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4

Q evaporator
Qcrystallizer

37525.33333 KW
265.6948564 KW

Feed
Flow Rate
60000 kg/h
Temperature
25 C
Concentration
3.5 %
dissolved salt
2100 kg
Pressure
70 kPa

Pressure at 2 = 101 kPa

3
Steam
Flow rate
Temperature
Pressure

61352.105 kg/h
120 C
200 kPa

Dissolved salt 35 g/L in sea water


Composition Parts per thousand
Percentage %
Chloride
19.345
55.03

Sodium
Sulfate
Magnesium
Calcium
Potassium
Bicarbonate
Bromide
Borate
Strontium
Fluoride
Other
Total

10.752
30.59
2.701
7.68
1.295
3.68
0.416
1.18
0.39
1.11
0.145
0.41
0.066
0.19
0.027
0.08
0.013
0.04
0.001
0.003
less than 0.001
less than 0.001
35.151
99.993

Condensate
flowrate
temperature
Vapor
flowrate

Evaporator

61352.105
100 C

51600

Separation

Chemical Reactor

Concentrated Brine
Flowrate
Temperature
Concentration
Pressure

8400
100
25
101

kg/h
C
%
kPa

H2SO4 5M
7
NaOH 1M
Flowrate
Temperature

11
2576 kg/h
25 C

Flowrate
temperature

2318.4
Solid Mg(OH)2 at Stream 10

g/L in sea water


mol
0.272464789

component
Chloride

186.76

Stream 6 composition
kilograms
mass fraction
total Kmol/h
1155.63 0.137575 16.2764789

0.467478261
0.042203125
0.053958333
0.0104
0.01
0.002377049
0.000826033
0.000465517
0.000148402
5.26316E-05
0
0.86037414

Sodium
Sulfate
Magnesium
Calcium
Potassium
Bicarbonate
Bromide
Borate
Strontium
Fluoride
Water

642.39
161.28
77.28
24.78
23.31
8.61
3.99
1.68
0.84
0.063
6300.147

0.076475
0.0192
0.0092
0.00295
0.002775
0.001025
0.000475
0.0002
0.0001
7.5E-06
0.750018

27.93
2.52
3.22
0.6195
0.59769231
0.14114754
0.04993742
0.02896552
0.00958904
0.00331579
88.7344648

Flowrate

Mole of water at stream 12


Mole of water needed for crystallization
excess water to be evaporated
or

10789.24 kg/h

Side Product

Separation

Temperature at stream 12

9
Temperature
Flowrate
Vapor

Mg(OH)2
10

13

12
Chemical Reactor

986.125 kg/h
25 C

kg/h

Steam
Temperature
Flowrate
Pressure

15

150 C
434.398239 kg/h
200 kPa

12
Crystallizer

28666.66667
71333.3333
42666.6667
14000

43.6936111
22.54
21.1536111
380.765

water needed for crystallization


ter to be evaporated

Kmol/h
Kmol/h
Kmol/h
kg/h

80 C

100 C
380.765 kg/h

14
MgSO4.7H2O
amount of solid MgSO4.7H2O

16
Condensate

792.12 kg/h

3500
0.049065421
3500
0.08203125
3500
0.25

Steam
Pressure
Temperature
Flowrate

200 kPa

Feed
50000 kg/h

Feed

Feed
25000 kg/h

25000 kg/h

hF
Temperature
Flowrate
xF

-310.5
25 C
60000 kg/h
0.035
Feed

Steam
Ts
Ps
Flowrate

120 C
200 kPa
61352.105 kg/h

Flowrate
x1
T1

Vapor
Flowrate
T1
Hv

51600
373 K
2257 kJ/kg

P1

101 kPa
Condensate

Flowrate
lamda

61352.105
2201.9 kJ/kg

Brine
8400 kg/h
0.25
373 K

hF
Temperature
Flowrate
xF

Vapor
Flowrate
T1
Hv

-82.8
80 C
1172.885 kg/h
0.035
Feed

P1

Steam
Ts
Ps
Flowrate

120 C
200 kPa
434.398239 kg/h

Flowrate
lamda

solid
Flowrate
x1
T1

792.12
0.25
373

380.765
373 K
2257 kJ/kg

101 kPa
Condensate
434.398239
2201.9 kJ/kg

kg/h
K

Feed
60000 kg/h
NaOH
2576 kg/h
H2SO4
986.125 kg/h
Steam evaporator
61352.105 kg/h
Steam Crystallizer
434.398239 kg/h

Total

125348.628

Side Product
10789.24 kg/h
MgSO4.7H2O
792.12 kg/h

Condensate evaporator
61352.105 kg/h
Condensate crystallizer
434.398239 kg/h
Vapor evaporator
51600 kg/h
Vapor
380.765 kg/h
Total

125348.628

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