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Amin

AMIN
I. CNG THC TNG QUT AMIN : CxHyNt
vi y 2 x + 2 + t , y, t cng chn hoc cng l, nguyn
Nu amin no n chc t = 1 nn amin : CxHyN
Amin no : C n H 2n + 2 + t N t (n 1; t 1)
Amin no n chc : C n H 2n + 3 N (n 1; t = 1)
Amin thm n chc : C n H 2n 5 N (n 6) hay C n H 2n 7 NH 2 (n 6)
II. TNH CHT
Tnh cht 1 :

R-NH2 + HCl

R-NH3Cl

Ch : s nhm amin + s lin kt =

Tnh cht 2 :
R_NH3Cl + NaOH R_NH2 + NaCl
Tnh cht 3 : Amin phn ng vi axit nitr (HNO2)
+ Amin no bc 1 : cho sp l ancol, N2
t0 thng
CnH2n+1-NH2 + HONO
+ Anilin v cc amin thm bc 1 : sp l mui iazoni

n HCl
n a m in

+ H2O

CnH2n+1-OH + N2 + H2O

00 - 50C
CnH2n -7N2Cl + 2H2O
Tnh cht 4 : Phn ng ankyl ha (thay th H ca NH2)
R-NH2
+
R-I

R-NH-R + HI
6n + 4
2n + 3
1
O 2 nCO 2 +
H 2O +
N2
Tnh cht 5 : Phn ng chy C n H 2n + 3 N +
3
2
2

CnH2n -7-NH2 + HONO

Ch : n O2 = n CO2 +

1
nH O
2 2

3
n amin = n CO2 n H2O
2

Tnh cht 6 : 3Cn H 2n +1 NH 2 + 3H 2 O + FeCl3

3C n H 2n +1NH 3Cl + Fe(OH)3

Amin no : tnh baz ca amin Bc 2 > bc 1 > bc 3

Tnh baz ca * (CH3)2NH > CH3NH2 > (CH3)3N ;
* (C2H5)2NH > (C2H5)3N > C2H5NH2
* p-NO2-C6H4NH2 < m-NO2-C6H4NH2 < C6H5NH2 < NH3 < CH3NH2 < C2H5NH2 < C3H7NH2
* p-CH3-C6H4NH2 > m-CH3C6H4NH2
VD 1 : Cho cc cht sau : NH3 (1) ; C2H5NH2 (2) ; CH3CH2CH2NH2 (3) ; CH3NH2 (4)
Chiu tng dn tnh baz l :
A. 1 2 4 3
B. 1 4 2 3
C. 2 4 1 3
D. 4 2 3 1
VD 2 : Tnh baz cc cht c sp xp
A. NH3
> CH3NH2 > C6H5NH2
B. CH3NH2 > NH3 > C6H5NH2
C. C6H5NH2 >
NH3 >
CH3NH2
D. CH3NH2 > C6H5NH2 > NH3
III. ANILIN : Anilin c tnh baz ................................
+ khng ........................................................v dung dch phenolphtalein................................................
Tnh cht 7 : Phn ng th nhn thm ca anilin

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Amin

VD : Cho cc dung dch hex-1-en (hexen-1); benzen ; aniline. Ch dng mt ha cht no sau y c th nhn bit
c ba cht trn ?
A. NaOH
B. HBr
C. Dung dch Br2
C. HNO3
Tnh cht 8 : phn ng chy anilin v ng ng

C n H 2n 5 N +

6n 5
2n 5
1
O 2 nCO 2 +
H 2O + N 2
4
2
2

VD : t chy hon ton hp cht X l ng ng ca anilin th t l T =

A. C7H7NH2

B.C8H9NH2

n CO2
n H2O

= 1, 4545 . Vy CTPT X l :

C. C9H11NH2

D. C10H13NH2

C 6 H 5 -NO 2 C 6 H 5 -NH 2
iu ch anilin : C 6 H 6
VD : Cht no sau y dng kh nitrobanzen thnh anilin ?
A. H2/Ni
B. Br2
C. KMnO4
HNO 3 ,H 2SO 4

Fe, HCl

D. Fe + HCl

Bng s lng ng phn :

NG PHN

CH5N

Amin bc 1

Amin bc 1

C2H7N

C3H9N

C4H11N

C5H13N

Amin bc 1

Tng s

17

Cu 1 (C 2007): trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml
dung dch HCl 1M. Cng thc phn t ca X l
A. C3H5N.
B. C2H7N.
C. CH5N.
D. C3H7N.
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Cu 2 (H khi A 2007): Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh
N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16)
B. C2H7N.
C. C3H9N.
D. C4H9N.
A. C3H7N.
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Cu 3 (H khi B 2010): t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c
0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l
A. 0,3.
B. 0,1.
C. 0,4.
D. 0,2.
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Cu 4 (H khi B 2010): Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn
nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l
B. CH3CH2CH2NH2.
A. H2NCH2CH2CH2CH2NH2.
D. H2NCH2CH2NH2.
C. H2NCH2CH2CH2NH2.
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Amin
Cu 5 (H khi A 2009): Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam
mui. S ng phn cu to ca X l
A. 4.
B. 8.
C. 5.
D. 7
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Cu 6 (C 2009): S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l
A. 4.
B. 2.
C. 5.
D. 3.
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Cu 7 (C 2008): Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy
ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to
ng vi cng thc phn t ca X l
A. 5.
B. 4.
C. 2.
D. 3.
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Cu 8: kh mi tanh ca c sau khi m nu, ngi ta s dng cch no sau y ? (Bit mi tanh ca c l
do mt s amin gy nn)
A. Dng nc sch
B. Dng gim
C. Dng ancol (ru)
E. Dng Na2CO3
F. Dng mui n
D. Dng HNO3 c
Cu 9 (H khi B 2007): Dy gm cc cht u lm giy qi tm m chuyn sang mu xanh l.
A. Anilin, metylamin, amoniac
B. Anilin, amoniac, natri hiroxit.
C. Metylamin, amoniac, natri axetat.
D. Amoniclorua, metylamin, natri hiroxit.
Cu 10 (H khi B 2011): Ancol v amin no sau y cng bc?
B. C6H5NHCH3 v C6H5CH(OH)CH3
A. (C6H5)2NH v C6H5CH2OH
D. (CH3)2CHOH v (CH3)2CHNH2
C. (CH3)3COH v (CH3)3CNH2
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Cu 11: Hn hp (X) gm 3 amin no n chc mch h ng ng lin tip nhau vi t l s mol theo th t
phn t khi tng dn l 1 : 2 : 4. Ly 4,55 gam hn hp X cho tc dng hon ton vi dung dch HCl d ri c
cn dung dch thu c 7,105 gam mui khan. Xc nh CTPT cc amin trong X ?
B. C2H7N, C3H9N v C4H11N
A. CH5N, C2H7N v C3H7NH2
D. C3H7N, C4H9N v C5H11N
C. C3H9N, C4H11N v C5H11N
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Amin
Cu 12: Trong cc tn gi di y tn no ph hp vi cht CH3-CH(CH3)-NH2
A. Metyl etyl amin
B. Etyl metyl amin
C. Isopropan amin
D. Isopropyl amin
Cu 13: Trong cc cht sau y cht no c tn gi khng ph hp ?
: N-Metyletanamin
A. CH3-CH2-NH-CH3
: N-Metylpropan-2-amin
B. CH3-CH2-CH2-NH-CH3
: Hexan-1,6-iamin
C. H2N-[CH2]6-NH2
: ietylmetylamin
D. (C2H5)2N-CH3
Cu 14: Khng nh no sau y lun ng ?
A. Phn t khi ca mt amin lun l s l.
B. Phn t khi ca mt amin lun l s chn.
C. t chy a mol amin X lun thu c ti thiu 0,5a mol N2.
D. Cng thc tng qut ca amin no, hai chc, mch h l CnH2n+3N2
Cu 15: Khi cho qu tm vo dung dch C6H5NH3Cl th qu tm
A. Ha
B. Ha xanh
C. Khng i mu
D. C mu khng xc nh
Cu 16: Cht no sau y khng phn ng vi nc brom ?
B. C6H5-CH=CH2
C. C6H5-OCH3
D. C6H5-NH2
A. C6H5-OH
Cu 17: Anilin l nguyn liu quan trng trong ngnh sn xut
A. Phm nhum
B. Axit benzoic
C. Thuc tr su 6,6,6
D. Cht ty ra tng hp
Cu 18: Khi cho vi git dung dch FeCl3 vo dung dch metyl amin th c hin tng xy ra l
A. C kt ta mu trng.
B. C kt ta mu nu.
C. Dung dch chuyn sang mu vng ca ion Fe3+
D. Dung dch phn lp do hai cht khng phn ng vi nhau.
Cu 19: Cho 13,5 gam mt amin no n chc vo dung dch st III clorua thu c 10,7 gam kt ta. Xc
nh cng thc phn t amin ?
B. C2H7N.
C. CH5N.
D. C3H7N.
A. C3H5N.
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Cu 20: Cho 9,3 gam mt ankylamin tc dng vi dd FeCl3 d thu c 10,7 gam kt ta. Ankylamin CTPT?
B. C2H5NH2
C. C3H7NH2
D. C4H9NH2
A. CH3NH2
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Cu 21: Cho 1,87 g hn hp anilin v phenol tc dng va vi 20g dung dch Brom 48%. Khi lng kt
ta thu c l: A. 6,61g
B.11,745g
C. 3,305g
D. 1,75g
Cu 22: Vi cc cht amoniac (1), metylamin (2), etylamin (3), anilin (4). Tnh baz tng dn theo trnh t:
A. (4) < (1) <(2) < (3)
B. (4) < (1) < (3) < (2)
C. (3) < (2) < (1) <(4)
D. (3) < (2) < (4) < (1)
Cu 23: t chy 2 amin no n chc ng ng lin tip nhau thu c 2,24 lt CO2 (kc) v 3,6g nc. Hai
amin c CTPT l:
B. C3H9N v C4H11N
C. C2H7N v C3H9N
D. C4H11N v C5H13N
A. CH5N v C2H7N
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Cu 24: Hm lng nit trong amin n chc A l 19,17%. A c CTPT:
A.CH5N
B. C2H7N
C. C3H7N
D C4H11N
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Amin
Cu 25: t chy hon ton mt amin thu c CO2 v H2O t l l 8:9. CTPT ca amin l
B. C4H8N
C. C4H9N
D. C3H7N
A. C3H6N
Cu 26: Cho cc hp cht: (1) C6H5NH2, (2) C2H5NH2, (3) (C6H5)2NH, (4) (C2H5)2NH, (5) NaOH, (6) NH3.
Sp xp theo th t gim dn tnh baz l:
A. 5, 2, 3, 4, 1, 6
B. 5, 2, 4, 3, 1, 6
C. 5, 4, 3, 2, 1, 6
D. 5, 4, 2, 6, 1, 3
Cu 27: C bao nhiu amin bc hai c cng thc C5H13N: A. 4
B5
C. 6
D. 7
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Cu 28: Cho 9 g hn hp X gm 3 amin: n-propyl amin, etylmetylamin, trimetyl amin. Tc dng va vi V
ml dung dch HCl 1M. Gi tr ca V l:
A. 100ml
B. 150 ml
C. 200 ml
D. Kt qu khc
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Cu 29: t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 (lt) CO2 (ktc) v 7,2 g
H2O. Gi tr ca a l:
A. 0 ,05 mol
B. 0,1 mol
C. 0,15 mol
D. 0,2 mol
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Cu 30: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l.
A. Anilin, amoniac, natri hiroxit
B. Metylamin, amoniac, natri axetat
C. Amoniclorua, metylamin, natri hiroxit
D. Anilin, metylamin, amoniac
Cu 31: t hon ton amin X bng mt lng khng kh va thu c 4,48 lt CO2 (ktc), 9 g nc v
42,56 lt kh nit (ktc) ( bit khng kh c 20% oxi v th tch). Tm cng thc phn t ca X ?
A. C3H7N
B. CH5N
C. C2H7N
D. C4H11N
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Cu 32: Cc cht NH3, CH3NH2 v C6H5NH2 (anilin) u th hin tnh baz. Tnh baz ca chng c sp
xp theo th t tng dn nh sau
B. NH3 < CH3NH2 < C6H5NH2
A. CH3NH2 < C6H5NH2 < NH3
D. C6H5NH2 < NH3 < CH3NH2
C. CH3NH2 < NH3 < C6H5NH2
Cu 33: Cho cc cht sau: C6H5NH2 (1); C2H5NH2 (2); (C2H5)2NH2 (3); NaOH (4); NH3 (5) Trt t tng dn
tnh baz (t tri qua phi) l:
A. (1), (2), (5), (3), (4)
B. (1), (5), (3), (2), (4)
C. (1), (5), (2), (3), (4)
D. (2), (1), (3), (5), (4)
Cu 34: Cho cc cht sau: (1) NH3; (2) CH3NH2; (3) (CH3)2NH; (4) C6H5NH2; (5) (C6H5)2NH. Trnh t tng
dn tnh baz ca cc cht trn l;.
A. (4) < (5) < (1) < (2) < (3).
B. (1) < (4) < (5) < (2) < (3).
C. (1) < (5) < (2) < (3) < (4).
D. (5) < (4) < (1) < (2) < (3).
Cu 35: C hai amin bc nht: A l ng ng ca anilin v B l ng ng ca metylamin. t chy hon ton
3,21 gam A thu c 336 cm3 N2 (ktc); t chy hon ton B cho hn hp kh v hi trong t l
VCO2 : VH 2O = 2 : 3 . Cng thc cu to thu gn ca A, B ln lt l

A. C2H5C6H4NH2 v CH3(CH2)2NH2
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B. CH3C6H4NH2 v CH3(CH2)3NH2
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GV : Nguyn V Minh
Amin
D. CH3C6H4NH2 v CH3(CH2)2NH2
C. CH3C6H4NH2 v CH3CH2 NHCH3
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Cu 36: t chy hon ton 6,2g mt amin n chc no, th phi dng 10,08 lt O2. cng thc phn t ca amin
B. CH3NH2
C. C3H7NH2
D. C4H9NH2
l A. C2H5NH2
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Cu 37: Hy ch ra iu sai trong cc iu sau?
A. Cc amin u c tnh baz
B. Tnh baz ca anilin yu hn NH3
C. Amin tc dng vi axit cho ra mui
D. Amin l hp cht hu c c tnh cht lng tnh
Cu 38: Dung dch etylamin tc dng vi dd ca nc no sau y?
C. NaCl
D. FeCl3 v H2SO4
A. NaOH
B. NH3
Cu 39: Hp cht no di y c tnh baz yu nht?
A. Anilin
B. Metylamin
C. Amoniac
D. imetylamin
Cu 40: Cht no di y c tnh baz mnh nht?
B. CH3CONH2
C. CH3CH2CH2OH
D. CH3CH2NH2
A. NH3
Cu 41: Dung dch no di y khng lm qu tm i mu?
B. NH3
C. CH3CH2NH2
D. CH3NHCH2CH3
A. C6H5NH2
Cu 42: Dung dch etylamin tc dng c vi cht no sau y?
C. Cu(OH)2/ddNaOH
D. Cu(OH)2
A. Giy pH
B. dd AgNO3
Cu 42: Pht biu no sai?
A. Anilin l baz yu hn NH3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp.
B. Anilin khng lm i mu giy qu tm.
C. Anilin t tan trong nc v gc C6H5- k nc.
D. Nh tnh baz, anilin tc dng vi dd Brom.
Cu 43: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y?
B. Anilin v xiclohexylamin
A. dd anilin v dd NH3
C. Anilin v phenol
D. Anilin v benzen.
Cu 44: Theo s phn ng sau:
0
0
Fe,HCl,du
3 ,H 2SO 4
CH4 t
A tC
B HNO
D. th A, B, C, D ln lt l :

C
1:1

A.C2H2, C6H6, C6H5NO2, C6H5NH2

B. C2H2, C6H6, C6H5NO2, C6H5NH3Cl
D. C6H6, C6H5NO2, C6H5NH2,C6H5NH3Cl
C.C2H4, C6H6, C6H5NH2, C6H5NH3Cl
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Cu 45: Trung ha 3,1 gam mt amin n chc X cn va 100ml dd HCl 1M. CTPT X l?
B. CH5N
C. C3H9N
D. C3H7N
A. C2H5N
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GV : Nguyn V Minh
Amin
Cu 46: t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua
bnh ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc
dng vi HNO2 to ra kh N2. X l:
A. imetylamin
B. anilin
C. etylamin
D. Metylamin
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Cu 47: Cho cc cht C4H10O, C4H9Cl, C4H10, C4H11N. S ng phn cu to ca cc cht gim theo th t l
B. C4H10O, C4H11N, C4H10, C4H9Cl
A. C4H11N, C4H10O, C4H9Cl, C4H10
D. C4H10O, C4H9Cl, C4H10, C4H11N.
C. C4H10O, C4H9Cl, C4H11N, C4H10
Cu 48: Cho cc hp cht hu c:
(1) amin no n chc mch h
(2) ancol no, n chc, mch h;
(3) xicloankan;
(4) ete no, n chc, mch h;
(5) anken;
(6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin;
(8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. (1), (3), (5), (6), (8).
B. (3), (4), (6), (7), (10).
C. (3), (5), (6), (8), (9).
D. (2), (3), (5), (7), (9).
Cu 49: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dung
dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l
A. 3.52 gam
B. 6.45 gam
C. 8.42 gam
D. 3.34 gam
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Cu 50: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch
thu c 51,7 gam mui khan. Cng thc phn t 2 amin l
B. C2H7N v C3H9N
A. CH5N v C2H7N
D. C3H7N v C4H9N
C. C3H9N v C4H11N
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Cu 51: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol),
C6H6(benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l
A. 5
B. 6
C. 7
D. 8
Cu 52: Dy no sau y c sp xp theo chiu tng tnh baz
A. C2H5ONa, NaOH, NH3, C6H5NH2, CH3C6H4NH2, CH3NH2

B. C6H5NH2, CH3C6H4NH2, NH3,CH3NH2, NaOH, C2H5ONa.

C. NH3, C6H5NH2, CH3C6H4NH2, CH3NH2, C2H5ONa, NaOH
D. C6H5NH2, CH3C6H4NH2, NH3,CH3NH2, C2H5ONa, NaOH.
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GV : Nguyn V Minh
Amin
Cu 53: Cho 6,75 g mt amin n chc A tc dng vi dung dch HCl d. C cn dung dch sau phn ng thu
12,225 g mui khan. t chy hon ton cng lng A nh trn ri cho sn phm chy li qua dung dch
Ca(OH)2 d thu c khi lng kt ta l :
A. 10 gam
B. 20 gam
C. 15 gam
D. 30 gam
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Cu 54:
(1)
(2)
(3)
(4)
X
Y
Z
Anilin
Axetilen
X, Y , Z ln lt l :
A. C6H6; C6H5NO2; C6H5NH3Cl
B. C6H6; C6H5NO2; C6H4(NO2)2
D. C6H12 ; C6H6; C6H5NO2
C. C6H6; C6H5Cl; C6H5NO2
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Cu 55:
C2H5Br

KOH/ancol, t0

HBr

NH3 d

Z (sn phm chnh)

Trong s , CTCT thu gn ca Z l :

B. CH3CH2Br
C. C2H5NHCH2CH3
D. CH3CH2NH2
A. (CH3CH2)3N
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Cu 56:
CH4

Anilin

Trong s trn, cht X v Z tng ng l :

A. Axetilen, Toluen
B. Xiclohexan, Toluen
C. Axetilen, nitrobenzen
D. Axetilen, pheyl, pheylamoniclorua
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Cu 57: t chy mt amin no n chc mch thng ta thu c CO2 v H2O c t l mol
nCO2 : n H2O = 8 :11 . CTCT ca X l:
A. (C2H5)2NH
B. CH3(CH2)3NH2
C. CH3NHCH2CH2CH3
D. C 3 phng n trn.
Cu 58: t chy hon ton a mol hn hp X gm 2 amin no n chc thu c 5,6 (l) CO2 (ktc) v 7,2 g H2O. Gi tr
ca a l: A. 0 ,05 mol
B. 0,1 mol
C. 0,15 mol
D. 0,2 mol
Cu 59: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO2 v
14,4 g H2O. CTPT ca hai amin l:
A. CH3NH2 v C2H7N
B. C3H9N v C4H11N
C. C2H7N v C3H9N
D. C4H11N v C5H13N
Cu 60: Dung dch metylamin khng tc dng vi cht no sau y?
A. HNO2
B. Dung dch HCl
C. Dung dch FeCl3
D. Dung dch Br2
Cu 44: Anilin v phenol u c phn ng vi:
A. Dung dch NaOH
B. Dung dch NaCl
C. Dung dch Br2
D. Dung dch HCl
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