zinc coated tanks.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

FUSEL OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Grain Oil, Potato Oil, Isobutyl Carbinol : 1201 :3 3 2 2 2 : (CH ) CHCH CH OH : : Alcohol A volative oily mixture of amyl , propyl and ethyl alcohol dependent upon type , which can also contain esters, acids and aldehydes. : 0.813 @C : : : : : : : : : : TBA Normally Ambient Normally Ambient Can react vigorously with reducing agents. Portable lines to drop lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel, Zinc Silicate , Polyurethane

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : TBA ppm TLV 100 ppm Flash point : 43 C Draeger Tube No. : TBA Boiling Point : 132 C Explosive Range : 1/2% to % Freeze Point : 132 C Autoignition Point : 343 C Operational Problems/Hazardous Observe standard procedures for low flash and solvents No specific Operational problems. Personnel Protection; Boiler suit, gloves, goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Discharge slops on passage according to regulation. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

Slight

Cold sea water pre-wash (1 hour) to remove residues. Hot wash with chemical injection , 5 ft half hour drops Ventilate Educt and mop dry. Tank must be dry Used in the preparation of amyl alcohol and for gelatinizing explosives.

Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

GAS OIL
Synonyms IMO No IMO TYPE : Light Industrial Diesel : 1202 :3

Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : Hydrocarbon : Water white to light yellow petroleum distillate. : 0.707 to 0.86 : : : : : : : : : :

Ambient Ambient Ambient Nothing specific Portable line to manifolds or droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel , Epoxy, Polyurethane, Zinc Silicate.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 65 C Draeger Tube No. : TBA Boiling Point : 232-426 C Explosive Range : 6 % to % Freeze Point : C Autoignition Point : 339 C Operational Problems/Hazardous High flash product Avoid degrading flash point Should not have common vent line with low flash products. Personnel Protection; Boiler suit and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Classed as persistent oil. Decanted slops to bunker tanks. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Drying oil : NO

Hot SW wash with chemical injection -5 ft half hour drops Fresh water rinse or steam. Ventilate to gas and odor free, Educt and mop dry. S.G- These are approximate for exact gravity check, Cleaning #2 and marine grades are not good last cargoes for finer chemical , After Butterworthing , tanks appear clean, but some seeping may be show up the next day- Keep checking . Deodorizing of tank is a must . Polycomplex is the best cleaning /deodorizing agent. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier

and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

GENKLENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity : 1,1,1 Trichlooethane Which See : Not listed :3 : ICI Solvent : : Stabilized Trichloroethane : Clear non-flammable solvent. : to

Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : Ambient : Ambient : Ambient : Can reacts with aluminum and its compound, also reactive to Chemical metals., e.g. sodium, potassium. : Portable lines to manifolds or droplines : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Stainless Steel , Epoxy, Polyurethane, Check locally with Surveyors, as product may soften coatings.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 350 ppm Flash point : none C Draeger Tube No. : Boiling Point : 78-81 C Explosive Range : % to % Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Being a solvent, tanks will have to be completely grease-free Low general toxicity, although vapor is anesthetic Avoid inhalation. Observe normal procedures for loading solvents Advisable stow away from heated cargo Personnel Protection; Boiler suit and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Slight Hot wash 5 ft half hour drops, Fresh water rinse or steam. Ventilate to gas and odor free, Educt and mop dry.

GLYCERINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Glycerol;glycyl alcohol;1,2,3-propanetriol Trihydroxypropane; 1,2,3-trihydroxypropane : 2689 : GCR : CH3COCH2COH(CH3)2 : Colorless liquid faint pleasant odor. : 290C/ 554 F : 18C/ 64 F : 1.26 : Ketone/alcohol(exhibits properties of both) : Very Low

Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : : : : : :

III Very Low D D Complete 3.17 Portable lines to droplines may sometimes be splash loaded. NO Purge : NO Blanket : NO Stainless steel , Epoxy, Zinc Silicate with restrictions.

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Slight hazard, when exposed to heat, flame, or powerful oxidizers. Flash Point (F) : 320 Flammable Limits : Unavailable Auto igniting Temp.(F) : 698 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Water may be ineffective on fire. cool exposed tanks with water. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance

: : : : : : :

0,0,0 Odorless 10 mg/m3as a mist 10mg/m3 as a mist Skin contact with liquid causes slight skin irritation. Contact with the liquid can cause skin irritation. No appreciable hazard.

Exposure Procedure : Wash glycerin form skin with water. Launder clothing contaminated by the liquid Reactivity Data Stability: Reacts with strong oxidizing agents. Polymerizes about 300 F Compatibility: Material : No apparent effect on steel or aluminum. Cargo : Group 20 of compatibility chart. See also Appendix 1- exception to the chart. Spill or Leak Procedure secure ignition sources. spill may be washed away with water. remarks: Even a small amount of water or other impurity will greatly lower he freezing point. Operational Problems/ hazards Practically non-hazardous. As product is transparent, tanks and lines must be scrupulously clean. May require heating - check locally. Personnel Protection Boiler suit, gloves and goggles

Tank cleaning Cold sea water wash ( 1hour) to remove residues Hot wash, 5 ft half hour drops Fresh water rinse, or steam Educt and mop dry Tank and line will have to be spotlessly clean Crude - FFA Vary a great deal. It is usually vary high, but check Handling - Same way as tallow no problems. Z-11 : This is an excellent coating for this product, DOW (only) says NO but approve of D-4. Handling - This fine and expensive product needs careful handling Spotless tanks and lines are a must. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (B)Warm water (38 to 55 degree C )

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK

Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

GLYOXAL 40% SOLUTION

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : Ethanedial, Oxalaldehyde. TBA 3 OHCCHO TBA Yellow liquid in aqueous solution. 1.26 @ 20C

: : Ambient : Ambient : Ambient : 19 In pure form polymerizes in the presence of the slightest trace of water. Not normally carried in bulk in pure form at sea. Portable lines to deck or poison bank manifolds , Bondstrand 4000 Epoxy is suitable No information on compoflex - Check locally. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless Steel, Epoxy with restrictions, Check coating compatibility.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : C Draeger Tube No. : Boiling Point : 51C Explosive Range : Freeze Point : 15C Autoignition Point : Operational Problems/Hazardous Very little information - check locally . Moderately toxic by ingestion and inhalation- avoid contact. Personnel Protection; Boiler suit and gloves, goggles, Breathing apparatus on standby. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

YES

Hot wash with chemical injection ,5 ft half hour drops Fresh water rinse or steam. Ventilate to gas and odor free. Educt and mop dry.

Coating - Phenoline O.K. 64/66 - O.K. but tank must be to first class condition with no mild steel showing. A very sensitive cargo. No other problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (B)Warm water (38 to 55 degree C )

GROUNDNUT OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : Peanut Oil, Arachis Oil. N/A 3 N/A 19

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Ester : Yellow or greenish yellow oil. : 0.91to 0.92 : 0.00068 : 15 C : 21-27 C : 21- 27C : 34 : Basically non hazardous. : No specific handling regulation. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Stainless Steel , Epoxy, Polyurethane, Can be carried in zinc silicate if FFA is below 5%.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 315 ppm Flash point : 315 C Draeger Tube No. : Boiling Point : 285 C Explosive Range : Freeze Point : 0C Autoignition Point : C Operational Problems/Hazardous Solidifies at 0 C. May require food grade tanks. Personnel Protection; Boiler suit and gloves., normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

NO

Pre-clean with warm sea water to remove residues. Hot sea water wash minimum 3 hour with chemical injection, spot cleaning as required Fresh water rinse or steam. Ventilate Educt and mop dry. Tank must be dry * Spot cleaning may be extensive depending upon amount of tank structure. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes.

Wash water temperature Code (D)Ambient water followed by warm water

HEPTANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) : : : : : : : : : : : : : Dipropylmethane; n-Heptane;heptyl hydride Normal heptane. 1206 HPT 3 2 5 3 CH (CH ) CH Volatile, Colorless liquid; Sweet gasoline-like odor. 98C/ 208 F -91C/ -132 F 0.68 Saturated hydrocarbon 11.4 C 1.8

Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-C Electrical Group General

: : : : : : : :

D,O 2.5 Negligible 3.45 Compoflex, Bondstrand or ships lines NO Purge : NO Blanket : NO Stainless Steel, Zinc, Epoxy or polyurethane

Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : Fire fighters should have respiratory devices. Keep fire exposed containers cool with water. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms

: Flammable liquid :D Highly flammable, dangerous fire risk. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. : 25(cc) : 1.2 ~6.7% : 433 : Confined area- Co2, dry chemical. open area- foam.

: : : : : :

0,0,1 220 400 400 Moderately toxic by inhalation. irritation of mucous membranes, dizziness, slight nausea, intoxication.

Short Exposure Tolerance: 1000 ppm for 6 minutes developed slight dizziness. 500 ppm for 15 min. results in a condition resembling intoxication by ethyl alcohol. Exposure Procedure : If inhaled in conc. amounts, remove victim to fresh air and use oxygen. if splashed in eyes, wash with water for 15 min. Call a doctor. Reactivity Data Stability: Non- reactive but dangerous fire risk. keep away from heat, sparks, or open flame. Compatibility: Material : Mild steel and stainless steel are suitable. natural rubber will soften and deteriorate rapidly. Cargo : Group 31 of compatibility chart. Spill or Leak Procedure avoid contact with liquid. have all purpose canister masks available. secure ignition sources. Operational Problems / Hazards Flammable and toxic. Should be tank cleaning as Methanol Loading standard with per-inspection for chloride and hydrocarbons. There is little or no problems with this cargo. A well cleaned tank/lines is all thats needed. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system.

The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

1-HEPTANOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Heptan-1-OL, Alcohol C7m n-Heptanol, Hpetyly Alcohol. N/A Chapter VII 3 2 5 2 CH (CH ) CH OH 123 Alcohol ( Primary , aliphatic ) Colorless liquid Fragrant Odor) 0.8424 @ 20C 0.00069 Ambient Ambient Ambient 20 Dangerous reactions with oxidizing agents and mineral acids. Bondstrand, Compoflex or ships lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel , Zinc. Epoxy or polyurethane.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV N/A ppm Flash point : 74 C Draeger Tube No. : CH297 Alcohol 100/a Boiling Point : 176 C Explosive Range : Freeze Point : -35 C Autoignition Point : C Operational Problems/Hazardous No Main hazards. Personnel Protection; Boiler suit and gloves., normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Cold wash Fresh water rinse Educt and mop Drying oil : NO

Negligible

HEPTENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : Heptylene : TBA :3 7 14 :C H : 124 : Hydrocarbon ( Unsaturated, aliphatic) Colorless liquid with a strong pleasant smell rather resembling pine odor. : 0.715 @ 15.56C : : : : :

Ambient Ambient Ambient TBA

Reactivity: Can react with oxidizing agents, also with concentrated nitric acid. Also check other cargoes on data sheet in question. Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : No via portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coating are suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV TBA ppm Flash point : -7 C Draeger Tube No. : CH 312 Olefins 0.05%/a Boiling Point : 85 C - 100C Explosive Range : 1.0% to 7.0 % Freeze Point : -120C Autoignition Point : 263 C Operational Problems/Hazardous It is not hydroscopic and is stable except for slight gum formation, possibly. Acute effect slightly anesthetic resulting in dizziness and drowsiness Shows irritation effect on eyes Is volatile and highly flammable. Personnel Protection; Boiler suit and gloves., Breathing apparatus for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Partial Wash tank in inert or gas free condition Hot salt water wash with chemical injection , 5 ft. half hour drops. Ventilation to gas/ odor free Fresh water rinse or steam Educt and mop dry. Tank must be dry M.Steel - If Last cargoes are animal / Veg oils it is difficult to get tanks past surveyor in Canada. In Philly No problems loading M.S no other problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

HEXAMETHYLENEIMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : : : : Azacyclohelane; hexahydroazepine; homopiperidine 2493 HMI 6 13 CH N Colorless to light yellow liquid ammonia-like-odor. 132C/ 270 F -38C/ -36 F 0.88 Imine 5 C 4.2 O 5.6 Complete + Stainless lines to deck tank manifolds NO Purge : Possible Blanket : Possible Stainless steel deck tanks.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :C General: Toxic oxides of nitrogen may form in fire. Dangerous fire hazard. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.

Flash Point (F) : 62 Flammable Limits :1.6~ 2.3 % Auto igniting Temp.(F) : Unavailable Extinguishing Agents : Water, CO2, Dry chemical. Special fire Procedures : Wear eye protection and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 3,3,3 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid is irritating to the skin and respiratory tract and the vapor causes eye injury high vapor concentration may cause serious eye injury. Symptoms: Eye, skin and respiratory irritation. Short Exposure Tolerance: The approximate lethal vapor concentrations for a four hour exposure is reported to the 4800 ppm in rats. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration. Oxygen, administered trained personnel, is often helpful. skin or eye contact- Immediately flood affected areas gently with water. remove contaminated clothing and continue to flush affected areas for 15 min. Get medical attention. Reactivity Data Stability: Stable. Compatibility: Material : Corrosive copper and its alloys in air; corrodes aluminum especially when wet. removers paint; swells rubber. No effect on carbon steel, wood, cloth. Cargo : Group 7 of compatibility chart. Spill or Leak Procedure Self-contained breathing apparatus of all purpose canister mask should be worn when contact is anticipated. Wear Impervious gloves and safety goggles. keep away from heat, sparks, and open flames; avoid breathing of vapors. flush spill with large quantities of water. secure ignition sources. Operational Problems / Hazards A highly corrosive liquid and vapor - Avoid all contact High vapor concentrations can effect central nervous system Moderate fire hazard Decomposes with heat, giving off ammonia vapors Information at present scanty - check locally Highly reactive cargo. Tanks and line have to be thoroughly clean. Personnel Protection Total protection suit and Breathing apparatus, Restrict personnel on deck Secure accommodation, A/C on Recirculation. Vapor return system : Possibly Tank cleaning Cold se water pre-wash to remove residues ( 2hours) Hot sea water chemical wash, half hour 5 ft drops Fresh water rinse or steam Thoroughly ventilation Educt and mop Tank must be completely clean and dry Check locally with surveyor for more information on product.

React : Incompatible with :acids, oxidizing agents, anhydrides, ketonnes, aldehydes, nitrates, phenols, isocyanates, monomers and chlorinated compounds. Handling - Tanks must be 100% clean and dry before loading Nitrogen blanket is must. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running

water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

n-HEXANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : : : : Hexane; Hexyl hydride; normal hexane 1208 HXA 6 14 CH Colorless watery liquid gasoline like odor. 69C/ 156 F -94C/ -137F 0.66 Saturated hydrocarbon 97.0 C 5.0 D,O 7.0 Insoluble 2.98 Compoflex Bondstrand or ships lines NO Purge : No Blanket : NO Stainless steel , zinc, epoxy or polyurethane.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General: Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : -7.0 Flammable Limits : 1.1~ 7.7% Auto igniting Temp.(F) : 500 Extinguishing Agents : Dry chemical, foam or carbon dioxide. Special fire Procedures : Water may be ineffective on fire. cool fire exposed tanks with water. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General :

: : : :

0,0,1 Unavailable 50 50

Minor skin irritant. irritation caused by vapor inhalation. n-hexane is toxic by ingestion. Symptoms: Inhalation causes irritation of respiratory tract cough and mild depression. aspiration causes severe lung irritating, coughing and pulmonary edema. Ingestion causes nausea, vomiting, swelling of abdomen, headache, and depression. Short Exposure Tolerance: 30,000 ppm vapor concentration causes narcosis of rats in one hour. 0.5% vapor concentration caused distinct dizziness and giddiness of humans in just ten minutes. Exposure Procedure : Vapor- remove from area and administer artificial respiration, if necessary and then oxygen. Eye- wash immediately with copious amounts of water. Ingestion- DO NOT induce vomiting. Get medical attention or advice. Reactivity Data Stability Compatibility: Material : Certain plastics are suitable.

: Stable.

Spill or Leak Procedure Wear rubber gloves, face shield and protective clothing. have all purpose canister mask available Gas leak-keep concentration of gas explosive limits by forced ventilation. Liquid- absorb on paper and discharge paper. secure ignition sources. Operational Problems/ Hazards Fire Hazards Personnel Protection Boiler suit and gloves Tank Cleaning Gas free or inert tank or cold sea water wash to disperse residues. Hot wash Fresh water rinse Educt and mop Commercial shipments may contain as little as 40% of the normal isomer in which case chemical and physical constants will be different from those given above. M.Steel - With no scale and well cleaned - O.K No problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

HEXANOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance Alcohol C-6, Amyl carbinol; 1-hexanol n-hexanol, hexanols, Hexyl alcohol, n-hexyl alcohol, 1-hydroxyhexane; pentylcarbinol : 2282 : HXN : CH3(CH2)4CH2OH : Colorless liquid, mild sweet odor : 157C/ 315F : -52C/ -62 F : 0.82 : Alcohol : <1.0 : :D : 0.75 :D : 1.00 : Slight : 3.52 : Compoflex, Bondstrand or ships lines : NO : Purge : NO Blanket : NO : Stainless Steel, zinc, Epoxy or polyurethane

: : : : : : : :

Combustible liquid D Moderate hazard, when exposed to heat or flame. 140 1.2~ 7.7% (calculated) 559 Carbon dioxide, dry chemical, alcohol foam, water spray. Water may be ineffective on fire.

: : : : : : :

Unavailable Unavailable " " Practically non-toxic. handle as a detergent. Similar to alcohol intoxication. Saturated vapor not fatal.

Exposure Procedure : Vapor- remove victim to fresh air if breathing stops, apply artificial respiration. skin or eye contact - remove contaminated clothing and gently flush affected areas with water for 15 min. Reactivity Data Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. May soften some paints and plastic. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear chemical gloves and goggles. avoid contact with liquid.

secure ignition sources. Operational Problems/ Hazards

Personnel Protection Boiler suit and gloves Tank Cleaning Hot wash ( Check Gas concentration ) Fresh water rinse Educt and mop dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin.

Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

HEXYLENE GLYCOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity 2-methyl-2, 4-pentanediol; trimethyltrimethylene glycol; alpha,alpha, Alpha'-trimethyltrimethylene glycol : : HXG 3 2 2 3 : (CH ) COHCH CHOHCH : Colorless liquid; slight odor. : 196C/ 385 F. : -50C/ -58C : 0.92

Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : : : : : : :

Glycol 0.05 III LOW D 0.01 Complete 4.0 Compoflex, Bondstrand or ships lines NO Purge : No Blanket : Possible Stainless Steel, Zinc, Epoxy or polyurethane.

: : : : : : : :

Combustible liquid D Moderate hazard, when exposed to heat or flame. 205 4.7 ~ 100% Greater than 500 F CO2, dry chemical, alcohol foam, water fog. Water or foam may cause frothing.

Health Hazard Data Health hazard Rating : 1,0,0 Odor Threshold(ppm) : Less than 50 PEL/TWA(ppm) : 25 TLV/TWA(ppm) : 25 General : Vapor irritating to skin and eyes at high concentrations. liquid very irritating to eyes, slightly irritating to skin. Symptoms: Headache, dizziness, nausea, strong local irritating of the eyes, nose, and throat; and respiratory discomfort. Short Exposure Tolerance: 1 ppm for 30 minutes. Exposure Procedure : Remove victim to fresh air, give artificial respiration if necessary. Wash spilled liquid from skin with water. get medical attention if rash develops or if victim has any breathing difficulty. Reactivity Data Stability: Reacts with strong oxidizing agents. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. Operational Problems/ Hazards Hazard to eyes - May cause corneal injury Personnel Protection Boiler suit, gloves and goggles

Tank Cleaning Cold wash Fresh water rinse Educt and mop dry Fine glycol needing good tanks Excellent cargo. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

HYDROCHLORIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) : Chlorohydric acid; Hydrogen chloride; Muriatic acid : 1789 : HCL : HCI(dissolved in water) : Colorless to light yellow liquid irritating, pungent odor. : 110C/ 230 F : -76C/ -105 F :1.01~ 1.21 : Inorganic acid : 212 :D :D : 8.0 :O : 10.5 : Complete : 1.26

Handling Inhibitor Nitrogen Tank Coating

: : : :

Stainless Steel or Bondstrand NO Purge : NO Blanket : NO Stainless Steel Only.

Fire & Explosion Hazard Data Grade: Non-flammable. classified as a corrosive liquid. Electrical Group : B(based upon possible hydrogen gas(H2) generation should a leak occur) General: Hydrochloric acid will not burn. it will react with many metals, giving off hydrogen gas which is highly flammable. If hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See data sheet for hydrogen. toxic and irritating vapors are generated when heated. Flash Point (F) : Non- flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : " Special fire Procedures : Acid tanks exposed to a fire should be closed by a water spray. fire parties must wear respiratory protection in order to avoid breathing acid vapor full protective clothing must also be worn. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

3,3,2 1~5 5* 5*

General : Inhalation of gas results primarily in irritation of upper respiratory passages. Liquid severely irritating to skin and eyes. Symptoms: Where touched by liquid. The skin may tingle or burn. breathing the vapors will cause severe coughing and watering of the eyes. Short Exposure Tolerance: Inhalation of 1500 ppm in air are fatal in a few minutes. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. oxygen, administered by trained personnel, is often helpful. skin or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical advice or attention. Reactivity Data Stability: Reacts with bases( caustic) to generated heat. Compatibility: Material: corrodes many metals, causing the evolution of hydrogen gas. iron and aluminum are corroded readily. Cargo : Group 1 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, self contained breathing apparatus, protective clothing. Have body shield available. secure ignition sources. if possible, cover the contaminated surface and spill with sodium biscaronate or a soda ash, slaked lime mixture(50-50). Mix and add water if necessary to form a slurry. scoop up slurry. wash site with soda ash solution. remarks: PEL and TLV based hydrogen chloride gas.

Operational Problems / Hazards Highly corrosive liquid and vapor Personnel Protection Chemical suit, rubber gloves and goggles, Breathing apparatus available Restrict personnel on deck. Tank Cleaning Cold wash Fresh water rinse Educt and mop dry

HEALTH HAZARDS Contact cause burns to skin and eyes If inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID

Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

HYDROFLUORIC ACID
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Flourhydric Acid 1790 TBA HF 129 Inorganic Acid. Clear, colorless fuming liquid pungent irritating odor. 1.12 to 1.26 Approx. 0.0006 Dependent on concentration Various 1 Highly reactive - see USCG compatibility chart. Stainless steel. NO (Ensure Certificate obtained and Duration Checked) Purge Blanket : Possible Stainless steel only.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV TBA ppm Flash point : Non-flammable Draeger Tube No. : Boiling Point : * 79C Explosive Range : Non flammable Freeze Point : * 42C Autoignition Point : Non flammable Operational Problems/Hazardous Highly corrosive liquid and vapor Vent line desiccators may be required.

Non- flammable, but may give off hydrogen gas in contact with some metals. Personnel Protection; Chemical suit, gloves and goggles, Breathing apparatus available Restrict personnel on deck. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

Complete

Cold wash, Fresh water rinse Educt and mop. Tank must be dry HEALTH HAZARDS Poisonous if inhaled or swallowed. Skin contact poisonous Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause water pollution. FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Some of these materials may ignite combustibles (wood, papor, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection Structural Firefighters protective clothing is not effective for these materials CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small dry spills; Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills; dike liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing Give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

2- HYDROXY ETHYL ACRYLAE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : HEA TBA 2 Complex 14 Acrylates Light yellow to water white. 1.11 @15.56C

Ambient Ambient Ambient 14 Can polymerize in contact with air, light and other contaminants. Very clean very dry ship lines to stainless steel poison bank/deck tanks. YES(Ensure Certificate obtained and Duration Checked) Purge YES Blanket : YES Stainless Steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV TBA ppm Flash point : + 93 C Draeger Tube No. : Boiling Point : 76 C Explosive Range : % to % Freeze Point : -60C Autoignition Point : TBA C Operational Problems/Hazardous Always shipped with an inhibitor- however can still polymerize under influence of light Liquid corrosive to tissues - vapor highly toxic-Avoid all contact Vent line desiccators may be required - check locally. Personnel Protection; Chemical suit, gloves and goggles Breathing apparatus for topping off and P/R work. Check protection Suit compatible with Product

Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : Possible Retain on board, well diluted Discharge on passage according to control regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Cold pre-wash ( 2 hour) Hot wash with chemical injection - 5 ft. half hour drops Fresh water rinse or thorough steam. Ventilate to gas and odor free. Educt and mop dry. Tank and lines must be absolutely clean and dry. A functional monomer for the manufacture of thermosetting acrylic resins. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided.

ISO

AMYL ACETATE
: : : : : : : : : : : : : : : : : : Banana Oil, Pear Oil 1104 TBA 3 2 2 3 2 CH COOCH CH CH(CH ) 15 Ester( Aliphatic) Colorless liquid with a Banana or pear -like odor. 0.876 @ 15.56C 0.00096 Ambient Ambient Ambient 34 Dangerous reaction with oxidizing agents and concentrated Nitric acid. Complex, Bondstrand or ships lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel, Epoxy, Polyurethane, zinc not recommended.

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 10 ppm TLV 100 ppm Flash point : 25 C Draeger Tube No. : CH 202 Ethyl Acetate 200/a Boiling Point : 142C Explosive Range : 1.0% to 7.5% Freeze Point : - 70C Autoignition Point : 379C Operational Problems/Hazardous Moderate fire hazard Avoid exposure of skin or eyes to liquid Personnel Protection; Chemical protective clothing, gloves and goggles Breathing apparatus. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO

(A) Cleaning from Solubility in water : Slightly Cold salt water wash. Ensure all residues removed and pump and line thoroughly flushed. Ventilate to gas and odor free., Educt and mop ( NOTE : Steaming may be required to remove odor.) FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ISO BUTANOL
Synonyms Iso Butyl Alcohol, 1-Hydroymethyl propane, 2- Methyl propanol-1, Iso-Propylcarbinol : 1212 :3 : (CH3)2 CH: CH2 OH : 27 : Hydrocarbon ( Unsaturated, aliphatic) : Clear and colorless with a sweet odor. : 0.8058@ 15.C

IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : 0.00076 Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 20 Reactivity : Dangerous with oxides, acids halogens and phosphorus. Handling : Portable deck lines to droplines or ships lines to deck/ poison tanks. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chatters Reg. ) : Purge NO Blanket : Possible Tank Coating recommended : Any coating , subject to coating guides. However, Epoxy Zinc and polyurethane coatings require 24 hours ventilation after discharge/ cleaning. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 50 ppm Flash point : 25 C Draeger Tube No. : CH 297 Alcohol 100/a Boiling Point : 108 C Explosive Range : 1.7% to 11 % Freeze Point : -107C Autoignition Point : 427C Operational Problems/Hazardous Liquid on skin causes defatting and is irritating in eyes. Vapor can cause dermatitis , particularly on fingers and nails. Desiccators may be required in event lines. Personnel Protection; Protective clothing , gloves and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Retain on board until next passage Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Partial Hot salt water wash, 5 ft half-hour drops. Ventilate to gas/ odor free Drying oil : NO

Thoroughly steam out tank and lines ( to neutralize chlorides) Fresh water rinse Educt and mop dry. Evaporating residues is not sufficient to clean tank. MS- Exxon does not accept MS tanks - others do. 64/66- coating is O.K. at ambient temperature, but soften with adjacent heat - avoid - good cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

HEPTENE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

: : : : : : : :

Acetic acid Isobutyl Ester, Beta methyl propylenethanoate. 1213 3 4 9 3 C H OOCCH 33 Aliphatic Ester Colorless liquid with a Fruit like odor. 0.8685@ 15.56C

: 0.00103 : Ambient : Ambient : Ambient : 34 Dangerous reactions possible with oxidizing agents and concentrated nitric acid. : Compoflex and ships lines. : NO (Ensure Certificate obtained and Duration Checked) : Purge Blanket : Possible : Stainless Steel or polyurethane Limitations on zinc and Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 150 ppm Flash point : 18 C Draeger Tube No. : CH 202 Ethyl Acetate 200/a Boiling Point : 116C Explosive Range : 2.0% to 15% Freeze Point : - 99 C Autoignition Point : 423 C Operational Problems/Hazardous Fire risk, Moderate toxic, Susceptible to moisture May require vent line desiccator. Personnel Protection; Boiler suit and gloves., Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

Slight

Gas free or inert or cold SW wash to disperse residues Hot wash ( Check LEL) Fresh water rinse, Educt and mop dry 64/66 /Heat - There must be no heat adjacent if this coating in use. Ventilate /dry tank for 24 hours after discharge. No other problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible.

These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ISO BUTYL ACRYLATE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : 2- Methylpropyl Acrylate 2527 2 3 2 2 (CH ) CHCH OOCCH : CH 14

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

: Ester ( Acrylate) : Clear colorless liquid with sweet pungent odor. : 0.8824@15.56C : 0.00094 : Ambient : Ambient : Ambient : 14 Will react with acids and oxides. May react with water and heat Check other cargo. : Compoflex or ships lines to center/ deck tanks. : YES(Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Possible : Stainless Steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 10 ppm Flash point : 30 C Draeger Tube No. : Boiling Point : 85 C - 100C Explosive Range : 1.8% to 8.0 % Freeze Point : - 61C Autoignition Point : 340C Operational Problems/Hazardous Product highly flammable Liquid and vapor harmful, particularly to eyes and membranes . Keep away from adjacent heat, as inhibitor may degrade May polymerize in contact with excessive heat or moisture Nitrogen blanket and/or vent line desiccator required Clear lines with Nitrogen Use Closed ullaging system. Personnel Protection; Chemical protective clothing, goggles, gloves Breathing Apparatus Secure accommodation and recirculate air during all operations. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B

Vapor Return System Reg. : YES Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

Slight

Cold sea water pre-wash to flush system, disperse residues and inhibitor. Hot salt water wash, minimum 2.5 hours. Check LEL Ventilation to gas/ odor free Extensive ventilation may be required as odor is persistent Steam tank and lines Ventilate Educt and mop dry.

Tank must be dry, grease free and coating in good condition Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

ISO BUTYL AMINE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling : : : : : : : : : : : : : : : 1214 2 3 2 2 2 (CH ) CHCH NH Amines. Colorless Amine odor. 0.7377@ 15.C 0.00094 Ambient Ambient Ambient 7 May reacts with acids and alkalis check other cargo. Compoflex and ships lines. Normally to center or deck tanks.

Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

: NO (Ensure Certificate obtained and Duration Checked) : Purge Blanket : Possible : Normally Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV ppm Flash point : -9 C Draeger Tube No. : 67184 Triethyllamine 5/a Boiling Point : 66C Explosive Range : % to % Freeze Point : - 84C Autoignition Point : N/A 378 C Operational Problems/Hazardous Dangerous fire risk. Highly toxic and irritant to skin and harmful to eyes. Strongly caustic. Personnel Protection; Chemical protective clothing, Breathing apparatus Gloves Secure accommodation and recirculate air during all operation. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Discharge to sea on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Partial Drying oil : NO

Gas free or inert prior to washing. Alternatively cold sea water wash tank to disperse residues Ventilate to as and odor free Warm sea water wash ( Minimum 3 hours) Ventilate, F.W rinse Educt and mop. NOTE: Amines absorb water rapidly and care should be taken to allow tank to breath while washing - to prevent vacuum forming. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural

firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ISO BUTYRALDEHYDE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : Iso butyl Aldehyde, 2- Methyl propanol 2045 3 (CH3)2 CHCHO Aldehyde A transparent, colorless, highly flammable liquid with a pungent odour. 0.7945@ 20C

: : Ambient : Ambient : Ambient : 19 Forms isobutric acid in contact with air, can also polymerize in contact with concentrated inorganic acids and alkalis. : Compoflex hoses , or shore lines to deck tank manifolds. : NO (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : YES : Stainless Steel

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV TBA ppm Flash point : - 40 C Draeger Tube No. :

Boiling Point Explosive Range Freeze Point Autoignition Point

: 65 C : % to : - 66C : 254 C

Operational Problems/Hazardous Stow away from heated cargo,. Highly toxic, and irritant to skin and eyes . Avoid all contact. Use Closed loading system for ullaging. Personnel protection; Chemical protective clothing, Breathing apparatus. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : NO Gas free or inert or cold SW wash to disperse residues Hot wash ( Check LEL) Fresh water rinse, Educt and mop dry Cleaning ;- Butterworth tank immediately after discharge. Handling ;- Product must be carried under nitro pos. pressure. No problems ever reported. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ISO DECANOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Iso Decyl Alcohol, IDA. TBA 3 10 21 C H OH 59 Alcohol A Colorless liquid with a characteristic odor. 0.84 @ 15C 0.00072 Ambient Ambient Ambient 20 Basically stable. Possible reaction with oxidizing agents. Portable lines to manifold or droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel or polyurethane, zinc and Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 36 C Draeger Tube No. : 6730202 Petroleum Hydrocarbon 5 Boiling Point : 220 C Explosive Range : Freeze Point : - 76 C Autoignition Point : C Operational Problems/Hazardous Practically non-toxic, although avoid contact with eyes Possible electrostatic generation, therefore lines should be blown with Nitrogen.

Personnel Protection; Boiler suit and gloves., normal working , gear goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO Discharge on passage to sea according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : TBA

NO

Warm sea water with chemical injection - 5 ft. half hour drops Ventilate to gas/ odor free Fresh water rinse or steam Educt and mop dry Tank must be dry (C10) Color - product discolor Use a good coated tank HEAT ADJ : Try in every avoid heat adjacent . Good cargo no problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

ISODECYL METHACRYLATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : TBA 2 3 10 21 (CH ) (CH ) C: COOC H

A light yellow to brown clear liquid with a very light acidic odor. 0.878@ C

Ambient Ambient Ambient Reacts with Oxidizing and reducing agents otherwise basically stable. Portable lines to deck tank manifolds. YES(Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Stainless Steel at present . More information requested.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 125 C Draeger Tube No. : Boiling Point : 126C Explosive Range : Slight % to % Freeze Point : - 42C Autoignition Point : C Operational Problems/Hazardous Polymerization can occur when elevated temps, therefore stow away from heated cargo. Tanks must be dry and moisture free. May be loaded through a drier and also may require a vent line dessicator, check locally, slight toxic and irritating effects of vapor and liquid. Personnel Protection; Boiler suit and gloves, goggles Check protection Suit compatible with Product Pollution Guide

IMO pollution Rating :

TBA

Vapor Return System Reg. : YES Retain slops on board well diluted. Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : very Slight Cold SW wash to remove residues (1.5 hrs), Hot wash with chemical injection (.5 hrs 5ft drops) Fresh water rinse or steam, Ventilate to gas and odor free Educt and mop dry. Tank must be completely dry.

ISO DODECANE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Penta Methyl Heptone 2286

Hydrocarbon (Synthetic) Clear Colorless liquid with no odor . 0.75 @20 C TBA Ambient Ambient Ambient 31 May react with acids . Check other cargo. Portable lines to droplines . Lines must be dry. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Any Coatings.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 44 C Draeger Tube No. : Boiling Point : 175C Explosive Range : 0.6% to 5% Freeze Point : - 70C Autoignition Point : C Operational Problems/Hazardous Product is flammable. Product generally non-hazardous, although liquid and vapor may cause irritation, particularly to the eyes. Tanks and line must be dry. Vent line desiccator may be requested. Personnel Protection; Boiler suit and gloves, goggles Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO

Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Partial. Gas free or inert tank Hot sea water wash ( Minimum 2 hours) check L.E.L Ventilate to gas/ odor free. Thoroughly steam tank and line Ventilate Educt and mop Tank to be dry USCG : Stow as dodecane Handling : This is a very clean product Needing good tanks and clean/dry and lines. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

Drying oil : NO

FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is difficult, give

iso-OCTYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating Draeger Tube No. Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Alcohol C-8, diethyl-1-hexanol; Isooctanol; Isooctyl alcohol; 6-methyl-1-heptanol; octanal; iso-octanol; oxooctyl alcohol. : : IOA 7 5 2 : C H CH OH : Clear liquid, mild odor. : 171C/ 339 F : -105C/ -157 : 0.83 : Alcohol : 3.06 : :C : 0.02 : D,O : 0.03 : Negligible : 4.5 : Load through portable lines and droplines. : NO : Purge : NO Blanket : NO : Any coatings : CH297

: : : : : : : :

Combustible liquid D Moderate fire hazard if exposed to heat or flame. 180 0.9~ 5.7% 530 Confined area- Co2, dry chemical, Open- foam. Use water to cool fire exposed tanks.

Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 50/skin TLV/TWA(ppm) : 50/skin General : Low toxicity; irritation of skin and mucous membranes. Symptoms : Irritates skin and eyes. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air. Skin or eye contact- remove contaminated clothing and gently flushed affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data

Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. See also Appendix 1-Exceptions to the chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. avoid contact with liquid. secure ignition sources. Operational problems/ Hazards Portable lines should be flushed out as soon as possible. Personnel Protection Boiler suit, gloves and goggles Breathing apparatus standby Tank Cleaning Cold salt water wash for 2 hours ( or inert ) gas free Hot salt water wash - 5 ft. half hour drops Ventilate to gas free Steam tank line and pump Educt and mop Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

ISOPHORONE

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Cleaning Draeger Tube No Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : : : : : : : : : : : : : : : :

Isoacetophenone; 3,5,5-trimethyl-2-cyclohexene-1-one IPH 3 2 3 2 2 C(O)CHC(CH )CH C(CH ) CH Water white liquid; peppermint odor. 215C/ 419 F -8C/ 17 F 0.93 Ketone 0.3 D D Low D Low Slight 4.75 Load via portable lines to droplines, or ships lines to poison tanks. NO Purge : NO Blanket : NO Stainless steel, polyurethane, Zinc, or Epoxy subject to limitations. CH229 Acetone 100/b

: : : : : : : :

Combustible liquid D Moderate fire hazard when exposed to heat or flame. 184 0.84~3.8 % 860 Water spray, carbon dioxide, dry chemical or foam. Use water spray to disperse vapors, water may be used to flush spills.

Health Hazard Data Health hazard Rating : 2,2,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) :4 TLV/TWA(ppm) :5 General : Highly toxic, strong irritation to skin and eyes. Symptoms : Eye, nose, and throat irritation, narcosis. Short Exposure Tolerance: 25 ppm is an irritant most humans. Animal tests resulted in eye injury and slight skin irritation after 24 hours; inhalation killed 1 of 6 animals in 8 hours. Exposure Procedure : Remove victim to fresh air and use oxygen. flush eyes for 15 min. with water wash off skin. Get medical help. Reactivity Data Stability: Stable. Compatibility: Material : steel is satisfactory. Cargo : Group 18 of compatibility chart. See also appendix 1- exception to the chart. Spill or Leak Procedure

Wear rubber gloves, face shield, and protective clothing. Secure ignition sources. have all purpose canister mask available. Keep unprotected personnel upwind. flush spill with water. Operational Problems/ Hazards The odor is first detectable at 21.5 ppm , but most subjects will cease to be aware of the odor at 25 ppm after continued exposure. Adequate warning is therefore NOT GIVEN before harmful concentrations are reached. Liquid and vapor will irritate both skin and eyes Inhalation of vapor will have a narcotic effect Considered one of the most toxic of the Ketone family. Personnel Protection Chemical protection suit, gloves and Breathing apparatus. Tank Cleaning Ventilate to gas free, or wash/ inert Hot sea water wash, 5 ft. half drops Steam out tanks , lines and pumps. Ventilate to gas and odor free Educt and mop Vapor Return system : Possible M. Steel : A perfect tanks should be used. Handling : Nitrogen blanket should be applied to all tanks This is Ketone is not a compliance cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

ISOPAR M SOLVENT C,E,G,H,K,L,M

SECTION 1. Product Identification & Emergency Information Product Name : ISOPAR M SOLVENT Chemical Name : Not Applicable: Blend CAS 64742-47-8 Chemical Family : Synthetic Isoparaffinic Hydrocarbon Product Description : Clear colorless liquid Emergency Telephone Number : EXXON CHEMIAL America 800-726-2015 CHEMTREC 800-424-9300

Section 2. Hazardous ingredient Information This Product is hazardous as defined in 29 CFR1910.1200 OSHA HAZARD Combustible for additional information see Section 3. Section 3 Health Information & Protection Eye Contact : Slight irritating but does not injure eye tissue. Skin Contact : Frequently or prolonged contact may irritate and cause dermatitis. Low odder of toxicity. skin contact may aggravate an existing dermatitis condition. Inhalation: High vapor/aerosol concentrations (greater than approximately 700ppm. attainable at elevated temperatures well above ambient) are irritating to the eyes and the respiratory tract. and may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects, including death. Ingestion : Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchopneumonia or pulmonary edema. Minimal toxicity. First aid Eye Contact: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. Skin Contact: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. Inhalation: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. Ingestion: If swallowed, Do Not induce vomiting. Keep at rest. Get prompt medical attention. workplace exposure limits EXXON RECOMMENDS THE FOLLOWING OCCUPATIONAL EXPOSURE LIMITS: 300ppm total hydrocarbon based on composition. Precautions Special Precautions: Health studies have shown that many petroleum hydrocarbons pose potential human health risks which may vary from person to person. as a precaution, exposure to liquids, vapors , mists or fumes should be minimized. Personal Protection: For open systems where contact is likely, wear safety glasses with side shields, long sleeves, and chemical resistant gloves. Where contact may occur., wear safety glasses with side shields. where contact concentrations in air may exceed the limits given in this Section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH/MSHA approved respirators may be necessary to prevent overexposure by inhalation. Ventilation: The use of mechanical dilution ventilation is recommended whenever this product is used in a confined space, is heated above ambient temperatures. Section 4 Fire & Explosion Hazard Flash point Flammable Limit Auto ignition Temperature

: 177 deg F. Method :PMCC Note : Minimum. : LEL: 1.3 UEL : 8.8 Note : Approximate. : 640 degF. Note : "

General Hazard: Combustible Liquid, can foam combustible mixture at temperatures at or above the flash point.

static discharge, material can accumulate static charge which can cause an incendiary electrical discharge. "Empty" containers retain product residue (Liquid and/or vapor) and can be dangerous. Do NOT Pressurize, Cut, WELD, Braze, Solder, Drill, Grind, or Expose such containers to HEAT, Flame, Sparks, Static Electricity, or Other sources of Ignition; they may Explode and cause injury or death. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioned, or properly disposed of. Fire Fighting: Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire. Use foam, dry chemical, or water spray to extinguish fire. Avoid spraying water directly into storage containers due to danger of boil over. this liquid is volatile and gives off invisible vapors. Either the liquid or vapor may settle in low areas or travel some distance along the ground or surface to igniting sources where they may ignite or explode. Section 5 Spill control Procedure land spill: Eliminate sources of ignition. prevent additional discharge of material, if possible to do so without hazard. for small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in public area, keep public away and advise authorities. Also, if this product is subject to CERCLA reporting(see Section 7) notify the national response center. Prevent liquid from entering sewers, watercourses, or low areas. contain spilled liquid with sand or earth. Recover by pumping or with a suitable absorbent. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Water spill: Eliminate sources of ignition. Warm occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or with suitable adsorbents. if allowed suitable dispersants may be used in non-confined waters. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Section 6 Notes Notes: 1. CEFIC TREMCARD Number : Tech (R) 26 - applies if name is changed. this product has been evaluated by EXXON chemical and determined to meet the low vapor pressure (LVP) exemption set by the California Air Resources Board for volatile organic compounds in consumer products 2. (California code of Regulations, Title 17, Article 2. Section 94510). Hazard Rating Systems: This information is for people trained in : National paint & coatings Association's (NPCA) Hazardous Materials Identification System(HMIS) National fire protection Association (NFPA 704) Identification of the fire Hazards of Materials NPCA-HMIS NFPA 704 KEY Health 1 1 4= severe Flammability 2 2 3= Serious 1= Slight Reactivity 0 0 2= Moderate 0= Minimum. Section 7 Regulatory Information Department of transportation(DOT): DOT Shipping description: petroleum distillate, N.O.S Combustible Liquid. UN 1268, III DOT Hazard Class : Not regulated. DOT Identification Number : Not applicable. Flash Point : 177 Deg F. Method : PMCC Note : minimum. TSCA: This product is listed on the TSCA inventory at CAS Registered Number 64742-47-8 CERCLA: If this product is accidentally spilled, it is not subject to any special reporting under the requirements of the

comprehensive Environmental response, compensation, and Liability Act (CERCLA), We recommended you contact local authorities to determine if there may be other local reporting requirements. SARA TITLE III: under the provisions of title III, Section 311/312 of the superfund Amendments and reuthorization Act, this product is classified into the following hazard categories: fire. This Information may be subject to the provisions of the community right-to know Reporting Requirement (40 CFR 370) if threshold quantity criteria are met. Section 8 Typical Physical & Chemical Properties. Specific Gravity Vapor Pressure, mmHg at F Solubility in water, WT. % At F Viscosity of Liquid, CST at F SP. GRAV. of Vapor, at 1 atm (Air=1) Freezing/Melting Point, F Evaporation Rate, n-Bu Acetate = 1 Boiling point, F Section 9 Reactivity Data Stability Hazardous polymerization Conditions to avoid instability Materials and conditions to avid incompatibility Hazardous Decomposition Products Section 10 Storage and Handling Electrostatic accumulation Hazard Storage Temperature, F Loading/Unloading Temp., CST : : : : : : : : 0.79 at 60 Less the 0.1 @68 Less than 0.01 at 77 3 at 77 approximate. 5.90 Less than 76 Less than 0.0 421 to 484

: Stable : will not occur. : not applicable : Strong oxidizing agents. : None.

: Yes, use proper grounding procedure. : Ambient : Ambient

Storage/ transport Pressure, mmHg : Atmospheric. Visc. at loading/unloading Temp., CST : 7 USCG : These odorless solvents( Thinners) should be stowed as mineral spirits. M.Steel : Exxon is reluctant to stow in M.S even if tank and clean lines is all that is needed. Operational Problems/ Hazards Tanks should be vented for 24 hours after discharge as product softens coatings Due to extraordinary purity of these products tanks will have to be salts clean and dry Previous cargoes of salts, alcohols, ketonnes, acetates, and lub. additives may cause tanks to be failed. Previous cargoes of paraffins preferred. Tank Cleaning : Cold sea water wash to remove residues (1.5 hours ) Hot sea water wash with chemical injection , 5 ft half hour drops Fresh water rinse or steam Ventilate Educt and mop dry Tank Coating Stainless Steel, Epoxy, polyurethane, Zinc Silicate. ISOPAR SG C 0.696 B.PT/F 217 F.PT/F 40 Heat/F 100

G H K L M Cosmetic

0.72 0.75 0.76 0.76 0.78 0.76

240 320 365 380 400 350

45 105 126 144 175 144

100 100 100 100 100 100

Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

ISOPRENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating : : : : : : : : : : : : : : : : : : : : : Beta-methylbivinyl; 2-methyl-1,3-butadiene 3-methyl-1,3-butadiene 1218 IPR 2 3 2 CH = C(CH )CH=CH Colorless liquid; mild aromatic odor. 34C/ 93 F -146C/ 231 F 0.69 Olefins * B C 15.0 O 23.0 Insoluble 2.35 Portable lines to manifold or drop lines YES Purge : Usually Blanket : Usually Stainless steel, Polyurethane, Epoxy and Zinc silicate with restrictions.

Fire & Explosion Hazard Data Grade-A : Flammable liquid Electrical Group :D General : In a fire, polymerization may occur and violently rupture the container. it is recommended that isoprene be stored under an inert atmosphere(preferably nitrogen) with at least 50 ppm ter-butylcatechol present as an inhibitor. Keep away from sparks, heat or open flame. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : -65 2.0~ 9.0% 428 Carbon dioxide, dry chemical, foam. Cool exposed tanks with spray.

Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 0.005 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : Unavailable General : Isoprene is an irritant to mucous membranes of the eyes, nose, and upper respiratory passages. Symptoms: Vapor- eye and upper respiratory tract irritant. Liquid may irritate eyes. Short Exposure Tolerance: No data on human exposure are available but concentrations of 5% in air are fatal to mice. Exposure Procedure : Remove to fresh air . in case of contact with liquid immediately flush skin or eyes with water for at least 15 min. Remove contaminated clothing and shoes at once. call a physician. Reactivity Data Stability: Readily oxidized, polymerized. should be inhibited to prevent polymerization. Compatibility: Material : may soften some types of rubber or paint. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. secure ignition sources. Do not flush spill into confined spaces where flammable vapors can accumulate. remarks: Vapor pressure: 400 mmHg at 15 C.

Operational Problems/ Hazards Polymerizes readily unless inhibited. Can have serious explosion hazard if in contact with source of ignition in enclosed space. Due low B.P stow away from heat. Max. temp. +15C May require cargo cooling for carriage (10N 15C) Liquid and vapor have moderate irritation and narcotic effect therefore avoid contact. Major hazards - Fire. Personnel Protection Boiler suit, normal working gear Tank cleaning Cold salt water wash to remove residues (1.5 hors) Hot sea water wash with chemical injection , 5 ft half hour drops.

Ventilate, Educt and mop Tank must be dry and grease free USCG/IMO- Product mild properly inhibited and cool down to a safe level -50 is safe. Carried with no problem reported. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal.

Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

iso-PROPYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating Alcohol C-3;dimethyl carbinol; IPA; iospropanol;iospropyl alcohol; Petrohol; 2-propanol; sec-propyl alcohol; rubbing alcohol. : 1219 : IPA 3 2 : (CH ) CHOH : Colorless liquid; Sharp, Somewhat unpleasant odor. : 82C/182F : -88C/ -126 F : 0.79 : Alcohol : 33 : : III : 1.4 :D : 3.0 : Complete : 2.07 : Load via portable lines to droplines Bondstrand Not Suitable. : NO : Purge : NO Blanket : NO : Any, but restrictions on Epoxy and polyurethane.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Dangerous. Keep away from heat and open flame. flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) : 53 Flammable Limits : 2.0~ 12.0% Auto igniting Temp.(F) : 750 Extinguishing Agents : CO2, Dry chemical, Alcohol foam, water fog. Special fire Procedures : Cool tank with water spray. Water may be ineffective on fire.

Health Hazard Data Health hazard Rating : 1,0,2 Odor Threshold(ppm) : 200 PEL/TWA(ppm) : 400 TLV/TWA(ppm) : 400 General : Acts as a local irritant and high concentrations as a narcotic. Prolonged or repeated skin contact may cause defatting of the skin and may produce dermatitis from daily contact. Severely irritating to the eyes and may cause eye injury if not removed promptly. Symptoms : Dizziness and sleepiness; eyes,nose,and throat irritation. Short Exposure Tolerance : 400 ppm for 30 minutes. Exposure Procedure : Vapor- remove victim to fresh air. Apply artificial respiration if needed. Eye contact- wash eyes gently for 15 minutes with fresh water. Get medical attention for eye contact. Reactivity Data Stability: Stable. Compatibility: Material : Aluminum, especially at elevated temp. is unsuitable. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems / Hazards Liquid and vapor irritate skin and eyes, also corneal burns and eyes damage. Highly flammable product with high specification. Susceptible to water, grease, rust , smell, chlorides and hydrocarbons. Stow away from adjacent heat. MS- For purest (99%) grade, coated /SUS tanks 95% grades can go MS. 64/66- Coating is OK - if heat adjacent. Exxon- Tank inspection loading is the same as for Methanol. Handling - Only problems the Exxon peoples. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. Nature of Hazard Eye contact : Irritating, and will injure eye tissue if not removed promptly. Skin contact :

Frequent or prolonged contact may irritate and cause dermatitis. Low order of toxicity. Inhalation : Vapor concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects. Negligible hazard at ambient temperature (-18 to 38 deg. C; 0 to 100 Deg F). Ingestion : Minimal toxicity. Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchopneumonia or pulmonary edema. First Aid Eye Contact : Immediately flush eyes with large amounted of the water for at least 15 minutes. Get prompt medical attention. Skin Contact: Immediately flush with large amounts of water; use soap if available. Remove contaminated clothing, include shoes, after flushing has begun. Inhalation: Using proper respiratory protection, immediately remove the effected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. Ingestion: If swallowed. DO NOT induce vomiting . Keep at rest . Get prompt medical attention. Acute Toxicity Data is Available Upon Request. Workplace exposure Limits. OSHA Regulation 29CFR1910.1000 Requires the following permissible Exposure Limits: A TWA of 400ppm (980mg/M3) and a STEL of 500ppm(1225 mg/m3) for Isopropyl Alcohol. The recommended permissible exposure levels indicated above reflect the levels revised by OSHA in 1989 or in subsequent regulatory activity. Although the 1989 levels have since been vacated by the 11th circuit court of Appeals, EXXON Chemical recommended the lower exposure levels be observed as reasonable worker protection. The ACGH Recommends the following threshold Limit Values: a TWA of 400ppm (983mg/m3), and a STEL of 500ppm(1230mg/m3) for Isopropyl Alcohol. Precautions Personal Protection: For open systems where contact is likely, wear long sleeves, chemical resistant gloves, and chemical goggles. where contact may occur, wear safety glasses with side shields. Where concentrations in air may exceed the limits given in this section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH/MSHA approved respirators may be necessary to prevent overexposure by inhalation. Ventilation: The use of machinery dilution ventilation is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Use explosion- proof ventilation equipment. Chronic effects : In developmental toxicity studies conducted by the chemical manufacturers association, unexpected acute toxicity was found when Isoproppanol was administered to pregnant rabbits by garbage. there were no unexpected toxic effects in pregnant rats exposed in the same study. In rats there were some relatively mild developmental effects at maternally toxic levels. there was no evidence developmental toxicity in the rats at levels which did not also produce maternal toxicity. there were no indications of developmental toxicity reproduction study indicate that infant an immature rats are more sensitive than their parents to the acute oral toxicity induced by high (1000mg/kg/day) doses of Isopropanol. the effect levels for rats and rabbits were at several times the maximum exposure that would occur at the TLV. This information has been reported to the

U.S. EPA under the provisions of Section 8(e) of TSCA. Chronic Toxicity Data is available Upon Request Section 4 Fire & Explosion Hazard Flash Point Flammable Limits Auto ignition Temperature

: 54 Deg F. Method : TCC : LEL : 2.0 UEL : 12.7 @ 77 Deg F. : >662 Deg F.

General Hazard: Flammable liquid, can release vapors that foam flammable mixture at temperatures at or above the flash point. "empty" containers retain product residue (liquid and or vapor) and can be dangerous. DO NOT pressurize, Cut, Weld, Braze, Solder, Drill, Grind, or Expose Such containers to Heat, Flame, sparks, static electricity, or other sources of ignition; they may explode and cause Injury or Death. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioned, or properly disposed of. Fire fighting : Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak or spill has not ignited, use water spray to disperse the vapors. Either allow fire to burn under controlled condition or extinguish with alcohol type form and dry helical. try to cover liquid spills with foam. Hazardous combustion Products: No Unusual Section 5 Spill Control Procedure Land spill: Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without hazard. for small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in product is subject to CERCLA reporting (see section 7) notify the national Response center. Prevent liquid from entering sewers, watercourses, or low areas, contain spilled liquid with sand or earth. Do Not use combustible materials such as sawdust. Recover by expert on disposal of recovered material and ensure conformity to local disposal regulations.

ISOPROPENYL BENZENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : G- Methyl Styrene. : 2303 : : : : Hydrocarbon (Synthetic) : : @ C : : : : : : : : NO (Ensure Certificate obtained and Duration Checked) : Purge Blanket : :

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : C Explosive Range : Freeze Point : C Autoignition Point : C Operational Problems/Hazardous

Personnel Protection; Boiler suit and gloves, goggles Breathing apparatus standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Retain on board until on passage Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : Cold bottom wash to remove residues and gas free or inert. Hot sea water wash, 5 ft. half hour drop Ventilate to gas/ odor free. Steam tank, line and pump, Educt and mop

Tank must be completely dry and grease free. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

ISO PROPYL ACETATE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

: : : : : : : : : : : : : : : : : :

1220 3 3 3 2 Ch COOCH (CH ) 179 Ester Colorless liquid with a pleasant and fruity odor. 0.87 @ 20 C 0.00101 Ambient Ambient Ambient 34 React with oxidizing agents, acids and alkalis. Portable lines to droplines . Bondstrand Not suitable. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel or zinc , Epoxy , Polyurethane with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 100 ppm TLV 200 ppm Flash point :7C Draeger Tube No. : CH202 Ethyl Acetate 200/a Boiling Point : 88 C Explosive Range : 1.8% to 7.8 % Freeze Point : - 77 C Autoignition Point : 460C Operational Problems/Hazardous Stow away from adjacent heat. Liquid and vapor irritate the eyes and skin. If inhaled the vapor has narcotic effect. High specification cargo susceptible to moisture and grease. Personnel Protection;

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : FLASH POINT - 60F is correct. has it at 40F 64/66 - No heat adjacent. Ventilate tank 48 hours after discharging soft. Handling - Use Nitrogen blanket on slack loaded tanks. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Drying oil :

Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ISO PROPYL AMINE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity : 2 Aminopropane : 1221 :2 : (CH3) 2CH NH2 : : Amine : A colorless volatile liquid with a ammonia like odor. : 0.694@ 15 C

Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended :

: 0.0011 : Ambient : Ambient : Ambient :7 Can react vigorously with oxidizing agents. Also mercury can have dangerous reaction. Portable lines to manifold deck tanks or poison bank. Compoflex lines are suitable. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO

Stainless steel only.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : less 1ppm TLV 5 ppm Flash point : -20C Draeger Tube No. : CH318 Hydrazine 0.25/a Boiling Point : 32C Explosive Range : N/A% to % Freeze Point : - 95C Autoignition Point : 402 C Operational Problems/Hazardous Low flash cargo. Lines must be blown with nitrogen. Stow away from heated cargo. Highly flammable. Product highly toxic by inhalation and ingestion. Mercury thermometers should not be used for temps. Portable lines must have electrical continuity. Personnel Protection; Chemical protective clothing, Breathing apparatus standby and used during topping-off operation. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Retain on board until on passage Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Slight. Cold sea water pre-wash Gas free or inert Hot sea water wash, 5 ft. half hour drops Ventilate Steam tank, line and pump Educt and mop Tank should be completely dry and grease free. 100% Grade - LPG ships needed because of too high vapor pressure. 50% grade- Boiling point ; check B.P before booking to be sure. Drying oil : NO

This solution is O.K. for vessel with deep well pumps such as our Mohn pump. Keep deck cool on hot days with water flushing. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

ISO PROPYL ETHER

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity : : : : : : : : : : : : : : 2 Isopropxypropane, Di-Isopropyl Ether,I.P.E 1159 3 C6 H14 O Aliphatic ether A colorless mobile liquid with an etheral odor. 0.7332 @15 C 0.00102 Ambient Ambient Ambient TBA Basically stable when inhibited.

Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended

Portable stainless steel or compoflex hoses to deck tanks or Pison bank manifolds. : YES (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Possible : Stainless steel or Zinc

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 300ppm TLV 250 ppm Flash point : Below 0C Draeger Tube No. : TBA Boiling Point : 65-70 C Explosive Range : 1.4% to 21 % Freeze Point : - 86C Autoignition Point : 443C Operational Problems/Hazardous Must be carried inhibited , or else forms explosive peroxides in contact with air or exposure to light Must be stowed away from heated cargo Very susceptible to static All lines must be bonded, and blown with Nitrogen High grade solvent, may require Methanol standards of tank cleanliness. Moderately toxic vapor and liquid ( Avoid contact) May require vent line desiccator. Personnel Protection; Full chemical protection and B/A. Air condition on Recirculation. Restrict personnel on deck. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) Drying oil : NO (A) Cleaning from Solubility in water : YES. Wash in overrich or with tank inerted. Cold wash to remove residues ( 1.5 hour) Hot wash with chemical injection ( 0.5 hour 5 ft. drop) Fresh water rinse or steam.. Ventilate to gas and odor free Educt and mop Tank to be dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS

May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

JET FUEL
Synonyms : JP-1 ~ 6 A1,B IMO No : TBA IMO TYPE :3 Formula : Various ICS Guide Page No. : Family : Hydrocarbon Appearance and character : Mainly water white. Low viscosity liquid Specific Gravity : Various below 1.0 Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 83 Reactivity : Basically stable. Handling : Portable lines to manifold or droplines Lines to be bonded for electrical continuity. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to chatters Reg. ) : Purge YES Blanket : NO Tank Coating recommended : Stainless Steel, Zinc silicate, Epoxy , Polyurethane Subject to coating compatibility Lists Consult USCG Compatibility Chart

Odor threshold Flash point Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: : Various with grades : : Various : : Various : C

Operational Problems/Hazardous When carrying for military purposes, very extreme standard of tank and line cleanliness are liable to be encountered. Very susceptible to static generation. Closed loading required. When loading commences, starting rate should be slow until droplines are fully covered. Lines must be blown with Nitrogen. Personnel Protection; Boiler suit and gloves, goggles Breathing apparatus for topping off and P/R work Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage according to regulations. Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : NO Ventilate to gas and odor free Cold sea water wash ( 2hour) to disperse residues Ventilate Fresh water rinse or steam Ventilate Educt and mop Very high standard of cleanliness required. JET FUEL GRADES Grade S.G JP1 0.79- 0.8 JP4 - ditto JP5 JP6 Drying oil : NO

F.P Autoignition Point 35 C 228 C -23 C 242 C 35C 246 C 38C 224 C

Handling - For finest grade prepare tanks as for B.T.X or similar W.W products. No big problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

JET FUEL ADDITIVE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : Trade name for Ethylene Glycol, Monomethyl ether. : 1171 :3 : : : A water -white liquid containing 99.6% Methyl Oxitol, 0.4% Glycerine. Used as an anti-icing agent. : 0.97 @ C : : : : : : : : : :

Ambient Ambient Ambient

- (Ensure Certificate obtained and Duration Checked) Purge Blanket : Stainless Steel

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 44 C Draeger Tube No. : Boiling Point : 124C Explosive Range : Freeze Point : C Autoignition Point : 288C

Operational Problems/Hazardous See file on Ethylene Glycol Monomethyl Ether for full information. Personnel Protection; Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Cleaning Guidelines ( To solvent Standard ) (A) Cleaning from Solubility in water : Drying oil : NO

Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal.

Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

KEROSENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen : : : : : : : : : : : : : : : : : : : : Coal oil; fuel oil no,1; illuminating oil, kerosene; range oil. 1223 KRS Mixture of hydrocarbon Pale yellow to water white oily liquid strong odor. 170~300C/338~572 F -45C/ -50 F 0.81 Petroleum oil 2.04 I 0.1 D 0.15 Negligible 4.5 Portable lines to manifolds or droplines NO Any Coating suitable

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Flammable, moderate risk Flash Point (F) : 100~150 Flammable Limits : 0.7~ 5.0% Auto igniting Temp.(F) : 444 Extinguishing Agents : Confined area- Co2, dry chemical. open area- foam, water fog. Special fire Procedures : Tanks exposed to fire should be kept cool with a water spray. Water may be ineffective on fire. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm)

: : : :

1,1,1 1 Unavailable Unavailable

General : Moderate toxic by ingestion and inhalation. Symptoms : Inhalation- marked vertigo, inability to walk a straight line, hilarity, in coordination, intense burning in throat and lungs, possibly bronchopneumonia, nausea, vomiting. Short Exposure Tolerance : Unavailable Exposure Procedure : Inhalation; remove victim from contaminated atmosphere. if breathing is interrupted, artificial respiration should be applied immediately. call a doctor. Reactivity Data Stability: Stable. Compatibility: Material : most metals are suitable, but kerosene causes rusting of steel. Cargo : Group 33 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. secure ignition sources. small spills may be flushed away with water. Operational Problems/ Hazards Subject to static Lines must be blown with Nitrogen Grades may be base for jet fuels, therefore one might encounter high specification cargo, requiring extremely clean tanks and lines. Personnel Protection Boiler suit , normal working gear. Tank cleaning Cold sea water wash to remove residues (5 hour) Hot sea water wash with chemical injection 5 ft. half hour drop Fresh water rinse or steam, Ventilate to gas free Educt and mop dry Tank must be dry S.G - It various from 0.78 to 0.82 . Most common is 0.81 Lamp oil- This fine grade from Exxon needs especially good tanks. Go for coated or S.S good cargo. No problem. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard.

HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

LARD OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : Latex. : N/A :3 : N/A : 19 : Ester Soft, white mass, with a faint odour and bland taste. Derived from the carcasses of pigs. : 0.86 @ C : : 38-40 C : 52 C : 50 C. : 34 Basically non- hazardous. Lard slops when mixed with hot water react similarly to that of tallow. No Specific handling regulations Ensure portable lines hot washed as soon as possible after use. : NO (Ensure Certificate obtained and Duration Checked) : Purge Blanket : Stainless Steel, Epoxy, polyurethane, Not recommended for Zinc Silicate.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 221 C Draeger Tube No. : Boiling Point : 220C Explosive Range : Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Temperature of cargo not to raised more than 3 C/day Sweeping required will depend upon the quality of the grade. Lines should be steamed back to tank to prevent oil solidifying in pipelines after discharge. Personnel Protection; Boiler suit , Normal working gear Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Discharge to sea according to regulations. Cleaning From Drying oil : NO Solubility in water : Slight

Pre-clean with hot water to remove residues Hot salt water wash, minimum 3 hours with chemical injection ( Maximum temperature compatible with coating) Spot clean as required Fresh water rinse or steam Ventilate Educt and mop dry Edible - Heating : for discharge heat slowly - maximum 5 F per day please comply. M.S- some shippers request tanks to be sprayed with mineral spirit before loading. That takes approximately 8 hours SPIA chicago demands it. Inedible (Grease oil) - There are several grades with different FFA and heating. Check . this grade of lard oil is more like grease. No problems. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture).

LATEX (NATURAL )
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character : : TBA : N/A 2 3 2 : CH CCH : CHCH : : Natural Hydrocarbon White opaque smooth viscous liquid with mild rubbery with some ammonia odor. : 0.95 @ C

Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : N/A Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : 25 ~ 30 C USCG Compatibility chart Group No : N/A Reactivity: Product is non-reactive but degrades with heat. Ammonia is introduced to reduce putrefaction and this may present an inhalation hazard. Handling : Always shore hoses and pumps for load and discharge. Via hatch and disposable plastic hose in body tanks. Shore hose connected direct to under tank elbow in deck tanks. There must be NO ullage space remaining in tank. Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless Steel, Epoxy or polyurethane.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : C Explosive Range : Freeze Point :0C Autoignition Point : C Operational Problems/Hazardous Product loaded either deck tank or small bodytank, by shore equipment. Following to be blanked : tank vent, suction ( in body tank ) IG vent , dropline (in bodytank) . Whose gauge float and wires to be removed and pedestal blanked. Heating coils to be blown clear and blanked . a patent relief V/V will be fitted at ullaging position. In bodytank, access ladder to be unbolted at top to allow freedom of movement to insert discharge pump. Product sucked from undertank connection in case of deck tanks. Tank to be sprayed with wax emulsion over all surfaces 2/3 days prior to load. Allow to dry to tacky and opaque and remove free wax from tank bottom. Product must be puddled. Personnel Protection; Normal working gear Breathing apparatus to be worn when entering tanks. (Due to ammonia content) in order to pudding , reposition pump, clear deposits, etc. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Discharge as required .Tank may be washed to deck

Vapor Return System Reg. : NO Cleaning from As soon as discharge completed, tank to be sprayed with coagulant solution ( 2.5 % solution calcium chloride/ fresh water plus detergent ) and left for approximately 90 minutes. After inspection, and removal of coagulate product, cold sea water wash ( using maximum number of machines ) half-hour 5 ft. drops. Inspect tank and remove coagulant lumps every 30 minutes. When all residues disposed, hot sea water wash to remove residual grease. Some hand cleaning will be required Tank requires a high standard of cleanliness and considerable preparation. Product shipped normally 50% rubber 40% water. Spraying equipment (45 :1 pump, lance, spray nozzle 25/1000 60 C, hose and wax emulsion ) will be supplied as required. Coagulant solution will be supplied at discharge port. Phenolic - coating is 100% all grades where ammonia AA the stabilizer. Any exposed M.Steel must be waxed. 64/66 - Maximum ammonia allowed is 1 % . Forward specification to Ameron for evaluation Pumps- piston pumps NO regular Mohn pumps OK Slowing centrifugal pumps with wash cooling are OK. -mostly used. Cleaning : At this writing this are no easy way to clean a tank after N/Latex. Hand stripping dried on Latex is a long and tedious job, using rubber rafts many days. See Appendix Special cargo Manual

LATEX (SYNTHETIC)
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family : Various Grades E.G. isr index 131. : :3 : Mixture : :

Appearance and character : Smooth pure white viscous liquid with sharp odor. Specific Gravity : 0.96to 1.04 Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : None Disch . : None Average Expected Load Temp. : None USCG Compatibility chart Group No : 43 Reactivity : May react with acids and anhydrides Will tend to polymerize if subjected to excessive heat. Handling : By portable lines to direct loads on center tanks or direct at elbow to deck tanks Do not manifold ships lines. Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : YES : Stainless Steel, Polyurethane or Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : 5- 10 C Autoignition Point : Operational Problems/Hazardous Product should not normally be heated unless absolutely necessary , as product polymerizes around coils. Shippers instruction vary , but requirement is normally for product to be carried at above 10C, but as load temperature is generally high , heating should be avoided on passage Product will harden and form :skin: on surfaces when exposed to air, and tank should be steam fogged to wet all surfaces prior to loading . Expansion is minimal and tanks should be pressed up to leave no ullage space. If ullage space necessary (slack tank) then gentle steam fogging on passage at frequent intervals is necessary. Nitrogen blanket and/or vent line desiccator will be required Ensure all portable hoses, etc. cleared by warm washing directly after use. If product is not allowed to dry off there will be no problems Only after residues removed may hoses be steamed. Personnel Protection; Boiler suit and gloves Vapor return system : NO IMO Pollution rating : D May be discharged as convenient and as per regulations. Cleaning from; As soon as possible after discharge ( and Surveyors inspection) tank should be washed down, using as many machines as practicable with ( preferably fresh ) hot water (50 ~ 70C) for minimum 2 hours This should remove all residues; however, some hand stripping when all residues removed, hot sea water wash Ventilate Fresh water rinse Educt and mop Consult company Memo in handling this product. During discharge steam fogging tank is beneficial . Tank may also be pressurized with air/ steam /I.G subject to charterers. Tank normally discharged by shore pumps as excessive agitation puts product off specification. Load closed (i.e. P/V battened down, etc.) but allow openings to be opened at intervals to prevent air locks

causing ullage spaces in pressed up tank. Discharge : The viscosity 77F is 7000 SSU . Some heat be needed for our mhon pump to handle. Heating coils cant be used. Cleaning code 7. Cargoes listed under this group are natural and synthetic latex, and are cleaned using ambient temperature fresh water, often followed by solvent cleaning. Refer to latex manual.

LAURIC ACID
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : Cocecanoic Acid. : Not Listed :3 : Ch3 (CH2) 10 COOH : : Organic Acid A colorless fatty acid found in may vegetable oils. Forms needle- like crystals. : 0.833 @ C : : 70 C : : :

Reactivity: Can react with oxidizing materials. When surface is exposed to air, May spontaneously ignited. Handling Inhibitor Nitrogen (Subject to chatters Reg. ) Tank Coating recommended : : - (Ensure Certificate obtained and Duration Checked) : Purge Blanket : YES : Polyurethane if temp below 60 C Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 160 C Draeger Tube No. : Boiling Point : 225 C Explosive Range : Freeze Point : 44 C Autoignition Point : 360C Operational Problems/Hazardous Low toxicity, but ingestion should be avoided causes irritation on the eyes and skin Blow lines with steam or nitrogen - Not -air.

Personnel Protection; Chemical protective clothing , Gloves, Goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Nil Soluble in alcohol and ether. Cleaning from:

LEMON OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor : : : : : : : : Limonis Oil. N/A 3 N/A Essential oil Pale /deep yellow greenish liquid Fragrant odor. 0.849 to 0.855

: TBA : Ambient : : : : Basically non-hazardous . Being a foodstuff pipes will have to be scrupulously clean. Ship or shore lines. : NO(Ensure Certificate obtained and Duration Checked)

Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Purge NO Blanket : Possible : Polyurethane, Stainless steel, Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Requires food grades tank, and surveyors will expect high standard of coating Nitrogen blanket and/or vent line desiccator may be required for quality control. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Hot salt water wash with chemical injection, Spot clean if required Fresh water rinse or steam, Ventilate Educt and mop dry. Food grade tank required for loading Note: Similar characteristic will be found with other citrus oils, e.g. grapefruit , lime, orange, tangerine.

LINEVOLS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Linevol 79, Linevol 911, Shell Noeflex 3

A mixture of primary alcohols A water white liquid with a mild odor. 0.83 to 0.837 0.00066 Ambient Ambient 20 Basically stable Portable lines to manifold or droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible Epoxy, polyurethane, Zinc Silicate, Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold :

Flash point Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: 77-107 C : : + 175 C : : -9 or less C :

Operational Problems/Hazardous Liquid and vapor moderately irritating - Avoid contact A nitrogen blanket may be required for quality control Very little information available - check locally. Personnel Protection; Boiler suit, gloves , goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Slight

Cleaning from: Hot wash with chemical injection , 5 ft half hour drops Fresh water rinse or steam Ventilate Educt and mop dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

LINSEED OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : Flaxseed oil, Raw Linseed oil, Boiled Linseed oil. N/A 3 N/A 19 Ester Yellow brown/ reddish brown liquid with characteristic odor. 0.931 to 0.936 @15C

: 0.00068 : 10-20 C : 10-15 C : 10 -20C : 34 :Subject to spontaneous heating Dries with exposure to air Otherwise basically non-hazardous. : No specific handling regulations Ship or shore lines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Epoxy, polyurethane, Stainless steel , Epoxy recommended.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : 205 C Draeger Tube No. : Boiling Point : 340 C Explosive Range : Freeze Point : -19 C Autoignition Point : C

Operational Problems/Hazardous Oil dries by absorption of oxygen, Boiled linseed oil dries about five times faster than raw Avoid heat on adjacent tanks. After discharge tank should be cold washed immediately DO not enter tank until oxygen content has been checked and adequate ventilation is operative. FFA content of Linseed oil usually below 2%. Personnel Protection; Boiler suit , Gloves, Goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Nil Soluble in alcohol and ether.

Cleaning from: Pre-wash cold sea water wash minimum 3 hours Hot sea water wash with chemical injection Fresh water rinse Ventilate Educt mop dry. Heat adjacent - With higher heat some baked on (Black) oil appear on bulkheads after discharge Cargokleen will remove it. Zinc - The FFA is usually water below 2.5%. making zinc OK, but check. Handling - No problems. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

LISSAPOLS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Lissapol -N, NX N/A 3 ICI Grand Detergent Detergent Colorless to slightly tinted, clear or slightly hazy viscous liquid 1.055 @ 20C

Ambient 20-30 C Ambient Stable Portable lines to manifold or droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, polyurethane, Stainless steel

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Nothing specific. Personnel Protection; Boiler suit , Gloves, Goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Hot sea water wash, 5 ft. half hour drops. Fresh water rinse or steam. Ventilate, Educt mop dry. Tank must be dry and moisture free. Soluble in water : Complete

MESITYL OXIDE
Synonyms Isobutenyl methyl Ketone; Isopropylideneacetone; Methyl iso-butenyl ketone; methyl isobutenyl ketone; 4-methyl-3-penten-2-one, iso-propylideneacetone. : 1229 : MSO 3 2 3 : (CH ) C=CHCOCH : Oily, colorless liquid; Honey odor : 130C/ 266 F : -59C/ -74F : 0.86 : Ketone : 8.7 : :D :+ :O : 0.67 : Slight : 3.5 : Ships lines or compoflex to droplines : NO : Purge : NO Blanket : NO : Stainless steel , Zinc subject to limitation. : CH229 Acetone 100/a

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating Draeger Tube No

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Flammable, dangerous fire risk, vapor forms explosive mixture with air. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 84 Flammable Limits : 1.3~ 8.8% Auto igniting Temp.(F) : 652 Extinguishing Agents : Alcohol foam, carbon dioxide or dry chemical Special fire Procedures : Wear complete protective clothing and self contained breathing apparatus. Cool exposed tanks with water. Water may be ineffective on fire. Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General

: : : : :

3,3,3 12 15 15 Moderately toxic by ingestion, inhalation, and skin absorption.

Symptoms: Irritation of eyes, headaches, coughing, difficult breathing, nose and throat irritation,mild intoxication. Short Exposure Tolerance: 5 minutes- 100 ppm predicted eye and mucous membrane irritation with difficult breathing, headache, similar exposure at 800 ppm. predicted severe eye and respiratory irritation. Vapor conc. 500 ppm for 30~60 min. considered dangerous to life. Exposure Procedure : Immediately remove victim from exposure and treat on symptomatic bases. flush skin promptly with soap and water. if swallowed, do not induce vomiting. Get medical attention. Reactivity Data Stability: Stable. Reacts with oxidizing agents; strong alkalis(caustics), and mineral acids. Compatibility: Material : Non- corrosive to steel. Cargo : Group 18 of compatibility chart. See also appendix 1- Exception to the chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems/ hazards Both liquid and vapor are harmful to eyes and skin and toxic by absorption, ingestion and inhalation, causing lung, kidney and liver damage. Basal irritation occurs at 25 ppm Irritation of the eyes occurs at 50 ppm Exposure to 800 ppm and above could be fatal. Product is highly flammable with explosion hazard Stow away from adjacent heat. Personnel Protection Total protection suit Restrict personnel on deck. Secure accommodation and recirculate air. vapor return system : YES Tank cleaning Cold salt water wash, minimum 3 hours Ventilate to gas free Fresh water rinse Educt and mop Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

META CRESOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No : : : : : : : : : : : : : M-Cresol, M-Cresylic Acid, M- Methyl Phenol, 3- Methyl Phenol. 2076 3 3 6 1 CH C H OH 48 Phenol Colourless to Yellowish liquid with sharp disinfectant-like odor. 1.038 @15C 0.0008 20-70 C 20-70 C 20- 70 C 21

Reactivity: Reacts dangerously with oxidizing agents, acids, alkalis and acid anhydes. Handling : Portable lines to manifold or droplines Ships lines to deck/center tanks. : NO (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Possible : Stainless Steel or Zinc, but subject to limitations.

Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 5 ppm TLV 5ppm Flash point : 86 C Draeger Tube No. : CH315 Phenol 5/a Boiling Point : 202 C Explosive Range : 1.1 % to % Freeze Point : 12 C Autoignition Point : 538 C Operational Problems/Hazardous Hazards very similar to phenol Liquid and vapor cause severe burns to eyes and skin Skin absorption or inhalation may be FATAL. May require vent line desiccator. Personnel Protection; Total protection suit ( with PVC gloves) Restrict personnel on deck Secure accommodation and recirculate air Use Closed Ullaging system. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A Vapor Return System Reg. : NO Should be discharge to shore receptacle , but in the absence of such facility retain on board until on passage and then discharge as per control regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Gas free or inert, Hot sea water wash , 5 ft half hour drops

Steam tank, line and pump. Educt and mop, Tank must be dry , as product becomes corrosive when mixed with water. Uses : Manufacture of Phenol - formaldehyde type resins and modified resins for surface coatings. Production of Tri Tolyl phosphate, synthetic tanning agents, bactericidal compounds and organic intermediates. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note.1 Cargoes such as acids, alkalis and oxidizers may react with water, product heat and form a much more corrosive solution. To minimize this reaction, large amounts of water must be introduced as quickly as possible. The water should be allowed to accumulate in the cargo sump or on the tank top. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

META PARA CRESOL

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity: Reacts dangerously with oxidizing agents , Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : See also: Meta Cresol*, Para Cresol. 2076 3 3 6 4 CH C H OH 48 Phenol A Clear pale amber liquid with a sharp disinfectant-like odor. 1.035- 1.042 @ 20C TBA 35 C + 35 C + 35 C + 21

acids, alkalis and acid anhydrides : Ships lines or compoflex. : NO (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Probable : Stainless or Zinc but subject to limitation.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : 5ppm TLV 5ppm Flash point : 88 C Draeger Tube No. : CH315 Phenol 5/a Boiling Point : 199 C Explosive Range : 1 % @ 150C % Freeze Point : 34 C Autoignition Point : 538 C Operational Problems/Hazardous Meta para Cresol is a mixture of the meta and para isomers of Cresol. *information on this sheet has been taken from ICS Guide at worst (i.e. Flash point 34C which is for Para, Meata being 12C) ICS sheets and all local information should be studied when handling this product. Essentially it is very similar to the other Cresol Isomers. Hazards very similar to Phenol Liquid and Vapor cause severe burns to eyes and skin Skin absorption or inhalation may be fatal. May require vent line desiccator, Use Closed Ullaging system. Personnel Protection; Total protection suit with PVC gloves Restrict personnel on deck Secure accommodation and recirculate air. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A Vapor Return System Reg. : NO Should be discharged to shore receptacle, but in the absence of this facility retain on board until on passage then discharge as per control regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Gas free or inert, Hot sea water wash, 5 ft. half hour drops

Steam tank, lines and pump, Ventilate Educt mop dry. Tank must be dry and product becomes corrosive when mixed with water. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note.1 Cargoes such as acids, alkalis and oxidizers may react with water, product heat and form a much more corrosive solution. To minimize this reaction, large amounts of water must be introduced as quickly as possible. The water should be allowed to accumulate in the cargo sump or on the tank top. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

META XYLENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : 1,3- Dimethyl benzene 1307 3 6 4 3 2 C H (CH ) 228 Aromatic Hydrocarbon Colorless Liquid with characteristic aromatic odor. 0.8684 @ 15C 0.00085 Ambient Ambient Ambient 32 Reacts dangerously with oxidizing agents and acids. Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Any, possibly with restrictions, but Zinc preferred.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odor threshold : ppm TLV 100 ppm Flash point : 25 C Draeger Tube No. : CH278 Toluene 25/a Boiling Point : 139 C Explosive Range : 1.09 % to 6.4 % Freeze Point : -48 C Autoignition Point : 528 C Operational Problems/Hazardous Vapor and liquid may cause irritation Inhalation may cause injury to the kidneys, heart and arteries. No information regarding odor threshold , but olfactory fatigue occurs rapidly. Personnel Protection; Boiler suit , Gloves, Goggles. Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Retain on board until on passage Discharge on passage as per control regulations. Drying oil : NO Soluble in water : NIL

Cleaning from: Gas free or inert, Cold sea water wash , 5 ft half hour drops Fresh water rinse or steam. Ventilate Educt mop dry. Tank must be dry and Grease free. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames.

Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

METHYL ALCOHOL
Synonyms UN. No CHris Code Alcohol C-1,carbinol; colonial spirits; Columbian spirits; Methanol; methyl hydroxide; Pyroxylic spirits; wood alcohol ; wood spirit. : 1230 : MAL

Formula : CH OH Appearance-Odor : Colorless liquid; smells like wine or shellac thinner. Boiling Point : 64C/ 148 F Freezing Point : -98C/ -144 F Specific Gravity : 0.79 Chemical Family : Alcohol Vapor Pressure(20C) : 100 Pollution Category USEPA :D IMO : III Reid Vapor Pressure(psia) : 4.5 Applicable Bulk reg.46 Subchapter :D Vapor pressure 46C(psia) : 7.0 Solubility in water : Complete Vapor Density(air = 1.0) : 1.11 Handling : Portable lines to drop lines, Preferably compoflex , but if Bondstrand used should be blown and flushed out as soon as possible after use. Inhibitor : NO Nitrogen : Purge : possible Blanket : Probably Tank Coating : Any with restriction on epoxy and polyurethane, normally zinc preferred. Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Methyl alcohol is a flammable liquid. At "room" temp. gives off a vapor which is both toxic and, when mixed with air , explosive within certain limits. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 61 Flammable Limits : 5.5~36.5% Auto igniting Temp.(F) : 878 Extinguishing Agents : CO2,dry chemical, alcohol foam, water fog. Special fire Procedures : Avoid breathing vapors. Provide body and respiratory protection for fire parties. Keep tanks cool with water spray. Water may not be effective unless large quantities are used. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General : Vapor inhalation dangerous. May be absorbed through skin. Poisonous if

: : : :

1,1,2 50~2000 200/skin 200/skin

swallowed.

Symptoms: Dizziness, unconsciousness, and sighing respiration. Short Exposure Tolerance: 1000 ppm for 1 hour has caused headache, eye irritation and fatigue. Exposure Procedure : Remove victim to fresh air, Give artificial respiration if breathing stops. Skin or eye contact- Remove contaminated clothing. flush affected areas gently with water for 15 minutes. Get medical advice or attention.

*NOTE :Odor threshold is not considered adequate warning of potential dangerous vapor concentrations. Reactivity Data Stability: Stable. Can react vigorously with oxidizing materials. Compatibility: Material : Compatible with most materials of construction. Cargo : Group 20 of compatibility chart. See also Appendix 1- Exception to the chart. Spill or Leak Procedure Wear rubber gloves, protective clothing. Have all-purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards Stow away from adjacent heat Product may required a vent line desiccator Product may soften certain coatings, therefore tanks should be thoroughly ( by all available means) ventilated for at least 24 hours before washing. Tanks having just contained Methanol should not be ballasted between cargoes if possible, but in any case not for at least seven days. Last cargoes preferably solvents and/or clean chemicals Very high specification cargo - very susceptible to chlorides and hydrocarbons. Personnel Protection Boiler suit, gloves and goggles, B.A sets for topping off. and pump room work. Tank cleaning Gas free to dryness, May require half-hour cold bottom wash, fresh water rinse, Educt and mop dry. Tank should be thoroughly steamed to remove chlorides. This should be followed by spraying with a chemical suitable for the removal of hydrocarbons. This should be followed by a distilled water rinse and the process repeated until the tank is completely free of hydrocarbons. Prior to survey the whole tank should, if possible, be sprayed with Methanol, but in any case the tank bottom and lower bulkheads should be done . It is then advisable to carry out a swab test for chlorides and hydrocarbons. It is normal practice to flush the tank bottom , line and pump with Methanol (10-15 tones normally supplied by shore installation ) Shore specification less than 1 ppm chlorides and hydrocarbons. Do not apply water for rinse after discharge. Ventilate tank 24 hours minimum . Getting tank for loading is the problem tank is visible clean, steam tank at least 6 hours. this is to remove hidden residues chlorides, hydrocarbons, Bulk head test will take if tank OK or not. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames vapors may travel to a source of ignition and flash back container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials

Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. . FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Move container from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; Stop leak if you can do it without risk water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

METHYL ACETATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) : : : : : : : : : : : : : : : Acetic acid, methyl ester. 1231 MTT 3 3 CH COOCH Colorless liquid, fragrant odor 54C/ 129 F -98C/ -144 F 0.92 Ester 170 III 4.6 D 6.1

Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : :

Slight 2.6 Compoflex portable lines to droplines NO Purge : NO Blanket : NO ANY coating , but with restrictions

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General: Dangerous, when exposed to heat or flame. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 14 Flammable Limits : 4~ 14% Auto igniting Temp.(F) : 850 Extinguishing Agents : Alcohol foam, dry chemical, or Co2. Special fire Procedures : Water may ineffective due to low flash point, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited. use water spray to dispense the vapors and to protect men attempting to stop a leak. Water may dilute spills to non-flammable mixtures. Health Hazard Data Health hazard Rating : 2,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 200 TLV/TWA(ppm) : 200 General : Skin contact with liquid causes defatting and cracking of skin. Vapor irritating. Symptoms: Irritation of respiratory passages, eyes, dizziness, depression, burning of eyes. Short Exposure Tolerance: 400 ppm for unknown duration. Exposure Procedure : If the eye are effected, irrigate continuously with water for at least 15 min. Obtain medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : Compatible with common materials of construction. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards Stow away from adjacent heat Pumps may Gas Up due to high vapor pressure Liquid and vapor cause considerable irritation of eyes and defatting and cracking of the skin. Inhalation of vapor may have narcotic effect High explosion and fire risk

Clear lines with Nitrogen Personnel Protection Boiler suit , gloves and goggles, Breathing apparatus for topping off and pumproom work. Tank Cleaning Cold sea water pre-wash to remove residues Ventilate to gas free or inert Hot sea water wash, 5 ft half hour drops Steam tank, line and pump Educt and mop Tank should be completely dry and grease free. Adjacent heat is NO because of low boil and flash point. Handling - Nitrogen blanket recommended when loading slack tank. Cargo -O.K. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane Move container from fire area if you can do it without risk.

or nitroethane.

Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

METHYL ACRYLATE
Synonyms : Acrylic Acid Methyl Ester, Lenning Solvent 13. IMO No : 1919 IMO TYPE :2 2 Formula : H C : CHCOOCH ICS Guide Page No. : 136 Family : Ester ( Aliphatic ) Appearance and character : Colourless Liquid with a sharp and pungent odor. Specific Gravity : 0.9610 @ 15C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00120 Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 14 Reactivity: Reacts dangerously with oxidizing agents acids, waters, and several other chemicals - See ICS guide , note IV on 136.5 Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : Ships lines to poison bank or deck tanks. YES (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : YES Stainless Steel or Zinc with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 10ppm Flash point :-3C Draeger Tube No. : 6728161 Methyl Acrylate 5/a Boiling Point : 80C

Explosive Range Freeze Point Autoignition Point

: 2.8 % to 25 % : -77 C : C

Operational Problems/Hazardous Both liquid and vapor highly toxic - may be absorbed through the intact skin. Exposure to vapor will dull the ability to detect their odor, nevertheless high concentration of vapor will not be tolerated voluntarily. Product is liable to polymerization and is usually inhibited. However , polymerization may still occur under fire conditions and in any case may be speeded up by heat, light or the presence of organic peroxides. Polymerization may result in the rupturing of the tank. STOW away from Adjacent HEAT. Product mat require a vent line desiccator. Personnel Protection; Total protection suit and breathing apparatus Restrict personnel on deck Secure accommodation and recirculate air Use Closed Ullaging system. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO Retain on board until on passage Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Cold salt water wash immediately after discharge to prevent polymerization of residues. Ventilate to gas free or inert. Hot salt water wash, 5 ft half hour drops Thorough steam of tank line and pump to remove odor Educt mop dry. Tank must be dry and Grease free. USCG- Inhibitor brand and amount must be made known if requested. Phenoline : Coating is 100 % resistant after being in service for 6 months. 64/66 - It softens- avoid Handling - Tank/line/valve must be free from any residues liquid. This is to avoid polymerization. Vapor return line requested. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. Soluble in water : Slight

After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID

Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

METHYLAMYL ACETATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended Sec-Hexyl Acetate, 2- Methylamyl Acetate, Methylisobutyl Carbinol Acetate, 4-Methyl-2-Pentanol Acetate, 4-Methyl Pentyl2-Acetate : 1233 :3 3 3 2 3 2 : CH COOCH(CH ) CH CH (CH ) : : Ester ( Aliphatic ) : Colourless Liquid with a mild agreeable odor. : 0.8595 @ 20C : : : : : : : : : : 0.00095 Ambient Ambient Ambient Reacts with oxidizing agents and some acids. Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Any coating subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 50 ppm Flash point : 43 C Draeger Tube No. : Boiling Point : 146C Explosive Range : % to % Freeze Point : -68 C Autoignition Point : C Operational Problems/Hazardous Stow away from adjacent heat. Hydrolysis occurs when product comes into contact with water, forming acids. Liquid and vapor cause irritation of eyes and skin Inhalation of vapor may have a narcotic effect. Personnel Protection; Boiler suit , Gloves, Goggles. Breathing apparatus for topping off and pumproom work.

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Retain on board until on passage Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Very slight

Cleaning from: Ventilate to gas free or inert Hot salt water wash, 5 ft half hour drops Thoroughly steam of tank, line and pump (All traces of the cargo must be removed from the coating before next cargo and to prevent coating damage) Tank should be cleaned before ballasting. Tank must be dry and Grease free. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces.

Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

METHYLAMYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Isobutyl methyl carbinol;Isobutyl methyl methanol; MAOH; Methyl iso-butyl carbinol; 4-methyl-2-pentanol; MIBC; MIC : 2053 : MIC 3 2 3 2 : CH CH(OH)CH CH(CH ) : Colorless liquid; mild alcoholic odor. : 132C/ 269 F : -90C/ -130 F : 0.81 : Alcohol : 3.8 : :C : 0.2 : D,O : 0.4 : 1.8% : 3.5 : Portable lines to droplines : NO : Purge : Possible Blanket : YES : Any Coating

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Moderate hazard, when exposed to heat or flame. Flash Point (F) : 131 Flammable Limits : 1.0~ 5.5% Auto igniting Temp.(F) : 583(calculated) Extinguishing Agents : CO2,dry chemical alcohol foam, water fog. Special fire Procedures : Provide fire parties with respiratory protection if they must enter space to fight the fire. Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 25/skin PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 25/skin General : Essentially an anesthetic with tittle or no cumulative toxicological properties. prolonged contact with liquid may produce drying cracking of the skin. Symptoms: Burning of nasal passages and water of eyes, burning or itching at site contact, dizziness or drowsiness.

Short Exposure Tolerance: 2900 ppm cause immediate watering of eyes, nose and throat; 2~4 hours, narcosis; 8~10 hours, profound depression and possible death. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advises or attention. Reactivity Data Stability: Relatively stable. Compatibility: Material : Most materials of construction are satisfactory. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Operational Problems / Hazards Product may require a vent line desiccator, Liquid and vapor may irritate skin and eyes Possibly a high specification cargo Stow away from adjacent heat. M.S - It is difficult to even an excellent tank past loading. Handling- No problems is reported . Good cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam.

Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

METHYL ETHYL KEYONE

SECTION 1. Product Identification & Emergency Information Product Name : METHYL ETHYL KETONE Chemical Name : 2-Butanone Chemical Family : Ketone. Product Description : Clear colorless liquid. Emergency Telephone Number EXXON CHEMIAL America 800-726-2015 CHEMTREC 800-424-9300 Section 2. Hazardous ingredient Information This product is not hazardous as defined in 29 CFR1910.1200 OSHA HAZARD Flammable PEL; TLV Eye irritant for additional information see section 3. Section 3 Health Information & Protection Eye Contact : Severely irritating. If not removed promptly, will injure eye tissue. which may result in permanent damage. Skin Contact : frequent or prolonged contact may irritate and cause dermatitis. Low order of toxicity. Inhalation: Vapor concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects. Low order of toxicity. Ingestion : Low order of toxicity. Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchopneumonia or pulmonary edema. First aid Eye Contact: Immediately flush eyes with large amount of water for at least 15 minutes. Get prompt medical attention. Skin Contact: Immediately Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. Inhalation: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. Ingestion: If swallowed, Do Not induce vomiting. Keep at rest. Get prompt medical attention. workplace exposure limits OSHA Regulation 29CFR 1910.1000 Requires the Following permissible exposure Limits: A TWA of 200 PPM (590 mg/m3) and a STEL of 300 ppm (885 mg/m3) for Methyl Ethyl Ketone(2-Butanone). The recommended permissible exposure levels indicated above reflect the levels revised by OSHA in 1989 or in subsequent regulatory activity. Although the 1989 levels have since been vacated by the 11th Circuit Court of Appeals, EXXON Chemical recommends that the lower exposure levels be observed as reasonable work protection. The ACGIH Recommends the following threshold Limit Values: TWA of 200 ppm (590 mg/m3), and a STEL of 300 ppm (885 mg/m3) for Methyl Ethyl Ketone. Precautions Personal Protection: For open systems where contact is likely, wear safety glasses with side shields, long sleeves,

and chemical resistant gloves. Where contact may occur., wear safety glasses with side shields. where contact concentrations in air may exceed the limits given in this Section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH/MSHA approved respirators may be necessary to prevent overexposure by inhalation. Ventilation: The use of mechanical dilution ventilation is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Use explosion proof ventilation equipment. Chronic effects: There is no evidence that exposure to Methyl Ethyl Ketone (MEK) alone causes progressive or irreversible neurotic effects. However, simultaneous Over-exposure to MEK and n-Hexene can potentiate the known Irreversible neurotoxic effects of n-Hexene. There is no reported human evidence that these established OSHA and ACGIH limits. Section 4 Fire & Explosion Hazard Flash point Flammable Limit Auto ignition Temperature

: 25 deg F. Method :TCC note: TOC: -2 C IMCO: -1C : LEL: 1.8 UEL : 11.5@ 77 Deg.F : 860 Deg F.

General Hazard: Flammable Liquid,can release vapors that form flammable mixture at Temperatures at or above the flash point. "Empty" containers retain product residue (Liquid and/or vapor) and can be dangerous. Do NOT Pressurize, Cut, WELD, Braze, Solder, Drill, Grind, or Expose such containers to HEAT, Flame, Sparks, Static Electricity, or Other sources of Ignition; they may Explode and cause injury or death. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioned, or properly disposed of. Fire Fighting: Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire. If a leak or spill has not ignited, use water spray to disperse the vapors. either allow fire to burn under controlled conditions or extinguish with alcohol type foam and dry chemical. Try to cover liquid spills with foam. Hazardous Combustion Products: None unusual Section 5 Spill control Procedure land spill: Eliminate sources of ignition. prevent additional discharge of material, if possible to do so without hazard. for small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in public area, keep public away and advise authorities. Also, if this product is subject to CERCLA reporting(see Section 7) notify the national response center. Prevent liquid from entering sewers, watercourses, or low areas. contain spilled liquid with sand or earth. Recover by pumping or with a suitable absorbent. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Water spill: Eliminate sources of ignition. Warm occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Remove from surface by skimming or with suitable adsorbents. If allowed suitable dispersants may be used in non-confined waters. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Section 6 Notes This information is for people trained in: National Paint & Coatings Association's (NPCA) Hazardous Materials Identification System (HMIS) National fire protection Association (NFPA 704) Identification of the fire Hazards of Materials

Health Flammable Reactivity Section 7

NPCA-HMIS 3 3 0

NFPA 704 1 3 0

KEY 4- Severe 3- Serious 2- Moderate 1- Slight 0- Minimal

Regulatory Information

Department of transportation(DOT): DOT shipping Description Flash Point

: Methyl Ethyl Ketone, 3 UN 1193, II : 25 Deg F. Method : TCC Note: TOC : -2C IMCO: -1 C

TSCA: This product is listed on the TSCA inventory at CAS Registry Number 78-93-3 CERCLA: If the reportable of this product is accidentally spilled, the incident compensation and liability Act (CERCLA) and must reported to the National Response Center by call 800-424-8802. The reportable spill quantity of this product is 5,000 pounds. this product contains : Methyl Ethyl Ketone. SARA TITLE III: under the provisions of title III, Section 311/312 of the superfund Amendments and reauthorization Act, this product is classified into the following hazard categories: Immediate health, delayed health, fire. This information may be subject to the provisions of the community Right or know Reporting Requirements (40 CFR 370) if threshold quantity criteria are met. This product contains the following section 313 Reportable Ingredients: Component Methyl Ethyl Ketone CAS NO. 78-93-3 MAXIMUM% 100.0

Section 8 Typical Physical & Chemical Properties. Specific Gravity : 0.81 at 68 Vapor Pressure, mmHg at F : 83 at 75, 173 at 100 Solubility in water, WT. % At F : 26.30 at 68 Viscosity of Liquid, CST at F : 1 at 68 SP. GRAV. of Vapor, at 1 atm (Air=1) : Greater than 1.00 Freezing/Melting Point. F : Less than 32 Evaporation Rate, n-Bu Acetate= 1 : 6.0 Boiling point, F : 175 to 177. Section 9 Reactivity Data Stability Hazardous polymerization Conditions to avoid instability

: Stable : Will not occur. : Not applicable

Materials and conditions to avid incompatibility : caustics, amines, alkanolamines, aldehydes, ammonia, strong oxidizing agents, and chlorinated compounds. Handling : May be loaded through ships portable lines and droplines. Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank Coating : Any, but Zinc preferred Tank Cleaning Cold sea water wash, minimum 1.5 hours Ventilate to gas and odor free Good steam out of tank , line and pump

Ventilate, Educt and mop Tank to be ventilated prior to next cargo/ ballast Tank must be completely dry and grease free. Color -/MS- Product is usually discolored after carriage in M.S- avoid. Phenoline - Do not stow Ketonnes as first cargo . After 6 months in our service -coating 100% OK. Handling - Protect color with Nitrogen blanket . Discoloring is the problem with all Ketonnes. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

2-METHYL-5-ETHYL PYRIDINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Aldehyde-colidine; aldehydine; 3-ethyl-6-methyl pyridine; 5-ethyl-2-mehtyl pyridine; 5-ethyl-2-picoline; MEP : 2300 : MEP 3 5 3 2 5 8 11 : CH C H NC H , or C H N : Colorless liquid; sharp penetrating. : 178C/ 353 F : -70C/ -94 F : 0.92 : Amine : 0.9 : :B : 0.1 :O : 0.16

Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General: Moderate fire hazard when exposed to heat Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : :

Slight 4.18 Portable lines to deck tanks NO Purge : Possible Blanket : Possible Stainless Steel

: Combustible liquid :D or flame. Irritating vapors are generated when heated. : 165 : 1.1~ 6.6% : 939 : Alcohol foam, carbon dioxide, dry chemical, water spray. : Wear protective clothing and self contained breathing apparatus.

Health Hazard Data Health hazard Rating : 2,2,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Moderately toxic, skin irritant. Symptoms : Redness and swelling from skin contact with liquid. Short Exposure Tolerance : 1700 ppm lethal to a rat in 3.7 hours. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or Eye contact- Remove contaminated clothing and gently affected area with water for 15 min. a physician must see all cases of eye contact immediately after eye wash is completed. Reactivity Data Stability: Stable. Can react with oxidizing or strongly alkaline(caustics) materials. Compatibility: Materials: polyethylene- lined containers suitable. Cargo : Group 9 of compatibility chart. Spill or Leak Procedure Avoid contact with liquid. Keep unprotected personnel away from spill area. Collect material in plastic containers using absorbents, for small spills; flush large spills. Operational Problems/ Hazards Product is flammable Liquid and vapor cause irritation and in high concentrations may be harmful Product will rapidly absorb water/ Moisture and consequently be contaminated Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection Chemical protective clothing , gloves, goggles, Breathing apparatus Secure accommodation during all operations. Tank Cleaning Cold sea water wash ( Minimum 2 hours ) to remove all residues Ventilate and test for gas present Hot sea water wash, 5 ft half hour drops

Ventilate to gas/ odor free. Steam tank and line Ventilate Educt and mop Tanks must be dry and grease-free Note : Amine absorb water rapidly - ensure tank open while washing to prevent vacuum forming. Handling - Product carried with no problems. it needs good tanks. check coating condition - it must be good. Vapor return lines may requested required for loading transfer - Check. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

HEALTH HAZARDS Contact cause burns to skin and eyes If inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

METHYL ISO AMYL KETONE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : MIAK, 5 Methyl 2 Hexanone TBA 3 3 2 4 3 2 CH COC H CH CH (CH ) TBA Ketonne Colourless Liquid with a pleasant odor. 0.8132 @ 20C

Ambient Ambient Ambient 18 TBA. Portable lines to droplines NO(Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Probable Any coating

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 100 ppm Flash point : 43 C Draeger Tube No. : Boiling Point : 144C Explosive Range : % to % Freeze Point : -74 C Autoignition Point : C

Operational Problems/Hazardous Solvent type product which will dissolve traces of lube oils from tank coating. Stow away from adjacent heat. May require a vent line desiccator, Health Hazard Low Toxicity Personnel Protection; Boiler suit , Gloves, Goggles. Breathing apparatus for topping off and pumproom work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA Vapor Return System Reg. : NO Discharge on passage as per control regulations. Drying oil : NO Soluble in water : slight

Cleaning from: Ventilate to gas free or inert Hot salt water wash, 5 ft half hour drops Thoroughly steam of tank, line and pump Educt and mop. Tank must be dry and Grease free. M.S - It is next impossible to arrive at discharge with those two ketonnes on space if M.S in use stay off. 64/66 - No heat adjacent if coating in use. It is a poor for ketonnes . Ventilate tank 48 hours after discharge to harden. Phenolic - Do not stow the ketonnes as first cargo. After months in our service the coat is 100% OK. No soften . Handling - To protect to color , use Nitrogen blanket ways No other problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

METHYL ISO BUTYL KETONE

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Hexone;Isobutyl methyl ketone; Isopropylacetone; 4-methyl-2-pentanone; MIBK; MIK : 1245 : MIK 3 2 3 2 : CH COCH CH(CH ) : Colorless liquid;pleasant odor. : 116C/ 241 F : -84C/ -119 F : 0.80 : Ketone : 10 :D :D : 0.8 :D : 1.2 : 2.0% : 3.45 : Portable lines to droplines : NO : Purge : Probable Blanket : YES : ANY

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General: Irritating vapors are generated when heated. dangerous fire hazard when exposed to heat or flame; moderate explosion hazard when vapor exposed to heat or flame. Flash Point (F) : 75 Flammable Limits : 1.2 ~ 8.0% @ 200 F Auto igniting Temp.(F) : 858 Extinguishing Agents : CO2,dry chemical, alcohol foam, water fog.

Special fire Procedures

Fire parties must wear respiratory protection. Water may be ineffective on fire.

Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 0.47 PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 50 General : Vapor causes eye, nose, throat irritation. Aspirated methyl isobutyl Ketone may cause severe lung damage and present a significant hazard. Repeated or prolonged skin contact may cause defatting of the skin with primary irritation resulting. Symptoms: Headache, dizziness and nausea. Short Exposure Tolerance: 200~400 ppm for 5 minutes has produced eye irritation; 400 ppm for 5 minutes may produce nasal irritation. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 minutes. If swallowed, do not induce vomiting. Get medical attention. Reactivity Data Stability: Stable. Compatibility: Material : will soften many plastics. Cargo : Group 18 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards Stow from adjacent heat May require a vent line desiccator Product will be seriously put off specification if allowed to come into contract with moisture Vapor and liquid irritate skin and eyes, but inhalation of vapor may be Fatal. At 200~400 ppm irritation of nose and throat will occur. Headache and dizziness may occur after exposure to 100 ppm for eight hours. Personnel Protection Boiler suit and gloves with B.A Tank Cleaning Cold sea water bottom wash to remove residues , then ventilate or gas free, or inert Hot sea water wash, 5 ft half hour drops Steam tank, pump and line Educt and mop Tank must be completely dry and grease free. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

METHYL METHACRYLATE MONOMER

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Methyl Methacrylate, Acrylic Resin Monomer , MMM 1247 2 2 3 3 H C : C(CH ) COOCH 142 Ester ( Aliphatic ) Colourless, mobile limpid liquid with sharp characteristic pear-like odor. 0.9495 @ 15C 0.00110 Ambient Ambient Ambient 14 Reacts dangerously with oxidizing agents and certain acids. Ships lines to center tank or deck tank YES (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Stainless steel or Zinc, Polyurethane or Epoxy with restrictions

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : 50 ppm TLV 100 ppm Flash point : 10 C Draeger Tube No. : 6728171 Methyl Methacrylate Boiling Point : 100C Explosive Range : 2.1% to 12.5% Freeze Point : -48 C Autoignition Point : N/AC Operational Problems/Hazardous Cargo will polymerize readily unless inhibited Under Certain conditions (fine) inhibited product may polymerize and cause serious rupture of tank Vapor is uninhibited and may form polymers in way of vents and flame arrestors, resulting in their blockage. Stow away from adjacent heat and cargoes susceptible to smell . May require a vent line desiccant Vapor and liquid cause irritation of skin and eyes Ingestion or inhalation may have serious narcotic effects. Personnel Protection; Boiler suit , Gloves, Goggles. Breathing apparatus for topping off and pumproom work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations.

Drying oil : NO

Soluble in water : slight

Cleaning from: Cold sea water wash as soon as possible after discharge to remove residues and prevent polymerization of same Hot salt water wash, 5 ft half hour drops Thoroughly steam of tank, line and pump Educt and mop. Tank must be dry and Grease free. Tank history important. USCG : Product must be put inhibited. Amount and brand name requested. 64/66 - Carried long voyage no problems; coating O.K. without softening. Handling - Pay special attention to dryness -tank/line must clean/dry . Polymerizing is problems. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided.

FIRE OR EXPLOSION

Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

MOLASSES
Synonyms : Treacle

UN. No : ++ CHris Code : Formula : Mixture of socrose and sugar Appearance-Odor : Dark brown syrupy liquid Boiling Point : V.high Freezing Point : Varies Specific Gravity : 1.45 Chemical Family : Alcohol, glycols and glycol ethers Vapor Pressure(20C) : Low Pollution Category USEPA : IMO : III Reid Vapor Pressure(psia) :" Applicable Bulk reg.46 Subchapter :* Vapor pressure 46C(psia) :" Solubility in water : Soluble Vapor Density(air= 1.0) : ** Handling : No specific regulation, but largest lines possible should be used to minimize back pressure and maximize flow rate. Best discharge rates are achieved by Overalling into center tanks being continuously pumped ashore; rather than stripping individual tanks ashore. Fire & Explosion Hazard Data GradeElectrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : :

Non-Flammable NA Non-Flammable and non-combustible. Non-flammable " " " "

Health Hazard Data Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : " TLV/TWA(ppm) : " General : Non-toxic. molasses fermentation occurs when molasses is diluted with salt or fresh water and is accelerated by heat. during fermentation Co2,(with possible traces of ethanol and higher alcohol vapor) is given off, which will produce inhalation hazard in compartment containing molasses residue. Symptoms : Non-toxic. Short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove victim to fresh air. Skin or eye contact- remove contaminated clothing and flush affected areas gently with water. Reactivity Data Stability: Stable. reacts with conc. nitric acid and conc. sulfuric acid. Fements when diluted with salt or fresh water. Compatibility: Material : Mild steel and stainless steel are suitable. Cargo : Group 20 of compatibility chart. Spill or Leak Procedure Wash area with water after removing bulk of spill by general means.

remarks: Unregulated, Table 2, 46 CFR part 153. ** H2O vapor only. Operational Problems / Hazards Product practically non-hazardous, although if fermentation occurs (due to water dilution and heat) an unpleasant odor is formed, which creates an inhalation hazards. Observe tank entry precautions. Product may foam, due to Co2, ullage will change and tank may pressurize. Temperature will rise significantly even with coils off. Check ullages and temperatures frequently on passage. Should fermentation occur, effect may be reduced by introducing compressed air to the bottom of the tank. Alternatively the level may be reduced by deanting to empty tank. Personnel Protection Boiler suits and normal working gear Tank Cleaning Hot sea water wash as soon as possible after discharge Do not leave molasses /water slops in tank as product becomes very acidic and may damage the coating Thoroughly steam tank and lines Ventilate ( odor is very persistent and may be difficult to remove), Educt and mop NOTE : Product may bake onto coils in powder form - this must be removed with a wire brush. Tank and line to be dry Steam may be used to assist in stripping tank Check tank strength as SG is greater than 1 Loading figures normally found by deadweight survey, although. No temperature correction factor is possible , and product will layer on heating and does not circulate Check pump , buckets, springs, valves, etc. for damage after. Heat/Blackstrap : For grade with pumping rates. Slow -very slow, and dead slow . Highest allowable heat must be applied. 115F becomes bare minimum for these grades. 125F a better number. Zinc /PH : The PH must be above 5.3 for Zinc carriage. Resistance lists read 5.5 and above -conservative . At a pH of 5.2 -complete run. Cleaning : Any tank started on Must be complied water/ steam mixed with molasses make acetic acid . No coatings are resistant to acetic acid. Beet : Heat slowly 5F per day increase is safe . Good cargo. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (B)Warm water (38 to 55 degree C)

MONO METHYL ETHANOLAMINE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) : : : : : : : : TBA CH3 NHC2 H4 OH 142a Nitrogen Compounds Water white liquid with mild ammonia odor. 0.9414 @ 20C

Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : :

0.00073 Ambient Ambient Ambient 42 Reacts dangerously with oxidizing agents and Strong acid Portable lines to droplines (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO TBA

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 74 C Draeger Tube No. : Boiling Point : 159 C Explosive Range : % to % Freeze Point : -4 C Autoignition Point : N/A C Operational Problems/Hazardous The liquid is extremely hazardous in contact with the eyes, and will irritate the skin Skin absorption and ingestion of the liquid is also hazardous. Portable lines should be flushed out as soon as possible after use. Personnel Protection; Chemical protective suit , gloves and goggles Breathing apparatus for topping off and pumproom work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Complete Cleaning from: Ventilate to gas free or inert Hot sea water wash, 5 ft half hour drops Steam tank line and pump. Educt and mop.

MORPHOLINE
Synonyms Diethylene imidoxide; diethylene oximide Diethylenimide oxide; Tetrahydro-1,4-oxazine; tetrahydro-2H-1,4-oxazine; Tetrahydro-p-oxazine : 2054 : MPL 2 4 : (CH ) ONH : Colorless oily liquid; ammonical odor : 128C/ 262 F : -4C/ 25 F : 1.00 : Amine : 7.0 :

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA

IMO :D Reid Vapor Pressure(psia) : 0.55 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 0.8 Solubility in water : Complete Vapor Density(air= 1.0) : 3.0 Handling : Copper and its alloys and rubber unsuitable Must be loaded through ships lines. Compoflex and Bondstrand NOT suitable. Inhibitor : NO Nitrogen : Purge : Possible Blanket : YES Tank Coating Stainless steel, some zinc, but limited to 2 months may be carried in certain Polyurethane coatings, but essential to check coating guide lists. Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General: Moderate fire hazard when exposed to flame or heat. When heated to decomposition, it emits highly toxic fumes of oxides of nitrogen. Flash Point (F) : 100 Flammable Limits : 1.8~ 10.8% Auto igniting Temp.(F) : 590 Extinguishing Agents : CO2, dry chemical, water fog, alcohol foam. Special fire Procedures : Provide fire parties with full biddy and respiratory protection. Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 0.01 PEL/TWA(ppm) : 20/skin TLV/TWA(ppm) : 20/skin General : Vapor moderately irritating. Liquid causes severe burns. Symptoms: Burning of throat and eyes ; itching or burning of the skin at site of contact. Short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical attention or advice. Reactivity Data Stability: This material is more stable than most of the other amines listed in this volume. It is a mild base. Compatibility: Material : Copper and it alloys and galvanized iron are not compatible. Cargo : Group 7 of compatibility chart. See also Appendix 1- Exceptions to the chart. Spill or Leak Procedure Wear butyl rubber gloves, plastic protective apron, self-confined breathing apparatus. avoid contact with liquid. Secure ignition sources. Small spills may be washed away with water. Operational Problems/ Hazards Liquid and vapor harmful to eyes, and to less extent skin

Attacks most rubber materials - use only Butyl Rubber Gloves for handling. For reasons of quality control , air in the ullage space must be dry; dry Nitrogen being safe to use as an inert gas pad. Prior to loading tanks must be dry. Personnel Protection Use chemical protective suit and breathing apparatus for cargo working and tank cleaning. Restrict personnel on deck. Secure accommodation and recirculate air during loading , discharging and tank cleaning. HEAT : Only in extremely cold climate is heat needed -check Zinc : Coating is resistant , but discoloring of coating a possibilities , Due no other problem with this cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires:

Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

iso-AMYL ACETATE
Synonyms Amyl acetate; sec-amyl acetate, amylacetic ester,banana oil; isoamyl acetate,isoamyl ethanoate, isopentyl acetate, 3-methyl-1-butanol acetate; 2-methylbutyl ethanoate; pear oil. : 1104 : IAT : CH3COO(CH2)2CH(CH3)2 : Colorless liquid; pleasant fruity banana-like odor. : 149C/ 300F : -70 C/ 094F : 0.88 : Ester : 4.0 :D :C : 0.1 : D.O : 0.34 : Slight : 4.5 : Compoflex , Bondstrand or Ships lines. : NO : Purge : NO Blanket : NO : Restrictions on Epoxy , Zinc and polyurethane. Use Stainless Steel.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air = 1.0) Handling Inhibitor Nitrogen Tank Coating

Fire & Explosion Hazard Data Grade- D : Combustible liquid Electrical Group :D General: No smoking or open flames, flashback along vapor trail may occur. vapor may explode if ignited in an enclosed space. precautions should be taken to prevent the accumulation of static electricity. Flash Point (F) : 100 Flammable Limits : 1.1 ~ 7.5% Auto igniting Temp.(F) : 714 Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog Special fire Procedures : Water may be ineffective. Health Hazard Data Health hazard Rating : 1,0,1 Odor Threshold(ppm) : 7 ~ 10 PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Little hazard from inhalation below 500 ppm. it may dry and defat skin. Symptoms: Headache, dizziness, nausea; irritation of mucous membranes of eyes and respiratory tract, coughing. Short Exposure Tolerance: 500 ~ 1000 ppm for 30~60 min. will produce definite irritation of eyes ,throat, and trachea. Exposure Procedure : Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with for 15 min. Get medical attention. Reactivity Stability: Chemically stable. Compatibility: Material : this compound will soften, then dissolve, a great many plastic material, and rubber. Attacks asbestos. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all-purpose canister mask available avoid contact with liquid. secure ignition sources. flush minor spill away with water. Operational Problems /Hazards Moderate fire hazards Avoid exposure of skin or eyes to liquid Personnel Protection Boiler suit, gloves and goggles Tank Cleaning Cold salt water wash minimum 3 hours Fresh water rinse Educt and mop Draeger Tube No. : CH202 Ethyl Acetate 200/a

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system.

The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces.

Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

NAPHTHA: stoddard solvent

Synonyms Drycleaners naphtha;drycleaners safety solvent (in USA); mineral spirits; petroleum solvent; spotting solvent,stoddard solvent; white spirits : 1255 : NSS : mixture : Colorless liquid; gasoline-like odor : 160~199C/ 320~390 F : : 0.78 : Petroleum oil : 3.0 : : @ Oil : 0.1 :D : 0.2 : Negligible :+ : May be loaded through ships portable lines and fixed droplines. : NO : Purge : NO Blanket : NO ANY< but unfinished or virsin naphthamay damage zinc silicate coatings.

UN NO. CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank cleaning

Fire & Explosion Hazard Data Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

: : : : : : :

Combustible liquid D Flammable, moderate fire risk 110(cc) 0.8~ 5.0% 540(approx.) Foam, dry chemical or CO2.

Special fire Procedures

: Cool exposed tanks with water.

Health Hazard Data Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Toxic prolonged or repeated skin contact may cause defatting of the skin and may produce dermatitis from daily contact. Symptoms: Inhalation- intoxication may result from high vapor concentration. Short Exposure Tolerance: 500 ppm for 30 minutes. Exposure Procedure : Inhalation: remove victim to fresh air. Administer artificial respiration if necessary. Ingestion : do not induce vomiting. Eyes: flush with water for 15 minutes. Call a doctor. Reactivity Data Stability: Stable. Compatibility: Material : Solvent effects on some paints and rubber. Carbon steel satisfactory. Cargo : Group 33 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Wear self contained breathing apparatus. Secure ignition sources. Operational Problems /Hazards In the case of fire ( Which is the main hazards ) Fluorotein foam should be used as Naphtha causes a breakdown of other foams, including regular protein foam compounds. Must be stowed away adjacent heat sources Has a high vapour pressure rate should be adjusted accordingly gas up: - discharge rate should be adjusted accordingly Vapor should not be inhaled. Personnel Protection Full boiler suit, loves and goggles Breathing apparatus may be required for ullaging near completion and pump room work. Tank Cleaning Minimum 1.5 hours cold sea water wash Ventilate to gas free Steam out and reventilate Educt and mop dry On occasions dirty naphtha products may be carried. If so, the tank will also required a hot wash after the cold pre-wash. Discharge rate for piston pumps is poor for all grades. especially in Hot climate and during stripping of tank . Mohn pumps do much better. No other problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or

a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

NAPHTHA , SOLVENT
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Naphtha Coal Tar 1256 3 A mixture of xylenes and Homologues 147 Miscellaneous Hydrocarbon mixture Dark straw to water white liquid with sweetish and pungent odor. 0.87 @ 20C 0.00087 Ambient Ambient Ambient 33 Reacts dangerously with oxidizing agents and some acids,. Portable lines to droplines NO(Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings suitable However, can soften Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 30 C Draeger Tube No. : CH254 Hydrocarbons 2 Boiling Point : 125 C Explosive Range : 1 % to 6 % Freeze Point :0C Autoignition Point : 500C Operational Problems/Hazardous Vapor and liquid will cause irritation of the eyes and the liquid will cause defatting of the skin Physical and chemical data will vary depending upon composition. Check locally with Surveyor. Personnel Protection; Boiler suit , gloves and goggles Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : LOW

Cleaning from: Ventilate to gas free or inert Hot sea water wash, 5 ft half hour drops Further chemical purging may be needed ) Steam tank line and pump. Educt and mop. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

NAPTHENIC ACIDS
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) : : : : : : : : : : : : : : : : : No common synonyms. NTI 2 2 10 CnH nCOOH to CnH n- COOH n=13-28 Gold to dark red to black liquid; penetrating, persistant putrid odor* 132~243C/ 270~470 F <0 c/ <0 0.98 @ 20 C Organic acids <0.1 B A " D,O " Insoluble 0.9

Fire & Explosion Hazard Data Grade- E : Combustible liquid Electrical Group : NA General : Combustible Liquid Flash Point (F) : 300 Flammable Limits : LEL=1% UEL-unavailable Auto igniting Temp.(F) : Unavailable Extinguishing Agents : Foam, dry chemical, carbon dioxide Special fire Procedures : Water may be ineffective; cool exposed tanks with water to prevent over pressurization and rupture. Handling : Ships lines Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank coating : SUS, polyurethane or epoxy with restrictions. Health Hazard Data Health hazard Rating : Unavailable Odor Threshold(ppm) : PEL/TWA(ppm) : " TLV/TWA(ppm) : 10mg/m 3 General : Mildly hazardous to man; hazardous to aquatic life in low concentrations. Symptoms: Irritating to eyes, nose ,throat, inhalation: coughing, difficulty in breathing. skin contact- irritating. Ingestion- nausea. Short Exposure Tolerance: Exposure Procedure : Inhalation- remove victim to fresh air, Ingestion- give large quantities of fresh water. Eye contact- flush with water until irritation stops. Skin contact- flush with water and soap. Reactivity Data Stability: Stable. Compatibility:

Material : Generally corrosive to metals. Cargo : Group 4 of compatibility chart. Spill or Leak Procedure Avoid contact, wear safety glasses or face mask. Dike and remove spilled material. prevent from reaching bodies of water. since it foul beaches, and taints aquatic life. remarks: Often odorless after processing. Operational Problems/ hazards Liquid causes severe burns Information on sheet very general and taken at worst Chemical and physical data vary with grade. STOW AWAY FROM HEATED CARGO. Personnel Protection Chemical protection suit, gloves and goggles Tank Cleaning Hot SW wash with chemical injection Ventilate and gas free Thorough steam of tank line and pump. Color : Excessive heat adjacent will damage the refined grade. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

n- BUTYLAMINE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : Amino Butane 1125 2 4 9 2 C H NH N/A

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : Colorless liquid with smell of Ammonia. : 0.738@ 20C : : : : : : : : : : 0.00092 Ambient Ambient Ambient N/A Compoflex of ships lines. NO(Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible SUS Epoxy or polyurethane Check coating guide.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point :-2C Draeger Tube No. : Boiling Point : 77C Explosive Range : 1.7% to % Freeze Point : -49 C Autoignition Point : 310C Operational Problems/Hazardous Irritant to skin and mucous membranes Use closed ullaging system Clear line with Nitrogen. Information insufficient on this product. Check locally. Personnel Protection; Boiler suit , gloves and goggles Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Cold salt water wash minimum 2 hours or dispose residues. Hot salt water wash minimum 3 hours Ventilate, Fresh water rinse Educt and mop Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (B)Warm water (38 to 55 degree C ) FIRE OR EXPLOSION Soluble in water : Complete

Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

NIAX POLYOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage : TBA : TBA : N/A : N/A : : N/A Opaque, pure white substance with consistency of treacle (Looks like smooth rise pudding). Faint rubbery odor. : 1.023 @ 20C : 0.0008 : 38 C

Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : :

60 C 40- 60 C 40 Reacts dangerously with oxidizing agents and acids. Should be loaded through portable lines and droplines. NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : YES ANY.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 248 C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : 40 C Autoignition Point : 410C Operational Problems/Hazardous Some shippers/ charteres do not require this product to be heated. Propylene oxide is a contaminant The product is usually loaded under a nitrogen blanket, provided by shore installation, the vessel then maintains the blanket on passage. Water contamination and overheating will cause discoloration Product requires a vent line dessicator. Personnel Protection; Full Boiler suit , gloves and goggles ( Gloves should be of plastic type ) Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : NIL Cleaning from: Prolonged hot salt water wash Chemical may be required if difficulties are encountered On contact with water the product emulsifies, thus the lines flushed out Ventilate to gas/ odor free. Educt and mop Tank should be extremely clean and dry prior to loading Usually shipped by Union Carbide from Houston/ U.S Gulf . For fire fighting use Co2 or dry chemical on small fires. On large fires use alcohol, polymer or ordinary foam. Heat - There has been changes in heating instruction several times. Be sure to obtain UCC Exact instructions each & every time. Heating differs from area to area Check. Handling - These products are similar to : Polyethylene Glycol, polypropylene cargoes . No problems. Cleaning code 2.

Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

NITRIC ACID (56~68%)

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Aqua fortis Azotic acid Engravers acid Engravers oil Hydrogen nitrate : 2031 : NCD 3 : HNO Colorless to yellow liquid, fumes in moist air; characteristic, Choking odor. : 122C/ 251 F : -34C/ -30 F : 1.35~1.41 : Inorganic acid : 7.1 :C :C : 2.7 :D : 3.6 : Complete : 2.17 : Ships lines to deck tanks compoflex hoses may be used.

Inhibitor Nitrogen Tank Coating Draeger tube No.

: NO : Purge : NO Blanket : NO Stainless Steel, but may be carried in certain Polyurethane for limited periods : 6728311

Fire & Explosion Hazard Data Grade: Non-flammable. classified as corrosive liquid. Electrical Group : B(based upon possible hydrogen gas(H2) generation should a leak or spill occur) General: Nitric acid will not burn. It will react with many metals, giving off hydrogen gas which is highly flammable. If hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See data sheet for hydrogen. May give off toxic oxide of nitrogen and acid fumes when heated in a fire. Flash Point (F) : Non-flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : Water Special fire Procedures : If fire results, water will absorb the toxic oxides generated. for fighters should wear full protective clothing respiratory protection. Health Hazard Data Health hazard Rating : 3,4,3 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) :2 TLV/TWA(ppm) :2 General : Breathing of vapors is extremely dangerous. Little warning of danger is at first apparent and initial symptoms are obscure. Liquid burns the skin forming deep ulcers which leave leathery scars. Symptoms: Vapor: immediately severe skin and lung burns. Liquid smarting, itching, and yellow discoloration upon skin contact. Short Exposure Tolerance: 15 ppm for 5 minutes. Exposure Procedure : Remove the affected individual from the contaminated atmosphere and call a physician at once. Keep patient at rest until seen by the physician. In case of eye or skin contact, flush immediately with copious quantities of water while removing contaminated clothing. the eye irritation should be continued for 15 minutes. Cases involving eye contact and inhalation Must have medical help!. Reactivity Data Stability: reacts violently with numerous organic materials. Decomposes at temp near boiling. Soda ash will neutralize residual acid from spills. Compatibility: Materials: Attacks aluminum; compatible with stainless steel and high chrome iron alloys. Cargo : Group 3 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing, body shield and self contained breathing apparatus should be available. Secure ignition sources. flush cautiously with water. avoid directing stream into large pools or pockets of concentrated acid. If possible, cover contaminated surfaces and spill with large quantities of soda ash or sodium bicarbonate. Mix and add water if necessary to effect good mixing. Scoop up slurry. Wash site with soda ash solution. Operational Problems / Hazards Both the liquid and vapor will cause severe burns if in contact with the eyes or skin or if inhaled. Closed ullaging system should be used. Personnel Protection

Total protection suit. Tank cleaning Pre-wash for 1 hour with cold sea water Then .5 hr, 5 ft. drop with hot sea water Fresh water rinse Ventilate Educt and mop USCG/IMO- Maximum acid concentration allowable for shipping is 70% HNO3. SUS - Grade 316-L is O.K, provided there is no heat adjacent . The temperature is a very important factor for carriage. Flush down deck on hot days. Handling - Protective clothing & face mask is a must while handling this dangerous cargo -CAREFUL. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note.1 Cargoes such as acids, alkalis and oxidizers may react with water, product heat and form a much more corrosive solution. To minimize this reaction, large amounts of water must be introduced as quickly as possible. The water should be allowed to accumulate in the cargo sump or on the tank top. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION May ignite other combustible materials (wood, paper, oil, etc). Violent reaction with water reaction with fuels may be violent flammable/poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: water, Dry chemical or soda ash. Large Fires: flood fire area with water move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Keep combustibles (wood, paper ,oil, etc.) away from spilled material fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not put water directly on leak or spill area.

Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

NITROBENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Essence of mirbane benzene, nitro Mononitrobenzene; nitrobenzol; Oil of mirbane. : 1662 : NTB 6 5 2 : C H NO : Light yellow green to brown liquid; similar odor to oil bitter almonds. : 211C/ 412 F : 5C/ 41 F : 1.20 : Nitrocompounds : 0.20 : C :B : 0.01 :O : 0.02 : Negligible : 4.24 : Ships lines to center (poison) tank or deck tank (Is compatible with compoflex) : NO : Purge : Possible Blanket : YES : Stainless Steel or zinc( May also be carried in some polyurethane)

Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General: Moderate fire hazard; at elevated temp, flammable, toxic vapor may be given off. Flash Point (F) : 190

Flammable Limits : LEL=1.8% UEL- Unavailable Auto igniting Temp.(F) : 900 Extinguishing Agents : Confined area- CO2,dry chemicals. Open area-foam. Special fire Procedures : Use water to keep fire exposed containers cool. Wear complete rubber protective clothing including eye protection and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 3,2,4 Odor Threshold(ppm) : 0.0047 PEL/TWA(ppm) : 1/skin TLV/TWA(ppm) : 1/skin General : Highly toxic when absorbed through the skin, inhaled as vapor, or swallowed. This is blood poison and a nerve poison which is readily absorbed by the body. Symptoms: "Blue lip" or bluish tinge seen in fingernail beds, lips, lobe of ears; conjunctive, mucous membranes and tongue. Fatigue, headache, vomiting, general weakness and signs of nervous system involvement. Short Exposure Tolerance: 200 ppm for one hour- no serious disturbance; 40~80 for a few hours-slight symptoms. Absorption may cause death due to nervous system poisoning. Exposure Procedure : Remove all contaminated clothing, wash skin with soap and water, flush skin for approx. 15 minutes. If swallowed, induce vomiting until fluid is clear. If inhaled, remove victim to fresh air and start oxygen inhalation. Contaminated clothing should be thoroughly washed in soap and water before using again. Get medical help. Reactivity Data Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 42 of compatibility chart. Spill or Leak Procedure Flush areas with large quantities of cold water. Ventilate freely. Hot water can be used to remove some absorbed material. Wear protective clothing including eye and respiratory protection. Operational Problems/ Hazards Odor threshold has not been established , but is likely to be in excess of the TLV and of the order of a few ppm. Product has no direct effect on the eyes and skin but causes toxic cyanosis by skin absorption, ingestion and inhalation. May require a vent line desiccant. Personnel Protection Total protection suit Restrict personnel on deck Secure accommodation and recirculate air Tank cleaning Warm sea water wash, 5ft. half hour drops, with chemical Fresh water rinse or steam Ventilate to gas and odor free Educt and mop dry IMO- Product is listed as MONONITROBENZNE Heat- Be sure to obtain exact heating instruction . See no big problems with cargo except a severe health hazard if not handled with CARE.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

NITROETHANE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : 2842 3 2 2 CH CH NO 150 Nitro Compound Colorless, oily liquid with a pleasant odor. 1.052 @ 20C

Ambient Ambient 42 Reacts with oxidizing agents and acids, alkalis and amines. Ships lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : YES Stainless Steel or Zinc

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : 200 ppm TLV 100 ppm Flash point : 41 C Draeger Tube No. : Boiling Point : 114 C Explosive Range : 3.4 % to % Freeze Point : -90 C Autoignition Point : 414C Operational Problems/Hazardous Liquid and vapor may cause irritation to the eyes Inhalation of vapor will have a narcotic effect and repeated exposure may result in damage to the liver and kidneys. May require a vent line desiccant Stow away from adjacent heat - at high temperatures it decomposes to yield highly toxic fumes. If heated rapidly it may explode. Any salts formed when dry will be explosive. The odor warning properties are not considered to be dependable. Personnel Protection; Full Boiler suit , gloves and goggles, Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Slight

Cleaning from: Cold sea water bottom wash to remove residues Ventilate to gas free, or inert Hot sea water wash, 5 ft half hour drops.

Steam tank, line and pump. Educt and mop Product and tank must be completely dry and grease free. Product is an excellent solvent and will dissolve cargo residues from tank walls. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

1-NITROPROPANE
Synonyms UN. No CHris Code Formula Isonitropropane; 2-Nitopropane; Nitropropane Nitropropanes; sec-nitropropane; 2-NP; propane, nitro: 2608 : NPP 3 7 2 : C H NO

Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : : : : : : : : : : : :

Colorless liquid; Odorless 121C/ 249 F -93C/ -135 F 0.99 Nitro compounds 12.9 A D + O 1.05 Slight 3.06 Load via portable lines and droplines NO Purge : Possible Blanket : YES May be carried in certain types of zinc, epoxy or polyurethane coating.

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General: Toxic oxides of nitrogen may form in fire. moderate fire hazard. Decomposes when subjected to high temp. Flash Point (F) : 103 Flammable Limits : LEL=2.6% UEL-Unavailable Auto igniting Temp.(F) : 802 Extinguishing Agents : Alcohol foam, water spray, CO2, dry chemical, foam. Special fire Procedures : Water protective clothing and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 300* PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Suspected carcinogen. slight irritation form liquid contact with skin and eyes. Vapor inhalation is irritating to respiratory tract with moderate systemic effect. Symptoms: Headache, dizziness, nausea, vomiting, diarrhea. Short Exposure Tolerance: 500~ 1000 ppm for up to one hour. Exposure Procedure : In case pulmonary symptoms or cyanosis, remove workers from contaminated area at once; place in bed, rest, use oxygen, if respiratory distress is present, and obtain medical attention. *NOTE: detectable odor is greater than the TLV. Exposure to potentially dangerous vapor concentrations can occur before the vapor is detected by smell. Reactivity Data Stability: stable under normal conditions. decomposes when subjected to high temp. Rapid heating to high temp. may cause an explosion. Compatibility: Material : Copper and its alloys, wet mild steel, and lead and its pigments are incompatible.

Cargo :

Group 42 of compatibility chart.

Spill or Leak Procedure If possible, wear neoprene gloves, plastic protective apron or coat and self contained breathing apparatus. provide good ventilation. secure ignition sources. If possible, cover with soda ash and spray with water. scoop up. Wash site with soap solution. Operational Problems / Hazards Portable lines should be flushed out as soon as possible after use with this product. Stow away from adjacent heat, Heating coils should be blanked off Product requires a vent line desiccator. Personnel Protection Boiler suit, gloves , goggles, Breathing apparatus standby Tank cleaning Cold bottom wash to remove residues Ventilate to gas free Hot sea water wash, minimum 2 hours Steam tank and lines Ventilate Educt and mop Tank and product must be dry Heat-adjacent- If at all possible no heat adj. Loading - Tank inspection is very strict - same as Methanol WWT must show . No Hydrocarbons , No chlorides, No other problems reported. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will

provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

2-NITROPROPANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Isonitropropane; 2-Nitopropane; Nitropropane Nitropropanes; sec-nitropropane; 2-NP; propane, nitro: 2608 : NPP 3 7 2 : C H NO : Colorless liquid; odorless : 121C/ 249 F : -93C/ -135 F : 0.99 : Nitro compounds : 12.9 :A :D :+ :O : 1.05

Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : :

Slight 3.06 Load via portable lines and droplines NO Purge : Possible Blanket : YES May be carried in certain types of zinc, epoxy or polyurethane coating.

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General: Toxic oxides of nitrogen may form in fire. moderate fire hazard. Decomposes when subjected to high temp. Flash Point (F) : 103 Flammable Limits : LEL=2.6% UEL-Unavailable Auto igniting Temp.(F) : 802 Extinguishing Agents : Alcohol foam, water spray, CO2, dry chemical, foam. Special fire Procedures : Water protective clothing and self contained breathing apparatus. Health Hazard Data Health hazard Rating : 1,1,1 Odor Threshold(ppm) : 300* PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Suspected carcinogen. slight irritation form liquid contact with skin and eyes. Vapor inhalation is irritating to respiratory tract with moderate systemic effect. Symptoms: Headache, dizziness, nausea, vomiting, diarrhea. Short Exposure Tolerance: 500~ 1000 ppm for up to one hour. Exposure Procedure : In case pulmonary symptoms or cyanosis, remove workers from contaminated area at once; place in bed, rest, use oxygen, if respiratory distress is present, and obtain medical attention. *NOTE: detectable odor is greater than the TLV. Exposure to potentially dangerous vapor concentrations can occur before the vapor is detected by smell. Reactivity Data Stability: stable under normal conditions. decomposes when subjected to high temp. Rapid heating to high temp. may cause an explosion. Compatibility: Material : Copper and its alloys, wet mild steel, and lead and its pigments are incompatible. Cargo : Group 42 of compatibility chart. Spill or Leak Procedure If possible, wear neoprene gloves, plastic protective apron or coat and self contained breathing apparatus. provide good ventilation. secure ignition sources. If possible, cover with soda ash and spray with water. scoop up. Wash site with soap solution. Operational Problems / Hazards Portable lines should be flushed out as soon as possible after use with this product. Stow away from adjacent heat, Heating coils should be blanked off Product requires a vent line desiccator. Personnel Protection

Boiler suit, gloves , goggles, Breathing apparatus standby Tank cleaning Cold bottom wash to remove residues Ventilate to gas free Hot sea water wash, minimum 2 hours Steam tank and lines Ventilate Educt and mop Tank and product must be dry Heat-adjacent- If at all possible no heat adj. Loading - Tank inspection is very strict - same as Methanol WWT must show . No Hydrocarbons , No chlorides, No other problems reported. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks.

For massive fire in cargo area, use unmanned hose holder or monitor area and let fire burn.

nozzles; if this is impossible, withdraw from

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

NONANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Fire & Explosion Hazard Data Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) : : : : : : : : : : : : : : : : : : : : 1-Nonane; n-Nonane 1920 NAN 9 2 CH0 Colorless liquid; gasoline like odor. 149C/ 300 F -54C/ -65 F 0.72 Saturated aliphatic hydrocarbon 10 C* 0.2 D,O 0.4 Negligible 4.41 Portable lines to droplines Purge : Blanket:

: : : : : :

Combustible Liquid D Moderate fire hazard when exposed to heat or flame. 86(cc) 0.74 ~ 2.9% 545

Extinguishing Agents : Dry chemical, foam, CO2. Special fire Procedures : Tanks exposed to fire should be kept cool with a water spray. Water may be ineffective on fire. Health Hazard Data Health hazard Rating : 0,0,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 200 TLV/TWA(ppm) : 200 General : Low toxicity; irritant, narcotic in high concentrations. Symptoms : Irritation of respiratory tract. Narcotic in high concentrations. Short Exposure Tolerance : Unavailable. Exposure Procedure : Remove victim to fresh air. apply respiration if breathing stops.Get medical attention. Reactivity Data Stability: Stable. Compatibility: Material : compatible with most materials of construction. Cargo : Group 31 of compatibility chart. Spill or Leak Procedure Have al purpose mask available. secure ignition sources. remarks: Pollution Category C oil-like, 33CFR 151.49. Operational Problems/ Hazards Product is highly flammable Liquid and vapor irritant and narcotic in high concentration Contact may lead to dryness of skin and dermatitis Heating to decomposition will cause toxic fumes Personnel Protection Boiler suit , gloves, goggles Tank cleaning Vent to gas free, or inert Hot sea water wash Fresh water rinse Educt and mop dry Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if

breathing is

difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

NONIDET NP40
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : TBA 9 19 4 2 2 2 C H H O (CH CH O ) H 153a Detergent containing Nonyl Phenol Ethylene Oxide condensates Pale amber liquid with a very odor. 1.059 @ 20C

: : 25 ~ 30 C : : 25 ~ 30 C : 213 Very little information available Becomes corrosive to metal when contaminated with water. : Portable lines to droplines : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : ANY

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 247 C Draeger Tube No. : Boiling Point : 235 C Explosive Range : % to % Freeze Point :6C Autoignition Point : C Operational Problems/Hazardous Liquid and may cause irritation to the eyes. Personnel Protection; Boiler suit , gloves and goggles, Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : TBA

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Miscible

Cleaning from: Hot sea water wash, 5 ft. half hour drops. Ventilate to gas free, Fresh water rinse. Educt and mop Tanks must be dry

NONYL ALCOHOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Alcohol C-9, Nonanol, n-Nonyl Alcohol, Octyl Carbinol. : TBA : : C9 H19 OH : 154 : Alcohol ( Aliphatic ) : Colorless-yellowish liquid Sweet odor. : 0.8287@ 15C : : : : : : : : : : 0.00070 Ambient Ambient 20 May Reacts with oxidizing agents and acids. Load through portable lines and droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless Steel or Zinc

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 79 C Draeger Tube No. : CH297 Boiling Point : Great than 180C Explosive Range : 1 % to 6 % Freeze Point :-5C Autoignition Point : Operational Problems/Hazardous Portable lines should be flushed out as soon as possible after use. Irritates skin and eyes. Personnel Protection; Full Boiler suit , gloves and goggles, Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations.

Drying oil : NO Cleaning from:

Soluble in water : NIL

Hot sea water wash, 5 ft half hours drops, with chemical Ventilate to gas free, Thorough Steam tank, line and pump. Educt and mop Tank must be completely As a solvent for coatings of ures and melamine resins A reforming agent The preparation of lubricant additives and polasticizers. Heat- Slight heat may be needed in colder climate. Be sure to obtain exact heating instruction for this very fine alcohol. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

NONYL PHENOL
Synonyms : No common synonyms. UN. No : CHris Code : NNP Formula : C6H4OHC9H19 Appearance-Odor : Clear, straw colored syrupy liquid phenolic odor, like disinfectant. Boiling Point : 304C/ 579F Freezing Point : -20C/ -4 F Specific Gravity : 0.94 Chemical Family : Phenol Vapor Pressure(20C) : Low Pollution Category USEPA : IMO :A Reid Vapor Pressure(psia) : Low Applicable Bulk reg.46 Subchapter : D,O Vapor pressure 46C(psia) : " Solubility in water : Negligible Vapor Density(air= 1.0) : 7.59 Handling : Load through portable lines and droplines (If Bondstrand used should be flushed out as soon as possible) Inhibitor : NO Nitrogen : Purge : No Blanket : Possible Tank Coating : Stainless Steel or Zinc restricted. Fire & Explosion Hazard Data Grade-E : Combustible liquid Electrical Group :D General : Slight hazard, when exposed to heat or flame. Flash Point (F) : 300 Flammable Limits : LEL= 1% UEL- unavailable. Auto igniting Temp.(F) : Unavailable Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Water or foam may cause frothing. Fire fighting parties should be provided with full body and respiratory protection. Health Hazard Data Health hazard Rating : 1,2,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid irritating to skin and eyes. Symptoms : Skin contact may cause burns and blisters. Short Exposure Tolerance: Breathing the vapors in a state approaching saturation on room air was not fatal to animals nor was a 4-hour exposure to mists, generated form the chemical heated to 170c Eight hours exposure to the mist killed 2 of 6 animals. Exposure Procedure : Remove a victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- immediately flush affected areas gently with water for 15 min.

Remove contaminated clothing. Get medical attention. Reactivity Data Stability: Stable. Compatibility: Material : Should be stored in stainless steel. nonyl phenol picks up iron in plain steel. Copper and its alloys promote color formation. Cargo : Group 21 of compatibility chart. Spill or Leak Procedure Wear rubber, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. Operational Problems /Hazards Because of its viscosity this compound is usually handled at temperatures above , but for reasons of color control 40C should not be exceeded, although this may vary with the shipper. Product classed as poison in U.K. Some shippers may require poison bank stowage. Will darken on exposure with air , therefore some shippers may require Nitrogen blanket Any contact with skin should be washed immediately. Personnel Protection Protective clothing , gloves and goggles Breathing apparatus standby Tank Cleaning Hot sea water wash, 5 ft half hour drops Ventilate to gas free Steam tank, line and pump Educt, mop and dry Heat- Arkopal Voyage 86 discharge at 104F Other ship discharge at 70/80F . Handling - None of these grades of Nonyl phenol are difficult to handle.The word Phenol is misleading to some. Good cargo- small problems. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture).

PENTANE
Synonyms UN. No CHris Code : Amyl hydride;normal pentane; n-pentane : 1265 : PTA

Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating

: : : : : : : : : : : : : : : : : :

CH (CH ) CH Colorless liquid with gasoline odor. 36C/ 97 F -130C/ -202F 0.63 Saturated hydrocarbon 431 C* 15.5 D,O 21.0 Slightly soluble 2.48 Load through portable lines and droplines NO Purge : NO Blanket : Possibly Any, with some restrictions.

2 3

Fire & Explosion Hazard Data Grade- A : Flammable liquid Electrical Group :D General: Highly dangerous when exposed to heat or flame. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : -56 Flammable Limits : 1.4~ 8.5 % Auto igniting Temp.(F) : 544 Extinguishing Agents : Foam, dry chemical, carbon dioxide Special fire Procedures : Water may be ineffective on fire. Cool exposed tanks with water. Use water spray to "knock down" vapor. Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : 10 PEL/TWA(ppm) : 600 TLV/TWA(ppm) : 600 General : Vapors may cause dizziness or difficult breathing. Liquid is harmful if swallowed. Symptoms: Low toxicity. Very high concentration of vapors may cause narcosis. Short Exposure Tolerance: Unavailable Exposure Procedure : Vapor- inhalation- move victim to fresh air. if breathing stops, administer artificial respiration, Liquid- have victim drink plenty of water or milk. DO NOT INDUCE VOMITING. Call a doctor. Reactivity Data Stability: Stable. dangerous reaction possible with deoxidizing agents. Keep away from heat, sparks, or open flame. Compatibility: Material : mild steel and stainless steel are suitable. Natural rubber will soften and deteriorate rapidly. Cargo : Group 31 of compatibility chart.

Spill or Leak Procedure Wear polyethylene gloves, face shield, protective clothing, Have all purpose canister mask available. for gas leaks keep vapor concentration below explosive mixture range. Secure ignition sources. DO not flush spill into confined spaces where flammable vapor can accumulate. remarks: Pollution category C oil-like, 33 CFR 151.49 Operational Problems / Hazards If Bondstrand used they should be flushed out as soon as possible. Because of its low boiling point this product carried with over-pressure to minimize prevent boil off unless cooled or under cold climate conditions. May irritant skin and eyes Product has a high vapor pressure, therefore pumps may be liable to gas up Stow away from adjacent heat. Personnel Protection Boiler suit, gloves and goggles Breathing apparatus standby Tank cleaning Cold sea water wash bottom wash to remove residues Gas free or inert, Hot salt water wash Ventilate Steam tank, line and pump Educt and mop Uses: Anesthetic, artificial ice manufacture, low temperature thermometers, solvent, blowing agent in plastics, pesticides. Boil/Flash points are very low. but cooled down it can safety be carried . Pumps: Deepwell (MP) pumps are O.K. piston pumps NO. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate

closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

n-PROPYL ACETATE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) : : : : : : : : : : : : : Acetic acid, n-porpyl ester,propylacetate 1276 PAT 3 3 CH COOC H7 Colorless liquid; pleasant, fruity odor 102C/ 215 F -92C/ -134 F 0.87 Ester * D 1.3

Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : : :

D 1.9 Slight 3.52 Portable lines to droplines Bondstrand NOT suitable NO Purge : NO Blanket : NO Stainless steel or Zinc, Epoxy and Polyurethane with restrictions.

Fire & Explosion Hazard Data Grade-C : Flammable liquid Electrical Group :D General : Dangerous, when exposed to heat or flame. Flash Point (F) : 70 Flammable Limits : 1.7~ 8.0% Auto igniting Temp.(F) : 842 Extinguishing Agents : CO2,dry chemical, alcohol foam, water fog. Special fire Procedures : Use of dry chemical where it can get into a tank of propyl acetate is not recommended. fire involving spills outside of tanks can be extinguished with dry chemical. Water may be ineffective on fire. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 200 TLV/TWA(ppm) : 200 General : Liquid causes slight irritation on contact. Vapor inhalation results in irritation of mucous membranes with moderate systemic effect. Symptoms: Sleepiness, fatigue, and retarded respiration rate. Short Exposure Tolerance: Unavailable. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops; apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Hydrolyzes(reacts with water) on standing to form acetic acid and n-propyl alcohol. The presence of bases(alkalis) speeds up the reaction. Reacts vigorously with oxidizing agents. Compatibility: Material : Softens or dissolves many plastics. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Small spills may be washed away with water. remarks: Vapor pressure : 30 mmHg @ 28.8c. Operational Problems/ Hazards Liquid and vapor irritate the eyes and skin Inhalation of vapor should be avoided as in large concentration will cause narcosis and may be fatal . Stow away from adjacent heat High specification cargo susceptible to moisture and Grease.

Personnel Protection Chemical protective clothing Breathing apparatus standby and used during topping off operations. Tank cleaning Cold salt water pre-wash Gas free or inert Hot salt water wash, 5 ft. half hour drops Ventilate Steam tank, line and pump Educt and mop Tank should be completely dry and grease free. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam.

Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

NYLON 6:6 SALT

Synonyms : Hexamethylene Diammonium Adipate. IMO No : TBA IMO TYPE : Formula : ICS Guide Page No. : Family : Appearance and character : Pebbles of Nylon in 50% solution with water. Specific Gravity : 1.0969@ 30C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : 33 -35 C Disch . : Average Expected Load Temp. : 33-35 C USCG Compatibility chart Group No : Reactivity : A neutral , harmless, non-toxic salt Non-corrosive, non-caustic Handling : Ships lines to stainless steel tanks Portable lines may be used if necessary. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge Possible Blanket : YES Tank Coating recommended : Stainless Steel or Possibly Zinc dependent on shipper. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : 107 C Explosive Range : % to %

Freeze Point Autoignition Point Operational Problems/Hazardous Non- Hazardous Personnel Protection; Full Boiler suit , gloves and goggles

: 26 C :

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Warm sea water wash, minimum 3 hours Fresh water rinse Educt and mop Tank must be completely dry and grease free Soluble in water : Complete

iso-OCTYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Alcohol C-8,diethyl-1-hexanol; isooctanol; isooctyl alcohol; 6-methyl-1-heptanol; octnaol; iso-octanol;oxooctyl alcohol. : : IOA 7 5 2 : C H CH OH : Clear liquid, mild odor. : 171C/ 339 F : -105C/ -157 F : 0.83 : Alcohol : 3.06 : :C : 0.02 : D,O : 0.03 : Negligible : 4.5 : Load through portable lines and droplines : NO : Purge : NO Blanket : NO : Zinc Silicate or Epoxy

: : : : :

Combustible liquid D Moderate fire hazard if exposed to heat or flame. 180 0.9~ 5.7%

Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: 530 : Confined area- CO2, dry chemical, Open- foam. : Use water to cool fire exposed tanks.

Health Hazard Data Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 50/skin TLV/TWA(ppm) : 50/skin General : Low toxicity; irritation of skin and mucous membranes. Symptoms : Irritates skin and eyes. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air. Skin or eye contact- remove contaminated clothing and gently flushed affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart. See also Appendix 1-Exceptions to the chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. secure ignition sources. Operational Problems/ Hazards Combustible -low toxicity Personnel Protection Boiler suit, gloves and goggles, Breathing apparatus standby Tank cleaning Hot salt water wash, 5 ft hour drops Ventilate to gas free Steam tank, line and pump Educt and mop Draeger tube : CH297

OCTENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : Alpha Octene. 1- Octene, 2- Octene. 3 3 2 5 2 CH (CH ) CH CH Olefins A clear, colorless , flammable liquid with a slight odor. 0.716 @ 20C

: : Ambient : : Ambient : 30 Can react vigorously with oxidizing materials. Otherwise basically stable. : Portable lines to droplines or manifolds. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possibly : All coatings suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 21 C Draeger Tube No. : Boiling Point : 112 C Explosive Range : % to % Freeze Point : -102C Autoignition Point : Operational Problems/Hazardous May require nitrogen blanket. Check locally. Otherwise no specific problems, treat as normal Low/med. flash solvent. Personnel Protection; Boiler suit , gloves and goggles Check protection Suit compatible with Product

Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Wash tank inert or over rich. Hot SW wash with chemical injection (0.5 hrs 5 ft drops ) Fresh water rinse or steam Educt and mop Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. Soluble in water: NO

OLEFFINS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Alpha Olefins : TBA :3 2 : Cn H n ( General ) : 157 : Hydrocarbon Colorless to pale yellow, depending on type. Strong characteristic odor, similar modeling gule. : 0.688 to 0.82 @ 20C : : : : : : : : : :

Ambient Ambient 30 May react dangerously with oxidizing agents and acids. Load through portable lines and droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possibly Any Coatings

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 2-100 C Draeger Tube No. : CH312 Boiling Point : 67- 280 C Explosive Range : Freeze Point : -136C Autoignition Point : Operational Problems/Hazardous Portable lines should be flushed out as soon as possible Liquid and vapor may irritate skin and eyes. Personnel Protection; Boiler suit , gloves and goggles Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Slight

Cleaning from: Ventilate to gas free or inert Hot chemical sea water wash, 5 ft half hour drops Ventilate to gas free Thoroughly steam tank, line and pump Educt, mop and dry Note : odor is very persistent - extensive ventilation may be required. This product is a mixture shipped under the general name Olefins: , Alpha olefins being the most common. This accounts for the wide ranges of SG flash points, etc. and for a particular Olefin cargo the relevant data sheet should be consulted , viz. : Butene, Diisobytylene , Ethylene, Heptene, Pentene , Etc. M.S - A good M.S tank is OK for every one, excepted SHELL . Go coated or SUS. Good cargoes - No problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

OLEIC ACID
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : Oleine, Red Oil, CIS.9.Octadecenoic Acid. TBA 3 3 2 7 2 7 CH (CH ) CH=CG (CH ) COOH 157a Fatty acid Light yellow to dark brown liquid with a slightly sharp, fatty odor. 0.8939@ 15C

: 0.00069 : 20 C : 25 C : 20 C : 34 Reacts dangerously with oxidizing agents. React with some acids , alkalis and amines. : Portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possible : Stainless Steel or Epoxy or Polyurethane subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : 193 C Draeger Tube No. : Boiling Point : 286 C Explosive Range : % to % Freeze Point : 14 C Autoignition Point : 364 C Operational Problems/Hazardous Spontaneous ignition may occur well below flash point when soaked into absorbent material. Product darkens on exposure to air Liquid irritates the eyes. Personnel Protection; Boiler suit , gloves and goggles Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Soluble in water : Nil

Cleaning from: Cold sea water wash to remove residues and prevent varnishing effect on surfaces Hot sea water wash, 5 ft half hours drops Ventilate to gas free Steam tank, line and pump Educt and mop dry

Tank must be completely dry and grease free Note : Some grades mat dry on surfaces. Check locally when loading product. Heat - During the voyage , no heat is needed when in warm climate. Handle as Tallow No Problems. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

OLIVER OIL
Synonyms UN. No CHris Code : Sweet Oil : : OOL

Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: Mixture including oleic : Pale yellow or greenish-yellow liquid; slight characteristic odor. : V.High : : 0.91~0.92 : Ester : 2.04 : :D : 0.1 :D : 0.15 : Negligible : NP No specific handling regulations Portable lines to droplines or ships line to deck lines. : NO : Purge : No Blanket : NO Epoxy, Polyurethane, Stainless Steel.Can be carried in Zinc Silicate if FFA is below 5% and Not recommended to be stored in zinc Silicate for more than two Months.

Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance Exposure Procedure

: : : : : : : :

Combustible liquid D Slight fire hazard when exposed to heat or flame. 437 Unavailable 650 Dry chemical, foam or carbon dioxide. Water may be ineffective on fire. Cool exposed tanks with water.

: : : : : : : :

0,0,0 Unavailable Not pertinent Not pertinent Not harmful None Non-toxic Non toxic. Wash thoroughly with soap and water.

Reactivity Data Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 34 of compatibility chart. Spill or Leak Procedure Operational Problems/ Hazards May require food tank, and surveyor may not accept tank where last cargo could have leached into coatings. High cleanliness and coatings standard required Heat as per shippers instructions. Personnel Protection

Boiler suit, normal working gear Tank cleaning Pre-clean with warm sea water to remove residues Hot wash with chemical injection . Spot cleaning may be required Ventilate If residues removed, thoroughly steam tank and lines. Ventilate Educt and mop dry Tank must be dry ZINC - If FFA is below 2% upon loading Zinc O.K Edible : This grade can go in Phenoline providing the coating is perfect . SUS may be requested/ required. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

ORANGE OIL OF TURPENTINE

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : : : : : : : : d- Limonene, 1- Methyl-4- Isopropenyl-1-Cyclohexene. 1299 3 C10 H16 Hydrocarbon ( Olefins) Water white to yellowish Slight orange odor. 0.84532

: 0.00054

Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Ambient : : Ambient : 30 : Large surface area exposed to air may cause spontaneous heating. : Load through portable lines and droplines : NO(Ensure Certificate obtained and Duration Checked) : Purge Possibly Blanket : Possible Stainless Steel or Zinc, Polyurethane or Epoxy, but subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 45 C Draeger Tube No. : Boiling Point : 175 C Explosive Range : 0.8 % to % Freeze Point : -57 C Autoignition Point : 253 C Operational Problems/Hazardous This product is a flammable organic solvent, subject to oxidation . Steps should be taken to minimize oxidation, i.e. tank ullage to absolute minimum, otherwise product will adhere to tank sides Vapor inhalation is harmful, the liquid may irritate skin and eyes. Personnel Protection; Boiler suit , gloves and goggles, Breathing Apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO If no shore facilities available retain on board until on passage. Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Cold sea water wash pre-wash Ventilate to gas free ( or inert ) Hot chemical sea water wash, 5 ft half hour drops If any residues remaining spray with Toluene Hot sea water wash ( Check LEL ) Fresh water rinse Ventilate Educt and mop dry The product has only been carried once to date, this subject to change as feedback obtained. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Soluble in water : Negligible

May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

ORTHO CRESOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor : O-Cresylic acid, O-Hydroxytoluene, 2-Methyl phenol, O-Crestylol. : 2076 :3 3 6 4 : CH C H OH : 49 : Phenol White liquid ( Forming white crystals upon freezing ) Sharp disinfectant odor. : 1.047@ 20C : 0.0008 : 50 ~ 70 C : 50 ~ 70 C : 50~ 70 C : 21 Reacts dangerously with oxidizing agents. Some acids, alkalis and acid anhydrides. : Compoflex hoses to droplines : NO(Ensure Certificate obtained and Duration Checked)

Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Purge Possible Blanket : YES : Stainless Steel or Zinc with some restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : 5 ppm TLV 5ppm Flash point : 80 C Draeger Tube No. : CH315 Phenol 5/a Boiling Point : 191 C Explosive Range : % to % Freeze Point : 28-31 C Autoignition Point : 538 C Operational Problems/Hazardous Liquid and vapor cause severe burns to the skin and eyes. Skin absorption , ingestion and inhalation will have serious effects and may be FATAL. Personnel Protection; Total protection suit Restrict personnel on deck Secure accommodation and recirculate air. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A

Vapor Return System Reg. : YES Residues should be pumped to shore reception facilities but if these are not available then retain on board until on passage and then discharge as per control regulations. Drying oil : NO Soluble in water : Very slight

Cleaning from: Ventilate to gas free , or inert, Hot sea water wash , 5 ft half hour drops Steam tank, line and pump, Educt and mop Tank must be dry Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (B)Warm water (38 to 55 degree C ) HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is

not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

OLEIC ACID
Synonyms : Oleine, Red Oil, CIS.9.Octadecenoic Acid. IMO No : TBA IMO TYPE :3 3 2 7 2 7 Formula : CH (CH ) CH=CG (CH ) COOH ICS Guide Page No. : 157a Family : Fatty acid Appearance and character : Light yellow to dark brown liquid with a slightly sharp, fatty odor. Specific Gravity : 0.8939@ 15C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00069 Carriage : 20 C Disch . : 25 C Average Expected Load Temp. : 20 C USCG Compatibility chart Group No : 34 Reactivity: Reacts dangerously with oxidizing agents. React with some acids , alkalis and amines. Handling : Portable lines to droplines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : Possible Tank Coating recommended : Stainless Steel or Epoxy or Polyurethane subject to restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 193 C Draeger Tube No. : Boiling Point : 286 C Explosive Range : % to % Freeze Point : 14 C Autoignition Point : 364 C Operational Problems/Hazardous Spontaneous ignition may occur well below flash point when soaked into absorbent material. Product darkens on exposure to air Liquid irritates the eyes. Personnel Protection; Boiler suit , gloves and goggles Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Retain on board until on passage then Discharge on passage as per control regulations. Drying oil : NO Cleaning from: Cold sea water wash to remove residues and prevent varnishing effect on surfaces Hot sea water wash, 5 ft half hours drops Ventilate to gas free Steam tank, line and pump Soluble in water : Nil

Educt and mop dry Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

ORTHO NITROCHLOROBENZENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : ONCB, Ortho chloronitrobenzene, 1-CHloro-2-Nitrobenzene. 1578 2 6 4 1 2 C H C NO

Family : Nitrobenzene Appearance and character : Clear liquid with not more than a trace of visible impurity. Specific Gravity : 1.36 @ 22C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : Reactivity : Handling : Ships lines to poison bank or deck tanks.Deck tank stowage preferred Lines to be blown with Nitrogen Inhibitor : NO(Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : No Tank Coating recommended : Stainless Steel or Zinc but subject to restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 127 C Draeger Tube No. : Boiling Point : 245 C Explosive Range : % to % Freeze Point : 33 C Autoignition Point : C Operational Problems/Hazardous Product is highly toxic by ingestion, skin absorption and inhalation of vapor. No available data on reactivity Stow away from adjacent heat - emits highly toxic flammable vapor when heated. Personnel Protection; Total chemical protection suit Restrict personnel on deck Secure accommodation and recirculate air Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Retain slops on board Discharge on passage as per control regulations. Drying oil : NO Soluble in water : NO Cleaning from: Cold sea water wash to remove residues Hot sea water wash with chemical injection Ventilate and inspect ( Full protection suit and breathing apparatus required.) Re-wash if required. Fresh water rinse or steam Ventilate to gas and odor free Educt and mop Tank must be dry and grease free. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible.

These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ORTHONITROTOLUENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : ONT, O-Nitro- Toluol, Ortho-methylnitrobenzene. 1664 2 2 6 4 3 NO C H CH Nitrocompounds A Yellow liquid with characteristic almond smell. 1.1678 @ 15C

: 0.00097 : Ambient : : Ambient : 42 : Can react with oxidizing agents and organic acids,. Portable lines to drop lines or ships lines to deck tanks poison banks. : NO(Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : Possibly Stainless Steel or Epoxy or Polyurethane, Zinc silicate. Deck tanks or poison bank recommended because of high toxicity.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 5 ppm Flash point : 106 C Draeger Tube No. : Boiling Point : 222 C Explosive Range : % to % Freeze Point :-9C Autoignition Point : V.high Operational Problems/Hazardous Highly toxic vapor and liquid avoid all contact. Use Closed loading method for ullaging. Stow away from heated cargo. May require nitrogen blanket check locally. Lines should be cleared with nitrogen. Personnel Protection; Full protection clothing and B.A Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO Retain slops well diluted discharge on passage according to regulations. Drying oil : NO Soluble in water : V. Slight Cleaning from: Wash with tank inert. Cold SW pre-wash to remove residues (1.5 hours) Hot SW wash with chemical injection (.5 hrs 5 ft. drops) Fresh water rinse or steam

Ventilate to gas and odor free Educt and mop Tank must be dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

ORTHO-XYLENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Benzene, dimethyl-; 1,2-dimethyl benzene; Orthoxylene; ortho-Xylene; Xylol : 1307 : XLO 6 4 3 2 : C H (CH ) : Colorless liquid; benzene like- aromatic odor. : 144C/ 292F : -25C/ -13F : 0.89 : Aromatic hydrocarbons : ** :C : C* : 0.28 : D,O : 0.40 : Negligible : 3.66 : Portable lines to droplines : NO : Purge : NO Blanket : NO : Most coatings suitable

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General: Moderate fire hazard, when exposed to heat or flame. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : 90 Flammable Limits : 1.1~ 7.0% Auto igniting Temp.(F) : 867 Extinguishing Agents : CO2,dry chemical, foam, water fog. Special fire Procedures : Water may be ineffective but water should be used to keep fire exposed containers cool. If a leak or spill has not ignited. Use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spay may be used to flush spills away from exposures. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 0.05 PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Vapor inhalation harmful. liquid irritating. Symptoms : Headache, dizziness, staggering, nausea, and drowsiness. Short Exposure Tolerance: Narcosis in animals beings with inhalations of 2300~350o ppm. Instances of unconsciousness in humans from severe exposures have been described, but the specific concentrations were unknown. Exposure Procedure :

Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and flush affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : Most materials of construction are satisfactory. rubber will swell and soften after prolonged exposure. Spill or Leak Procedure Wear polyethylene gloves, face shield, protective clothing. Have all purpose canister mask available. avoid contact with liquid. Secure ignition sources. remarks:* Pollution category C oil-like,33 CFR 151.49 ** Vapor pressure: 10 mmHg @ 32.1c. Operational problems/ Hazards Liquid and vapor cause irritation to eyes and skin ,Stow away from adjacent heat. Personnel Protection Boiler suit, gloves and goggles, Breathing Apparatus on standby Tank cleaning Ventilate to gas free, or inert Hot sea water wash, 5 ft. half hour drops Fresh water rinse or steam Educt and mop Flash Point - Open cup reading . 64/66 - Ventilate talk for at least 24 hours After discharge. - to harden . Handling - Clean , tank, lines, pump and lines is all thats needed . Excellent cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (A)-

Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS

May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

PALM KERNEL OIL

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character : P.K.O. : N/A :3 : N/A : 19 : Ester A pale yellow oil with a pleasant odor and taste. Solid at ambient temperatures.

Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: 0.92 @ 15C : 0.00068 : 27~ 32 C : 43 ~ 48 C : 46 C : 34 : When mixed with caustic forms crude soap. No specific handling regulations Ships or shore lines. Sometime splash loaded without droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Epoxy, polyurethane , Stainless steel Check coating lists and FFA % against them.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : 26 ~30 C Autoignition Point : Operational Problems/Hazardous Requires strict adherence to charterers heating instructions. Tanks required to be swept, therefore oxygen content to be checked before tank entry. Amount of sweeping required often depends on whether tank has double bottom and the state of sea temperature. Product often forms very hard skin on tank bottom if sea temperature is low. After discharge, line usually cleared ashore with steam Temperature rise when heating not to exceed 6C/day Personnel Protection; Normal working gear with goggles, gloves Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO Some time slops pumped ashore, or discharge to sea according to regulations. Drying oil : NO Soluble in water : NO Cleaning from: Steam down.. Very hot wash with chemical injection ( temperature maximum compatible with coating ) Spot clean as required, this may be extensive , especially in winter time. It may also be necessary to scrape the persistent spots Fresh water rinse or steam Ventilate Educt and mop Note : It may necessary to wash the tank several times before it will be acceptable to carry solvents. Tank must be dry For long voyage , start heating 7-10 day before arrival at discharge port. Some surveyors may refuse tanks that have carried PKO no matter how clean they are,

if they are to carry solvents. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

(PARA) CHLOROTOLUENE
Synonyms : 4-Chloro-1-Methylbenzene. IMO No : 2238 IMO TYPE : Formula : C6 H4 C1.CH3 ICS Guide Page No. : 463 Family : Chlorotoluene Appearance and character : Colorless liquid with distinctive odor. Specific Gravity : 1.065 @ 25C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00097 Carriage : Above 10 C Disch . : Average Expected Load Temp. : Above 10C USCG Compatibility chart Group No :5 Reactivity: May react with oxides. Insufficient data on compatibility with other products - ensure kept separate Handling : Portable lines to drop lines, or ships lines to deck tanks./ poison banks.

Compoflex hoses are NOT suitable with this product Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : NO (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Possibly : Stainless Steel or Zinc .

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 49 C Draeger Tube No. : Boiling Point : 162 C Explosive Range : % to % Freeze Point : 7C Autoignition Point : Operational Problems/Hazardous Flammable and must be kept dry Liquid and vapor are Harmful - Avoid any contact Product will become corrosive if wet. Personnel Protection; Protective clothing , gloves, goggles and breathing apparatus. Secure accommodation and recirculate air.

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : A

Vapor Return System Reg. : NO Retain slops well diluted discharge on passage according to regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Cold sea water wash to remove residues ( Minimum 2 hours ) Ventilate to gas/ odor free Hot sea water wash, 5 ft. half hour drops Ventilate Fresh water rinse ( steaming may be required ) Educt and mop Tank must be dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 7. Cargoes such as esters, acetates and halogenated hydrocarbons can form mineral or organic acids when mixed with water. To prevent any damage to coated tanks the water/slop must not be allowed to stay in the tank during or after the tank-cleaning program.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

CRESOLS
Synonyms Cresol(2,3,4) cresylic acid, cresylol, Hydroxymethyl benzene Hydroxytoluene, methylphenol(2,3,4-), Oxytoluenes, Tar acids, Toluol, Tricresol : 2076 : CRS : CH3C6H4OH : Colorless to brown liquid, smells : 146~192C/ 295~378 F. : 12~35C/ 54~95 F : 1.03~1.05 : Phenol : 0.52 :C :A : 0.03 :O : 0.06 : 2.5% : 3.72 : Compoflex hoses ( with restrictions ) to dropline : NO : Purge : Possible Blanket : YES : Stainless Steel or zinc with restrictions

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General:

: Combustible. :D

Moderate fire hazard when exposed to heat Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents

or flame. when heated, toxic vapors are given off. : 178 ~187(varies with composition and purity) : LEL= 1.1% UEL= unavailable. : 1038~1195 : CO2,dry chemical, foam, water fog.

Special fire Procedures : Full body and respiratory protection should be provided. use water to keep fire exposed tanks cool. Use water spray to disperse vapors. Health Hazard Data Health hazard Rating : 2,3,2 Odor Threshold(ppm) : 1~5 PEL/TWA(ppm) : 5/skin TLV/TWA(ppm) : 5/skin General : Suspected carcinogens. causes severe burns. poisonous by skin absorption. Odor threshold is about the same as the TLV. exposure to potentially dangerous vapor concentration can occur before the product can be detected by smell. Symptoms: Burning sensation in throat, nose and eyes. burning sensation at the site of contact, skin may tun white. Short Exposure Tolerance: Extensive skin contact may be fatal in a very short time. Exposure Procedure : Vapor- remove victim to fresh air, if breathing stops, apply artificial respiration skin or eye contact- remove contaminated clothing and gently flush affected area with water for 15 min. Get medical advice or attention. Reactivity Stability: Not dangerously reactive. Compatibility: Material: Not considered corrosive to most of the usual material of construction. Cargo : Group 21 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, and protective clothing. avoid contact with the liquid. do not flush into navigable water it may be contacted by humans or animals. Operational Problems / Hazards Both liquid and vapor will cause severe burns to the skin and eyes. Skin absorption , ingestion and inhalation will be Very harmful, if not Fatal. May require a vent line desiccant Product is stable up to its boiling point, but will darken when exposed to light ( Properties similar to Phenol ) Personnel Protection Total Protection suit , Restrict personnel on deck Secure accommodation and recirculate air. Tank cleaning Ventilate to gas free, or inert Hot sea water wash, 5 ft. half hour drops Steam tank, line and pump Educt and mop Slops should be discharge to a shore reception facility.

Color-/Grades - Ortho Grades with clear color need to be carried under Nitrogen pressure. If color is remain clear. Other grades shipped no Nitrogen required /requested . Heat- follow heating instruction -raise temp slowly max. 10F/ day. Handling - Use protective clothing mask when working around this product. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X Wash water temperature Code (B)Warm water (38 to 55 degree C ) HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

p-CYMENE
Synonyms Cymol; dolcymene; 4-Isopropyl-1-methyl benzene; Isopropyltoluene; 4-Isopropyl toluene, p-isopropyl toluene, Methylisopropylbenzene, 1-methyl-4-isopropylbenzene, methyl propyl benzene. : 2046 : CMP 3 6 4 3 2 : CH C H CH(CH ) : Colorless liquid; benzene odor : 177C/ 351F : -68C/ -90F : 0.86 : Aromatic hydrocarbon : Low : : C* : Low : D,O : 0.46 : Negligible : 4.62 : Portable lines to droplines : NO : Purge : NO Blanket : NO : Any coatings

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :D General : Slight explosion hazard when in the form of vapor. Flash Point (F) : 117 Flammable Limits : 0.7~5.6% Auto igniting Temp.(F) : 817 Extinguishing Agents : CO2,dry chemical, water fog. foam. Special fire Procedures : Fight in the same manner as any grade D petroleum product fire . Water may be ineffective. the vapors of cymene are more toxic than those of petroleum products. Health Hazard Data Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance

: : : : : : :

0,1,1 Unavailable Unavailable " High vapor concentrations are intoxicating. Dizziness, headache, and nausea. the victim may at as if drunk. Unavailable.

Exposure Procedure : Vapor-remove victim to fresh air. if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical attention. Reactivity Stability: Stable.

Compatibility: Material : Cymene will cause rubber to swell and soften. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Secure ignition sources. remarks: * Pollution category C oil like, 33 CFR 151.49. Operational Problems / hazards Product is practically non-hazardous, although liquid may cause some defatting. Vapor cause irritation and nausea at high concentrations Vapor is easily detectable at low concentrations in confined spaces. Personnel Protection Boiler suit, goggles , gloves Tank cleaning Cold sea water wash for minimum of 2 hours Ventilate to gas and odor free Fresh water rinse Educt and mop Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS

May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

PARAFFIN WAX
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity : : : : : : : : Hard wax; paraffin; paraffin scale; Petroleum wax. WPF High weight hydrocarbons. White to yellow translucent ~370C/ ~698 F 42~60C/ 108~140F 0.80~0.88

Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Tank Coating Fire & Explosion Hazard Data Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: : : : : : : : : : : :

Saturated hydrocarbon V.Low III " D " Negligible NP Load through portable lines and droplines NO Stainless steel, epoxy, polyurethane, zinc restricted check acid value

: : : : : : : :

Combustible D Slight fire hazard if subjected to heat or flame. 380~465 Unavailable 473 Confined are-CO2,dry chemical pen area-foam, water spray. Water or foam may cause frothing.

Health Hazard Data Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 2 mg/m3 as a fume TLV/TWA(ppm) : 2 mg/m3 as a fume General : Non-toxic, but possibility of thermal burns from hot liquid. Symptoms : Non- toxic. short Exposure Tolerance : Non-toxic. Exposure Procedure : Liquid on skin- remove wax and contaminated clothing and cool affected areas with water. Liquid in eye- flood eyes gently with clean sea or fresh water. continue washing for at least 15 minutes. Get medical attention. Reactivity Data Stability: Stable Compatibility: Material: Usual materials of construction are suitable. Spill or Leak Procedure Avoid with hot liquid. Wear goggles or face shield, protective clothing for hot liquid. Clean or scrape up into containers. remarks: Normally transported at elevated temp. See 46 CFR 36- Elevated temp. Cargoes. ++ Unassigned Operational problem/ Hazards Practically non-hazardous Check heating instructions prior to loading as effective temperature limit on Epoxy and Polyurethane is 75~ 80C. Personnel Protection Boiler suit , glove and goggles

Tank cleaning Hot chemical salt water wash, 5 ft half hour drops Ventilate Through steam of tank, line and pump Educt and mop Chemical injection may be required Exxon /MS- The Exxon people surveyor are very strict in their tank inspection if M.steel i.e. presented. With lined tanks - no problems. Mobil 141/145 : Before loading fresh water is covering bottom . Discharge not through lines, but overhead. Slack Wax - This is usually a poorer grade with minimum requirement for loading /discharge. Cleaning - As soon as tank is empty, fill 3 feet of Hot water into tank leaving heating coils on full until Hot-HOT. butterworthing commences - All thats needed is heat repeat Heat for cleaning after any grades of Wax. Uses : Candles, waxed paper, waterproofing wood, preserving egg, electrical insulation and many other uses. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture).

PARALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter p-Acetaldehyde; paracetaldehyde; 2,3,6-Trimethyl-1,3,5-trioxane; 1,3,5-trioxane, 2,4,6-trimethyl : 1264 : PDH : C6H12O3 : Colorless liquid; aromatic odor. : 128C/ 262 F : 13C/ 55 F : 0.994 : Aldehydes :+ :C :C :+ :O

Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : :

8.3 Slight 4.55 Ships lines only NO purge : Possible Blanket : Possible Most coatings suitable, however, check lists for restrictions.

Fire & Explosion Hazard Data Grade-D : Combustible liquid Electrical Group :C General: Toxic fumes are given off when heated. Dangerous when exposed to heat, flame, or oxidizers. Flash Point (F) : 96 Flammable Limits : LEL= 1.3%, UEL- Unavailable Auto igniting Temp.(F) : 460 Extinguishing Agents : Alcohol foam, Co2, or dry chemical Special fire Procedures : Water may be ineffective on fire. wear full protective clothing and respiratory protection. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapor harmful if inhaled. Symptoms: Irritation, headache, bronchitis, incoordination, drowsiness, digestive disturbance Can cause serious eye injury. Short Exposure Tolerance: 4000 ppm fatal to 3 of 6 rats in hours. The lowest toxic dose for humans is 14 mg/kg. Exposure Procedure : Remove from exposure; give artificial respiration or oxygen if needed. flush eyes with water for 15 min. wash skin with soap and water. Remove contaminated clothing and shoes. Reactivity Data Stability: Dangerous when exposed to heat or flame. Can react vigorously with oxidizing materials. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 19 of compatibility chart. Spill or Leak Procedure Wear protective clothing, goggles and self contained breathing apparatus. Avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards Stow away from heated cargo as toxic vapor emitted at elevated temps. Has a hypnotic and analgesic effect, avoid skin contact. Check spec. for purity/ acid content. Personnel protection Gloves, B.A Tank cleaning Hot wash with chemical injection, Fresh water rinse or steam Ventilate to gas and odor free, Educt and mop dry

Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

para-XYLENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Fire & Explosion Hazard Data Grade-D Electrical Group Benzene, dimethyl-; 1,4-dimethyl benzene; Paraxylene; para-xylene; Xylol : 1307 : XLP : C6H4(CH3)2 : Colorless liquid; benzene-like aromatic odor. : 138C/ 281 F : 13C/ 56 F : 0.86 : Aromatic hydrocarbon : ** :C : C* : 0.34 : D,O : 0.51 : Negligible : 3.66 : Portable line to droplines : NO : Purge : NO Blanket : NO : Any, but Zinc preferred

: Combustible liquid :D

General : Moderate fire hazard, when exposed to heat or flame. Flash Point (F) : 81 Flammable Limits : 1.1~ 7.0% Auto igniting Temp.(F) : 870 Extinguishing Agents : CO2, Dry chemical, water fog. Special fire Procedures : Water may be ineffective but water should be used to keep fire exposed containers cool. if a leak or spill has not ignited. use water spray to disperse the vapors and to protect men attempting to stop a leak. Water spray may be used to flush spills away from exposures. Health Hazard Data Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 0.05 PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Vapor inhalation harmful. Symptoms : Headache, dizziness, nausea. Short Exposure Tolerance: Narcosis in animal beings with inhalation of 2300~ 3500 ppm. instances of unconsciousness in humans from severe exposures have been described, but the specific concentrations were unknown. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Reactivity Data Stability: Stable. Compatibility: Material : Most materials of construction are suitable. Rubber exposed to xylene will swell, soften and eventually deteriorate. Cargo : Group 32 of compatibility chart. Spill or Leak Procedure Wear polyethylene gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. remarks: Pollution Category C oil-like, 33 CFR 151.49. * Vapor pressure : 10 mmHg @ 28.3c. Operational problems/ Hazards Product may require some heat during carriage and discharge if climate cold. Possibly a high specification cargo Liquid and vapor may irritate the eyes and skin, Inhalation of vapor may lead to loss of consciousness. Flash Point - Open cup reading . 64/66 - Ventilate talk for at least 24 hours after discharge - to harden Handling - Clean , tank , pump, and lines is all thats needed. Excellent cargoes. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product.

Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID

Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

PENTACHLOROETHANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : : : : : : : : : : : : : : : : : : : : : Ethane, pentachloride, ethane, pentachloro-pentalin. 1669 PCE 2 3 CHCI CCI Liquid with sweetish chloroform odor. 162C/ 324 F -29C/ -20 F 1.67 Halogenated hydrocarbon * A B + O + Insoluble 7.0 Ships lines to poison bank/deck tanks NO Purge : Possible Blanket : Possible Any, with restrictions

Fire & Explosion Hazard Data

Grade: Non flammable Electrical Group : NA General: Dangerous when heated to decomposition; dehalogenation will produce spontaneously explosive chloroacetylenes. Flash Point (F) : Non-flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : " Special fire Procedures : "

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) : Unavailable : Unavailable

PEL/TWA(ppm) : " TLV/TWA(ppm) : " General : Highly narcotics. eye and upper respiratory tract irritant. Symptoms: Has been indicated as being more narcotic than chloroform. Exposure to this material may cause injury to liver, lung and kidneys. Has alcohol irritating effect on eyes and upper respiratory tract. Short Exposure Tolerance: Lethal oral dose of 1.75 g/kg of body weight in dogs. Exposure Procedure : Vapor- remove victim to fresh air and administer artificial respiration if necessary. Skin flush affected areas with water. Eyes- flush with water for 15 min. in all cases call a doctor.

Reactivity Data
Stability: Stable. Compatibility: Material : Usual materials of construction are satisfactory.

Spill or Leak Procedure

Wear rubber gloves, self-contained breathing apparatus and protective clothing. secure all ignition sources. remarks: Vapor pressure :3.4 mmHg@ 25 C. Operational Problems /Hazards It is thought that a lethal dose in man is 50-500 mg/kg. Odor threshold is insufficient to provide adequate warning of dangerous vapor concentrations. Product is stable for 6-8 months if stored in a cold place,away from direct light. Exposure to light causes decomposition with the production of hydrochloric acid. Strong alkalis will react to form explosive chloroacetylenes Product is considered to be a poison Vapor and liquid cause irritation of eyes and skin Skin absorption is possible, Inhalation of vapor may cause unconsciousness. Personnel Protection Chemical protection suit , gloves and Breathing apparatus Tank cleaning Ventilate to gas free or inert Hot sea water wash, 5 ft half hours drops Steam out tank, line and pump Educt and mop ADJ-64/66 - No heat adjacent if this coating in use. Poor coating for this product - it soften. Discharge : Be prepared to use portable pumps for stripping if suction is lost on piston pumps. No problems with M/pumps No other problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product.

Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating. HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature delayed; keep victim under observation.

iso-PENTANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : : : : : : : : : : : : : : : : : : : : : Ethyl dimethylmethane; Isoamyl hydride Isopentane;2-methylbutane 1265 IPT (CH3)2CHCH2CH3 Colorless Mobil, liquid; pleasant odor 28C/ 82 F -159C/ -255 F 0.62 Saturated hydrocarbons 510 C* 20 D,O 27 Insoluble 2.48 Load through portable lines and droplines NO Purge : NO Blanket : Possibly Any coatings

Fire & Explosion Hazard Data

Grade-A : Flammable liquid Electrical Group :D General: Severe explosion hazard in enclosed space in presence of a source of ignition. Electrostatic generation likely. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : -70 Flammable Limits : 1.4~ 7.6% Auto igniting Temp.(F) : 788 Extinguishing Agents : Foam, Co2, dry chemical Special fire Procedures : Water may be ineffective on fire. Cool exposed tanks with water. Use water spray to "knock down" vapors.

Health Hazard Data

Health hazard Rating : 0,0,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid irritating to skin and eyes. Inhalation causes slight local irritation. An aspyxiant, also, a narcotic in high concentrations resulting in dizziness and drowsiness. Symptoms: Breathing high concentrations of vapor for some time may cause dizziness, drowsiness. Short Exposure Tolerance: Unavailable Exposure Procedure : Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact; Remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Stable. Dangerous reaction possible with oxidizing agents. Compatibility: Material : Certain plastics are unsuitable. Cargo : Group 31 of compatibility chart.

Spill or Leak Procedure

Wear polyethylene gloves, face shield, protective clothing, Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Do not flush spill into confined spaces where flammable vapors can accumulate. remarks: Pollution Category C oil-like, 33 CFR 151.49 Operational Problems/ Hazards If Bondstrand used, they should be flushed out as soon as possible Because of its low boiling point this product cannot be carried without some over-pressure to minimize/ prevent boil-off, unless cooled climatic conditions. May irritate the skin and eyes Product has a high vapor pressure, therefore pumps may be liable to gas up Stow away from adjacent heat. Personnel Protection Boiler suit, gloves and goggles, Breathing apparatus standby Note : Some rubbers attacked - Nitryl suitable. Tank cleaning Cold sea water bottom wash to remove residues Gas free or inert Hot sea water wash Ventilate Steam tank, line and pumps. Educt and mop dry The ratios of isomers may vary with different cargoes. The physical constant may therefore vary from those given. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS

May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

1-PENTENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) : : : : : : : : Alpha-N-Amylene. 1108 3 ( Chapter VII) CH3 CH2 CH2 CH : CH2 Hydrocarbon ( Aliphatic Unsaturated ) Colorless liquid with a characteristic odor. 0.641 @ 20C

Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : :

Ambient Ambient 30 React dangerously with oxidizing agents and some acids. Portable lines to drop lines, . NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possibly ANY.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : C Autoignition Point : 273 C Product has high vapor pressure Operational Problems/Hazardous Cargo should only be carried in temperature climate water spray deck to cool cargo if required. Stow away from adjacent heat Liquid will irritate eyes, Inhalation of vapor asphyxiates, also has a narcotics effect. Personnel Protection; Boiler suit , gloves and goggles Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO Retain on board until on passage then discharge as per regulations. Drying oil : NO Soluble in water : NIL Cleaning from: Ventilate to gas free, or inert Hot sea water wash, 5 ft. half hour drops Fresh water rinse,Educt and mop Tank must be dry Mixed : This grades could be shipped without cooling. Other grades need cooling. Advice : Cool all grades downs to a safe level. Pumps : deep well pumps are the right ones- M/Pumps. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire, Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

2- PENTENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling : : : : : : : : : : : : : : : SYM-Methyethylethylene, Beta-n- Amylene TBA CH3 CH2CH : CHCH3 163 Hydrocarbon ( Aliphatic unsaturated ) Colorless liquid with a characteristic odor. 0.65 @ 20C

Ambient Ambient 30 Reacts possibly dangerously with oxidizing agents acids water and air.

Portable lines to drop lines, but should be thoroughly blown with nitrogen and flushed through as soon as possible. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge Possible Blanket : YES Tank Coating recommended : ANY Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 45 C Draeger Tube No. : Boiling Point : 36 C Explosive Range : 1.4 % to % Freeze Point : -130 C Autoignition Point : Product has high vapor press. Operational Problems/Hazardous Reaction with air and moisture will cause combustion, thus possibility of purge required before loading and should be carried under a blanket of inert gas, Liquid and vapor are Harmful - Avoid any contact Will also require a vent line desiccant Stow away from adjacent heat - due to low BP should only be carried in temperate climates. If required, water spray decks to cool cargo. Liquid will irritate the eyes, Inhalation of vapor causes asphyxiation and also has a narcotic effect. Personnel Protection; Boiler suit, gloves, and goggles, Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO Retain slops well diluted discharge on passage according to regulations. Drying oil : NO Soluble in water : NIL Cleaning from: Maintain inert atmosphere in tank, Cold sea water wash to remove all residues Hot sea water wash, 5 ft half hour drops Fresh water rinse or steam Educt and mop. Tank must be completely dry Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

PERRILLA OIL
Synonyms : IMO No : TBA IMO TYPE :3 Formula : ICS Guide Page No. : 19 Family : Ester Appearance and character : A light yellow oil, liquid at normal temperatures. Specific Gravity : 0.928 to 0.9233 @ 15C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient normally Disch . : Average Expected Load Temp. : Normally ambient USCG Compatibility chart Group No : 34 Reactivity : Can react with oxidizing materials also subject to spontaneous heating. Handling : Load through drop lines for quality control. No specific handling regulations. Lines must be clean and dry. Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Epoxy, Polyurethane, stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold :

Flash point Draeger Tube No. Boiling Point Explosive Range Freeze Point Autoignition Point

: 286 C : : : : C :

Operational Problems/Hazardous May require sweeping depending upon temperature As it is a drying oil, check oxygen content before tank entry Keep away from heated cargo. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO Cleaning from: Cold sea water wash immediately after discharge to remove residues. Hot sea water wash with chemical injection ( .5 hours 5 ft drops ) Ventilate Spot clean as required ( Observe tank entry procedure ) Fresh water rinse or steam Ventilate Educt and mop Tank must be dry

PETOLEUM SULPHONATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : TBA 3 Variable Saturated hydrocarbons A clear to yellowish rather viscous liquid. 0.98 to 1.135 @ 15C

50 C 65 C 40~50 C 34 Can react with oxidizing agents, otherwise basically stable. Portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Polyurethane, stainless steel. Zinc silicate with restrictions

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 204 C Draeger Tube No. : Boiling Point : Explosive Range : % to % Freeze Point : C Autoignition Point : Operational Problems/Hazardous No significant hazards Product is a highly refined mineral oil containing a variable suphonate radical.

Will require high standard of tank cleanliness Easily emulsified with water, therefore tank must be dry Will defat skin - avoid contact. Personnel Protection Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO Cleaning from: Cold sea water wash to remove residues ( 2 hour)to ( Some sulphonates may produce heavy foam build up ) Hot sea water wash with chemical injection ( .5 hours 5 ft drops ) Fresh water rinse or steam Ventilate Educt and mop dry Note : It may be necessary to spray neat chemical on tank surfaces if greasy areas persist. Tank must be dry

PETROLEUM SULPHONATE C-300

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Bryton Hybase C-300 : : : : : : Thick viscous heavy lube additive . black ( Makers Lubrizol ) : 1.161 @ 60F : : : : : : : : : :

Ambient 150 -170F 150 F Min. React with water to Gel. NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : YES

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Highly susceptible to water contamination, when forms gel. and becomes useless. Is not miscible with water. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations.

Drying oil : NO Soluble in water : Cleaning from: Spray with Kerosene/ Paraffin , approx. 100 liters per average tank. Spray then with perolin 818 or equivalent. Hot sea water wash with chemical injection ( .5 hours 5 ft drops ) Wipe and greasy marks with chemical, Steam, Educt and mop dry Japanese receivers request discharge temp 65-75 C Great care must be taken to ensure that cleaning is a continual process as any remaining product gels and sticks in patches, that are difficult too remove. This information applies equally to petsulp M-400, which similar in all properties and qualities.

PHENOL
Synonyms Benzene,hydrox-; carbolic acid; hydroxybenzene; monohydroxybenzebe; oxybenzene; phenic acid; phenyl hydroxide; phenylic acid. : molten-2312/ solid-1671 : PHN 6 5 : C H OH Colorless-to pink solid or thick liquid; sweet, disinfectant-like odor(like Lysol) : 182C/ 359 F : 41C/ 106 F : 1.07 : Phenol :* :C :B : 0.3 :O : 0.6 : at 16c, 6.7% @ 66C. : 3.24

UN. No CHris Code Formula Appearance-Odor

Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Ships lines to poison bank or deck tank stowage Is compatible with compoflex but Not bondstrand Inhibitor : NO Nitrogen : Purge : Possibly Blanket : YES Tank Coating : Stainless steel or Zinc but subject to restrictions

Fire & Explosion Hazard Data Grade-E : Combustible Electrical Group :D General: When heated, it emits toxic and irritating fumes. Moderate fire hazard when exposed to heat or flame. Flash Point (F) : 185 Flammable Limits : 1.7~8.6% Auto igniting Temp.(F) : 1319 Extinguishing Agents : CO2,dry chemical, alcohol foam, water fog. Special fire Procedures : Where there is Danger of skin contact, provide full body protection. Full respiratory protection should be worn by fire parties at all times. Health Hazard Data Health hazard Rating

: 2,3,3

Odor Threshold(ppm) : 0.047 PEL/TWA(ppm) : 5/skin TLV/TWA(ppm) : 5/skin General : Causes severe burns. poisonous by skin absorption. Class B poison. Symptoms: Headache, weakness, ringing of the ears, and irregular breathing. Skin contact will cause white, winkled, soft skin at site of contact. Absorption through skin is rapid and can cause death within 30 minutes after exposure. Short Exposure Tolerance: Unavailable. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get victim to a hospital or treatment center as soon as possible. All exposure victims should get medical attention. Reactivity Data Stability: Stable. Compatibility: Material : rubber, aluminum and its alloys,zinc and lead are attacked by phenol. Cargo : Group 21 of compatibility chart. Spill or Leak Procedure Wear rubber gloves, face shield, protective clothing, Have all purpose canister mask available. do not permit anyone near spill unless suitably protected. remarks: Normally transported at elevated temp. See 46 CFR 36- Elevated Temp. cargoes. Vapor pressure: 30.6 mmHg @ 25 C. Operational Problems / Hazards Phenol is an extremely dangerous combustible poison Exposure to either the liquid or vapor will lead to serious burns, gangrene and dermatitis. It May be Fatal. The vapor may condense and solidify causing blockage of flame screen and pressure vacuum valves. Product is hygroscopic, therefore vent line desiccator required. Closed ullage system should be used. Personnel protection Total protection suit, restrict personnel on deck. Secure accommodation and recirculate air during loading, discharging and tank cleaning . NOTE : Gloves should be of Butyl Rubbers. Tank Cleaning Gas free or inert, Hot sea water wash, 5 ft half hour drops Ventilate, Steam tank, line and pump, Educt and mop Tank must be completely dry Heating - Disconnect return lines from heating coils on deck. Return (Condensate ) must be tested before reuse. Handling - Be sure to use protective clothing mark,when working around this very Dangerous cargo. Study all safety data sheet available. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X.

Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture). Reference note 18. These cargoes leave an odor that in very difficult to remove especially in zinc coated tanks.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

PHOSPHORIC ACID
Synonyms Metaphosphoric acid; Orthophoshoric acid; meta-phosphoric aic;ortho-phosphoric acid; White phosphoric acid. : 1805 : PAC 3 4 : H PO : Clear, syrupy liquid, practically odorless. : <130c/ <266 F : 42C/ 108 F : 1.83 : Inorganic acid : Low :D :D : Low :O :" : Complete : 3.38

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Compatible with portable line, but mainly ships lines to Stainless steel tank. Inhibitor : YES Nitrogen : Purge : Possible Blanket ; Probably Tank coating : Stainless steel only

Fire & Explosion Hazard Data

Grade: Non-flammable. classified as corrosive liquid. Electrical Group : B (based upon possible hydrogen gas(H2) generation should a leak or spill occur) General: Phosphoric acid will not burn. it will react with many metals, giving off hydrogen gas which is highly flammable. If hydrogen is trapped in a confined space, it can form an explosive mixture with air. See data sheet for hydrogen. Flash Point (F) : Non-flammable. Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : " Special fire Procedures : Keep tank cool with water spray. since toxic fumes of oxides of phosphorous are evolved when phosphoric acid is heated to decomposition, fire fighters should be provided with self contained breathing apparatus.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance Exposure Procedure : : : : : : : : 0,3,1 None 1 mg/m3 1 mg/m3 Causes burns. Irritation of skin in contact with liquid; burning of eyes. Unavailable.

Skin contact- remove contaminated clothing and flush affected areas gently with Large amounts of water. Eye contact- Immediately flush eyes gently with water; continue to flush for 15 minutes. Get medical attention.

Reactivity Data
Stability: Stable over a wide temp. range. Compatibility: Material: very corrosive to ordinary ferrous metals and alloys particularly at temp. above 180 F.

Spill or Leak Procedure

Wear rubber gloves, protective clothing. Have body shield available. avoid contact with liquid. secure ignition sources. flush spills with large amounts of water or, if possible, cover contaminated surface and spill with sodium bicarbonate, or a soda ash-slacked lime mixture(50-50) Mix and add water, if necessary to form a slurry. Scoop up slurry. Wash site with soda ash solution. remarks: The information provided is for 100 % phosphoric acid. Operational Problems / Hazards Liquid may cause severe burns to the eyes and skin Vapor may cause mild irritation if inhaled. The SG and freezing point will vary with the concentration of the acid. See notes on page 167.4 in ICS Guide. It may be necessary to lag vents to prevent blockage caused by the condensate freezing. Product is stable until it reaches its boiling point, when it loses water. Product requires agitation on passage. Personnel Protection Chemical protective suit, gloves and goggles ( Rubber is a suitable substance for handling this product ) Tank cleaning Hot sea water wash, 5 ft. half hour drops Ventilate to gas free Steam tank, line and pump Educt and mop Tank must be completely dry and grease free. (wilson ) If discharge cool climate external heat to 86F needed. Acid solidify when cold. but will revert back to liquid state at 80/86F. Purity : All 5 grades are fine product needing no agitation no sediments. All SUS grades O.K. Beker-NOLA/RDM- no agitation needed but keep pump clear by blowing air through pump stack. 11,12,13- there 4 grades needs max. agitation heat sediment. Refer to Appendix Special cargoes manuals.

HEALTH HAZARDS Contact cause burns to skin and eyes if inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.)

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

PINE OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) : : : : : : : : Fir Tree Oil, Huon Pine Oil N/A 3 N/A 19 N/A Colorless to light amber liquid with characteristic pinaceous odor. 0.927-0.940

Correction factor : Carriage : Ambient Disch . : Ambient Average Expected Load Temp. : Ambient. USCG Compatibility chart Group No : Reactivity : Combustible liquid, Low toxicity. Handling : No specific handling regulations, although being combustible should be loaded through drop lines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Epoxy, Polyurethane, Stainless steel, Can be carried in Zinc silicate if FFA is below 5% but not recommended. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 78 C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : C Autoignition Point : Operational Problems/Hazardous Product may cause softening of epoxy coating therefore stow away from adjacent heat. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO Cleaning from: Cold S.W pre-wash minimum 2 hours to remove residues Hot S.W. wash minimum 3 hours chemical injection (temp compatible with coating ) Fresh water rinse or steam, Ventilate Educt and mop dry Pine oil is a loosely defined term which covers a variety of volatile oils with characteristic pinaceous odors. A combustible liquid. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 21. These cargoes can reduce the permanganate time of a methanol wall wash and require the use of an oxidizer in the cleaning process.

POLYETHYLENE GLYCOL
Synonyms : PEG IMO No : IMO TYPE :3 Formula : Various ICS Guide Page No. : Family : Various Glycol Ethers Appearance and character : Clear, generally colorless , slightly viscous liquid with no odor. Specific Gravity : 1.127 to 1.13 @ 20C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient. USCG Compatibility chart Group No : 40 Reactivity: Generally little reaction but check other cargo.

May be discolored by heat and are easily contaminated by heat and moisture. Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : Portable lines to droplines or Shiplines to deck center tanks. NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Any coating subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : + 5 ~ -50 C Autoignition Point : Operational Problems/Hazardous Product is derived from ethylene glycol and ethylene oxide. Generally non toxic and non volatile. Some grades are very high specification for medicines or food and tank cleanliness must be of very high standard. Hoses to be thoroughly steamed before use. All equipment to be dry. Product is easily contaminated by odor, water or rust and damaged by excessive heat. Nitrogen blanket and/or vent line dessiccator may be required. Some grades may require heating, Stow away from adjacent heat. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Partial Cleaning from: Hot S.W wash 5ft. 0.5 hrs drops. Ventilate ( check with explosimeter as no odor) Steam tank and lines. Ventilate Educt and mop Thoroughly steam tank and lines after which ensure tank pump and lines absolutely dry. Heating- Check heating for ensure particular grade to be shipped it varies. Handling - It is a problem cargo - Excellent. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

POLYPROPYLENE GLYCOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : PPG , Propylan : TBA :3 3 6 : HO (C H O)N H : 171 : Glycol Clear, light colored , slightly oily , viscous liquid with a faint ether - like odor. : 1.000 @ 25 C : : : : : : : : : :

Ambient Ambient 40 Reacts with oxidizing agents, some acids, and air. Portable lines to drop line NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : YES Any, but restrictions on Zinc,

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 199-227 C Draeger Tube No. : CH297 Alcohol 100/b

Boiling Point Explosive Range Freeze Point Autoignition Point

: : : :

188 C 2.6 % to 12.5% -40 C 260 C

Operational Problems/Hazardous Product may require a vent line desiccator When in contact with air, it may de-polymerize at elevated temperatures. Product decomposes before boiling. Possibly a high specification cargo Liquid may irritate the eyes. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Hot sea water wash, 5 ft half hour drops -with chemical cleaning if required. Ventilate to gas free Steaming tank, line and pumps. Educt and mop Tank must be completely dry Bayer - Shipper demands External Heating for his Desmonohen ideal heat adjacent 140F tried with 100F- dead slow discharge. MS- most of these fine products request need lined tanks. Avoid M.Steel tanks. Handling - With clean tanks pumps & lines - No problems. Excellent cargoes. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration.

Negligible

All of the cargoes can be cleaned using only water and all can be considered as good last cargoes.
Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

POTASSIUM HYDROXIDE (SOLUTION)

Synonyms Caustic Potash Liqueur, Caustic Potash Solution, LYE, Potassium Hydrate Solution. : 1814 :3 : KOH : 172 : Alkali : Colorless or light yellow , syrupy liquid odor. : 1.500 @ 20 C

IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : 0.0006 Carriage : 10~40 C Disch . : Average Expected Load Temp. : 10~ 40 C USCG Compatibility chart Group No :5 Reactivity: Product is highly reactive and should be checked against other cargoes. See ICS and USCG guides and all other available information. Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : :

Portable lines to drop line Bondstrand NOT suitable. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel or Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart 3 Odour threshold : ppm TLV2mg/m Flash point : Draeger Tube No. : Boiling Point : 150 C Explosive Range : % to % Freeze Point :4C

Autoignition Point

Operational Problems/Hazardous Both the liquid and vapor may cause severe burns to the eyes or skin. Product is Highly reactive and while not flammable, some reactions may evolve hydrogen , which is highly flammable - zinc being one such reactive agent. Personnel Protection; Chemical protective suit with breathing apparatus , gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Warm/ hot salt water wash, half hour 5 ft. drops Ventilate to gas free. Steaming tank, line and pumps. Educt and mop Tank must be completely dry Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Contact cause burns to skin and eyes if inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK

Complete

Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

n-PROPYL ALCOHOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Draeger Tube No. Alcohol C-3;Ethyl carbinol; Propanol; 1-propanol; n-propanol, propyl alcohol; propyl alcohol normal; proylic alcohol : 1274 : PAL 3 7 : C H OH : Colorless liquid; alcohol like odor. : 97C/ 207 F : -127C/ -197 F : 0.80 : Alcohol :* : : III : 0.87 :D : 1.2 : Complete : 2.07 : Load via portable line to droplines, Bondstrand NOT suitable. : NO : Purge : NO Blanket : NO : Any, but restrictions on epoxy, and Polyurethane. : CH297 Alcohol 100/a

Fire & Explosion Hazard Data

Grade-D Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid D Dangerous, when exposed to heat or flame. 85 2.0~ 13.5% 700 CO2, dry chemical, alcohol foam, water fog. Water may be ineffective on fire. Cool exposed tanks with water.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) : 1,0,2 : Unavailable

PEL/TWA(ppm) : 200 TLV/TWA(ppm) : 200/skin General : Vapor- inhalation causes slight irritation of mucous membranes with moderate narcotic effect resulting in dizziness, drowsiness. Symptoms : Salivation, reacting, vomiting. Short Exposure Tolerance : 400 ppm to 30 minutes. Exposure Procedure : Vapor- remove victim to fresh air. Apply artificial respiration if needed. Eye contact- wash eyes gently for 15 minutes with water.

Reactivity Data
Stability: Stable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 20 of compatibility chart . See also Appendix 1- Exception to the chart.

Spill or Leak Procedure

Wear rubber gloves, face shield, protective clothing. have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. remarks: Vapor pressure : 10 mmHg @ 14.7 C. Operational Problems/ Hazards Liquid and vapor irritate skin and eyes Prolonged exposure may lead to defatting Highly flammable product with high specification Susceptible to water, rust, grease, chlorides and hydrocarbons Stow away from adjacent heat. Personnel Protection Boiler suit, gloves and goggles Breathing apparatus standby Tank cleaning Cold bottom wash to remove residues and gas free or inert. Hot salt water wash, 5 ft. half hour drops Ventilate to gas free Steam tank, line and pump Educt and mop Tank must be completely dry and grease free M.S : Shippers requested lined tank- reluctant to M.S Dont Try. 64/66 - Coating could be used but softening is expected . Ventilate /dry tank for at least 24 hours after discharge Handling - Very strict tank inspection for loading. Fine product -no problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 6. Cargoes such as alcohol and Ketone do not require extensive machine washing and can be cleaned by positioning a tank cleaning machine close to the pump well and giving a short fresh water wash. For coated tanks, it is necessary to consult the manufactures resistance list to ensure this method will not

adversely affect the tank coating. When the coating can be affected, it is still necessary to flush the entire pump/line system with fresh water as much as possible to remove any remaining cargo form valves, drain cocks, low points on line system, etc.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

PROPIONALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Methyl acetaldehyde; propanal; propionic aldehyde; propylic Aldehyde : 1275 : PAD 2 5 : C H CHO : Colorless liquid with suffocating fruity odor. : 47C/ 117F : -79c/ -112 F : 0.80 : Aldehyde : 258 : :D : 6.7 :O : 14 : 22% : 2.0 : : NO : Purge : Possible Blanket : YES : Stainless steel or Zinc

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :C General: Extreme fire hazard due to low flash point. flashback along trail may occur. Vapor may explode if ignited in an enclosed area. reacts vigorously with oxidizers. Flash Point (F) : 15~ 19 Flammable Limits : 2.9~ 17% Auto igniting Temp.(F) : 405 Extinguishing Agents : Carbon dioxide, dry chemical and alcohol foam. Special fire Procedures : Keep tanks cool with water spray. provide fire fighters with self contained breathing apparatus and protective clothing. fire may be difficult to control due to ease with which vapor is re-ignited. Water may be ineffective on fire.

Health Hazard Data

Health hazard Rating : 2,1,1 Odor Threshold(ppm) :1 PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : Unavailable General : Liquid irritation to skin and cause eye injury. Vapor inhalation dangerous. Symptoms : Dizziness, drowsiness. Short Exposure Tolerance : 8,000 ppm Exposure Procedure : Skin contact should be thoroughly washed off with soap and water.

In case of liquid contact of the eyes, flush eyes with water for at least 15 minutes then obtain medical treatment.

Reactivity Data
Stability: Highly reactive. Normally stored under nitrogen blanket. Reacts vigorously with oxidizers. Compatibility: Material : Either stainless steel or aluminum are suitable materials. Tanks may be coated with phenolic resin. Cargo : Group 19 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus, protective clothing. Avoid contact with liquid Secure ignition sources. If possible, cover with sodium bisulfate(NaHSO3). Add small amount of water and mix. Scoop up. wash site soap solution. Operational problems/ Hazards Stow away from adjacent heat- In tropical climates it may be necessary to spray decks to cool cargo due to low B.P Contact with acids and alkalis may cause polymerization Contact with air causes oxidization and the formation of propionic acid Both liquid and vapor cause irritation to eyes and skin, Inhalation of vapor causes irritation of the air passages. Personnel Protection Chemical protection suit , gloves and Breathing apparatus. Tank cleaning Ventilate to gas free, or inert, Hot sea water wash, 5 ft half hour drops Steam tank, line and pump Educt and mop Tank must be absolutely dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers

Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

PORPIONIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Ethane carboxylic acid; ethylformic acid methacetonic acid; methylacetic acid;propanoic acid. : 1848 : PNA 3 2 : CH CH COOH : Clear, colorless liquid; pungent odor.

Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Draeger Tube No.

: : : : : : : : : : : : : : : : :

141C/ 286 F. -21C/ -6 F 0.995 Organic acid 2.5 D D 0.2 O 0.3 Complete 2.56 Ships lines only NO Purge : Possible Blanket : Probably Stainless steel only 6722101 Acetic acid 5/a

Fire & Explosion Hazard Data

Grade-D : Combustible liquid. Electrical Group :D General : Ignited by heat and flame. Flash Point (F) : 140 Flammable Limits : 2.9~14.8 Auto igniting Temp.(F) : 955 Extinguishing Agents : Alcohol foam, water spray,co2,dry chemical. Special fire Procedures : Provide fire fighters with goggles, self contained breathing apparatus and protective clothing.

Health Hazard Data

Health hazard Rating : 2,3,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 10 TLV/TWA(ppm) : 10 General : Vapor extremely irritating. Liquid causes severe burns. Symptoms: Causes burns on the skin, particularly mucous membranes (mouth, nose)and eyes. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with 15 minutes. Get medical attention.

Reactivity Data
Stability: Stable, when heated, emits acrid fumes. Compatibility: Material : Corrosive Cargo : Group 4 of compatibility chart

Spill or Leak Procedure

Wear rubber gloves, face shield,protective clothing. body shield and self contained breathing apparatus should be available. avoid contact with liquid. secure ignition sources. if possible,cover spill with soda ash or sodium bicarbonate. Mix and add water if necessary to effect good mixing, scoop up slurry and wash site with soda ash solution.

Operational Problems/ Hazards Product is hygroscopic, therefore may require nitrogen blanket and/or vent line desiccant. It is a highly corrosive liquid which will cause severe burns. The vapor may also cause irritation and cause burns, Clear lines with nitrogen Use Closed ullaging system. Personnel Protection Chemical protective suit, gloves and goggles, Breathing apparatus standby Tank cleaning Prolonged cold salt water wash, min. 5 ft half hour drops Ventilate to gas free Steam tank, line and pump Educt and mop Tank should be completely dry. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note.1 Cargoes such as acids, alkalis and oxidizers may react with water, product heat and form a much more corrosive solution. To minimize this reaction, large amounts of water must be introduced as quickly as possible. The water should be allowed to accumulate in the cargo sump or on the tank top.

HEALTH HAZARDS Contact cause burns to skin and eyes If inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE

Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

PROPIONIC ANHYDRIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Methylacetic anhydride; propanoic acid; anhydride; propanoic anhydride; propionyl oxide. : 2496 : PAH 3 2 2 : (CH CH CO) O : Colorless liquid; pungent odor. : 169C/ 336 F : -45C/ -49 F : 1.01 : Organic acid : 1.0 :D :C : Low :O :" :*

Vapor Density(air= 1.0) : 4.49 Handling : Ships lines to deck tanks, which must be absolutely dry. May require a vent line dessicator, Bondstrand is not suitable. Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank coating : Stainless steel only

Fire & Explosion Hazard Data

Grade-E : Combustible liquid Electrical Group :D General: Moderate fire hazard when exposed to heat or flame, more of a health hazard than a fire or stability hazard. Flash Point (F) : 165 Flammable Limits : 1.48~ 11.9% Auto igniting Temp.(F) : 600 Extinguishing Agents : Carbon dioxide or dry chemical Special fire Procedures : Do not use WATER as extinguishing media; propionic anhydride reacts slowly with water to form propionic acid- reaction rate increases with temp.

Health Hazard Data

Health hazard Rating : 3,2,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapors irritating when inhaled. liquid irritating to skin on contact. may produce sensitization effects. Symptoms : Respiratory irritation, skin irritation. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air; apply artificial respiration if breathing stops. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water Get medical attention if discomfort persists.

Reactivity Data
Stability: Decomposes on contact with water. Can react with oxidizing materials. Compatibility: Material : non corrosive to aluminum or stainless steel. Cargo : Group 11 of compatibility chart.

Spill or Leak Procedure

Have self contained breathing apparatus available. avoid contact with liquid. secure ignition sources. remarks: Reacts with to form propionic acid. Operational Problems/ Hazards Decomposes with heating giving off acrid fumes. Stow away from heated cargo Cargo decomposes with water , so tank and lines will have to be thoroughly dry. Liquid very corrosive, causes severe burns to skin and eyes . Avoid any contact. Vapor is pungent and will give ample warning of its presence, but avoid any inhalation. Use Closed loading method when ullaging.

Personnel Protection Full protective clothing and B/A. Tank cleaning Cold S.W wash to remove residues ( 2hrs) Hot SW wash with chemical injection ( 2hrs) Steam tank and lines. Ventilate to gas free Educt and mop. Tank and lines must be absolutely dry

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Do not get water inside container apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Use water spray to reduce vapor; do not get water inside container. Small spills: Take up with sand or other noncombustible absorbent Material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

PROPYLAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Draeger tube No. 1-Aminopropane;monopropylamine; 1-propanamine; n-propylamine; mono-n-propylamine. : 1277 : PRA 3 2 2 2 : CH (CH ) NH : Colorless liquid with a pungent. : 49C/ 120 F. : -82C/ -116F : 0.72 : Amine : 250 :D :C : 10.4 :O : 14.1 : Soluble : 2.0 : Ships line to center or deck tanks : NO : Purge : Possible Blanket : Possible : Stainless steel : 67184 Triethylamine

Fire & Explosion Hazard Data

Grade- B Electrical Group General: : Flammable liquid :D

Quite flammable. Emits toxic and irritating vapors when heated. Vapor is heavier than air and may travel to a source of ignition and flash back. Flash Point (F) : -35 Flammable Limits : 2.0~ 10.4% Auto igniting Temp.(F) : 604 Extinguishing Agents : Carbon dioxide, dry chemical or alcohol foam. Special fire Procedures : Water may be ineffective on fire. Cool exposed tanks with water.

Health Hazard Data

Health hazard Rating : 3,3,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 5* TLV/TWA(ppm) : 5* General : A severe eye, skin and respiratory irritant. Highly toxic when ingested or inhaled. Symptoms: Severe irritation of skin, eyes and respiratory tract. Short Exposure Tolerance: Unavailable Exposure Procedure : Skin- wash with soap and water, then flush area with water, Eye- flush with copious amounts of water. Vapor- remove victim to fresh air. Administer artificial respiration if necessary. In all cases call a doctor.

Reactivity Data
Stability: Stable. Compatibility: Material : Glass and stainless steel Cargo : Group 7 of compatibility chart.

Spill or Leak Procedure

Wear full skin protection and self contained breathing apparatus. Secure ignition sources. Add sodium bisulfate and spray with water. Then clean up. remarks: PEL and TLV based upon iso-propylamine. Operational Problems / Hazards Stow well away from adjacent heat In very hot weather it may be necessary to spray the deck to reduce risk of boiling off. Liquid and vapor may cause severe damage to skin and eyes Skin absorption, ingestion and inhalation may be FATAL. Personnel Protection Total protection suit, Restrict personnel on deck Secure accommodation and Recirculation air Tank cleaning Ventilate to gas free, or inert, Hot sea water wash, 5 ft half hour drops Steam tank, line and pump Educt and mop Note : Amines absorb waters rapidly ensure tank open during washing to avoid vacuum. This low boil/flash point cargo must be handled with care.

On hot days flush down deck with cold sea water . - its cooling. Hazards - Avoid contact vapors Use protective mask , clothing when working this cargo. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

HEALTH HAZARDS Poison; extremely hazardous. Inhalation extremely dangerous; may be fatal. Contact with liquid may cause frostbite. Initial odor may be irritating, foul or absent and may deaden your sense of smell. FIRE OR EXPLOSION Extremely flammable; May be ignited by heat sparks or flames. Flame may be invisible vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural Firefighters protective clothing is not effective for these materials Isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE. FIRE Let burn unless leak can be stopped immediately. 2 Small Fires:. dry chemical or co or water spray. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks for massive fire in cargo area, use unmanned hose holder or monitor Nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully-encapsulating, vapor-protective clothing should be worn for spills and Leaks with no fire. Stop leak if you can do it without risk Isolate area until gas has dispersed FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration;

if breathing is difficult, give oxygen. in case of frostbite thaw frosted parts with water. Keep victim quiet and maintain normal body temperature. Effect may be delayed; keep victim under observation.

PROPYLENE DICHLORIDE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : 1,2- Dichloropropane, Propylene Chloride, Propene Dichloride. 1279 2 3 2 CH CHCLCH CL 182 Halocarbon ( Saturated Aliphatic ) Colorless liquid with a chloroform-like odor. 1.1583 @ 20 C

Ambient Ambient 36 Reacts with oxidizing agents, some acids and alkalis. Ships lines to center or deck tanks only NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : YES Stainless steel or or Zinc with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 75 ppm Flash point : 20 C Draeger Tube No. : 67189 Chloroprene 5/a Boiling Point : 96 C Explosive Range : 3.4 % to 14.5% Freeze Point : -80C Autoignition Point : 550 C Operational Problems/Hazardous Stow away from adjacent heat. Tank must be cleaned thoroughly before use as a ballast tank. Liquid and vapor cause irritation of eyes and skin. Inhalation of vapor will have narcotic effect. Personnel Protection; Boiler suit, gloves with breathing apparatus , gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO Retain onboard until on passage discharge on passage according to regulations. Drying oil : NO Soluble in water : Very slight Cleaning from: Ventilate to gas free, or inert Hot sea water wash, 5 ft half hour drops Steam tank, line and pump, educt and mop Tank and product must be completely dry FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames.

Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

PROPYLENE GLYCOL
Synonyms IMO No IMO TYPE Formula : : : : Methylethylene Glycol Mehtyl Glycol. 1188 3 3 2 CH CHOH CH OH

ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : : : : : :

183 Glycol Colorless, moderately viscous liquid. Almost no odor. 1.0400 @ 15 C 0.00072 Ambient Ambient 20 May react with oxidizing agents and acids. Load through portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Stainless steel or epoxy. epoxy or polyurethane, Zinc with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 75 ppm Flash point : 107 C Draeger Tube No. : Boiling Point : 187 C Explosive Range : 2.6 % to 12.6% Freeze Point : -60 C Autoignition Point : 421 C Operational Problems/Hazardous Product is hygroscopic therefore may require nitrogen blanket and/or vent line desiccator. May oxidize at high temperature and so should be stowed away from adjacent heat. Practically non-hazards, but care should be taken as the product is odorless and has a relatively low TLV. Very easily put off spec. Susceptible to moisture chlorides and rust. Personnel Protection; Boiler suit, gloves and goggles, Breathing apparatus standby. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water :

Complete

Cleaning from: Hot salt water wash, 5 ft half hour drops Ventilate to gas free Thorough steam of tank, line and pump Educt and mop Tank should be completely dry and grease free. Usually high specification cargo. Z-11- DOW will not load Use grade in Z-11 , but will load into D-4 (NUTS) Handling - There are no problem with this cargo . provided tanks pumps/line are 100% clean and dry. Nitrogen for slack tanks.

Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

PROPYLENE GLYCOL MONOMETHYL ETHER

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor : : : : : : : : : Dowal PM, 1-Methoxy-2-Propanol, Propylene Glycol Methyl ether 3 CH3 OCH2 CHOH CH3 184 Glycol Ether Colorless liquid with a mild and pleasant odor. 0.919 @ 25 C

Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Ambient : : Ambient : 40 Reacts with oxidizing agents and some acids Reacts dangerously with phohorus trichloride. : Portable lines to drop line : NO (Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : YES : Stainless steel or Zinc. Epoxy with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 100 ppm Flash point : 38 C Draeger Tube No. : Boiling Point : 120 C Explosive Range : % to % Freeze Point : -97C Autoignition Point : C Operational Problems/Hazardous Product may require a vent line desiccant If carried in Epoxy lined tank, tank should not be cleaned or ballasted until all residues have been removed by ventilating. Product has good solvent properties Liquid and vapor cause irritation of eyes Inhalation will lead to dizziness; however, the vapor is considered safe at concentrations which can be tolerated by unacclimatized individuals. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Complete

Cleaning from: Ventilate to gas free, or inert Hot sea water wash, 5 ft half hours drops Fresh water rinse Educt and mop Tank must be completely clean and dry possibly high specification product Adj./Heat - DOW will not load this product if cargoes in adjacent tanks are under heating. Handling - This is not a difficult cargo . A good lined tanks will clean lines/ pumps will do Similar cargo Cellosolve

PROPYLENE OXIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water : : : : : : : : : : : : : : : : 1,2-Epoxypropane; Methyloxirane; propene Oxide 1280 POX 2 3 CH OCHCH Colorless liquid; ether like odor 34C/ 94 F -112C/ -170 F 0.86 Alkaline oxide 449 B D 18.0 O 22.0 59%

Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : :

2.00 Ships lines to center or deck tanks only NO Purge : Possible Blanket : YES Stainless steel or Zinc

Fire & Explosion Hazard Data

Grade-A : Flammable liquid Electrical Group :B General: An extremely reactive, flammable liquid with a wide explosive range. ignited by heat, sparks or open flame flashback along vapor trail occur. fire or concentration may cause violent rupture of tank. Flash Point (F) : -35 Flammable Limits : 1.8~38.5% Auto igniting Temp.(F) : 869 Extinguishing Agents : Stop flow of gas; large volumes of water,co2,alcohol foam. Special fire Procedures : If a fire breaks out near a propylene oxide tank, keep tank cool with a water spray. Explosion hazard requires approaching a burning tank with caution.

Health Hazard Data

Health hazard Rating : 3,2,2 Odor Threshold(ppm) : 200* PEL/TWA(ppm) : 20 TLV/TWA(ppm) : 20 General : Suspected carcinogen. vapor harmful. liquid cause eye burns. Liquid or water solutions absorbed into clothing, particularly shoes, cause delayed skin burns. Symptoms: Nausea, vomiting and irritation to eyes and respiratory passages. Short Exposure Tolerance: 2,000 ppm for 4 hours. Exposure Procedure : Vapor- remove victim to fresh air ; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Note: Detectable odor is greater than the TLV. Exposure to potentially dangerous vapor concentration can occur before product can be detected by smell.

Reactivity Data
Stability: Polymerizes violently with catalysts such as acids, bases, and certain slats. Reacts violently with chlorine and with ammonia. Compatibility: Material : Avoid copper and other acetylide-forming metals. Cargo : Group 16 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, large heavy face shield,(if in doubt, use body shield also),self contained breathing apparatus. avoid contact with liquid. secure ignition sources. Do not flush spill into confined spaces where flammable vapors can accumulate. remarks: Must be shipped with inert pad.

Operational Problems/ Hazards Stow away from adjacent heat - may only be carried in temperature climate voyages due to low BP In most cases of reaction the product polymerizes violently. A relatively stable compound, but it undergoes isomerisation at high temperatures ( 500 C). Liquid will cause severe burns and serious damages to eyes and skin. Vapor also may cause injury The odor of the vapor gives good warning against acute exposure, but cannot be relied upon as a warning against chronic exposure. Personnel Protection Boiler suit , gloves and breathing apparatus. Tank cleaning Cold sea water wash, 5 ft. half hour drops maximum Ventilate to gas free, Fresh water rinse Educt and mop Tank must be completely dry and free from impurities. Boil Point - Cargo must be cooled down to below 68F Carried at 55F- no problems. Handling - All areas around to be loaded must be inerted. Nitrogen vapor return with hoses when loading. Cargo under Nitrogen positive pressure. See Appendix Special Cargo Manual; Tank Washing/ 1. After discharge, keep the tanks inerted until cleaned. 2. Without opening any tank hatches, pump a few cubic meters of fresh water into the tank from the manifold. Pump this water out of the tank and overboard if at sea, or alternatively, into a slop tank. 3. Ventiate the tank (by forcing air into the tank) using one or more ventilates for a minimum of two hours. 4. During the cleaning/ventilation operation, all precautions must be taken to avoid any sources of ignition at or near the tank. Crew members should be kept away from the area.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out.

Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor area and let fire burn.

nozzles; if this is impossible, withdraw from

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

PROPYLENE TETRAMER
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Dodecane, Dodecylene, Tetrapropylene. 2850 3 3 6 4 (C H ) 186 Hydrocarbons (Unsaturated Aliphatic ) Colorless liquid with a characteristic odor. 07723 @ 15 C 0.0007 Ambient Ambient 30 May react with oxidizing agents Load via portable line to droplines or manifolds. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : Possible Most coatings suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 5 ppm Flash point : 78 C Draeger Tube No. :

Boiling Point Explosive Range Freeze Point Autoignition Point

: 157 C : 0.8 % to : -35C : C

Operational Problems/Hazardous The data given is for 100% concentration and may vary with concentration. Personnel Protection; Boiler suit, gloves, and goggles. Breathing apparatus. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NIL Cleaning from: Cold sea water pre-wash Ventilate to gas free, or inert Hot sea water wash, 5 ft half hours drops with chemical if required. Steam tank, line and pumps. Educt and mop These 2 common Olefins almost trouble free. Clean tank and lines & pumps are all thats been asked for. Excellent cargo. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is difficult, give

PROPYLENE TRIMER
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Tripropylene. 2057 3 3 6 3 (C H ) 187 Hydrocarbon (Unsaturated Aliphatic ) Colorless liquid with a characteristic odor. 0.738 @ 20 C

Ambient Ambient 30 May react with oxidizing agents. Portable lines to drop line but flush out as soon as possible after use. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 40 C Draeger Tube No. : Boiling Point : - 35C Explosive Range : 0.8 % to % Freeze Point : -81C Autoignition Point : C Operational Problems/Hazardous Data given is for 100% concentration of C9 mono-olefins- data may vary with changes in mixture

Liquid has slight effect on eyes and skin. Inhalation of vapor may have a moderate systemic effect. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water :

NIL

Cleaning from: Ventilate to gas free, or inert Hot sea water wash, 5 ft half hours drops Steam tank, line and pump Educt and mop Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.
FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let

fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is difficult, give

PYRIDINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : Azabenzene; Azine : 1282 : PRD 4 : HCN(CH) : Yellow to colorless liquid; nauseating, unpleasant odor. : 115C/ 239 F : -42C/ -44 F : 0.98 : Amine :* :C :D : 0.77 :O : 1.3 : Complete : 2.72 Compoflex portable lines to droplines, but normally ships lines to Stainless steel tanks. : NO : Purge : Possible Blanket : Probably : Stainless steel

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :D General: Highly toxic fumes give off upon decomposition. Fire hazard high, when exposed to heat or flame. Explosion hazard severe, in the form of vapor, when exposed to flame or spark. flashback along vapor trail may occur. vapor may explode if ignited in an enclosed area. Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents : : : : 68 1.8 ~ 12.4% 900 Alcohol foam, dry chemical, CO2.

Special fire Procedures : Keep tanks cool with water spray. provide fire fighters with self contained breathing apparatus.

Health Hazard Data

Health hazard Rating : 2,2,1 Odor Threshold(ppm) : 0.021 PEL/TWA(ppm) :5 TLV/TWA(ppm) :5 General : Liquid mildly irritating to the skin and can be absorbed through the skin. Vapor inhalation results in slight irritation of airway with slight anesthetic effect. Symptoms: Nausea, headache, insomnia, nervous, low back or abdominal discomfort. Short Exposure Tolerance: Very disagreeable odor at 30 ppm. Exposure averaging 125 ppm, four hours per day for one to two weeks give rise to symptoms. Exposure Procedure : Vapor- remove from exposure, use artificial respiration if necessary, and obtain medical attention. skin contact- Remove contaminated clothing and wash thoroughly with large amounts of water. Eye contact- irrigate eyes with water for at least 15 minutes.

Reactivity Data
Stability: Stable. possibility of a dangerous reaction with acid anhydride. Compatibility: Material : Copper and its alloys and some synthetic rubbers are unsuitable. Cargo : Group 9 of compatibility chart.

Spill or Leak Procedure

If possible, wear boots, rubber gloves, rubber or plastic coat, and self contained breathing apparatus. Extinguish sources of ignition. if possible, cover large spills with sand and soda ash mixture(90-10). Mix and shovel into a cardboard box. remarks: Vapor pressure: 20 mmHg @ 25c. Operational Problems/ Hazards Stow away from adjacent heat and away from cargoes susceptible to smell (e.g. Vegetable oils, Glycols, etc.) May require a vent temperatures (about 540C ) the product will decompose, evolving highly toxic cyanide fumes. Liquid and vapor are anesthetic effect High specification cargo. Personnel Protection Chemical protection suit with Breathing apparatus and gloves (PVC is suitable material for protective clothing ) Tank cleaning Cold sea water wash to remove residues Ventilate to gas free, or inert Hot sea water wash, 5 ft half hour drops Thorough steam of tank, line and pump Educt and mop Tank must be completely free of all traces of previous cargoes. M.Steel- A scale free tank cleaned to perfection is O.K. but lined tanks requested. Handling - Be prepared to use vapor -return line for loading & transfer , Toxic , Use face mask. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration.

All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

RAPE SEED OIL

Synonyms : Colza Oil, Rape Oil, Toria oil, Yellow Sarson oil. IMO No : N/A IMO TYPE :3 Formula : N/A ICS Guide Page No. : 19 Family : Ester. Appearance and character : Dark brown to pale yellow depending on stage of refinement. Viscous liquid with unpleasant taste and odor . Contains approx. 50% erucic acid. Specific Gravity : 0.913- 0.917 @ 15 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00068 Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient USCG Compatibility chart Group No :3 Reactivity : Basically non-hazardous. Handling : No specific handling regulations ships or shore lines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended Epoxy polyurethane, stainless steel, not recommended but can be carried in zinc silicate if FFA content is below 5%. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 163 C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : -2 to -10C Autoignition Point : C Operational Problems/Hazardous Semi -drying oil, therefore tank should be cold washed immediately following discharge. May require sweeping depending on sea temperature. Keep away from heated cargo. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO discharge on passage according to regulations.

Drying oil : YES Soluble in water :

NO

Cleaning from: Pre-wash with cold water to remove residues as soon as possible after discharge. Hot sea water wash, 5 ft half hours drops with chemical injection. Spot clean as required. Fresh water rinse or steam Educt and mop dry Tank must be dry As this is a drying oil, before any tank entry oxygen content to be checked. Heat- Only in cold climate is heat needed, for crude . FFA : It is usually below 2.5% but check before stowing in Zinc tanks. Good cargo- no problems. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

RESIN PLASTICIZER
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : SEE note Below : :3 : : : : Various. : 1.115 to 1.123 @ 25 C : : Ambient : 25 C : 47 C : 34 Generally non-reactive. Check locally with surveyor for compatibility : SEE Note. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : SUS or Zinc.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous NOTE : Resin plasticizer is a generic term for products such as; DI-Octyl Phathalate Benzyl Butyl Phthalate Trade name used ( Monsanto ) is Santicizer Check locally when loading. Personnel Protection; Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Carried many times with no problems of any kind. shipped be cleared by USCG & IMO.

Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

SANDALWOOD OIL (EastIndian)

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Santalwood Oil, Santal Oil, Sandal Oil N/A 3 N/A 19 N/A A pale yellow, essential oil, with faint aromatic odor. 0.96 @ 25 C

25~30 C 20~30 C

No specific regulations Ship lines to droplines or shore lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Polyurethane, Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Product practically non hazardous Heating subject to shippers requirements Check Locally High standard of coating and tank cleanliness will be required. Personnel Protection; Normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : No

Cleaning from: Hot S.W wash minimum 2. 5 hours with chemical injection ( temp. compatible with coating ) Ventilate to remove steam . If all residues removed, Ventilate Educt and mop

SESAME OIL
Synonyms : Gingelly Oil, Benne oil, Teel oil

IMO No : N/A IMO TYPE :3 Formula : N/A ICS Guide Page No. : 19 Family : Ester. Appearance and character : A fixed pale yellow oil, liquid at ordinary temperatures. Noes not readily become rancid Specific Gravity : 09187 @ 25 C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 34 Reactivity : Basically non hazardous.. Handling No specific handling regulations Ship lines preferably , Portable lines to droplines or shore lines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended Polyurethane , Epoxy, Stainless steel. Can be carried in Zinc Silicate if FFA is below 5%. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : - 5C Autoignition Point : C Operational Problems/Hazardous May require sweeping, dependent upon temperature Shipper may require product to be heated - check locally Coating condition will be checked by surveyor Should be stowed preferably away from heated cargo. Personnel Protection; Boiler suit, normal working gear Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Hot sea water wash, minimum 2.5 hours with chemical injection. Spot clean as required Fresh water rinse or steam Ventilate Educt and mop Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser NIL

and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 22. These cargoes are drying or semi-drying oils which require cold(ambient) washing immediately after discharging.

SHELLFLEX - VARIOUS GRADES(Duflex)

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) : : : : : : : : A Range of process oils similar to shell Dutrex oils q.v 3 Hydrocarbon mixtures Paraffin or Naphthenic concentrate Light amber to black viscous liquid Characteristic odor. See list

Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : :

Ambient Ambient 33 Generally no reaction except with Nitric Acid Ships lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Zinc or SUS check manufacturers list.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : - C Explosive Range : % to % Freeze Point : below 0 C Autoignition Point : C Operational Problems/Hazardous Probably flammable, but very low volatilities. May be carcinogenic - Avoid Skin contact. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO Persistent - Residues to bunkers. Drying oil : NO Soluble in water : Cleaning from: Hot wash with chemical injection - 5ft half hour drops Steam tank and lines Ventilate Educt and mop dry TYPICAL PROERTIES OF SHELLFLEX OILS Grades 131 210 212 213 214 274 292 293 310 3310 371 412 683 724 SG @ 60F 0.8718 0.8644 0.9024 0.9053 0.9218 0.9018 0.9020 0.9159 0.8789 0.8735 0.8978 0.9147 0.9279 0.9452 Flash pt. 149 193 171 168 163 185 185 202 229 224 216 207 238 221 Pour pt.C 54 12 43 34 40 37 37 7 12 12 32 7 18 12

790 881

0.9042 0.9218

304 310

-7 -7

No.312 is Aromatic oil No 371 are petroleum. Book/stow & handling same as for Lube oils. No problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 14. Lube oils with low viscosity can be extremely hard to remove, especially form inorganic(zinc) coatings. Generally if the viscosity is less than 100cst and the subsequent cargo is of high specification, it is necessary to toluene float the tank. Obtain the viscosity at the port to assist in cleaning the tank after discharge.

SHELLSOLS
Synonyms : Shellsol- A,AB,E<F,LF,N,R,RA,T IMO No : TBA IMO TYPE :3 Formula : Varies with grade ICS Guide Page No. : 190 Family : Hydrocarbon Appearance and character : Mobile volatile solvent which vary in color and odor according to grade (See List) Specific Gravity : Various 20 C Heating Range (Subject to Chart.Reg.) Correction factor : Carriage : Ambient Disch . : Average Expected Load Temp. : Ambient USCG Compatibility chart Group No : 32 Reactivity: Can react with oxidizing agents and concentrated sulfuric and nitric acids, Otherwise basically stable.

Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : :

Portable lines to drop line. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO SUS, Polyurethane, Epoxy , Zinc silicate

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : CH254 Hydrocarbon 2 Boiling Point : -C Explosive Range : Freeze Point : C Autoignition Point : C Operational Problems/Hazardous High grades solvents - tank and lines will have to be grease and moisture free. Although not specifically prone to static, lines should be blown with Nitrogen Slight narcotic effect with vapor off some grades Moderate to low fire risk. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO

Cleaning from: Inert or cold pre-wash. Hot sea water wash with chemical injection 5 ft half hour drops. Fresh water rinse or steam Ventilate to gas free Educt and mop dry Grade A AB E F K LF N R RA S T color WW WW WW S.G@15C 0.87 64 0.894 67 0.86 45 0.83 49 0.78 71 0.82 49 0.879 53 0.89 80 0.907 62 0.86 10 0.76 56 F.P 160-182 187-213 160-200 160-199 194-258 159-199 167-263 203-267 182-312 115-155 180-215 B.P 504 503 475 409 235 465 488 554 366 A.I

SOFTANOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Secondary Alcohol, 3 Mol Ethoxylate TBA 3 Not known Secondary Alcohol A non- combustible clear to white, non-toxic liquid. 0.925 @ 20 C

Ambient Ambient Basically stable. Portable lines to drop line, manifolds. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings compatible.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 180 C Draeger Tube No. : Boiling Point : C

Explosive Range Freeze Point Autoignition Point

: : :

% to C C

Operational Problems/Hazardous No real problems. However, being an industrial detergent, can have large build up of froth when washing. Shippers normally supply anti-foaming agent, or one can use a hydrocarbon (e.g. Toluene ) to break up foam. Personnel Protection; Boiler suit, Normal working Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Add anti-foaming agent or hydrocarbon (e.g. Toluene ) Cold sea water wash , 5 ft half hour drops Fresh water rinse or steam Ventilate Educt and mop Tank must be dry Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated. Reference note 21. These cargoes can reduce the permanganate time of a methanol wall wash and require the use of an oxidizer in the cleaning process.

Complete

SOLVESS 100/150
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : :3 : : : Aromatic Hydrocarbon : A clear colorless liquid with distinctive odor.. : 0.869/0.892 C : : : : : : : : : : 0.00092 Ambient Ambient 33 Basically stable. Very clean portable lines to tank drop lines for quality control. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 42/46C Draeger Tube No. : 67188 Benzene 5a /CH230 Toluene Boiling Point : 155/188 C Explosive Range : % to % Freeze Point : -18C Autoignition Point : C Operational Problems/Hazardous Being base solvent will require very clean and dry tanks and lines. Non-contamination of cargo imperative.

Product contamination may occur from leeching out of previous cargo; in this respect surveyors may refuse tanks that have previously contained lube or Veg. oils. No specific health hazards Ventilate epoxy tanks for 24 hours after discharge. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO

Cleaning from: Wash tank inert or Gas free Hot sea water wash, chemical injection (0.5 hour 5 ft drops ) Fresh water rinse or thoroughly steam tanks. Ventilate to gas and odor free Educt and mop dry. Tank must be dry and grease free USCG/IMO : All these solvent mixtures come under USCG. Heading: MISC, Hydrocarbon mixtures Other names : petroleum spirit and Thinners , Mineral thinner, varnish makers and painters; cleaners similar to Stoodard solvent. Product are not containing benzene. Handling :- Cleanliness is the key in handling these excellent cargoes. Clean good tanks /lines/ Valves/ hoses and pumps is all it takes. M.S- Tank must be free of any scale in addition to 100% clean. Shell /MS- It is next to impossible to get M.S tanks past Shells surveyors . GO Coated or SUS. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature.

SORBITOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating D-glucitol; L-Gulitol; 1,2,3,4,5,6-hexanehexol sorbicolan; sorbit; Sorbo; sorbol; sorbostyl; : : SBT : CH2OHH(CHOH)4CH2OH : White, odorless crystalline powder with a faint sweet taste. : V.High : 110C/ 230F : 1.49 @ 150c(liquid) : Glycol : Low : : III :" :* :" : : 3.2 : Usually shore lines into tanks ( Splash loaded) : NO : Purge : No Blanket : NO : SUS, Epoxy, Zinc, Polyurethane

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid D Slight fire hazard if exposed to heat or flame. Greater than 150 Unavailable " Water Use water to cool fire exposed tanks to avoid combustion.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) : : : : Unavailable None Not pertinent No pertinent

General : No threat of damage from vapor inhalation since the volatility of orbital is so low Symptoms : Hot liquid will burn skin. Short Exposure Tolerance : Not applicable Exposure Procedure : Treat for burn resulting from contact with hot liquids.

Reactivity Data
Stability : Stable. Compatibility : Material : Mild or stainless steel is acceptable. Cargo : Group 20 of compatibility chart.

Spill or Leak Procedure

Avoid contact with hot liquid. Wear goggles or face shield, protective clothing for hot liquid. Stop discharge if possible. remarks: Unregulated, table 2, 46CFR part 153 ** Very soluble in hot water ++ Unassigned Operational Problems/ Hazards Normally loaded and discharged through portable pumps Being classed as food grades product, tanks will have to be exceptionally clean and coatings in top class condition. Surveyor are extremely critical in passing tanks Meticulous hand cleaning is almost certainly required before tank will be passed. Personnel Protection Boiler suit Normal working gear Tank cleaning Hot sea water wash, 5 ft. half hour drops Fresh water rinse or steam Ventilate Educt and mop dry * Very susceptible. Hand cleaning may include scraping of any residues remaining on bolts round suction strums, etc. especially if last cargo was an animal or vegetable oil. Heat- For discharge in Italy & Japan- 122F (50C) for Rotterdam (100F). Heating slowly 5F per day. Zinc Europe. The pH if shipped from Europe The pH must be above 5PH. Handling - Tank must be 100% clean & odor free before loading Strict inspection. Overhead loading discharge always. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

SOYBEAN OIL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : Chinese bean oil; soybean oil; soy oil : ++ : OSB : Mixture : Pale yellow liquid; weak odor : V.High : -20C/ -4 F : 0.92~ 0.93 : Ester : 2.04 : :D : 0.10 :D : 0.16 : Slight : NP : No specific handling regulations Ship or shore lines. : NO : purge : NO Blanket : NO Epoxy, Polyurethane SUS,Can be carried in Zinc silicate If FFA below 5% but not recommended.

Fire & Explosion Hazard Data

Grade-E : Combustible liquid Electrical Group :D General : Slight fire hazard when exposed to heat or flame. Flash Point (F) : 540 Flammable Limits : Unavailable Auto igniting Temp.(F) : 833 Extinguishing Agents : Dry chemical, foam or carbon dioxide. Special fire Procedures : Water may be ineffective on fire. Cool exposed containers with water.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance Exposure Procedure : : : : : : : : Unavailable Not pertinent Not pertinent " Not harmful. None Does not penetrate skin in harmful amounts. Non-toxic. Wash thoroughly with soap and water.

Reactivity Data

Stability Compatibility

: Stable. Material usual materials of construction are suitable. will soften some paints and rubber

Spill or Leak Procedure

Wear rubber gloves, face shield and protective clothing. secure all ignition sources. Operational Problems/ Hazards Solidifies at -8C If being used for edible purposes, food grades tank may be required As a drying oil, requires immediately cold wash after discharge Check Oxygen content before any tank entry May possibly require sweeping, Shipper may require heating for discharge- Check locally. Personnel Protection Boiler suit, normal working gear Tank cleaning Cold sea water pre-wash, minimum 2 hours to remove residues as soon as possible after discharge Hot sea water wash, 5 ft. half hour drops, with chemical injection Ventilate If residues removed , fresh water rinse Educt and mop Spot cleaning may be required Tank must be dry Heat- If temperature falls below 50F- apply some heat. Maximum for discharge 80F. Zinc: Usually the FFA is below 2.5% , but once in a while it is higher at St.Rose- Check Refined - Lined tank Only. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

SPERM ,WHALE OIL

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling : : : : : : A Yellowish-brown fixed oil, with strong fishy odor. Derived from arcasses and blubber of the sperm and blue whale. : 0.87 @ 32C

: 0.00059 : 21-25 C : 30- 35C : 27 C : 34 : Basically non-hazardous No specific handling regulations, although all lines must be dry and rust/scale free. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Epoxy, Polyurethane, stainless steel. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 247 C Draeger Tube No. : Boiling Point : 260 C Explosive Range : Freeze Point : Autoignition Point :

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid D Slight fire hazard when exposed to heat or flame. 428 Unavailable 586 Carbon dioxide, dry chemical Water foam may cause frothing

Health Hazard Data

Health hazard Rating : 0,1,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Toxicity probably low. details unavailable. Symptoms : Unavailable Short Exposure Tolerance : Unavailable Exposure Procedure : Flush affected areas with plenty of water; wash thoroughly with soap and water.

Reactivity Data
Stability : Stable

Operational Problems/Hazardous Oil Temperature should not be raised more than 2 C/day Temperature of cargo must not exceed 43 C Oil required to be swept. Check Oxygen content before any tank entry When sweeping, vapor from oil will make eyes smart Requires strict observance of charterers heating instruction Should not be allowed to fall below 20C as solids start to separate and are difficult to absorb by heating. Personnel Protection; Boiler suit, gloves, and goggles. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NO

Cleaning from: Pre-wash with warm sea water to remove any sledge Hot sea water wash, chemical injection Spot clean as required (Observe tank entry procedure) Fresh water rinse or thoroughly steam tanks. Ventilate Educt and mop dry. Tank must be dry and grease free Heat- Always heat slowly . No more than 5F per day Zinc - The FFA is usually . low but check before stowing Zinc tanks.

STYRENE MONOMER
Synonyms UN. No CHris Code Formula Appearance-Odor Cinnamene; Cinnamol;Ethenylbezene; Phenylethylene; Styrene; Styrolene; Vinylbenzene : 2055 : STY 6 5 2 : C H CHCH Colorless liquid; sweet odor when pure; Sharp disagreeable odor with impure : 145C/ 293F : -30C/ -23 F : 0.92 : Hydrocarbon (Unsaturated Aromatic) : 6.0 :C :B : 0.27 :O : 0.4 : Negligible : 3.6

Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Very clean portable lines Load through droplines Lines must be bonded or electrically non-conductive. Inhibitor : YES Nitrogen : Purge : NO Blanket : Possible Tank coating : SUS, Not recommended to be stored for more than three months in Epoxy, Polyurethane or for more than two months in some zinc.

Fire & Explosion Hazard Data

Grade-D : Combustible liquid

Electrical Group :D General: Ignited by heat and open flame. or contamination may cause violent rupture of tank. Flash Point (F) : 100 Flammable Limits : 1.1 ~ 6.1% Auto igniting Temp.(F) : 914 Extinguishing Agents : CO2, dry chemical, water fog, foam. Special fire Procedures : Avoid breathing vapors. provide body and respiratory protection. Keep tanks cool with water spray.

Health Hazard Data

Health hazard Rating : 2,2,2 Odor Threshold(ppm) : 0.15 PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 50/skin General : Suspected carcinogen. vapor very irritating to eyes, moderately irritating to respiratory tract with moderate systemic effect. Liquid irritating to skin. Symptoms: Weakness, dizziness, nausea, and sleepiness. Short Exposure Tolerance: 10,000 ppm may be fatal 30 to 60 minutes. Exposure Procedure : Vapors- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Soap, if available, should be used on effected skin areas. get medical attention.

Reactivity Data
Stability: Will readily form peroxides which catalyze polymerization unless inhibited. heat, light and strong acids also catalyze polymerization reaction. Compatibility: Material : Most materials of construction are suitable. Do not use copper or its alloys. styrene can be polymerized at explosive rates by certain contaminants. Cargo : Group 30 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. remarks: * Even the inhibited product, when heated above 125 F, can polymerize with the generation of so much heat that ignition is possible. Operational Problems/ Hazards Cargo is inhibited to prevent polymerization. Length of time on board may require addition of more inhibitor. Check locally. Even when inhibited will polymerize violently if temperature exceed 32 C. Therefore stow away from heated cargo. May require deck cooling. Also may be carried under Nitrogen blanket for quality control- check locally. Some contaminants may also cause polymerization, so tanks and line must be scrupulously clean and dry. Moderate irritation from both liquid and vapor . Avoid all contact Very prone to static. Lines must be blown with Nitrogen After discharge vent tanks for at least 24 hours to allow coatings to harden. Personnel Protection

Chemical suit, goggles , gloves, Breathing apparatus on standby Tank cleaning Vent for 24 hours to allow coatings to harden Cold sea water pre-wash ( 2hour) to remove any residues Hot sea water wash with chemical injection, 5 ft half hour drops, Fresh water rinse or steam Ventilate to gas and odor free Educt and mop May require additional steaming to remove odor. ADJ/HEAT- There must be Heat adjacent if carried in Epoxy. MS.- A scale -free MS tank if cleaned to perfection. but over a 30 day voyage Avoid . Handling - To avoid problems product must be properly inhibited & stowed in clean & dry tanks. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends

of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

SULFURIC ACID
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank Coating : Battery acid, Chamber acid; fertilizer acid Oil of vitriol. : 1830 : SFA 2 4 : H SO Colorless to brown oily liquid; no or unless hot, then the odor is choking : 340C/ 644 F : 10C/ 50 F : 1.56~ 1.84 : Inorganic acid : Low :C :C :" :O :" : Complete : 3.4 : Stainless Steel Only : NO : Purge : Possibly Blanket : Possibly : Stainless Steel Only

Fire & Explosion Hazard Data

Grade: Non- flammable. Classified as a corrosive liquid. Electrical Group : B(based upon possible hydrogen gas (H2) generation should a leak or spill occur) General: Sulfuric acid will not burn. It will react with many metals, giving off hydrogen gas which is highly flammable. if hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See data sheet for hydrogen. Flash Point (F) : Non- flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : "

Special fire Procedures : DO NOT USE WATER to put out a fire if the water can get into concentrated sulfuric acid. In case of a fire to a sulfuric acid tank, use respiratory protection against fumes.

Health Hazard Data

Health hazard Rating : 2,4,2 3 Odor Threshold(ppm) : Greater than 1 mg/m 3 PEL/TWA(ppm) : 1 mg/m 3 TLV/TWA(ppm) : 1 mg/ m General : Liquid causes severe burns with destruction of tissue. Vapor very irritating. Symptoms: The inhalation hazard is sight at ordinary temp. The skin on which acid is spilled may feel hot or it sting or itch. Short Exposure Tolerance: 3 10 mg/m for 5 minutes; 5 mg/m for 10 minutes; 2mg/m for 30 minutes. Exposure Procedure : Drench with water. Remove contaminated clothing and flow water onto affected area for 15 minutes. For eyes contact- immediately flush eye with large amounts of water for 15minutes. Get medical attention.
3 3

Reactivity Data
Stability: Stable, but can react very easily with many other materials Compatibility: Material : highly corrosive to most metals; particularly at concentrations below 60 Be. May cause wood or cellulose to ignite. Cargo : Group 2 of compatibility chart. See also Appendix 1- Exceptions to the chart.

Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus, protective clothing. have body shield available, avoid contact with liquid. secure ignition sources because of the hydrogen gas generation. if possible, cover spill with sodium bicarbonate or soda ash-slacked lime mixture (50-50). Mix and add water to from a slurry. Scoop up slurry. Wash site with soda ash solution. Otherwise flush cautiously with water. avoid directing stream into large pools or pockets of concentrated acid. remarks: -Never add water to the acid, otherwise spattering will occur. if dilution is required, always add the acid very carefully to the water. The acid is heavier than water. thus, the heat of solution will be more uniformly dissipated, and spattering will be avoided. Operational Problems / Hazards See I.C.S Guide This is a very absolutely dry and vent line desiccator may be required. Use Closed Ullaging system All flange connection to be bolted. Personnel Protection Total protection suit and breathing apparatus Restrict personnel on deck Secure accommodation and recirculate air. Tank cleaning Commence cleaning as soon as practicable after discharge using copious quantities of cold water to rapidly neutralize the acids. Do not Steam of hot wash Ventilate

Fresh water rinse Educt and mop dry Check Ambient temporary the area loaded/voyage discharge if heat needed. It must be a steam coils in tank- NO. traced and/or insulated lined vessel and shore might do be sure to check. Cleaning- There must be abundance of fresh water empty tanks all at once- No trickling. Handling - Nitrogen blanked recommended always. Slop. if unable to pump straight overboard, Phenoline tank be used . Provided such a tank has a 5% Caustic soda solution in it. Use 95% fresh water and 5% caustic . This will a neutralizer . Pump slop & Caustic overboard as soon as possible. See Appendix Special cargoes Manuals HEALTH HAZARDS May be fatal if inhaled swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. May ignite other combustible materials (wood, paper, oil, etc) violent reaction with water. Flammable/poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. FIRE Do not get water inside container. 2 Small Fires: Dry chemical, Co Large Fires: Flood fire area with water from a distance do not get water inside container. Move container from fire area if you can do it without risk apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor; do not put water directed on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Spills; Dike for later disposal; do not apply water unless directed to do so cleanup only under supervision of an expert. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature

SULPHURIC ACID (FUMING )

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Oleum, Disulphuric acid, Prosulphuric acid. : 1830/1831/1832 :2 2 4 3 : H SO So : 201 : Inorganic Acid Colorless to dark brown heavy oily liquid. Fumes in moist air. Sharp, penetrating odor. : 1.9 to 2.1 : : : : : : : : : : 0.00116 Various with concentration 2 Highly reactive -see ICS guide and check compatibility chart. Stainless Steel Only. NO (Ensure Certificate obtained and Duration Checked) Purge Possibly Blanket : Possible SUS Only.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : 135 C Explosive Range : % to % Freeze Point : 35 C Autoignition Point : C Operational Problems/Hazardous See ICS Guide This is a very corrosive and toxic cargo ( Fuming vapor are both corrosive and highly toxic ) Tanks/lines should be absolutely dry Use vent line desiccators All flanges to be bolted. Personnel Protection; Total protection suit and breathing apparatus Restrict personnel on deck Secure accommodation and recirculate air Use Closed Ullaging systems. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : C

Vapor Return System Reg. : NO

discharge on passage according to regulations. Drying oil : NO Soluble in water : Complete

Cleaning from: Commence cleaning as soon as practicable after discharge using copious quantities of cold water to rapidly neutralize the acid. Do not steam or hot wash Ventilate Fresh water rinse Educt and mop dry Tanks and lines must be absolutely dry May purge with dry Nitrogen HEALTH HAZARDS May be fatal if inhaled swallowed or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. May ignite other combustible materials (wood, paper, oil, etc) violent reaction with water. Flammable/poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials isolate the leak or spill area immediately for at least 150 feet in all directions. See the table of in initial isolation and protective action distances. If you find the ID Number and the name of the material there begin protective action. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. FIRE Do not get water inside container. Small Fires: Dry chemical, Co2 Large Fires: Flood fire area with water from a distance do not get water inside container. Move container from fire area if you can do it without risk apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor; do not put water directed on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Spills; Dike for later disposal; do not apply water unless directed to do so cleanup only under supervision of an expert. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature

SAFFLOWER OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : :3 : : 19 : Ester Golden yellow oil, which is liquid at normal temperatures. Somewhat similar to that of Linseed oil. : 0.923 - 0.927 : : : : : : : : : :

Ambient 16 ~ 24 C Ambient 32 Basically Non-hazardous. Drying oil. No specific handling regulations Sip or shore lines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Epoxy, Polyurethane, Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Avoid contact with water as this can increase FFA content and therefore may damage coating. Not Normally swept, but may require sweeping if sea temperature low. As this is a drying oil, check Oxygen content before tank entry. Also requires cold pre-wash immediately after discharge As used for foodstuffs, surveyors becoming increasingly critical of tank cleanliness Keep away from heated cargo to avoid hardening on bulkheads. May be loaded overall. Personnel Protection; Boiler suit, normal working gear. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : YES Soluble in water : NO Cleaning from: Cold pre-wash to remove residues as soon as possible as after discharge Hot wash with chemical injection ( temperature compatible with coating) Fresh water rinse or steam Ventilate

Educt and mop Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 22. These cargoes are drying or semi-drying oils which require cold(ambient) washing immediately after discharging.

SUNFLOWER SEED OIL

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family : : :3 : : 19 : Ester

Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: A pale yellow liquid with a pleasant odor. : 0.924 @ 16C : 0.00063 : Ambient : 15 ~ 20 C : 10 ~ 15 C : 34 : Basically non-hazardous. Non toxic. No specific handling regulations Ships lines, Preferably portable via droplines or shore lines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Epoxy, Polyurethane,Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : C Autoignition Point : C Operational Problems/Hazardous May require sweeping. Check Oxygen content before tank entry. Avoid stowage next to cargo heated above 35 C. Personnel Protection; Boiler suit , normal working gear. Check Protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : YES Soluble in water : NO Cleaning from: Cold pre-wash after discharge to remove residues Hot sea water wash, minimum 3 hours , with chemical injection. Spot clean as required Fresh water rinse or steam Ventilate Educt and mop dry. Heat - Only in very cold area season is heat needed at some time /places. heat to 70 ~80 F . This will give reactive an empty tank. Zinc - The FFA is always low 1~1.5% but check to FFA sake of good order. Good Cargo.

SYNPERONICS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. : : : : : : : : ICI Products of Alkyl Phenol and Alcohol Ethoxylates.

Various

Colorless to gray white normally clear liquid with mild odor. 0.897 ~ 1.014 @ 25 C

: : 25 ~ 50 C : :

USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : :

40 Generally non-reactive Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge Possibly Blanket : YES Any coating, subject to heat restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : C Draeger Tube No. : Boiling Point : C Explosive Range : % to % Freeze Point : 7~ 20 C Autoignition Point : C Operational Problems/Hazardous Generally non-hazardous , but liquid may be harmful to eyes. Product is highly Slippery and care should be taken to prevent any spillage from hoses or sampling equipment. Product is easily contaminated by rust and moisture Nitrogen blanket and/or vent line desiccator may be required. Personnel Protection; Boiler suit, goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Product may require Anti-froth treatment. Check with shipper. Cold sea water pre-wash for minimum 2 hours Hot sea water wash , minimum 3hours Fresh water rinse Educt and mop dry Products are Nonionic Surface active agents (Frothier) and are variously numbered NP or OP dependent on type. N.P.E- Handling - None of these grades of Nynyl Phenol are difficult to handle. The Word Phenol is misreading to some. Good cargo small problem. Partial

TALL OIL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen : Liquid rosin; tallelol; tallol : : OTL : Mixture rosin acids. : Yellow of rosin acids : V.High : : 0.95~1.00 : : 1.5 : : B, D : 0.1 : D,O : 0.15 : Negligible : NP No specific handling regulations Preferably load through droplines. If possible use shore hoses as difficult to clean. : NO : Purge : NO Blanket : NO

Tank coating

: Epoxy, Polyurethane, May be carried in Stainless Steel

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid D Slight fire hazard when exposed to heat or flame. 380 Unavailable " Foam, dry chemical or Co2. Water may be ineffective on fire. Use water to cool exposed tanks.

Health Hazard Data

Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : " TLV/TWA(ppm) : " General : Avoid contact with liquid. Symptoms : Skin contact will cause minor reddening. Short Exposure Tolerance : Not pertinent Exposure Procedure : Skin- flush affected areas with plenty of water; wash thoroughly with soap and water

Reactivity Data
Stability : Stable Compatibility: Material: Usual materials of construction are suitable Cargo : Group 34 of compatibility

Spill or Leak Procedure

wear butyl gloves, face shield and protective clothing. Operational Problems/ Hazards Product liable to settle out in crystalline form. Be prepared to recirculate product pre-heated prior to loading Portable hoses to be hot washed and steamed as soon as possible after use. Acid content may be high, Product residues will be left after discharge. Sweeping is not normally advised Product to be discharge temperature two days prior to arrival. Maximum increase 5 C per day. Personnel Protection Boiler suit, goggles, gloves Normal working gear. Tank cleaning Should be washed as soon as possible after discharge. Results have been obtained by first spraying tank with warm Gas oil and allowing one hour soak in time, then round washing with fresh water/ Caustic (3% or 5% solution) Inspect tanks after two hours (Observe tank entry procedures) If residues dispersed or solution degraded to require disposal Hot sea water wash, minimum 4 hours - 5 ft. drops with chemical injection. Ventilate and inspect Steam tank and line - Ventilate ( Hand cleaning will be require ), Educt and mop NOTE : Tank may be gently steamed to keep residues soft if it is not possible to wash straight after discharge . Cold sea water wash as soon after discharge as possible will remove heaviest residues then gas oil spray and caustic solution wash. Crude- S.G varies from 0.93~ 0.98 -common-0.95. Heat - It is imperative that product is under heat during voyage.

Restrict cargo. if improperly Heated. 6/12 hours before discharge. Distilled- SUS may be needed /requested for this super-sensitive grades of defined Tall oil Phenoline is resistant. See Appendix Special Cargoes Manual Tank cleaning/ Upon completion of the mandatory prewash, if required, (as the tank has been prewashed with Tall Oil Fatty Acid, the same is consicered as the last cargo) carry out methods below: 1. If slops cannot immediately be disposed after discharge, machine wash each tank with warm seawater (50C) for 1 hour without pumping out. 2. Leave the wash water/slop in the same tanks until cleaning can commence and the slop disposed (Ensure nay sloshing will not adversely effect the heating coils). 3. When commencing tank cleaning, machine wash the tank(s) hot (80C-85C) for 8 hour. 4. When using portable machines, position machines for 2 hours at 10/20/30/40 ft. drops. When using fixed tank cleaning machines washing time can normally be reduced to 4 hours. 5. On completion of washing fresh water rince and eject the tank. 6. Prepare a mixture in the tank of, adding 3000 liters of fresh water and 350 Kg caustic flakes. 7. Reciculate the caustic/fresh water for two hours (35-40 C) on each drop, starting from bottom going up; 40/30/20/10 ft. 8. During the recirculation apply heating on the coils, maximum 40 C in the tank. The heating must be applied only during the actual recirculating via the tank washing machine. 9. On cokpletion of recirculation rinse the tank warm (35-40 C) for 6 hours, 1 1/2 hours on each drop. 10. Fresh water rinse tank and lines. 11. Toluene steam cargo lines.

TALLOW
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) : : : : : : : : : : : : : : : : : Edible tallow; inedible tallow; tallow oil TLO Fats containing C16~C18 Dark yellow liquid with a waxy odor V.High 2~7 c/ 35~45 F 0.85~ 0.89 @ 70c Ester 2.0 D 0.1 D 0.2 Negligible NP

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures Handling : : : : : : : : : Combustible liquid D Slight fire hazard when exposed to heat or flame. 509 Unavailable " Foam, water. Co2, dry chemical Water may be ineffective. Cool exposed containers with water. No specific handling regulations ship or shore lines.

Inhibitor Nitrogen Tank coating

: NO : Purge NO Blanket : NO : Epoxy, Polyurethane, SUS

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms Short Exposure Tolerance Exposure Procedure : : : : : : : : Not pertinent Unavailable " Not pertinent Non- toxic, but possibility of thermal burns from hot liquid. Non- toxic Hot liquid can burn eyes and skin. Treat burns caused by hot liquid.

Reactivity Data
Stability : Stable. Compatibility: Material: Cargo : Group 34 of compatibility chart. See also Appendix-1 Exceptions to the chart.

Spill or Leak Procedure

Wear rubber gloves, face shield and protective clothing for hot liquid. Operational Problems/ Hazards Temperature given are general approximations will be dependent upon charterers requirements. Temp must not be raised more than 6 C/day. Sweeping of tallow tanks and amount of work required to get tank empty is dependent entirely upon the grade. Solidification temp varies according to grade, Edible grades will require particularly standard of cleanliness and coatings. Personnel Protection: Boil suit , normal working gear, gloves. Tank cleaning Per-clean with warm sea water to remove residues Hot sea water wash, min. 3 hour, with chemical injection (Max. temp compatible with coatings) Spot clean as required. may require spraying with neat chemical. Fresh water rinse or steam Ventilate, Educt and mop. Note : Check gas and oxygen content before entry into tanks or tallow slops tanks. TALLOW FATTY ACID; Fax-no nitrogen blanket no heat required. fine product. Westaco- To preserve cream color, dry ice is added to cargo upon loading-supply by shipper. Union/heat- Temp. must never go below 40F product changes color at lower temp. Discharge any where between 80/90F. Handling- All above Acids fine products needing careful handling-Important. Edible - A maintain heat during Voy. at 110F discharge-131F. All other grades can be carried without heat up to one week before discharge. heating Tallow 135F on week is OK. Discharge temp. should be reached 24 hours before arrival at discharge port. TALOW FATTY ACOHOL; This fine/expensive Fatty alcohol (Natural) a good lined tank cleaned tank perfection.

TALLOW FATTY ACID #153(95); These refined tallow products need lined tanks. must be good condition. If carried on old line be sure for check lined for careless . If in doubt discharge head overhead loading always. TALLOW STERINE; Zinc- The FFA is 0.5% Max. making zinc OK. Cleaning- Product handle like Wax . With plenty HOT water/Steam . Cleaning after an easy jobs. Start B/W on bottom. Live Steam will good. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code ( C ) Hot water (55 degree C up to the maximum allowed by the tank coating manufacture).

TAR ACID
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : :

3 A mixture of phenols, cresols and higher tar acids. Phenols A black brown viscous liquid with a sharp characteristic odor. 1.06 @ 15C

: : 45 ~ 65 C : 60 C : 50 C : 21 : Reacts with oxidizing agents, sulfuric and nitric acid Shore lines preferably to deck tank manifolds, or stainless steel poison bank. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless Steel only at present.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 90 C Draeger Tube No. : CH315 Phenol 5/a Boiling Point : 180~ 300C Explosive Range : % to % Freeze Point : below 0/C Autoignition Point : 700 C Operational Problems/Hazardous Very corrosive to human skin- full protective clothing required. Vapors and liquid also toxic by inhalation and ingestion Problems can be encountered when tank cleaning to remove staining from coating - see over. Check locally for temperature of carriage and discharge as this may vary with grade composition. Although a crude product it is essential that no contamination occurs in transit. Closed loading ullaging should be used.

Personnel Protection; Full protective clothing and breathing apparatus while loading, discharging, tank cleaning Secure accommodation and recirculate air. Restrict personnel on deck. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water :

NO

Cleaning from: Cold to warm sea water pre-wash to remove residues (2 hour) Hot sea water wash with chemical injection, 5 ft half hour drops. May require a gas oil spray between washes if residue is particularly thick Ventilate and inspect, Re-wash if necessary Fresh water rinse or steam Ventilate to gas and odor free. Educt and mop dry. Treat as Phenol and Cresol. USCG: Since all grades contain Phenols and/or Xylenols compliance cargo rating can be expected. Be prepared for long hard cleaning after discharge. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 8. Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

TEE FROTH
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Teefroth A*, Teefroth D*, ICI Trade names. Not listed 3

A mixture of polypropylene and polyethylene glycols. A straw-colored liquid with a faint odor. 0.979 @ 15.5 C

Ambient 40 Basically stable. Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 82.2 C Draeger Tube No. : Boiling Point : 125C Explosive Range : % to % Freeze Point : - 70 C Autoignition Point : C Operational Problems/Hazardous Vapor may cause slight eye irritation Splashes to eye or skin should be washed off with plenty of water. Personnel Protection; Boiler suit, goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO

Soluble in water :

Complete

Cleaning from: Add anti-frothing agent, Cold sea water wash, 5ft half hour drops Fresh water wash, or steam, Ventilate, Educt and mop Phenolic: Test will in all like hood prove coating OK. Handling : It is a strong solvent needing 100% clean tank and lines Good cargo with no problems.

TEEPOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : Teepol 514, Teepol 610, Teepol GD 53. 3 an aqueous solution of alkyl and alkyl benzene sulphates. 203 A Biodegradable liquid detergent A pale amber liquid with a mild odor. 1.07 ~ 1.08 @ 15 C 0.00057 Ambient Stable. Portable lines to droplines NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Any coating, suitable.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : None flammable Draeger Tube No. : Boiling Point : 100 C Explosive Range : Freeze Point :5C Autoignition Point : C Operational Problems/Hazardous Normally carried ambient however should be maintained above clear point which is 5 C. Problems from frothing are likely to be encountered when washing. Therefore add anti-frothing agent to tank before starting to wash. Otherwise no significant hazards. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Complete Cleaning from: Cold warm SW wash (.5 hour foot drops )

Fresh water rinse or steam Ventilate to gas and odor free. Educt and mop dry

1,1,2,2-TETRACHLOROETHANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Acetylene tetrachloride; Ethane,1,1,2,2-tetrachloro-; Tetrachloroethane; sym-tetrachloroethane : 1702 : TEC 2 2 : CI CHCHCI : Clear to slight yellow liquid with chloroform- like odor. : 146C/ 295 F : -44C/ -47 F : 1.60 : Halogenated hydrocarbons : 13.0 :B :B : 0.5 :O : 1.0 : Slight : 5.8 : Clean, dry ships lines to deck lines : NO : Purge : Possible Blanket : Possible : SUS, ZINC with restrictions

Fire & Explosion Hazard Data

Grade: Non- flammable Electrical Group : NA General: Non-flammable, corrosive liquid. when heated, it emits highly toxic decomposition products. Flash Point (F) : Non-Flammable Flammable Limits : " Auto igniting Temp.(F) : " Extinguishing Agents : " Special fire Procedures : Wear self contained breathing apparatus.

Health Hazard Data

Health hazard Rating : Unavailable Odor Threshold(ppm) : 0.5 PEL/TWA(ppm) : 1/skin TLV/TWA(ppm) : 1/Skin General : Suspected carcinogen. A powerful narcotic and liver poison. Symptoms: Ingestion- vomiting, diarrhea. Acute intoxication with unconsciousness, cyanosis, loss of reflexes and death. Inhalation- can be absorbed by lungs. fatal after repeated inhalation. Short Exposure Tolerance : 10 ppm for 30 minutes. Exposure Procedure : Inhalation- remove to fresh air and, if necessary, administer artificial respiration. Ingestion- induce vomiting. Eyes- flush with water for 15 minutes. Skin- remove clothing and wash skin with soap and warm water. in all causes call a doctor.

Reactivity Data
Stability: Stable. Compatibility: Material : May attack some forms of plastics. Cargo : Group 36 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus and protective clothing. secure all sources of ignition. Absorb with vermiculite and clean up. Wash site with soap and water. Operational Problems/ Hazards Very susceptible to moisture. Tanks and lines must be clean and dry. Probably loaded through a dryer, and vent line may require a desiccator . Check locally with surveyor. Highly toxic and corrosive liquid and vapor . Avoid all contact . Stow away from heated cargo as extremely toxic decomposition products emitted at elevated temperatures. Products considered a servere industrial hazards and its use has been restricted and even forbidden in some countries. Product itself is non-flammable. Personnel Protection Chemical protective clothing, gloves and goggles Breathing apparatus Secure accommodation and recirculate air during all operations. Tank cleaning Cold sea water wash, 5 ft half hour drops Ensure all residues dispersed from tank, lines and pump Ventilate to gas/odor free (steaming may be required to disperse odor) Fresh water rinse Educt and mop Draeger tube hyaszine 0.25/a, or CH205 Ammonia, will give indications of vapors. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases

FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

TETRACHLOROETHYLENE
Synonyms IMO No IMO TYPE Formula Carbon Dichloride, Ethylene Tetrachloride, Perchloroethylene, Perklone. : 1897 :3 2 2 : CL C : C CL .

ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling

: 204 : Hydrocarbon (aliphatic Unsaturated ) : A colorless mobile liquid with a sharp aromatic ether-like odor. : 1.63 ~1.636 @ 15 C : 0.00166 : Ambient : : : 36 Can have some reaction with oxidizing agents, otherwise basically stable Very clean portable line to deck tank manifolds, or load via droplines for quality control. : NO (Ensure Certificate obtained and Duration Checked) : Purge Probably Blanket : Probable

Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : Stainless steel preferred Can be carried in Epoxy and zinc silicate with restrictions polyurethane is NOT suitable for this product. consult coating list Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : None flammable Draeger Tube No. : CH307 Perchloroethylene 10/a Boiling Point : 121 C Explosive Range : % to % Freeze Point : - 23 C Autoignition Point : C

Operational Problems/Hazardous Being a solvent for the dry cleaning industry, absolute cleanliness of tanks and lines and non-contamination of the cargo is essential Should be stowed away from heated cargo because of derivation of highly toxic gases at elevated temperatures Susceptible to static . Lines should be blown with Nitrogen Liquid and vapor moderate/ highly toxic. Avoid all contact Closed loading ullaging should be used, as vapor heavier than air may not disperse readily on still days. Very susceptible to moisture , usually loaded through a drier with Nitrogen blanket to exclude air. Vent lines require desiccator Tanks and lines must be scrupulously clean and dry Soften coatings . Tanks should be vented for a minimum of 24 hours to allow hardening off.

Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Before starting tank cleaning the tank/s MUST be vented for at least 24 hours to remove all traces of ammonia vapor .

Complete

Test with Draeger tube to check ammonia presence (CH205 Ammonia 5/a) Hot sea water wash, 5 ft half hour drops Fresh water rinse Educt and mop Tank must be dry Tank must not be Dirty ballasted (i.e. tank must be cleaned before being used as a ballast tank ) Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating.

HEALTH HAZARDS Vapors may cause dizziness or suffocation Exposure in on enclosed area may be very harmful. Contact may irritate burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials but none of them ignites readily. Most vapors heavier than air Air/vapor mixtures may explode when ignited. Container may explode in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Remove and isolate contaminated clothing at the site.

CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co . Large Fires: Water spray ,fog or regular foam apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Small Liquid spills: Take up with sand, earth or other noncombustible absorbent Material Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; \ if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Use first aid treatment according to the nature of the injury

TETRAETHYLENE GLYCOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) bis[2-(2-hydroxyethoxy)ethyl]ether; TEG 3,6,9-Trioxaundecanol, 11-diol : : TTG 2 4 3 2 4 : HO(C H O) C H OH : Colorless to pale straw colored liquid; sweet odor. : 327C/ 621 F : -6C/ -21 F : 1.13 : Glycol ether : Low : : III :" :D :"

Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : :

Complete 6.7 Load via portable lines to droplines for quality control NO Purge : NO Blanket : NO Most coatings are suitable

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid C Slight fire hazard when exposed to heat or flame. 345 Unavailable " Alcohol foam, Co2, water, dry chemical Water may cause frothing. Cool exposed tanks with water.

Health Hazard Data

Health hazard Rating : 0,0,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Low to no toxicity; no skin, ingestive or inhalation effects. Symptoms : Unavailable Short Exposure Tolerance : Unavailable. Exposure Procedure: Vapor- remove victim to fresh air. Skin or eye contact- remove contaminatedclothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: No spontaneous decomposition, not dangerously reactive. Compatibility: Material : Steel or stainless steel recommended. Cargo : Group 40 of compatibility chart.

Spill or Leak Procedure

Avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards No specific problems Personnel Protection Chemical protective clothing, gloves, goggles. Breathing apparatus on standby Tank cleaning Ventilate to gas free or inert (Or cold sea water pre-wash to disperse all residues then ventilate ) Hot sea water wash, 5 ft half hour drops with chemical injection if required. Steam tank, line and pump Educt and mop Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration.

All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

TETRAHYDROFURAN
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : : : : : : : : : : : : : : : : : : : : : Diethylene oxide; furan, tetrahydro-; Tetramethylene oxide; THF. 2056 THF 2 4 2 (C H ) O Colorless liquid; ether like odor. 66C/ 150 F -108C/ -162 F 0.89 Ether 142 C D 7.7 O 8.5 Appreciable 1.35 Portable lines to deck tank manifolds YES Purge : Possible Blanket : Probably Stainless steel, Further information required - check locally

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :C General: Dangerous fire hazard; moderate explosion hazard. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) :6 Flammable Limits : 2.0~11.8% Auto igniting Temp.(F) : 610 Extinguishing Agents : CO2, dry chemical, alcohol foam, water spray. Special fire Procedures : Give off toxic fumes when heated. provide respiratory protection for firefighters. Water may be ineffective.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General : Liquid irritating on contact. Vapor inhalation causes severe irritation of severe headache and drowsiness. : : : : Unavailable 400* 200 200

mucous membranes with strong narcotic action resulting in

Symptoms: Irritation of eyes and mucous membranes; headache or drowsiness. Short Exposure Tolerance: 500 ppm for 30 minutes. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention. Exposure to a potentially dangerous vapor concentration can occur before the product is detected by smell.

Reactivity Data
Stability: May form explosive peroxides upon storage or exposure to light. Should be stabilized to prevent peroxide formation. Compatibility: Material : This compound dissolves rubber. Cargo : Group 41 of compatibility chart

Spill or Leak Procedure

Wear polyethylene gloves, protective clothing and face shield. Have all purpose canister mask available. Avoid contact with liquid. secure ignition sources. remarks: Note: Detectable odor is greater than the TLV. Exposure to a potentially dangerous vapor concentration can occur before the product is detected by smell. Operational Problems / Hazards Unless established it may from organic peroxides which can decompose with explosive violence. Check inhibitor content if cargo remains on board for a long period. If cargo is not established then tanks must be inerted. Check locally for charterers requirements. Moderate narcotic and irritation form liquid and vapor . Avoid contact . Odor threshold is above TLV. Even when cargo is inhibited, the vapor may not be; the vapor may therefore polymerize when it condenses and could cause blockages on flame arrestors and P/V valves A base solvent, it will require good standard of tank and line cleanliness .

Reactivity: Reacts dangerously with the following; halogensm nitric acids hydrogen peroxide, most acids, and ammonia solutions. Also reacts with air unless inhibited or carried under inert blanket. Personnel Protection Gloves, goggles, Protective suit, B.A on standby,. Tank cleaning Cold S.W wash to remove stripping and residues (2hour) Hot S.W wash with chemical injections ( wash in lean ), Steam Ventilate till tank odor free Educt and mop dry (Observe tank entry procedures ) Handling - Tank inspection prior to loading strict- With N2 purging of tank. Apply Nitrogen Blanket. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk.

Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

TETRAHYDRONAPHTHALENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating 1,2,3,4-Tetrahydronaphthalene; Tetralin; Tetraline; Tetramp; Tetranap. : 2136 : THN 10 12 :C H : Colorless liquid; Odor similar : 206C/ 402F : -25C/ -13F : 0.98 : Aromatic hydrocarbons : Low : : C* : 0.02 : D,O : 0.04 : Insoluble : 4.55 : Load via portable lines to droplines or manifolds. : : Purge : Possibly Blanket : YES : Most coatings suitable

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid D Moderate fire hazard when exposed to heat or flame. 172 LEL= 0.8%, at 100c. UEL= 5.0%, @ 150c. 722 Foam, carbon dioxide, dry chemical. Water may be ineffective on fire.

Health Hazard Data

Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapor irritating at high concentrations. Symptoms: Vapor causes headache, vomiting, eye irritation, and coughing. Skin contact is irritating. Short Exposure Tolerance : Unavailable Exposure Procedure : Ingestion- induce vomiting. Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Fairly stable but will, however, polymerize and oxidize giving rise to discoloration and resinous material. Compatibility: Material : some rubber and plastics unsuitable. Cargo : Group 32 of compatibility chart.

Spill or Leak Procedure

wear polyethylene gloves, face shield, protective clothing. have all purpose canister mask available. avoid contact with liquid. Secure ignition sources. remarks: * Pollution category C oil-like, 33 CFR 151.49 ++ Unassigned. Operational Problems /Hazards Susceptible to static. Blow lines with Nitrogen Not highly flammable, although intimate contact with air causes it to oxidize and polymerize, leaving explosive resinous residues; therefore must be carried under a nitrogen blanket Vapor pressure is low, so high concentrations of vapor should not be expected. However, vapor and liquid have respectively moderate narcotic and irritating properties. Personnel protection Boiler suit , normal working gear Tank cleaning Per-wash with cold sea water immediately following discharge to remove residues Hot sea water wash with chemical injection , 5 ft. half hour drops Spot water as required Fresh water rinse or steam Ventilate Educt and mop dry 64/66 - there must be no heat adjacent if this coating in use. Good cargo - No problems. Uses : In the paint and varnish industries and as a linseed oil substitute. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)-

Ambient water followed by warm water.

FIRE OR EXPLOSION May be ignited by heat, sparks or flames container may explode violently in heat of fire may explode from heat or contamination runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Contact may cause burns to skin and eyes fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small fire; dry chemical, co ,water spray or regular foam. Large Fires: flood fire area with water from a distance. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks for massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills; take up with sand or other noncombustible absorbent materials from spill area. Large spill; wet down with water and dike for later disposal. FIRST AID Move victim to fresh air; call emergency medical care in case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Wash skin with soap and water Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

TETRAPROPYLENE BENZENE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : :

3 Mixtures.

Clear colorless liquid with sweet benzene like odor. 0.82 @ 20 C

Ambient May react with oxides and acids check other cargo. Portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Most coatings suitable , subject to coating guides.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : None flammable Draeger Tube No. : Boiling Point : Explosive Range : Freeze Point : Autoignition Point : Operational Problems/Hazardous Product liquid and vapor cause irritation and can be harmful to eyes. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : V. Slight

Cleaning from: Cold S.W wash to remove residues Hot S.W wash with chemical injection ( 0.5 hrs 5 ft half hour drops ) Fresh water rinse or steam Educt and mop

TOLUENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Portable lines to either manifolds or droplines Lines to be bonded or electrically non-conductive. Inhibitor : NO Nitrogen : Purge : NO Blanket : Possible Tank coating : Most coatings suitable Benzene , methyl-; Methacide; methylbenzene; Methylbenzol; phenylmethane; toluol : 1294 : TOL 6 5 3 : C H CH : Colorless liquid; benzene-like odor : 111C/ 231 F : -95C/ -139 F : 0.87 : Aromatic hydrocarbon : ** :C : C* : 1.1 : D,O : 1.5 : Negligible : 3.14

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :D General: Dangerous fire hazard when exposed to heat or flame. moderate explosion hazard when exposed to flame. Flash Point (F) : 45 Flammable Limits : 1.27~7.0% Auto igniting Temp.(F) : 1026 Extinguishing Agents : CO2, dry chemical, foam, water fog. Special fire Procedures : Fight the same as a petroleum fire. the vapors are more toxic than those of petroleum and should be avoided. a fire should be fought in the same manner as any grade C flammable petroleum product.

Health Hazard Data

Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 0.17 PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Liquid slightly irritating, vapor inhalation has moderate narcotic effect causing dizziness and headache, with severe fatigue and metal confusion. Symptoms:

Nausea, dizziness, and headache. the victim may appear to be drunk. Short Exposure Tolerance: Inhalation of 600 ppm for 30 minutes has cause severe fatigue, metal confusion, nausea, dizziness and headache. Exposure Procedure : Ingestion- do not induce vomiting. Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Stable. Compatibility: Material : rubber exposed to toluene will swell, soften, and deteriorate. most are compatible with toluene. Cargo : Group 32 of compatibility chart.

Spill or Leak Procedure

Wear plastic gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. remarks: * Pollution category C oil-like, 33 CFR 151.49. ** Vapor pressure: 28 mmHg @ 25c.

Operational Problems/ Hazards Susceptible to static, Blow lines with Nitrogen Vapor and liquid have moderate narcotic and systemic effects. As product is base solvent tanks and lines will have to be scrupulously clean. Foot samples from tanks can be expected to be taken and analyzed before commencement of full rate loading. Surveyor becoming increasingly critical on tank inspections. Possibly now classed as high specification cargo, therefore all contamination must be avoided Moderate fire and explosion hazards. Personnel Protection Chemical suit, gloves Breathing apparatus, All contact with vapor and liquid Must be avoided. Tank cleaning Cold S.W pre-wash to remove residues (2 hours) Hot sea water wash with chemical injection, 5 ft half hour drops. Fresh water rinse or steam Ventilate Educt and mop dry 64/66- Ventilate tank for at least 24 hours after discharge -to harden. Handling - No problems if Tank/pump /line are clean. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames.

Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

-TOLUENE DIISOCYANATE (T.D.I)

Synonyms Benzene,1,3-diisocyanatomethyl-; 2,4-diisocyanatotoluenene; TDI; 2,4-toluene; Diisocyanate; Toluene-2,4-diisocyanate; 2,4-tolulene diisocyanate : 2078 : 3 6 3 2 : CH C H (NCO) : Clear, faintly yellow liquid strong : 251C/ 484F : 19C/ 57 F : 1.21 : Aromatic isocyanate : Low :B :C :" :O :" : Reacts : 6.0

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : Stainless Steel lines to deck tanks, direct After loading elbow should be reconnected and purged from ashore with dry nitrogen to maintain positive pressure throughout system. Inhibitor : NO Nitrogen : purge : YES Blanket : YES Tank coating : Stainless steel

Fire & Explosion Hazard Data

Grade-E : Combustible liquid Electrical Group :D General : Highly toxic nitrogen dioxide gas is produced when this product burns. Flash Point (F) : 270 Flammable Limits : 0.9~ 9.5 % Auto igniting Temp.(F) : above 300 Extinguishing Agents : CO2, dry chemical, water fog. Special fire Procedures : Provide firefighters with full body and respiratory protection, do not allow water to get into of toluene diisocayanate

Health Hazard Data

Health hazard Rating : 3,3,4

Odor Threshold(ppm) : 0.4 PEL/TWA(ppm) : 0.005 TLV/TWA(ppm) : 0.005 General : Suspected carcinogen. Liquid extremely harmful by absorption. Vapor inhalation severely irritating to nose and throat repeated exposure to low concentration can lead to respiratory problems and severe dermatitis. Symptoms: Burning at site of contact. Vapor inhalation causes intense irritation of nose and throat. inhalation can also cause asthma-like symptoms. which may not appear for several hours after exposure. Short Exposure Tolerance: 0.5 ppm are irritating to nose and throat for brief exposure. Exposure Procedure : Do NOT induce vomiting. Vapor- remove victim to fresh air; if breathing stops apply artificial respiration. Oxygen, administered by trained personnel. is often helpful. Skin or eye contact- immediately flush affected parts gently with water while removing contaminated clothing. continue to flush for 15 minutes. Get medical help promptly.

Reactivity Data
Stability: Product will reacts with water and even the moisture in the excess of 100 ppm, evolving Co2 and heat, can react violently with animals, alcohols and acids. Compatibility: Material : Stainless steel, nickel and aluminum are satisfactory construction materials. avoid copper and copper alloys. mild steel may be used if it clean and entirely free of rust and moisture. Cargo : Group 12 of compatibility chart.

Spill or Leak Procedure

Wear butyl rubber gloves, protective clothing, self contained breathing apparatus, protective shoes. Avoid contact with liquid. Keep unprotected personnel away from spill area. May mix with vermiculite, sodium bicarbonate, or sand Pack in cardboard box and burn in open pit using crumpled paper and wood pplinters as fuel. Wash site with soap solution. Operational Problems/ Hazards An extremely toxic product in all forms. Extremely reactive, especially with water in any form (i.e. moisture ) All pipes to be well made and have new packing. Tank lids and B.W openings to have new packing and sealed with paraffin wax. Requires high standard or tank cleanliness Surveyors will be highly critical. After passed as suitable, tank will be purged ( ship or shore) with dry Nitrogen. Ensure chemist attending has requisite dew point measuring instruments. Line will be purged before and after loading . T.D.I neutralizer liquid/ powder must be on board before starting loading to deal with any spillages. No other cargo to be worked when loading/ discharging TDI, Nitrogen blanket positive pressure must be maintained throughout voyage. Extra cylinders are supplied for this purpose. Hydraulic oil to be used in cargo coils to heat/cool cargo as required. Circlip thermometers should be fitted to forecle header tank and inlet to . Personnel protection Chemical suit, gloves, goggles Tank cleaning Warm S.W. wash ( 0.5 hour 5 ft drop) Good fresh water rinse or steam Ventilate to gas and odor free Educt and mop dry

Heat - Use adjacent tank for heating . Steam coils Unsafe. Coating- It is risky - If cleaning problems develop after discharge. All shippers So far prefer /request SUS. Handling - Special handling & cleaning instructions will follow each shipments. Details refer to Appendix Special cargoes Manual

HEALTH HAZARDS Poisonous; may be fatal if inhaled or absorbed through skin contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION May be ignited by heat, sparks or flames contact may cause burns to skin and eyes. Vapor explosion and poison hazard indoors, outdoors or sewers EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires: Dry chemical, Co2, water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Cool container with water using unmanned device until well after fire is out fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal do not scatter the material. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material; stop leak if you can do it without risk. Water spray may reduce vapor; but it may nit prevent ignition in closed space. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature Effect may be delayed; keep victim under observation.

TRIBUTUL PHOSPHATE
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity : TBA : :3 4 9 3 4 : ( C H ) PO : 209A : Organic Phosphates : Clear colorless liquid with slight smell of Butanol. : 0.978 @ 25 C : : Ambient : : : Oxidizing agents possible at high temperature Slow hydrosis Reaction with alkalis not dangerous . Data not available on further chemicals. : Portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Any coatings suitable

Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV5mg.cm 3 Flash point : 102 C Draeger Tube No. : Boiling Point : 289 C Explosive Range : % to % Freeze Point : -80 C Autoignition Point : 289 C Operational Problems/Hazardous Dangerous when heated to decomposition Otherwise low toxicity. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: V. Slight

Warm sea water wash, 5 ft. half hours drops. Fresh water rinse or steam. Educt and mop Tanks must be dry See more major problems with this non-hazardous additive . Not carried yet. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

1,1,1-TRICHLOROETHANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : Chlorothene;ethane;1,1,1-trichloro- Methyl chloroform; 1,1,1-TCE : 2831 : TCE : CH3CCI3 : Colorless liquid; sweetish : *74c/ 165 F : 2C/ 36 F : 1.46 : Halogenated compound : 100 :C :B : 4.0 : O,** : 4.9 : Negligible : 4.6 Load via portable lines to droplines or manifold should be flushed out immediately after use. : : Purge : NO Blanket : NO Stainless steel, also Zinc Silicate, Epoxy and polyurethane with restrictions.

Fire & Explosion Hazard Data

Grade: None assigned Electrical Group :D General: Does not burn readily but can produce a dangerous "flash" when vapors are exposed to a high-energy spark sources in a confined space. When in contact with hot metal or a flame, methyl chloroform can decomposes to form phosgene, which is highly toxic. Flash Point (F) : Unavailable Flammable Limits : 7~ 16%(approximate value for flash described above) Auto igniting Temp.(F) : 932 Extinguishing Agents : Dry chemical, form or CO2. Special fire Procedures : Wear eye protection, self contained breathing apparatus and protective clothing.

Health Hazard Data

Health hazard Rating : 1,1,2 Odor Threshold(ppm) : 100 PEL/TWA(ppm) : 350 TLV/TWA(ppm) : 350 General : Vapor inhalation gives moderate irritation of air passage plus moderate narcotic effect. Prolonged or repeated skin contact may cause defeating of the skin and may produce dermatitis from daily contact. Symptoms Short Exposure Tolerance : Dizziness, headache, nausea, and drowsiness. : 1500 ppm.

Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply respiration.

Skin or eye contact- remove contaminated clothing and gently affected areas with water for 15 min., Get medical advice or attention.

Reactivity Data
Stability: Begins to decomposes at 350 F. May decomposes to hydrogen chloride and other toxic products. Compatibility: Material : the uninhibited grade is corrosive to aluminum, although the inhibited grade may be used with aluminum and any common construction metals at temperature up to 175F Cargo : Group 36 of compatibility chart. See also, Appendix 1- Exceptions to the chart.

Spill or Leak Procedure

Wear rubber gloves and protective clothing. avoid contact with liquid. Secure ignition sources. remarks: The commercial inhibited product has a boiling range of 160~190F.

* Unregulated, Table 2, 46 CFR 153.

Operational problems/ Hazards Does not readily burn, however can be ignited by high energy sources, although flame speed is slow. Moderately toxic by inhalation Cargo can become acidic when mixed with water, may therefore contain inhibitor to minimize this reaction Tanks must be washed before being used for ballast Product should be stowed away from heated cargo. May be loaded through a drier. Vent line desiccator may be required- check locally Susceptible to static - lines should be blown with Nitrogen Personnel Protection Chemical suit Breathing apparatus Tank cleaning Hot salt water wash, Ventilate to gas and odor free Fresh water rinse, Educt and mop Tank must be dry and grease free M.S - M.S is O.K , but Dow is reluctant to load, no matter how good a tank- Avoid M.S tanks Good cargo- No problems. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating. HEALTH HAZARDS Vapors may cause dizziness or suffocation Exposure in on enclosed area may be very harmful. Contact may irritate burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials but none of them ignites readily. Most vapors heavier than air Air/vapor mixtures may explode when ignited. Container may explode in heat of fire.

EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co . Large Fires: Water spray ,fog or regular foam apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Small Liquid spills: Take up with sand, earth or other noncombustible absorbent Material Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; \ if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Use first aid treatment according to the nature of the injury

1,1,2-TRICHLOROETHANE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Ethane trichloride; ethane,1,1,2-trichloro beta-T; 1,1,2-TCE; beta-trichloroethane; Vinyl trichloride : : TCM 2 2 : CH CICHCI : Colorless liquid; sweet, chloroform : 114C/ 237 F : -38C/ -36F : 1.43 @ 25C : Chlorinated hydrocarbon

Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: 18.8 :B :B :+ :O :+ : 0.45% @ 20 C : 4.55 Portable lines to droplines or manifolds should be Flushed out immediately after use. : Possible : Purge : NO Blanket : Possible Stainless steel, also Epoxy, Zinc and Polyurethane with restrictions. Consult lists.

Fire & Explosion Hazard Data

Grade: None assigned Electrical Group :D General: Very degree of flammability. Normally will not burn, but will in fire of other fuel or with strong inhibitor(large spark, welding torch), will give off toxic and irritant gases, including hydrogen chloride, chorine, and/or phosgene. Flash Point (F) : None measurable due to low degree of combustibility Flammable Limits : 6~ 15.5% Auto igniting Temp.(F) : Unavailable Extinguishing Agents : Dry chemical, foam, CO2. Special fire Procedures : Cool exposed tanks with water, provide respiratory protection for fire parties.

Health Hazard Data

Health hazard Rating : Unavailable Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 10/skin TLV/TWA(ppm) : 10/skin General : Suspected carcinogen. very toxic, much more so than 1,1,1-trichloroethane. Central nervous system suppressant. Toxic to liver and kidneys. realigned or repeated skin contact may cause defeating of the skin and may produce dermatitis form daily contact. Symptoms: Eyes- irritation, discomfort, soreness. Skin- irritation. Inhalation- irritation, drowsiness, unconsciousness. Ingestion- Headache, lassitude, coma. Short Exposure Tolerance: Short term exposure near 2000 ppm cause central nervous system depression distorts equilibrium. Exposure Procedure : Eye- flush with water for at least 15 minutes, call physician. Skin- wash soap and water for at least 15 minutes. Inhalation- remove to fresh air, give oxygen or artificial respiration as needed. Ingestion- call physician.

Reactivity Data
Stability: Generally stable, decomposes when heated. Reacts with strong oxidizers, strong caustics, and active metals to cause fires and explosions. Compatibility: Material : Attacks some plastics, rubbers, coatings, reacts with aluminum.

Cargo : Group 36 of the compatibility chart.

Spill or Leak Procedure

Wear protective clothing, self contained breathing apparatus, and full face shield. Stop release dike spill, collect with inert absorbent, dispose in sanitary landfill. Handling - Use protective clothing /mask when working the cargo. No problems ever report. Operational Problems/ Hazards Susceptible to static, lines should be blown with Nitrogen Moderate narcotic and systemic effect of liquid and vapor - avoid contact. Tanks must be washed before being used for ballast Cargo becomes acidic when mixed with water - may contain inhibitor to minimize this product. Personnel Protection Full chemical protection and breathing apparatus during all operations and tank cleaning Secure accommodation and recirculate air Restrict personnel on deck Tank cleaning Cold S.W pre-wash to remove residues ( 2Hour) Hot wash with chemical injection 5 ft. half hour drop Fresh water rinse or steam Ventilate to gas and odor free, Educt and mop Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (E)Warm water followed by hot water. For vegetable oil cargoes, warm water if defined as the maximum discharge temperature. Reference note 16. Whenever a chlorinated solvent is the last cargo or used in the cleaning process and the tank will not be adversely affected, the tank pump and line systems must be hot water washed for a minimum of two hours after taking necessary precautions (alcohol flushing , ventilation etc.) to protect the coating.

TRICHLOROETHYLENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Chlorylen; Ethene; Trichloro-; Ethyl Trichloride; Ethylene trichloride; Tri; Trichloroethene. : 1710 : TCL : CIHC= CCI2 : Colorless liquid;chloroform odor : 87C/ 189F : -87C/ -124F : 1.47 : Halogenated compound : 57.8 :B :B : 2.5 :O : 3.5 : Negligible

Vapor Density(air= 1.0) : 4.54 Handling : Clean portable lines to droplines or manifolds Inhibitor : Nitrogen : Purge : NO Blanket : Possible Tank coating : Stainless steel, Zinc Silicate, Polyurethane with restrictions, Epoxy is Not suitable for this product. Draeger tube No. : CH244 Trichloroethylene 10/a

Fire & Explosion Hazard Data

Grade: None assigned Electrical Group :D General: Although trichloroethylene does not ignite readily, it can flash under certain conditions. a high energy ignition source is one of the necessary factors. The liquid or vapor on contract with hot metal or a flame can decomposes to form phosgene, which is highly toxic. Flash Point (F) : Practically non- flammable Flammable Limits : Variable at high temp. Auto igniting Temp.(F) : 770 Extinguishing Agents : Dry chemical, carbon dioxide, or foam. Special fire Procedures: Tanks should be cooled by a water spray to prevent vaporization. Wear eye protection, self contained breathing apparatus and productive clothing.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) : : : : 1,1,2 50 50 50

General : Suspected carcinogen. Vapor inhalation leads to slight irritation of airway with moderate systemic effect. Prolonged or repeated skin contact may cause defeating of the skin may produce dermatitis from daily contact. Symptoms: Headache, nausea, eye and throat irritation, drowsiness. short Exposure Tolerance: 150 ppm for 30 minutes. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: In the presence of a strong alkali it reacts to form a gas will ignite or explode spontaneously. Compatibility: Material : stabilized trichloroethylene may be used in the presence of air, water and light with any of the common construction metals at temp. up 248 F.

Spill or Leak Procedure

Wear rubber gloves, protective clothing, self contained breathing apparatus. Avoid contact with liquids Operational Problems/Hazards Although classed as non-flash, certain mixtures of vapor and air can ignite if in the presence of powerful sources of ignition, however flame travels slowly Base solvent , will require very clean tank and lines Cargo becomes acidic in contact with water, therefore tanks must be dry. Suspected carcinogen, although opinion divided

Moderate narcotic and systemic effect of vapor and liquid - Avoid contact May require inert blanket and vent line desiccator check locally. Personnel Protection Boiler suit, goggles, gloves Tank cleaning Hot sea water wash with chemical injection 5ft half hour drops. Fresh water rinse or steam Ventilate to gas and odor free Educt and mop dry Note : Amines absorb water rapidly , therefore ensure all tank lids, etc. open to prevent formation of vacuum. SUS- It is unnecessary to inquire about C/W. Product is OK for SUS. Handling - Be careful when stripping, if piston pumps in unsuction is easily lost and pumps becomes Gasbound /vapor no other problems.

HEALTH HAZARDS Vapors may cause dizziness or suffocation Exposure in on enclosed area may be very harmful. Contact may irritate burn skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials but none of them ignites readily. Most vapors heavier than air Air/vapor mixtures may explode when ignited. Container may explode in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co . Large Fires: Water spray ,fog or regular foam apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Small Liquid spills: Take up with sand, earth or other noncombustible absorbent Material

Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; \ if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Use first aid treatment according to the nature of the injury

TRIDECANOL
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating Alcohol C-13;Isotridecanol;isotridecyl alcohol; Oxotridecyl alcohol;1-tridecanol; Tridecyl alcohol : : TDN 12 25 2 : C H CH OH : Water-white liquid with pleasant : 274C/ 525F : 31C/ 87 F : 0.85 : Alcohol : Low : : III :" :D :" : Negligible : 6.9 : Portable lines to droplines or manifolds : NO : Purge : No Blanket : NO : Most coatings suitable

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) : : : : Combustible liquid D Slight fire hazard when exposed to heat or flame. 250

Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

: Unavailable : " : Alcohol foam, water spray, dry chemical, CO2. : Water or foam may cause frothing.

Health Hazard Data

Health hazard Rating : 0,0,0 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Possibility of some adverse effects from liquid contact with skin. Symptoms: Inhalation hazard is slight. Skin contact causes minor irritation. Eye contact causes severe irritation. Short Exposure Tolerance : Unavailable Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently wash affected area with water.

Reactivity Data
Stability: Stable. Compatibility: Material : aluminum unsuitable. Cargo : Group 20 of compatibility chart.

Spill or Leak Procedure

Avoid contact with liquid. Secure ignition sources. Operational Problems/ Hazards No significant hazards, although avoid contact with liquid Possibility of static generation, lines should be blown with Nitrogen. Personnel Protection Boiler suit, gloves Classed as non-hazardous to environment. Tank cleaning Cold sea water wash to remove residues ( 1 hour ) Hot sea water with chemical injection 5 ft. half hour drops Fresh water rinse or steam Educt and mop dry Melt/Heat - Product shipped of Rotterdam has no melting point- needing no heat. Handling - Easy cargo - no problems. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 8.

Cargoes belonging to the olefin, phthalate, adiptate, fatty acid and fatty alcohol categories are difficult to clean. When the subsequent cargo requires a high degree of cleanliness (wall wash), alternative stowage should be carefully evaluated.

TRIETHANOLAMINE
Synonyms 2,2,2"-Nitrilotriethanol; TEA; Triethyloamine; Tri(hydroxyethyl)amine; Tri(2-hydoxethyl)amine; Trihydroxytriethylamine; Tris(hydroxyethyl)amine; Trolamine : : TEA 2 4 3 : (HOC H ) N : Colorless, oily liquid; Slight ammonia-like-odor. : 19C/ 68F : 19C/ 68 F : 1.13 : Amine : Low : :D :" :O :" : Complete : 5.14 : Portable lines to droplines or ships lines to deck tanks : NO : Purge : NO Blanket : NO Stainless steel, Polyurethane, Epoxy,and Zinc Silicate can be used but have restrictions Check coating lists. Stainless steel preferred.

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

Fire & Explosion Hazard Data

Grade-E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) : Combustible liquid :C Slight hazard, when exposed to heat or flame. The oxidation products are poisonous. : 365 : Unavailable : "

Extinguishing Agents : CO2, dry chemical, alcohol foam, water fog. Special fire Procedures : Keep tanks cool with a spray of water. provide respiratory protection for fire parties.

Health Hazard Data

Health hazard Rating : 0,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid causes irritation and burns to skin and eyes on contact. Symptoms: Itching or burning of skin at site of contact. If inhaled, the respiratory passages will be irritated. Short Exposure Tolerance : Unavailable. Exposure Procedure : Wash spill form the skin with water. if liquid has splashed in the eyes, wash them with water for 15 minutes and get medical attention.

Reactivity Data
Stability: Beings to decompose at 450 F. Compatibility: Material : copper and its alloys are corroded.

Spill or Leak Procedure

Wear butyl rubber gloves, protective clothing. Avoid contact with liquid. cover spill with sodium bisulfate. Spray with excess water and wash up. Wash area with soap solution. remarks: Partly to lower the high freezing point, the commercial product is a mixture of triethanolamine with up to 25% diethanolamine and 5% ethanolamine. The resulting mixture will have properties that vary somewhat from those shown. Operational Problems/ Hazards May require heating to keep cargo above freezing point. Check with Charterers/ Surveyors Slight irritation of liquid on eyes and skin otherwise no significant problems. personnel protection Boiler suit, gloves, Breathing Apparatus for topping off and P/R works. Tank cleaning Cold sea water wash to remove residues (1.5 hour) Hot sea water wash with chemical injection 5 ft. half hour drops. Fresh water rinse or steam Ventilate to gas and odor free Educt and mop dry Heating - DOW : 90~100F for both grades UCC : 90/100F for pure, 70/80F for 85% Handling - This Amines is not difficult to handling . No problems ever reported. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes.

Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

TRIETHYLAMINE
Synonyms : N,N-Diethylethanamine; TEN. UN. No : 1296 CHris Code : TEN Formula : (C2H5)3N Appearance-Odor : Colorless liquid,ammoniacal odor Boiling Point : 89C/ 192 F Freezing Point : -115C/ -175 F Specific Gravity : 0.73 Chemical Family : Amine Vapor Pressure(20C) : 53.5 Pollution Category USEPA :D IMO :C Reid Vapor Pressure(psia) : 2.3 Applicable Bulk reg.46 Subchapter :O Vapor pressure 46C(psia) : 2.5 Solubility in water : Slight Vapor Density(air= 1.0) : 3.49 Handling : Portable lines to poison bank or deck tank manifolds. Bondstrand is NOT suitable. No information on compoflex. Inhibitor : Possible Nitrogen : Purge : Possible Blanket : Possible Tank coating : SUS , Zinc silicate, Epoxy with restriction, Because of reactivity , poison bank or deck tank stowage

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :C General: Dangerous, Keep away from heat or open flame. flashback along vapor trail may occur. Vapor may explode if ignited an enclosed area. Flash Point (F) : 25 Flammable Limits : 1.2~ 8.0% Auto igniting Temp.(F) : 842 Extinguishing Agents : Alcohol foam, Co2, dry chemical. Special fire Procedures : Use water to keep fire-exposed containers cool. if a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak. Water spray may be used to flush spills and to dilute, rendering non-flammable.

Health Hazard Data

Health hazard Rating : 2,2,2

Odor Threshold(ppm) : 10 PEL/TWA(ppm : Unavailable TLV/TWA(ppm) : 10 General : Liquid dangerously absorbed through skin, vapor inhalation harmful. it is one of the most severe eye irritants and permanent injury may follow eye contact despite prompt treatment efforts.

Symptoms: Liquid causes eye injury and skin irritation. short Exposure Tolerance: Less than 100 ppm for humans for 30 minutes. a 4 hour exposure was lethal to 1/8 of rats tests. Exposure Procedure : In case of contact with eyes or skin, immediately flush with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove contaminated clothing and shoes at once.

Reactivity Data
Stability: Stable. Compatibility: Material : Copper and its alloys are incompatible with triethlamine. Cargo : Group 7 of compatibility chart.

Spill or Leak Procedure

If possible, wear butyl rubber gloves, face shield or all purpose canister respirator, and full protective clothing. Secure ignition sources. Cover spill with bisulfate. Spray with water and wash up. Operational Problems/ Hazards Highly corrosive and toxic vapour and liquid Avoid all contact. P.V.C materials will degenerate Keep away from heated cargo. Personnel Protection Boiler suit, gloves Breathing apparatus Tank cleaning Cold sea water pre-wash to remove residues Hot sea water wash with chemical injection 5 ft. half hour drops Fresh water rinse or steam Educt and mop dry Zinc - coating is resistant, but product could pick up enough Zinc- putting it Off-spec. -go SUS. Handling - Be sure to dress properly when working this amine. It is toxic/ flammable plus a strict irritant. Carried with no problems. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS Poisonous if swallowed. May be Poisonous if inhaled. Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical, Co , water spray or regular foam. Large Fires: Water spray ,fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Do not touch or walk through spilled material; Stop leak if you can do it without risk Water spray may reduce vapor; but it may not prevent ignition in closed spaces Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

breathing is

TRIETHYLBENZENE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : : : : : : : : : : : : : : : : : : : : : 1,3,5-triethylbenzene; sym-triethylbenzene ++ TEB 6 3 2 3 3 C H (CH CH ) Clear, colorless liquid; weak aromatic odor. 216C/ 421 F -70C/ -94 F 0.86 Aromatic hydrocarbon Low A 0.03 D,O 0.05 Insoluble 5.6 Portable lines to droplines NO Purge : NO Blanket : NO Any coating suitable

Fire & Explosion Hazard Data

Grade- E Electrical Group General Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : : : : : : : : Combustible liquid. D Moderate fire hazard when exposed to heat or flame. 181 Unavailable " Foam, carbon dioxide or dry chemical Water may be ineffective on fire. cool exposed tanks with water.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms : 1,1,1 : Unavailable : Unavailable : " : Slight smarting of the eyes or respiratory system if present in high concentrations. short Exposure Tolerance : Unavailable. Exposure Procedure : Vapor- remove victim to fresh air. Skin or eye contact- remove contaminated clothing and gently affected areas with water.

Reactivity Data
Stability: Stable. Can reacts with oxidizing materials. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 32 of compatibility chart.

Spill or Leak Procedure

Avoid contact with liquid. secure ignition sources.

Operational Problems/ Hazards Inhalation causes nausea, dizziness, possibly loss of consciousness. Personnel Protection Boiler suit, goggles, gloves, B/A for topping off, p/room work. Tank cleaning Cold pre-wash to remove residues Hot sea water wash with chemical injection (Check LEL) Fresh water rinse or steam, Ventilate to gas and odor free Educt and mop dry Tank must be dry Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

TRIETHYLENE GLYCOL
Synonyms Di-beta-hydroxyethoxyethane; 2,2'-ethylene Dioxybis(ethanol); 2,2'-ethylene dioxydiethanol; Ethylene glycol dihydroxydiethyl ether;

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

Glycol bis(hydroxyethyl) ether; TEG; triglycol : : TEG 2 2 2 2 : (CH OCH CH OH) : Colorless liquid with a slight,sweet odor. : 278C/ 533F : -7C/ 19 F : 1.12 : Glycol ether : V.Low : : III :" :D :" : Complete : 5.17 : Clean and dry portable lines to droplines : NO : Purge : NO Blanket : NO : All coatings suitable

Fire & Explosion Hazard Data

Grade-E Electrical Group General : Combustible liquid :C Slight fire hazard when exposed to heat or flame. Moderate explosion hazard when vapor is exposed to flame, spark or heat sources. : 350(cc) : 0.9~ 9.2% : 700 : Carbon dioxide, dry chemical, or alcohol foam. : Water or foam may cause frothing.

Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General Symptoms short Exposure Tolerance : : : : : : : 0,0,0 Unavailable Unavailable " Considered non- toxic under normal handling condition. Liquid is a irritant. Vapor is a lung and upper respiratory tract irritant. Unavailable

Exposure Procedure : Skin- flush eyes and skin with water. Vapor- remove victim to fresh air. and administer artificial respiration. Call a doctor.

Reactivity Data
Stability: Stable. Can react with oxidizing material are suitable. Compatibility: Material : Usual materials of construction are suitable. Cargo : Group 40 of compatibility chart.

Spill or Leak Procedure

Avoid contact with liquid. Secure ignition sources.

Operational problems/ Hazards Practically non -hazardous However, being odorless and colorless, tanks and lines will have to be scrupulously clean Non- contamination essential Surveyors liable to be extremely critical when undertaking tank inspection To avoid contamination coils should be blanket off. This product not as difficult as fiber grade but would need cleaning close to methanol standard. Personnel Protection Boiler suit and goggles, gloves Tank cleaning Hot salt water wash, Ventilate to gas and odor free Fresh water rinse, Educt and mop dry Coating s: Both Zinc and Phenoline are resistant. UCC & MSK demanded SUS. Handling - Tank must be prepared for loading same as for Methanol. There are no Short cuts for loading/ voyage and discharge for this very fine product. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 4. The application of hot water to these product will cause the product to degrade and may cause gels to form on the tanks surfaces, line system pump, etc. these gels once formed can be removed by use of a cleaning solvent. Once they have formed, they may alter the non-volatile specification of the subsequence cargo.

TRIETHYLENE TETRAMINE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) : : : : : : : : : : N,N'-bis(2-aminoethyl)ethylenediamine; TETA; Trien 2259 TET 2 2 4 3 H N(c H NH) H Moderately viscous,amber liquid ammonia-like -odor. 278C/ 532 F -35C/ -31 F 0.98 Amine Low

Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: :D :" :O :" : Complete : 5.04 Portable line to deck tank manifolds. Line should be flushed clean after use. : NO : Purge : Possible Blanket : Probably : Stainless Steel

Fire & Explosion Hazard Data

Grade-E Electrical Group General : Combustible liquid. :C Slight fire hazard when exposed to heat or flame. No spontaneous heating. : 290 : Unavailable : 642 : Alcohol foam,carbon dioxide or dry chemical.

Flash Point (F) Flammable Limits Auto igniting Temp.(F) Extinguishing Agents Special fire Procedures : Water or foam may cause frothing. fire fighters to wear self contained breathing apparatus, goggles and protective clothing.

Health Hazard Data

Health hazard Rating : 2,2,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Liquid causes severe burns to skin and eyes with only slight contact. Vapor causes primary irritation and dermatitis. Symptoms: Vapor - skin irritation, dermatitis, nausea,faintness, anxiety. Liquid- severe skin burns. Short Exposure Tolerance: Unavailable Exposure Procedure : Vapor- remove victim o fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- Remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Stable. Can react with oxidizing materials. Compatibility: Aluminum or stainless steel are suitable. Cargo : Group 7 of compatibility chart. See also Appendix 1- Exceptions to the chart.

Spill or Leak Procedure

Wear butyl rubber gloves, face shield or all purpose canister respirator, protective clothing. Avoid contact with liquid. Cover spill with sodium bisulfate. Wash up with water. Wash site with soap solution.

Operational Problems/ Hazards Odor threshold should not be relied upon for warning properties. Highly corrosive liquid, avoid all contact, although vapor hazard negligible, individual burnt by liquid can become sensitized to vapor. May require vent line dessicator . Check locally. Check compatibility of cargoes before slopping to common tank. Personnel Protection Extremely toxic in all forms, Total protection suits required during all cargo operation and tank cleaning. Accommodation to be battened down. Air conditioning on Recirculation. ONLY people required for cargo operations to be on deck. Lift gangway to ensure no unauthorized persons can come on board In event of any contamination personnel should have professional medical attention immediately . ( odor threshold is higher than TLV). Tank cleaning After discharge backload from shore up same line immediately cleaning medium ( between 5 to 10 MT ) This may be either Acetone, Gas oil or Toluene. Some port Authorities do not allow this . Check local regulations at discharge port- In the event of this, cleaning medium will have to be pumped from one of the ships tank. After backload, Recirculation wash with Butterworth machines for at least 2 hours (Tank hatches to be well padded to stop splash back and spray). Then discharge slops either ashore or overside. Hot sea water wash for at least 3 hours. Severe ventilation required ( 12 hours plus) Fresh water rinse, Educt and mop dry. Tank must be exceptionally clean and dry. Be prepared for a good deal of tank preparation. Carriage temp. limits are extremely critical. Should be checked at a max. of four hourly intervals. Above 32 C subject to spontaneous heating, below 18/20 C isomers start to split out, both of which can cause tank to rupture. Extremely water-reactive- on no account must cargo come into contact . After discharge pump and valves should be inspected for TDI solidification. Cleaning code 1. Cargoes listed under this group are completely water soluble or miscible. Some are water reactive; however such reaction will be of an acceptable extent and duration. All of the cargoes can be cleaned using only water and all can be considered as good last cargoes. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. HEALTH HAZARDS Contact cause burns to skin and eyes If inhaled, may be harmful. Effect may be delayed; keep victim under observation. Runoff from fire control or dilution water may cause pollution FIRE OR EXPLOSION Some of these materials may burn, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.) EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Some of these materials may react violently with water. 2 Small Fires: Dry chemical or Co Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk.

Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. SPILL OR LEAK Do not touch or walk through spilled material; Stop leak if you can do it without risk Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry Container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site Keep victim quiet and maintain normal body temperature

TRICRESTYL PHOSPHATE
Synonyms o-Crestyl phosphate; phosphoric acid; Tris(methylphenyl)ester; TCP;TOCP; Tolyphosphate; Tri-crestyl phosphate; Tri-toly phosphate; triolyl phosphate : 2574 >3% ortho : TCP/TCO 3 6 4 3 4 : (CH C H ) PO : Colorless liquid; slight odor. : 410C/ 770 F : -32C/ -25 F : 1.17 : : V.Low : :A :+ :O : V.Low : Negligible : 12.7 : Load via portable line to droplines : NO

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor

Nitrogen Tank cleaning

: Purge : NO Blanket : NO : Stainless steel, Epoxy, Polyurethane,Zinc Silicate with restrictions

Fire & Explosion Hazard Data

Grade- E : Combustible liquid Electrical Group :D General: Slight hazard when exposed to heat or flame. will decompose at extremely high temp. releasing toxic POx gases. Flash Point (F) : 437 Flammable Limits : Unavailable Auto igniting Temp.(F) : 725 Extinguishing Agents : CO2, dry chemical Special fire Procedures : Water may be ineffective on fire. cool exposed tanks with water. Wear protective clothing, goggles or face shield and self contained breathing apparatus.

Health Hazard Data

Health hazard Rating : 1,0,4 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : 0.01/skin General : Vapor slight hazard due to low vapor pressure. Liquid extremely toxic when ingested. Symptoms: Vapors may irritate eyes at high temp. Ingestion causes severe damage to central nervous system. short Exposure Tolerance: Unavailable. Exposure Procedure : Ingestion- induce vomiting and call a physician. Skin or eye contact- for eyes flush with water for 15 minutes; for skin, wash with soap and water.

Reactivity Data
Stability: Stable. Can react with oxidizing materials when heated to decomposition. Compatibility: Material ;Usual materials of construction are suitable. Cargo : Group 34 of compatibility chart.

Spill or Leak Procedure

Wear protective clothing. goggles or face shield. Remove ignition sources. Operational Problems/ Hazards This product exists in three forms, Ortho, Meta, and Para,of which the Ortho Isomer is highly toxic to the central nervous system. The Meta Isomer is not so toxic as the Ortho and the Para Isomer is non-toxic. Check with shipper as to composition and take relevant safety precautions to avoid contact. Otherwise no other significant problems Possible susceptibility to static , therefore lines should be bonded , and blown with Nitrogen. Personnel Protection Boiler suit, goggles, gloves, Breathing apparatus for topping off and P/R works. Tank cleaning Gas free or inert, Hot sea water wash , 5 ft half hour drops

Fresh water rinse or steam, Ventilate to gas and odor free Educt and mop dry Tank and line must be thoroughly clean and dry. USCG: If product contains more than 1% ortho Isomer or less a non-compliance cargo. carried with no problems.

HEALTH HAZARDS Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Runoff from fire control or dilution water may give off poisonous gases and Cause water pollution. Fire may produce irritating or poisonous gases FIRE OR EXPLOSION Some of these materials but none of them ignites readily Container may explode violently in heat of fire. EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, keep out of low areas, and ventilate closed spaces before entering positive pressure self-contained breathing apparatus (SCBA) and chemical protective clothing which is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection structural Firefighters protective clothing is not effective for these materials Remove and isolate contaminated clothing at the site. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, Especially if there is no local hazardous materials team available. FIRE Small Fires:. Dry chemical, water spray or regular foam. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Stay away from ends of tanks. Dike fire- control water for later disposal; do not scatter the material. SPILL OR LEAK Do not touch or walk through spilled material; stop leak if you can do it without risk. Fully-encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to reduce vapor Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small Dry spills; With clean shovel place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Speed in removing material from skin is of extreme importance. Remove and isolate contaminated clothing and shoes at the site keep victim quiet and maintain normal body temperature effect may be delayed; keep victim under observation.

TRIXYLYL PHOSPHATE
Synonyms : TBA IMO No : IMO TYPE :3 Formula : (CH3)2 C6 HO 3 PO ICS Guide Page No. : 34 Family : Ester ( Aromatic ) Appearance and character : Clear colorless liquid with Little or no odor. Specific Gravity : 1.133 @ 20 C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00080 Carriage : Ambient Disch . : Average Expected Load Temp. : USCG Compatibility chart Group No : 34 Reactivity: Can react dangerously with hydrogen peroxide. Otherwise basically stable. Handling : Load via portable lines and drop lines for quality control. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Any coatings suitable . Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV Flash point : 235 C Draeger Tube No. : Boiling Point : 270 C Explosive Range : % to % Freeze Point : -33 C Autoignition Point : C Operational Problems/Hazardous No specific health hazards, however any contamination should be washed off immediately. Possibly susceptible to static, lines must be blown with nitrogen.

Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Cleaning from: Warm sea water wash, 5 ft. half hours drops. with chemical injection Fresh water rinse or steam. Ventilate Educt and mop Tanks must be dry Information on this product is not specific, and local information should be obtained. V. Slight

TUNG OIL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : TBA 3 19 Essential Oil Thick, viscous amber liquid with characteristic odor. 0.932 @ 29 C 0.00063 Ambient Reputed to be poisonous. Therefore Avoid contact. Ship or shore lines loaded preferably through droplines. NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Epoxy, Polyurethane, Stainless steel.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV Flash point : 289 C Draeger Tube No. : Boiling Point : Explosive Range : % to % Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Contains x-eloestrearic acid which can be isomerized by sunlight , sulphur or iodine into B form, where upon the oil is transformed into a solid mass A very fast-drying oil, tank must be cold washed immediately after discharge Shipper may require heating, depending on grade check locally. Stow away from heated cargo. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work.

Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : YES Soluble in water : NO

Cleaning from: Gas free or inert Cold sea water pre-wash (1.5 hour.) Hot wash with chemical injection 5 ft. half hour drops Fresh water rinse or steam Ventilate to gas and odor free Educt and mop dry Zinc- the FFA is usual below 2.5%- but check Handling - Water will ruin cargo. Be sure to have dry lines and pumps in addition to clean/ dry tank. Excellent cargo. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water.

TURPENTINE
Synonyms D.D turpentine;Gum spirits; Gum turpentine Spirits of turpentine; Oil turpentine; Steam distilled turpetine; sulfate turpentine; sulfate wood turpentine; turps; wood turpentine : 1299 : TPT 10 16 : Mostly C H : Colorless liquid; smells like oilbase paint. : 150~160c/302~320 F : : 0.85~0.87 : Olefin : * : :B : 0.26 : D,O : 0.40 : Negligible : 4.84

UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling : As this is a base solvent, lines will have to be scrupulously clean load preferably through dropline for quality control. Inhibitor : NO Nitrogen : Purge : NO Blanket : NO Tank coating : Polyurethane, Epoxy, Stainless steel, Zinc silicate

Fire & Explosion Hazard Data

Grade-D : Combustible liquid Electrical Group :D General: Give off acrid fumes when heated. moderate fire hazard. forms heavy black smoke and soot. Flashback along vapor trail may occur. Vapor may explode in an enclosed area. Flash Point (F) : 95 Flammable Limits : LEL=0.8% UEL-Unavailable. Auto igniting Temp.(F) : 488 Extinguishing Agents : CO2, dry chemical, water fog, foam. Special fire Procedures : a tank exposed to fire should be kept cool with a spray of water.

Health Hazard Data

Health hazard Rating : 1,1,1 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : 100 TLV/TWA(ppm) : 100 General : Vapor inhalation harmful. liquid irritating on contact. Symptoms: Pickling sensation of eyes, dizziness, acceleration of pulse, respiratory irritation and nausea. short Exposure Tolerance:

750 ~ 1000 ppm for several hours caused eye irritation, headache, dizziness, nausea and acceleration of pulse; 1878 ppm for one to four hours is toxic to man. Exposure Procedure : Remove victim to fresh air; if breathing stops, apply artificial respiration. skin or eye contact- remove contaminated clothing and gently flush affected area with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Under certain conditions(large surface area exposed to air) turpentine can undergo spontaneous heating. Compatibility: Material: Almost any metal is suitable. Ordinary rubber is attacked and should not be used for gaskets or fittings. Cargo : Group 30 of compatibility chart.

Spill or Leak Procedure

Wear polyethylene gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources Operational problems/ Hazards Vapor inhalation harmful liquid irritating on contact Moderate fire hazard Stow away from heated cargo. Personnel Protection Gloves, Goggles, Protective suit, B.A on standby Tank cleaning Cold sea water wash to remove stripping and residues ( 2hrs). Hot S.W wash with chemical injections ( wash in lean condition .5 hour 5 ft drops ) Steam Ventilate till tank odor free Educt and mop dry Heat Adjacent - If heat adjacent can be avoided when carrying Gum grade, a smell cleaning problem is being eliminated. If unavoidable - clean same as after drying oils. All grades are good cargoes. Cleaning code 5. Cargoes listed this group are not water soluble and require the use of a degrease and/or saponifier to alter the composition of the residue so that it can be removed. Frequently the use of a solvent is needed after degreaser and/or saponifier (Stolt C, caustic or LAC) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (D)Ambient water followed by warm water. Reference note 18. These cargoes leave an odor that in very difficult to remove especially in zinc coated tanks.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames.

Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

breathing is

UNDECANE
Synonyms IMO No IMO TYPE : n-UNDECANE, HENDECANE : 2330 : TBA

Formula : CH (CH ) CH ICS Guide Page No. : Family : Hydrocarbon Appearance and character : Colorless liquid with sharp odor. Specific Gravity : 0.7439 @ C Heating Range (Subject to Chart.Reg.) Correction factor : 0.00073 Carriage : Ambient Disch . : Average Expected Load Temp. : USCG Compatibility chart Group No : 30 Reactivity: Reacts with oxidizing agents and will give off toxic fumes if subject to excessive heat. Handling : Portable lines to droplines, or ships lines to center /deck tanks. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : Possible Tank Coating recommended : Any coatings , subject to coating guides. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV Flash point : 65 C Draeger Tube No. : Boiling Point : 195 C Explosive Range : % to % Freeze Point : C Autoignition Point : -26 C Operational Problems/Hazardous Product is flammable, and is a central nervous system depressant. Vapor has narcotic effect, and causes irritation. Liquid may cause defatting or dermatitis and is harmful if ingested. May require vent line desiccator / Nitrogen blanket. Personnel Protection; Chemical protective clothing , gloves and goggles Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : YES Soluble in water :

2 9

NO

Cleaning from: Ventilate to gas free, or inert, (Or cold sea water pre-wash to disperse all residues then ventilate ) Hot wash with chemical injection 5 ft. half hour drops if required. steam tank . line and pump, Educt and mop Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes.

Wash water temperature Code (D)Ambient water followed by warm water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes.

Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

UREA/ AMMONIA SOLUTION

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage : : : : : : : : TBA 3 Variable aqueous solution Ammonia Colorless liquid with an ammonia -like odor. 1.039 @ 25 C

: 0.0006296 : 15~ 25 C

Disch . : Average Expected Load Temp. : 15~ 25 C USCG Compatibility chart Group No :6 Reactivity: Reacts dangerously with some oxidizing agents, some acids, halogens, mercury, alcohols, glycols, esters, aldehydes, Ketonnes and phenols. Handling : Portable lines to droplines. Inhibitor : NO (Ensure Certificate obtained and Duration Checked) Nitrogen (Subject to charterers Reg. ) : Purge NO Blanket : NO Tank Coating recommended : Polyurethane, or Epoxy with restrictions. Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : 20~50 ppm TLV 50 ppm Flash point : 50 C Draeger Tube No. : CH318 Hydrazine Boiling Point : 35 C Explosive Range : 16 % to 26 % Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Heating instructions must be followed closely and in tropical conditions cooling may be required. To maintain control stow away from adjacent heat. No freeze point available but Salting out occurs at 19 C. Check compatibility of cargo stowage with local surveyors. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : D Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : YES Soluble in water : Complete Cleaning from: Before starting tank cleaning the tank/s, MUST be vented for at least 24 hours to remove all traces of ammonia vapor. Test with Daeger tube to check ammonia presence ( CH205 Ammonia 5/a) Hot wash with chemical injection 5 ft. half hour drops Fresh water rinse or steam, Educt and mop dry Tank must be complete dry Tank must not be Dirty ballasted (i.e. tank must be cleaned before used as a ballast tank ). Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

UREA-AMMONIUM NITRATE SOLUTION(more than 2% free ammonia)

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor : : : : : : : : : : : : : : : : : : : Solar nitrogen solution; UAN-Nitrogen solution; UAN solution. UAS 2 2 4 3 3 2 NH CONH NH NO NH H O mixture Colorless liquid slight ammonia odor 100C/ 212 F 1.3 * C Varies O Varies Soluble " Portable lines to droplines NO

Nitrogen Tank coating

: Purge : NO Blanket : NO : Polyurethane or Epoxy subject to coating guides

Fire & Explosion Hazard Data

Grade: None assigned Electrical Group :D General: No direct fire hazard until water evaporates. Thermal decomposition yields toxic ammonia carbon monoxide, and nitrogen oxide gases. Flash Point (F) : Pure ammonia nitrate-urea solution is not flammable. Flammable Limits : for ammonia 16 ~ 25% Auto igniting Temp.(F) : for ammonia 1205 Extinguishing Agents : Water Special fire Procedures : Do not use Co2, dry chemical, foam extinguishers. dry ammonia in contact with combustibles increases potential for fire. if confined an explosion will result. Use self contained breathing apparatus and stay upwind.

Health Hazard Data

Health hazard Rating : 0,1,1 3 4 Odor Threshold(ppm) : ~45 for NH NH OH PEL/TWA(ppm) : TLV/TWA(ppm) : ** General : Urea itself is non-toxic. solution will produce irritation due to ammonia being present. Symptoms: Prolonged contact will produce mild irritation, bisters or rash, Eyes will become painful. Ingestion results in nausea, vomiting, intestinal bleeding, coma, convulsions, and or death. short Exposure Tolerance: 100 ppm for 30 minutes(ammonia gas). Lethal dose of ammonium nitrate is 10~15 grams. Exposure Procedure : Wash skin or eyes with water. for ingestion seek medical assistance promptly, induce vomiting after two glasses of water only if conscious. monitor breathing. remove to fresh air.

Reactivity Data
Stability: Stable. reacts with oxidizing material, combustible material, wood chips, organic materials sulfur, metal, finely subdivided lead, zinc, galvanized iron, or acids. Compatibility: Material : Cargo : Group 6 of compatibility chart.

Spill or Leak Procedure

Certain material to prevent contamination of land or water. Allow water to evaporate, scoop up remaining residue. flush area with water to remove remaining traces. avoid mixing or contact with organic or combustible materials. Spontaneously combustible may occur. remarks: The more than 2% free ammonia normally required shipment under pressure(0~30 psia @104F) #vapor pressure: 15 mmHg @ 77F. ** NO2-5ppm,Co-50 ppm NH3-25 ppm NHOH4- 1 ppm. Operational Problems/ Hazards Data varies with concentration, Stow away from adjacent heat Liquid and vapor cause irritation, particularly to throat and eyes.

Personnel Protection Chemical protection clothing, gloves and goggles, Breathing apparatus Secure accommodation and recirculate air during all operations. Tank cleaning Cold sea water wash, 5 ft. half hour drops Ensure all residues dispersed from tank, lines and pumps Ventilate to gas and odor free ( steaming may be required to disperse odor) Fresh water rinse Educt and mop Dareger tube Hyaszine 0.25/a, or Ch205 Ammonia, will give indications of vapor. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (B)Warm water (38 to 55 degree C )

UREA/ FORMALDEHYDE SOLUTION

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : TBA 3 Complex Formaldehyde Resin A clear colorless liquid with characteristic pungent odor. 1.324 @ 25 C

: : 20~ 30 C : : 20~ 30 C : 19 Reacts with oxidizing agents, strong acids and alkalis particularly caustic soda. : Portable lines to droplines, flush out after use. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless steel, Polyurethane, or Epoxy. Zinc silicate is not suitable

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 3 ppm Flash point : 70 C Draeger Tube No. : Boiling Point : 97 C Explosive Range : 7 % to 73 %

Freeze Point Autoignition Point

: :

C C

Operational Problems/Hazardous Moderate irritating vapor and liquid avoid contact. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Complete Cleaning from: Cold warm SW wash (.5 hour 5 ft. drops ) Fresh water rinse or Steam Ventilate to gas and odor free. Educt and mop dry USCG- Max. Formaldehyde 50% IMO - Max. Formaldehyde 45% Allow for transport. Heat - UF- no heat. Barcelona - Min. 64 max. 85 F Comment - Check formaldehyde content before booking. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

n-VALERALDEHYDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating : : : : : : : : : : : : : : : : : : : : : Amyl Aldehyde; pentanal; Valeral; Valeric Aldehyde. 2058 VAL 3 2 3 CH (CH ) CHO Colorless liquid with a fruity odor 103C/ 217 F -91C/ -132 F 0.81 Aldehyde 26 D 1.2 O 1.8 Slight 2.96 Normally ships lines to deck/center tanks NO Purge : Possible Blanket : Possible Stainless steel

Fire & Explosion Hazard Data

Grade-C : Flammable liquid Electrical Group :C General : Flashback along trail may occur. Vapor may explode in a closed area. Flash Point (F) : 54 Flammable Limits : Unavailable Auto igniting Temp.(F) : " Extinguishing Agents : Carbon dioxide, Dry chemicals, foam, water spray. Special fire Procedures : Wear self contained breathing apparatus and protective clothing as protection against acrid fumes. Water may be ineffective on fire.

Health Hazard Data

Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable. PEL/TWA(ppm) : 50 TLV/TWA(ppm) : 50 General : Vapor is flammable and very irritating. liquid cause severe burns. Symptoms: Vapor- severe irritation of air passages with headache and rapid heart beat, eye irritation. Liquid causes severe skin and eye irritation on contact. Short Exposure Tolerance: Unavailable. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- immediately flood affected area with water for at least 15 min. Remove contained clothing.

Reactivity Data
Stability: Stable. Compatibility: Material : Stainless steel or aluminum are recommended. Cargo : Group 19 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus, protective clothing. avoid contact with liquid. Secure ignition sources. Cover spill with sodium bisulfate(NaHSO3). Add small amount of water and mix. Scoop up. Wash site with soap solution. Operational Problems/ Hazards Stow away from adjacent heat Does not react dangerously with air , but forms explosive peroxides under air pressure. liquid and vapor cause severe irritation to eyes and skin Inhalation of vapor will cause stupefaction. Personnel Protection Chemical protective suits, gloves, goggles Breathing apparatus Tank cleaning Cold sea water bottom wash to remove residues Ventilate to gas free or inert Hot sea water wash, 5 ft half-hour drops Steam tank, line and pump Educt and mop dry USCG/SUS - Product must be carried under nitrogen positive pressure. Water /Moisture must be kept out of cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Dry chemical or Co2 water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

VARSOLS
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : : : : : : : : : : : 3 Various Hydrocarbon Clear colorless liquid with a Turpentine -like odor. Approx. 0.75 @ 15 C

Ambient Ambient Reacts with acids and oxides Check other cargo. Portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO Stainless steel, Polyurethane, or Epoxy.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV100 ppm Flash point : 30-40 C Draeger Tube No. : 261 Hydrocarbons 0.1%/b Boiling Point : Over 150 C Explosive Range : % to % Freeze Point : Below 0 C Autoignition Point : C Operational Problems/Hazardous Product is flammable. liquid and vapor will cause irritation Surveyors may be critical of coatings breakdown. Personnel Protection; Chemical protective clothing, gloves, goggles Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Slight

Cleaning from: Gas free or inert tank Some coatings may require ventilation prior to washing Hot sea water wash, minimum 3 hours Ventilate to gas and odor free. Fresh water rinse Educt and mop dry Tank must be dry Registered U.S.A Trade mark of white spirit 100 See sheet 323A - White spirit These paint & varnish thinners are all good cargoes. with no problems ever reported. (They are also good tank cleaners) Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water.

VEOVA 10
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : : : : : : : V/ 10 TBA Non-hazardous 2r1 + r2 =7 223a Ester of Tertiary Carboxylic Acids Colorless mobile liquid with a pleasant odor. 0.876 @ 15 C

: 0.00080 : Ambient : : Ambient : Reacts with oxidizing agents, acids and alkalis organic peroxides and vinyl acetate : Portable lines to droplines. : YES ( Ensure Certificate obtained and Duration Checked) : Purge Possible Blanket : Possible Stainless steel, Polyurethane, or Epoxy. Zinc mild steel, NOT Zinc silicate as discoloration may occur.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 75 C Draeger Tube No. : Boiling Point : 133 C Explosive Range : Freeze Point : -20C Autoignition Point : 309 C Operational Problems/Hazardous Product is inhibited by hydroquinone methyl ether and this must be maintained above 5 ppm. High specification cargo. Do not store adjacent to heated cargo Liquid will irritate skin and eyes Max. storage temperature 50 C Personnel Protection; Boiler suit, goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Immiscible Cleaning from: Cold warm SW wash as soon as possible after discharge to remove al traces of cargo and prevent polymerization Ventilate to gas free, or inert

Hot sea water wash, 5 ft half hour drops, Fresh water rinse or odor free. Educt and mop dry There may be stringent requirements against allowing this product to come into contact with impurities such as rust or with traces of previous cargo- this being for quality control. Uses : A Modifying monomer with materials such as Vinyl Acetate.

VERSATIC 911
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. : : : : : 223b

Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: Mixture of saturated carboxylic acids : Pale amber liquid with a pleasant odor. : 0.924 @ 20 C : : Ambient : : Ambient : Reacts with alkalis to form soaps. No reaction with water or air other data not available. : Stainless steel lines preferred. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO : Stainless steel, preferred Polyurethane with restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : 138 C Draeger Tube No. : Boiling Point : 266-285 C Explosive Range : % to % Freeze Point : - 30 C Autoignition Point : C Operational Problems/Hazardous Dermatitis from prolonged contact. Personnel Protection; Boiler suit, goggles and gloves. B/A for topping off and P/R work. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Hot sea water wash Ventilate to gas and odor free Fresh water rinse or Steam Educt and mop dry

VINYL ACETATE MONOMER

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Acetic acid, ethenyl ester;acetic acid; Vinyl ester;VAM; Vinyl acetate monomer; vinyl A monomer;Vy Ac : 1301 : VAM : CH3COOCH =CH2 : Colorless liquid; sweet odor : 73C/ 163 F : -100c/ -148 F

Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating

: : : : : : : : : : : : : :

0.94 Vinyl acetate 90 D C 3.7 O 5.8 2% 2.97 Portable lines to droplines YES Purge : NO Blanket : Possible Any, with certain restrictions

Fire & Explosion Hazard Data

Grade-C : Flammable Liquid Electrical Group :D General: When heated, acrid vapors are given off. Ignited by heat, sparks or open flame. fire may cause violent rupture of tank due to polymerization. Flash Point (F) : 18 Flammable Limits : 2.6~13.4 % Auto igniting Temp.(F) : 801 Extinguishing Agents : CO2, dry chemical, alcohol foam, water spray. Special fire Procedures : if fire parties must work in confined quarters, provide respiratory protection. Keep tank cool with a water spray.

Health Hazard Data

Health hazard Rating Odor Threshold(ppm) PEL/TWA(ppm) TLV/TWA(ppm) General : 1,1,2 : 0.12 : 10 : 10 Liquid irritating to skin and eyes. vapor inhalation cause slight narcotic effect. : Dizziness, drowsiness. : Unavailable.

Symptoms short Exposure Tolerance Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial . Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: Polymerizes readily if not inhibited. heat can start the reaction. Emits acrid fumes when heated to decomposition. Can react vigorously with oxidizing materials. Compatibility: Material : Most of the usual materials of construction are suitable. Cargo : Group 13 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, face shield, protective clothing. Have all purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Flush area with water spray.

Operational problems/ Hazards The uninhibited product will polymerize on exposure to air, light or heat. The product is however normally inhibited with either hydroquinone or diphenylamine Contamination by other cargoes may also trigger polymerization even when inhibited. Stow away from adjacent heat. Liquid will irritate the eyes and de-fat the skin Vapor will also irritate the eyes and have a narcotic effect if inhaled. Personnel Protection Boiler suit, gloves, goggles and breathing apparatus Tank cleaning Ventilate to gas free or inert Cold sea water pre-wash Hot sea water wash, 5 ft half hour drops Steam out tank, line and pump Educt and mop Tank must be completely dry and clean USCG- Inhibitors name and amount must always accompany shipment . Handling - Tank /pump and line must be completely dry in addition to being 100% clean. Tank inspection prior to loading strict. Cleaning code 4 Cargoes listed under this group are not or are only partially water soluble. These products are either inhibited against self-reaction or are of the phenol or cresol families. These products present a cleaning in that they adversely affected the potassium permanganate time test. There are several ways to increase permanganate time; these include the use of an oxidizer (bleach), chlorinated solvent recirculation, and using Stolt X. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. Reference note 9. After initial water wash the tank, pump and line systems need to be recirculated with an oxidizer solution. The selection of a suitable oxidizer is dependent upon the tank lining. Most common oxidizers are sodium hydroxide and sodium hypochlorite (bleach) Reference note 15. Heat applied directly or indirectly on these products can cause polymerization, as such same must always be avoided. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection.

Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

VINYL ETHYL ETHER

Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor : : : : : : : : : : : : : : : : : : : Ethoxyethene; Ethyl vinyl ether; EVE; Vinama 1302 VCM 2 2 5 CH =CHOC H Colorless liquid disagreeable odor. 37C / 99 F -115c/ -175 F 0.763 Ether 426 C + O + Slight 2.49 Very clean stainless steel lines to deck tank manifold. YES

Nitrogen Tank coatings

: purge : YES Blanket : YES : Stainless steel. Deck tanks only.

Fire & Explosion Hazard Data

Grade- C : Flammable liquid Electrical Group :C General: Extremely flammable; may form explosive peroxides. flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Flash Point (F) : Less than -50 (cc) Flammable Limits : 1.7~ 28% Auto igniting Temp.(F) : 395 Extinguishing Agents : Alcohol foam, foam, CO2, dry chemical. Special fire Procedures : Wear goggles and self contained breathing apparatus. Water may be ineffective on fire. Cool exposed tanks with water.

Health Hazard Data

Health hazard Rating : 1,1,2 Odor Threshold(ppm) : Unavailable PEL/TWA(ppm) : Unavailable TLV/TWA(ppm) : " General : Vapor or liquid may be irritating to skin and eyes. concentrated vapors result in rapid anesthetic effect and loss of consciousness. Symptoms: Excitement followed by unconsciousness and respiratory paralysis. Prolonged skin contact causes dermatitis. short Exposure Tolerance: Data not available. Exposure Procedure : Remove from area and administer artificial respiration or oxygen if necessary. flush affected areas with large amounts of water.

Reactivity Data
Stability: Can react vigorously with oxidizing materials. Compatibility: Material : Cargo Group 13 of compatibility chart.

Spill or Leak Procedure

Wear goggles, self contained breathing apparatus, rubber gloves, Stay upwind, knock vapors down with water spray. Secure ignition sources as dangerous peroxides form upon heating. Operational Problems/ Hazards A highly reactive product which must be carried inhibited and under an inert blanket Must be stowed away from adjacent heat, and may require water spray on tanks in hot climates to reduce boil -off. Very high standard of tank and line cleanliness required. Personnel Protection Total protection suit Secure accommodation and recirculate air during all operations Tank cleaning

Cold sea water wash, minimum 2 hours , to disperse residues and inhibitors Ventilate to gas and odor free Hot sea water wash with chemical injection for minimum 2.5 hours Ventilate Fresh water rinse Educt and mop Tank must be dry and grease free Coating to be in good condition. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks.

For massive fire in cargo area, use unmanned hose holder or monitor area and let fire burn.

nozzles; if this is impossible, withdraw from

SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

VINYLIDENE CHLORIDE
Synonyms UN. No CHris Code Formula Appearance-Odor Boiling Point Freezing Point Specific Gravity Chemical Family Vapor Pressure(20C) Pollution Category USEPA IMO Reid Vapor Pressure(psia) Applicable Bulk reg.46 Subchapter Vapor pressure 46C(psia) Solubility in water Vapor Density(air= 1.0) Handling Inhibitor Nitrogen Tank coating 1,1-dichloroethene;1,1-dichloroethylene; asym-dichloroethylene; Ethene; 1,1-dichloro. : 1303 : VCI 2 2 2 : C H CI : Colorless liquid; sweet odor. : 32C/ 89 F : -123C/ -189 F : 1.21 : Vinyl halide : * :B :B : 18.3 :O : 24 : Negligible : 3.34 : Ships lines to center or deck tanks compoflex hoses also compatible. : YES : Purge : Probable Blanket : YES : Stainless steel, Zinc, epoxy

Fire & Explosion Hazard Data

Grade-A : Flammable liquid. Electrical Group :D General: Dangerous fire hazard; extremely flammable. combustion products include hydrogen chloride and poisonous phosgene. fire may result in violent rupture of tank due to polymerization.

Flash Point (F) :0 Flammable Limits : 5.6~ 16.0% Auto igniting Temp.(F) : 1058 Extinguishing Agents : Carbon dioxide, dry chemical, foam, water fog. Special fire Procedures : Keep tank cool with water spray. wear eye protection, self contained breathing apparatus and protective clothing.

Health Hazard Data

Health hazard Rating : 2,2,3 Odor Threshold(ppm) : 500~ 1000 PEL/TWA(ppm) :1 TLV/TWA(ppm) :5 General : Suspected carcinogen. Liquid irritating on contact. Vapor harmful and has narcotic effect. Symptoms: Dizziness, nausea, and sleepiness. liquid causes skin burns and eye irritating. Short Exposure Tolerance: Inhalation of 4000 ppm rapidly produces symptoms of drunkenness;unconsciousness may follow shortly afterward. Exposure Procedure : Vapor- remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye contact- remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get medical advice or attention.

Reactivity Data
Stability: will polymerize if exposed to heat and air. this commodity must be inhibited for shipment. Compatibility: Material : Copper and copper alloys are unsuitable. Cargo : Group 35 of compatibility chart.

Spill or Leak Procedure

Wear rubber gloves, self contained breathing apparatus, and protective clothing. avoid contact with liquid. secure ignition sources. Do not flush spill into confined spaces where flammable vapors can accumulate. remarks: vapor pressure : 400 mmHg @ 14.4 c. Operational Problems/ Hazards Product will polymerize readily unless inhibited-air, light and water will accelerate this process. Explosive organic peroxides may also be formed Inhibitor used will be p-methoxy phenol, thymol or phenol . If phenol is used extra care must be taken to avoid physical contact. Vapor will be uninhibited and may therefore polymerize and block P/V valves and flames screens Stow away from adjacent heat, Will require vent line desiccant Liquid and vapor cause irritation of skin and eyes Inhalation will have a narcotic effect leading to liver and Kidney damage. Personnel Protection Total protection suit Restrict personnel on deck. Secure accommodation and recirculate air Vapor return system : YES Tank cleaning Cold sea water pre-wash to remove all residues Ventilate to gas and free or inert Hot sea water wash, 5 ft half hour drops

Fresh water rinse Educt and mop

FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas Positive pressure self-contained breathing apparatus (SCBA) and structural Firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE 2 Small Fires: Dry chemical or Co water spray or alcohol-resistant foam. Large Fires: Water spray ,fog or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if

breathing is

difficult, give oxygen. In case of contact with material , immediately flush eyes with running water for at least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

VORANOL
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended : : :3 : Complex : : Polyols : A non-flammable thick viscous liquid. : 1.0188 @ 25 C : : : : : : : : : :

May required 28- 36 C 20 Basically stable,. Load via portable lines to tank drop lines, for quality control. NO (Ensure Certificate obtained and Duration Checked) Purge Possible Blanket : Possible Stainless steel, epoxy, Polyurethane , Zinc silicates.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : Flash point : 182- 238 C Draeger Tube No. : Boiling Point : 390 C Explosive Range : Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Fairly innocuous product, no specific danger; tanks however will have to be absolutely clean and dry Non-contamination of product essential. * More information required. Check locally with surveyors. Personnel Protection; Boiler suit, goggles and gloves. Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : Vapor Return System Reg. : NO

discharge on passage according to regulations. Drying oil : NO Soluble in water : Slight Cleaning from: Hot sea water wash with chemical injection ( 0.5 hour 5 ft drops) Fresh water rinse or thoroughly Steam Educt and mop dry Tanks must be dry USCG- Stow as either polyethylene or polypropylene Glycol- Much the same. Heat - Latest instruction of 100/120 F leading -carried and discharge. Handling - All grades are excellent cargoes with no major problems. Eye ; Flush with plenty of water for 5 minutes and obtain medical help if ill effects occurs. Skin; Wash with soap and water. remove badly contaminated clothing and wash before reuse. Inhalation/Ingestion; Not likely a problem. If large amounts are swallowed willfully, induce vomiting and obtain medical help. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible. These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (D)Ambient water followed by warm water.

WHITE SPIRIT
Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended Mineral Spirits, Subst. of Turpentine, Petroleum Thinners, Safety solvent. : 1300 :3 : Various : 196 : Hydrocarbons : Clear colorless liquid with sharp alcoholic odor. : Approx. 0.7 C : : Ambient : : C : : Reacts with oxidizing agents Check other cargo. : Via portable lines to droplines. : NO (Ensure Certificate obtained and Duration Checked) : Purge NO Blanket : NO Stainless steel, epoxy, Polyurethane , Zinc silicates subject to restrictions.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV 100ppm Flash point : 38 C Draeger Tube No. : Hydrocarbons/Toluene 25/a Boiling Point : 170-460 C Explosive Range : % to % Freeze Point : C Autoignition Point : C Operational Problems/Hazardous Product is flammable Liquid and vapor may cause irritation, and in severe cases dermatitis. Personnel Protection; Chemical protective clothing, goggles , gloves, Check protection Suit compatible with Product Pollution Guide IMO pollution Rating : B

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NIL Cleaning from:

Cold sea water pre-wash to remove residues ( or gas free or inert tank) Ventilate to gas/ odor free. Hot sea water wash, minimum 3 hours ( chemical injection may be required in Zinc after some grades ) Ventilate, Educt and mop, Tanks must be dry and grease free. Product varies as differing hydrocarbons - some may contain additives. See also Varsol. Cleaning code 3. Cargoes listed under this group are not water-soluble and require the use of a emulsifier and/or a detergent to reduce their surface tension. Frequently the use of a solvent is needed even after the emulsifier and/or detergent (i.e. Stolt B) cleaning has been completed. Cargoes under this group are not considered as good last cargoes. Wash water temperature Code (F)Ambient water for the first 30-45 minutes followed by hot water. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

XYLENE ( MIXED ISOMERS)

Synonyms IMO No IMO TYPE Formula ICS Guide Page No. Family Appearance and character Specific Gravity Heating Range (Subject to Chart.Reg.) Correction factor Carriage Disch . Average Expected Load Temp. USCG Compatibility chart Group No Reactivity Handling Inhibitor Nitrogen (Subject to charterers Reg. ) Tank Coating recommended

: : : : : : : : : : : : : : : : : :

Dimethylbenzene, Xylol 1307 3 (Chapter VII) C6 H4 (CH3)2 227 Aromatic Hydrocarbons Colorless liquid with a characteristic aromatic odor. 0.868 @ 15 C 0.00085 Ambient Ambient 32 Reacts dangerously with oxidizing agents and some acids. Portable lines to droplines. NO (Ensure Certificate obtained and Duration Checked) Purge NO Blanket : NO ANY.

Subject to coating compatibility Lists Consult USCG Compatibility Chart Odour threshold : ppm TLV ppm Flash point : 23- 50 C Draeger Tube No. : CH278 Toluene 25/a Boiling Point : 138-144 C Explosive Range : 1.1% to 6.6 % Freeze Point : 0-25C Autoignition Point : 498- 635 C Operational Problems/Hazardous Data will vary depending on grade No conclusive information regarding odor threshold, but olfactory fatigue occurs rapidly Liquid and vapor will cause nausea. Stow away from adjacent heat. Personnel Protection; Boiler suit, goggles and gloves. Breathing apparatus on standby Check protection Suit compatible with Product Pollution Guide IMO pollution Rating :

Vapor Return System Reg. : NO discharge on passage according to regulations. Drying oil : NO Soluble in water : NIL Cleaning from: Ventilate to gas free or inert, Hot sea water wash, 5 ft half hour drops Fresh water rinse , Educt and mop dry Flash point - Open Cup reading . 64/66 : Ventilate talk for at least 24 hours after discharge - to harden. Handling - Clean , tank, pump , and lines is all thats needed . Excellent cargo. Cleaning code 2. Cargoes listed under this group are not or are only water soluble or miscible.

These products can be removed by water displacing the product remaining within the cargo tank, pump, line system. The temperature may have to be adjusted to displace or evaporate any remaining product. Wash water temperature Code (A)Ambient temperature water or at least 10 degree C above the melting point of the cargo. FIRE OR EXPLOSION Flammable/combustible material; may be ignited by heat sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion and poison hazard indoors, outdoors or sewers Runoff to sewer may create fire or explosion hazard. HEALTH HAZARDS May be Poisonous fatal if inhaled or absorbed through skin Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution . EMERGENCY ACTION Keep unnecessary people away; isolate hazard area and deny entry Stay upwind, keep out of low areas, and ventilate closed spaces before entering Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. FIRE Small Fires: Let burn unless leak can be stopped immediately. Large Fires: Water spray fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. FIRST AID Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen In case of contact with material , immediately flush eyes with running water for a t least 15minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

APPENDIX-1 SPECIAL CARGO HANDLING MANUAL

ACRYLIC ACID (ESTER GRADE)

2.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk

shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Acrylic Acid must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water Acroleic Acid, Ethylene Carboxylic Acid, 2-propenic Acid, Acid, Vinyl Formic Acid. C2H3COOH Colorless liquid Acrid odor 1.05 Organic acid ACR 141 C 12-14C 3.1 0.2 0.4 2.48 Complete Propenoic

2.1.2

FIRE & EXPLOSION HAZARD 1. Status 2. General Flammable vapors, combustible liquid. Presents no special fire or explosion hazard because of its relatively high flash point and low vapor pressure poisonous gases may be produced in a fire. 54 C 446 C Alcohol resistant foam Follow SNI contingency plan A fire involving a spill on tankdeck could be extinguished with dry chemical or foam. Wear full protective clothing. Eye protection and self contained breathing apparatus.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

2.1.3

HEALTH HAZARD

1. 2.

Irritating vapor Irritation from liquid

Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate or high vapor concentrations. Fairly sever skin irritants, usually causing pain and second degree burns after a few minutes contact. Some hazard, typically having threshold limits of 100 to 500 ppm. Unavailable.

3. 4. 5. 6. 7.

Chemical poisons Odor threshold (ppm)

Permissible exposure limits/TWA 10 ppm (skin) Threshold limit value/TWA General 10 ppm (skin) Acrylic Acid, when in contact with skin or eyes, may result in a burn upon short contact. Vapor may present an inhalation hazard from single exposures; irritating to eyes, nose and throat. Vapors are capable of causing definite skin or eye irritation, nasal irritation and lachrymation. 0.5 ppm. If contact with skin or eye occurs, immediately flush with plenty of water for at least 15 minutes. Get medical attention promptly. Immediately remove contaminated clothing and shoes. Refer to the IMO Medical first aid guide (MFAG).

8.

Symptoms

9.

Short exposure tolerance

10. Exposure procedures

11. Medical management

2.1.4

REACTIVITY INFORMATION 1. Stability 2. Material compatibility 3. USCG compatibility Polymerize readily. Should be inhibited to insure safety and stability during storage and handling. Severely corrodes iron and steel. Glass, low carbon content stainless steel and high purity aluminum are recommended. Group4. See also exception to the chart.

2.1.5

SPILL OR LEAK PROCEDURE 1. Personnel protection 2. Contingency plan If possible, wear rubber gloves, face shield, protective clothing. Body shield and self-contained breathing apparatus should be available. Follow SPTI contingency plan.

3. Leak combat

If leak on cargo transfer system. Stop transfer and empty the line system. Flush contaminated area with a weak caustic soda solution(10%), then flush the area with large quantity of water.

2.2.1

CODES MINIMUM REQUIREMENTS ACRYLIC ACID (ESTER GRADE)

Acrylic acid is an unstable product when not inhibited. The ester grade (technical grade) covered by this manual is relatively stable when properly inhibited. Acrylic acid is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements:

UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction Special requirement Respiratory and eye protection

2118 D. Safety hazards. 3. Integral gravity tank. Controlled venting. No requirements. Special requirement. Restricted. Flammable and toxic vapors. Alcohol resistant foam. Steel covered with a suitable protective lining or coating, Aluminum or stainless steel. See IBC code Chapter 15,15.13,16.6.1 and the BCH code, Chapter IV, 4.10, 4.12,6, 4.18.1. Individual unit are not required for emergency escape purpose.

2.3.1

ARRANGEMENT PLANNING

1. Establish method for hearing the cargo. Thermal oil, hot water, and/or adjacent heating is to be used. If no thermal oil/hot water heating system exists, the operations department will advise on alternative heating methods on a case by case basis. 2. For the transportation, and in case of rapid temperature increase ensure to have prepared plans to abandon the cargo overboard if so is required to protect the safety of crew and ship. 3. Stowage is to be arranged so that tanks are not filled to more than 90% full. 4. The cargo should never be allowed to freeze (MP 12-14C) as when cargo is re-melted there is great risk of violent polymerization.

2.3.2

EQUIPMENT PLANNING 1. Ensure to have on board sufficient acid resistant hoses for the cargo transfer. 2. Ensure to have on board sufficient acid spray shield to cover flanges on manifold and hose connections according to IBC code 15.11.4 and BCH code 4.8.4. 3. Ensure to have onboard caustic soda for neutralization purposes in case of spills. 4. Tanks to be loaded need a minimum, of two temperature sensors in each tank with high and low temperature alarms. Ullages need to be arranged accordingly so that two sensors are in contact with the cargo during the voyage in each tank. High temperature alarms to be set at 34 C and low temperature alarm to be set at 16 C.

2.4.1

PREPARATION FOR LOADING 1. Do not purge the tank or lines with nitrogen as the inhibitor stabilizing the cargo is oxygen dependent. 2. Check that the P/V valve function normally. 3. The tank must be dry, free from chlorides (less than 2 ppm when wall washing with deionized water) and previous cargo residues. See wall wash specs sect 2.8. 4. Ascertain that all hatch packings are intact and in good condition. If in doubt, change packings. 5. Check that the remote reading thermometers and alarms when required are in working condition and accurate. 6. Check that all hoses to be used are clean and dry. 7. Check heating coils for leaks (follow procedure for non-destructive pressure testing of heating coils). Steam coils to be blown dry and blanked off. 8. Purge the Framo pump and check for seal tightness (use air) 9. Prepare 10% caustic soda solution for neutralization of spills. 10. Ensure that all handling personnel are using acid resistant protective gear. 11. Have respiratory apparatus, eyewash, soap and emergency showers ready for use. 12. Ensure to cover flanges on manifold including hose connection with acid spray shields. 13. Adjacent tanks or ballast spaces must not contain cargo or ballast with a temperature less than 18 C at time during the loading or voyage. any

2.4.2

LOADING 1. The cargo should be loaded with a temperature range of 18/28 C. 2. The shippers surveyors will gauge using the ships gauge. 3. No samples to be retained onboard 4. An inhibitor certificate must be obtained. 5. During loading cargo temperature must be checked and logged every 30 minutes. 6. The first 24 hours after loading the cargo temperature must be checked and logged every 2 hours.

2.4.3 1. 2.

AFTER LOADING For line clearing use air, do not use nitrogen, as the inhibitor stabilizing the cargo is oxygen dependent. All equipment used for Acrylic Acid loading must be thoroughly cleaned before stowed away. Cargo hoses should be flushed with warm (35-40 C) water and steamed before stowed away. VOYAGE

2.5.1

Do not add nitrogen to the tank as the inhibitor stabilizing the cargo is oxygen dependent.

The temperature to be kept at 18-28 C during the voyage, or other when advised. The cargo temperatures must be monitored every four hours (00-04-08-12-16-20) and the results recorded in the cargo temperature log. If the temperature falls below 18C, introduce heat using thermal oil/hot water or adjacent tank heating system. Heating coils surface temperature must not exceed 35 C. If the temperature continues to either decrease or increase to 16 C or 34 C respectively, urgently notify SPTI operations f the temperature change is not due to the corresponding ambient temperatures. If the temperature rises to 35 C see Jettison Procedures, section 2.8.2

2.6.1 1. 2. 3. 4. 5.

PRE-DISCHARGE ARRANGEMENTS Prepare and use only thoroughly cleaned, dry hoses. Ensure to cover flanges on manifold including hose connections with acid spray shields. Prepare :10% caustic soda solution for neutralization of spills. All handling personnel should wear protective acid resistant gear. Gauging and sampling will be done by receivers surveyor similarly as done at loading.

2.6.2 1. 2. 3. 2.7.1 1.

DISCHARGE Do not nitrogen to the tanks as the inhibitor stabilizing the cargo is oxygen dependent. The cargo should preferably be discharge at a temperature between 18 C and 28 C. During discharging cargo temperature must be checked and logged every 30 minutes. TANK CLEANING All tanks need to be stripped as per P & A Manual. Shortly after discharge all tanks are to be rinsed with clean ambient fresh water ( not ship channel water) to dilute any remaining acid by a minimum of 10 parts water to 1 part acid. This mixture is to remain in the tank until it is cleaned at sea (slat water O.K.) as per MARPOL regulations. Alternatively this fresh water/acid mixture may be transferred into another clean Ss tank or empty acid tank so the tank may be cleaned in port. Under no circumstance is the fresh water/acid mixture to be mixed with any other slops onboard along with any other compatible slops. This cargo can polymerize violently if contaminated or if exposed to freezing (12-14 C) or excessive heat (45 C) so utmost care needs to be taken when handling or cleaning from this cargo. If heating coils have not been used for heating, remove blind and thoroughly flush the coils with fresh water. Steam line systems, ensure to flush at all drain cocks and plugs.

2. 3.

2.7.2

SLOP DISPOSAL AND ARRANGEMENT

The slops are to be disposed according to : Regulations for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II and, when it is necessary to dispose slops to shore reception facilities, the ship must report estimated quantity to the ship operator and the local agent. Before mixing compatible slop residues or slops ad cleaning agents consult the local agent.

2.8.1 H/C

WALL WASH SPECS FOR ROHM & HAAS LOADING JAPAN Nil using 20- part MEOH 80 Part water.

Chlorides PTTColorOdor-

Less than 2 ppm More than 30 min. N/A Pass.

2.8.2

ACRYLIC ACID JETTISON PROCEDURE

Should the cargo Temperature rise to 35 C. 1. 2. Begin checking the temperature every 30 minutes. Plot on graph paper. Notify SPTI operations. If adjacent tanks or any tanks vicinity are being heated stop heating these tanks. If adjacent tanks are empty fill with ballast if possible, provided seawater temperature is between 18-30 C. Line up for circulation either through existing drop line or rig portable hoses.

3.

Should the cargo temperature rise to 40 C. 1. 2. Begin circulation of the cargo. Continue temperature monitoring.

At a temperature of 45 C 1. Prepare to pump cargo overboard. 2. Add cold fresh water to tank as void space permits. Continue circulation . continue adding fresh water until tank is full, as fresh water supply permits. Closely monitor temperature. Should temperature rise to 50 C Jettison. 1. 2. 3. Begin pumping cargo overboard. Continue adding fresh water while cargo is being discharged overboard, as FW supply permits. When tank is empty start cleaning with cold water and continue cleaning until tank is clean.

Emergency phone number for Rhom and Haas. USA (215) 592-3000 Alternate : (202) 483-7616 (Chemtrec), (800- 424-9300 (Chemtec USA/Canada phone only)

ACRYLONITRILE

3.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Acrylonitrile must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, Vinyl cyanide. CH CHCN Colorless liquid Resembles that of peach seed. 0.81 Nitrile ACN 77 C -85C 83 3.5 5.0 1.8 Moderate
2

3.1.2 1. Status

FIRE & EXPLOSION HAZARD Flammable liquid. When heated, this material may evolve cyanide gas, or explode, both. Flashback along vapor trail may occur. Fire may cause violent rupture of the tank. 0C 3.0 to 17.0% 481 C N2, CO2, dry chemical, alcohol resistant foam. Follow SPTI contingency plan. DO NOT use dry chemical for large, confined fire. If the tank is fitted with an N2 line, a fire may be extinguished by introducing N2. Water or foam may cause frothing. Keep tank cool with water spray. Fire fighters must wear respiratory. Protection and full protective clothing including rubber boots.

2. General

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

3.1.3 1.

HEALTH HAZARD Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate or high vapor concentrations. Minimum hazards. Usually includes chemical which, if spilled on clothing and allowed to remain. Will cause smarting and reddening of the skin. Moderately hazardous chemical. 21.6.

Irritating vapor

2.

Irritation from liquid

3. 4. 5. 6. 7. 8.

Chemical poisons Odor threshold (ppm)

Permissible exposure limits/TWA 29 ppm. Threshold limit value/TWA General Symptoms 2 ppm. Suspected carcinogen. Harmful by inhalation and skin absorption Penetrates leather, liquid in shoes and gloves should be destroyed. Eye irritation, headache, nausea, blueness of lips and finger tips. Contact with skin may also cause dermatitis. 400 ppm for 30 min. Remove victim to fresh air. If he is not breathing, apply artificial respiration. Remove contaminated clothing and wash chemical from skin with gentle flow of water. Get medical attention. If patient is unconscious, administer vapor of amyl nitrite (Brake an amyl nitrite ampule in a cloth and hold it lightly under the nose of the victim. But away from the person giving first aid, for about 15 seconds. Repeat five times at about 15 seconds intervals).

9.

Short exposure tolerance

10. Exposure procedures

11. Medical management

Refer to the IMO Medical first aid guide (MFAG).

3.1.4 1. Stability

REACTIVITY INFORMATION Very reactive; may polymerize explosively in the presence of strong bases (Such as caustic soda). The product must be inhibited to prevent polymerization. Polymerization could be initiated by visual light.

2. Material compatibility

Copper and copper alloys are attacked and should not be used. Attacks aluminum in high concentrations. Group 15. See also exception to the chart.(Do not stow AN adjacent Caustic).

3. USCG compatibility

3.1.5

SPILL OR LEAK PROCEDURE Wear rubber gloves, breathing apparatus, protective clothing. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Flush contaminated area with a weak LAC solution (1%), then flush the area with large quantity of water.

1. Personnel protection 2. Contingency plan 3. Leak combat

3.2.1

CODES MINIMUM REQUIREMENTS- ACRYLONITRILE

Acrylonitrile is an unstable product when not inhibited. Acrylonitrile is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements:

UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection

1093 B. Safety and pollution hazards. 2. Integral gravity tank. Controlled venting. No requirements. Special requirement. Closed. Flammable and toxic vapors. Alcohol resistant foam.

Material of construction Aluminum, magnesium, zinc, galvanized steel and lithium should not come in contact with acrylonitrile. Material normally used in electrical apparatus, such as copper, aluminum

and insulation, vapor of Acrylonitrile. Special requirement BCH code, Respiratory and eye protection 3.3.1

should as far as practicable be protected to prevent contact with See IBC code Chapter 15,15.12,15.13, 15.17, 15.19, and the BCH Code, Chapter IV, 4.9, 4.10, 4.12.3, 4.13.1, 4.14, 14.17. Individual unit are not required for emergency escape purpose.

the

SLOP DISPOSAL AND ARRANGEMENTS

The slops are to be disposal according to: 1. 2. Regulation for control of pollution by noxious liquid substances in bulk, IMO, Marpol Annex II and, When it is necessary to dispose slops to shore reception facilities, the ship must report estimated quantities to the ship operator and the local agent. Before mixing compatible slop residues or slops and cleaning agents consult the local agent.

3.8.1

REMOVAL OF ACRYLONITRILE FROM DRIP TRAYS

The customer BP is stressing the personnel and environment safety when handling Acrylonitrile as cargo and waste. Any product that may enter drip trays when disconnecting the cargo hoses must be transferred to a slop tank or a toxic waste container by safe methods. Personnel must wear rubber gloves, fate shield, and plastic coated clothing and wear self-contained breathing apparatus. Small spills may be flushed away with water.

PROPYLENE OXIDE

4.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Propylene Oxide must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water 1,2-Epoxypropane; Methyloxirane; Propene Oxide. CH CCHCH
2 3

Colorless liquid Ether-like Odor. 0.83 Alkylene Oxide POX 33.9 C -104.4C 449 18.0 22.0 2.00 59

4.1.2 1. Status

FIRE & EXPLOSION HAZARD Flammable liquid. An extremely reactive, flammable liquid with a wide explosive range. Ignited by heat, sparks or open flame. Flashback along vapor trail may occur. Fire or contamination may cause violent rupture of the tank. Less than - 29 C 2.3 to 37.0% 465 C

2. General

3. Flash point 4. Flammable limits 5. Autoignition temperature

6. Extinguishing agents

Alcohol resistant foam or multi-purpose form and water spray. Stop flow of gas. N2 purging of the tank. Use alcohol foam for fire fighting. Follow SPTI contingency plan. Explosion hazard requires approaching a burning tank with caution. Cool tanks with water spray. Use water spray to knock down vapor. Use water for dilution and heat removal. Massive water spray can extinguish small Propylene Oxide fires.

7. In case of fire 8. Special fire fighting procedures

4.1.3

HEALTH HAZARD Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate or high vapor concentrations. Will burn skin and eyes. Harmful if swallowed. If vapor inhaled, it will cause headache, nausea, vomiting or loss of consciousness. 200 ppm. Unavailable 20 ppm. Irritation of eyes and respiratory tract. Overexposing will cause serious injury. Contact with eyes will cause burns. Contact with uncovered skin produces frostbite. Ingestion will cause serious illness or death. Coughing, watering eyes, sickness of stomach, frostbitten skin. Prolonged contact with skin causes frostbite burn. Smarting of skin and first-degree burns on short exposure; may cause secondary burns on lung exposure. Vapor: Remove the victim to fresh air. If breathing has stopped, use oxygen inhalation. If ingested, make victim vomit, at least 2-3 times, and then give the victim a tablespoon of Epsom salt in glass of water. Eye contact: immediately flush eyes gently with water for 15 minutes. Remove contaminated clothing immediately. Wash skin with soap and water. Refer to the IMO Medical first aid guide (MFAG).

1. Irritating vapor 2. Irritation from liquid 3. Chemical poisons

4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General

8. Symptoms 9. Short exposure tolerance

10. Exposure procedures

11. Medical management

4.1.4 1. Stability

REACTIVITY INFORMATION Polymerize violently on distillation or in the presence of catalysts such as nonoxidizing mineral acids, sulfuric acid, nitric acid, organic acids, caustics, ammonia, aliphatic amines, alkanolamines and certain salts.

2. Material compatibility No Copper and copper containing alloys or other acetylide forming metals should be in contact with liquid or gaseous Propylene Oxide. Stainless steel, Mild steel, Zinc

silicate coatings 3. USCG compatibility 4.1.5

are materials resistant to Propylene Oxide. Group 16.

SPILL OR LEAK PROCEDURE Wear chemical resistant protective clothing and respiratory protective Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Flush contaminated area with large amounts of water(at least 22 parts of water to 1 part of oxide).

1. Personnel protection device. Avoid contact with liquid. 2. Contingency plan 3. Leak combat

4.1.6 1.

PERSONNEL TRAINING/INVOLVEMENT

All personnel involved in handling must be instructed concerning the characteristics of Propylene Oxides including: a. b. c. d. e. Chemical properties. Procedures in case of spills. Fire fighting. Medical treatment in case of exposure. Emergency measures in case of internal leaks and/or reaction (polymerization).

2. 3.

Propylene Oxide is normally handled in a complete closed system, and the potential for personnel exposure is low. Personnel protection during normal handling is chemical goggles and glove. During activities where the potential for exposure is high, like connection and disconnection, sampling and opening the tank after discharge for cleaning, the personnel involved should wear full personal protective equipment, which includes full eye, body, and respiratory protection. Each participating person should be instructed in his role and duties for each aspect of the carriage according to the Masters orders. All crewmembers should be advised about the hazards of the Propylene Oxide and be instructed to stay away from the deck area around the manifold during cargo operations. Appropriate warning signs should be posted at the gangway and around the deck also indicating that double skin and bottoms as well as cofferdams are inerted. All equipment used for Propylene Oxide must be thoroughly cleaned before it is stowed away. Vessel ventilation systems drawing air form the weather deck area should not be used during all loading, discharging, and cleaning operations involving Propylene Oxide.

4. 5.

6. 7.

4.2.1 CODES MINIMUM REQUIREMENTS- ACRYLONITRILE Propylene Oxide is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category 1280 D (Will upgrade to C year 1994.)

Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction

Safety hazards. 2. Integral gravity tank. Controlled venting. Inerted. Special requirement. Closed. Flammable and toxic. Alcohol resistant foam or multi-purpose foam and water spray. Materials normally used in electrical apparatus, such as copper, aluminum and insulation, should as far as practical be protected to prevent contact with vapor from the product. See IBC code Chapter 15,8.15.12.1,15.14, 15.15, 15.19, and the BCH Code, Chapter IV, 4.7, 4.9, 4.11., 4.14. Individual unit are not required for emergency escape purpose.

Special requirement Respiratory and eye protection

4.3.1 1. 2. 3. 4.

EQUIPMENT PREPARATION

Carry out inspection and if necessary cleaning of the P/V valve. Ensure that P/V valves (3 PSI) are fitted on the void spaces to be inerted (double skin and bottoms). Ensure to prepare/rig (nitrogen connection and purging pipe/hose) for inerting of void spaces. Ensure to order sufficient supply of N2 (commercial purity N2 99.9%) for the maintenance of the N2 blanket during the voyage. Ensure to have onboard full sets of for all cooling units and compressors. Ensure to have onboard sufficient Propylene Glycol for cooling mixture during the voyage (Ethylene Glycol is no longer accepted as a cooling medium and must therefore not be used.) Ensure to have onboard sufficient portable stainless steel valves for doubling up on cargo line and vapor return line, according to requirement for load preparation. (the purpose of these additional valves is to minimize potential of Propylene Oxide liquid and vapors to escape from the ships piping in the event that the lines are not properly blown or the manifold valve is leaking). Ensure to arrange for extra MDO for running of aggregate(s) (2 M/T per aggregate per day). Ensure there are means installed or onboard for samplings of the bottom atmosphere.

5. 6. 7.

8. 9.

10. Ensure to have onboard sufficient equipment for vapor return rigging. 11. Ensure to have onboard sufficient of the special gaskets (Spirally wonded) required for handling of P.O. refer to the company policy Use of gaskets and bolting up line connections.

4.4.1 1.

LOAD PREPARATION Prepare the tank(s) according to regulatory requirements and to customers standard. If previous cargo was an acid/caustic or an amine, or if acid/caustic was used in cleaning ensure all residues have been removed. The lines/system should be tested by checking the Ph of the cleaning water during the final cleaning. Ballast and void spaces affected according to regulations must be well drained. When conditions allow, inerting of double bottoms can be done when deballasting the same spaces. Each ballast space must be fitted with a P/V valve, nitrogen filling lines and be gastight. All packings and gaskets in the cargo containment system to be check and replaced as necessary. The cargo pump cofferdam to be purged with nitrogen to check for leaks. Heating coils to be pressure tested for leaks, purged with N2 and sealed off. Cooling units to be cleaned inspected and test run according to standing instruction from manufacturer and SNSO guidelines. Closed level gauging devices to be tested and operational. To prevent incorrect readings from pressure sensor based systems, correct function and zero setting must be carried out according to manufactures instructions (Instructions before zero setting of top sensors for cargo master).

2. 3. 4. 5. 6. 7. 8.

9.

10. Pressure gauges (if applicable) to be installed on each tank. 11. Nitrogen filing connections and equipment for maintenance of N2 blanket to be checked. 12. If additional Y-piece and reducer are used, position a stainless steel valve at the outside (to prevent spill when disconnecting the shore hose). 13. Prior to arriving at the load berth all valves, piping and the tank(s) scheduled to load Propylene Oxide are to be pressure tested to ensure tightness. Any leaks must be repaired. For pressure testing refer to the procedure, Pressure testing cargo tanks with Air/N2, in the Stolt Tankers Cargo handling Manual. 14. Besides preparation of general fire fighting equipment, the sprinkler system require according regulation (IBC Code 14.8 and BCH Code 4.7.21) to be checked and tested. 15. Closed sampling device to be checked ready for correct sampling. 16. Use only stainless steel hoses marked: For alkylene oxide transfer only. 17. Manifold drip trays to be cleaned and filled 1/3 with fresh water. 18. Test and calibrate Oxygen meters. 19. Check vapor return hoses and connections. Vapor return hoses must be clean.

4.4.2 1.

IMMEDIATE BEFORE AND DURING THE LOADING Very often pre-inspection of tank cleanliness/suitability will be arranged in order to start Nitrogen purging prior to arrival at the load berth. Purging of ballast and void spaces will also normally take place prior to arrival at the load berth. It is very important that all hatches, etc., be kept closed and tight after such prior purging and not be opened before final purging at the load berth.

2.

In all cases, double bottom and void spaces adjacent to the Propylene Oxide tanks must be purged down to an Oxygen level of less than 2% prior to commencement of loading. Adjacent cargo tanks that have been previously loaded do not require purging. Under no circumstances should loading be started before completion of purging all adjacent void spaces. Connecting the cargo hose must be supervised by a senior deck officer, either Master or the Chief officer must be present. Prior to loading the manifold and the affected tank area to be roped off and unauthorized personnel not allowed in this area. Post proper warning signs. Pre-loading inspection to be conducted together with a representative from the terminal or the cargo surveyor. The pre-loading inspection should include : High level and overflow control functional check, tank tightness, remote temperature accuracy check, tank pressure gauge, closed ullage device and safety equipment preparedness check. Stolt pre-loading check list. Cargo tanks for Propylene Oxide will be purged down to less than 2% Oxygen or as per customer requirements (See section 4.8) Before commencement of loading the piping system to be pressurized and tested for leaks, using Nitrogen. The tanks must be loaded according to regulations, i.e. using the reference temperature for calculation max. Allowable ullage. For proper operation of coolers the tank filling must satisfy manufacturers filling requirement. Under no circumstances must the tank be opened for ullaging or sampling. Always use closed level gauging and sampling devices.

3. 4. 5.

6. 7.

8.

9.

10. Ships equipped with inert gas system ( As per SOLAS requirement) can use the same for purging of void spaces and double bottoms. 11. Adjacent cargo tanks must either be inerted, loaded with compatible cargo or ballasted. 12. Double bottom must be inerted or ballast.

4.4.3 1. 2. 3.

IMMEDIATE AFTER LOADING For line cleaning use nitrogen. Cargo line must not allowed to be drained into the drip trays. Disconnecting the cargo hose must be supervised by a senior deck officer, either the master or the chief officer must be present. Immediate after loading,, and after gauging ad sampling adjust tank overpressure to 150 mbar and monitor if pressure holds steady. Start cooling units and run them for system function check, provided cargo level is sufficient in the tank.

4. 5.

4.5.1 1.

PROPYLENE OXIDE TEMPERATURE REQUIREMENTS In general the cargo temperature should be kept/maintained below 25 C. for specific customer requirement refer to section 4.8 or as per instructions received at load port.

2.

By regulatory requirements, 100% emergency backup cooling capacity is required. The backup unit(s) should not be use unless in an emergency situation, i.e. breakdown of the unit(s). running of all units just in order to bring the temperature as low as possible should not take place. As for proper running and operation of the cooling plant and units, refer to manufacturer and company technical information.

4.5.2 1. 4.5.3 1. 2. 3.

TANK VAPOR SPACE ATMOSPHERE Positive pressure between 70-150 mbar must be maintained throughout the voyage. MONITORING & RECORDING Observe and record cargo temperature every 4 hours, tank by tank. Observe and record tank pressure every 4 hours. Daily measure the Oxygen content in ballast tanks and void spaces surrounding the P.O. tanks. Keep a slight overpressure in these spaces, the same as for cargo tanks.

4.5.4 1.

TANK INTEGRITY AND EMERGENCY PROCEDURE Rise in Temperature Indicates, relative to the ambient sea and air temperature, which either the cooling units are not working or that the cargo may be reacting.

2.

Loss of Cooling Immediately identify the problem and, if possible, repair the same. The coolers are never to be removed form the tank(s) loaded with Propylene Oxide. Watch the cargo temperature and tank pressure closely. In the event of a cooler breakdown or leakage, the unit should be shut down and only the backup unit should be used. Monitor the temperature closely. Notify the ship operator and the SNSO fleet Manager.

3. 1. 2.

Internal Reaction (Polymerization) The Propylene Oxide is normally of sufficient purity to preclude a concern for abnormal reactivity at ambient or slight elevated temperature. A slow increase in temperature that cannot be explained by changes in conditions external to the tank, such as increased ambient temperatures or solar exposures, should be monitored closely and increased cooling and rising the deck with seawater should be considered. Contact head office if the cargo temeprature continues to rise. A sudden unexplained increase in temperature is highly unlikely, but in case that happens, the ship operator and SNSO Fleet Manager must be contracted immediately. Abandonment of the cargo could be necessary in such cases. Loss of nitrogen pressure in tank Immediately check the tank accesses for leaks. Once the problem is located, repair leaking tank accesses as appropriate.

3.

4.

4.6.1 1. 2.

PRIOR TO DISCHARGING PREPARATION Purge the pump(s) cofferdam by N2 before commencement of pumping. Test the water sprinkler system

3. 4. 5.

Manifold drip tray to be cleaned and filled 1/3 with fresh water. Use only stainless steel hoses marked: For alkylene Oxide transfer only. Prior to discharging the manifold and the affected tank area to be roped off and unauthorized personnel not allowed in this area. Post proper warning signs. Under no circumstances must the tank(s) be opened to the atmosphere for ullaging and sampling. Use only closed devices. The Oxygen level in the tank9s) will normally be checked prior to discharging. For specific customer requirement refer to section 4.8 or the specific information received at load port or at discharge port.

6. 7.

4.6.2 1.

DISCHARGE OPERATION The tank atmospheric pressure to be closely monitored and kept on/around 150 mbar during the discharging. Nitrogen balancing may be necessary to maintain this overpressure.

4.7.1 1. 2. 3. 4.

TANK WASHING After discharge, keep the tank(s) inerted until cleaned. Without opening any tank hatches, pump a few cubic meters of fresh water into the tank form the manifold. Pump this water out of the tank and overboard if at sea, or alternatively, into a slop tank. Ventilate the tank (by forcing air into the tank) using one or more ventilators for a minimum of two hours. During the cleaning/ventilation operation, all precautions must be taken to avoid any sources of ignition at or near the tank. Crewmembers should be kept away from the area. VENTILATION PROCEDURE The ventilator(s) must be placed on tank opening(s) located as far as possible form the gas outlet(s) to create an effective flow of air through the entire areas of the tank(s) and to prevent escaped gas to reenter the tank through the ventilator(s). The ventilator must be put in place and started before the gas escape hatches is opened. Be sure the ventilator is properly grounded and secured. If the gas-freeing must be stopped before the tank is gas-free, be sure that the gas escape hatch is closed before the ventilators in stopped. Remove the ventilators after stopping and close the hatches.

4.7.2 1.

2.

3.

4.7.3 1.

WARNING Propylene Oxide vapors are heavier that air, and in certain weather conditions, Propylene Oxide vapor may concentrate above deck level and travel a considerable distance along deck or enter into any other tank or spaces that may be left open. Propylene Oxide vapors are highly soluble in water, such that a water spray (Butterworthing) into a tank containing Propylene Oxide vapor may result in a rapid reduction of the interior pressure. Such a sudden pressure drop could result in outside air entering the tank creating a combustible atmosphere or could result in structural damage of the tank.

2.

4.7.4 1.

SLOP DISPOSAL AND ARRANGEMENT The slop is to be disposal according to IMO regulation for control of pollution by noxious liquid

substances in bulk MARPOL Annex II. For slop arrangements that require disposal to shore facilities, the ship must report its estimate slop quantity. When the ship requires slop disposal to shore and before mixing it with other compatible slop residues it must be discussed with the local agent.

4.8.1 1. 2. 3.

DOW CHEMICAL REQUIREMENTS For K-40 class using pressure sensor gauging system analyzing foot sample the quantity received should be checked against shore figure when loading at DOW Freeport TX. Prior to loading cargo tanks will be purged to 0.05% (500 ppm) Oxygen level. The load temperature should maintained throughout the voyage, however, we have not guaranteed any temperature below 16 C. The Oxygen level in the tank(s) will normally be checked prior to discharging and DOW chemical requires maximum 0.05% (500ppm)

4.

4.8.2 1.

ARCO REQUIREMENTS The load temperature should maintained throughout the voyage, however, we have not guaranteed any temperature below 16 C. The Oxygen level in the tanks will normally be checked prior to discharging and Arco asks for maximum 2% (20,000ppm)

2.

CAPROLACTAM ( PURE )

5.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Caprolatam (pure) must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Liter weight 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 80 C (mmHg) E-Caprolactam, 2-Oxohexamathylenimine. CH (CH ) CONH Colorless liquid Odorless 1.0 at 80 C (see section 5.8.3 Density Table) Cyclic amide CLS 268.5 C @ 1013MB 69C 62 Pascal
2 2 4

11. Raid vapor pressure (mbar) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.0) 14. Solution in water (25 C)

0.8 0.011 3.9 @ 0 C 525g/100ml

5.1.2 1. Status 2. General

FIRE & EXPLOSION HAZARD Combustible liquid. Toxic oxides of nitrogen may be formed in fire. Negligible hazard polymerization below 93 C. 140 C (Pensky-martens) 1.4 to 8.0% 375 C Water, foam, dry chemical, N2. Follow SPTI contingency plan. Combustion may produce toxic fumes. e.g. carbon monoxide and nitrogen-oxides. Fire fighters should wear self contained breathing equipment.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

5.1.3

HEALTH HAZARD Vapor concentration of 25 ppm irritates eyes and the respiratory tract; nose bleeding may occur; systemic effects were not found 18 years exposure to 14 ppm caprolactam. Skin and eyes scald by liquid contact. Irritation of reparatory tract. Severely hazardous chemical usually having limits below 10 ppm. 0.3mg/M 5 ppm. 5 ppm.(vapor) Possibility of thermal burns from hot liquid if carried at elevated temperature. From inhalation; irritation of respiratory tract. Skin irritation: scalds by liquid contact. Eyes irritation; scalds by liquid contact and irritation by vapor contact. For guidance see point 1 (above) If vapor inhaled, remove the victim to fresh air. If liquid contact
3

1. Irritating vapor

2. Irritation from liquid 3. Chemical poisons

4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms

9. Short exposure tolerance 10. Exposure procedures

skin, cool rapidly with cold water and obtain medical attention for removal of adhering material and treatment of scalds. 11. Medical management Refer to the IMO Medical first aid guide (MFAG).

5.1.4 1. Stability

REACTIVITY INFORMATION Stable. Non-corrosive to steel and other common materials avoid oxygen and oxidizing agents. Remarks: Caprolactam is hygroscopic. Group 22.

2. Material compatibility 3. USCG compatibility

5.1.5

SPILL OR LEAK PROCEDURE Wear appropriate protective gloves and safety goggles or face shield. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Allow product to solidify. Contain and sweep up, put the substance in an adequate container for later removal.

1. Personnel protection 2. Contingency plan 3. Leak combat

5.2.1

SAFETY PRECAUTION

Caprolactam (pure) is not considered to come within the scope of the IBC/BCH Code. Caprolactam is listed in the IBC/BCH Code, Chapter18, respective Chapter VII. Although Caprolactam falls outside the scope of the IBC/BCH Code some safety precaution may be needed for the safe transportation; Pollution category D

5.3.1

SPECIAL EQUIPMENT

Due to the high melting point and the sensitivity of the product to heat, oxygen and water, special equipment will be required as follows: 1. 2. 3. 4. Sufficient deck mounted Framo submerged heating units. Self-contained units with heat exchanger/ recirculation pumps and associated equipment for the recirculation of hot water through both heating coils and the Framo heating unit indicated in (1). Hot water traced and insulated vent lines. Hot water traced and insulated cargo lines form pumpstack valve to tank entry point on deck. Insulated cargo lines form manifold. Dedicated nitrogen line/system fitted with; a) Pressure regulating valve. b) Flow meter ( which can supply 0-4 liters of Nitrogen per minute continuous flow). c) Nitrogen filling connection on the forward of the cargo tank for supplying initial blanket and maintenance of blanket during the voyage. 6. Teledyne (Oxygen) meter, capable to measure oxygen levels below 50 ppm. Meter and instructions

5.

for use will be supplied at time of loading. 7. 8. 9. Three fixed installed temperature sensors at top/middle and bottom of the tank. High velocity type PV valve. Sampling connection on the drop line to take a sample while maintaining a closed system. On tanks without drop lines fitting will be located between the pumpstack valve and the pump.

10. If fixed pressure sensor is not fitted. Pressure gauge capable of monitoring pressure in the cargo tank (form 1-3 PSI). 11. Sufficient N2 bottle with purity of 99.99% (maximum 50 ppm oxygen) to maintain N2 blanket throughout the voyage (Charterers surveyor will sample and test ships N2 supply). 12. Sufficient supply of Teflon gasket required for rigging of manifold and cargo circulation system. 13. Isolation valve to be installed in the cargo manifold crossover line (modification of crossover line). 14. Specially made T piece for loading multiple tanks. (to be supplied in Rotterdam)

5.4.1 1. 2. 3.

TANK ALLOCATION Due to the modification required for carriage, stowage will be limited to tanks/line systems that are modified. Stowage is stainless steel tank and lines (charterers requirement). Heat calculations for heating equipment is based on adjacent tans either: a. b. Being empty or, Containing cargo heated to a minimum of 60 C or higher.

4.

Adjacent cargo must never exceed 100 C.

5.4.2 1. 2. 3.

TANK PREPARATION Pressure test the tank and its associated piping with compressed air. Follow the procedure for Pressure testing cargo tanks with air N2 contained in the Stolt tankers-cargo handling manual. Test heating coils and heat exchanger circulation in accordance with Framo documented test procedures (see Framo manual). In addition to the visual tank inspection a wall wash will be performed and the same will be tested for nonvolatile matters (NVM) with maximum specs of 10 ppm. Additional tests may be performed pending last cargoes. It is intended that the cargo tanks and the associated heating equipment will always be preinspected/tested and pre-purged prior to arriving the load berth. Hot water circulation for the tanks and heat-traced lines should be started well in advance prior to the loading to allow the tank and line systems to warm up. Deck units should be started as soon as the cargo level is sufficient (approximately 80% full tank) according to the manufacturers instructions. The isolation valve fitted n the offshore part of the crossover manifold must be closed. A valve must be fitted on vapor return line prior to loading to be ready for connection of vapor return at

4. 5.

6. 7.

discharge. No vapor return at loading. 8. Cargo ball valves, in particular the pumpstack valve, must be checked and proven tight in order that no product can enter the cargo line during sample taking process. When loading more than one tank one tank a specially designed T piece must be connected to the manifold.

9.

5.4.3 1.

NITROGEN PURGING Cargo tanks will be purged down to 1000 ppm of oxygen prior to loading. Cargo pipe lines will be purged down to 50 ppm Oxygen prior to the loading.

2. 3.

Purging must be carried out in accordance with the cargo handling manual. Sufficient hatches must be open to avoid potential of over pressuring the tank. In most cases purging will be done prior to berthing at the loading terminal. Shipboard personnel will be required to monitor the oxygen content. When the 1000 ppm level is reached the surveyor should be called in to verify. Nitrogen used for purging will usually be supplied at a temperature of approximately 70 C and at a rate of approximately 1500 cm/hr.

4.

5.4.4 1. 2.

LOADING The cargo should be loaded at a temperature of at least 85 C. Due to the high melting point, avoid stoppages as this could result in solidification of product in the line system. If stoppage becomes necessary the line must be blown immediately. For this purpose N2 must always be readily available from shore during the entire loading operation. Loading will be done under closed condition with all vapors being released via vessels vent line and PV valve. No vapor return line will be supplied at loading. Tank pressure must be carefully monitored, especially due to the possibility of the caprolactam freezing and blocking the vent line/PV valve. Foot sample analysis will be required. After loading the first foot, the loading will be stopped. The ships line will be blown from shore. The cargo pump will be started and the Caprolactam will be recirculated via the drop lines. After 5 minutes of recirculation the sample will be taken. On tanks which do not have drop lines, the cargo will be pumped up against the closed pumpstack valve and allowed to drop back into the tank at least three times over a five minute period prior to taking the sample. For multiple tank loadings all foot samples will be loaded prior to clearing the lines for analysis. When stopped during analysis of the foot sample the pumpstack valve should be opened. Nitrogen should be continuously supplied from shore to keep the line clear. For proper operation of the deck heaters the tank filling must satisfy manufacture-filling requirement (minimum 80% of tank volume). Tank volume should be calculated basis a cargo temperature of 70 C to ensure the unit can be run under all conditions. A number of draincock should be steamed from the outside throughout loading to ensure they are clear for Nitrogen blowing if required for stoppage.

3.

4. 5.

6. 7.

8.

5.4.5 1. 2.

AFTER LOADING The shoreline will be pigged to the jetty, the loading arm will be blown to the ship. After load samples to be taken using the same procedure as for foot samples. The charterers surveyor will take 3 samples for ships account (manifold/first foot/final). These samples to be stored onboard as per standard companys policy. Ensure the line system is cleared using N2. Follow the procedure Cargo line clearing contained in the cargo handling manual.

3.

4.

On completion of loading, the charterers will provide an N2 blanket via the forward Nitrogen connection. The N2 blanket is to be introduced direct to the vapor space, not via the cargo load line. A nitrogen regulator will be supplied by Rotterdam and must be used to control the Nitrogen flow into the tank in order to avoid the potential of over pressuring the tank. Excessive pressure in thee tank will be released via the PV valve only. The oxygen level in the tank atmosphere will be reduced to less than 50 ppm and verified by the charterers surveyor. Charterers surveyor will seal all flanges/drain cocks on the cargo line and the bypass valve on the hearing system. For the first 2 hours, after placing the positive N2 blanket, frequently check for pressure drop and leaks.

5.

6.

5.5.1 1.

TEMPERATURE REQUIREMENTS Caprolactam should be maintained at 85 C during the voyage. At no time should the temperature be allowed to fall below 75 C or exceed 90 C. The heating medium (hot water ) in both heating coils and the deck heating units should be maintained at 100 C and must never exceed 105 C as this will cause deterioration of the cargo. The temperature regulator on the system must be set accordingly. The cargo temperature must be monitored according to charterers/surveyors instructions. The results to be recorded using for supplied by the charterers. Refer to the format in section 5.8

2.

3.

5.5.2 1. 2. 3.

TANK ATMOSPHERE REQUIREMENT N2 blanket to be maintained and tested according to charterers instruction. For maintenance of the Nitrogen blanket, only Nitrogen with less than 50 ppm Oxygen from certified cylinder/supply can be used. Maintain a positive N2 blanket (above 70 mbar) and a constant Nitrogen flow of 100 liters hour.

5.5.3 1.

VOYAGE LOGS A copy of the logs must be available for the receiver at the discharge port.

5.6.1 1.

PRE-DISCHARGE Prior to arrival all cargo lines must be checked to ensure they are clear. In the event of blockage or suspected blockage a blank flange is to be fitted at the pumpstack connection and the line steamed/drained/dried to melt and remove any solidified product.

2. 3.

Nitrogen will be supplied by shore to blow the lines dry and bring the oxygen level of the lines and vapor return system down to the 50 ppm level. At Ulsan (UTT terminal), three delicated Caprolavtam, vapor return hoses, (55 foot lengths of 3 inch stainless steel hose), and a 4 to 3 adaptor are stored. The agent will arrange delivery to the vessel prior to berthing to allow time for rigging. Each hose will have a blank flange which was sealed by the local surveyor after the previous vessel. These are dedicated hoses and care must be taken to ensure no foreign particles or contaminates enter the hose. The end of the hose to be connected to the shore, vapor return line should remain closed until time of connection. At Taichung (west wharf 2 berth), vapor return hoses will be supplied sufficient to reach the ships tank or manifold connection.

4.

Upon arrival at the discharge port, ullage and samples will be taken. Both must be taken while maintaining the closed system, similar to the method used after completion of loading, except for tans not fitted with drop lines. On tanks not fitted with drop lines approximately 500 liters will be prepumped to shore into drums prior to sampling in order to ensure a good representative sample of the tank(s) is obtained. The surveyor will take one extra tank/manifold sample for the ship. DISCHARGE OPERATION The circulation pump for the cargo heater unit must be stopped when the discharging commences. Hot water circulation pump to the heating coils to run throughout the discharge operation. Monitor vapor return pressure carefully. As the shore tanks will most likely be empty. A negative tank pressure may be experienced initially and supplemental Nitrogen will have to be supplied form shore. Each tank will be discharged separately one at a time. After completion of each tank, lines will be blown and both cargo and vapor return hoses will be shifted to the next tank/ manifold. The discharge of each tank should be continuous without any stoppage. Shore nitrogen should be supplied to the pumpstack drain connections. Nitrogen form shore must always be readily available. Should stoppage be required, all line valves except the insulated pumpstack valve must be left open. The entire line from shore tank to ships tank must be blown clear of product. A constant flow of nitrogen must be maintained throughout stoppages in order to keep the cargo lines clear.

5.6.2 1. 2.

3.

4. 5.

5.6.3 1.

POST DISCHARGE After discharge is completed the vapor return hose should be disconnected form shore. The three hoses are to be disconnected and blank flanges replaced on the end of each hose. Blank are also to be put on the 4 to 3 adaptor. The local surveyor will seal each flange. The 3 hoses and the adaptor are to be landed prior to departure.

5.7.1 1. 2. 3. 4. 5.

CLEANING Caprolactam, in its liquid stage, is soluble in hot water. Wash the tank with hot sea water (85 C) for about two hours. Simultaneously with the machine washing, ensure to steam out the vent system. Etc. Heat should be applied to deck heaters, heating coils and steam traced line systems throughout the tank washing. To ensure cleanliness of deck heaters, circulate hot washing water when washing the tank.

6. 7. 8. 9.

Immediately upon completion of tank washing, live steam the tank for 3 hours. Avoid tank atmosphere temperature to exceed 90 C, measured on the remote temperature reading system. Steam the line systems and ensure to flush at all drain cocks and plugs. On completion of washing/steaming shut down heating systems and heat traced lines. Drain and dry tank and systems.

5.7.2 1.

SLOP DISPOSAL AND ARRANGEMENTS The slops are to be disposed according to the regulations for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II. If it is necessary to dispose slops to shore reception facilities, the ship must report estimated quantities to the Ship operator and the local agent. Before mixing compatible slop residues or slops and cleaning agents consult the local agent.

2.

5.7.3

FRAMO SUBMERGED CARGO HEATER

At completion of cleaning the tank, the Framo heater must be removed form the tank, inspected and moved to a proper location for storage. Framo heaters are for use with Caprolactam only.

5.8.1 1.

D.S.M REQUIREMENTS Load ex TTR terminal Rotterdam- Port side alongside. Note: The capacity of the shoreline is approximately 9 cubic meters. Sufficient space must be left in the ships tank for blowing the line to the ship.

2. 3.

Discharge to UTT terminal Ulsan- Port side along side. Weekly, submit copy of daily temperature log (copy of DSM form attached) by fax to the charterer DSM Holland with copy to ship operator.

5.8.2 1. 2. 3.

BASF REQUIREMENTS Load ex TTR Terminal Rotterdam (same as DSM) Discharge at Ulsan or Taichung. Ulsan discharge at UTT (same as DSM). Taichung discharge at WW 2(Unishine terminal) 6 cargo connection. Weekly submit copy of daily temperature log to DSM with copy to ship operator as indicated in 5.8.1 (3) above. (DSM will forward information to BASF.)

FORMIC ACID

6.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Formic Acid must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water Formylic Acid; Hydrogencarboxylic Acid; Methanoic Acid. HCOOH Colorless liquid Sharp, penetrating Odor. 1.2076 (90%) 1.2225 (99%) Organic Acid. FMA 101 C 6.2C (90%) 8.4 (99%) 0.6 (23mmHg-90%) 33 mmHG-90% 1.5 2.1 1.6 (90%) 1.64 (99%) Complete.

6.1.2 1. Status 2. General

FIRE & EXPLOSION HAZARD Combustible liquid. Formic Acid is corrosive, combustible liquid. Toxic vapor are generated in fire. 69 C (58.8C-90%) 18 to 57.0% 601 C Water fog, dry chemical, alcohol foam, CO2, N2. Follow SPTI contingency plan. Wear full protective clothing. Eye protection and self-contained breathing apparatus. (47.7C-99%)

4. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

6.1.3

HEALTH HAZARD

1. Irritating vapor 2. Irritation from liquid

Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate or high vapor concentrations. Fairly sever skin irritants, usually causing pain and second degree burn after a few minutes contact. Moderate hazardous chemical. The product is highly corrosive and decomposes slowly during storage and shipment, evolving carbon monoxide, which is a hazardous, poisonous gas that is practically odorless. Unavailable. 5 ppm. 5 ppm. Natural, slow decomposition yields carbon monoxide C),a chemical asphyxiate, and water. Enclosed spaces must be tested for oxygen content before entering. Vapor is irritating. Liquid causes burns. Choking, respiratory irritation, watering of eyes; skin contact will cause severe itching or burning. Unavailable. Vapor: Remove the victim to fresh air. If breathing has stopped, apply artificial respiration. Skin or Eye contact: Remove contaminated clothing immediately flush affected areas gently with water for 15 minutes. Get medical attention. Use protective clothing to prevent personal contact. Refer to the IMO Medical first aid guide (MFAG).

3. Chemical poisons

4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General

8. Symptoms 9. Short exposure tolerance 10. Exposure procedures

11. Medical management

6.1.4 1.

REACTIVITY INFORMATION React with bases (alkalis) to produce heat. It is also a reducing agent. Type 316 stainless steel is satisfactory. Group 4. See also exceptions to the chart.

Stability

2. Material compatibility 3. USCG compatibility

6.1.5

SPILL OR LEAK PROCEDURE Avoid contact with liquid. Use full protective clothing and self contained apparatus. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Eliminate all sources of ignition. Flush contaminated area with large amounts of water.

1. Personnel protection 2. Contingency plan 3. Leak combat

6.2.1

CODES MINIMUM REQUIREMENTS- ACRYLONITRILE

Formic Acid is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction 1779 D Safety hazards. 3. Integral gravity tank. Controlled venting. No requirements Special requirement Restricted. Toxic Vapor. Alcohol resistant foam. Aluminum or stainless steel for product concentration of more than 98%. Special acid resistant steel for product concentration of less than 98%. Special requirement See IBC code Chapter 15,15.11.2,15.11.2 to15.11.4, 15.11.6 to 15.11.8 and BCH Code, Chapter IV, 4.8, 4.8.2 to 4.8.4, 4.8.6 to 4.8.8, 4.12.7, 4.17 Individual unit are not required for emergency escape purpose.

Respiratory and eye protection

6.3.1

EQUIPMENT PLANNING

Ensure to have onboard sufficient acid resistant hoses for the cargo transfer. Ensure to have on board sufficient acid spray shields to cover flanges on manifold and hose connections according to IBC code 15.11.4 and BCH code 4.8.4.

6.4.1

PRE-LOADING

This product is subject to hydrocarbon and chloride bulkhead tests prior to loading by some shipper. Check with ship operator regarding the requirements on each shipment.

6.4.2

TYPICAL LOADING SPECS 125ppm as n-Heptene 8 ppm 10 max. 40 minutes

Hydrocarbon Chlorides Color, Alpha Permanganate Test

Odor, residual Odor or Dilution

None Essentially none.

6.4.3 1. 2.

PRE-LOAD TESTS

Heating coils to be pressure tested, according to company procedure for Non destructive testing of heating coil contained in the tank cleaning manual then, blow and blank the coil before loading. Carry out wall wash if required.

Ensure to cover flanges on manifold including hose connections with acid spray shields. Some shippers require a nitrogen blanket, other require a nitrogen purge of the tank to reduce the moisture content. Should the purge be required prior to loading, follow the procedure N2 purging of line and tanks contained in the Cargo handling manual. For line clearing use nitrogen. Following the procedure cargo line clearing contained in the Cargo handling manual.

6.5.1

ROUTINE LEAK DETECTION

Concerning the IBC Code 15.11.7 and the BCH Code 4.8.7 follow SNSO procedure for routine leak detection of Acid into adjacent spaces.

6.5.2

IF HEAT IS REQUIRED

1. Generally no heat is required, however if the ambient temperature is at or below the freezing point adjacent heat should be used. Heating through coils should be avoided. 2. If coils are used, then thermal oil or hot water should be used to keep surface temperature of coils at maximum 50 C. 6.6.1 DISCHARGE

1. Ensure to cover flanges on manifold including hose connections with acid spray shields. 2. For efficient stripping and line clearing use nitrogen.

6.7.1

CLEANING

1. Wash the tank with ambient temperature seawater for 2 hours. The following must be washed/steamed simultaneously when washing the cargo tank. 2. Cargo line, valves, drain cocks and removal of blinds if fitted on valves. 3. Vent line system including P/V valve and vent riser. 4. Heating coils or heat exchanger 5. Cargo pump cofferdam 6. Restricted gauge pipe if fitted. 7. Housing for tank level gauging.

8. On completion of washing fill the tank with seawater until it is overflowing (allow air pockets to escape form B/W hatches. Leave the ballast water in the tank for 12 hours and then empty the tank. 9. Mechanically ventilate the tank as follows; a. b. Stop the tank ventilation and check the tank atmosphere form hatches in the aft part and fore part using portable equipment. Provided tests show no traces of formic acid vapors or carbon monoxide, and the oxygen is showing 21%, then the following may be carried out; Before the tank is considered safe to enter a person equipped with self-contained breathing apparatus, and vapor testing equipment should enter the tank for testing. Vapor tests should be taken from pumpwell, all corners of the tank and any other pocket such as behind web frames where product gases may accumulate. The tank entry can be made according to the tank entry procedure. At every re-entry, up to the next loading, this tank must be re-tested for traces of formic acid vapor or carbon monoxide.

c. d.

6.7.2 DISPOSAL OF SLOPS The slops are to be disposal according to: 1. Regulations for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II and, 2. When it is necessary to dispose slops to shore reception facilities the ship must report estimated quantities to the ship operator and the agent. Before mixing compatible slop residues or slops and cleaning agents consult the local agent. 6.8.1 1. 2. 3. 4. GRADES AND STRENGTHS

Formic Acid 90% Formic Acid Glacial 98% Formic Acid Pharmaceutical 98% Formic Acid Technical 98% 6.8.2 ALSO SHIPPED INFREQUENTLY Ucar picking Acid 80% Formic acid 85%.

1. 2.

HEXAMETHYLENE DIAMINE SOLUTION.

7.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Hexamethylene Diamine Solution must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 1,6-Hexanediamine; 1-6-Diaminohexane; HMD; HMDA. NH (CH )NH
2 2 2

Colorless liquid Weak ammonia Odor. 0.93-89 (70-90% solution) Aliphatic Amines.

7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water

HMD 111 130 C (70-90% solution) 6-30C (70-90% solution) Data not available Date not available Data not available Data not available Complete.

7.1.2 1. Status 2. General

FIRE & EXPLOSION HAZARD Combustible liquid. Hexamathylene diamine forms explosive mixture with air. Hazardous gases/vapors produced in fire are noxious. 94-116 C 0.9 to 4.1% (in air volume ) 390-420 C Water fog, dry chemical, alcohol foam, CO2, N2. Follow SPTI contingency plan. Wear self-contained breathing apparatus, Wear full protective equipment. Hose with water from a distance to prevent splashing on personnel.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

7.1.3

HEALTH HAZARD Moderate hazardous chemicals. Fairly sever skin irritants, usually causing pain and second degree burn after a few minutes contact. Moderate hazardous chemical. 0.6 Unavailable Unavailable Vapor will cause irritation to eyes and respiratory tract. Liquid irritate eyes and skin, may cause dermatitis. Repeated exposure at low toxicity can cause anemia and damage kidney and liver.

1. Irritating vapor 2. Irritation from liquid 3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms

9. Short exposure tolerance 10. Exposure procedures

Unavailable. Remove the victim form contaminated area. Remove contaminated clothing and shoes. Flush affected areas with plenty of water. If in eyes: hold eyelids open and flush with plenty of water, if swallowed, and the victim is conscious, have the victim to drink water or milk. Exposure to skin or eyes; flush immediately with water for 15 min. get medical attention. Refer to the IMO Medical first aid guide (MFAG).

11. Medical management

7.1.4 1. Stability

REACTIVITY INFORMATION The product is stable and doesnt reaction with water. No reaction with common materials. Group 7.

2. Material compatibility 3. USCG compatibility

7.1.5

SPILL OR LEAK PROCEDURE Avoid contact with liquid. Use full protective clothing and self contained apparatus. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Eliminate all sources of ignition. Flush contaminated area with large amounts of water.

1. Personnel protection 2. Contingency plan 3. Leak combat

7.2.1

CODES MINIMUM REQUIREMENTS- ACRYLONITRILE

Hexamethylene Diamine Solution is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction 1783 C Safety and pollution hazards. 3. Integral gravity tank. Controlled venting. No special requirements No Special requirements Restricted. Toxic Vapor. Alcohol resistant foam. Copper, copper alloys, zinc and galvanized steel should not be

used. Special requirement See IBC code Chapter 15,19.6,16.2.9 and BCH Code, Chapter IV, 4.12.2, 4.14.1, 5.2.8 Individual unit required for emergency escape purpose.

Respiratory and eye protection

7.3.1

EQUIPMENT PLANNING

HMD, because of its high quality and sensitivity, requires special equipment for carriage; 1. Two temperature sensors with remote readouts. One sensor located near the tank top, the other at 1/2 the tank height. The tank vent system should have a high velocity P/V valve, ensure to have the same onboard if not fitted. Recirculation arrangement in stainless steel. See sketch attached in section 7.8 Special arrangement for tank atmosphere oxygen testing see a sketched in section 7.8 Special oxygen meter to be supplied by customer. Sufficient quantity of high purity N2 (certified purity of 99.999%) to maintain N2 blanket throughout the voyage. 7.4.1 1. TANK PREPARATION

2. 3. 4. 5. 6.

Tank must be of stainless steel, and cleaned to the following requirements in excess of the Visual water white standard. a. No hydrocarbons b. Maximum 2 ppm chlorides. c. Absolutely free of dust and from particles (The tank will first be visually inspected and the tank must be 100 percent free from dust/loose particles or remnants of cotton from rags, etc. tank surfaces in the bottom area should be rolled with adhesive rollers. d. When flushing/steaming the cargo lines, drain water from draincock and drain plug opening should be tested until neutral pH value is obtained. e. Tank(s) must be pressure tested before loading (to maximum pressure setting of the tanks P/V valve).

7.4.2 1.

PRE-LOADING

After passing, the tank will be rinsed with deionized water supplied by tank truck (approxmately 22 M3). The deionized water will be pumped into the tank via the manifold, then recircled through a portable (or fixed) cleaning machine. All equipment used must be stainless steel. After rinsing (recirculating), the water will be tested for: a. Color no increase b. PH 7.0 c. Conductivity 25 micrometers d. Total organic carbon- no increase.

2. 3.

After passing above test, the water will be pumped out and stored on board. (N.B. Water should still be good if other tanks require Deionized rinsing). The tank will be purged with nitrogen to less than 300 ppm oxygen. Nitrogen will be supplied from shore.

7.4.3 1. 2.

LOADING

HMD will be loaded at a temperature of approximately 50 C. after loading, a nitrogen pad to be established and maintained at a slight overpressure. When loading for Dupont, see their attached in section 7.8 7.4.4 AFTER LOADING

1. 2. 3.

The line system to be cleared using high purity N2. On completion of line cleaning obtain a positive N2 blanket of 100 mbar. Check the tank (deck penetrations) and its line system for leaks.

7.5.1 1.

MONITORING AND RECORDING

The N2 blanketing (measuring oxygen content), and cargo temperatures must be monitored at least twice daily (08:00-20:00) and the results recorded in tis respective logs (Nitrogen blanket log & cargo Temeprature Log contained in SNSO binder # 8 or the specific Dupont form contained in section 7.8) 7.5.2 TANK ATMOSPHERE REQUIREMENTS

1.

If the oxygen level exceeds 300 ppm (0.03%), add Nitrogen to the tank until oxygen content is less than 300 ppm.

7.5.3 1.

TEMPERATURE REQUIREMENTS

HMD 85% freeze at 23 C. if the cargo temperature falls to 28 C heat should be added in following manner; a. b. Start recirculating via the deep-well pump, approximately 30-40 M3/hr. After 10 minutes recirculating, apply steam to the heating coils. Use low pressure steam, about 2 kg/Cm2 on coils. Bring the temperature up to 33 C and close off the steam supply to the coils. Run recirculation for another 10 minutes.

c. d.

7.5.4 1.

INCREASING TO DISCHARGE TEMPERATURE

Five days before arrival (heating to be applied as mention above), the temperature to be slowly increased to 40 C, which is the discharge temperature. Recirculation must continues uninterrupted during this heating.

7.6.1 1. 2.

DISCHARGE

HMD will be discharged with a vapor return line from the shore tank. Nitrogen should be flushed until measuring leas than 300 ppm Oxygen at the ship vapor return connection before opening the valve to the cargo tank vapor space.

3.

The discharge must be adjusted so that the Nitrogen displacement is maintained at or above 100 mbar tank pressure ( Please be guided by the procedure Nitrogen displacement during discharge contained in the cargo handling manual ) For efficient stripping and line clearing use nitrogen,

4.

7.7.1 1. 2.

TANK CLEANING

Machine wash the tank with warm water for 2 hours followed by hot water for 1 hour. Simultaneously with washing the tank and cargo lines, steam out the vent line system and the heating coils if used for steam heating. Fresh water rinse the tank. Steam the tank and simultaneously strip out the condensate. Steam out the cargo line system. Ventilate, eject and dry the tank.

3. 4. 5. 6.

7.7.2

SLOP DISPOSAL AND ARRANGEMENT

The slops are to be disposed according to; 1. 2. Regulations for control of pollution by noxious liquid substance in bulk, IMO, MARPOL Annex II and, When it is necessary to disposal slops to shore reception facilities, the ship must report estimateed quantity to the ship operator and the local agent. Before mixing compatible slop residues or slops and cleaning agents consult the local agent.

7.8.1 1.

DUPONT REQUIREMENTS

Maintenance of nitrogen pad: Should pressure fall below 0.1 atmosphere (1.5 psig) in the tank void space, nitrogen should be added to raise pressure to 0.2 atmosphere (2.9 psig). Heating procedure: During the voyage the temperature of the cargo is to be monitored regularly. When the temperature reaches 28 C, please apply heat gradually using hot water until the temperature of the cargo reaches 33 C. gradual heating is imperative. Prior to discharge, gradually heat the cargo until it is 40 C. heating the cargo should be done at a rate that allows only 1 C rise every 2 hours. Oxygen Contamination: Oxygen content in void spaces should be measured every 24 hours and recorded on the HMD Cargo record sheet Should oxygen content of greater than 0.03% be observed, nitrogen should be added to the void space until a reading of less than 0.03% is obtained. Tanks to remain secure: All hatches and other openings into the tank(s) are to remain closed during transit. Customer or assigned surveyor will sample cargo at discharge port. HMD Cargo record sheet: Entry onto subject sheets must be made at four hour intervals showing date, hour, cargo temperature, pressure of nitrogen pad and any related comments. Special notations should be made if nitrogen is added to pad. These sheets are to be given to the surveyor at the discharge port. Neoprene seals may be required for butterworth hatches, check with ship operator before loading.

2.

3.

4.

5.

6.

7.8.2

INFORMATION SUPPORT

1.

The local area office (SPTI Houston) may submit additional information regarding HMD handling.

ISOCYANATES (MDI, PAPI, TDI)

8.1.1

PRODUCT CHARACTERISTIC- MDI

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for MDI (Diphenylmethane diisocyanate) must be posted and observed. 1. Common synonyms 4,4-Diisocyanodiphenylmethane; 4,4-Diphenylmethane diisocyanate; Diphenylmethane-4,4-Diisocyanate; MDI; Methylene bis(4-phenyl isocyanate); Methylene bispheylisocyanate. (OCNC H ) CH
6 4 2 2

2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.0) 14. Solution in water

Color is light yellow Slight musty odor. 1.19 @ 25 C Isocyanate DMP 392 C (Decomposes) 37C Very Low Very Low Very Low 8.5 Negligible; reacts slowly.

8.1.2 1. Status

FIRE & EXPLOSION HAZARD- MDI Combustible liquid.

2. General

Light yellow solid. Flammable at high temperatures. Toxic vapors of carbon monoxide, oxides of nitrogen, hydrogen cyanide is generated when heated. Fire may cause polymerization and decomposition leading to violent rupture of containers or tanks. 190 C Unavailable. 240 C Water spray, dry chemical, CO2. Follow SPTI contingency plan. Wear respiratory protection and full protective clothing including rubber boots. Cool exposed tanks with water. Do not allow water to enter a tank of MDI.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

8.1.3

HEALTH HAZARD- MDI Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate of high vapor concentrations. Chemicals that cause smarting of the skin and first degree burns on long exposure. Severely hazardous chemical. Usually having threshold limits below 10 ppm. Unavailable. 0.01 ppm 0.005 ppm Vapor is strong irritant to eyes and throat; can cause eyes and lung injury. Cannot be tolerated even at low concentrations. Watering and reddening of eyes, diarrhea, and loss of weight. Breathlessness, chest discomfort, and reduced pulmonary function. Animal tests have shown slight eye damage in 50% solution; oral lethal dose is in excess of 21.6g/kg of body weight; no primary skin irritation; no deaths by inhalation in 5-6hours. Remove the victim to fresh air. If breathing stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and flush affected areas with water for 15 minutes. Get medical attention. If patient is unconscious, administer vapor of amyl nitrite. Brake an amyl nitrite ampule in a cloth and hold it lightly under the nose of the victim, but away from the person giving first aid, for about 15 seconds. Repeat five times at 15 seconds intervals. Refer to the IMO Medical first aid guide (MFAG).

1. Irritating vapor 2. Irritation from liquid

3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms 9. Short exposure tolerance

10. Exposure procedures

11. Medical management

8.1.4 1. Stability

REACTIVITY INFORMATION- MDI The product must be blanketed with dry nitrogen; unstable in traces of moisture, slowly forming carbon dioxide gas. Prevent direct contact with wood. Group 12. See also exception to the chart.

2. Material compatibility 3. USCG compatibility 8.1.5

SPILL OR LEAK PROCEDURE- MDI Wear rubber gloves, face shield, breathing apparatus, protective clothing. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Secure ignition sources. Spray area with a neutralizing agent. Remove polymer/sediment into suitable containers for disposal.

1. Personnel protection 2. Contingency plan 3. Leak combat

8.1.6

PRODUCT CHARACTERISTIC- PAPI

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for PIPA(Polymethylene polyphenly isocyanate) must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.0) 14. Solution in water Polymethylene polyphenyl isocyanate; PAPI. C H ON
23 15 3 3

Dark brown liquid. No appreciable odor. 1.2 Isocyanates PPI 230 C Unavailable 0.00016 Very Low Very Low 8.6 Reacts with water and form solid polymer.

8.1.7 1. Status 2. General

FIRE & EXPLOSION HAZARD- PAPI Combustible liquid. Minor to moderate fire risk due to high flash point somewhat selfextinguishing as CO2 is given off. 281C Unavailable. Unavailable. Confined ares-CO2; self extinguishing. Follow SPTI contingency plan. Wear respiratory protection and full protective clothing including rubber boots. The product reacts with water to evolve CO2 and form solid polymer. Do not allow water to enter a tank of PAPI.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

8.1.8

HEALTH HAZARD-PAPI Exposures to high concentrations of isocyanate vapors can lead to formation of solid crystals in the eye fluid causing mechanical eye irritation of the eye hours after exposure. Isocyanates reacts with skin protein tissue moisture. If not promptly, liquid spilled on the skin can cause reddening, swelling and blistering of the exposed area. Repeated skin contact can cause skin sensitization in humans and should be avoided. Inhalation is the biggest health risk with isocyanatees. Inhaled vapors can produce severe irritation of the mucous membranes in the respiratory tract, i.e., the nose, throat and lungs. 0.4 ppm Unavailable 0.01 ppm not

1. Irritating vapor

2. Irritation from liquid

3. Chemical poisons

4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA

7. General Will discolors skin to brown color, reacting slowly and painlessly if promptly removed. Additives used are extremely toxic. 8. Symptoms 9. Short exposure tolerance Labored breathing, watering of eyes. Animal tests shown inhalation of 2.2 ppm were fatal to 4 of 6 rats. No toxic effects were observed on skin contact; eye distress was temporary. Remove the victim to fresh air. Administer oxygen if breathing is labored. Flush skin with water after removing contaminated clothing. Wash eye with water for at least 15 minutes. Ingestion induce vomiting 3 times; follow with 1/2 liter of milk and cathartic. Get medical help. Refer to the IMO Medical first aid guide (MFAG).

10. Exposure procedures

11. Medical management

8.1.9 1. Stability

REACTIVITY INFORMATION- PAPI Stable. Heat, water, and acids will react to evolve CO2. Not corrosive to mild steel however, aluminum cannot be used. Group 12. See also exception to the chart.

2. Material compatibility 3. USCG compatibility

8.1.10 SPILL OR LEAK PROCEDURE 1. Personnel protection 2. Contingency plan 3. Leak combat Wear rubber gloves, face shield, breathing apparatus, protective clothing. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Secure ignition sources. Spray area with a neutralizing agent. Spray area with neutralizing agent. Remove polymer/sediment into suitable containers for disposal.

4. Spill combat

8.1.11 PRODUCT CHARACTERISTIC- TDI Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for TDI (Toluene diisocyanate) must be posted and observed. 1. Common synonyms Benzene, 1,3-diisocyanatomethyl-; 2,4-Diisocyannatotoluene, TDI, 2,4-Toluene diisocyanate, 2,4-Toluene diisocyanate, m,Tolylene diisocyanate. H CC H (NCO)
3 6 3 2

2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point

Clear, faint yellow liquid Strong pungent odor. 1.21 Aromatic Isocyanate TDI 251C 19 C

10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia)

Very Low Very Low Very Low

13. Vapor density (air=1.0) 14. Solution in water

6.0 Reacts with waters.

8.1.12 FIRE & EXPLOSION HAZARD- TDI 1. Status 2. General 3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures Combustible liquid. Highly toxic nitrogen dioxide gas is produced when this product burns. 132 C 0.9 to 9.5%. Above 150 C CO2, dry chemical, water fog. Follow SPTI contingency plan. Wear full body and respiratory protection r. Do not allow water to enter a tank of MDI.

8.1.13 HEALTH HAZARD- TDI 1. Irritating vapor Moderate irritating volatile chemicals, such that personnel will not usually tolerate moderate of high vapor concentrations. fairly severe skin irritants, usually causing pain and second degree burn after a few minutes contact. Severely hazardous chemical. Usually having threshold limits below 10 ppm. 0.4. 0.005 ppm 0.005 ppm Suspected carcinogen. Liquid extremely harmful by skin absorption. apor inhalation severely irritating to nose and throat. Repeated exposure to low concentration can lead to respiratory problems and evere dermatitis. Burning at the site of contact. Vapor inhalation causes intense irritation of nose and throat. Inhalation can also cause asthma like symptoms, which may not appear for several hours after exposure. 0.5 ppm are irritating to nose and throat for brief exposre. Ingestion: do not introduce vomiting: Remove the victim to fresh air. If breathing stops, apply artificial respiration. Skin or eye contact immediately flush affected parts gently with water while removing contaminated clothing. Continue to flush for 15 minutes

2. Irritation from liquid 3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General

8. Symptoms

9. Short exposure tolerance 10. Exposure procedures

seconds. 11. Medical management

If patient is unconscious, administer vapor of amyl nitrite. Brake an amyl nitrite ampule in a cloth and hold it lightly under then nose of the victim, but away from the person giving first aid, for about 15 Repeat five times at 15 seconds intervals. Refer to the IMO Medical first aid guide (MFAG).

8.1.14 REACTIVITY INFORMATION- TDI 1. Stability The product will react with water and even moisture in the air in access of 100 ppm, evolving CO2 and heat. Can react violently with amines, alcohol and acids. Stainless steel, nickel and aluminum are satisfactory construction materials. Avoid copper and copper alloys. Mild steel may be used if it is clean and entirely free of rust and moisture. Group 12. See also exception to the chart.

2. Material compatibility

3. USCG compatibility

8.1.15 SPILL OR LEAK PROCEDURE- TDI 1. Personnel protection Wear rubber gloves, face shield, breathing apparatus, protective clothing. Avoid contact with liquid. Keep unprotected personnel away from spill area. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Secure ignition sources. Spray area with a neutralizing agent. Remove polymer/sediment into suitable containers for disposal. Wash the site with detergent solution.

2. Contingency plan 3. Leak combat

8.2.1

CODES MINIMUM REQUIREMENTS- MDI

MDI is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection 2489 (B) under further evaluation Safety and pollution hazards. 2. Integral gravity tank. Controlled venting. Dry No Special requirement Closed. Toxic Vapor.

Fire protection Material of construction Special requirement

Alcohol resistant foam, regular foam, water spray (not into closed tanks), dry chemical. Aluminum, copper and alloys of either should not be used. See IBC code Chapter 15,12, 15.16.2, 15.17, 15.19.6, 162.6, 16.2.9, 16A.2.2, and BCH Code, Chapter IV, 4.9, 4.12.5, 4.13.1, 4.14.1,4.15.2, 5.2.5, 5.2.8.1, 5A.2.2 Individual unit not required for emergency escape purpose.

Respiratory and eye protection

8.2.2

CODES MINIMUM REQUIREMENTS- PAPI

PAPI is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction Special requirement Respiratory and eye protection 2206(I) 2207 D S 2. Integral gravity tank. Controlled venting. Dry No Special requirements Closed. Toxic Vapor. Alcohol resistant foam or multi-purpose foam. Aluminum, copper and alloys of either should not be used. See IBC code Chapter 15,12, 15.16,2, 15.19.6, and the BCH Code, 4.9, 4.12.5, 4.14.1, 4.15.2 Individual unit required for emergency escape purpose.

8.2.1

CODES MINIMUM REQUIREMENTS- TDI

TDI is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type 2078 C Safety and pollution hazards. 2.

Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection

Integral gravity tank. Closed venting. Dry No special requirement, standard requirements Closed Flammable and toxic vapors Alcohol resistant foam. Regular foam, water spray (not into a closed tank), dry chemical. Copper, copper bearing- alloys should not be used. See IBC code Chapter 15,12,.1516.2,15.17, 15.19,16.2.6,16.2.9 and BCH Code, Chapter 4.9, 4.12.4,4.13.1,4.14,4.15.2,4.17,5.2.8 Individual unit required for emergency escape purpose.

Material of construction Special requirement Respiratory and eye protection

8.3.1

EQUIPMENT PLANNING

1. Ensure that sufficient and suitable hoses for vapor return are onboard. 2. Ensure that sufficient nitrogen hoses are onboard 3. Ensure that closed sampling devices is onboard. 4. Ensure to have onboard sufficient quantity of Diiso Octyl Phalate (DOP) to fill the cargo pump cofferdam before the loading. 5. If the permanent cargo line is not used for loading/discharging ensure to have sufficient suitable cargo hoses, valves for the hose connections, any stainless steel bends for cargo handling and cleaning including drip pans for the connection/disconnection points. The rigging must have connections for line blowing. 6. If gas oil is used for cleaning, the ship Operator will arrange gas oil supply with a moisture specification for line blowing. 7. For TDI, gas oil is to be used as the tank cleaning medium (recirculation via fixed tank cleaning machines in an inerted tank atmosphere) ensure that the product is received at loading or at discharge port. The quantity should be approximately 10 M3 per tank, depending on the tank size. 8. If a chlorinated solvent is used as the tank-cleaning medium (when portable tank cleaning machines have to be used for tank cleaning or when cleaning Isocyanate other than TDI) ensure that the product is received before discharging the cargo. The quantity should be approximately 10-15MT per tank, depending on the tank size. The moisture specifications of chlorinated solvent should be less than 400 ppm. 9. For line cleaning after loading (regardless the cleaning medium selected for the tank cleaning), ensure to order sufficient quantity of toluene (drums). To calculate the quantity to order, calculate the capacity of the cargo transfer line system including the crossover. 10. For personal protection and spill neutralization, ensure to have onboard 2 drums (2 x 200 liters) of Isopropyl Alcohol (IPA), before the loading. 11. For personnel protection and spill neutralization, ensure to have onboard 1 drum (200 Liter) of Aqua Ammonia, before loading.

12. For personal protection (decontamination of protective gear), ensure to have onboard two spray cans (garden type can of approximately 20 liters capacity), before the loading. 13. For personal protection including cleaning of personal protective gear ensures to have 1% Tincture of Green Soap. 14. Ensure of have valid vapor test tubes and medications according to regulations (IMO MFAG). 15. Ensure to have onboard the equipment for maintaining and monitoring the nitrogen blanket.

16. As steam or hot water cannot be used as the heating medium for isocyanates, figure out and arrange for suitable heating capability. This might be thermal oil or adjacent compatible cargoes. Prevent stowage of adjacent :cold cargoes that may cause solidification of Isocyanate on the bulkheads/tank top.

8.4.1

PREPARATION BEFORE LOADING

1. CHECK WITH THE Ship Operator if the particular customer requires tank cleanliness beyond water white standard. 2. Heating coils to be tested according to the procedure in the Tank cleaning Manual. Finally (when thermal oil is not used as heating medium), blow the heating coils with nitrogen and blank them off. 3. Cargo pump(s) cofferdam to be purged with nitrogen and filled with Diiso Octyl Pthalate (DOP). 4. As the cargo is reaching with water/moisture it is extremely important to have the tank, cargo line system, tank venting system, fixed tank cleaning machines, level gauging systems (coatings & floats), level alarm systems (tube & floats), any drain cocks or drain plugs in valves and line systems completely free water before commencement of nitrogen purging. 5. The cargo should not be stowed adjacent to tanks containing water. 6. Tank(s) to be fitted/equipped with tank pressure gauge(s)/sensors according to requirements in the cargo handling Manual. 7. Prepare for N2 purging and blanketing. Sufficient high pressure hoses and regulating valves must be onboard and pre-rigged. 8. Prepare for vapor return to shore. 9. Install the specially sampling device (if required). Sampling is often done by cargo surveyor at the pumpstack. 10. For nitrogen purging, follow the procedure N2 purging lines and tanks contained in the Cargo handling Manual. 11. Tank(s) to be battened down and pressure tested according to the procedure; Pressure testing cargo tanks with air/N2 contained in the Cargo handling manual. Leaking packings, etc., must be renewed. Ensure that the P/V valve(s) operate properly. 12. If not loading through the ships manifold, install an SS valve with the blind flange on the pumpstack fitted with N2 connection. 13. If loading through hoses Hostaflon ot Chemflex hoses should be used. Do not used stainless steel hoses. There should be a double valve at the pumpstack. There should be a valve at any Y pieces so each section can be blown individually. There should be a valve between the shoreline valve and the ships portable line.

A valve must be fitted at each outlet in use so each line can be blown to the tank individually. If this method is used then the ship staff must be completely satisfied with the integrity of all valves on the system. At the end of the loading it must be ensured that no trace of product is left in the lines or crossover.

8.4.2

FINAL LOAD PREPARATION

1. Follow procedure N2 purging of lines and tanks contained in the Cargo Handling Manual. Purging will continue until the dew point in the tank has been reached as governed by regulation contained in the IBC/BCH code (minus 40 C). Before commencement if loading, following must be arranged and observed; 2. The affected loading area must be roped off. 3. All crew onboard must be notified of the danger and hose not directly involved in the loading instructed to stay away from the loading area. 4. Communication links between ship/shore and onboard must be tested and agreed upon. 5. Safety showers and eyes washes must be tested and under pressure. 6. One drum (55 gal.) of the neutralizer (50% IPA, 10% Aqua Ammonia, and 40% water) must be placed close to the loading area ready with barrel pump and spray hose of sufficient length to cover the entire loading area. 7. Two spray cans of neutralizer for personal decontamination (99% IPA and 1% tincture of green soap) must be readily available. 8. Isocaynate vapor test (Draeger) tubes must be available and used on and around the loading area during the loading.

8.4.3 1. 2.

AFTER LOADING

When sampling, upon completion of loading, use the portable closed sampling device. When loading is completed and cargo samples taken, the line must be blown with nitrogen from shore for at least 15 minutes. For final line clearing (ships responsibility) follow the line clearing procedure in the Cargo handling Manual. If loading more than one tank, be sure that each line is blown independently, also for 15 minutes. If any spill occurs during hose disconnection, spray the area immediately with the neutralizer. When the line clearing has completed (all valves and flanges closed) secure the pumpstack valve in closed position with a rope or wire. Without allowing air/moisture into the cargo line, immediately after line clearing, fill the cargo line(from the pumpstack to the manifold headers) with toluene. Leave the toluene in the line for 3 days. During the 3 days period, operate the valve in the manifold crossover (without removing the end flanges) to dissolve trapped Isocyanate residues. Before draining the cargo line, operate all drain cocks while flushing some toluene into a bucket. Upon completion of draining the cargo line, thoroughly blow the cargo line with nitrogen without allowing air/moisture into the line system. Secure the line, unsecured the pump stack valve.

3. 4. 5.

6.

7.

8.5.1

MONITOR & RECORDING

1.

The N2 blanketing , and cargo temperatures must be monitored daily (08:00) and the results recorded in its respective logs (Nitrogen blanket Log & Cargo Temperature Log) contained in SNSO binder #8 or the specific form received by surveyor at load port.

8.5.2

MDI

1. Maintain the cargo temperature between 35 C and 40 C. do not allow the temperature to go below 32 C or above 43 C. 2. Maintain N2 blanket according to the procedure: Maintenance of N2 blanket during the voyage, N2 blanket with positive pressure contained in the Cargo Handling manual. 3. Due to variation in product specification, ensure to verify and follow specific instruction received at the load port. 8.5.3 1. PAPI

Maintain the cargo temperature between 24 C and 29 C. do not allow the temperature to go below 18 C or above 32 C. Maintain N2 blanket according to the procedure: Maintenance of N2 blanket during the voyage N2 blanket with positive pressure contained in the cargo Handling Manual. Due to variation in product specification, ensure to verify and follow specific instruction received at the load port.

2.

3.

8.5.4 1.

TDI

Maintain the cargo temperature between 23 C and 32 C. do not allow the temperature to go below 21 C or above 35 C. Maintain N2 blanket according to the procedure: Maintenance of N2 blanket during the voyage, n2 blanket with positive pressure contained in the Cargo Handling Manual.

2.

8.6.1 1. 2.

DISCHARGING

The same safety precautions must be taken as during loading. When discharging, the tank must be inerted with N2 from shore during the entire operation (Via the vapor return line). Follow the procedure Nitrogen displacement during discharging contained in the Cargo handling Manual. For efficient during disconnecting of the shore hose occurs, spray the area immediately with the neutralizer.

3.

8.7.1 1. 2. 3. 4.

CLEANING FROM TDI USING GAS OIL (USED WITH TDI ONLY)

This cleaning procedure may only be used in cargo tanks that are fitted with fixed tank cleaning machines. Ensure that the gas oil is handled/stored under dry conditions (e.g dry lines and storage tank). To remove possible water in the gas oil, it is advisable to flush some product into a drum before entering the tank to be cleaned. To obtain good cleaning results, the gas oil may have to be pre-heated (above the freezing point of the TDI but always remain below its own point of 38 C).

5. 6.

Before adding the gas oil, the tank must be tested for oxygen content; one meter below the deck level and at the middle of the tank height. If the measured oxygen level exceed 8% then the tank must be purged with nitrogen to below 8% prior to proceeding further (If nitrogen is unavailable locally then the tank should remain closed until sufficient nitrogen can be supplied). Once the safe oxygen level is measured (below 8%), a sufficient quantity of gas oil (Usually 5-15 M3 depending the actual tank size) is added to the tank to be recirculated. Prior to commencing recirculation, supply and maintain a positive N2 pressure throughout the cleaning operation (Closely monitor the positive). When recirculating, via the pump stack or manifold, all fixed tank cleaning machines must be used.

7. 8.

9.

10. Recirculate the gas oil for a minimum of 2 hours. 11. Vent line, cargo line, drop line and stripping line must also be flushed with gas oil as part of the cleaning procedure. 12. Upon completion of recirculation the tank may be electrically charged and must therefore be allowed to sit for a minimum of 30 minutes before transferring the gas oil. 13. The gas oil mixture may be reused in additional tanks by repeating the above procedure (four parts of gas oil are required to dissolve one part of TDI.) 8.7.2 1. CLEANING FROM ISOCYANATES USING CHLORINATED SOLVENTS

This cleaning procedure is used when cleaning form Isocyanates such as MDI, PAPI and TDI with exception as mentioned under 8.7.1 (for TDI when using gas oil and fixed tank cleaning machines). Ensure that the tank cleaning is resistant to the particular chlorinated solvent being used (Some coatings e.g. Phenoline and Devchem 253 are not resistant to MEC). Ensure that the selected chlorinated solvent is handled/stored under dry conditions (e.g. dry lines and storage tank.) The chlorinated solvent should be heated to a point above the melting point of the Isocyanate to be cleaned. Ensure that the temperature of the chlorinated solvent is kept below the boiling point of the selected chlorinated solvent. Transfer a sufficient quantity (approximately 10 M3) into the tank to be recirculated. Prior to placing the portable cleaning machines, supply and maintain a positive N2 pressure throughout the cleaning operation (Closely monitor the pressure). When recirculating, via the pump stack or manifold, all tank cleaning machines (as fitted or each section) must be used. Recirculate the selected chlorinated solvent for a minimum of 2 hours. Vent line, cargo line, drop line and stripping line must also be flushed with chlorinated solvent as part of the cleaning procedure.

2. 3. 4.

5. 6.

7. 8. 9.

10. Chlorinated solvent may be reused in additional tanks by repeating the above procedure.

8.7.3

SUCCESSIVE CLEANING

1.

Upon completion of the cleaning procedures described under 8.7. and 8.7.2 the cleaning should continue as described in the Tank cleaning manual for respective Gas oil and chlorinated solvent as last product in the tank and line systems.

8.7.4

SLOP DISPOSAL AND ARRANGEMENTS

The slops are to be disposed according to: 1. Regulations for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II and, 2. When it is necessary to dispose slops to shore reception facilities, the ship must report estimated quantities to the ship operator and the local agent. Before mixing compatible slop residues or slops and cleaning agents consult the local agent.

8.7.5

DISPOSAL OF GAS OIL/TDI MIXTURE

1. Arrangements for disposal will be made by either operations or the local area office or agent. This will be done either immediately after the cleaning process or at a subsequent port. If arrangements are made for a subsequent port the gas oil/TDI mixture may either be kept in the same tank or transferred to another tank onboard. 2. The gas oil/TDI mixture should not be combined with any other slops onboard as this will affect disposal possibilities and cost. Additionally, the gas oil/TDI mixture may not be used for fuel and cannot be incinerated onboard. 3. The solubility of TDI in gas oil is very similar to that of chlorinated solvents. Once the gas oil has been recirculated the TDI will be completed dissolved and moisture exposure should be not have an effect on the gas oil/TDI mixture.

NATURAL LATEX

9.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Natural Latex must be posted and observed. 1. Common synonyms 2. Formula A white tacky, aqueous suspension of a hydrocarbon polymer occurring naturally in some species of trees. The natural latex shipped consists of 60%-70% latex and 30-40% fresh water. It also contains 1%-2% ammonia that is used to control bacteria and help preventing coagulation. White tacky liquid Dominating ammonia Odor form the additive. 0.945(centrifuged) 0.9378 (creamed) Hevea brazilensis tree. Not listed Unavailable Unavailable Very Low Very Low Very Low Unavailable Complete (as liquid)

3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water

9.1.2

FIRE & EXPLOSION HAZARD

1. Status 2. General

N/A Not flammable unless coagulated. Heat may coagulated the latex and form sticky plastic that may burn. Unavailable Unavailable Unavailable Water spray. Follow SPTI contingency plan. Wear respiratory protection as hazardous gases may develop. Cool exposed tanks with water.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

9.1.3

HEALTH HAZARD Due to the ammonia additive, its vapor may cause moderate irritation, such that personnel will find high concentration unpleasant. This effect is temporary. Due to the low concentration of ammonia additive, the liquid is practically harmfulness to the skin. Information unavailable. Unavailable Unavailable Unavailable Due to the ammonia additive, the vapor may cause irritation. Irritation of eyes. Irritation of eyes due to the ammonia additive. Remove the victim to fresh air. Refer to the IMO Medical first aid guide (MFAG).

1. Irritating vapor

2. Irritation from liquid 3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms 9. Short exposure tolerance 10. Exposure procedures 11. Medical management

9.1.4 1. Stability

REACTIVITY INFORMATION No reaction with fresh water. Coagulation may develop when mixed with salt water. Heat will coagulate the latex. No reaction with common materials. Group 43.

2. Material compatibility 3. USCG compatibility

9.1.5

SPILL OR LEAK PROCEDURE Wear protective clothing. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Wash contaminated area with water. On completion of containing the liquid, wash the area with water.

1. Personnel protection 2. Contingency plan 3. Leak combat

9.2.1

SAFETY PRECAUTION

Latex is not considered to come within th scope of the IBC/BCH Code. Latex is listed in the IBC/BCH Code, Chapter 18, respective Chapter VII. Latex was evaluated and found to fall outside the categories A,B,C or D. although Latex falls ouside the scope of the IBC/BCH Code some safety precautions may be needed for the safe transportation: Pollution category : D

9.3.1 1.

EQUIPMENT PLANNING

Ensure to have the portable latex pump and associated hoses available before commencement of discharging.

9.3.2 1. 2.

CARGO PUMP MODIFICATION

Generally it is necessary to make modifications to the main cargo pumps to make them suitable to pump natural latex. A natural latex pump modification consist of : 1) Open finger impeller installation. The impeller modification must be made correctly. Attention must be given to proper alignment and clearance. The pump must be tested after modification.

2) 3.

If cargo pump is not to be modified then the pump needs to be blanked off at the impeller end ot removed form tank and stored for voyage prior to loading latex. The cargo will then be discharged with portable pump(s) only.

9.4.1 1.

PRE-LOAD ARRANGEMENT

In all ports of loading, plan to load via a portable dropline supplied by the charterer. The dropline will be lowered through a deck opening. The outlet of the dropline must be submerged into the cargo during the loading to prevent foaming. Free drop of the latex will create foaming.

9.4.2 1.

CLEANLINESS

TANK SHOULD BE PREPARED TO Visible water white standard, as putline =ed in the Tank cleaning manual.

9.4.3

STOWAGE

1. The cargo quantity must be adjusted to fill the designated tank to minimum ullage. The coefficient of expansion is negligible, therefore, we can load to 99% capacity. Latex will coagulate in the void space between the tank overhead and level of the liquid. Therefore, it is necessary that this space be minimized.

9.4.4

WAXING

1. If you intend to present tanks in which the coating is not completely sound, i.e. rust spots are apparent, you will have to arrange to have those rust spots painted with hot paraffin wax. The wax will have to be melted and hand painted over the rust spots with brushes. The drying time is only a few minutes. 2. Epoxy coated tanks may be completely coated/sprayed with hot paraffin wax. Ship operators will advise what arrangements have been made regarding waxing tanks.

9.4.5

HEATING COILS

1. It may at time be necessary to have the tanks fumigated prior to loading. The loading surveyor will advise same after tank inspection. This applies only to coated tanks, as stainless steel does not require fumigation. The gas used in fumigation is usually formaldehyde. It takes about one hour to fumigate a tank. This entire operation will be accomplished by charterers shore personnel.

9.5.1 1. 2.

ADJACENT TEMPERATURE

Since the latex coagulates any heat adjacent e.g. cleaning, steaming, heated cargo must be avoided. Under certain circumstances low heat cargoes may be stowed adjacent but this must be discussed with the ship operator on a case by case basis.

9.6.1

PORTABLE PUMP USED FOR N30 CLASS SHIPS

1. The above mentioned class of ship are fitted with a portable Framo LN 150 pump which are fitted with a special latex impeller. Another portable pump will be supplied for standard purposes.

9.6.2

PORTABLE PUMP USED FOR ALL OTHER CLASSES

1. Ship will be supplied with portable Framo or Marflex latex pumps for discharge. 2. Ships with modified cargo pump should discharge with cargo pump via pump stack connection. A portable Framo or Marflex latex pump will be supplied for standby purposes.

9.7.1

CLEANING PROCEDURES

1. If the cargo has been properly carried, with little or no heat adjacent and properly stowed, with minimum ullage, the cleaning operation is fairly simple and effective, though it will be time consuming. Coagulation of the clingage on the bulkhead and any internal members is directly affected by two factors.: 1. Heat. 2. Amount of time to which the discharged tank is exposed to air. It is, therefore, imperative that prior to the completion of discharge, 1. 2. The required number of butterworth machines are lowered into the tank (or laid out on deck) connected and ready for use, and One crewmember is stationed at the tank hatch with a freshwater hose.

As soon as the tank is empty, certificate is approved by the surveyor, immediately fill the pumpwell with

fresh water. This will prevent the residual latex from coagulating around the pump due to the high heat of the pump. Simultaneously, commence Butterworthing with cold fresh water for one hour (ensure to have sufficient fresh water on board). The tank should then be drained via the cargo pump. Once the tank is confirmed safe for entry, crewmember should be sent into the tank to remove any coagulated latex floating around the bottom. Any sheets of latex remaining on the bulkhead should be peeled off. If necessary, carry out secondary cleaning with chlorinated solvent as per procedure outlined in the Tank cleaning manual.

9.8.1 1. 2.

LATEX PUMPS

For modification to latex impeller refer to the pump manufacturers instruction. For operation of portable latex pumps refer to the pump manufacturers instruction.

PHOSPHORIC ACID (75~85%/WET) 10.1.1 PRODUCT CHARACTERISTIC -PHOSPHORIC ACID (WET) Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master

should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Phosphoric Acid must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water Meta-phosphoric acid; ortho-phosphoric acid; meta-phosphoric acid; ortho-Phosphoric acid; White phosphoric acid. H PO
3 4

Clear, syrupy liquid. Practically odorless. 1.83(80%) Inorganic acid. PAC > 130 C 5 (80% concentration) Low Low Low 3.38 Complete

10.1.2 FIRE & EXPLOSION HAZARD -PHOSPHORIC ACID (WET) 1. Status 2. General Non-flammable. Phosphoric acid will not burn. It will react with many metals, giving off hydrogen gas that is highly flammable. If hydrogen is trapped in a confined space, it can form an explosive mixture with air. Non Flammable. Non Flammable. Non Flammable. Non Flammable. Follow SPTI contingency plan. Keep tank cool with water spray. Since toxic fumes of oxides of phosphorus are evolve when phosphoric acid is heated to decomposition, fire fighters should be provided with self contained breathing apparatus.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

10.1.3 HEALTH HAZARD -PHOSPHORIC ACID (WET)

1. Irritating vapor 2. Irritation from liquid

Non-irritating to eyes and throat. Fairly sever skin irritants, usually causing pain and second degree burns after a few minutes contact. Minimum hazard. Includes most chemicals having threshold limits above 500 ppm. None 1 mg/m3 1 mg/m3 Causes burns. Irritation of eyes of skin in contact with liquid. Burning of eyes. Unavailable. Skin contact: remove contaminated clothing and flush affected areas gently with large amount of water. Eye contact: immediately flush eyes gently with water, continue to flush for 15 minutes. Get medical attention. Refer to the IMO Medical first aid guide (MFAG).

3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms 9. Short exposure tolerance 10. Exposure procedures

11. Medical management

10.1.4 REACTIVITY INFORMATION -PHOSPHORIC ACID (WET) 1. Stability 2. Material compatibility 3. USCG compatibility Stable over a wide temperature range. Very corrosive to ordinary ferrous metals and alloys particularly at temperature above 82 C. Group 1. See also exceptions to the chart.

10.1.5 SPILL OR LEAK PROCEDURE - PHOSPHORIC ACID (WET) 1. Personnel protection Wear rubber gloves, protective clothing. Have body shield available. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Secure ignition sources. Flush contaminated area with large amounts of water.

2. Contingency plan 3. Leak combat

10.1.6 PRODUCT SAFETY INFORMATION -PHOSPHORIC ACID (WET) Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Phosphoric Acid must be posted and observed. For safety information be guided by the Phosphoric Acid (75-85%) safety Information.

10.1.7 PRODUCT SAFETY INFORMATION -PHOSPHORIC ACID (SUPER) Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Phosphoric Acid must be posted and observed. For safety information be guided by the Phosphoric Acid (75-85%) safety Information.

10.2.1 CODES MINIMUM REQUIREMENTS- PHOSPHORIC ACIDS Phosphoric Acid is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction Special requirement Respiratory and eye protection 1805 D Safety hazards. 3. Integral gravity tank. Open venting. No special requirement No special requirement Open No No. See special requirement. See IBC code 15,11.1 to 15.11.4,15.11.6 to 15.11,8, and BCH Code, Chapter 4.8.1 to 4.8.4, 4.8.6 to 4.8.8 Individual unit required for emergency escape purpose.

10.3.1

EQUIPMENT PLANNING

1. Ensure to have onboard sufficient acid resistant hoses for the cargo transfer. 2. Ensure to have onboard sufficient acid spray shields to cover flanges on manifold and hose connection according to IBC code 15.11.4 and BCH 4.8.4. 3. If it is excepted that the particular acid contents sediments ensure to have onboard sufficient portable acid resistant equipment for recirculation of acid tanks for discharge operation. 4. High wear and tear on pumps cargo seals form acid containing sediments can be excepted. Cargo pump

seal (cargo seal & oil seal) integrity should carefully be examined prior to loading.

10.4.1

PHOSPHORIC ACIDS

1. Phosphoric acids are shipped as different grades which may vary on purity and acid concentration (e.g. food grade, wet processed fertilizer grade, commercial, etc.) For proper handling ensure the grade is known, and that the specific information requested by the steel manufactory is obtained.

10.4.2

PURE PHOSPHORIC ACID

1. Since pure phosphoric acid (80% solution) is used as additives in food and beverages, a very high degree of tank cleanliness is necessary. Check with the Ship operator if a wall wash is required.

10.4.3

WET PROCESS PHOSPHORIC ACID

1. Almost all wet process phosphoric Acids contain solid particles that may form adherent despots. The steel surface of the tank top may be attacked during the voyage. Therefore, arrangement for circulate the liquid above the tank top should be prepared. 2. In some cases the cargo acid may be loaded at temperatures grater than ambient. Depending upon the origin this can have an adverse effect on the stainless steel. It is important the ship operator is consulted before loading any Phosphoric acid that is over 40 C. If the temperature of the acid is exceeding 50 C the cargo will normally not be loaded.

10.5.1

PURE PHOSPHORIC ACID

1. Pure Phosphoric Acid 80% freeze at 5 C and may therefore require heating in cold climate. Steam must not be used for heating as maximum allowable coil temperature is 90 C. Heating must be done with adjacent cargoes or by used of water or a thermal oil.

10.5.2

WET PHOSPHORIC ACID

1. The solids (impurities) in the WPA will quickly settle out and build up a thick heavy sediment layer on the tank top. This sediment layer, if left undisturbed could block the pump impeller and make pumping impossibly. To prevent pump blockage, it is necessary to blow the pumpstack with compressed air at least once a day. The pump should be run slowly, a few minutes to ensure that the impeller is operating freely.

10.5.3

SUPER PHOSPHORIC ACID

1. The SPA should be heated and kept at a temperature of 65 C. 2. Maximum temperature : 82 C. 3. Minimum temperature : 60 C 4. Excessive heat rapidly degrades the SPA 5. At temperatures below 60 C, the SPA becomes very viscous and un-pumpable. 6. Maximum allowable temperature on the heat media is 90 C.

10.5.4

ACID LEAK DETECTIVE

1.

Refer to the IBC Code 15.11.7, BCH Code 4.8.7 and follow SNSO procedure for routine leak detective of Acid into adjacent spaces.

10.6.1

CARGO LINE AND HOSE PRECAUTION

1. Because of the high gravity of Phosphoric acids, very high pump pressure may be experienced. In such cases care must be taken to quickly open or close valves in the pump system as this causes pressure surges that rupture lines or hoses.

10.6.2

SEDIMENTS

1. If the particular grade of Phosphoric acid contains sediments, recirculation of cargo via acid resistant hoses and portable machines may be necessary in order to remove/minimize the sediment remaining in tanks. The following method should be used: a. Rig portable equipment (acid resistant hoses and tank cleaning machines), from pumpstack to available tank openings. b. Discharge the small tanks first. c. Flush sediments out of the first empty tank by using good acid from another tank.

d. It may be necessary to position the machine (vertically & horizontally) to break down lumps of sediment. e. When the first tank has become sediment free refilled the same tank with good acid which is to be used when flushing the sediment from the last remaining tank.

10.7.1

WET PROCESS PHOSPHORIC ACID INFORMATION

1. The corrosion phenomena occurring in wet process phosphoric acid are very complex. This acid can therefore be regarded as the most difficult chemical that can be carried in stainless steel tanks. 2. A normal concentration of wet acid is 54%. A clean acid of this strength is not very corrosive to stainless steel. 3. The corrosion is affected by various impurities normally present in wet process acid.

10.7.2

WET PROCESS PHOSPHORIC ACID CLEANING

1. Preferably, fresh water should be used as cleaning medium but if not available large amounts of seawater must be used/added to the tank. 2. In addition to using all available tank cleaning machines put additional water into the tank using ballast pump. 3. Ensure the tank and its associated line system is cleaned until all deposits are washed out and a neutral pH value is obtained.

10.7.3

PHOSPHORIC ACID (75-85%) CLEANING

1. If sediment remains in the tank fresh water should preferably be used. If sufficient fresh water is not available the cleaning method described in 10.7.2 should be followed.

10.7.4

LINE/HOSE PRECAUTIONS

1. Just prior to stopping the cleaning of the tank ensure all line systems and hoses used are free from acid/acid residue. Acid/sea water mixture remaining in lines and stainless steel hoses will soon result in pittings.

10.7.5

SLOP DISPOSAL AND ARRANGEMENTS

The slops are to be disposed according to : Regulation for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II.

SULFURIC ACID 11.1.1 PRODUCT CHARACTERISTIC -SULFURIC ACID

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Sulfuric Acid must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) Battery acid, Chamber Acid; fertilizer acid; Oil of vitriol. H SO
2 4

Colorless to brown oil liquid. No odor unless hot. Then the odor is choking. 1.56 to 1.84 Inorganic acid. SFA 340 C 10 C Low

11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water

Low Low 3.4 Complete

11.1.2 FIRE & EXPLOSION HAZARD -SULFURIC ACID 1. Status 2. General Non-flammable. Sulfuric acid will not burn. It will react with many metals, giving off hydrogen gas that is highly flammable. If hydrogen is trapped in a confined space, it can form an explosive mixture with air. Non Flammable. Non Flammable. Non Flammable. Non Flammable. Follow SPTI contingency plan. Do not use water to put out fire if the water can get into concentrated Sulfuric acid. Use respiratory protection against fumes.

3. Flash point 4. Flammable limits 5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

11.1.3 HEALTH HAZARD -SULFURIC ACID 1. Irritating vapor 2. Irritation from liquid 3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General May cause moderate irritating. Unpleasant at high concentrations. Severe skin irritant, causing second and third degree burns after on short contact and very injurious to the eyes. Some hazard, typically having threshold limits of 100 to 500 ppm. Great then 1 mg/m3. 1 mg/m3 1 mg/m3 Liquid causes severe burns with destruction of tissue. Vapor is very irritating. The inhalation hazard is slight at ordinary temperatures. The skin on which acid is spilled may feel hot or it may string or itch. 10 mg/m3 for 5 minutes, 5 mg/m3 for 10 minutes, 2 mg/m3 for 30 minutes. Drench with water. Skin contact: remove contaminated clothing and flush affected areas gently with large amounts of water. Eye

8. Symptoms 9. Short exposure tolerance

10. Exposure procedures

contact: immediately flush eyes gently with water, continue to flush for 15 minutes. Get medical attention. 11. Medical management Refer to the IMO Medical first aid guide (MFAG).

11.1.4 REACTIVITY INFORMATION -SULFURIC ACID 1. Stability 2. Material compatibility 3. USCG compatibility Stable, but can react very easily with many other materials. Highly corrosive to most metals particularly at concentrations below 60 deg Be. May cause wood or cellulose to ignite. Group 2. See also exceptions to the chart.

11.1.5 SPILL OR LEAK PROCEDURE 1. Personnel protection 2. Contingency plan 3. Leak combat Wear rubber gloves, protective clothing. Have body shield available. Avoid contact with liquid. Follow SPTI contingency plan. If leak on cargo transfer system. Stop transfer and empty the line system. Secure ignition sources. Flush contaminated area with large amounts of water.

10.2.2 CODES MINIMUM REQUIREMENTS- SULFURIC ACIDS Sulfuric Acid is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction Special requirement Chapter 4.8, 4.15.2, 5.2.7, 5.2.8. 1830 C Pollution and safety hazards. 3. Integral gravity tank. Open venting. No special requirement No special requirement Open No No. See special requirement. See IBC code 15,11. to 15.16.2, 16.2.8 to 16.2.9, and BCH Code,

Respiratory and eye protection

Individual unit required for emergency escape purpose.

11.3.1

SPECIAL ARRANGEMENTS

Ensure to have onboard sufficient acid resistant hoses for the cargo transfer. Ensure to have onboard sufficient acid spray shield to cover flanges on manifold and hose connection according to IBC code 15.11.4 and BCH code 4.8.4

11.4.1

PRELOADING PRECAUTION

1. Sulfuric Acid is normally carried in stainless steel tanks with a minimum concentration of 90% and at temperatures not exceeding 35 C 2. Highly concentrated, sulfuric acid may be carried in mild steel tanks, but only after obtaining special permits from the class.

11.4.2

PREPARATIONS FOR LOADING

1. The tank must be cleaned to Visual water white standard as outlined in the Tank cleaning Manual. And free of any residues from previous cargoes, chlorides and any other foreign matters. 2. A thorough inspection of the tanks lower areas and tank-top must be carried out, with special emphasis on steel defect detection. Any suspected areas, and welding seams, must be dye and any other foreign matters. 3. Heating coils to be pressure-tested for leaks, blown empty and dried with nitrogen. The tank must be dry before loading is permitted. 4. The surrounding cofferdams and double bottoms must be empty and dry.

11.5.1 1.

ACID LEAK DETECTION

Refer to the IBC Code15.11.7 BCH code 4.8.7 and follow the SNSO procedure for routine leak detection of Acid into adjacent spaces.

11.6.1

DISCHARGING

Because of the high gravity of Sulfuric Acid, very high pump pressure may be experienced. In such cases care must be taken not to quickly open or close valves in the pump system as this causes pressure surges that may rupture lines ir hoses.

11.7.1

CLEANING PRECAUTION

1. Sulfuric Acid in 30-70% concentration is non-oxidizing and attacks the steel rapidly, particularly at elevated temperatures. 2. When concentrated Sulfuric Acid is diluted the reaction is exothermic and the temperature of acid will rapidly increase. If the tank is cleaned with inadequate quantities of water, the acid will become hot, as it is diluted, and rapid attack will occur on the stainless steel until sufficient water is introduced. Large quantities (preferably fresh water) must be put into the tank to rapidly pass the dangerous concentration range and heat increase. Preferably if stainless steel hoses were used on the manifold for discharge should be replaced with non-stainless acid resistance hoses before the cleaning operation starts.

11.7.2

CLEANING

1. Preferably, fresh water should be used as cleaning medium but if not available large amounts of seawater must be used/added to the tank. Cleaning must start as soon as possible after discharge, but do not commence cleaning unless slop disposal is available, either to shore or as per MARPOL regulations. 2. Sulfuric acid slops should normally not be kept on board as diluted acid slops are very aggressive to all metals. In case where acid slop must be retained onboard, consult the ship operator for advice. 3. Cleaning with water (adding water to acid ) will generate much heat with release of Hydrogen gas. 4. Cleaning must be started with as much water as possible introduced into tank form the begging. 5. Continuously drain the tank, do not allow acid/water mixture to collect in the tank. Do not stop cleaning before a litmus paper check of the drain water reads neutral. 6. If seawater was used, the tank must be immediately desalted with fresh water or di-water. 7. Ensure that the line systems, including the vent system, are cleaned out and free of any acid remains. 8. Flush out the heating coils with freshwater and check for acidity using litmus paper.

11.7.3 1.

SLOP DISPOSAL AND ARRANGEMENTS

The slops are to be disposed according to : Regulations for control of pollution by noxious liquid substances in bulk IMO, MARPOL Annex II.

TALL OIL (CRUDE)

12.1.1

PRODUCT CHARACTERISTIC

Product safety data sheets may be available from various sources. For safety preparation, until the specific product safety data sheet can be obtained, the below information, mainly selected from the chemical data guide for bulk shipment by water (U.S. DOT), should be used. In reference to the IBC/BCH code (respective 16.2/5.2) the Master should request the specific product safety data sheet before commencement of loading. The safety data sheet posted must be in a language understood by ships officers and crew (English). A product safety data sheet for Tall Oil must be posted and observed. 1. Common synonyms 2. Formula 3. Appearance 4. Odor 5. Specific gravity 6. Chemical family 7. CHRIS code 8. Boiling Point 9. Freezing point 10. Vapor pressure 20 C (mmHg) 11. Raid vapor pressure (psia) 12. Vapor pressure 46C (psia) 13. Vapor density (air=1.o) 14. Solution in water Liquid rosin; Talleol; Tallol. Mixture of rosin acids. Yellow oil liquid. Acid odor. 0.95 to 1.0 OTL Very high 1.5 0.1 0.15 Not pertinent Negligible

12.1.2 1. Status 2. General 3. Flash point

FIRE & EXPLOSION HAZARD Combustible liquids. Slight fire hazard when exposed to heat or flame. 193 C Unavailable

4. Flammable limits

5. Autoignition temperature 6. Extinguishing agents 7. In case of fire 8. Special fire fighting procedures

Unavailable Foam, dry chemical, N2 or CO2. Follow SPTI contingency plan. Water may be ineffective on fire. Use water to cool exposed tanks.

12.1.3

HEALTH HAZARD Unavailable Unavailable Unavailable Unavailable Unavailable Unavailable avoid contact with liquid. Skin contact will cause minor reddening. Not pertinent Skin contact: flush affected areas with large amounts of water. Wash thoroughly with soap and water. Refer to the IMO Medical first aid guide (MFAG).

1. Irritating vapor 2. Irritation from liquid 3. Chemical poisons 4. Odor threshold (ppm) 5. Permissible exposure limits/TWA 6. Threshold limit value/TWA 7. General 8. Symptoms 9. Short exposure tolerance 10. Exposure procedures

11. Medical management

12.1.4 1. Stability

REACTIVITY INFORMATION Stable Usual material of construction are suitable. Group 34.

2. Material compatibility 3. USCG compatibility

12.1.5 1.

SPILL OR LEAK PROCEDURE Wear appropriate protective, gloves and safety goggles or face shield. Follow SPTI contingency plan. the

Personnel protection

2. Contingency plan 3. Leak combat

If leak on cargo transfer system. Stop transfer and empty the line system. Allow the product to solidify. Contain and sweep up, put substance on an adequate for later removal.

12.2.1 CODES MINIMUM REQUIREMENTS- SULFURIC ACIDS Tall oil is regulated for bulk transportation by the IMO, BCH and IBC codes. Following is the summary of the codes minimum requirements: UN Number Pollution category Hazards Ships type Tank type Tank vents Tank environment Electric equipment Gauging Vapor detection Fire protection Material of construction Special requirement Respiratory and eye protection B Pollution hazards. 3 (Normally stowed in type 2 ) due to melting point greater than 15 C. Integral gravity tank. Open venting. No requirement No special requirement Open No Alcohol resistant foam No special requirement. See IBC code 15,19.6, 16.2.6, 16.2.9, 16A.2.2 and BCH Code, Chapter 4.14.1, 5.2.5, 5.2.8, 5A.2.2. Individual unit required for emergency escape purpose.

12.3.1

PREWASH PROCEDURE- TALL OIL (CRUDE )

If applicable, study the prewash procedures for CTO as outlined in the ships P & A Manual Annex II (addendum) If applicable, ensure to get sufficient details regarding the delivery of the prewash medium (Tall oil Fatty acid). For cleaning purposes ensure to have onboard sufficient caustic flakes (approximately 350 kg for a 2000 m3 tank.)

12.4.1

BEFORE LOADING

1. Due to different grades of CTO ensure to obtain correct handling instruction at load port, in particular heating instruction (also see the requirements in section 12.8)

12.4.2

AFTER LOADING

1. Ensure proper line clearing to prevent solidification of line system.

12.5.1

TEMPERATURE REQUIREMENTS

1. Depending on the product, specification the cargo may be heated or carried at ambient temperature during the voyage. For charterers specific temperature requirement refer to section 12.8 2. Discharge temperature of minimum 63 C is required to avoid prewash in Japan.

12.5.2

DAILY TEMPERATURE LOG

1. Daily temperature logs to be maintained, according to charterers instructions, contained in section 12.8 (specific form(s) may be received at the load port).

12.6.1

CLEANING METHODS

Upon completion of the mandatory prewash, if required, (as the tank has been prewashed with Tall Oil fatty Acid, the same is considered as the last cargo) carry out the cleaning methods below; 1. If slops cannot immediately be disposed after discharge, machine wash each tank with warm seawater (50C) for 1 hour without pumping out. Leave the wash water/slop in the same tank until tank cleaning can commence and the slop disposed (ensure any sloshing will not adversely effect the heating coils). When commencing tank cleaning, machine wash the tank(s) hot (80C-85C) for 8 hours. When using portable machines, position machines for 2 hours at 10/20/30/40ft. drops. When using fixed tank cleaning machines the washing time can normally be reduced to 4 hours. On completion of washing fresh water rinse and eject the tank. Prepare a mixture in the tank of, adding 3000 liters of fresh water and 350Kg caustic flakes. Recirculate the caustic/fresh water for two hours (35-40 C) on each drop, starting from bottom going up; 40/30/20/10 ft. During the recirculation apply heating on the coils maximum 40 C in the tank. The heating must be applied only during the actual recirculating via the tank washing machines. On completion of recirculation rinse the tank warm (35-40C) for 6 hours. 1 1/2 hours on each drop.

2. 3. 4.

5. 6. 7. 8.

9.

10. Fresh water rinse tank and lines. 11. Toluene steam cargo line.

12.6.2

LOP DISPOSAL AND ARRANGEMENTS

The slops are to be disposed according to: 1. Regulations for control of pollution by noxious liquid substances in bulk, IMO, MARPOL Annex II and, when it is necessary to dispose slops to shore reception facilities, the ship must report estimated quantities to the ship operator and the local agent. Before mixing compatible slops residues or slop and cleaning agents consult the local agent.

12.7.1

MITSUI TEMPERATURE REQUIREMENTS

1. This particular customer requires ambient cargo temperature during the voyage. 2. Prior to arriving at the discharge port (7 days), the cargo temperature is to be gradually heated up to 65 C. 3. If the specific heating instructions are not followed, the cargo is most likely to be received off specifications. 4. For all Mitsui CTO, at least every 3 days, from loading till discharging, the Master is to TLX the actual cargo temperature to the ship operator. 5. This grade of CTO has less solid content and sediment should not be problem. 6. Stowage of adjacent heated cargoes should be avoided whenever possible.

12.7.2

HARIMA TEMPERATURE REQUIREMENTS

1. The cargo temperature during the voyage should be maintained between 50-55 C. 2. Prior to arriving at the discharge port, the cargo temperature is to be increased to 65 C.

APPENDIX-2 Wall Wash & Berth Information

WALL WASH SPECS:

As customers keep changing their inspection companies and every inspection company applies different standards, extreme care should be exercised to use the wallwash spec list as and indication only, as further communication will be needed to confirm the specifics.

ARGO WALLWASH SPECS

Product Acetone Acetone Acetone Acetone Aceton/MEK AN AN Brake Fluid Caustic potash Caustic soda Chlorinated Charterer/ Supplier Celmex EXXON EXXON Shell/Pectin Toyomenka Gantrade/ Sterling (*)Mitsubishi (*)Occidental (*) Occidental DOW Inspector Comtrol SPC USC Comtrol SGS Chemcoast Coastal gulf SPC Comtrol/ Accutest ITC calebett Terminal Georgia gulf Paktank DP Paktank DP ITC DP Shell Sterling ITC Petrounited ITC/Paktank C.Christi Baytank/ Medium Acetone Acetone Acetone Methanol Acetone Methanol Toluene Methanol Methanol Acetone Perman Minute 60 + 30 30 50 30 N/A N/A N/A N/A Hydro Carbon Nil Nil Nil Nil Nil Nil Nil Nil N/A Chloride s (PPM) <5 <20 N/A <8 <10 N/A N/A N/A N/A (pt-Cob) Color <10 20 <5 <10 <5 <15 Color <25 <5 + <13 <50 N.V.M N/A N/A N/A N/A N/A <50 Odor (2) (2) (2) (2) (2) (2) (2) (2) (2)

solutions/ EDC/MEC/ Trichloro/ TECA/ETC Cumene DEG DEG DMF EDC Epikote Ethanol-INO Ethanol 200% Ethanol 200% Exxpar 271/291 HMO IPA IPA IPA IPA MEC MEG FG(EG) MEG FG(EG) MEG FG(EG) MEG FG(EG) MEG INO MEK MEK MEK MEK METHANOL METHANOL METHANOL Sunny Tops Occidental Brentag (*) Dupont (*)Occidental (*)SHELL Itochu UCC Petrochem EXXON (*) Dupont EXXON EXXON Shell/Exxon Celmex (*) Occidental Occidental Oxyde/ Occidental Texaco Chem UCC Occidental EXXON EXXON SHELL/Pecte n SEHLL Beaumont Methanol VINMAR BORDEN ITC Calebrett SPC SGS Chemcoast Inspectorate SGS ITC ITS Coastal Gulf USC SPC Chemcoast USC SPC Comtrol SGS Inspectorate SPC SGS Bayport Thibodeaux SGS SPC USC SPC Comtrol SGS CPI SGS USC

Freeport

KOCH Petrounited PT.Neches Paktank DP Occidental C.C Stolthaven Stolthaven UCC Baytank Paktank Paktank DP Paktank DP Paktank DP Shell DP Shell DP Baytank Petrounited Petrounited Port Arthur UCC Petrounited Paktank DP Paktank DP ITC DP SHELL Dupont Paktank DP Paktank DP Beaumont Dupont Paktank DP

Cumene Methanol Methanol Methanol Methanol Methanol Ethanol 200% Ethanol 200% Ethanol Exxpar Methanol DI water IPA IPA MEOH MEOH MEOH Methanol Methanol DI water Cotton Swab Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol N/A 60+ N/A N/A 50 + N/A No 50 + N/A N/A Test for iron N/A N/A 50 50 + 60 N/A 50 NO NO N/A N/A N/A 50 60 + 60 60 + 30 Slight trace Nil Nil N/A Nil N/A Nil Nil N/A <20 <5 N/A N/A <10 N/A No tested 2PPM <1 N/A N/A Nil Nil Nil Nil Nil Nil Nil Nil Nil Slight trace N/A Slight trace Nil Nil Nil Nil Nil N/A <20 <8 <5 <9 <5 <1 <1 0.249 max <20 N/A N/A <8 <1 <1 <1 <0.7 40 <5 <10 <25 <5 N/A Clear <5 N/A N/A <10 10 30 <10 <5 <5 30 <5 <5 <5 50 <10 30 <10 <5 <5 <5 N/A N/A N/A <50 N/A N/A <60 N/A N/A N/A 50ppm 5ppm N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 20ppm N/A Nil susp N/A N/A N/A N/A (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2)

CARGO WALLWASH SPECS CONT.

PRODUCT METHANOL MIBK MIBK Neutral oil150 Chevron15 or Petroleum jelly cosmetic grades Nitro Propane (TT-Ethane) O.Dichlorbene P.Glycol INO Paraxylene CHARTERER / SUPPLIER PECTEN EXXON EXXON INSPECTOR COMTROL BERGERON USC SPC TERMINAL ITC DP Paktank DP Paktank DP Paktank DP MEDIUM Methanol Methanol MIBK Methanol Perma Minute 50 50 + N/A N/A Hydro Carbon Nil Nil N/A Slight Trace Chloride (PPM) <8 <5 N/A N/A (pt-Cob) Color <10 <5 15 30

NVM
N/A N/A N/A N/A

Odor
(2) (2) (2) (2)

TEXACO (Caltex)

Inspectorate

Stolthaven

Methanol

N/A

N/A

<5

N/A

(2)

ANGUS STANDARD SHELL/ARCO (*)EXXON

SPC SPC SPC USC

Paktank DP Stolthaven Stolthaven Petrounited ITC EXXON

Methanol Toluene Methanol Paraxylene

N/A N/A N/A N/A

Nil N/A Nil N/A

<10 N/A <10 N/A

<20 30 20 <5

N/A N/A N/A N/A

(2) (2) (2) (2)

Baytown Paraffin HM/LM Medical grade PHENOL Propylene Oxide Styrene TEG TETA THF Toluene VAM VAM VAM VAM VAM Xylene Xylene SHELL Georgia Gulf Olin/ARCO (*) Metmar Occidental DOW (*)Dupont SHELL Borden Gantrade (*) Dupont QUantum Pecten EXXON Mobile Inspectorate SGS COMTROL Comtrol SPC ITC Chemcoast SGS USC Comtrol Chemcoast SPC USC Chemcoast SPC Mobile Stolthaven/ ITC (rail car) Georgia gulf Huntsman Petrounited Petrounited DOW Paktank DP SHELL Paktank DP ITC Paktank DP Paktank DP ITC DP Paktank DP Xylene Methanol Methanol Methanol Methanol Methanol Acetone Methanol Methanol Methanol Methanol & VAM Methanol VAM MEOH N/A 30 + 60 + 50 N/A Nil Nil Nil Nil Slight traces N/A Nil <125 N/A <5 <5 <1 <8 <20 <5 <10 <5 <10 40 13 <15 <10 N/A 5 N/A N/A N/A N/A N/A 50 Mx <50 N/A N/A N/A (2) (2) (2) (2) (2) (2) (2) (2) (2) (2)

<10 N/A (2) <5 <5 N/A (4) <6 Acid Methanol N/A N/A N/A N/A (2) wash Run acid wash color, chloride, sulfur, purity, distillation same as shore tank.

N/A N/A N/A N/A 50 + <5 30 <0.7 N/A DistilatiNil <1 on range N/A Nil N/A Purity by gas chromatograph N/A Nil <1

(*) Indicates Not Mandatory will only wallwash if: A. B. C. D. E. If Last cargo CPP If inhibited cargo last If non water white last cargo (color pick up) If any oil last cargo Looking for iron

(2) Indicates no foreign odor/No suspended matter N.B Increasing in the US gulf area, If last cargo in tank is bad and next cargo water white then surveyor will perform a wallwash.

ARCO CARGO WALLWASH SPECS

PRODUCT 1.4 Butylene Glycol Dipropylen Glycol Methanol Methyl N Proproldonel None 1 P Glycol INO P.Glycol USP Polyol Niax Polyol Polyol HS40 Polyol HS100 Polyol E 786 Polyol E 788 CHARTERER / SUPPLIER (*) ARCO (*) ARCO ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO INSPECTOR SPC SPC Bergeron SPC SPC SPC SPC SPC SPC SPC SPC SPC TERMINAL Stolthaven Petrounited Paktank DP Stolthaven 3 Paktank DP 1 PKTK/PETR O Petrounited (barge) Paktank/ Petro Petrounited Petrounited Petrounited Petrounited MEDIUM Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Perma Minute N/A N/A 50 + N/A N/A N/A N/A N/A N/A N/A N/A N/A Hydro Carbon Slight Trace Slight trace Nil Slight Trace Slight Trace Nil Nil Nil Slight trace Slight trace Slight trace Slight Chloride (PPM) <10 <10 <5 <5 <5 <10 <10 <10 <10 <10 <10 <10 (pt-Cob) Color <20 <205 <5 <20 <20 20 20 <5 <10 <20 <20 <20 <20 N.V.M N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Odor (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2) (2)

Polyol E 815 Polyol E 824 Polyol E 825 Polyol E 3020 P Oxyde Styrene Styrene TPG ULTRACEL 200 WHITE OIL (ARCO PRIME 90/350)

(*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO (*) ARCO ARCO (*) ARCO

SPC SPC SPC SPC SPC SPC SPC SPC SPC

Petrounited Petrounited Petrounited Paktank Dp #1,3 Petrounited Paktank DP 3 Paktank DP 3 Petrounited Petrounited

Methanol Methanol Methanol Methanol Methanol Methanol Toluene Methanol MEOH

N/A N/A N/A N/A N/A N/A N/A N/A N/A

trace Slight trace Slight trace Slight trace Slight trace Nil Slight trace N/Al Slight Trace Slight trace Nil

<10 <10 <10 <10 <10 <10 N/A <10 <10

<20 <20 <20 <20 40 5-10 40 <40 <20

N/A N/A N/A N/A N/A N/A N/A N/A N/A

(2) (2) (2) (2) (2) (2)

(2) (2)

(*) ARCO

Inspectorate

ARCO

Methanol

N/A

<5

<5

N/A

(2)

(*) Indicates not Mandatory will only wallwash if; A. B. C. D. (2) If If If If last cargo CPP (Leaded and Dyed) inhibited cargo list (VAM ETC) non water white last cargo (Color pick up) any oil last cargo (LUB/ADDITIVE/VEG)

Indicates no foreign odor.

HOECHST CELANESE CARGO WALLWASH SPECS

PRODUCT METHANOL VAM Propanol Butanol MEK Di-n-Propylamine *Lauryl alcohol (Iso Decanol) Ethyl acetate Propyl acetate Butyl Acetate Isobutyl Acetate Acetic acid Acetic Anhydride Propionic Acid Formic Acid Butyl Acrylate Ethyl Acrylate Methyl Acrylate 2 EH Acetaldehyde Butyraldehyde Propionaldehyde Methyl Formacel Butyl Formacel Formaldehyde CHARTERER / SUPPLIER HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE HCELANESE Inspect or SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS SGS TERMINAL CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE CELANESE MEDIUM Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Perma Minute 50 50 50 50 50 50 40 50 50 50 50 50 50 50 50 50 40 40 40 50 50 50 40 40 40 Hydro Carbon NIL NIL NIL NIL NIL 250 NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL NIL Chloride (PPM) 8 3 3 3 3 8 15 3 3 3 3 3 3 3 3 12 12 12 12 5 5 5 12 12 12 (pt-Cob) Color 10 10 10 10 10 10 10 10 10 10 10 15 15 15 15 15 15 15 15 10 10 10 10 10 10 N.V.M N/A N/A N/A N/A N/A N/A N/A Odor None Moderate None None None None None None None None None None None None None Moderate Moderate Moderate Moderate Moderate Moderate Moderate Moderate Moderate Moderate

N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A

Solution DiEthylene Glycol Ethyl Glycol Propylene Glycol Butylene Glycol

HCELANESE HCELANESE HCELANESE HCELANESE

SGS SGS SGS SGS

CELANESE CELANESE CELANESE CELANESE

Methanol Methanol Methanol Methanol

50 50 50 50

NIL NIL NIL NIL

5 5 5 5

10 10 10 10 10

N/A N/A N/A N/A N/A

Moderate None None None None

(*) Indicates not Mandatory will only wallwash if; E. F. G. H. (2) If If If If last cargo CPP (Leaded and Dyed) inhibited cargo list (VAM ETC) non water white last cargo (Color pick up) any oil last cargo (LUB/ADDITIVE/VEG)

Indicates no foreign odor.

HISTORICAL PRE-WASH INFORMATION

Product/Trade Name A.C.H Antarox Nonyl Phenol CD-630 Alkyl Ketone Coal Tar Cresol (Meta/Para/ Acid) Crude Biphenol Crude EDC Lightends Ethyl Acrylate U46 M Herbicides Herbicides 240 MDI (NOLA) MDI METACHLOR Receiver/ Destination ITC/ LUX CHEM STANTRANS Stolthaven (Tank trucks) Stolthaven/Kop pers GATX GP/Sumitomo GATX GP Formosa plastics Point comfort ITC (Vacuum trucks) Stolthaven Paktank DP #1 Delta Comm #2 Stantrans Paktank Dp #1 Charterer R&H GAF Bayer/TTS Koppers Merichem Special Instruction USCG Compliance cargo 24 hour Notice Check C.O.A Check C.O.A USCG Compliance cargo 24 hour Notice USCG Compliance cargo 24 hour Notice USCG Compliance cargo 24 hour notice USCG Compliance cargo USCG Compliance cargo 24hour Notice USCG Compliance cargo 24 hour notice USCG Compliance cargo 24 hour notice Check C.O.A Check C.O.A Check C.O.A Prewash 45/50C Special Pre-wash Fresh water to container recycled product Fresh water to shore tank Fresh water to truck Fresh water to barge 60C into cargo Fresh water with cargo on barge Min 60 Deg. C Solvent wash to shore tank Check disch temp Fresh water to barge Customer Contact N0. Jim Weston 713-478-1819 Jim Vickery Ben Ditta 713-457-4951 Water Geels 713-453-5446 Larry Gaskamp 713-455-1311 Jerry Cozetti 713-789-4477 Bill McGee 512-987-2666 Jim Westin (R & H) 713-476-8608 Gene Devoid 203-316-7022 Charles Hayes 919-632-7022 RIB/ NOLA 504-831-5336 Jim Kimling 409-948-3561 Charles Hayes 919-632-7022 Remarks Category A Category B Category B Category A Category A Category A

PASA/ ASAP

C ITHO

Category B

Rohm & Haas Mobay/BASF Ciba Giegy AH Marks ICI/BASF Bayer Ciba Giegy

Fresh water Fresh water to trucks Fresh water to trucks 45C pre-heat water Solvent wash with MCB Recycled product Solvent wash recircled Monochloro Benzene Fresh water to trucks

Category A Category A Category B Category B Category B Category B 3 Tank<1200m -

10m PW. 3 Tank>1200m 3 20m PW METAM SODIUM OCTEL (gasoline Additive) Resin Oil C-9 Shell SAP3113A Shell 199(AC60) if<70 Shell 383 (AC100) Softanol Stolthaven (rail cars) Old Manchester #2 Stolthaven UCB/TTS OCTEL Hercules USCG Compliance cargo 24 hour notice USCG Compliance cargo 24 hour notice USCG Compliance cargo 24 Hour notice USCG Compliance cargo 24 hour notice USCG Compliance cargo 24 hour notice Heat up to 60C Fresh water Fresh water to trucks 60C Fresh water to trucks Prewash to trucks 60 degrees potable fresh water to trucks 60 C Min. potable Fresh water to shore Ben Ditta 713-457-4951 Rudy Megle 609-540-3653 Joe Cruz 302-594-5000 Jim Gaughan 713-241-3604 Ben Ditta 713-457-4951 Category A Category A Category A Category C High viscosity

Stantrans

Shell Int.

UCC

Toyomenka

Category A Category A 0-750 3 20m /tank 751-1000 3 25m /tank 1001-1500 30m 3/tank 1501-2000 3 35m /tank Category B 750m3 tank20m3 PW 1000m3 tank-25m3 PW 1500m3 tank-30m3 PW Category B

Sodium Cresylate Spent Caustic

Stolthaven

Merichem

USCG Compliance cargo 24 hour Notice

Potable fresh water to barge/ Min 60C.

Larry Gaskamp 713-455-1311

Sodium Dicromate

Oil Dock #4/C Christi

Bayer

Check C.O.A

Fresh water to trucks 60C-check cargo heater

Chuck Davis 412-777-2029

Trichlorobenzene

Stantrans/Stolt

Bayer/Mobay

Check C.O.A

Fresh water to trucks

Howard Jarvis 713-383-2411 Ext. 46300 STORES Yes Limited Yes Yes Yes Yes- Good Limited ??? Yes Good Yes Good Yes ??? Limited Yes Yes Limited Limited Limited Limited Yes Yes Yes- Good V-Good Limited Yes Yes Yes Yes Yes Yes Yes V-Good V-Good Yes

BERTH INFORMATION IN HOUSTON AREAS

BERTH MI>SEA SIDE TO Gangway BARGING HOUSTON Maximum Channel Draft 36-00 Fresh water (Min. +1 tide Gauge) CITY DOCK #1W 52.8 Option Ship Limited CITY DOCK #1E 52.7 Option Ship Limited CITY DOCK #2 52.6 Option Ship Limited PACIFIC MOLASSES 52.1 Option Ship Limited OLD MAN. #3 50.8 Option Ship Limited OLD MAN. #2 50.7 Option Ship Limited TRAWEK (BASIS) 49.7 Option Ship No BASIS #1 49.6 Option Ship Yes WOODHOUSE** 49.5 Option Ship Yes PETROTEX A 49.4 Option Ship No PETROTEX B 49.4 Option Ship No VALERO #1 49.6 STBD Ship Limited HOUSTON Maximum Channel Draft 39-00 Fresh water(Min. +1 tide Gauge) LYONDELL B 49.2 Option Ship No LYONDELL C 49.1 Port Ship No PAKTANK GP 49 Option Ship No GATX GP #1 48.5 Option Ship No GATX GP #2 48.5 Option Ship No GATX GP #3 48.5 Port Ship No GATX PASD 47.1 STBD Ship No HESS 46.7 STBD Ship No TESSENDERLO KERLEY 45.5 Option Ship Yes ADAMS 45.1 STBD Ship No BULK PLANT ** 45.1 STBD Ship Yes GEORGIA GULF 43.6 Option Ship No ARISTECH 43.2 Option Ship No SHELL-EAST 42.7 STBD Ship No SHELL-MID 42.7 STBD Ship No SHELL-WEST 42.7 STBD Ship No STOLTHAVEN #2 42.5 PORT * Ship Yes SOTLTHAVEN #3 42.5 STBD Ship Yes CARGILL #3 ** 41.5 Option Ship Yes JACINTOPORT ** 40.9 STBD Ship Yes CARE ** 40.9 Option Ship Yes ITC #1 40.9 STBD Ship Yes F. Water Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes * Yes * NO Yes Yes Yes Yes Yes NO Yes Yes Yes Yes Yes Yes Yes Yes Yes * BUNKER X-Barge X-Barge X-Barge X-Barge X-Barge X-Barge NO X-Barge X-Barge NO NO X-Barge NO NO NO NO NO X-Pipe NO X-Pipe X-Barge NO X-Barge NO NO NO NO NO X-Pipe X-pipe X-Barge X-Barge X-Barge X-Pipe T/Cleaning Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes NO NO Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes NO Entry NO Entry NO Entry Yes Yes Yes Yes Yes Limited

ITC #2 ITC #3 ITC #7/8 ** PAKTANK #1 PAKTANK #2 PAKTANK #3 PORTLAND CEMENT ** EXXON #1 B1 EXXON #1 B2 EXXON #2 B3 & B4 BARBOURS CUT ** BARBOURS LASH **

40.9 40.9 40.9 40.9 40.9 40.9 40.5 35.3 35.2 35.2 32 32

STBD * PORT Option PORT PORT Option Option Option Option Option Option Option

Ship Ship Ship Ship Ship Ship Ship Ship Ship Ship Ship Ship

Yes Yes Yes Yes Yes Yes Yes NO NO NO Yes Yes

Yes * Yes * Yes * NO NO NO Yes Yes Yes Yes Yes * Yes *

X-Pipe X-Pipe X-Barge X-Barge X-Barge X-Barge X-Barge NO NO NO X-Barge X-Barge

Poor Poor Good Yes Yes Yes Limited NO NO NO V-Good V-Good

Limited Limited Limited Yes Yes Yes Yes NO Entry NO Entry NO Entry Yes Yes

BAYPORT Maximum Channel Draft : 3906 (Min +1 Tide Gauge) PETROUNITED 30.9 PORT Ship NO BAYTANK #1 30.9 Option Ship Yes BAYTANK #2 30.9 STBD Ship Yes CELANESE 30.9 Option Shore NO TEXAS CITY Maximum Channel Draft 39-06 (Min. +1 tide gauge) STERLING 14.1 STBD Ship NO STANTRANS #15 14.2 PORT Ship Yes * STANTRANS #16 14.3 Option Ship Yes * STANTRANS #19 14.4 STBD Ship Yes * AMOCO OIL #31,37,38 14.6 Option Ship No AMOCO CHEM #50 15.5 Option Ship NO UCC #66 16.1 STBD Shore NO UCC #67 16.1 STBD Shore NO BOLIVAR ANCHORAGE 8 BUNKER FREEPORT Maximum Channel Draft 42-00 (Min. +1 tide gauge) DOW A8 3 PORT Shore NO DOW A22 3 PORT Shore NO DOW A14 3 STBD Ship NO PHILLIPS 3,4 Option Ship NO BRAZOPORT #1 & 2 4,5 Option Ship Yes POINT COMFORT General cargo Dock Liquid cargo Pier

NO Yes Yes NO

NO X-Pipe X-Pipe NO

Limited V-Good V-Good NO

Limited Yes * Yes * NO

Yes Yes Yes Yes Yes Yes NO NO N/A Yes Yes Yes Yes Yes

NO NO NO NO NO NO NO NO X-Barge NO NO NO NO X-Barge

Limited Good Yes Limited Yes Limited Boat only Boat Only N/A Yes Yes- Good Limited Yes V-Good

NO Yes Yes Yes NO NO Entry NO Entry NO Entry Yes NO NO NO Yes Yes

30 30

STBD Option

Ship Ship

??? ???

Yes Yes

NO NO

Yes Yes

Yes Yes

BEAUMONT/ PORT ARTHUR Star Enterprises 17 CLARK(CHEVRON) #1 18 #2 18 FINA #1 (OIL DOCK) 27 FINA A 27 HUNTSMAN CHEMICAL 40 DUPONT 40.9 MOBIL OIL #2 50 UNICAL 37 SUN OIL 37 LAKE CHARLES PPG A & C WESTLAKE STYRENE CONOCO WESTLAKE CONOCO #3 CITGO B CITGO C CITGO D CORPUS CHRISTI FINA (HBR ISLAND) OCCIDENTAL (INGL) SOUTHWEST #2 SOUTHWEST /KOCH #3 CHAMPLAN #1 COASTAL #1 VALERO KOCH #8

Option Option PORT Option Option Option Option Option Option Option

Ship Ship Ship Ship Ship Ship Ship Ship Ship Ship

NO NO NO NO NO NO NO NO NO NO

NO NO NO Yes Yes NO NO Yes Yes Yes

X- Pipe NO NO NO NO NO NO X-Pipe NO X-Pipe

Yes Limited Limited Yes Yes Yes Limited Limited Limited Limited

Yes Yes Yes Yes Yes Yes NO Entry Yes Yes Yes

50 48 48 48 42 42 43

STBD STBD STBD STBD PORT PORT PORT

Ship Shore Ship Ship Ship Ship Ship

NO NO NO NO NO NO NO

NO NO NO NO Yes Yes Yes

NO NO NO NO NO NO NO

Limited Limited Limited Limited Yes Yes Yes

Yes NO Yes Yes Yes Yes Yes

2 18.5 25.5 25.5 26 26.8 29.3 32

Option PORT Option Option Option Option STBD STBD

Ship Ship Ship Ship Ship Ship Ship Ship

NO NO NO NO NO NO NO NO

Yes NO Yes Yes Yes Yes Yes Yes

??? NO X-Pipe X-Pipe NO X-Barge X-Pipe X-Barge

Yes Limited Yes Yes Yes Yes Yes Yes

Yes Yes Yes Yes Yes Yes Yes Yes

BROWNSVILLE ITAPCO (LIQ CGO) STACIA OIL DK #1 STACIA OIL DK #2 PET. LIQUID OIL DK #3

14.5 15.2 15 14.3

STBD PORT PORT PORT

Ship Ship Ship Ship

NO NO NO NO

Yes Yes Yes Yes

X-Truck X-Truck X-Truck X-Truck

Yes Yes Yes Yes

Yes Yes Yes Yes

APPENDIX 3

TANK PREPARATION TO WALL WASH SPECIFICATION

GENERAL GUIDELINE 1. 2. 3. 4. 5. 6. 7. 8. Methanol testing Procedure Methanol test kits Standard Laboratory Procedure Methanol Specifications by Load port and supplier Comments which highlight Particular areas of concern at each load port Cleaning form water white to known wall wash specifications flow chart Guidance for U.V. Test Preparation Guidance for N.V.M

METHANOL TESTING PROCEDURES- METHANOL TEST KIT As a result of the increasing quantities of methanol and other cargoes requiring wall washes being loaded. We provided the following as a guideline for materials to be kept in the Methanol (wall wash) Test kit. This inventory is based on what has been consumed on several ships recently preparing from 20 to 25 tanks for wall wash testing. If a full stocked test kit is not maintained, it would be difficult to carry out tank testing to determine the ships preparedness. We, therefore suggest that an inventory be taken and replacement items ordered as soon as possible. After difficult last cargoes, the cleaning program, in preparing for a large quantity of Methanol, is a trying tome for all onboard. The uncertainty, regarding the status of tanks after initial cleaning, can result in costly overkill with respect to more cleaning than is required to ensure methanol standards! However, if doubt, additional cleaning is a prudent action and will not be disputed, Each additional, unnecessary hour spent is a multiple number of man-hours that could have been used more effectively in other areas of shipboard maintenance. Adherence to the enclosed procedures will assist you in determining the cleanliness status of each tank and when have achieved the desired standards. With a little time and effect it is possible to approach laboratory standards to ensure your test results are accurate. Included with those guidelines are standard laboratory procedures which are used worldwide. Particular attention is drawn to the page dealing with Procedures for Methanol Wall Wash Test. This section cover testing procedures wherein filter paper is used when wall washing. The filter papers are diluted with a substantial amount of pure methanol. This method is less severe than collecting method from bulkheads with a funnel. The procedure closely simulates actual laboratory testing. However, we would be suggest that this procedure be used only when a person with experience in interpreting the results is available. We have concluded an agreement with two companies in Houston for the supply of items for the Methanol Test Kit on board your ship. The price of the material is extremely competitive and should yield a substantial savings over items having been supplied up to this point. The importance of pre-planning, however cannot be over emphasized. Prior to arrival in Houston, please take a few moments to go through the test kit and advise your ship operator of requirements you have to achieve the standard inventory level. Any feedback may have with regard to items supplied in Houston will be helpful in enabling us to maintain the highest standards of quality from the suppliers. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Laboratory pure Methanol 100 liters Deionized water for testing 100 liters Silver nitrate solution 10% with squeeze top 8 ounces 3% Peroxide with 2% Hydrochloric Acid solution 1 liters Disposable plastic gloves 200 pieces Whatman filter papers #42 (chloride free-ashless) 200 pieces Washing bottles conventional polyethylene 6 x 500 ML Graduate cylinders Pyrex brand glass single metric scale Calibrate to contain 100ML.size 5 with bases Pen light flashlight with batteries 2 pieces Wooden stand for graduate cylinders 1

11. 12. 13. 14. 15. 16. 17. 18.

Pipette pytex brand 10 ML size Pre-measured permanganate crystals 0.1 grams Plastic funnels for wall washing Standard potassium permanganate solution Standard stock Salt solution Jars (sample) round wide mouth 16 once size Nessler tubes 50 ML with stoppers Twenty percent solution Nitric acid

2 10 capsules 4 pieces 1 bottle 1 quart 6 pieces 1 liters

NOTES: 1. Regarding item #4, the hydrochloric acid/peroxide mixture is used to rinse the tubes in which the permanganate time tests are done. These tubes will discolor to brownish color after about 3 successive time tests are run. To remove this discoloration and before using again, rinse with acid, flush 3 times with tap water, twice with Deionized water, and twice with methanol. The solution should be made just prior to use and disposed of as soon as possible. 2. Items #6, filter paper, can be used to simulate laboratory conditions in tanks which are deemed borderline. Normally, one paper is used on each bulkhead, placed in a jar (using plastic gloves ) and diluted with 50 ML. Of pure methanol for each filter paper. It is recommended that filter papers are tested for chlorides prior to use. Item #16, glass jars, are for use in catching wall liquid to transport samples from tank to testing area. Should you have difficulty in obtaining any of the above materials, please do not hesitate contact the ship operator for assistance.

3. 4.

In addition to the standard quality checks that are to be made when loading sensitive cargoes, we would emphasize the following items. 1. 2. The methanol must be tested for chlorides and other impurity before being introduced in the tanks. This also applies tot he methanol that you will use for testing. Check the steam from the boilers. We have experienced that boiler treatment chemicals have caused the wall wash test to fail on Hydrocarbons. Clean the butterworth pump filter and butterworth heaters as fish, mud, shells, or grease may have entered the system. Ensure that the vessel is adequately stocked with cleaning chemicals and in particular, whenever your ship is in Rotterdam or US. Gulf, make sure that spare filters for the Deionized water unit are taken on board. In some areas, the water used for washing can contain impurities which adversely affect the cleaning. In certain areas, plankton may affect the wall washes. To test for plankton. Mix 75 ML. Water with 25 ML acetone. If there are plankton present, they will quickly settle to the bottom. Water used for washing can contain plankton, but same must be immediately rinsed off with good water before the bulkheads dry.

3. 4. 5.

WALL WASH PROCEDURE 1. Suggest using a plastic bucket to transport materials for obtaining wall wash samples. Carry in bucket, plastic spray bottles, plastic gloves, funnel, and jars for the number of tanks to be sampled. Items in bucket are to be rinsed with methanol after entering tank and before taking wall wash. Mark each bottle with tank number. Randomly select one spot on each bulkhead for methanol rinse. Holding funnel and sample jar in one hand, use spray bottle to wash an area directed at a minimum of three feet above funnel and jar (four to five feet is preferable). By collecting about 25 ML of wash for each bulkhead, you will have enough to use for testing. It is extremely important that surfaces to be methanol washed are dry!

2.

3.

If the laboratory area is neat and orderly, it will greatly facilitate testing. Ideally, if a refrigerator is nearby, it can be set to 15 degrees C for permanganate testing. There must also be a sink for rinsing material.

TESTING FOR HYDROCARBONS (WATER MISCIBILITY) Using a clean Nessler Tube, pour 25 ML of wall wash from sample jar. To this, add 75 ML of deionized water. Stopper and invert tube to mix same and allow to stand for about 20 minutes. Place the tube on a black on a surface. Turn off light to darken room and shine a light through the side of the tubes while looking down through the liquid column. A wide beam flashlight should be used and kept about six inches from columns. Frequently, a pen light is used for this test. This is more critical due to the intensity of the beam. If this method is used on a standard (25 ML of laboratory pure methanol and 75 ML of deionized water should be prepared to compare to the wall wash samples. If a bluish tint is present, there are moderate to heavy hydrocarbons. If a whitish haze is observed, this usually indicates slight hydrocarbons. Factors which could affect this test are: if the graduation numbers on the tubes are in blue, if the column is dirty, or if the bulkhead is damp!

TESTING FOR CHLORIDES Using the same tube in which the water miscibility test was done (if no hydrocarbons were found), add 5 drops of Nitric Acid solution and check for turbidity. Provided sample remains clear, add 5 drops of 10% Silver Nitrate solution. Stopper and invert the tube to mix and observe if any turbidity is formed. To do this, compare the turbidity of the sample with the standard by looking down through the liquid against a black background. Comparison of wall wash samples to a standard should be done in a darkened room, by looking down through the tubes using a wide beam flashlight held about one foot from the sides of the tubes. A standard solution for varying amounts of chloride levels may be prepared form the standard chloride solution which should be included in the Methanol test kit. As chloride level vary from 0.3 PPM to 8 PPM from various charterers/ suppliers, it will be necessary to gauge cleaning with regard to various chloride levels. The most effective method for reducing chloride levels is to flush with copious amount of chloride-free water. In Vancouver, for instance, this is not a critical problem as dock water is virtually chloride-free. However, in Kitimat there is no fresh water line on the dock and fresh water can only be supplied by tank truck in 10 ton loads, i.e. very expensive and time-consuming. In Al Jubail, initial indications are that there will be no fresh water available. To assist in determining the chloride levels in wall wash samples, we will arrange to supply on your request in Houston and Yokohama, a chloride sample. This will be delivery in quarter bottles, and mixed as follows: Take 1 ML of chloride standard and add same to 25 ML of laboratory pure methanol. To this add 75 ML of deionized water. This solution will have the turbidity equivalent to 1PPM chlorides. To make a higher chloride standard, just increase above procedure accordingly. i.e. for a 2 PPM chloride solution just add 2 ML of standard 25 ML of methanol add 75 ML D.I. water, etc.

PERMANGANATE TIME TEST Of all the tests performed on board, this one is most subject to error due to its complexity. Ideally, Nessler tubes, used for testing, will have been thoroughly cleaned with hydrochloric acid and rinsed 3 times with tap water, twice with deionized water and twice with methanol. Then 50 ML of wall wash should be added to the previously labeled test tubes. To this, add 2 ML of the previously mixed permanganate solution. The pipette used for this should be thoroughly rinsed prior to use. As dispensette (a bottle with a pump top, calibrated for 2 ML delivery) is the best method for introducing the solution ; however, a cleaned pipette is amply good. The preparation of a new permanganate solution (0.1 gram of potassium permanganate to 1/2 liter of distilled water)

should be done every 3 days. This solution should be stored in an amber-colored bottle in a cool, dark place. Before adding the permanganate solution, fill the tubes to the 50 ML level with wall wash and place in a water bath which is maintained at 15 degree C (+/- 1 degree C) for ten minutes. Then add 2 ML of solution to each tube, stopper and invert once to mix, nothing the exact time. The tubes containing wall wash to which 2 ML of permanganate solution is added should have their stoppers rinsed with methanol before inverting to mix the solution. A dirty stopper could affect the time test. Place the tubes in the bath in a dark place which is being maintained at 15 degree C. Determine the intensity of the pink color at 10 minute intervals. Report the minutes elapsed between the time the permanganate was added and the time pink color matches the standard.

It is helped to make a standard solution to be run with each group of test tubes. This is made up by using 50 ML lab methanol (used for the wall washing) and 2 ML of the permanganate solution and run simultaneously with the other tubes. Therefore, if the standard fades at less time than you are testing for, it is indication of a problem with either the lab methanol, the permanganate solution, or the testing containers. Under the purest conditions, the permanganate time test will run 120 minutes.

SUGGESTIONS In consideration of the lack of laboratory condition on board, it is possible to approach these standards by use of the following; A) B) Galley pots can be used to simulate the water bath laboratory equipment. These should be large enough to accommodate four Nessler tubes with bases. A refrigerator or cooler, set to 15 degrees C, will also facilitate testing. The pots holding the tubes can be left filled with water inside the cooler. Then the pots can be removed from the refrigerator while preparing tubes for the time test and replaced after the permanganate solution is added. Again, it is important to set up the on board laboratory in an that can be darkened and where there are facilities on board which will not adversely affect on board sewage systems.

C)

METHANOL SPECIFICATIONS BY LOAD PORT AND SUPPLIER Attached is a recap by port and suppliers of methanol wall wash specifications. Additionally, there are some comment for each port that highlight the particular areas of concern we have noticed. It must be remembered, however, that specifications can be changed at any time, depending upon the receiver and sales contract for each lifting. Therefore, this is merely a guide and with each fixture the wall wash requirements should be confirmed.

METHANOL WALL WASH SPECIFICATION LOAD PORT AL Jubail SITRA KITMAT Vancouver Cape Horn La Buan New Plym. Point Lisas H.C Nil Nil Nil Nil Nil Nil Nil Nil P.T 50 Min 50 Min 50 Min 50 Min 50 Min 50 Min 60 Min 60 Min CHLORIDES Max 5/2PPM Max 2PPM Max 3 PPM Max 2 PPM Max 3 PPM Max 3 PPM Max 1 PPM Max 1 PPM ODOR Char. Char. Char. Char. Char. Char. Char. Char COLOR 10 10 <10 10 <10 <10 <10 5 REMARKS Depends on supplier Coating cond. can be problem Very strict H.C & Odor Very strict on odor Very strict H.C Test *See Note 1

Note 1: Petralgas COA- Portion of cargo to be stowed in tanks where last 3 cargoes do not contain Monomers (i.e. VAM, Styrene Monomer, Acrylic Monomer, Methaaacrylic Monomer, and similar compounds). FOOT SAMPLE SPECS. H.C NIL P.T CHLORIDES 60 Min + 0.25 PPM ODOR Char. COLOR 5 Max

ALL PORTS

JUVAIL METHANOL (SABIC) WALL WASH SPECS Supplier Chloride Hydrocarbons Color(APHA) PTT Appearance N.M.C (IBAN SINA) SABIC CELANESE MAX 5 PPM MAX 2 PPM PASS (25/75) PASS (25/75) 5 MAX 5 MAX 50 MIN 60 MIN C/B C/B S.M.C (AR-RAZI) MAX 2 PPM PASS (10/90) 5 MAX 50 MIN C/B

FOOT SAMPLE SPECS Chloride MAX 2 PPM MAX 0.3 PPM MAX 0.3 PPM Hydrocarbons PASS (25/75) PASS (25/75) PASS (10/90) Color(APHA) 5 MAX 5 MAX 5 MAX PTT 50 MIN 60 MIN 50 MIN WATER 500 PPM MAX 500 PPM MAX N/A Appearance C/B C/B C/B Density @15 in Vac 0.7957-0.7959 Temp Co-efficient 0.00092/Deg C Load Temperature Ambient (35-37 Deg C) Surveyor Company Watson & Gray IBN SINA3 Loading arms 12 inch chicksan 150 ASA flange AR_RAZI3 Loading Arms- Hydraulic quick couple 8-10-12 inch. Loading rate : 900-1200M3/hour. Wall wash samples collected by funnel from 6-8 difference spots in tank. Methanol is sprayed on bulkhead and allowed to run down the surface approximately 3 to 4 feet collected. Coating condition is normally not a concern for the surveyors. Lab is not accessible to ships personnel. Tanks will not pass hydrocarbon test with even slightest hydrocarbons present. Hydrocarbons are tested using a fluorescent light. SITRA (BARAIN) METHANOL WALL WASH SPECS

Hydrocarbons; Permanganate Time Chlorides Odor Color Surveyor Company

NIL 50 Min Max 2PPM Characteristic 10 SGS

Very strict visual inspection prior to wall wash. Surveyors are concerned about coating condition. Wall wash sample collected by funnel form up to 10 difference locations in tank bulkheads). (Pumpstack, heating coils,

If you are anchored awaiting berth availability and have a pre-inspection carried out, surveyors will perform tests on board, otherwise samples will be brought ashore to SGS lab. Another point of interest is that surveyors bring one full and one empty sample bottle down in the tank and splash product on bulkhead with one hand while collecting with the other. This procedure allows a large amount of methanol to run straight from the bottle into the funnel. In general, wall wash methods is not as strict as what is common in most ports. Note that hydrocarbons test done by mixing 10 ML wall wash and 90 ML DI-water, as this test is a lot less strict than in most other ports, no traces of hydrocarbons will be accepted. No fresh water available at berth.

KITMAT B.C METHANOL WALL WASH SPECS CELANESE Hydrocarbons Permanganate time Chlorides Odor NIL 50 Min MAX 8 PPM Characteristic

Color Surveyor company

<10 SGS

Wall wash sample collected by SWAB method. One sample collected from each bulkhead. Filter paper used (Whatman No 42) 6 Dia. Surveyors using plastic spray bottle with very fine nozzle, spraying an area of approximately one square meter on each bulkhead; as such the very first methanol running down the wall will be absorbed by the filter paper. The SGS lab is right at the berth and ships staff are invited to overlook the test are run. The 4 test papers from each tank will be diluted in 200 ML pure test methanol before the tests are run Hydrocarbons test very strict, not the slightest trace will be allowed. Odor test also very strict, the slightest difference from the standard and tank will be rejected. Coating condition is normally not a problem. Advantage to pick up pilot around midnight in order to have next day for final drying of tanks. No fresh water available at berth.

VANCOUVER BC METHANOL WALL WASH SPECS CELANESE Hydrocarbons: Permanganate Time Chlorides Odor Color NIL 50 Min Max 2PPM Characteristic 10

WALL WASH SPECS ALBERTA GAS Hydro carbons Permanganate Time Chlorides Odor Color Surveyor company NIL 30 Min Max 2 PPM Characteristic 10 SGS

Surveyors are actually longshoremen and all they do is collect samples. Samples are collected by filter paper (Whatman No 42). One sample each bulkhead, total of 4. The area of bulkhead sprayed by methanol is considerably smaller than what is done in Kitmat and spray bottles have a large opening which creates a good flow of methanol on bulkhead, therefore less chance to pick up contaminants hidden deep in the coating. Fresh water available at berth contain less than one PPM chlorides. If tanks fail on wall wash test, they usually fail on odor. CAPE HORN METHANOL WALL WASH SPECS. Hydrocarbons Permanganate Time Chlorides Odor Color Surveyor Company NIL 50 Min. 3 PPM MAX Characteristic < 10 Inter Control (Caleb Brett Subsidiary)

Wall wash samples collected by funnel from 4 different area in tank. Methanol is sprayed on bulkhead about 6 feet from bottom and caught in funnel about 3 feet from bottom. Berthing is allowed only during daylight at slack water. There is no fresh water at berth. It can be arrange from plant; however, cost is $20.00/MT. Fresh water should be taken in Callo or Chilean ports in sufficient volume to prepare all tanks. Water is not expensive and 1 and 3 PPM chloride; however, some ports 5 day notice for volumes of 500 tons or more. The hydrocarbon test is very strict here. Surveyors use a turbidity meter.

LABUAN METHANOL WALL WASH SPECS. Hydrocarbon Permanganate Time Chloride Odor Color NIL 50 Min 3 PPM Characteristic Less than 10

Wall washing done using the funnel method, the diluted one part wall wash to nine parts water for testing. If any tanks fail, can flush same with methanol while alongside, but no other type of cleaning is allowed Loads via two chicksan arms S.G 0.7903 at 20 degrees C C.O.E 0.00093 C Usual load temperature about 29-33 degrees C Several days prior to arrival, have SNSP confirm that manifold can be pre-rigged. Shore will not commence loading until all tanks have passed. No night navigation.

NEW PLYMOUTH METHANOL (FLETCHER CHALANGE/PETRALGAS) Hydrocarbons Permanganate Time Chlorides Odor Color NIL 60 Min 1 PPM Characteristic < 10

Strict tank coating inspection. Good coated tanks are necessary. Wall washes will be taken by the filter paper method, normally 5 areas (4: one each bulkhead; and 1: from the tank top). The papers are mixed with 25 ML of methanol for each paper. The test is run using 50 ML methanol from the paper/methanol mix with 50 ML water which makes the hydrocarbon test quite difficult. Depending upon actual fixture, some of the methanol may have to be stowed in tanks which have not had an inhibited cargo within last three cargoes carried. Necessary to check with ship operator if these restrictions apply.

No night berthing or sailing. Chicksan load (one 10 inch).

POINT LISAS (TRINIDAD) METHANOL Hydrocarbon Permanganate Time Chlorides Odor Color Very strict wall wash Sometimes helpful to order several drums of methanol form terminal for final flushing of tanks. NIL 60 Min 1 PPM Characteristic 5

Guidance when preparing the tank for an Ultra violet spectrum Test The cargoes covered by the chemical families; aromatics and chlorinated hydrocarbons affect this test. U.V. testing cannot accurately be carried out on board and the ship should select cleaning methods that basically dilute and remove aromatics and chlorinated hydrocarbons. Aromatics and chlorinated hydrocarbons may be used as tank cleaning agents due to their ability of diluting heavier aromatics or hydrocarbons. Occasionally the wall wash may be tested for both U.V. and Nonvolatile matters. It often happens that acceptance or failure of a cargo tank is based on more than one test method, besides the visual tank inspection. If the ship is in port when preparing tanks for U.V testing, pre-inspection should be arranged for. If the ship is at sea when preparing tanks for U.V testing, the tank must be prepared to a high methanol standard, keeping in mind that the cleaning agent may affect the U.V. test. To assist in selection of next cleaning procedure(s), when a tank is rejected, request the surveyor to advise if it was close or far off.

Guidance When preparing the tank for a Nonvolatile Matter test Nonvolatile matter (N.V.M) testing cannot be accurately carried out on board and the ship should select cleaning methods that basically dilute and remove vegetable oils and fats. Basically, this test is carried out to determine the weight of residue (MG/100 ML PPMs) left on the tank surface. The N.V.M detected usually originates from the previous cargo, but can contain other elements such as rust, dust, and tank cleaning product that was not properly rinsed off during tank washing. If the ship is in port when preparing tanks for N.V.M. testing, preinspection should be arranged for. If the ship is at sea when preparing tanks for N.V.M testing, the tank should be prepared to a methanol standard. It is advisable to carry out spot testing in the tank using a spray bottle containing a strong solvent such as Acetone or Hexane. Shortly after spraying small areas, the bulkhead will dry and give you an indication. When the area sprayed become surrounded by a visible oily boundary (burn marks), the tank lining contains residue of the previous cargo. When this indication is seen, it will also be detected by a laboratory N.V.M testing. It is difficult to give an exact comparison of the results from the spot testing versus proper laboratory testing. The following can be used as an indication: 1. 2. Spot testing that is not leaving any burn marks on the bulkhead will indicate a low PPM of N.V.M. Clear oily burn marks will indicate a high a PPM of N.V.M.

To assist in selection of next cleaning procedure(s), when tank is rejected, request the surveyor to advise the actual PPMs.

MECHANICAL DAMAGE FROM TANK CLEANING MACHINES Mechanicla damage to tank coating caused by the impact from portable cleaning machines is one of the most common coating damages we experience. In order to minimize or eliminate such coating damages, the following precautions must be observed.

Rough weather condition 1. 2. Unless there is pressing time demand, tank cleaning with portable machines should not be carried out in rough weather (pitching/rolling). If tank cleaning has to continue, the following precautions should be taken to minimize coating damage: a. Continue cleaning in top level only, where machines are not reaching the coating, until ladders and tank bottom are considered not too slippery for tank entry. b. On completion of washing in top level, continue ventilating until the tank is gas-free. c. Comply with Stolt tank entry procedure

d. Enter the tank and secure the machines in suitable positions for further cleaning using supporting ropes.

All weather conditions 1. A securing rope ( attached from the machines to deck) must always be used in order to: a. Prevent the machines from falling to bottom if they become detached from the cleaning hose. b. Prevent the machines from touching the bottom due to hoses being stretched 2. The cleaning hoses must be clearly marked at intervals (5 feet) in order to determine the correct positions of the machines.

Cleaning machines which are fitted with bumpers will assist in minimizing coating damages, but they should be used in accordance with these guidelines.

LINE CLEANING GUIDELINES 1. Introducing Many off specification First foots have resulted from contaminates remaining in the ships cargo line system. It is therefore most important that all aspects of line cleaning are included in the ships tank cleaning program and are clearly defined. 2. Line cleaning when tank washing: 2.1 During tank washing, a positive line pressure should be maintianed to ensure that all surfaces of the line are washed. The manifold valves should be adjusted to maintain the positive pressure. Crossover manifold, one must ensure that both sides of the manifold are washed out simultaneously with the tank. If fitted, drop lines, restricted gauging and stripping lines must be washed simultaneously with the tank. If any of the valves fitted in the cargo line have plugs, same should be removed. Alll such valves should be opened and closed at regular intervals. This assist the wash water in flushing the valve face and cashing. All drain cocks in the line should have the dust caps off, and the drain cocks flushed at regular intervals. Blind flanges must be loosened at the end of tank washing to ensure proper cleaning. Tank vent lines must be cleaned out during the rough washing as required. All vapor return lines and associated equipment must be thoroguhly cleaned and dried.

2.2 2.3 2.4

2.5 2.6 2.7 2.8

3.

After completion of tank washing: After completion of tank washing, if circumstances permit: all valves. Plugs and drains should be left in the open position. This allows the line(s) to drain and assist in drying.

4.

Visual inspection: The tank inspection, after washing, must include all lines and fittings associated with the tank as outlined in Tank inspection.

5.

Secondary cleaning: When a secondary cleaning methods is found necessary, the same cleaning methods must also be applied to all tank associated piping, including vapor return equipment.

6.

Final cleaning preparation A program for tank preparation can now be carried out (i.e.) fresh water rinsing the tanks, steaming the cargo lines, vent lines, drop lines, stripping lines, restricted gauge pipes and any other fittings required for such preparation.

7.

Line Steaming 7.1 7.2 Check the steam condensate for color and chlorides; if any contaminants found: clear the system. Connect suitable size steam hoses to each side of the manifold of the line to be steamed. Steam the line to the pump stack drain valve, with the pump stack cargo line valve initially closed. During the line steaming, the steam pressure must be sufficient to ensure a flow of steam at the pump stack drain valve outlet and not just condensate. All valves and drain valves including the pump stack valve should be opened and closed at regular intervals during the line steaming. This assist in removing any entrapped residues and dissolves chlorides salts left by the sea water washing. To prevent damage to seals, packings, etc, never force a valve which is heated to open or close. The coefficient of expansion of the seal is different from that of the casing and if force is used, the seal can be damaged. When a valve does not properly function when heated, allow the valve to cool prior to opening or closing. With difficult cargo residues or line design, using a system injector fitted to the manifold and injecting 5 liters of toluene has given very good results. The steam should be sampled at regular intervals at the stack drain valve outlet and condensate checked for contaminants. This will give an indication that the steaming has achieved the cleanliness required or that further cleaning and/or steaming is required.

7.3 7.4

7.5 7.6

8.

Vent Line 8.1 8.2 Vent line must always be fresh water rinsed and/or steamed upon completion of tank washing. When steaming vent lines, ensure that the steam is coming out both ends of line, open and close drain valves vapor return connections at regular intervals, and ensure a positive steam flow at these outlets.

9.

Drop and stripping lines: 9.1 Drop and stripping lines, should be steamed simultaneously when steaming cargo lines.

10.

Line steaming precaution 10.1 Line steaming must be closely monitored to ensure that line and valve seals and packing are not damaged by excessive heat. Do not use excessive force to open or close a valve which is heated.

NON-DESTRUCTIVE PRESSURE TESTING OF HEATING COILS 1. Introduction: Early detection and correction of piping defects in heating coils are of the utmost importance. Leaks have been detected from pittings, defective welds, coupling and sleeves. The proper testing of heating

coils cannot be over emphasized nor can the importance of detecting all leaks and potential leaks prior to loading cargo. The heating coils must be tested for tightness and heating capability. The heating capability can only be confirmed when the heating medium (steam/hot water/thermal oil) is applied. Lack of heating capability can be caused by damaged coils and/or malfunction of steam traps, strainers and valves.

2.

Testing: Non-destructive testing is a common and reliable method of conducting leak tests. The two methods used are: a. b. Hydraulic testing using water. Steam pressure testing.

3.

Frequency Hydraulic testing of heating coils is time consuming and cannot be carried out in all tanks on a regular basis. The hydraulic testing of heating coils must be carried, by ships engineers, once a year, or as dictated by the company, e.g. for (N-30) M/T Stolt Hellluland class follow special guidelines. It is recommended that tank tests are staggered so they are not all due at the same time. Hydraulic testing must be done after any repairs have been made to the heating coils. The results of all hydraulic tests must be recorded in the logbook and the planned maintenance system. Steam testing of coils is to be carried out before the loading of every heated cargo. Thermal oil heating coils are to be hydraulic tested, using oil, every two years. If detects occur, then the coils must be tested annually. The coils must also be tested after any repairs. All coils must be hydraulically tested when they have been replaced following disassembly for coating work, etc. in a docking situation this should be done before leaving the yard. If this is impossible, then testing should be scheduled for as soon as it is practical.

4.

Hydraulic Testing Procedure Cold hydraulic testing is the more severe of the two test methods due to the fact when using steam, heat expansion can cause small leaks to seal, and also higher pressure (1.5 times) than working pressure can be used. When carrying out hydraulic testing, it is important that the tank is completely dry which will make the detection of small leaks much more easier. 4.1 4.2 4.3 4.4 4.5 4.6 4.7 Install blanks to provide the required test boundary. Connect the hydraulic test pump to the coils and install a suitable pressure gauge. Fill the coils with good fresh water. Build up the pressure in the coils to 1.5 times their maximum rated working pressure. Close the hydraulic pump valve to prevent pressure drop. Monitor the pressure of at least 30 minutes, without additional pumping. If a leak is indicated by a pressure drop, then the entire system must be checked until the leak is found.

4.8

After 30 minutes, the coils are to be thoroughly examined. The thorough examination must include a very close visual inspection and also hand-feeling of coils in order to detect any pinhole leaks. Such pinhole leaks may not be indicated by a pressure drop on the manometer and can also be very hard to detect by the eye. Repair the test procedure after repair.

4.9

5.

Steam pressure testing

The testing of coils steam pressure from the ships boiler. Be aware that misleading results can be obtained from steam testing due to steam condensation in the if the test is not properly conducted as described below. 5.1 5.2 5.3 5.4 The maximum pressure to be used is the maximum that can be generated by the boiler. The coils to be tested should be exhausted to atmosphere until live steam is issuing from the return. Close the return against the steam. The steam pressure must be held for 30 minutes prior to inspecting. Carry out visually inspection of the coils for leaks. Exercise great care in the vicinity of the hot coil surfaces. Carefully search for steam release from small pinhole leaks. The light beam form a flashlight will great assist in detecting the mist originating form such small leaks. If a leak is detected and a section of piping has to be repaired, test should be carried out after the repair is completed.

5.5

Corrosion : When carrying our visual inspections for leaks, look closely for signs of corrosion. Corrosion leaks may require further close examination of the coils to determine the amount of damage. This may necessitate the cutting out of sections to determine the extent of possible renewal. All corrosion problems are to be reported to the fleet immediately.

CLEANING , HANDLING AND STORAGE OF CARGO HOSES Cleaning hoses be cleaned after use and always before testing or prolonged storage, Preferably, the initial cleaning should be carried out while hoses are connected between the tank being washed and the slop tank. When hoses are disconnected and the cargo being transferred is considered an easy cargo, only fresh rinsing or live steaming may be sufficient as final cleaning. When applying live steam, the steam hose must be flanged to one of end of the hose and leaving the other end unflanged. The steam hose should be free steam before connecting it to a cargo hose to assure its cleanliness. Cargo hoses with limited heat resistance must be live steamed for short periods only. During live steaming, the hoses cannot be exposed to temperatures exceeding the maximum recommended by the manufacturer. During the final cleaning, it is important to position the cargo hoses correctly n order to facilitate drainage of the washing medium being used. Hoses being facilitate proper drainage of the rinsing medium. Cargo hoses being live steamed must be positioned in such a way that the steam condense is not accumulating in the hose, between the end flanges. When cargo hoses are live steamed in a horizontal in a position, cargo residue is not easily removed from the inner-lining. Damage Prevention

To prevent damage to hoses during cargo transfer, the hoses must be support by tackles. Hoses being transported by crane or derrick must be supported by proper hose sling attached to end flanges only. When closing valves, a vacuum might be created in cargo hoses. The vacuum created may cause the hose to collapse if not carefully dealt with. Pigging of cargo hoses must not be done under any circumstance. Hoses must be electrically earthed to prevent static charge build up, especially when live steamed near flammable areas. Pre-storage requirement Cargo hoses must always be fresh water rinsed or live steamed and drained prior to storing them. If outside storage is the only alternative, the hoses should be sheltered with end of opening always covered.

APPENDIX 4
Product V.A.M Ethyl Acetate Butyl Acetate Oxitol Acetate

etc..
Corrrection factor and typical Density
TEC DCF 1.28 1.20 1.01 1.09 1.13 1.21 1.24 1.20 1.10 1.00 1.16 0.92 0.86 0.81 0.78 0.76 0.76 0.79 1.05 0.77 0.69 0.68 0.67 0.70 0.70 0.81 0.95 0.71 0.76 0.69 0.71 0.78 0.91 0.74 0.86 1.10 0.94 1.06 0.82 0.91 0.79 Density @ 15C 938.6 906.6 886.5 978.0 1054.9 1087.1 1226.5 961.0 929.0 899.0 949.1 795.9 793.6 789.2 807.5 805.8 813.4 792.0 792.0 953.2 822.6 834.0 832.0 828.7 839.5 810.5 1133.0 832.0 838.0 822.4 818.4 813.2 813.5 836.0 1026.0 694.6 737.7 711.6 763.6 732.6 1019.0 Product Ortho-Xylene Para- Xylene m-Xylene Iso- Propyl Benzene (Cumene) Pseudo Cumene Vinyl Benzene (Styrene) CHLORINATED SOLVENTS Carbon Tetra Chloride Chloroform Methylene Chloride Tri- Chloroethylene Perchloro Ethylene 111 Trichloroethane TEC 0.00094 0.00101 0.00098 0.00099 0.00092 0.00096 0.00120 0.00124 0.00135 0.00113 0.00101 0.00123 GLYCOL 0.00063 0.00067 0.00073 0.00069 0.00067 DCF 0.83 0.87 0.85 0.86 0.81 0.87 1.92 1.86 1.80 1.66 1.65 1.66 0.74 0.75 0.75 0.78 0.68 1.11 1.04 0.92 0.91 0.89 0.81 0.72 0.76 0.87 1.02 0.88 0.88 0.86 0.80 0.81 0.82 0.74 0.81 0.73 0.75 0.70 Density @ 15C. 884.3 865.4 870.0 866.1 879.8 910.8 603.7 1498.0 1334.0 1472.4 1631.1 1345.9 1117.1 1120.0 1029.0 1127.0 1008.0 796.0 810.1 805.3 815.8 951.0 743.0 772.3 761.0 910.8 686.1 658.0 663.8 682.9 696.0 706.6 1050.6 987.7 976.0 971.0 972.4 971.2

ACETONE 0.00136 0.00132 0.00114 0.00111 ACID Acetic Acid 0.00107 Acetic Anhydride 0.00111 Formic Acid 0.00101 ACRYLATE Methyl Acrylate 0.00125 Ethyl Acrylate 0.00118 Butyl Acrylate 0.00111 Methyl metacrylate monomer(MMM) 0.00122 ALCOHOL Mehtanol 0.00116 Ethnol (Ethyl acohol) 0.00108 Iso Propyl Alcohol (IPA) 0.00103 N-Propyl Alcohol (NPA) 0.00097 Iso Butyl Alcohol (IBA) 0.00094 Normal Butyl Alcohol (NBA) 0.00093 2-Butanol 0.00098 Tertiary Butanol 0.00133 Cyclohexano 0.00081 Heptanol 0.00084 Iso Octanol 0.00081 Octanol 0.00081 Nonanol 0.00084 Iso Decanol 0.00083 Methyl Iso-Butyl Carbinol 0.00100 Furfuryl Alcohol 0.00084 Linevol 79 0.00085 Linevol 911 0.00091 Hexanol 0.00084 Amyl Alcohol 0.00087 Amyl Sec. Alcohol 0.00096 Tertiary Amyl Alcohol 0.00112 2-Ethyl Hexyl Alcohol 0.00088 AMIINE Aniline 0.00084 Iso Propyl Amine 0.00158 Iso Butyl Amine 0.00127 Di Ethyl Amine 0.00149 Di Butyl Amine 0.00107 Tri- Ethyl Amine (TEA) 0.00124 Mono Ehtnaol Amine 0.00078

Mono Ethylene Glycol (MEG) Di Ethylene Glycol (DEG) Di Propylene Glycol (DPG) Tri-Ethylene Glycol (TEG) Mono Butylene Glycol (MBG) KETONE Acetone (DMK) 0.00139 Methyl Ethyl Ketone (MEK) 0.00128 Methyl Iso-Butyl Ketone (MIBK) 0.00114 Methyl N-Butyl Ketone (MBK) 0.00111 Cylco Hexanone 0.00094 OLEFFINICS Proplen Trimer 0.00109 Propylene Tetramer 0.00093 Oleffins C11 C12 0.00100 Styrene Monomer 0.00096 Isoprene 0.00149 PARAFFINIC SOLVENTS I -Hexane 0.00134 N-Hexane 0.00133 I- Heptane 0.00126 I- Octane 0.00115 N- Octane 0.00114 PHTHALATES Di Butyl Phthalate (DBP) 0.00078 Di Octyl Phthalate (DOP) 0.00075 Di Iso Nonyl Phthalate (DINP) 0.00083 Di Decyl Phthalate (DDP) 0.00075 Di Iso Decyl Pthalate (DIDP) 0.00077 Di Nonyl Phthalate(DNP) 0.00072 SOLVENTS

Triethanol Amine-99 Ethylene Di- Amine AROMATIC Benzene Toluene Ethyl Benzene

0.00049 0.00104 0.00119 0.00106 0.00101

0.55 0.94 1.05 0.92 0.88

1126.0 900.0 884.2 871.6 871.3

Cyclopentane Methyl Cyclo hexane Cyclo Hexene Methyl Cyclo Hexane Dobane MTBE TDI Acrylonitrile

0.00130 0.00123 0.00118 0.00113 0.00080 OTHERS 0.00142 -

0.98 0.93 0.92 0.87 0.70 1.03 1.02 1.10

750.2 753.4 783.1 773.4 870.0 746.0 1222.9 811.9

CONVERSION FROM TO S/G 15.56/4 C S/G 15.4 C S/G 25/25 C S/G 15/4 C S/G 20/20 C S/G 15/4 C S/G 15.56/A5.56 C S/G 15/4 C

FORMULA (S/G CORR. FACTTOR) X 0.56 + S/G @ 15.56 C (S/G 25/25 C x 0.997080) + (S/G CORR. FACTOR x 10) (S/G 20/20 C x 0.998230) + (S/G CORR. FACTORE x 5) (S/G 15.56/15.56 C x 0.999040) + (S/G CORR. FACTOR x 0.56)

HEATING INSTRUCTION
COMMODITY Voy Heating Temp min/max C 28-32 30-35 27-32 Ambient 27-32 25-30 40-45 32-40 55-60 20-25 20-25 Ambient Ambient Ambient Ambient Ambient Ambient Ambient Ambient Disch Heting Temp min/max C 35 40-45 40-45 20-25 40-45 25-30 60-65 50-55 62-65 25-30 38 63-69 30-38 Ambient 60-65 60-65 60-65 63-74 35 Ambient Ambient 74-80 64-70 74-80 75-80 75-80 64-70 55-70 70-80 36-38 65-75 65-75 65-75 45-70 Ambient 30-35 30-35 30-35 40-45 50-55 25-30 60-65 50-55 25-30 60-65 25-30 60-65 50-55 Ambient 85 Pollution Category Prewash required N2 Purge UN No. Heating Adjacent

Cashewnut sheel liquid Castor Oil Coconut Oil Cotton Seed Oil Crude Palm Kernel Oil Crude Palm Olein Crude Palm Stearin Crude palm oil Crude tall oil D.F. Palm Olein Dehydrated Castor Oil E.F.Tallow Ethylenediamine Heptane Hitec 1453M Hitec 1457 Hitec 1459 Hitec 611 Hydro Canola IPA Isopar M Lubad 743 7819A Lubrizol 3593 Lubrizol 4970 Lubrizol 4994E Lubrizol 4994E Lubrizol 6446 Lubrizol 6950J Lubrizol 7819A Lubrizol 78988 Lubrizol 8960 Lubrizol 8960B Lubrizol 8960B Lubrizol 9915M MEK Menhaden Fish oil Methyl Ester Palm kernel Caprylic Capriic Acid NBD Palm Kernel Olein NBD Palm Kernel Stearin NBD Palm Oil NBD Palm Olein NBD Palm Stearin Neutralised Bleached Palm Oil Neutralised Bleached Palm Olein Neutralised Bleaches Palm Stearine Neutralised Palm Olein Neutralised Palm Stearin Neutralised palm oil Norpar13 Oloa 219SM

Ambient Ambient Ambient Ambient Ambient Ambient Ambient 20-25 20-30 25-30 35-40 32-40 25-30 40-45 32-40 25-30 40-45 25-30 40-45 32-40 Ambient Ambient

B B B B B B B C

Yes Yes Yes Yes Yes Yes

Oloa 6750 Oloa 9050C POP Fat Palm Acid Oil Palm Fatty Acid Distillate Palm Mid Fraction Paranox 52 Paranox 52 Paratone 8103 Paratorq 4599 Parraffin Wax Phenol Polybutane Pranox 15 RBD Palm Kernel Olein RBD Palm Kernel Stearin RBD Palm Oil RBD Palm Olein RBD Palm Stearin Resin383 (DER) Salim FA26 Solv 150 Splitters Crude Glycerin Sunflower Seed oil TLX414 Tallow 9377 Voranol 3010 polyol Voranol 3022 polyol Acetic acid P.G USP DER-385 Diala-B

Ambient 33-36 42-50 42-50 26-32 71-82 71-82 80-85 Ambient 60 51-55 79-88 Ambient 25-30 35-40 32-40 25-30 40-45 20-40 Ambient 30-30 Ambient 37-54 44-49

18-32 Ambient 40-45 Ambient

82 65 40-45 67-72 67-72 44-49 82-88 82-93 93-110 Ambient 65-70 51-55 79-88 Ambient 37-42 40-45 50-55 25-30 60-65 45-55 30 Ambient 55-56 15-20 60-76 55-60 24-38 24-38 18-32 Ambient 45-55 Ambient

A D D

Yes

TOKYO WAN AND TOKYO MARTIS DANGEROUS CARGO LIST

PRODUCT 1- Octene 1.3.Dichloroprpene 3 Ethoxypropionate (Ucar ester eep) Acetic acid Acetone Acrylic acid Acrylonitorile Alpha methyl styrene Alpha oleffin C10/12 Alpha oleffine C6 Aniline Butane Butyl Acrylate Carbon Tetra Chloride Caustic Potash Cellosolve Acetate Cellosolve solvent Crude Oil Cylclohexane Decene 1 Dicylopentadiene Diethylene Triamine Diethelformamide Dowal PM-E Glycol ether Epichlorohydrin Ethyl 2 ethoxy propinate Ethyl Acrylate Ethyl Alcohol Ethylene diamine Ethylene dichloride Ethylene Glycol Monoethyl Ether Ethylene Glycol Monoethyl Ether Acetate Hexandiamine Hexene-1 Iso Butyl Alcohol Iso Propyl Alcohol Isopar G Metha Xylene Methyl Alcohol Methyl Cellosolve Methyl Isobutyl Ketone Methyl Metahacrylate Methyl Tertiary Butyl Ether Mixed Xylene Nonene Normal Butyl Acrylate Normal Butyl Alcohol Normal Butyl Methacrylate Normal Heptane Normal Propyl Alcohol Octene Para Xylene Phenol Propane Propionaldehyde Propionic Acid Propylene Glycol Methyl Ether Propylene Oxide Propylene Tetramer Styrene Monomer Toluene Ucar Ester EEP Vinyl Acetate Monomer White Spririt F.P 21 C 29 58 poison 20 poison 0 58 47 26 poison2 gas 49 poison corride 52 43 0 20 50 26 corride 58 39 poison2 58 9 13 corride 13 54 57 corride -29 28 22 42 27 12 46 24 10 28 27 26 49 29 52 -4 15 21 27 poison2 gas 15 poison 34 -37 58 32 7 58 -3 43 UN NO. 199302(B) 2047 (B) 199303 (C) 2789 (C) 1090 2218 1093 2303 126801 126801 1547(C) 1011 2348 1846 1814(D) 1172(D) 1171(D) 1267 1145(C) 126803(B) 2048 2079(D) 2265(D) 1993 2023(A) 199303 1917(A) 1170 1604(C) 1184(B) 1171(D) 1172(D) 1783(C) 1268 1212(C) 1219 199303 1307 1230 1188(D) 1245(C) 1247 2398 1307 2057(B) 2348 1120(B) 2227 1206 1274(D) 1993 1307 2821 1978 1143 1848 199303(D) 1280(D) 2850 2055(B) 1294(B) 199303 1301(C) 1300

MANAGEMENTS FOR DRYING OR SEMI-DRYING OILS Drying or Semi-drying oils will adhere to the tank surface in the form of a thin hard (Varnish) film if the tank is allowed to become hot or dry. DRYING OILS CANDLE NUT OIL FISH OIL LINSEED OIL POPPYSEED OIL SAFFLOWER OIL SESAME OIL SOYABEAN OIL TALL OIL TUNG OIL WALNUT OIL SEMI-DRYING OILS BABASSU OIL COD OIL CODLIVER OIL COTTON SEED OIL RAPESEED OIL SESAME OIL SUFLOWERSEED OIL WHALE OIL WHEAT OIL NON-DRYING OILS CAMPHOR OIL CASHEW NUT OIL CASTOR OIL COCONUT OIL COCONUT FATTY ACID GROUND NUT OIL LARD OIL(ANIMAL) HOG GREASE OLIVER OIL PALM OIL PALM FATTY ACID PALM OIL KERNERL RAPESEED RICE BRAN OIL SHEANUT BUTTER TALLOW OIL WATER SOLUBLE MOLASSES MOLASSES RESIDUE SPYA WHEY WATER LIGNIN PITCH

Remarks; Drying ro Semi-drying , . , , 2-3 , .

ODM CHECK LIST (SIMULATION)

DATA SHEET OF ONBOARD TEST FOR ODM (SASAKURA)

1) Calculation & Alarm of instantaneous discharge rate -3 Formula : L/M = C x Q x 10 C : Oil content (ppm) V V : ship speed (knots) Q : discharge flow rate (m3/H) Settings Results Item Oil content Ship speed Discharge flow rate Inst. Discharge rate 0 L/M 20 30 8 32 Alarm 20 L/M Off On On Off On 30 L/M Off Off On Off On Sea valve control Open Open Shut Open Shut Check of results Good Good Good Good Good

250 m3/H (1) 0 ppm 5 knots (2) 400 5 250 (3) 600 5 250 (4) 400 10 250 (5) 800 5 250 2) Calculation & Alarm of Total Oil Formula : Total oil = C x Q x 10-3 dt (liter) 60 Item Condition

C : Oil content (ppm) Q : Discharge flow rate (m3/H) t : time (minutes) Results Total oil Inst. Alarm Discharge T.oil rate

Check Sea valve of results control

Set at the following condition - Oil content = 900 ppm - Ship speed = 10 knots - Discharge flow rate = 200 m3/H - Total oil limit = 6 x 10 liters (2) Reset total oil (3) 10 minutes after the reset (4) 20 minutes after the reset 3) Accuracy of flowmeter Time Tank Qtty of ullage water Mesuring Start

(1)

0 x 10 L 3 x 10 L 6 x 10 L Change of quantity

18 L/M 18 L/M 18 L/M Flow rate

Off Off On Average flow rate

Open Open Shut Average indication

Good Good Good Acccuracy

Mesuring stop Note : measuring method tank ullage Manual sounding Local counter of float gauge

remote counter of float gauge