2013 Cshstedp

Experiment Title: Plant Viability in NanoRack Doc.
Version: 1 Food Growth Chamber Organization: Clear Springs Date: Page: 1
TEST EQUIPMENT DATA PACKAGE

Principal investigators name Alli Westover Clear Springs High School 501 Palomino Drive League City, TX 77573 281-284-1300 awestove@ccisd.net Cell Phone: 832-876-5724 Co-Principal Investigator Dr. Joe Morgan 3008 Aztec St College Station, TX 77845 morganj@suddenlink.net HUNCH NASA JSC Florence Gold, Ed.D. HUNCH Reduced Gravity Experiments/Web/Video Production Expert Montana State University- Billings, MT Phone: 406-690-2661 E-mail: Florence.V.Gold@nasa.gov
Experiment Title: Plant Viability for a NanoRack Food Growth Chamber

TEDP Completion Date: February 13, 2013
Verify that this is the correct version before use.
Experiment Title: Plant Viability in NanoRack Doc. Version: 1 Food Growth Chamber Organization: Clear Springs Date: Page: 2
CHANGE RECORD
Doc. Version 2 3 4 5 6 7 8 9 10 Date Description Added MSDS Sheets Added various Silicones to Equipment Description Changed Experiment Description Added Solenoid Valve to Equipment Description Added CO2 Sensor to Equipment Description Changed Total Weight Changed Moisture Sensor Picture Updated CO2 Sensor Description Updated MPGE (microcontroller) Control Board Description Page No. 67-101 16 9-11 13 13 19 13 13 12 Change Authority Nathan Hoffman Nathan Hoffman Nathan Hoffman Asim Momin Asim Momin Asim Momin Sanif Ali Asim Momin Asim Momin
4/19/13 4/22/13 4/22/13 4/29/13 4/30/13 5/8/13
QUICK REFERENCE DATA SHEET (AOD0072)

Team Name: Clear Springs High School HUNCH Team Principal Investigator: Alli Westover; CoInvestigator: Dr. Joe Morgan Contact Information: 501 Palomino Drive League City, Tx 77573 281-284-1300 Experiment Title: Plant Viability for NanoRack Food Growth Chamber Work Breakdown Structure (WBS): Flight Date(s): April 11, and April 12, 2013 Overall Assembly Weight (lbs): 74.001249 oz Assembly Dimensions (L x W x H): 10cm X 10cm X 15cm Equipment Orientation Requests: Yes, we need to have a horizontal glove box Proposed Floor Mounting Strategy (Bolts/Studs or Straps): NASA approved glove box will be bolted to the aircraft floor Gas Cylinder Requests (Type and Quantity): None requested Overboard Vent Requests (Yes or No): No Power Requirement (Voltage and Current Required): One aircraft power outlet (115 VAC 60 Hz) Free Float Experiment: No Flyer Names for Each Proposed Flight Day: Kevin Ly, Dylan Davis, Keith Esthay, Tyler Lori, Lucas Heaven, Alex Zahabizadeh Camera Pole and/or Video Support: GoPro provided by Clear Springs High School. Clear Springs High School
TABLE OF CONTENTS
Section__________________________________________________________________Page Number Change Page Quick Reference Sheet Flight Manifest Experiment Background Experiment Description Equipment Description Structural Verification Electrical Analysis Pressure Vessel or System Information Laser Certification Parabola Details Free Float Requirements Institutional Review Board Information Hazard Analysis Tool Requirements Photo Requirements Aircraft Loading Ground Support Requirements 36 Hazardous Material 37 Material Safety Data Sheets (MSDS)
2 3 6 7 8-11 12-18 20 21-26 27 28 29 30 31 32 33 34 35
38-100
Procedures Bibliography Deviations/Exceptions/Waivers
101-102 103 104
FLIGHT MANIFEST
Flight One Name Alex Zahabizadeh Tyler Lori Willis Twigge Samson Mathew Allison Westover Flight Two Name Organization CSHS HUNCH CSHS HUNCH Texas A&M CSHS HUNCH CSHS HUNCH Flyer/Ground Crew Flyer Flyer Flyer Ground Crew Ground Crew
Organization
Lucas Heaven CSHS HUNCH Dylan Davis CSHS HUNCH Kieth Esthay CSHS HUNCH Samson Mathew CSHS HUNCH Allison Westover CSHS HUNCH Kevin Ly flying with another HUNCH group, group A. EXPERIMENT BACKGROUND
Flyer/Ground Crew Flyer Alternate Flyer Flyer Ground Crew Ground Crew
The experiment is being flown as part of the High School Students United with NASA to Create Hardware (HUNCH) program from a Project Lead The Way (PLTW) school. It was designed by the students of the Engineering Design and Development program at Clear Springs High School in League City, Texas.
The plant growth chamber will grow legumes that will be supported by our artificial biome. A plant growth chamber has been developed to reduce the need for food resupply in space, especially for long duration missions. The experiment will test plant viability of the Medicago truncatula because it is easy and fast to grow, which is ideal for multiple trials. The chamber should allow enough room for the plant to grow while meeting the regulations and constraints provided by NanoLabs. Some of these requirements are an end-cap microcontroller, a camera as a part of the microcontroller and positioned over the plant chamber to take pictures for data, three levels of water containment (metal box, IV bag and tubing, inside box), more space for the plant, and the chamber is automated through the
microcontroller system that has been developed by Texas A&M University. Power will be delivered to the experiment via the laptop USB controlled by a laptop and is completely automated. The constraints are the size 10 X 10 X 15 cm cubed units, zero gravity environment, water cannot touch the electrical system, and low current for solenoid valve/ pinch valve/ sensors. The system will include LED lights, a water distributor, Gore-Tex, rock wool, a camera, and sensors that will measure moisture and carbon dioxide. Two years ago, an aeroponics design used a water misting/fogger system. However, their project exceeded size limitations as well as had problems with their misting system. Last years class redesigned the system to fit in 1.5U NanoLab and revised the watering and feeding system. The new system involved rubber bands wrapped around two Lexan plates on the either end of the IV bag. Other changed factors include using rock wool as food and a stationary holder for the plants. Also, they utilized a Gore-Tex membrane to let oxygen and carbon dioxide flow freely through the system while retaining any moisture released by the plant via transpiration. The lighting system will be the same and include blue and red lights to give the proper wavelengths to stimulate plant growth and simulate night and day.
EXPERIMENT DESCRIPTION
All components play off one another in various ways. If the moisture sensor doesnt give the correct water ratio, the plant could become either dehydrated or over watered and will suffer as a result. We were hoping to find pH and carbon dioxide sensors but so far have been unsuccessful. If we do find the sensors, we will use them for collecting data and seeing what conditions the plant grows the best under. The tubing is important for hydrating the plant and the water pressure determines how long the solenoid will open to give off the water. The microcontroller controls all of the sensors and records the data. The camera will take pictures of the plant throughout its growth. The food chamber will be in a NanoLab and will be in a zero gravity environment. The microgravity environment increases the difficulty of providing the basic needs for the plant which will affect its growth. So it is necessary for us to come up with non-mainstream ideas of how to go about with the nutrient transportation and water containment otherwise the plant could die. Therefore, the plant must have the essentials it needs to survive on land and in space as well.
Flow Chart Diagram
Plant Chamber
Rod
Plant Box
Tray
Cap
EQUIPMENT DESCRIPTION
A.
Ground-Based and Flight Equipment a. b. c. Pictures and descriptions of all equipment: (See table below) Dimensions and weights: (See table below) Hardware Class: The hardware type will be the Class 3 controlled hardware of flight design. This requires an AC power source to hook up the laptop. This laptop will be onboard receiving data from the sensors.
Item Moisture Sensor/Solen oid Interface Header
Part #
No. 1
Description
Dimensions
Weight
Picture
0.52x0.2x0. negligible 10 pin header 6 to allow communicatio n between PCB and moisture sensors/soleno id Used to control watering, lighting, and camera system. Form fitting cement 3.54x3.14 2 oz
MPGE (microcontro ller) Control Board
Sugru
can not be determined
One Pack is .17oz
Cargo Straps
Used to hold the experiment to the plate in the glove box. Used to monitor the progress and growth of the plants. Used to store various data, like pictures and data from the sensors. Used to control water flow from IV bag to the plants. Used to measure CO2 inside the 1.2 x .79 x .99 .65 oz
Serial Camera Module
C429-RS23 1 2
SD Micro Card
.591 x .3937 x .0394
.009249 oz
Solenoid Valve
LFVA 051012
1.57in x 1.44
1.0 oz
CO2 Sensor
MGA11
50mm x 15mm
growth chamber.
Moisture Sensor
SHT 75
Used to measure the humidity and temperature inside the box where the plants grow. Used to connect the board to the glove box and the laptop. Also, to provide extra power. Used to transport water and nutrients from the IV bag to the plant growth chamber.
.748 x.1575 .1 oz
Multi Ended USB
N/A
1.95 oz
Levin Tube
.062 orifice, 50 long
.247 oz
Baxter IV Bag (100 mL of water included)
0.9% Sodium Chloride Injection USP, 100 mL IV Bag used to store water and nutrient solution that will be
5.1 x 2.9 x 1
3.7 oz
transported to the seeds. Duct Tape 1 Used to hold down the Gore-Tex membrane in place. Used to provide pressure on the IV bag for water pressure to the Solenoid EMI Supply Inc 5005 1 To seal any possible leaks around the connection from the IV bag to the Levin tube Immeasurable Immeasur able Immeasurable Immeasur able
Brass Compression Spring
3 in, outer diameter .49 in
0.1 oz
Liquid Nails
To seal any possible leaks around the connection from the IV bag to the Levin tube
Immeasurable Immeasur able
American Sealants #502
GE Supreme Silicone
Oval Red LED
630-HLMP 4 -EG15-RU0 00
Used to give 0.1969 x light required 0.278 for plant photosynthesis
Negligible
Round Blue LED
604-WP711 4 3VBC/D
Used to give light required for plant photosynthesis .
0.195 x 0.334
Negligible
Grodan Rockwool Grow Cubes
A growth medium for the plants. Simulates soil on Earth.
1.5 x 1.5 x 1.5
1 cube = 0.15 oz
Medicago truncatula Seeds Gore-Tex 2-Layer Waterproof Breathable Ripstop Nylon
The plant seeds
Immeasurable Negligible
Allows free transfer of CO2 and O2 between the plant growth chamber and the outside atmosphere while retaining relative humidity and moisture inside the plant growth chamber.
Negligible
NanoRacks Box
Metal box that 3.94 x 3.94 contains the x 6 experiment. First level of containment.
17.6 oz (with one cap)
Luer locks: 1. Male connector 2. Female connector 3. Qosina both
1.BPLM24 0 2.BPLF240 3. 90400
1. 5 2. 5 3. 2
1-2. Quarter-turn cuff connector to help with IV bag/tubing separation
1. .957x.615x. 406 2..875x.325 x.252 3. 1.201x.348
1-2. Approx. .5 oz each 3 .875 oz
1.
2.
Inner Box
Contains the plants, IV Bag, and pump. Third level of containment. Also works as the second end cap. Contains seeds and
4.48 x 7.5 oz 4.043 4.016
Octogonal Plant Tray
the .752 X 3.219 X 3.219 Rockwool.
1.2 oz
Power Strip
Will distribute 12 X 2 X power and act 1.5 as kill switch
30.70 oz
Spring Control Rod
Stops the rods .3 Diameter, .1 oz from bending 1.784 Height throughout the experiment. .306 X 4 X Works with the inner box 3.736 to contain any possible water leaks. Helps create a Outer waterproof Diameter 4-7/16 in seal. Presses the IV Bag to create a more evenly distributed pressure Helps provide visualization of water flow throughout water distribution subsystem 3.157 X 3.361 x .203 2.3 oz
Box Lid
O-Ring
E70-156
.1 oz
IV Bag Plate
1.1 oz
Food coloring
Liquid, Immeasur Immeasurable able
B.
Equipment Layout for Take-off, in Flight, and Landing
The plants are installed inside the growth chamber. The plant chamber will be Velcroed and strapped to the bottom plate of the glove box. The only external connections will include a USB connection and power to the laptop provided by the power strip. The laptop will be stowed in one of the onboard stowage containers. Once students are cleared for release from seats, laptop will be unstowed and will be velcroed to the top of the glove box. The students will position themselves around the box to observe and perform duties needed.
C.
Special Handling/Special Hazards/Special Requirements
There are no special handling requirements or hazard requirements for the plant growth chamber in this experiment. The plants will be installed as late as possible prior to flight.
D.
Inventory of In-flight Items
In-flight items will be used: personal cameras, personal flip video cameras, stopwatch, laptop, and all clothing related gear.
E.
Free Float Items
At no point in the flight will the plant growth chamber be free floating. Only the water will be free floating within the triple contained chamber and glove box.
STRUCTURAL VERIFICATION
All experimental equipment except the HP Laptop will be located inside the NASA certified glove box, which has been structurally verified by the Reduced Gravity Office Analysis a. Weights Table N/A Include individual component and overall assembly weight, materials used and allowable loads, fastener/weld locations, etc.
b. Calculations N/A For ALL g-load conditions listed in sec. 2.0
http://jsc-aircraft-ops.jsc.nasa.gov/Reduced_Gravity/docs/AOD_33896.pdf Free-Body Diagrams Attachments to frame Full assembly Floor attachment Free Float Floor Load Analysis
c. Factor of Safety (FS)/Margin of Safety (MS) Table NA
A. Load Test N/A a. Test description b. Test equipment and calibration c. Certification of individual performing test d. Copies of applicable documentation e. FS/MS Table for each test
ELECTRICAL ANALYSIS The system will be powered through USB via the laptop. The laptop will be kept charging to prevent
power loss. The solenoid valve will operate as a water flow controller for the nutrients. The solenoid will be controlled by a MOSFET, allowing the solenoid to draw power from the main system power while still allowing it to be controlled by the microcontroller (The microcontroller cannot directly power the solenoid; that would be far too much current draw).The microcontroller will produce 5 volts of power to the solenoid to operate. A light system that contains red and blue LEDs will be located under and around the micro controller. There will be a certain number of hours that the lights will undergo a cycle of the
red and blue LEDs. In the microcontroller, it will also charge and control the camera. It is programmed to where the camera will take pictures while the lights are on. A camera module is located within the lights, and will take pictures at a predetermined time. A microcontroller will provide and control power for the camera so it is possible to take pictures, the pictures will be stored on a 2 Gigabyte Micro SD Card for later viewing with a 2 Gigabyte backup.
MICROCONTROLLER ANALYSIS
The microcontroller that we are using will use a USB as its source of power for the experiment. This USB will be connected to the laptop on board so there are no problems with power. The microcontroller will be the brain of our entire system. It will control all of the components in the plant system such as the LEDs, watering system, micro camera, CO2 sensors and systems check. With this control we can create an almost entirely autonomous system. The components that will be used autonomously is the solenoid valve in order to water the plants in the chamber. The LEDs will be autonomous operating in a cycle in order to simulate a more natural environment for the plants to grow within. The camera will be on an autonomous system in order to take picture in intervals in order to keep us updated on the status of the experiment. This will be same for the CO2 sensor except it will check the CO2 levels in the air. The systems check is a completely autonomous system that will check to make sure that all of the components of the system will be working properly. The moisture sensors, that are positioned under the rockwool, will also be on an autonomous loop to check values at random and periodic intervals in order to insure proper saturation of the rockwool. The only part of the system that will not operate autonomously will be the changing of the IV bag that contains the nutrient based solution, which will not be required on this zero gravity flight.
This is the microcontroller storyboard for the zero gravity flight:
1.
In the beginning of the zero gravity portions of the flight we would like to be able to turn on the
moisture sensor, the camera, and the LED lights with one push of the button. The CO2 sensor will automatically turn on when the system is plugged into the power source. Assuming that another one tap of the button would turn all of these devices off. We want to be able to see the values of the moisture sensor and the CO2 sensor on the laptop.
2. When the camera is on we would like for it to be taking a picture in one second intervals. If at all possible we would like to be able to see the pictures that are being taken on the laptop as they are being taken. 3. We would like for the solenoid valve to be controlled by a double tap of the button. Assuming that a double tap would open the valve and the second double tap would close the valve. 4. We would like for the LED lights to cycle through their various light cycle phases every time that they are turned on.
A. Schematic Include all wiring and electrical devices, power cords from aircraft, voltage and current draw from each power cord (nominal and peak current from previous testing), unique identifier on each wire or wire bundle, gauge and current of each wire, current limiting device and limiting value for each power cord, master kill switch labeled clearly, grounding method.
Microcontroller functional system diagram
Microcontroller diagram
Microcontroller processes The Microcontroller has to have a way which will keep the UART(the program the camera runs on) and Main System organized and perform in an orderly manner. This is how the Mainframe processes through the program autonomously.
B. Load Table
A load Table should include the laptop as the source of power and the sensors only in the last column that run off of it. (see Table 1 on page 14 of TEDP Requirement and Guidelines NASA JSC RGO)
Power Source Details Name: Voltage: Wire Gauge: Laptop USB Ports 5 VDC 12
Load Analysis Microcontroller Board: 250 mA Camera: 80 mA Solenoid: 260 mA Moisture Sensor: 5 mA LED Lights: 160 mA
Max Outlet Current:
0.5A
Total Current Draw:
755 mA
C. Stored Energy- If the system loses power then the entire PCB will turn off. However, there are capacitors on the board that act as power filters so that clean power signals (5.0 & 3.3 V) are distributed throughout the board.
D. Electrical Kill Switch- If power needs to be cut off, removing the USB from the laptop will cut the power and stop the system. The laptop will be connected to a power strip with a kill switch.
E. Loss of Electrical Power (Fail-Safe)- If there were to be a loss of power, the experiment would remain in the current state until power is restored. As mentioned in the Stored Energy section above, the system will turn off if the power is removed. However, all the data is stored in flash memory on two micro SD cards, so in the event of power loss, all the data should still be secure. PRESSURE VESSEL/SYSTEM (PV/S) A. Description and purpose of PV/S N/A B. System Schematic N/A C. Component Table
N/A D. Detailed Drawings of non-commercially produced components and subsystems N/A E. Calculations and assumptions of non-commercially produced components and subsystems N/A F. Certification/Inspection Records and Due Dates N/A LASER CERTIFICATION A. Laser Class, Type, and Manufacturer N/A B. Lasers Purpose N/A C. Laser Use and Duration During Flight N/A D. Containment Controls N/A E. Class 3 or 4 Additional Information a. Description of laser hardware N/A b. Description of laser parameters N/A
c. Operators training and experience N/A d. Medical surveillance requirements N/A PARABOLA DETAILS AND CREW ASSISTANCE REQUIRED A. Gravity Levels Required: The experiment requires a Zero-G environment to perform the experiments. The parabolas turnaround time will be used to start the next experimental procedure. B. Flight Crew Assistance Required: No specific crew assistance is required.
FREE FLOAT REQUIREMENTS

A. Weight and Dimensions of Free Float Object(s) N/A B. Area Required for Free Float N/A C. Flyer Action Items N/A
INSTITUTIONAL REVIEW BOARD

Only for human or vertebrate animal test subjects.
HAZARD ANALYSIS
A. General Hazard Identification Checklist http://jsc-aircraft-ops.jsc.nasa.gov/Reduced_Gravity/docs/NS-STO-CH01.pdf B. JSC Safety and Health Handbook References See Sec. 2.4 (for effective date April 16, 2008 pp. 79-87) http://jsc-aircraft-ops.jsc.nasa.gov/Reduced_Gravity/docs/JPR1700.1RevJ.pdf
TOOL REQUIREMENTS
A. Additional Tools that will be at Ellington Field Gorilla duct tape, and Velcro straps to secure the laptop and experiment. B. Special Tools Required on the Aircraft N/A
PHOTO REQUIREMENTS
A. Camera Pole/Bogen Arms Required None required.
B. S-Band Downlink Requirements None required.
C. Still/Video Photographer Special Requests We would like to have stills and videos of our students performing their food growth chamber experiment. We would like to have video of the students performing their experiment for educational outreach purposes. AIRCRAFT LOADING A. Load Equipment NanoLab Box will be hand-carried to the plane. The equipment will be stowed in a NASA certified Glove Box for takeoff and landing, therefore the loading requirements will be those currently required to load the glove box. No more than a forklift or lifting pallet is anticipated. The experiment will be able to be lifted onto the aircraft by 1 student.
B. Lifting Accommodations Forklift or lifting pallet to lift the NASA certified Glove Box onto the plane.
C. Weights and Areas The base plate for the plant growth chamber will be 6 x 4 x 6 inches
D. Critical Lift Plan

N/A GROUND SUPPORT REQUIREMENTS A. Power Requirements We will need one power outlet (120 VAC @ 60 Hz).
B. K-Bottle Requirements N/A
C. Hazardous Material Safety No materials are hazardous to handle for the plant growth chamber. The chamber that holds the water IV bag and water tubing is contained inside of the microcontroller chamber and inside the aluminum NanoRack box. Material Safety Data Sheets are included for the silicone that is used to seal portions of the inner experiment boxes that will be used on the Lexan piece where the LEDs and camera will be looking through the inside box.
D. After Hours Access Needed No after hours access should be needed. E. Special Tool/Handling Requirements N/A
HAZARDOUS MATERIAL
MATERIAL SAFETY DATA SHEETS (MSDS) Material Safety Data Sheet-EMI Supply Inc 5005
EMI SUPPLY INC. MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 1 OF 6 -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------Manufacturers name: EMI Supply, Inc. Address: 290 International Dr, NW Concord, NC 28027 Phone: (704) 721-3641 Prepared by: Chad Conrad Date: 07/01/2011 Generic Description: Silicone Elastomer Physical Form: Paste Color: Multiple blended colors aluminum, clear, white, red, black, grey, almond, bronze, yellow. Odor: Acetic acid odor NFPA Profile: Health 2 Flammability 1 Reactivity 0 Note: NFPA = National Fire Protection Association -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 2 - OSHA HAZARDOUS COMPONENTS -------------------------------------------------------------------------------------------------------------------------------------------------------------------CAS NO. INGREDIENT WT % EXPOSURE LIMITS TWA STEL Ceiling ppm Mg/m
3 ppm Mg/m3 ppm Mg/m3 4253-34-3 Methyltriacetoxysilane 1.0 5.0 See acetic acid comment below 17689-77-9 Ethyltriacetoxysilane 1.0 5.0 See acetic acid comment below 7631-86-9 Silica, amorphous 1.0 5.0 OSHA 20 b 80 c - - - NIOSH - 6 - - - ACGIH - - - - - CANADA - 2, 5 a - - - -
The above components are hazardous as defined in 29 CFR 1910.1200. Comments: a. CANADA Respirable mass; Total mass respectively. b. OSHA PEL table Z-3: Millions of particles per cubic foot of air. c. OSHA PEL Table Z-3: 80 mg/m
3. Under normal conditions of use no respirable silica particles should be released from this product. Acetic acid is formed on contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 3 - EFFECTS OF OVEREXPOSURE -------------------------------------------------------------------------------------------------------------------------------------------------------------------Acute Effects Eye: Direct contact irritates moderately with redness and swelling. Skin: A single short exposure (less than 24 hours) may irritate. Repeated prolonged contact (24 to 48 hours) may irritate moderately.
Inhalation: Vapor overexposure may irritate eyes, nose and throat. Oral: Small amounts transferred to the mouth by fingers during use, etc., should not injure. Swallowing large amounts may cause digestive discomfort.
Repeated Exposure Effects Skin: None Known.
Inhalation: None Known. Oral: None Known EMI SUPPLY INC. MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 2 OF 6 Special Hazards This material contains the following components with the special hazards listed below. Carcinogens None Known Teratogens None Known Mutagens None Known Reproductive Toxins None Known Sensitizers None Known Comments: When heated to temperatures above 150 C in the presence of air, product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Exposure Limit for formaldehyde.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 4 - FIRST AID MEASURES -------------------------------------------------------------------------------------------------------------------------------------------------------------------Eyes: Immediately flush with water for 15 minutes. Get medical attention.
Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist.
Inhalation: Remove to fresh air. Oral: No first aid should be needed. Comments: Treat according to persons condition and specifics of exposure. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 5 - FIRE FIGHTING MEASURES -------------------------------------------------------------------------------------------------------------------------------------------------------------------Flash Point (Closed Cup): Not Applicable - Solid Autoignition Temperature: Not Determined Flammability Limits in Air: Not Determined Extinguishing Media: Carbon Dioxide (CO 2). Water. Water fog (or spray). Dry chemical. Foam. Unsuitable Extinguishing Media: None Fire Fighting Procedures: Self contained breathing apparatus and protective clothing should be worn in fighting fires involving chemicals. If large amount is involved, evacuate area.
Unusual Fire Hazards: None Hazardous Decomposition Products: Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition products: Silicon dioxide, Carbon Oxides, and traces of incompletely burned carbon compounds,
Formaldehyde. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 6 - ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------------------------------------------------------------------------------------------------
Containment/Clean-up: Disposal of collected product, residues, and cleanup materials may be governmentally regulated. Observe all applicable local, state and federal waste management regulations. Scrape up and contain for salvage or disposal. Observe all personal protective equipment recommendations described in Sections 5 and 8. Local, state, and federal reporting requirements may apply to spills or releases of this material into the environment. See applicable regulatory compliance information in Section 15.
EMI SUPPLY INC. MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 3 OF 6 -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 7 - HANDLING AND STORAGE -------------------------------------------------------------------------------------------------------------------------------------------------------------------Handling: Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Storage: Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION -------------------------------------------------------------------------------------------------------------------------------------------------------------------Engineering Controls Local Exhaust: Recommended General Ventilation: Recommended Personal Protective Equipment for Routine Handling Eyes: Use proper protection, safety glasses as a minimum.
Skin: Washing at mealtimes and end of shift is adequate. Suitable Gloves: No special precautions needed. Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or air sampling data show exposures are within recommended exposure guidelines. Industrial Hygiene Personnel can assist in judging the adequacy of existing engineering controls.
Suitable Respirator: None should be needed. Recommended Safeguard - Organic Vapor / Dust / Mist Type. Personal Protective Equipment for Spills Eyes: Use proper protection, safety glasses as a minimum. Skin: Washing at mealtimes and end of shift is adequate. Inhalation / Suitable Respirator: Use respiratory protection unless adequate local exhaust ventilation is provided or air sampling data show exposures are within recommended exposure guidelines. Industrial Hygiene Personnel can assist in judging the adequacy of existing engineering controls.
Precautionary Measures: Avoid eye contact. Avoid breathing vapor. Keep container closed. Use reasonable care. Comments: Product evolves acetic acid when exposed to water or humid air. Provide ventilation during use to control acetic acid within exposure guidelines (see Section 2) or use respiratory protection.
Note: These precautions are for room temperature handling. Use at elevated temperature, or aerosol / spray applications may require added precautions.
-------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------------------------------------------------------------------------------------------Physical Form: Paste Color: Depends on product color Odor: Acetic Acid Specific Gravity (at 77F/25C): 1.03 Viscosity: Not Applicable
Freezing / Melting Point: Not Determined Boiling Point (at 760 mm Hg): Not Applicable Vapor Pressure (at 77F/25C): Not Applicable Vapor Density: Not Applicable EMI SUPPLY INC. MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 4 OF 6 Solubility in Water (%): None pH: Not Applicable
Volatile Content: Not Applicable Note: The above information is not intended for use in preparing product specifications. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 10 - STABILITY AND REACTIVITY -------------------------------------------------------------------------------------------------------------------------------------------------------------------Chemical Stability: Stable. Hazardous Polymerization: Hazardous polymerization will not occur. Conditions to Avoid: None. Materials to Avoid: Oxidizing material can cause a reaction. Comments: Water, moisture, or humid air can cause hazardous vapors to form as described in Section 2. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 11 - TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------Special Hazard Information on Components No known applicable information. ------------------------------------------------------------------------------------------------------------------------------------------------------------
--------SECTION 12 - ECOLOGICAL INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------Environmental Fate and Distribution Complete information not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC 50) High Medium Low Acute Aquatic Toxicity (mg/L) < =1 >1 and < =100 >100 Acute Terrestrial Toxicity < = 100 > 100 and < = 2000 >2000 This table is adapted from Environmental Toxicology and Risk Assessment. ASTM STP 1179, p34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 13 - DISPOSAL INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No. Federal Hazardous Waste Code: Not Applicable. Characteristic Waste: Ignitable: Not Applicable. EMI SUPPLY INC.
MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 5 OF 6 Corrosive: Not Applicable. Reactive: Not Applicable. TCLP: Not Applicable. State or local laws may impose additional regulatory requirements regarding disposal. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 14 - TRANSPORT INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------DOT Information (49CFR 172.101) Proper Shipping Name: Not Applicable. Hazard Technical Name: Not Applicable
Hazard Class: Not Applicable. UN / NA Number: Not Applicable. Packing Group: Not Applicable. -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 15 - REGULATORY INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------Contents of this MSDS comply with the OSHA Hazard Communication Standard 29CFR 1910.1200 TSCA Status: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements.
EPA SARA Title III Chemical Listings: Section 302 Extremely Hazardous Substances: None. Section 304 CERCLA Hazardous Substances: None.
Section 312 Hazard Class: Acute: Yes Chronic: No Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals: None present or none present in regulated quantities. Supplemental State Compliance Information: California: Warning: This product contains the following chemicals listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer: None Known.
Warning: This product contains the following chemicals listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause birth defects or other reproductive harm: None
Known. Massachusetts: CAS Number Wt % Component Name 7631-86-9 < = 10.0 Silica, amorphous New Jersey:
CAS Number Wt% Component Name 70131-67-8 < = 87.0 Dimethyl siloxane, hydroxy terminated 7631-86-9 < = 10.0 Silica, amorphous EMI SUPPLY INC.
MATERIAL SAFETY DATA SHEET EMI 5005 SILICONE SEALANT PAGE 6 OF 6 4253-34-3 1.0 5.0 Methyltriacetoxysilane
17689-77-9 1.0 5.0 Ethyltriacetoxysilane Pennsylvania:
CAS Number Wt% Component Name 70131-67-8 < = 87.0 Dimehtyl siloxane, hydroxy-terminated 7631-86-9 < = 10.0 Silica, Amorphous -------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION 16 - OTHER INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------------------These data are offered in good faith as typical values and not as a product specification. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.
Material Safety Data Sheet-Liquid Nails Silicone

MSDS for: LN-700 Revised: 12-Feb-2009 SECTION 1: PRODUCT IDENTIFIER: LN-700 LATEX CONSTRUCTION ADHESIVE VOC COMPLIANT DATE OF PREPARATION: NOVEMBER 3, 2008 PRODUCT USE: ADHESIVE MANUFACTURED BY: AKZO NOBEL 15885 WEST SPRAGUE ROAD STRONGSVILLE, OHIO 44136, U.S.A. AKZO NOBEL (CANADA) 8200 KEELE STREET CONCORD, ONTARIO L4K 2A5, CANADA EMERGENCY AND MSDS TELEPHONE NUMBER: 1-800-545-2643 MSDS PREPARED BY: PRODUCT SAFETY AND COMPLIANCE DEPARTMENT
AKZO NOBEL NORTH AMERICA SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT WT. % CHEMICAL NAME: POLYVINYL ACETATE COPOLYMER 20-30 COMMON NAME: POLYVINYL ACETATE EMULSION CAS NUMBER: CONFIDENTIAL CHEMICAL NAME: VINYL ACETATE MONOMER 0.1-1.0 COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 CHEMICAL NAME: LIMESTONE 20-30 COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 CHEMICAL NAME: KAOLIN 1-5 COMMON NAME: CLAY CAS NUMBER: 1332-58-7 CHEMICAL NAME: TITANIUM OXIDE 0.1-1.0 COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 CHEMICAL NAME: QUARTZ 0.1-1.0 COMMON NAME: QUARTZ CAS NUMBER: 14808-60-7 CHEMICAL NAME: FORMALDEHYDE 0.01-.1 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 CHEMICAL NAME: 1,2-PROPANEDIOL 1-5 COMMON NAME: PROPYLENE GLYCOL CAS NUMBER: 57-55-6 CHEMICAL NAME: WATER 30-40 COMMON NAME: WATER
CAS NUMBER: 7732-18-5 SECTION 3: HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT, INGESTION EFFECTS OF OVEREXPOSURE INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO HEADACHE, NAUSEA, PNEUMOCONIOSIS.
SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS. POSSIBLE SENSITIZATION TO SKIN. SKIN CONTACT MAY RESULT IN DERMAL ABSORPTION OF COMPONENT(S) OF THIS PRODUCT WHICH MAY CAUSE HEADACHE, NAUSEA, CENTRAL NERVOUS SYSTEM DEPRESSION. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN CAUSE TEARING OF EYES, REDNESS OF EYES. INGESTION: INGESTION MAY CAUSE MOUTH AND THROAT IRRITATION, NAUSEA, VOMITING, GASTRO-INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL NERVOUS SYSTEM DEPRESSION,
KIDNEY DAMAGE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS SECTION 4: FIRST-AID MEASURES INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL
HELP FOR ANY BREATHING DIFFICULTY. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR
MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE NEEDED. REMOVE CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL
TREATMENT. INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. SECTION 5: FIRE-FIGHTING MEASURES FLASH POINT (SETA): ABOVE 200F/93C LOWER EXPLOSIVE LIMIT: NOT AVAILABLE UPPER EXPLOSIVE LIMIT: 12.6 % FIRE EXTINGUISHING MEDIA: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE UNUSUAL FIRE AND EXPLOSION HAZARDS CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPERATURES. CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES. FIRE FIGHTING PROCEDURES WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES, TOXIC GASES, PROPIONALDEHYDE, ACETIC ACID, ACETALDEHYDE, OXIDES OF CALCIUM, SMOKE SECTION 6: ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. SPILLED MATERIAL IS EXTREMELY SLIPPERY.
COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. SECTION 7: HANDLING AND STORAGE STORE BELOW 100F (38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. OTHER PRECAUTIONS USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 ACGIH(TWA): 10 PPM ACGIH(STEL): 15 PPM COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 ACGIH(TWA): 10 MG/M3 OSHA(TWA): 5 MG/M3 COMMON NAME: CLAY CAS NUMBER: 1332-58-7 ACGIH(TWA): 2 MG/M3 OSHA(TWA): 5 MG/M3
COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 ACGIH(TWA): 10 MG/M3 OSHA(TWA): 10 MG/M3 COMMON NAME: QUARTZ CAS NUMBER: 14808-60-7 ACGIH(TWA): 0.025 MG/M3 OSHA(TWA): 0.1 MG/M3 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 OSHA(TWA): 0.75 PPM ACGIH(STEL): C 0.3PPM OSHA(STEL): 2 PPM RESPIRATORY PROTECTION CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED ELASTOMERIC SEALING-SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING.
CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4). VENTILATION PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. PERSONAL PROTECTIVE EQUIPMENT EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES, IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.334 BOILING RANGE (F/C): 212-374/100-190 WEIGHT PER GALLON: 11.11/13.34 IMP
APPEARANCE: TAN %VOLATILE BY VOLUME: 53.47 PHYSICAL STATE: PASTE SOLUBLE IN WATER: YES
PH: 8.15 SECTION 10: STABILITY AND REACTIVITY UNDER NORMAL CONDITIONS: STABLE (SEE SECTION 5 FIRE FIGHTING MEASURES) MATERIALS TO AVOID: OXIDIZERS, ACIDS, BASES, AMMONIUM SALTS, NITRIC ACID, HYDROFLUORIC ACID, MINERAL ACIDS, STYRENE MONOMER CONDITIONS TO AVOID: ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, FREEZING HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION 11: TOXICOLOGICAL INFORMATION
COMMON NAME: POLYVINYL ACETATE EMULSION CAS NUMBER: CONFIDENTIAL CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 CARCINOGENICITY LISTED BY: NTP NO IARC YES 2B OSHA NO ACGIH NO LD50: 2335.00 MG/KG SKN RBT LD50: 2920.00 MG/KG ORL RAT LC50: 4000.00 PPM IHL PIG COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 6450.00 MG/KG ORL RAT COMMON NAME: CLAY CAS NUMBER: 1332-58-7 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 CARCINOGENICITY LISTED BY: NTP YES 2B IARC YES 2B OSHA NO ACGIH NO LD50: 24.00 GM/KG ORL RAT LC50: 6820.00 MG/M3/4HR IHL RAT COMMON NAME: QUARTZ CAS NUMBER: 14808-60-7 CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA NO ACGIH YES A2 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA YES ACGIH YES A2 LD50: 100.00 MG/KG ORL RAT LC50: 203.00 MG/M3 IHL PIG COMMON NAME: PROPYLENE GLYCOL CAS NUMBER: 57-55-6 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 20.00 GM/KG ORL RAT LD50: 20.80 GM/KG SKN RBT SUPPLEMENTAL HEALTH INFORMATION NO ADDITIONAL EFFECTS ARE ANTICIPATED CARCINOGENICITY: CONTAINS FORMALDEHYDE, A POTENTIAL CANCER HAZARD. RATS EXPOSED TO FORMALDEHYDE VIA INHALATION DEVELOPED CANCER OF THE NASAL CAVITY. EVIDENCE IN HUMANS IS LIMITED (NASAL AND NASOPHARYNGEAL CANCER). FORMALDEHYDE IS LISTED AS A CARCINOGEN BY OSHA, PROBABLE HUMAN CARCINOGEN (GROUP 2A) BY IARC, AND ANTICIPATED HUMAN CARCINOGEN BY NTP. OVEREXPOSURE CAN CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION,
AND SKIN AND RESPIRATORY SENSITIZATION. CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY INHALATION. IARC HAS CLASSIFIED CRYSTALLINE SILICA AS CARCINOGENIC TO HUMANS (GROUP 1). CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. THE NATIONAL
TOXICOLOGY PROGRAM (NTP) HAS CLASSIFIED CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN. TREATMENT RELATED NASAL TUMORS WERE OBSERVED IN RATS AND MICE EXPOSED TO VINYL ACETATE VIA INHALATION AT 600 PPM FOR 2 YEARS. IN A LIFETIME INHALATION STUDY, EXPOSURE TO 250 MG/M3 TITANIUM DIOXIDE RESULTED IN THE DEVELOPMENT OF LUNG TUMORS IN RATS. THESE TUMORS OCCURRED ONLY AT DUST LEVELS THAT OVERWHELMED THE ANIMALS' LUNG CLEARANCE MECHANISMS AND WERE DIFFERENT FROM COMMON HUMAN LUNG TUMORS IN BOTH TYPE AND LOCATION. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNKNOWN BUT QUESTIONABLE. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON INADEQUATE EVIDENCE OF CARCINOGENICITY IN HUMANS AND SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANIMALS. REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATED MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED
SECTION 12: ECOLOGICAL INFORMATION NO ECOLOGICAL TESTING HAS BEEN DONE BY AKZO NOBEL ON THIS PRODUCT AS A WHOLE. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. SECTION 14: TRANSPORT INFORMATION DOT: CAULKING COMPOUND IMDG: NOT AVAILABLE IATA: NOT AVAILABLE TDG: NOT AVAILABLE SECTION 15: REGULATORY INFORMATION SARA SARA CERCLA HAZ AIR MARINE 302 313 302.4 POLLUTANT POLTNT CAS NUMBER: 108-05-4 YES YES YES YES NO COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 50-00-0 YES YES YES YES NO COMMON NAME: FORMALDEHYDE AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. SECTION 16: OTHER INFORMATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH AKZO NOBEL BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA. AKZO NOBEL SHALL NOT BE RESPONSIBLE FOR THE USE OF
THIS INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL.
MATERIAL SAFETY DATA

SECTION 1. INDENTIFICATION OF THE SUBSTANCE AND MANUFACTURE PRODUCT NAME: Component Hardware Silicone Sealant - White CHEMICAL NAME: Silicone elastomer DATE: 5/3/2010 CAS NUMBER: See below EINECS NUMBER: N/A PRODUCT CODE: M90-1014 SYNONYMS: Silicone Caulk COMPANY NAME: COMPONENT HARDWARE GROUP, INC. 1890 Swarthmore Avenue Lakewood, NJ 08701 Tel. 800-526-3694, 732-363-4700 Fax. 732-364-8110 IN CASE OF EMERGENCY IN U.S.:
800-526-3694 IN CASE OF EMERGENCY IN EUROPE: +31-76-596-8699 SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENTS: CAS= Wt% Component Name 64742-46-7 5.0 - 10.0 Hydrotreated middle petroleum distillates 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 4253-34-3 1.0 5.0 Methyltriacetoxysilane The above components are hazardous as defined in 29 CFR 1910.1200. OTHER INGREDIENTS: CAS= Wt% Component Name 70131-67-8 >60.0 Dimethyl siloxane, hydroxyl-terminated 7631-86-9 7.0-13.0 Silica, amorphous 63148-62-9 1.0-5.0 Polydimethylsiloxane 1333-86-4 </=2.0 Carbon Black 1332-37-2 </=2.0 Iron Oxide 147-14-8 </=2.0 Tetrabenzo-5,10,15,20diazaporphyrinephthalocyanine (Pigment Blue 15)
13463-67-7 </=1.8 Titanium dioxide 1309-37-1 </=1.0 Iron Oxide SECTION 3. HAZARD INDENTIFICATION EYES:
Direct contact may cause moderate irritation SKIN: May cause moderate irritation
INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. However, if material is heated or high vapor concentration is attained, central nervous system depression may occur, which is characterized by drowsiness, dizziness, confusion or loss of coordination. INGESTION: Low ingestion hazard in normal use. Repeated ingestion or swallowing large amounts may injure internally. SECTION 4. FIRST AID MEASURES EYE CONTACT: Immediately flush with water for 15 minutes. Seek medical attention. SKIN CONTACT: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Seek medical attention if irritation or other ill effects develop or persist.
INHALATION: Material is not likely to present an inhalation hazard at ambient conditions. If material is heated or vapor is generated, care should be taken to prevent inhalation. In case of exposure to vapor, move to fresh air.
INGESTION: Seek medical attention. NOTES TO PHYSICIAN: Treat according to person's condition and specifics of exposure.

SECTION 5. FIREFIGHTING MEASURES FLASH POINT: > 212F / > 100C (Closed Cup) FLAMMABLE LIMITS:
ND LOWER: ND UPPER: ND FIRE EXPLOSION HAZARDS: NONE EXTINGUISHING MEDIA: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire-exposed containers.
FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire-exposed containers cool. SECTION 6. ACCIDENTAL RELEASE MEASURES SMALL / LARGE SPILLS: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may
present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. SECTION 7. HANDLING AND STORAGE STORAGE: Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture.
HANDLING: Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Do not take internally. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERMISSIBLE EXPOSURE LEVEL: Hydrotreated middle petroleum distallates OSHA PEL (final rule) and ACGIH TLV for oil mists: TWA 5mg/m3 Ethyltriacetoxysilane and Methyltriacetoxysilane Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
PERSONAL PROTECTIVE EQUIPMENT: EYE AND FACIAL: Use proper protection - safety glasses as a minimum. SKIN: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.
RESPIRATORY: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. IH personnel can assist in judging the adequacy of existing engineering controls.
VENTILATION: Local and general ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: ND SOLUBILITY: ND pH: ND
PERCENT VOLATILE: ND VAPOR DENSITY (AIR=1): ND VAPOR PRESSURE@ 25C: ND EVAPORATION RATE (BUTYL ACETATE=1): SPECIFIC GRAVITY @ 25C : 1.007 APPEARANCE & ODOR: See product name for color. Acetic acid odor. PHYSICAL FORM: Paste

SECTION 10. STABILITY AND REACTIVITY STABILITY: Stable REACTIVITY: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form. HAZARDOUS DECOMPOSITION INGREDIENTS: Thermal breakdown of this product during fire or very high heat conditions may evolve the following products of decomposition: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. Metal oxides. Sulfur oxides. Nitrogen oxides. Chlorine compounds.
HAZARDOUS POLYMERIZATION: Will not occur SECTION 11. TOXICOLOGICAL INFORMATION THIS MATERIAL HAS SPECIAL HAZARD INFORMATION ON COMPONENTS HMIS HAZARD CLASS: Health=1 Flammability=1 Reactivity=0 Other=N/A RANKING:
0=Least 1=Slight 2=Moderate 3=High 4=Extreme S
ECTION 12: ECOLOGICAL INFORMATION Complete information is not yet available regarding Environmental Fate and Distribution, Environmental Effects or Fat and Effects in Waste Water Treatment Plants. SECTION 13: DISPOSAL CONSIDERATONS DISPOSAL: RCRA Hazard Class (40 CFR 261). Not classified as a hazardous waste. State or local laws may impose additional regulatory requirements regarding disposal.
SECTION 14: TRANSPORT INFORMATION SHIPPING NAME: Component Hardware Silicone Sealant - Aluminum HAZARDOUS CLASS: Not subject to DOT, IMDG code or IATA regulations. SECTION 15: REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA EPA SARA Title III Chemical Listings Section 302 - Extremely Hazardous Substances (40 CFR 355): None. Section 304 - CERCLA Hazardous Substances (40 CFR 302): None. Section 311/312 - Hazard Class (40 CFR 370): Acute: Yes Chronic: No Fire: No Pressure: No Reactive: No Section 313 - Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities. Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.

SECTION 16: OTHER INFORMATION ISSUE DATE: 5/3/10 REVISION DATE: 5/13/10 FOR ASSISTANCE ON THIS PRODUCT IN EUROPE: CHG EUROPE B.V. Hazeldonk 6475 4836 LH Breda The Netherlands Tel. +31-76-596-8699, Fax. +31-76-596-3114 IN CASE OF EMERGENCY IN EUROPE: +31-76-596-8699 NOTE: The information contained herein has been checked and is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results and assume no liability for damages incurred by the use, contact or handling of this material. This information should only be used as a guide.
It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.
MSDS for: LN-700 Revised: 12-Feb-2009 SECTION 1:
PRODUCT IDENTIFIER: LN-700 LATEX CONSTRUCTION ADHESIVE VOC COMPLIANT DATE OF PREPARATION: NOVEMBER 3, 2008 PRODUCT USE: ADHESIVE MANUFACTURED BY: AKZO NOBEL 15885 WEST SPRAGUE ROAD STRONGSVILLE, OHIO 44136, U.S.A. AKZO NOBEL (CANADA) 8200 KEELE STREET CONCORD, ONTARIO L4K 2A5, CANADA EMERGENCY AND MSDS TELEPHONE NUMBER: 1-800-545-2643 MSDS PREPARED BY: PRODUCT SAFETY AND COMPLIANCE DEPARTMENT AKZO NOBEL NORTH AMERICA SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT WT. % CHEMICAL NAME: POLYVINYL ACETATE COPOLYMER 20-30 COMMON NAME: POLYVINYL ACETATE EMULSION CAS NUMBER: CONFIDENTIAL CHEMICAL NAME: VINYL ACETATE MONOMER 0.1-1.0 COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 CHEMICAL NAME: LIMESTONE 20-30 COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 CHEMICAL NAME: KAOLIN 1-5 COMMON NAME: CLAY CAS NUMBER: 1332-58-7
CHEMICAL NAME: TITANIUM OXIDE 0.1-1.0 COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 CHEMICAL NAME: QUARTZ 0.1-1.0 COMMON NAME: QUARTZ CAS NUMBER: 14808-60-7 CHEMICAL NAME: FORMALDEHYDE 0.01-.1 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 CHEMICAL NAME: 1,2-PROPANEDIOL 1-5 COMMON NAME: PROPYLENE GLYCOL CAS NUMBER: 57-55-6 CHEMICAL NAME: WATER 30-40 COMMON NAME: WATER CAS NUMBER: 7732-18-5 SECTION 3: HAZARDS IDENTIFICATION PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT, INGESTION EFFECTS OF OVEREXPOSURE INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO HEADACHE, NAUSEA, PNEUMOCONIOSIS.
SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS. POSSIBLE SENSITIZATION TO SKIN. SKIN CONTACT MAY RESULT IN DERMAL ABSORPTION OF COMPONENT(S) OF THIS PRODUCT WHICH MAY CAUSE HEADACHE, NAUSEA, CENTRAL NERVOUS SYSTEM DEPRESSION. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN Verify that this is the correct version before use.
CAUSE TEARING OF EYES, REDNESS OF EYES. INGESTION: INGESTION MAY CAUSE MOUTH AND THROAT IRRITATION, NAUSEA, VOMITING, GASTRO-INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL NERVOUS SYSTEM DEPRESSION,
KIDNEY DAMAGE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS SECTION 4: FIRST-AID MEASURES INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE NEEDED. REMOVE CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. SECTION 5: FIRE-FIGHTING MEASURES FLASH POINT (SETA): ABOVE 200F/93C LOWER EXPLOSIVE LIMIT: NOT AVAILABLE UPPER EXPLOSIVE LIMIT: 12.6 % FIRE EXTINGUISHING MEDIA: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE UNUSUAL FIRE AND EXPLOSION HAZARDS Verify that this is the correct version before use.
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPERATURES. CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES. FIRE FIGHTING PROCEDURES WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES, TOXIC GASES, PROPIONALDEHYDE, ACETIC ACID, ACETALDEHYDE, OXIDES OF CALCIUM, SMOKE SECTION 6: ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. SPILLED MATERIAL IS EXTREMELY SLIPPERY.
COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. SECTION 7: HANDLING AND STORAGE Verify that this is the correct version before use.
STORE BELOW 100F (38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. OTHER PRECAUTIONS USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING
OR SMOKING. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 ACGIH(TWA): 10 PPM ACGIH(STEL): 15 PPM COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 ACGIH(TWA): 10 MG/M3 OSHA(TWA): 5 MG/M3 COMMON NAME: CLAY CAS NUMBER: 1332-58-7 ACGIH(TWA): 2 MG/M3 OSHA(TWA): 5 MG/M3 COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 ACGIH(TWA): 10 MG/M3 OSHA(TWA): 10 MG/M3 COMMON NAME: QUARTZ CAS NUMBER: 14808-60-7 ACGIH(TWA): 0.025 MG/M3 OSHA(TWA): 0.1 MG/M3 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 OSHA(TWA): 0.75 PPM Verify that this is the correct version before use.
ACGIH(STEL): C 0.3PPM OSHA(STEL): 2 PPM RESPIRATORY PROTECTION CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED ELASTOMERIC SEALING-SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING.
CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4). VENTILATION PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. PERSONAL PROTECTIVE EQUIPMENT EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES, IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.334 BOILING RANGE (F/C): 212-374/100-190 WEIGHT PER GALLON: 11.11/13.34 IMP APPEARANCE: TAN %VOLATILE BY VOLUME: 53.47 PHYSICAL STATE: PASTE SOLUBLE IN WATER: YES PH: 8.15 SECTION 10: STABILITY AND REACTIVITY UNDER NORMAL CONDITIONS: STABLE (SEE SECTION 5 FIRE FIGHTING MEASURES) MATERIALS TO AVOID: OXIDIZERS, ACIDS, BASES, AMMONIUM SALTS, NITRIC ACID, HYDROFLUORIC ACID, MINERAL ACIDS, STYRENE MONOMER
CONDITIONS TO AVOID: ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, FREEZING HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION 11: TOXICOLOGICAL INFORMATION COMMON NAME: POLYVINYL ACETATE EMULSION CAS NUMBER: CONFIDENTIAL CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 108-05-4 CARCINOGENICITY LISTED BY: NTP NO IARC YES 2B OSHA NO ACGIH NO LD50: 2335.00 MG/KG SKN RBT LD50: 2920.00 MG/KG ORL RAT LC50: 4000.00 PPM IHL PIG COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 6450.00 MG/KG ORL RAT COMMON NAME: CLAY CAS NUMBER: 1332-58-7 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: TITANIUM DIOXIDE CAS NUMBER: 13463-67-7 CARCINOGENICITY LISTED BY: NTP YES 2B IARC YES 2B OSHA NO ACGIH NO LD50: 24.00 GM/KG ORL RAT LC50: 6820.00 MG/M3/4HR IHL RAT COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7 CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA NO ACGIH YES A2 COMMON NAME: FORMALDEHYDE CAS NUMBER: 50-00-0 CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA YES ACGIH YES A2 LD50: 100.00 MG/KG ORL RAT LC50: 203.00 MG/M3 IHL PIG COMMON NAME: PROPYLENE GLYCOL CAS NUMBER: 57-55-6 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD50: 20.00 GM/KG ORL RAT LD50: 20.80 GM/KG SKN RBT SUPPLEMENTAL HEALTH INFORMATION NO ADDITIONAL EFFECTS ARE ANTICIPATED CARCINOGENICITY: CONTAINS FORMALDEHYDE, A POTENTIAL CANCER HAZARD. RATS EXPOSED TO FORMALDEHYDE VIA INHALATION DEVELOPED CANCER OF THE NASAL CAVITY. EVIDENCE IN HUMANS IS LIMITED (NASAL AND NASOPHARYNGEAL CANCER). FORMALDEHYDE IS LISTED AS A CARCINOGEN BY OSHA, PROBABLE HUMAN CARCINOGEN (GROUP 2A) BY IARC, AND ANTICIPATED HUMAN CARCINOGEN BY NTP. OVEREXPOSURE CAN CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION, AND SKIN AND RESPIRATORY SENSITIZATION. CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY INHALATION. IARC HAS CLASSIFIED CRYSTALLINE SILICA AS CARCINOGENIC TO HUMANS (GROUP 1). CRYSTALLINE Verify that this is the correct version before use.
SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. THE NATIONAL TOXICOLOGY PROGRAM (NTP) HAS CLASSIFIED CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN. TREATMENT RELATED NASAL TUMORS WERE OBSERVED IN RATS AND MICE EXPOSED TO VINYL ACETATE VIA INHALATION AT 600 PPM FOR 2 YEARS. IN A LIFETIME INHALATION STUDY, EXPOSURE TO 250 MG/M3 TITANIUM DIOXIDE RESULTED IN THE DEVELOPMENT OF LUNG TUMORS IN RATS. THESE TUMORS OCCURRED ONLY AT DUST LEVELS THAT OVERWHELMED THE ANIMALS' LUNG CLEARANCE MECHANISMS AND WERE DIFFERENT FROM COMMON HUMAN LUNG TUMORS IN BOTH TYPE AND LOCATION. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS UNKNOWN BUT QUESTIONABLE. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON INADEQUATE EVIDENCE OF CARCINOGENICITY IN HUMANS AND SUFFICIENT EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANIMALS. REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATED MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED SECTION 12: ECOLOGICAL INFORMATION NO ECOLOGICAL TESTING HAS BEEN DONE BY AKZO NOBEL ON THIS PRODUCT AS A WHOLE. Verify that this is the correct version before use.
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. SECTION 14: TRANSPORT INFORMATION DOT: CAULKING COMPOUND IMDG: NOT AVAILABLE IATA: NOT AVAILABLE TDG: NOT AVAILABLE SECTION 15: REGULATORY INFORMATION SARA SARA CERCLA HAZ AIR MARINE 302 313 302.4 POLLUTANT POLTNT CAS NUMBER: 108-05-4 YES YES YES YES NO COMMON NAME: VINYL ACETATE MONOMER CAS NUMBER: 50-00-0 YES YES YES YES NO COMMON NAME: FORMALDEHYDE AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. SECTION 16: OTHER INFORMATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH AKZO NOBEL BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA. AKZO NOBEL SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS
INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29CFR1910.1200.
MSDS MOMENTIVE PERFORMANCE MATERIALS VERSION: 1.5 09/05/2007 M90006 ACETOXY SANITARY SEALANT
1. CHEMICAL PRODUCT AND IDENTIFICATION MANUFACTURED BY: WATERFORD PLANT 260 HUDSON RIVER RD WATERFORD NY 12188
REVISED: 09/05/2007
PREPARER: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
CHEMTREC: 1-800-424-9300
CHEMICAL FAMILY/USE: SEALANT
FORMULA: MIXTURE
HMIS: HEALTH 0
FLAMMABILITY 1 REACTIVITY 0
NFPA: HEALTH
FLAMMABILITY 1 REACTIVITY 0
2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW:
WARNING!
MAY BE HARMFUL IF SWALLOWED. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
ADVERSE LIVER AND REPRODUCTIVE EFFECTS REPORTED IN ANIMALS.
FORM: SOLID
COLOR: TRANSLUCENT Verify that this is the correct version before use.
ODOR: ACETIC ACID
POTENTIAL HEALTH EFFECTS:
INGESTION: MAY BE HARMFUL IF SWALLOWED.
SKIN: UNCURED PRODUCT CONTACT WILL IRRITATE LIPS, GUMS AND TONGUE. SKIN IRRITATION IS POSSIBLE AFTER CONTACT WITH THE UNCURED PRODUCT.
INHALATION: INHALATION OF VAPORS MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. APPLIES IN UNCURED STATE.
EYES: EYE IRRITATION IS POSSIBLE AFTER CONTACT WITH THE UNCURED PRODUCT.
MEDICAL CONDITIONS AGGRAVATED: NONE KNOWN.
SUBCHRONIC (TARGET ORGAN): LIVER; REPRODUCTIVE HAZARD.
CHRONIC EFFECTS / CARCINOGENICITY: THIS PRODUCT OR ONE OF ITS INGREDIENTS PRESENT AT 0.1% OR MORE IS NOT LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP, IARC, OR OSHA.
ROUTES OF EXPOSURE: DERMAL
3. COMPOSITION / INFORMATION ON INGREDIENTS PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS:
METHYLTRIACETOXYSILANE
4253-34-3
1 - 5 % OCTAMETHYLCYCLOTETRASILOXANE
556-67-2
1 - 5 % B. NON-HAZARDOUS:
SILOXANES & SILICONES, DIMETHYLPOLYMERS W/METHYLSILSESQUIOXANES
68554-67-6
5 - 10 %
TREATED FILLER
68611-44-9
5 - 10 %
DIMETHYLPOLYSILOXANE
70131-67-8
60 - 90 %
4. FIRST AID MEASURES INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS, GIVE 1-3 GLASSES OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN: TO CLEAN FROM SKIN, REMOVE COMPLETELY WITH A DRY CLOTH OR PAPER TOWEL, BEFORE WASHING WITH DETERGENT AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION USING A BARRIER DEVICE. IF BREATHING IS DIFFICULT GIVE OXYGEN.
GET MEDICAL ATTENTION.
EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
NOTE TO PHYSICIAN: TREATMENT IS SYMPTOMATIC AND SUPPORTIVE.
5. FIRE-FIGHTING MEASURES FLASH POINT: >93 DEG. C; 199 DEG. F METHOD: ESTIMATED
FLAMMABLE LIMITS IN AIR - LOWER (%): NOT APPLICABLE FLAMMABLE LIMITS IN AIR - UPPER (%): NOT APPLICABLE
SENSITIVITY TO MECHANICAL IMPACT: NO
SENSITIVITY TO STATIC DISCHARGE: SENSITIVITY TO STATIC DISCHARGE IS NOT EXPECTED.
EXTINGUISHING MEDIA: ALL STANDARD EXTINGUISHING AGENTS ARE SUITABLE.
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS MUST WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURESELF-CONTAINED BREATHING APPARATUS WITH FULL FACE MASK AND FULLPROTECTIVE CLOTHING.
6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: WIPE, SCRAPE OR SOAK UP IN AN INERT MATERIAL AND PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES WITH DETERGENT AND WATER TO REDUCE SLIPPING HAZARD. WEAR PROPER PROTECTIVE EQUIPMENT AS SPECIFIED IN THE PROTECTIVE EQUIPMENT SECTION.
7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRODUCT RELEASES ACETIC ACID DURING APPLICATION AND CURING. USE ONLY IN WELL-VENTILATED AREAS. AVOID CONTACT WITH SKIN AND EYES. REMOVE CONTACT LENSES BEFORE USING SEALANT. DO NOT HANDLE LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM THE FINGERTIPS, NAILS AND CUTICLES. RESIDUAL SEALANT MAY REMAIN ON FINGERS FOR SEVERAL DAYS AND TRANSFER TO LENSES AND CAUSE SEVERE EYE IRRITATION.
STORAGE: STORE AWAY FROM HEAT, SOURCES OF IGNITION, AND INCOMPATIBLES. KEEP OUT OF THE REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: EYEWASH STATIONS; SHOWERS; EXHAUST VENTILATION
RESPIRATORY PROTECTION: IF EXPOSURE LIMITS ARE EXCEEDED OR RESPIRATORY IRRITATION IS EXPERIENCED, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. SUPPLIED AIR RESPIRATORS MAY BE REQUIRED FOR NON-ROUTINE OR EMERGENCY SITUATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH OSHA REGULATIONS (SEE 29 CFR 1910.134).
PROTECTIVE GLOVES: IMPERMEABLE OR CHEMICAL RESISTANT GLOVES.
EYE AND FACE PROTECTION: SAFETY GLASSES
OTHER PROTECTIVE EQUIPMENT: WEAR SUITABLE PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
EXPOSURE GUIDELINES:
COMPONENT
CAS RN
SOURCE
VALUE
ABSENCE OF VALUES INDICATES NONE FOUND
PEL - OSHA PERMISSIBLE EXPOSURE LIMIT
TLV - ACGIH THRESHOLD LIMIT VALUE TWA - TIME WEIGHTED AVERAGE
OSHA REVOKED THE FINAL RULE LIMITS OF JANUARY 19, 1989 IN RESPONSE TO THE 11TH CIRCUIT COURT OF APPEALS DECISION (AFL-CIO V. OSHA) EFFECTIVE JUNE 30, 1993. SEE 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: SOLID
ODOR: ACETIC ACID
COLOR: TRANSLUCENT
VOLATILE ORGANIC CONTENT (VOL): 1.5 %(M)
SOLUBILITY IN WATER (20 C): INSOLUBLE
SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT): SOLUBLE IN TOLUENE
VOC EXCL. H2O & EXEMPTS (G/L): 20
10. STABILITY AND REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS: CARBON DIOXIDE (CO2); CARBON MONOXIDE; ACETIC ACID; SILICON DIOXIDE.; FORMALDEHYDE
CONDITIONS TO AVOID: NONE KNOWN.
11. TOXICOLOGICAL INFORMATION ACUTE ORAL: REMARKS: UNKNOWN
ACUTE DERMAL: REMARKS: UNKNOWN
ACUTE INHALATION:
REMARKS: NONE FOUND
OTHER:
OCTAMETHYLCYCLOTETRASILOXANE INGESTION: RODENTS GIVEN LARGE DOSES VIA ORAL GAVAGE OF OCTAMETHYLCYCLOTETRASILOXANE Verify that this is the correct version before use.
(1600 MG/KG DAY, 14 DAYS) DEVELOPED INCREASED LIVER WEIGHTS RELATIVE TO UNEXPOSED CONTROL ANIMALS DUE TO HEPATOCELLULAR HYPERPLASIA (INCREASED NUMBER OF LIVER CELLS WHICH APPEAR NORMAL) AS WELL AS HYPERTROPHY (INCREASED CELL SIZE).
INHALATION: IN INHALATION STUDIES, LABORATORY RODENTS EXPOSED TO OCTAMETHYLCYCLOTETRASILOXANE (300 PPM FIVE DAYS WEEK, 90 DAYS) DEVELOPED INCREASED LIVER WEIGHTS IN FEMALE ANIMALS RELATIVE TO UNEXPOSED CONTROL ANIMALS. WHEN THE EXPOSURE WAS STOPPED, LIVER WEIGHTS RETURNED TO NORMAL. MICROSCOPIC EXAMINATION OF THE LIVER CELLS DID NOT SHOW ANY EVIDENCE OF PATHOLOGY. INHALATION STUDIES UTILILIZING LABORATORY RABBITS AND GUINEA PIGS SHOWED NO EFFECTS ON LIVER WEIGHTS. INHALATION EXPOSURES TYPICAL OF INDUSTRIAL USAGE (5-10 PPM) SHOWED NO TOXIC EFFECTS IN RODENTS. RANGE FINDING REPRODUCTIVE STUDIES WERE CONDUCTED (WHOLE BODY INHALATION, 70 DAYS PRIOR TO MATING, THROUGH MATING, GESTATION AND LACTATION) WITH OCTAMETHYLCYCLOTETRASILOXANE (D4). RATS WERE EXPOSED TO 70 AND 700 PPM. IN THE 700 PPM GROUP, THERE WAS A STATISTICALLY SIGNIFICANT REDUCTION IN MEAN LITTER SIZE AND IN IMPLANTATION SITES. NO D4 RELATED CLINICAL SIGNS WERE OBSERVED IN THE PUPS AND NO EXPOSURE RELATED PATHOLOGICAL FINDINGS WERE FOUND. INTERIM RESULTS FROM A TWO GENERATION REPRODUCTIVE STUDY IN RATS EXPOSED TO 500 AND 700 PPM D4 (WHOLE BODY INHALATION, 70 DAYS PRIOR TO MATING, THROUGH MATING, GESTATION AND LACTATION) RESULTED IN A STATISTICALLY SIGNIFICANT DECREASE IN LIVE MEAN LITTER SIZE AS WELL AS EXTENDED PERIODS OF OFF-SPRING DELIVERY (DYSTOCIA). THESE RESULTS WERE NOT OBSERVED AT THE 70 AND 300 PPM DOSING LEVELS. PRELIMINARY RESULTS FROM AN
ONGOING 24-MONTH COMBINED CHRONIC/ONCOGENICITY STUDY IN RATS EXPOSED TO 10, 30, 150, OR 700 PPM D4 SHOWED TEST-ARTICLE RELATED EFFECTS IN THE KIDNEY (MALE AND FEMALE) AND UTERUS OF RATS EXPOSED FOR 12 TO 24 MONTHS. THESE EFFECTS INCLUDE INCREASED KIDNEY WEIGHT AND SEVERITY OF CHRONIC NEPHROPATHY, INCREASED UTERINE WEIGHT, INCREASED INCIDENCE OF ENDOMETRIAL CELL HYPERPLASIA, AND AN INCREASED INCIDENCE OF ENDOMETRIAL ADENOMAS. ALL OF THESE EFFECTS ARE LIMITED TO THE 700 PPM EXPOSURE GROUP. THE RELEVANCE OF THESE DATA TO HUMANS IS UNCLEAR. FURTHER STUDIES ARE ONGOING. IN DEVELOPMENTAL TOXICITY STUDIES, RATS AND RABBITS WERE EXPOSED TO OCTAMETHYLCYCLOTETRASILOXANE AT CONCENTRATIONS UP TO 700 PPM AND 500 PPM RESPECTIVELY. NO TERATOGENIC EFFECTS (BIRTH DEFECTS) WERE OBSERVED IN EITHER STUDY.
SENSITIZATION: NO DATA AVAILABLE
SKIN IRRITATION: NO DATA AVAILABLE
EYE IRRITATION: NO DATA AVAILABLE
MUTAGENICITY: UNKNOWN
OTHER EFFECTS OF OVEREXPOSURE: THIS PRODUCT CONTAINS METHYLPOLYSILOXANES WHICH CAN GENERATE FORMALDEHYDE AT APPROXIMATELY 300 DEGREES FAHRENHEIT (150 DEG. C) AND ABOVE, IN ATMOSPHERES WHICH CONTAIN OXYGEN. FORMALDEHYDE IS A SKIN AND RESPIRATORY
SENSITIZER, EYE AND THROAT IRRITANT, ACUTE TOXICANT, AND POTENTIAL CANCER HAZARD. A MSDS FOR FORMALDEHYDE IS AVAILABLE FROM MOMENTIVE., ACETIC ACID
RELEASED DURING CURING. 12. ECOLOGICAL INFORMATION ECOTOXICITY: NO DATA AVAILABLE
DISTRIBUTION: NO DATA AVAILABLE
CHEMICAL FATE: NO DATA AVAILABLE
13. DISPOSAL CONSIDERATION DISPOSAL METHOD: DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
14. TRANSPORT INFORMATION FURTHER INFORMATION: THIS PRODUCT IS NOT REGARDED AS DANGEROUS GOODS ACCORDING TO THE NATIONAL AND INTERNATIONAL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS.
15. REGULATORY INFORMATION INVENTORIES:
CANADA DSL INVENTORY: Y (POSITIVE LISTING) Verify that this is the correct version before use.
JAPAN INVENTORY OF EXISTING & NEW CHEMICAL SUBSTANCES (ENCS): Y (POSITIVE LISTING)
KOREA EXISTING CHEMICALS INVENTORY (KECI): Y (POSITIVE LISTING)
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
AUSTRALIA INVENTORY OF CHEMICAL SUBSTANCES (AICS): Y (POSITIVE LISTING)
PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES (PICCS): Y (POSITIVE LISTING)
EU LIST OF EXISTING CHEMICAL SUBSTANCES: Y (POSITIVE LISTING)
CANADA NDSL INVENTORY: N (NEGATIVE LISTING)
TSCA LIST: E (SPECIAL CASE)
FOR INVENTORIES THAT ARE MARKED AS QUANTITY RESTRICTED OR SPECIAL CASES, PLEASE CONTACT MOMENTIVE.
US REGULATORY INFORMATION:
SARA (311,312) HAZARD CLASS: ACUTE HEALTH HAZARD; CHRONIC HEALTH HAZARD
SARA (313) CHEMICALS: Verify that this is the correct version before use.
CANADIAN REGULATORY INFORMATION:
WHMIS HAZARD CLASS: D2A: VERY TOXIC MATERIALS, D2B TOXIC MATERIALS
CALIFORNIA PROPOSITION 65: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
16. OTHER INFORMATION OTHER: THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS PRODUCT SPECIFICATIONS. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE.
C = CEILING LIMIT
NEGL = NEGLIGIBLE
EST = ESTIMATED
NF = NONE FOUND NA = NOT APPLICABLE
UNKN = UNKNOWN
NE = NONE ESTABLISHED
REC = RECOMMENDED
ND = NONE DETERMINED
V = RECOMMENDED BY VENDOR
SKN = SKIN
TS = TRADE SECRET
R = RECOMMENDED
MST = MIST
NT = NOT TESTED
STEL = SHORT TERM EXPOSURE LIMIT
PPM = PARTS PER MILLION PPB = PARTS PER BILLION Verify that this is the correct version before use.
BY-PRODUCT = REACTION BY-PRODUCT TSCA INVENTORY STATUS NOT REQUIRED UNDER 40 CFR PART 720.30(H-2). MATERIAL SAFETY DATA SHEET McCormick and Company, Inc 773302 - RED FOOD COLOR PAGE : 1 of 4 DATE PRINTED : 02/04/2010 RELATED PACK CODES 900329677, 900329422, 900306712, 900306711, 900299388, 900141383, 900058093, 900058051, 900057990, 900036400, 900033170, 900033169, 900033144, 900033143, 900031461, 900024102, 900024100, 996784, 988835, 986015, 982096, 974411, 974410, 930651, 930650, 910045, 907107, 907091, 773302 ----------------------------------------------------------------------------------------------------------------------------- ----------Section 1 - Product and Company Information ---------------------------------------------------------------------------------------------------------------------------------------PRODUCT NAME : RED FOOD COLOR FORMULA # : 773302 SUPPLIER : McCormick and Company, Inc 18 Loveton Circle Sparks, Maryland 21152 (410) 771-7500 8:30AM - 5:00PM EST CHEMTREC - 24 HOUR EMERGENCY : 800-424-9300 ----------------------------------------------------------------------------------------------------------------------------- ----------Section 2 Hazards Identification ---------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW APPEARANCE: Dark red liquid Verify that this is the correct version before use.
ODOR : Odorless NFPA HAZARD CLASSIFICATIONS : Health : 1 Flammability : 1 Reactivity : 1 POTENTIAL HEALTH EFFECTS All ingredients contained in this product are approved for use in a regulation of the Food and Drug Administration or on the FEMA GRAS List. Based on health hazard determination of ingredients contained at a concentration of one percent or greater, this mixture may exhibit the following health hazards: ACUTE EFFECTS Inhalation: Inhalation may cause respiratory irritation. Eye: May be irritating to eyes. Skin: May be irritating to skin. Ingestion: Does not constitute a health hazard. PRIMARY TARGET ORGANS: No known effect. CHRONIC EFFECTS: Prolonged or repeated exposure may cause allergic reaction in certain sensitive individuals.
----------------------------------------------------------------------------------------------------------------------------- ----------Section 3 - Composition/Information on Ingredients ----------------------------------------------------------------------------------------------------------------------------- ----------With the exception of the items listed below, the identity of individual components of this mixture is proprietary information and is considered to be a trade secret. PRINCIPAL HAZARDOUS COMPONENT(S) CAS NUMBER PROPYLENE GLYCOL FD&C RED #40 57-55-6 25956-17-6 ----------------------------------------------------------------------------------------------------------------------------- ----------- MATERIAL Verify that this is the correct version before use.
SAFETY DATA SHEET McCormick and Company, Inc 773302 - RED FOOD COLOR PAGE : 2 of 4 DATE PRINTED : 02/04/2010 RELATED PACK CODES 900329677, 900329422, 900306712, 900306711, 900299388, 900141383, 900058093, 900058051, 900057990, 900036400, 900033170, 900033169, 900033144, 900033143, 900031461, 900024102, 900024100, 996784, 988835, 986015, 982096, 974411, 974410, 930651, 930650, 910045, 907107, 907091, 773302 Section 4 - First Aid Measures ----------------------------------------------------------------------------------------------------------------------------- ----------EYE CONTACT : In the event of contact with eyes, irrigate with water for at least 15 minutes; obtain medical advice immediately.
SKIN CONTACT : Remove contaminated clothes. Wash affected area with water. If irritation persists, obtain medical advice.
INHALATION : Remove to fresh air and seek medical attention if necessary. INGESTION : In the event of accidental ingestion, rinse mouth with water. Give up to one tumbler (half pint) of milk or water. Obtain medical advice immediately.
----------------------------------------------------------------------------------------------------------------------------- ----------Section 5 - Fire-Fighting Measures ------------------------------------------------------------------------------------ ---------------------------------------------------FLASH POINT : > 98 C / > 210 F EXTINGUISHING MEDIA : Water, Foam, Carbon dioxide (CO2), Dry chemical FIRE FIGHTING PROCEDURES : Use standard procedures and preferred extinguishing media above.
UNUSUAL FIRE AND EXPLOSION HAZARDS : None HAZARDOUS COMBUSTION PRODUCTS (Released upon burning) : Carbon monoxide, Carbon dioxide, Smoke
SPECIAL PROTECTIVE EQUIPMENT : For fires in enclosed areas, fire fighters must use self-contained breathing apparatus.
------------------------------------------------------------------------------------------------------------------------------------- --Section 6 - Accidental Release Measures --------------------------------------------------------------------------------------- ------------------------------------------------LAND SPILL : Absorb spill with inert material (e.g., cloth, sand, sawdust) and then place in suitable containers for recycling or disposal. Consult an expert on disposal of recovered material and ensure conformity to local, state, and federal disposal regulations. WATER SPILL : Prevent additional discharge of material, if possible to do so without hazard. Advise authorities if floating material enters a watercourse or sewer. If possible, try to contain floating material and skim from surface. Consult an expert on disposal of recovered material and ensure conformity to local, state, and federal disposal regulations. PERSONAL PRECAUTIONS : Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8. ----------------------------------------------------------------------------------------------------------------------------- ----------Section 7 - Handling and Storage ---------------------------------------------------------------------------------------------------------------------------------------HANDLING : Keep product away from heat and open flame. Keep container closed when not in use. See Section 8 for additional personal protection advice when handling this product. STORAGE : Store in a cool, dry area with adequate ventilation.
EMPTY CONTAINER WARNING : Empty containers may retain residue (including vapors) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with government regulations. MATERIAL SAFETY DATA SHEET
McCormick and Company, Inc 773302 - RED FOOD COLOR PAGE : 3 of 4 DATE PRINTED : 02/04/2010 RELATED PACK CODES 900329677, 900329422, 900306712, 900306711, 900299388, 900141383, 900058093, 900058051, 900057990, 900036400, 900033170, 900033169, 900033144, 900033143, 900031461, 900024102, 900024100, 996784, 988835, 986015, 982096, 974411, 974410, 930651, 930650, 910045, 907107, 907091, 773302 ----------------------------------------------------------------------------------------------------------------------------- ----------Section 8 - Exposure Controls/Personal Protection ----------------------------------------------------------------------------------------------------------------------------------- ----ENGINEERING CONTROLS : Ventilation should be provided to control worker exposures and prevent health risk.
RESPIRATORY PROTECTION : Respiratory protection recommended when adequate ventilation is not available. Whenever workplace conditions warrant a respirator's use, seek professional guidance prior to respirator selection and follow OSHA respirator regulations (29 CFR 1910.134).
EYE PROTECTION : Safety glasses recommended. SKIN PROTECTION : Where contact is likely, wear protective gloves or clothing. OTHER PROTECTION : None required. EXPOSURE GUIDELINES : Component OSHA PEL ACGIH TLV ACGIH STEL Supplier PROPYLENE GLYCOL FD&C RED #40 None None None None None None None None GENERAL HYGIENE CONSIDERATIONS : Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
----------------------------------------------------------------------------------------------------------------------------- ----------Section 9 - Physical and Chemical Properties ---------------------------------------------------------------------------------------------------------------------------------------APPEARANCE : Dark red liquid ODOR : Odorless FLASH POINT: > 98 C / > 210 F DENSITY : 8.57 LB/GAL SOLUBILITY IN WATER : Soluble Verify that this is the correct version before use.
---------------------------------------------------------------------------------------------------------------------------------------Section 10 - Stability and Reactivity ----------------------------------------------------------------------------------------------------------------------------- ----------STABILITY : Presents no significant reactivity hazard. INCOMPATIBILITY (MATERIALS TO AVOID) : Avoid strong oxidizing agents. POSSIBILITY OF HAZARDOUS REACTIONS : Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS : Product does not undergo explosive decomposition. CONDITIONS TO AVOID : Extreme heat and high energy sources of ignition. ----------------------------------------------------------------------------------------------------------------------------- ----------Section 11 - Toxicological Information ----------------------------------------------------------------------------------------------------------------------------- ----------ACUTE EYE EFFECTS : Not established. ACUTE DERMAL EFFECTS : Not established. ACUTE INHALATION EFFECTS : Not established. MATERIAL SAFETY DATA SHEET McCormick and Company, Inc 773302 - RED FOOD COLOR PAGE : 4 of 4 DATE PRINTED : 02/04/2010 RELATED PACK CODES 900329677, 900329422, 900306712, 900306711, 900299388, 900141383, 900058093, 900058051, 900057990, 900036400, 900033170, 900033169, 900033144, 900033143, 900031461, 900024102, 900024100, 996784, 988835, 986015, 982096, 974411, 974410, 930651, 930650, 910045, 907107, 907091, 773302 ACUTE ORAL EFFECTS : Not established. ----------------------------------------------------------------------------------------------------------------------------- ----------Section 12 - Ecological Information ---------------------------------------------------------------------------------------------------------------------------------------Verify that this is the correct version before use.
No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information.
---------------------------------------------------------------------------------------------------------------------------------------Section 13 - Disposal Considerations --------------------------------------------------------------------------------------------------- ------------------------------------Incinerati on or sanitary landfill in accordance with local, state, and federal regulations.
----------------------------------------------------------------------------------------------------------------------------- ----------Section 14 - Transport Information ----------------------------------------------------------------------------------------------------------------------------- ----------DEPARTMENT OF TRANSPORTATION (DOT) : Not regulated by road. Consult your transportation compliance group for possible classifications pertaining to other modes of transport. ----------------------------------------------------------------------------------------------------------------------------- ----------Section 15 - Regulatory Information ----------------------------------------------------------------------------------------------------------------------------- ---------All ingredients contained in this product are approved for use in a regulation of the Food and Drug
Administration or on the FEMA GRAS List. ----------------------------------------------------------------------------------------------------------------------------- ----------Section 16 - Other Information ---------------------------------------------------------------------------------------------------------------------------------------The information contained in this MSDS is based on data available to us at this time. Although reasonable care has been taken in the preparation of this MSDS, no warranty of merchantability, fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or completeness of this
information, the results to be obtained from the use of this information or the product, the safety of this product or the hazards related to its use. ****************************************************************************************** PREPARED BY : McCormick and Company, Inc REVISION DATE : 02/04/2010 VERSION : 1
MSDS American Sealants MSDS for JB Kwik Weld MSDS Lexan Silicone Sealant
EXPERIMENT PROCEDURES DOCUMENTATION A. Equipment shipment to Ellington Field: Our Experiment will be delivered the day of the TRR.
B. Ground Operations: The plants will be installed into the food growth chamber box, the cap end of the box will be sealed and allowed to cure. The software program will be checked for any issues and LEDs, camera and sensors will be checked for any issues.
C. Loading/Stowing: Our experiment box will be loaded into a NASA Certified glove box, where it will be velcroed onto the base plate and strapped down if necessary.
D. Pre-Flight: We will need space in one of the onboard stowage containers to keep our laptop computer with its power cord. We will require normal 120 VAC power capabilities to have our laptop plugged into.
E. Take-Off/Landing: During takeoff and landing, the laptop and the clipboards will be stowed in one of the stowage containers. The flyers will attach the USB from the glovebox to the USB port on the laptop and they will plug the power cord for the laptop into the laptop.
F. In-Flight
Parabolas 1-3-Remain seated to allow for your body to adjust to the zero-g environment. Parabolas 4-12- Test the water delivery system. 1. Run the solenoid subroutine 2. Observe the readings of the sensors. 3. Once the microgravity is over stop the solenoid to see if it can stop correctly 4. If still running after shutdown unplug from the laptop to kill power. Parabolas 13-22 1. Run the routine for the camera to take pictures.
2. Start the solenoid subroutine up 3. See the quality of pictures and the observe the water system more Parabolas 23- 30 1. Educational Outreach (NEC schools)
G. Post-Flight After the flight we will need to observe the data gathered in our experiment from the camera and sensors by using our software system on the zero gravity laptop.
H. Off-Loading: The experiment will be housed in the glove box which will be removed from the aircraft in the same manner in which is was loaded, by fork lift. The Experiment will be carried by hand off of NASA property once flights are complete.
Emergency/Contingency: A. In an emergency, the USB connection to the laptop will be removed which will remove power from our experiment. We will also shut down power to the laptop by shutting down the laptop power as well as remove the power cord from the laptop. BIBLIOGRAPHY
I.
DEVIATIONS/EXCEPTIONS/WAIVERS

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Experiment Title: Plant Viability in NanoRack Doc.

Version: 1 Food Growth Chamber Organization: Clear Springs Date: Page: 1

TEST EQUIPMENT DATA PACKAGE

Experiment Title: Plant Viability for a NanoRack Food Growth Chamber

Verify that this is the correct version before use.

4/19/13 4/22/13 4/22/13 4/29/13 4/30/13 5/8/13

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QUICK REFERENCE DATA SHEET (AOD0072)

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2 3 6 7 8-11 12-18 20 21-26 27 28 29 30 31 32 33 34 35

Procedures Bibliography Deviations/Exceptions/Waivers

101-102 103 104

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Flow Chart Diagram

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Verify that this is the correct version before use.

Verify that this is the correct version before use.

Item Moisture Sensor/Solen oid Interface Header

MPGE (microcontro ller) Control Board

can not be determined

One Pack is .17oz

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Serial Camera Module

.591 x .3937 x .0394

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Multi Ended USB

.062 orifice, 50 long

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Baxter IV Bag (100 mL of water included)

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Brass Compression Spring

3 in, outer diameter .49 in

Immeasurable Immeasur able

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American Sealants #502

Immeasurable Immeasur able

Immeasurable Immeasur able

Oval Red LED

Used to give 0.1969 x light required 0.278 for plant photosynthesis

Round Blue LED

Used to give light required for plant photosynthesis .

Grodan Rockwool Grow Cubes

A growth medium for the plants. Simulates soil on Earth.

1.5 x 1.5 x 1.5

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Medicago truncatula Seeds Gore-Tex 2-Layer Waterproof Breathable Ripstop Nylon

The plant seeds

17.6 oz (with one cap)

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Luer locks: 1. Male connector 2. Female connector 3. Qosina both

1.BPLM24 0 2.BPLF240 3. 90400

1-2. Quarter-turn cuff connector to help with IV bag/tubing separation

1. .957x.615x. 406 2..875x.325 x.252 3. 1.201x.348

1-2. Approx. .5 oz each 3 .875 oz

4.48 x 7.5 oz 4.043 4.016

Octogonal Plant Tray

the .752 X 3.219 X 3.219 Rockwool.

Will distribute 12 X 2 X power and act 1.5 as kill switch

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Spring Control Rod

Liquid, Immeasur Immeasurable able