GENERAL ENERGY BALANCE

J(mu)
c
Jt
= __u +
1
2
u
2
+ gz] m _
]s
+

+ work rotc
J(mu)
c
Jt
+ __E +
1
2
u
2
+ gz] m _
]s
=

+w

ENTHALPY
JE = C
p
JI
INTERNAL ENERGY
Ju = C

JI

C
p
= C

+R
y =
C
p
C

TEMPERATURE DEPENDENCE OF HEAT CAPACITY

_
C
p
R
JI
1
1
0
= AI
0
( 1) +
B
2
I
0
2
(
2
1) +
C
S
I
0
3
(
3
1) +

I
0
_
1

]
=
I
I
0

MeanHeatcapacity:
(C
p
)
H
R
= A +
B
2
I
0
( +1) +
C
3
I
0
2
(
2
+ +1) +

:1
0
2

E = (C
p
)
H
(I I
0
)

LATENT HEAT
CLAPEYRONEQUATION
E = II
JP
sut
JI

TROUTONSRULE
E
n
RI
n
~1u
RIEDELEQUATION
E
n
RI
n
=
1.u92(ln P
c
1.u1S)
u.9Su I

n
=
I
n
I
c

WATSONEQUATION
E
2
E
1
= _
1 I

2
1 I

1
_
0.38

SECOND LAW
|w| = |
H
| |
c
|
p =
|w|
|
H
|
=
|
H
| |
C
|
|
H
|
= 1
|
C
|
|
H
|

|
H
|
|
C
|
=
I
H
I
C

J
c
= IJS
t

S
R
= _
C
p
g
R
JI
I

1
1
0
ln
P
P
0

_
C
p
g
R
JI
I

1
1
0
= Aln +_BI
0
+ _CI
0
2
+

2
I
0
2
__
+1
2
]_ ( 1)
Meanspecificcapacityf!ent!pyca"c#"atins:
(C
p
g
)
S
R
= A +_BI
0
+_CI
0
2
+

2
I
0
2
__
+1
2
]_
( 1)
ln

GENERAL ENTROPY BALANCE

(Sm )
]s
+
J(mS)
c
Jt
+
JS
su
t
Jt
= S
u

u
JS
su
t
Jt
=

]
I
c
.

IDEAL WORK
w

dcuI
= (Em )
]s
I
c
(Sm )
]s

W$enw
dcuI
> u%itist$e&ini&#&'!(!e)#i!e*+
W$enw
dcuI
< u%itist$e&a,i&#&'!(-taina-"e+

LOST WORK
w
Iost
= I
c
S
u