(A) 165 J/K (B) +279 J/K (C) 387 J/K (D) 501 J/K
2. A plot of PV
m
vs P is drawn for three gases as shown below:
Which of the following statement is correct?
(A) Gas 1 has minimum critical temperature and is the easiest to liquify
(B) Gas 1 has maximum critical temperature and is the easiest to liquify
(C) Gas 3 has maximum critical temperature and is the easiest to liquify
(D) Gas 3 has minimum critical temperature and is the easiest to liquify
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3. Three different solutions of oxidising agents K
2
Cr
2
O
7
(M
0
= 294), I
2
(M
0
= 254) and KMnO
4
(M
0
= 158)
is titrated separately with 0.19 g of K
2
S
2
O
3
(M
0
= 190). The molarity of each oxidising agent is 0.1 M and
the reactions are:
2 2 3+ 2
2 7 2 3 4
Cr O S O Cr + SO
+
2 2
4 6 2 2 3
S O I + S O I
+
2 2
4 2 3 2 4
MnO + S O MnO + SO
Which of the following statements is(are) correct?
I. All three oxidising agents can act as selfindicators.
II. Volume of I
2
used is minimum.
III. Volume of K
2
Cr
2
O
7
used is maximum.
IV. Weight of KMnO
4
used in the titration is maximum.
(A) I, IV (B) I, II, IV (C) I, III, IV (D) I, III
4. Which of the following is true about Castner Kellner Cell ?
I. Na
+
ions are discharged instead of H
+
ions due to high over voltage
II. Sodium metal discharged at the anode combines with mercury to form sodium amalgam
III. The sodiummercury amalgam is treated with water to give sodium hydroxide and hydrogen gas
IV. The concentration of the brine solution used remains constant during the whole process
The correct choice is :
(A) I, II, III, IV (B) I, II, III (C) I, III (D) II, III
5.
3 4 10 3
4 HNO + P O 4 HPO + Product(s), the product(s) is(are) :
(A) NO
2
, N
2
O
3
and O
2
(B) N
2
O
3
and O
2
(C) N
2
O
3
, O
2
and N
2
O
5
(D) Only N
2
O
5
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For Question 6  7:
2 4
MeOH MeOH
dry HCl H SO (140 C)
D Glucopyranose (A) (B)
6. Compound (A) is :
(A) (B)
(C) (D) Both (A) and (B)
7. Compound (B) is :
(A) (B)
(C) (D) None of these
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8. Which of the following compounds show optical isomerism?
I. cis[Co(NH
3
)
4
Cl
2
]
+
II. trans[Co(en)
2
Cl
2
]
+
III. cis[Co(en)
2
Cl
2
]
+
IV. [Co(en)
3
]
3+
The correct choice is :
(A) I and II (B) II and III (C) III and IV (D) I, III and IV
9. Some reactions are given below:
I.
2 3
FeO + SiO FeSiO
II.
2 2
FeS + 3O 2FeO + 2SO
III.
2 2 2 2
2Cu S + 3O 2Cu O + 2SO
IV.
2 2 2 2
2Cu O + Cu SO 6Cu + SO
The reactions actually taking place during bessemerisation are:
(A) I, II, III, IV (B) I, III (C) I, III, IV (D) III, IV
10. Which of the following is correct :
I. B is
O O
 
Ph C C Ph
II. D is
OH

Ph C COOH

Ph
III. F is
2
O

Ph C CH Ph
(A) I, II, III (B) I, II (C) II, III (D) None of these
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11. The major product of the reaction :
(A) (B) (C) (D)
12. Relate the following compounds :
(A) Identical (B) Enantiomers (C) Diastereomers (D) Different compounds
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SECTION  II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 4 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
13. The conductivity () of 10
3
M Na
2
SO
4
solution is 2.6 10
4
Scm
1
and increases to 8 10
4
Scm
1
when
the solution is saturated with CaSO
4
. The molar conductivity/conductance values of Na
+
and Ca
2+
are
50 Scm
2
mol
1
and 120 Scm
2
mol
1
respectively and conductivity of water is
2
H O
( ) is 10
5
Scm
1
.
Neglecting the distance factor answer the following:
(A) Molar conductance of sulphate ions is 150 Scm
2
mol
1
(B) Solubility of CaSO
4
in presence of 10
3
M Na
2
SO
4
is 2 10
3
mol / L
(C) Solubility product of CaSO
4
is 6 10
6
(D) If distance factor is neglected then molar conductance of a weak electrolyte is independent of
dilution
14. Thallium sulphide (Tl
2
S) is sparingly soluble in water, however whatever amount of sulphide ions get
dissolved, are almost completely hydrolysed to HS
)
(A) pH of solution is 6
(B) K
sp
of Tl
2
S is 410
24
(C) Concentration of sulphide ions ([S
2
]) is 10
12
M
(D) Tl exists in +1 oxidation state due to inert pair effect
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15. Which of the following is true about Mn
2
O
7
?
(A) It is a covalent green oil
(B) Each Mn is tetrahedrally surrounded by O's and it has a Mn O Mn bridge
(C) It is isostructural w.r.t Cl
2
O
7
(D) The ability of oxygen to stabilise high oxidation states exceeds that of fluorine which explains
that the highest fluoride which exists is MnF
4
whereas the highest oxide which exists is Mn
2
O
7
16. Styrene undergoes following reactions in acidic medium:
The various intermediate formed are:
(A) (B) (C) (D)
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SECTION  III
SUBJECTIVE TYPE
This Section contains 7 Subjective Questions. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer 5 should be filled
as 5 in the OMR sheet]
17. A straight line was obtained on plotting
n
10 10
log log (a )
dx
vs x
dt
 

\
with an intercept on log
dx
dt
 

\
axis
equal to 0.6021. The rate constant for the reaction is ....................litre
n1
mole
1 n
t
1
.
18. The quantum number n, corresponding to the excited state of He
+
ion, if on transition from that state to
the ground state it emits two photons in succession with wave lengths 121.5 nm and 30.4 nm, is ........
19. The total number of iron atoms present in the Prussian Blue coloured precipitate is _______
20. 20. 20. 20. The freezing point of 0.05 molal NaHSO
4
is 0.198C. The percentage of HSO
4
ions that transfers a
proton to water is 10x %. The value of x is _____. [Assume 100% ionization of NaHSO
4
and
2
1
f H O
(K ) = 1.8K molality
]
21. If 1bromo2butene is treated with Br
2
/CCl
4
, how many pairs of diastereomers would result?
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22. Number of amphoteric species out of Na
2
O, MgO, PbO, Al
2
O
3
, SnO
2
, BeO
2
, SiO
2
ZnO, Al(OH)
3
, CaO,
SO
3
and NaHCO
3
is _______ .
23. How many moles of Grignard Reagent (CH
3
MgBr) will be required to react completely with 1 mole of
the following compound?
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PART  II (PHYSICS) 80 MARKS
SECTION  I
STRAIGHT OBJECTIVE TYPE
This Section contains 12 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
24. If an object is placed 20 cm in front of a half thin convex lens of focal
length 10 cm, as shown in figure, then coordinates of image taking p
as origin are:
(A) [20 cm, 0.2 cm] (B) [40 cm, 0.4 cm]
(C) [40 cm, 0.2 cm] (D) [20 cm, 0.4 cm]
25. The voltage shown in the figure is applied
to a 0.5 H inductor. The graph of current
in inductor ( )
L
i versus time (t) is
represented best in:
(A) (B) (C) (D)
26. A rectangular bar of soap having density 800 kg/m
3
floats in water
of density 1000 kg/m
3
. Oil of density 300 kg/m
3
is slowly added,
forming a layer that does not mix with water. When top surface of
the oil is at the same level as the top surface of the soap, what is
the ratio of the oil layer thickness to the soaps thickness, x/L?
(A)
2
10
(B)
2
7
(C)
3
10
(D)
3
8
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27. A particle performs simple harmonic oscillations along a straight line with a period T and amplitude a.
Magnitude of the mean velocity of the particle averaged over the time interval during which it travels a
distance
2
a
starting from an extreme position is :
(A)
a
T
(B)
2a
T
(C)
3a
T
(D)
2
a
T
28. A wire carrying a current of 3 A is bent in the form of a parabola
2
4 y x =
as shown in figure, where x and y are in meter. The wire is placed in a
uniform magnetic field B = 5
i N (B) 60
i N
(C) 30
i + N (D) 30
i N
29. Figure shows a system of two blocks of masses 10 kg and 5 kg, connected by
ideal strings and pulleys. Here ground is smooth and friction coefficient
between the two blocks is 0 5 . = . A horizontal force F is applied on lower
block as shown. The minimum value of F required to start sliding between the
blocks is: (Take g = 10 m/s
2
)
(A) 12.5 N (B) 25 N
(C) 50 N (D) 100 N
30. A screw gauge has 100 parts on circular scale and one rotation of a circular scale the screw advances a
distance of 1 mm. The L.C. of screw gauge is:
(A) 0.1 cm (B) 0.01 cm (C) 0.001 cm (D) 0.02 cm
31. A boy of mass 30 kg starts running from rest along a circular path of radius 6 m with constant tangential
acceleration of magnitude 2 m/s
2
. After 2 sec from start he feels that his shoes started slipping on ground.
The friction coefficient between his shoes and ground is: (Take g = 10 m/s
2
)
(A)
1
2
(B)
1
3
(C)
1
4
(D)
1
5
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32. The current in a circuit varies with time as I = 2 t . Then the rms value of the current for the interval
t = 2 to t = 4 sec is:
(A) 3 A (B) 2 3 A (C) 3 2 / A (D) (4 2 2) A
Paragraph Question 33  35
A uniform rod is lying at rest on a frictionless horizontal surface. A particle of
same mass as of the rod collides with the rod at its end at an angle from the
normal as shown in the figure. Assume that there is no friction between the rod
and particle and the collision is perfectly elastic.
33. The magnitude of the velocity of the centre of mass of the rod after collision is:
(A) v cos (B) v sin (C)
2
5
vcos (D)
2
5
v sin
34. The magnitude of change in angular momentum of the rod about the point O after collision is:
(A) zero (B)
1
5
m vcos (C)
1
5
m v sin (D)
6
5
m v sin
35. The magnitude of the change in velocity of the particle after collision is:
(A)
8
5
vcos (B)
2
5
vcos (C)
8
5
v sin (D)
2
5
v sin
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SECTION  II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 4 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
36. The container containing some liquid shown in the diagram is given some small acceleration a
. P
A
and
P
B
represent pressures at A and B (both are fixed in the reference from of vessel, inside the vessel)
respectively, and P
0
= P
A
P
B
when the vessel is kept at rest in equilibrium:
(A) If a
is directed upwards,
0 A B
P P P >
(B) If a
39. In the figure shown R is a fixed conducting ring of negligible resistance and radius a. PQ is a uniform
rod of resistance r. It is hinged at the centre of the ring and rotated about this point in clockwise direction
with a uniform angular velocity . There is a uniform magnetic field of strength B pointing inwards.
r is a stationary resistance
(A) Current through r is zero.
(B) Current through r is
2
2
5
B a
r
 


\
(C) Direction of current in external r is from centre to circumference
(D) Direction of current in external r is from circumference to centre
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SECTION  III
SUBJECTIVE TYPE
This Section contains 7 Subjective Questions. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer 5 should be filled
as 5 in the OMR sheet]
40. A thin double convex lens forms a real image of an object on a screen which is fixed. Now the lens is
given a constant velocity
0
v along its axis and away from the screen. For the purpose of forming the
image always on the screen, the object is also required to be given an appropriate velocity. Find the
speed of the object (in m/s) at the instant its size is n
times the size of image.
(Take 1 2 n = and
0
4 v m s = )
41. A circuits for the measurement of resistance by potentiometer is shown.
The galvanometer is connected at point Aand zero deflection is observed at
length 30 PJ cm = . In second case the secondary cell is changed.
Take 10
s
E V = and 1 r = in 1
st
reading and 5
s
E V = and 2 r = in 2
nd
reading. In second case, the zero deflection is observed at length 10 PJ cm = .
What is the resistance ( ) R inohm ?
42. A square loop of area
3 2
2 5 10 . m
= ]
46. A coil is connected to an alternating emf of voltage 24 V and of frequency 50 Hz. The reading on the
ammeter connected to the coil in series is 10 mA. If a 1 F capacitor is connected to the coil in series the
ammeter shows 10 mA again. What would be the approx reading on a dc ammeter (in A) if the coil was
connected to a 180 V dc voltage supply? (Take
2
10 = )
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PART  III (MATHEMATICS) 80 MARKS
SECTION  I
STRAIGHT OBJECTIVE TYPE
This Section contains 12 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
47. O is the vertex, P and Q are end points of focal chord of parabola
2
4 y x = . Circles with OP and OQ as
diameter intersect at R. If equation of line OR is 2y = x then the point of intersection of tangents at P and
Q is :
(A) ( ) 1 0 , (B) ( ) 1 1 , (C) (1, 0) (D) ( ) 1 1 ,
48. If A is a square matrix such that :
( )
4 0 0
0 4 0
0 0 4
A adj A
(
(
=
(
(
, then
( ) Adj Adj A
Adj A
is equal to :
(A) 256 (B) 64 (C) 32 (D) 16
49.
2
0
1
1 2 3
x
lim x . . .
x
  (
+ + + 
(

(
\
is equal to, where [.] is greatest integer function :
(A) 1 (B)
3
2
(C)
1
2
(D) 2
50. a, b, c are all different and nonzero real numbers which are in arithmetic progression. If the roots of the
quadratic equation
2
0 ax bx c + + = are and such that
1 1
,
+ + and
2 2
+ are in
geometric progression, then the value of
a
c
is :
(A) 1 (B) 2 (C) 3 (D) 4
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51.
2
5 2 3 2 4
3 2
 

+

\
x x
a b
x x x x
ln a ln b
x dx
a b a b
is equal to : (where a, b R
+
)
(A)
2 3
2 3
2 3
1
6
x x
x x
a b
a b ln k
e
ln a b
+ (B)
2 3 2 3 2 3
1 1 1
6
x x x x
ln k
ln a b a b e a b
+
(C)
( )
2 3
2 3 2 3
1 1
6
x x
x x
ln a b k
ln a b a b
+ (D)
( )
2 3
2 3 2 3
1 1
6
x x
x x
ln a b k
ln a b a b
+
52. A coin is tossed 2n times. The chance that the number of times one gets head is not equal to the number
of times one gets tail is :
(A)
( )
( )
2
2
2 ! 1
2
!
n
n
.
n
 

\
(B)
( )
( )
2
2 !
1
!
n
n
(C)
( )
( )
2
2 ! 1
1
4
!
n
n
.
n
(D) None of these
53.
( )
( )
6 5
25
25
3
1
3 2
9
6
7
81 3
7 125
409
log
log
log
log
N
 
+
 =

\
, then
2
log N has the value :
(A) 0 (B) 1 (C) 1 (D) None of these
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Paragraph for Q.54  55
The general solution of a differential equation of the form :
1 2
1 2
1 2
0
n n n
n
n n n
d y d y d y
a a . . . a y
dx dx dx
+ + + + = (a
i
s being constants) is given by the following rules :
(i) If the roots of the corresponding auxiliary equation
1 2
1 2
0
n n n
n
D a D a D . . . a
+ + + + =
in D has unequal real roots
1 2 3 n
, , , . . ., then the general solution will be :
1 2
1 2
n
x x x
n
y c e c e . . . c e
= + + + , where c
i
s are arbitrary constants.
(ii) If the corresponding auxiliary equation has two equal roots (say,
1 2
= ) and the rest are unequal real
roots then the general solution will be : ( )
3 1
1 2 3
= + + + +
n
x x x
n
y c x c e c e . . . c e
.
(iii) If two roots of the corresponding auxiliary equation are
1 2
i , i = + = and the rest are real
and unequal then the general solution will be : ( )
3
3
n
x x x
n
y Acos x B sin x e c e . . . c e
= + + + + .
54. The general solution of the equation
3 2
3 2
7 16 12 0
d y d y dy
y
dx
dx dx
+ = is :
(A)
2 2 3
1 2 3
x x x
c e c e c e
+ + (B) ( )
2 3
1 2 3
x x
c x c e c e + +
(C) ( )
3 2
1 2 3
x x
c x c e c e
+ + (D) ( )
2 3
3
x x
Acos x B sin x e c e + +
55. ( )
1 2 3
x x
y c cos x c sin x e c e
+
=
+
1
n n
n n
n
 sin x   cos x
b lim lim
+
=
+
( ) 1 2
1
4 2 2 2 n
n
c lim cos cos . . . . . cos
n n n n
(
= + + + +
(
. Then :
Range of f (x) is :
(A) [0, 1] (B)
1
1
2
,
(
(
(C)
1
1
2
,
(
(
(D)
1
2
2
,
(
(
Paragraph for Q.58
In a ABC , radii of escribed circles are r
1
, r
2
, r
3
and inradius of the circle is r.
58. A(z
1
) ; B(z
2
) ; C (z
3
) are vertices of a ABC in Argand plane and
1 2 3
8  z   z   z  = = = then
1 2 3
r r r r + + is :
(A) 8 (B) 16 (C) 24 (D) 32
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SECTION  II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 4 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
59. A forecast is to be made of the results of five cricket matches, each of which can be a win or a draw or a
loss for Indian team. Let,
p = number of forecasts with exactly one error
q = number of forecasts with exactly three errors and
r = number of forecasts with all five errors
Then the correct statement(s) is(are) :
(A) 2 5 = q r (B) 8p = q (C) 8p = 5r (D) ( ) 2 p r q + >
60. Let a function f satisfy ( ) ( ) ( ) ( ) f x f x f x f x x R = and f (0) = 3, which of the following
statements is correct ?
(A) The value of ( ) ( ) f x f x for all real x is 9
(B) The value of ( ) ( ) f x f x for all real is 9 x
(C)
( )
51
51
1
equals 17
3
dx
f x
(D)
( )
51
51
1
3
dx
f x
equals 34
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61. Which of the following statements is(are) true ?
(A) The number of non zero complex roots of equation
2
z iz = is 3
(B) For k = 0, 1, 2, 3..6 ; z
k
be the root of (z + 1)
7
+ z
7
= 0 then
6
0 =
k
Re(z
k
) is 7
(C) If 1
1
and z z represents adjacent vertices of a polygon of n sides and
( )
( )
1
1
2 1
Im z
Re z
= then n is 8
(D) For real ( )
3 2
, if
1 2
+
i sin
i sin
=
+
`
)
a a
a
a a
n
a
n
k
k . n k
lim
n
/
is equal to _____.
66. If f (x) be a twice differentiable function from R R such that ( ) ( ) ( )
2
2 0 t f x tf x f x + = has two
equal values of t for all x and f (0) = 1, ( ) 0 2 f = . Find
( )
0
1
2
 

\
x
f x t
lim
x
.
67. Let f (x) be a polynomial of degree six divisible by x
3
, and having a point of extremum at x = 2. If ( ) f x
is divisible by 1 + x
2
, find the value of
( )
( )
3 2
4 1
f
f
.
68. If r N and z = x + iy, then find number of positive integral solutions of z (i.e. both x and y are positive
integers) satisfying the equations 8 2  z  r + = and ( ) 8
4
arg z
= is _______.
69. If
1 2 3 4 5
1 2 3 4
5 10 10 5
4 6 4
n n n n n n
r r r r r r
n n n n n
r r r r r
C C C C C C n k
C C C C C r k
+ + + + +
+ + + +
+ + + + + +
=
+ + + + +
. Find the value of k.
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