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Mr. Rizwan Ashraf
M.Sc.Chemistry ,0322-5488090
rizwan_chemist@yahoo.com

Chemistry XI Max. Marks 25

Chapter.04 Name: ..................

Q.No.1a)MCQ’S 1x10=10
1Which one of the following in its crystalline form will have lower enthalpy change of vaporization
a. Cl b. Ar c. P d.Si
2.When external pressure is 25mmHg then water will boil at
a.100 C b. 200 C c.98 C d.25 C
3.CO2 & SO2 are both triatomic molecules but heat of vaporization of SO2 is greater than that of CO2 this is due to
a. greater electronegative character of S b. greater size of SO2 molecule c.SO2 is polar and CO2 is non-polar
d.SO2 is more acidic in nature than CO2
4.The angles a=g= 90,b=90 are present in crystals of
a. Manganese oxide b. Boric acid c. Borax d. Bi
5................ has body centered crystals
a.Daimond b.NaCl c.iodine d.both a & b
6.saturated hydrocarbons having C atoms more than 20 in a molecule are solids due to
a.higher densities b. higher mol.mass c the chain are more zig zag d.all of these
7.Ammonia shows a maximum b.p among the hydrides of V-A group elements due to
a. very small size of nitrogen b. lone pair of electrons present on nitrogen c. enhanced E.N chracter of nitrogen
d. pyramidal structure of NH3
8.the polarizabilities of elements mostly increase down the group due to the reason that
a. the atomic no. increases b. no. of protons increases c. no. of shells increases along with increase of shielding effect
d. the behaviors of the elements remain the same
9. In DNA molecule the H-bonding is between
a. C and H b. O and N c.N and H d.O and H
10..............has highest lattice energy
a. LiBr b. LiCl c. LiF d.LiI

b)Give short answers

1.What is distribution law?Also give an example to support your answer 03

2.Piroxicam, a non-steroidal anti inflammatory drug is water soluble,it is also soluble in acetone.During its
preparation it remains in aqueous layer, write method that how will you separate it from aqueos layer 03
3.An organic chemist has prepared a product in acidic and oxidizing medium, at end he
wants to filter the reaction mixture, write down the best suitalble method of filteration
which he will adopt ? 03

4. If you are asked to prepare the crystals of benzoic acid, which properties
solvent should have,you are going to use. 03

5. Chromatography is a separation technique 03

a) On which basis separation takes place?

b) Why we cover the chromatographic jar before placing chromatogram in it?