THIONYL CHLORIDE TREE Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME THIONYL CHLORIDE ‘SYNONYMS C205, C2-0'S, S002. ‘sulin! chlonde’ “suphin/chlonde’, “sur chloride oxide, “sulphur chlonde oxie",“sufurous ico, “Sulphur Givonds"“sulurcus crychirde’“suiphurous oxychiorce PROPER SHIPPING NAME THIONYL CHLORIDE PRODUCT USE Used as a civoaton agert, 2 catalyst, and in ie manufacture of pesteties and engineering plastics. A component in ahium dy ce batons. HAZARD RATINGS wn vex Rammabiity: og Tot: . = oncom: tT rn Reactivity 2 Wier chron: on oe Section 2- HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE. FurANDOUS SUBSTANCE DANGEROUS GOODS Accord es Sas NOTES ane AOU Oo POISONS SCHEDULE noe RISK ‘SAFETY etc valenty winwalet. = Neveradawatert is produ. Hamby maton m0 ead (eGR IE DES og ot ose gs fae vapour so. Castes serore bus. vo ott wi oy S.Eotsermus camagete— yoorsutcio prteene ctctnng. + Incase of insutciort vontiauon wear sutable respatoy equipment + Keapeowaner ary. Use only in wel veniated areas. ~ Keop contanerin a mol ventictod pace eop contaner ght coso0. + This matetial acts container must be disposed of i a safe way. Keep away fom fod drink and animal feeding sts. + Tako of mmeditay at cortamsnatod coming, In ease of ansdant or you fal una IMMEDIATELY contact Goctr or Posons information Gente (shew noel € possi) + This material anc container must be disposed o as hazardous waste.‘Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS. NAME cas AN % ‘mony! enenas moor 398 reacts with water r moisture to produce ryatogen chionoe rear-01-0 ‘sullur doxide 7446-09-5 Section 4 - FIRST AID MEASURES ‘SWALLOWED ° For advice, contact a Peisons Information Centre ora doctor. swallned co NOT induce Voriirg, ‘© lf vomitng occu, lean patent icwvard or place on let side (head-down poston, i possibe) to msinian open elway and prevent aspraton. ‘Observe the patent cortuly ‘© Never gue iguido a person showing signs of being slepy or wit reduced awareness; Le. becoming unconscious ‘© Givewater to rinse out mouth, then provide liuid showy and as much as casualty can comfortably drink, Seok medial ave, EYE Mths product comos n contact wen mn oy: ‘¢mmestatey hold ysis apart anc flush the eye continuously wih running water nae compet rgton ce ey asp afte aa re avay Tom sje and moung ees Oy o=asonay Hr ne ‘© Contnue nusting untt aavsed to sto by te Poisons informaon Gente ora doctor, of tor at east 15 minus. “Transport hospital or doctor witout daly. ‘&Remaval of contac lenses alt an ay ry ould only be undertaken by skied parsons SKIN akin or ha contact oDcurs: ‘© limmessateyfush body and clothes with lage amounis of wale, using salty stoner ifavalaie ‘2 Quioey romavo all conamnatoc ettng, inctucing foctaea. ‘© Wasi skin anc hair with runing water. Continue fusing with water nil advised to stop bythe Poisons Infomation Centr ‘© Transport to nosptal, of coctor. INHALED Irtumes o: combustion products ate innaled remove tom contaminatec area. Lay patient down. Keep warm and rested. Prosineses such as fase teal, which May block away, shouldbe rereved, where possible, prior oiling ist at proved res ‘Azely artical resiraton i nat breathing, preferably wih a damand valve recuscater, bag valve mask device, or pocket mask as leaned Perform CPA # necassary ‘* Transport to hospital, or doctor. NOTES TO PHYSICIAN Foy a2 0 shot itm peated exposures to strong ands: ‘© Ainray problems may arise irom layngeel edema and innalaton exposure. Treatwn 100% oxygen inal Fespeatory dsttess may reque cithyoicotony i endtrach=al ination conteincated by excessive sweling Inravencus lias shouldbe ectapishod immociaiey all casos whore thea is evidence of ercuatorycompromi. 1S Suong acts proguse a coagulation naxoss characersad by fermalio ofa coagulum (aschal) as a esut othe dasstating action ‘of ne 2c on proteins inspect issues. INGESTION: ‘© irmeazate atuton (ra or water wrt 30 minutes postingeston ic recommended ‘© DONOT tempt to neutraise the acd since exothenc rea‘ion may exten the corrosive injury. (© Be cxoiulto avo turner vomit since re-acposure ofe mucosa i he aid is MarMZul.LMM IGS to one or wo asses in an adult. ‘© Chatcoal has no place in acc management. ‘© Soma authors sugges he use of lavage within 1 hour of ingction. SKIN: ‘© Skanesions requ copious saline migaton. Teal chemical burs 2s tnermal bums win non-acheren gauze and wrappng. ‘¢. Deep second-degree bums may bene from ‘opal siver sufacarine. EVE! (© Eye ines require retraction ofthe eyes to ensure thorough inigtion ofthe conjuctvelcu-de-sacs ligation should last least20-90 minuies. DO NOT use neutralsing 2g20ts or any other adstves. S2veral res of saline are requited. '© Cyciopiegic drops, (1% cyclopeniolate for short-term use or £%s homatropine for longer term use) entibiac drops, vasoconstictvs ‘agonis of atficial tears may be incicated dependent onthe seventy af the Inuy. ‘2. Stara eye crops should only bo administered withthe approval of a consultrg ophthalmologist). [Elennom ana Barceicux: Mecieal Tanlecogy) Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Dy chemical powder GF (where regulators pect). Carbon dioxide ‘© DONOT uso water. FIRE FIGHTING Ala Fre Brigade and tell them locaion and nature of hazard. (Clear area of personnel and move upwind May be violenty of explosively reactve. ‘Wear full booy protective cithing with breathing apparatus. Prevent, by ary means available, spillage irom entering drains cr watercourse. Consider evacuation (or protectin place). DO NOT use water. DO NOT aporcach containers suspected to De not Coo! fire exposed containers with water soray fom a protected location Avod spraying wator onto quid pos. Isafe ha s0, amave contaners rom peth ot fre. Equipment should be thoroughly deconiaminated after use FIRE/EXPLOSION HAZARD. ‘© Non combustible. 1S Not considered tobe a signiticant fre risk. ‘© Acids may react win metals to produce nyarogen. a hight tammable and explosive gas, Heating ay cause exansion or decomposition leading fo violent rupture of rigid containers. ‘© May emit acrid smoke. May emit corrosive and posancus furs. Decomposes on heating and produces foto fumes af yarogen chlorce. ‘Sufur oxides (SOx). FIRE INCOMPATIBILITY ‘© Avoid contamination with oxidising agents .e.nitrtes,oxidsing acs, chiorine bleaches, pool chlorine ec. as ignition may resuit HAZCHEM AWE: Personal Protective Equipment Gas tigi chemical resist suit ‘Section 6 - ACCIDENTAL RELEASE MEASURES. EMERGENCY PROCEDURES: MINOR SPLLS » Clean up al spils immediately, ‘Avod breathing vapoure ard contact with skin and eyes. ‘Wear protectwe cling, mpervious glo/es and safely gasses. ‘Contain spl wih sand_ earth or vemicute. Use soda ash or sleked ime to neutrals. © DONOT uso water. Wipe up. Cillectresicues and plane n labelled plasto coniainers with verted is. ‘Wash spill area wih large quantities of water MAJOR SPILLS. » Glear area of personnel and move upwna. ‘Alett Fire Brigade and ell them locaton and nalure of hazard, ‘© May be Violenty or explosively reactive.