CHM3U Unit 3 - Quantities in Chemical Reactions Lesson 21 Test

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Unit 3 Test A
There are 20 multiple choice questions. The answer guide is the last page of the test. Tear that page off to do the multiple choice. They are worth one mark each. The second part of the exam, which consists of 7 questions, starts on page 5. Do only 5 of these. These questions are worth 6 marks each. 1. How many oxygen atoms are present in 1.00 mol of HNO2? (a) 6.02 X 1023 (b) 1.20 X 1024 (c) 1.81 x 1024 (d) 2.00 x 1023 2. The mass of 1.50 mol of H2O is (a) 18.0 g (b) 24.0 g (c) 13.5 g (d) 4.17 x 10-2 g 3. If you have 19.6 g of H2SO4, how many moles of H2SO4 do you have? (a) 5.00 mol (b) 98.1 mol (c) 5.90 x 1025 mol (d) 0.200 mol 4. The number of NO2 molecules in a 184 g sample of NO2 is (a) 6.02 x 1027 (b) 2.41 X 1024 (c) 4.00 X 1023 (d) 6.02 X 1023 5. The mass of 1.20 x 1024 molecules of CH4 is (a) 8.00 g (b) 16.0 g (c) 32.1 g (d) 64.0 g

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6. The molar mass of Fe2(SO5)3 is (a) 282.0 g (b) 255.0 g (c) 130.0 g (d) 447.9 g 7. The empirical formula of a substance is found to be CH3. The actual molecular mass of this compound is determined to be 15.0 g. The molecular formula of this compound is (a) C6H6 (b) CH3 (c) C2H6 (d) C3H9 8. In the reaction 3C + 2Fe2O3 4Fe + 3CO2 the number of moles of Fe that can be prepared from 25 mol of C reacting with 4 mol of Fe2O3 would be (a) 4 mol of Fe (b) 29 mol of Fe (c) 8 mol of Fe (d) 12 mol Fe 9. What is the percent of Mg in Mg3(PO4)2? (a) 11.6% (b) 72.9% (c) 27.7% (d) 43.4% 10. Which one of the following samples contains the greatest number of molecules? (a) 10.0 g of H2 gas (b) 20.0 g of NH3 gas (c) 25.0 g of CO2 gas (d) 30.0 g of O2 gas 11. The simplest possible ratio between the elements in a compound is called (a) the molecular formula (b) the true formula (c) the molar formula (d) the empirical formula 12. The analysis of a certain compound showed that 7.0 g of nitrogen were combined with 1.0 g of hydrogen. The simplest formula of this compound would be (a) N2H (b) NH2 (c) NH7 (d) N7H
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13. Consider the following reaction: SO3 + H2O H2SO4 When 75 g of SO3 reacts with 25 g of H2O the following statement can be made. (a) SO3 is the limiting reagent and it will be used up completely. (b) SO3 is the limiting reagent, it will not be completely used up in this reaction. (c) H2O is the limiting reagent and it will be used up completely. (d) H2O is the limiting reagent, it will not be completely used up in this reaction. 14. Which of the following statements is/are true about vitamin C, C6H8O6? 1. It has an empirical formula of C3H4. 2. It contains 40.9% carbon. 3. It contains one mole of carbon atoms per mole of molecules of vitamin C. (a) 1 only (b) 1 and 2 (c) 1, 2, and 3 (d) 2 only 15. If 326.0 g of tin(11) chloride is the actual yield obtained in a reaction for which the theoretical yield is 387.59 g, the percentage yield is (a) 71.15% (b) 78.51% (c) 81.98% (d) 84.11% 16. The empirical formula of a compound is HO. Its molar mass is 34.02 g/mol. What is its molecular formula? (a) HO (b) H2O2 (c) H6O6 (d) H2O6 17. Hydrogen and nitrogen react to form ammonia according to the reaction, 3 H2 + N2 2 NH3. If 4.0 moles of H2 with 2.0 moles of N2, how many moles of NH3 are produced? (a) 0.38 moles (b) 2.0 moles (c) 2.7 moles (d) 4.0 moles

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18. According to the equation Mg + 2 HCl MgCl + H2 how many moles of magnesium are needed to produce 12.34 moles of hydrogen gas? (a) 6.17 moles (b) 24.68 moles (c) 12.34 moles (d) 3.09 moles 19. When does a reaction go to completion? (a) When one reactant is used up (b) When all reactants are used up (c) When products are made available (d) None of the above 20. Which reactant is the limiting reagent in the following reaction, if 10 mol CH4 reacts with 12 mol O2? CH4 + 2 O2 CO2 + 2 H2O (a) CH4 (b) O2 (c) CO2 (d) H2O

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Short Answer Questions Choose only 5 of the 7 questions, they are worth 6 marks each, write your answers on the lined paper provided. 1. A group of students carried out a lab similar to the one you did in class to find the empirical formula of magnesium oxide. They found the mass of a clean dry crucible and lid. They added some calcium metal to the crucible and found the mass again. They then heated the whole thing to form calcium oxide. After cooling, the mass of the crucible, lid and calcium oxide was determined. The following data was collected: Material crucible and lid crucible, lid and calcium before heating crucible, lid and contents after heating Mass 42.66 g 62.62 g 70.70 g

Calculate the empirical formula of the compound formed.

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2. Sodium reacts with chlorine gas to form sodium chloride. Calculate the mass of sodium chloride that would be expected from the reaction between 0.460 g of sodium with 0.426 g of chlorine.

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3. Phosphoric acid (H3PO4) is made in industry by reacting sulphuric acid with mineral phosphates. For example, 5 H2SO4 + Ca5(PO4)3F + 10 H2O HF + 3 H3PO4 + 5 CaSO4 . 2H2O If 300 g of H2SO4 and 300 g of Ca5(PO4)3F are reacted in an excess of water what mass of phosphoric acid can be produced? If 140.0 g of phosphoric acid are actually produced what is the percent yield?

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4. In this unit you carried out a lab where you reacted a known amount of CuCl2 . 2H2O with an excess of aluminium. You observed the actual amount of copper produced in this reaction and you calculated the mass of copper which could theoretically be produced from the known amount of CuCl2 . 2H2O. Using these values you calculated the percent yield of copper. Many groups found their percent yield to be greater than 100 %. Give at least two reasons (specific to this lab and reaction) why this might have happened. Explain your reasons.

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5. Consider the following reaction: Ca(OH)2 + 2 HCl CaCl2 + 2 H2O If 130 g of Ca(OH)2 is reacted with 120g of HCl, what mass of CaCl2 can be produced?

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6. Propane, C3H8, used in gas barbeques, burns in oxygen to produce carbon dioxide and water according to the following equation. C3H8 + O2 CO2 + H2O In a reaction 100.7 g of propane and 350.0 g of oxygen are available to react. Calculate the mass of water that would be formed in this situation.

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7. A compound is analyzed and found to contain 68.54 % carbon, 8.63 % hydrogen, and 22.83 % oxygen. The actual molar mass of this compound is known to be 140.00 g/mol. What is the molecular formula of this compound?

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Multiple Choice Answers 1. ____ 2. ____ 3. ____ 4. ____ 5. ____ 6. ____ 7. ____ 8. ____ 9. ____ 10. ____ 11. ____ 12. ____ 13. ____ 14. ____ 15. ____ 16. ____ 17. ____ 18. ____ 19. ____ 20. ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____

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