Académique Documents
Professionnel Documents
Culture Documents
Code N~.
(5)s ';f.
56/3
Roll No. Candidates must write the Code on
W1 ;t. the title page of the answer-book.
tRTaw.IT C!5ls em 3'rR -~~QJI W- ~-~
1:R~~ I
CHEMISTRY (Theory)
~fa"m;J(~)
56/3 1 p.T.a.
•
General Instructions :
(i) All questions are compulsory.
(ii) Marks for each question are indicated against it.
(iii) Questions number 1 to 8 are very short-answer questions and
carry 1
mark each.
(iv) Questions number 9 to 18 are short-answer questions and carry
2 marks each.
(v) Questions number 19 to 27 are also short-answer questions and
carry 3 marks each.
(vi) Questions number 28 to 30 are long-answer questions and carry
5 marks each.
(vii) Use Log Tables, if necessary. Use of calculators is not allowed.
~~:
(i) ff'ift ~ 31f.:r"cff4 $' I
(vii) 3WH4q,d/rf.f;-{/~"fifrr
~ I
'" ~ q:;r m cR I cJ,r::Pc1c:.~} ~ ~ ctt 3R11frr
'" ;rif
1
6) What is meant by the term 'pyrometallurgy' ?
inN_~' it CFIT ~ mm ~?
56/3 2
I
OH
OH
/,
i7~)
',-
What does '6,6' indicate in the name nylon-6,6 ? 1
~-6,6 ~ if ~ '6,6' 'Cp1T ~ Cfi\(IT * ?
8.
1
D
.~
2
Complete the following chemical reaction equations :
(i) XeF2 + H20 --7
(ii) BH3 + HgC12 --7
r r r. r ~ ~J-;lcp\u~ ciT ~ ~
(i) 0
0(CH3 + HI --7
56/3 3 p.T.a.
~---
--- ------------ . 1
I
11. Which one in the following pairs undergoes SN1 substitution reaction
faster and why ? 2
CI rn
(i) /I~ or ~
Cl. Cl
(ii) ~ or~
r r r: ~ if it ~ ~-SNI ~ ~:m~"ffiwIT it ~ ~ 31R
CFff?
Cl
(i) /I~
Cl
(ii) ~ 3l~ ~Cl
2
~comPlete the following chemical reaction equations:
, (i) MnO~ (aq) + C2O~- (aq) + H+ (aq) ~ .
(ii) Cr2O~- (aq) + Fe2+ (aq) + H+ (aq) -7
r r r r:m~ ~~·iICPo(Y~ cit 1:[Uf ~
13.
_
Describe
/' /- I
.. -,""
the Tole of the following : 2
~ NaCN in the extraction of silver from a silver ore.
(ii) Cryolite in the extraction of aluminium from pure alumina.
r rr ctT ~ CfiT quf;r ~ :
56/3 4
14. Define the following: 2
(i) Order of a reaction
(ii) ,Activation energy of a reaction
r r.r._ .. ~ -qft~ ~ :
(i) 31f~ c8 W
(ii) 31f~ c8 ~r~"jul ~
15. What type of cell is a lead storage battery ? Write the anode and the
cathode reactions and the overall cell reaction occurring in the use of a
lead storage battery. 2
OR
Two half cell reactions of an electrochemical cell are given below :
16. Name the four bases present in DNA. Which one of these is not
present in RNA ? 2
'qR ~ ~ ~ ~ ~ DNA if fc1'C.l~I..-j ~ I ~ it ~ ~ RNA if ~
~ ~ ?
56/3 5 p.T.a.
i/::;"~;
(.!_71 Differentiate between condensation and addition polymerisations. Give
one example each of the resulting polymers. 2
~ q§,(1cnlcn~ul 3fu: <iljll\<-icn q§,(1cnlcn{UI if ~ ~ ~ I ~ ~ c:rr#r ~
m it ~ q:;r~-~ ~c;.IQ{UI ~ I
~/--.
?!g~ Name two fat soluble vitamins, their sources and the diseases caused
'-- - due to their deficiency in diet. 2
qm if :!c.1•.p{ (1 G) fcR:1f~ it -;w:r,
11 ~ ~ 31R ~ ~ if CfilTI ~ ~ qTffi
:J, .. r. .Ii it -;w:r ~ I
19. Silver crystallises with face-centred cubic unit cells. Each side of the
unit cell has a length of 409 pm. What is the radius of an atom of
silver ? (Assume that each face atom is touching the four corner
atoms.) 3
~ ~-~ er.:fm ~ iwr if r9h~r(1c1 ~ ~ I ~ iwr it ~ fcfnR cnl
~409pm~ I ~~cnl~CFIT~? (~~~fcn~
') ~:qRf ~ it ~3TI ~ "Cf)\ill ~ I) m
20. A first order reaction has a rate constant of 0·0051 min-I. If we begin
with 0·10 M concentration of the reactant, what concentration of the
reactant will be left after 3 hours ? 3
~ >f2p1 c8R:- cnl 31f~ q:;r G\ ~ 0·0051 min-1 ~ I ~ ~ ~ it
0·10 M ~ it ~~ ~ ~, -ffi 3 ttZ ~ ~ ~ ~ it1f W
~?
(Given: EO
Ni 2 +/ Ni = - 0·25 V, EO
AI 3 + / Al = - 1·66 V) 3
r r r. ~_~
All A13+ (0,0010 M) 31R Ni I Ni2+ (0·50 M)
it ~~ ~ ClI<.'"GI~ iwr 25° C ~ ire cnl ~ ~ I ~ iwr ~ ~-mu ~
Cfi«IT ~ -ffi ~ cnw iwr ~ it ft;m: ~<-ilcn{ UI ~ 3fu: iwr fcrqq ~
~I
(~ TJ7.IT ~ : EO
Ni 2 +/ Ni = - 0·25 V, EO
AI 3 + / AI = - 1·66 V)
56/3 6
22. What happens in the following activities and why? 3
(i) An electrolyte is added to a hydrated ferric oxide sol in water.
(ii) A beam of light is passed through a colloidal solution.
(iii) An electric current is passed through a colloidal solution.
r..or or., , M3TI if CF1T ~ ~ 3lR ern ?
(i) 7j[B" if \J1c:1<.iif\J1<1
~ ~ if ~ ~-~
3-lTcffil~s ~ ~ ~
(ii) ~ fcm<:Rif it wmr $1
ct)c:1T~sl ~ ~ m-r ~ ~ I
/Liii) ~ fcm<:Rif it ~
ct)c:1T~sl mu ~ <tt ~ ~ I
t.-- ..,·::"'/"..... ,/
r rr itCfiRUT~~:
(i) ~ it .awq ftl:R it 3-l~Lhc:1chl<.!
cnT~cffi ~ ~ i
(ii) ~ ~ mq) it ~ m n-cnT~q-~ \ifH ~ iI
(iii) ~-m ~3TI it ~. CO fuitug NH3 <tt ~ 31f~ ~ ~
3l~
f:ikff~f.(9<1
~ (cnT~cffil) <tt "¥AT, ~ ~ <tt ~ 3-l1~~<.!1,.. .'L
0
~ ~ ~cnl~~'if ~ 00 it ~
3-lT~C.C1I· if ~ : 3
(i) [Ni(CN)4J2-
(ii) [NiC14J2-
(iii) [CoF 6J3-
['WJTll] ~ : Ni = 28; Co = 27J
56/3 7 p.T.a.
------,---.-------------
I
56/3 8
•
r rr ~ it Tf ~ i: ~
° ~1-;lctl-tU~
II LiAlH4 .
(i) R - C - NH2 )
H20
27. What are the following substances? Give one example of each of
them. 3
(i) Cationic detergents
(ii) Enzymes
(iii) Sweetening agents
r rr~.\: 'iC\I"1 cp:rr (!m (! ..•
~;): ( ~>t\"1q') CfiT ~-~ -:$<;IQ-tUI ~<..,11\)1'-' I
(i) ~ 31\.j"I~ctl
(ii) l!,~I~.,
(iii) ~GHII (r"dl~ctll-t) • (~)
56/3 9 P.T.D.
(a) Hkjrc1r~d ~ ~ ~ ~ :
(i) l1Wr am
(ii) CfR ~ ~
(b) ~ ~ ~ 1R ~ ~ ~ if ~ rjl~~I\!jrj ? ~
t
f1rc;mr CflT ~ Cf<IT ~
29. (a) Write chemical equations to illustrate the following name bearing
reactions:
(i) Cannizzaro's reaction
(ii) Hell-Volhard -Zelinsky reaction
56/3 10
~~1- I
(ii) ~-~-~rC1«h1 ~
" ?""~
<:il-\lcp'('UI CfiT I\'II~~ I
(ii) H2S207
56/3 11 . P.T.D.
~~-~1~--------~~-~------~---------------------J1
(i) XeF4
(ii) H28207
(b) H~r~r~~ 3-fC/ctlChrllc€r cx:m§'1T ~ :
mm ~ I
31~
(ii) 80;-
(b) H~r\1r~~ 3-fC/\1IChrll
~ 31f'iW: ~ ~ :
56/3 12 97,100