Contin Ed Unit 1 Energetics Worksheet Fri Nov 16 2012

1. Write the equation to show the enthalpy of formation for the

following compounds
a) C
2
H
4
b) C
2
H
6
c) H
2
O
2

d) N
2
H
4
e) NH
3
f) C
6
H
6


2. Use a standard enthalpies of formation table to determine the
change in enthalpy for each of these reactions. Please use the values that
are in kJ and NOT kcal.

a) 2 CO(g) + O
2
(g) ---> 2 CO
2
(g)
b) CH
4
(g) + 2 O
2
(g) ---> CO
2
(g) + 2 H
2
O(l)
c) 2 H
2
S(g) + 3 O
2
(g) ---> 2 H
2
O(l) + 2 SO
2
(g)


3. Use the following data draw the Born-Haber cycle for MgO and
calculate the lattice enthalpy of MgO.
Enthalpy of formation MgO : -601 kJ mol
-1

Enthalpy of atomization Mg: +148 kJ mol
-1
1
st
ionisation energy Mg: +738 kJ mol
-1

Bond dissociation O
2
: +498 kJ mol
-1
2
nd
ionisation energy Mg: +1451 kJ mol
-1

1
st
electron affinity O: -141 kJ mol
-1

2
nd
electron affinity O: +744 kJ mol
-1


































4. Use the bond energies table below to determine the enthalpy change
of reaction for the equations below


a) CH
4
+ Cl
2
CH
3
Cl + HCl

b) N
2
+ 3H
2
2NH
3


c)




5.