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  • 3 Formulations of Stat Physics

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    ddyzlee
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    The document discusses three formulations of statistical physics: microcanonical, canonical, and grand canonical. The microcanonical formulation describes an isolated system with fixed energy, volume, and particle number where temperature fluctuates. The canonical formulation describes a system in contact with a heat bath at fixed temperature, volume, and particle number where energy fluctuates. The grand canonical formulation describes a system that can exchange both energy and particles with a reservoir at fixed temperature, volume, and chemical potential where both energy and particle number fluctuate.

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    formulations of stat mech

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    The document discusses three formulations of statistical physics: microcanonical, canonical, and grand canonical. The microcanonical formulation describes an isolated system with fixed energy, volume, and particle number where temperature fluctuates. The canonical formulation describes a system in contact with a heat bath at fixed temperature, volume, and particle number where energy fluctuates. The grand canonical formulation describes a system that can exchange both energy and particles with a reservoir at fixed temperature, volume, and chemical potential where both energy and particle number fluctuate.

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    Attribution Non-Commercial (BY-NC)
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    20 vues1 page

    3 Formulations of Stat Physics

    Transféré par

    ddyzlee
    The document discusses three formulations of statistical physics: microcanonical, canonical, and grand canonical. The microcanonical formulation describes an isolated system with fixed energy, volume, and particle number where temperature fluctuates. The canonical formulation describes a system in contact with a heat bath at fixed temperature, volume, and particle number where energy fluctuates. The grand canonical formulation describes a system that can exchange both energy and particles with a reservoir at fixed temperature, volume, and chemical potential where both energy and particle number fluctuate.

    Droits d'auteur :

    Attribution Non-Commercial (BY-NC)
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 1

    3 FORMULATIONS OF STATISTICAL PHYSICS

    STATISTICAL (PROBABILITY)

    ENSEMBLE MACROSTATE

    THERMODYNAMIC

    Micro Canonical

    E, V, N (T fluctuates)

    1 Pr

    S (E, V, N) = k ln

    Canonical

    T, V, N (E fluctuates) fl )

    Pr

    e Er
    Z

    kT

    F (T, V, N) = - kT lnZ

    Grand Canonical

    T, V, PNr (E, N fluctuate)

    e( ENr N ) kT
    Z

    (T, V, ) = - kT lnZ

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