Vol c s/N

40
39
38
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
19
18
17
16
15
14
13
12
11
10
9
8
7
6
5
4
3
2
1
0

V B aadido V total
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45

[OH-]
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85

[H+]
0.1
0.09512195
0.09047619
0.08604651
0.08181818
0.07777778
0.07391304
0.07021277
0.06666667
0.06326531
0.06
0.05686275
0.05384615
0.0509434
0.04814815
0.04545455
0.04285714
0.04035088
0.03793103
0.03559322
0.03333333
0.03114754
0.02903226
0.02698413
0.025
0.02307692
0.02121212
0.01940299
0.01764706
0.01594203
0.01428571
0.01267606
0.01111111
0.00958904
0.00810811
0.00666667
0.00526316
0.0038961
0.0025641
0.00126582
0.0000001
1.9756E-13
1.9524E-13
1.9302E-13
1.9091E-13
1.8889E-13

pOH

pH
1
1.02171925
1.04346569
1.06526673
1.08715018
1.10914447
1.13127891
1.15358392
1.17609126
1.19883439
1.22184875
1.24517218
1.26884531
1.29291211
1.31742041
1.34242268
1.36797679
1.39414702
1.42100531
1.44863272
1.47712125
1.50657623
1.53711918
1.56889163
1.60205999
1.6368221
1.6734159
1.71213145
1.75332767
1.79745641
1.84509804
1.89701584
1.95424251
2.01822482
2.09108047
2.17609126
2.2787536
2.40936947
2.59106461
2.89762709
7
12.7042988
12.7094354
12.7143904
12.7191734
12.7237936

46
47
48
49
50

86
87
88
89
90

1.8696E-13
1.8511E-13
1.8333E-13
1.8163E-13
1.8E-13

12.7282594
12.7325786
12.7367586
12.7408061
12.7447275

1raD V (ml) 1raD dpH/dV

2daD V(ml) 2daD dpH2/dV2
0.5
0.02171925
1
36772.28392
1.5
0.021746444
2
18317.15074
2.5
0.021801038
3
12134.96879
3.5
0.021883444
4
9021.240522
4.5
0.021994294
5
7135.135495
5.5
0.022134445
6
5863.101129
6.5
0.022305003
7
4942.23566
7.5
0.022507341
8
4241.131379
8.5
0.022743127
9
3686.822378
9.5
0.023014363
10
3235.563654
10.5
0.023323429
11
2859.548874
11.5
0.023673134
12
2540.269265
12.5
0.024066793
13
2264.937632
13.5
0.024508306
14
2024.444931
14.5
0.025002269
15
1812.134224
15.5
0.025554104
16
1623.034395
16.5
0.026170234
17
1453.364317
17.5
0.026858293
18
1300.202303
18.5
0.027627404
19
1161.259936
19.5
0.028488538
20
1034.723749
20.5
0.029454979
21
919.1421473
21.5
0.03054295
22
813.3431591
22.5
0.031772444
23
716.3736506
23.5
0.033168363
24
627.4537337
24.5
0.034762106
25
545.9421163
25.5
0.036593802
26
471.3094488
26.5
0.038715551
27
403.1175931
27.5
0.041196216
28
341.0033331
28.5
0.044128739
29
284.665455
29.5
0.047641634
30
233.8544092
30.5
0.051917799
31
188.3639704
31.5
0.05722667
32
148.0244544
32.5
0.063982311
33
112.6971536
33.5
0.072855649
34
82.26971977
34.5
0.08501079
35
56.65224164
35.5
0.102662342
36
35.77366028
36.5
0.130615869
37
19.57741482
37.5
0.181695137
38
8.008498767
38.5
0.306562484
39
0.263448352
39.5
4.102372909
40
0.624248588
40.5
5.704298838
41
-0.175464386
41.5
0.0051366
42
-5504.335155
42.5
0.004954925
43
-5817.404409
43.5
0.004783027
44
-6141.390128
44.5
0.004620198
45
-6476.463311
45.5
0.004465792
46
-6822.795058

Punto inicial

Despues del
Punto Equivalencia
NOTA**
[HCl]
[KOH]
Kw
ka

Cuando son equimolares p

el exceso de oxihidrilo.
0.1
0.1
1E-14

46.5
47.5
48.5
49.5
25

0.004319225
0.00417996
0.004047508
0.003921422
0.25489455

47
48
49
37.25
12.5

-7180.556564
-7549.919114
93189.88535
-98.61613536
49.0398873

ando son equimolares podemos pasarlo por

exceso de oxihidrilo.
(V c. s/n)

14
12
10
8
6
4
2
0
0

10

Punto de equilibrio
14
12
10
8
6
4
2
20

30
pH

40

50

60

0
0

1raD dpH/dV

10

2daD dpH2/dV2
100000
80000
60000
40000
20000
0
-20000 0

10

20

30

40

50

60

6
5
4
3
2
1
0
0

10

pH

20

30

40

50

1raD dpH/dV

10

20

30

40

50

60

60