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  • Efh c2210 130614 DOC061613

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    Beauponte Pouky Mezonlin
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    Endo, exo, syn, anti Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[x.y.z]alkane (x >= y >= z >= 0 for x and y 0) if the group is oriented towards the highest numbered (locant) bridge it is given the description endo; if it is oriented away from the highest number of bridges it is given description anti.

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    Endo, exo, syn, anti Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[x.y.z]alkane (x >= y >= z >= 0 for x and y 0) if the group is oriented towards the highest numbered (locant) bridge it is given the description endo; if it is oriented away from the highest number of bridges it is given description anti.

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    9 vues11 pages

    Efh c2210 130614 DOC061613

    Transféré par

    Beauponte Pouky Mezonlin
    Endo, exo, syn, anti Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[x.y.z]alkane (x >= y >= z >= 0 for x and y 0) if the group is oriented towards the highest numbered (locant) bridge it is given the description endo; if it is oriented away from the highest number of bridges it is given description anti.

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    Stereochemical Descriptors for Bicyclo[x.y.

    z]alkanes (For CHM 2210 Prior to coverage of R/S Configurational Notation) endo, exo, syn, anti
    Descriptors of the relative orientation of groups attached to non-bridgehead atoms in a bicyclo[x.y.z]alkane (x y z 0 for x and y 0).

    If the group is oriented towards the highest numbered (locant) bridge (z bridge, e.g. C-7 in the examples of bicyclo[2.2.1]heptanes below) it is given the description exo; if it is oriented away from the highest numbered bridge it is given the description endo. If the group is attached to the highest numbered bridge and is oriented towards the lowest numbered bridge (x bridge, e.g. C-2 in the examples of bicyclo[2.2.1]heptanes below) it is given the description syn; if the group is oriented away from the lowest numbered bridge it is given the description anti.

    Adapted from Pure and Applied Chemistry 1996, 68, 2207 by E. F. Hilinski on May 15, 2013.

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