AUSMAT CHEMISTRY 2013 Test One Name: Class: Time: 8.00 a.m 9.00 a.

m (1Hour)

Answer all the questions below. Fill the answers for multiple choices in the boxes at page

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

Answers for multiple choices 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.

Section two: Short Answers 1. a)For each species listed in the table below, draw the structural formula, representing all valence shell electron pairs either as : or as and state or draw the shape of the molecule and state the polarity of the molecule Species Structure (showing all valence shell electrons) Shape (sketch or name) Polarity of molecule

Nitrogen trichloride

NCl3
Methanal

HCHO
Sulfur dioxide

SO2
Carbon Dioxide

CO2
Hydrogen Sulfide

H2 S
5

1. b) Using the axes provided, sketch a line graph to represent the relationship in EACH of the following:

(a)

The first ionisation energies of the alkali metals Li, Na, K, Rb and Cs.

First Ionisation Energy

Li

Na

Rb

Cs

(b)

The boiling points of the hydrides of the group VII elements

Boiling Point

HF

HCl

HBr

HI

[2 marks]

2. a.

Group the following liquid substances into appropriate columns below according to their dominant type of intermolecular forces that exist between their molecules. {Nitrogen, OBr2, CCl4, chlorine monofluoride, C2H5OH, hydrogen fluoride }

Dispersion

Dipole - Dipole

Hydrogen Bonding

[3 marks] b. (a) the following table gives some data about two elements in the fourth row of the Periodic Table.
Melting Point ( C) Potassium (K) Germanium (Ge) 63 937
o

Element

First Ionisation Energy (MJ mol ) 0.43 0.77

-1

Electrical Conductivity (MS m ) 14 10

-6 -1

Chloride and its melting point ( C) KCl 770 GeCl4 -50

o

Explain the difference in the melting points of KCl and GeCl4 . You may like to use diagrams and/or illustrations to help with your explanation.

[2 marks] 7

Extended Answer Select a row (an example is Period 3) of the periodic table, and describe and explain the relationship between the number of valence electron and an elements I. II. III. IV. bonding capacity position on the periodic table physical and the chemical properties ionisation energy

(10 marks)

The end

Prepared by Mr Mohanaraj Balakrishnan