...

...

*********************************************************************************************
SBIRO Abdelkrim Lyce Agricole Oulad-Taima rgion d'agadir Royaume du Maroc

Adresse lctronique : sbiabdou@yahoo.fr



"# $ "% # :      2011   



    

:
:  
: "!   #%& -1-1

*********************************************************************************************************************
m
m
m
37 g
V = =
=
= 46,8cm 3 47cm 3
=
: *+,:  )(1-2
3
d . e 0,79.1g.cm
V
m
n=
m a = n.M a = 0,5mol.60 g .mol 1 = 30 g

: *+, : - #.

M
*********************************************************************************************************************
. )(9& 0,05mol : - 9& 0,05mol : 7.8 9&10mL 0. (+ (3  - 1-3
: (3 <;  ,+ !  >,@" ,A  ! #%&

0,05
0,05-x
0,05-xf

0,05
0,05-x
0,05-xf

  (

0
x
xf

0
x
xf
n(ester ) t = x

n(acide) r = 0,05 n(ester) t

,@
0
x
xf

#
#C,3 #
(#
#CD*#

:t #
 ,*  )(E & #

: t #
 ,* 0@3 - & #
n(ester ) t = 0,05 n(acide) r : F*&
*********************************************************************************************************************
: +% "!  #%& -2-1- 2

CH 3 COOH + HO CH 3 COO + H 2 O
*******************************************************************************************************************
: # #% IJ 9& ," CH 3COOH / CH 3COO #A. #H #G 3%"-2-2
n ( acide ) r = 0 , 05 x

CH 3COOH + H 2 OCH 3COO + H 3 O +

[CH COO ] [H O ]
=

KA

[CH 3COOH ]

*******************************************************************************************************************
: +% !  # ( @ #G-2-3

pkA
CH 3 COO
K
10
K=
= A = pke = 10 pke pkA = 1014 4,8 = 1,58.10 9

K e 10
[CH 3COOH ]. HO
*******************************************************************************************************************
n a = 10C b .Vb = 10 1mol / L 4.10 3 L = 0,04mol : N< +% 3L & 10 F!!8" " 1L( 3( H&  -2-4

n(ester ) t = 0,05 n(ac) r = 0,05 0,04 = 0,01mol = 10 2 mol :1L( 3 &  )( <; #
*******************************************************************************************************************
xeq = 30m.mol = 30.10 3 mol = 0,03mol : *+, 0** IJ 9& -3-1 -3
: !   # ( @ #G
xeq xeq
2

xeq
0,03 2
[
ester ] [eau ]
V
V
K'=
=
=
=
= 2,25
[acide] [alcool ] 0,05 xeq 0,05 xeq (0,05 xeq ) 2 (0,05 0,03) 2
V
V
*******************************************************************************************************************
xexp
xexp = r.x max = 0,9.x max

r=
:  .% -3-2
x max
: O> D<P Q+ ; - & # : na

 ! #%&
  (
0,05
0
0,05-x
x
0,05-xeq
xeq

na+0,05
na+0,05-x
na+0,05-xeq

,@
0
x
xeq

0
x
xeq

.,)( (

#
#C,3 #
(#
#CD*#

x max = 0,05mol : N< < N %& -

xexp = r.x max = 0,9.x max = 0,9 0,05 = 0,045mol

. #@ #@ T!* U!" (#G N< #G  #A

xeq

xeq

xeq
0,0452
0,0452
V V
K' =
=
=
=
na + 0,05 xeq 0,05 xeq (na + 0,05 xeq )(0,05 xeq ) (na + 0,05 0,045)(0,05 0,045) (na + 0,005).5.10 3

V
V
0,0452
0,0452
0
,
005
na =

0
,
005
=
0
,
175
mol
n
+
=

a
.K '5.103
.K '5.103
*******************************************************************************************************************
: ;V
2+

.J"! 
Zn + 2e Zn
- 1
1
. ,"! 
H 2 O O 2 + 2 H + + 2e
2
***********************************************************************************************************
. ,(. QA( QY@ ( ( ," O2 W IY D* Z*+ ; , :-2 ;V
**********************************************************************************************************
-3
 ! #%&
(:  

#

no (Zn)

(<

#C,3 #

no ( Zn) x

(<

x
2

2x

(#

2 F .x
I .t
I .t
: F*&
x=

n (e) =
:  .%
t
2 .F
F
*************************************************************************************************************
m( Zn) I .t

x = n( Zn) =
=
:  - 4
M ( Zn) 2 F
I=

I .t
8.10 4 A 12 3600S
M ( Zn) =
65,4 g.mol 1 = 1171100 g 1,17.10 6 g
2F
2 9,65 10 4 C.mol 1
***************************************************************************************************************
.A( :  +! 9+ "
. yy' <[ (#\] 0. U I \) ( ,A(+ -
: ( (  1-1
- 1
**************************************************************************************************************
L.a 1,4.10 3 m.10 3 m
=
=
= 7.10 7 m = 0,7 m = 700nm -1-2
2D
2. 1m
***************************************************************************************************************
n . sin i

i1 = sin 1 0

n0 . sin i = n1 . sin i1 : 1   %]. #3* )+( L -2-1 -2

n

m( Zn) =

 n . sin i

i2 = sin 1 0
n2

: 2   %]. #3* )+( L

n0 . sin i = n 2 . sin i 2

i1 > i2
n0 . sin i
n . sin i
sin 1 0

n1
n2

= sin 1

n . sin i
n . sin i
= sin 1 0

sin 1 0
n
n

2
1

n2 =

n0 . sin i

n . sin i

sin sin 1 0
n1

= i1 i2 : *+, F*&

n2 > n1

n . sin i
n . sin i
= sin 1 0

sin 1 0
n
n

2
1

n . sin i
n0 . sin i

= sin sin 1 0
n2
n1

:-

1 sin 60

n2 =

sin 60
= 1,652
sin 31,62

1 sin 60
sin sin 1
0,563
1,626

*************************************************************************************************************
v
= :  .% -2-2
v = .

c
c
: F*& n. . = c :
n.v = c

n=
:
n.
v
c
3.10 8 m / s
2 =
=
= 2,42.10 7 m
14
n 2 . 2 1,652 7,5.10 Hz
**************************************************************************************************************
: D) :2 9+ 
.(2) `P(`  <; aL `P + t=0 #
. ,* -1-1 -1
. ( "` (" L [3Y

R.i + u L + u c = 0

u R + u L + uc = 0

. u L = E = 6V : F*& 0 + u L + E = 0

. i = 0 : u c = E

&](bV) #
. c><;

. u L :(( (<[ c) 0**

************************************************************************************************************
4,88.10 2 s 2div
x = 3,5div

: (  1-2
8,54.10 2 s xdiv
u
0,4
. i= R =
= 0,02 A : 1( t1 = 8,54.10 2 s 0 ( u R = 0,8V : (  u R : ./**( b) )((* +, -
R
20
**************************************************************************************
. u R > 0 78* *() 9: *" 2T t1 -0 -6-
. u R < 0 7 *() 9: *" t2 2T -0 -6
- 1-3
. ( "` (" L [3Y

di d 2 q
dq
= 2 : i =
: `&
dt dt
dt

R.i + L.

di q
+ =0
dt C

u R + u L + uc = 0

. L.

d 2q
dq q
+ R. + = 0
2
dt C
dt

***************************************************************************************
R
.t
2
2L
: @#" B #6 q (t ) = A.e
. cos( .t 0,077) : ( ) 7% *>  <.? +, - -1-4
T
0
: 1( C.E = A.e . cos(0,077) :
q (t = 0) = C.E
u c = E t=0 (

C.E
60 10 6 6
A=
=
= 3,60.10 4 C
cos(0,077) cos(0,077)
**************************************************************************************
. LC 9:  "6<6< EF  - 2

i=

dq (t ) q m
1
=
sin(
.t )
dt
LC
LC

q (t ) = q m . cos(

1
LC

.t ) : ( 

- 2-1

1 2 qm
1
: >G F(H* EF" #>
L.i =
sin 2 (
.t )
2
2.C
LC
2
1 q 2 qm
1
e =
=
cos 2 (
.t )
: I/%* @6"J% EF" #>
2 C
2.C
LC
***************************************************************************************
. >G F(H* EF I/%* @6"J% EF* L =<6<* % EF -2-2
2
2
q
1 q
1
1
ET = m + e = . m sin 2 (
.t ) + cos 2 (
.t ) = m = C te
2 C
LC
LC 2.C

m =

1 q
1 (CE ) 2 CE 2 60.10 6.6 2
=
=
= 1,08.10 3 J 1,1.10 3 J
ET == . m =
2 C
2 C
2
2
***************************************************************************************
U
. Io =
:  E  G % Z = R : > M* -M" ( -3-1 -3
R
U 20
. R1 =
=
= 20 : 1( . a )((* R: 9J: R1 O* ? ?-M"" *  HQ O* PM**
Io
1
U
20
. R2 =
=
= 40 : 1( . b )((* R: 9J: R2 O* ? 6# -M"" *  # O* PM**
I o 0,5
***************************************************************************************
N

R
1
o =
: o =
: S
Q = o = o : L .> -3-2
L
N o o
LC
L
1
Q=
=
3,2
R=R2 ? 9:
R2 . L.C 40 1 60 10 6
***************************************************************************************
1
8* "/* " S U " R#F( W? L o =
-M ? 9: R: -% (  E 6L % -4
C 'o
1

F=

F = Fo
: JXO*"
2 LC '
1
1
C' =
=
= 10 12 F = 1 pF
2
2
2
2
3 2
4 L.F
4 .8,7.10 .(540.10 )
*************************************************************************************
. M%* : W/ - "*
-1
2 .r
r = R. cos : S v p =
-1-1
T
2 .R. cos
2 .6400.10 3. cos 33,5.
vp =
=
= 389m / s 3,9.10 2 m / s
T
(23 3600 + 56 60 + 4)
2

***************************************************************************************
J: < Z F ) [?+* #(6 - J: 96 JM ?Z \  ?" # 9(FQ*" O -1-2
. "*O M 18* 9@J #(6 < -
***************************************************************************************
9: Z" X - 1 O#F* 9M% L E ) 9Z *"
S8"* 9: 1 ?"+, 9(FQ*" O SaU -2-1 -2
r
M .ms r
:6<LM "
 E
F = G.
n
( R + h) 2
: -( 9M/ MO R#F6
r
r
: F = m.a n : 9*0(* ) Ob6 F = m.aG
2

M .ms
v
G.M
M
2
3,07.10 3 m / s
G.
= v s : 1( G.
= ms . s
2
( R + h)
( R + h)
R+h
( R + h)
***************************************************************************************
9#FO * R: 1M  Z ?" cM 1 1MZ .2 *- :  9(FQ*" O R: * < -2-2
.d
*************************************************************************************
: 9M/
L
E m = E c + E pe + E pp : <6<* %M%* EF -1
vs =

E pp = 2mgd cos mgl cos : E c =

1
J . 2 :
2

E pe = C 2 + C 2 = 2C 2

: S

1
l
J . 2 + 2C 2 + 2mg cos (d )

2
2
***********************************************************************************

Em =

: 9 * *>  7% cos 1

2
2

: #O " O6 7%M ((( %* "H 6<6<  #(6 2-1- -2

dE m
1
l 2
= 0 6e %M%* EF* 6 E m = J .& 2 + 2C 2 + 2mg (d ) 1
dt
2
2
2

l
.& : 
UM $e J &.&& + 4C .& 2mg (d ) .& = 0 :
2
l

4C 2mg (d )

2 = 0 : 1( J && + 4C 2mg (d l ) = 0

. *> && +

J
2

***************************************************************************************
l
4C 2mg (d )
2
o =

&& + o 2 . = 0 : .%B ) O6 *>  -2-2

J
To = 2

To =

: $>M
l

o
4C 2mg (d )
2
***************************************************************************************


: 96" H 6<6< ? 9: ( 0, L* ) 9*(M ? 9:
-3
2
1
l
E m = J . 2 + 2C 2 + 2mg cos (d o )
2
2
dE m
l
& : 
UM J .&.&& + 4C& 2mg& sin (d o ) = 0

= 0 E m = C te
2
dt
l
&& + o 2 . = 0 : .%B *>  ) % 7L #8 6<6< # 9% J .&& + 4C 2mg sin (d o ) = 0
2
l
l
l
do =
: d o = 0
2mg sin (d o ) = 0 : % (  RO
2
2
2
****************************************************************************************
SBIRO Abdelkrim Lyce Agricole Oulad-Taima rgion d'agadir Royaume du Maroc

Adresse lctronique : sbiabdou@yahoo.fr