Etat dquilibre dun systme chimique
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aA(aq) + bB(aq) cC(aq) + dD(aq)

 4/ G! d c b a .  D  ,. D C B A 


C" B
. %

< FG=1 @HF 6<=( 1) 6<=> : '()1 @9 )(' , @BC
: IJB1 K
  7 =B
c

C . D
Qr = a b
A .B

 >: mol/l Z= @FB4 X = 7 >7B(  > T )@U9C 2 WB' XC [ X]
[ X]   X f `4  X i W1 <] 2 K _ KC . 
7 =B
.  b =d B

1 >9Fb _C@
S2O32-(aq) %4
3    ". I2(aq)  
/H I
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I2 (aq) + 2S 2 O23 (aq) 2I (aq) + S 4 O26 (aq) : ! '

:  ,.


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 %3 C3 t D

I2 = 1, 0.10 3 mol /
S 2 O23 = 2, 0.10 3 mol /
I = 5, 0.10 2 mol /
S 4 O26 = 2,0.104 mol /
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2

I . S 4 O26
Qr =
= 125
2
2

I
.
S
O
2 2 3
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2 >9Fb _C@
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CH3COOH(aq) + H2 O ( ) CH3COO (aq) + H3O+ (aq)

.(1) %_4 /  , %   ' %
4!3 j 1

CH3COO . H3O+
Qr =
CH3COOH
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  2
Page 1

CH3COO = H3O + = 1,2.10 4 mol /

t
t
CH3COOHt = 9, 6.10 4 mol /
`  . '  t D

Qr = 1,5.10 5
 : f <7  . '  4.' G  %o p '
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 I ' ,  .
2  
  <)  67Gi . F7g
"! '3 %4  D/ " q, ' ` Ag+(aq) 1! 
 :

)Cu(s) + 2Ag+ (aq) Cu2+ (aq) + 2Ag(s


  w13 o" C "
 %
x. 4D -
  w13 t
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 / I


C. Ag I
, Cu e.' Ag I
D . Cu
%3
 
 w{%! %
x `D . "! !, $y   1 '  / t D C ,
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+

2+

Cu2+
= Qr
2
Ag+
Jbg , >: ',W) l : )(' l)@ T  ( 4k 7B  K21
@3 >9Fb _C
1 ` !p `
%3 D ' AgCl 1%4 ' Ag2SO4 1! ,  ' '1
. Ag3PO4
2   j   %
4!3 ' .
3 , )(' =  W)
1 : pC@B
"  '  / Qr.eq
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D "B 


C
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! [X]eq 
.q3 %, Gf 'D2

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D
r4 
@, I WCW< : >FC )(' 91  . 7g
-3
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D % 
D V w h S%3 e "fg
 

/ C=1,0.10 mol/l

  
D D  25C / . = 5, 2mS.m1 :

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D  


C.. ,
"!  / -% : 25C

H O+ = 35,0mS.m2 .mol1
3

CH COO = 4, 09mS.m2 .mol1

3

2  
/ ' / Qr ,q .

II )1d) @9 <)1 4 > .

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r4 
@ @dw : 2 >FC< , 67 WF )('  >:) .
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D e "fg %3
  
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Page 2

C(mol/l)
1,0.10-2
5,0.10-3
2,0.10-3
1,0.10-3
-3
-3
-3
-1
16,2.10
11,4.10
6,9.10
4,9.10-3
(S.m )

 /   / D 
"
 B " B  
 %  1
. D C 4/,   / Qr,q '
: !"

H O+ = 35,0mS.m2 .mol1
3

CH COO = 4, 09mS.m2 .mol1

3

 /" 2
: gJ,
WF < x4 C) 1d ) W= '() , KC =B  @i W=
.  
7
) ) 1d pC@B 1
K ) ) 1d 6G ; Qr,q I ) W= '() , 2,wC _B '() FG=1
.  <@iW1 l v7B)l
: B1 2= > 7< >: '() FG=1 ) ) 1d })K

aA(aq) + bB(aq) cC(aq) + dD(aq)

K = Qr ,q =

C q .D q
A q .B q

: >)' Kr 67

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>7) ) )< 1d 2
%
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D ' %4!"
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4 K C3 "/
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: >7' : _ ~ iW` 7 (' : X

HC (g) + H2 O( ) C (aq) + H3 O + (aq)

@HF @ 6<=> : ) ) 1d 3
: (2) ( 1) I

/  H I.D I
D' %4!"

aA(aq) + bB(aq) cC(aq) + dD(aq)

K1

cC(aq) + dD(aq) aA(aq) + bB(aq)

K2

:   / '  %
4!3 ' 3 C 4/,   ,H %
4!3 C   /

K 1 = Qr1,q =

K 2 = Qr2 ,q =

C q . D q
A q . B q
A q . B q
C q . Dq

K1 =

1
:  /" I
G! I
K2

3 >9Fb _C@
1' D ,' 3 /
, . K1=5,5.10  $" 3 ,H n
1' D
` %3 '3 %4!"
. K2=1,8.10-10 $" 3 ,H  
10

Page 3

 1 ` %3
 "B Ag+ 
" B Cl- -    D .

2  /3
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x / %_4 , D
'  1  - '3 .

III   8@d  FG4 67)W9 =`>

1  @dw<  FG4 67 WF)W9 =`> .
r4 
@3 >FC
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D h 
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-2
-3
-3
)C(mol/l
1,0.10
5,0.10
2,0.10
1,0.10-3
-3
-3
-3
-1
16,2.10
11,4.10
6,9.10
4,9.10-3
) (S.m
1 ` " 4   C 4/, o/
2  /3
: gJ,
) FG4 I v7B)W9 =`> <1 7K:  
7 WF x4)@@g T
 FG4 x4)W9 =`> @F .
2  )1d @dw)  FG4 67)W9 =`> .

 ,H IC3  4" 0 3 I 

C   ' o/
r4 
@9 : 4 >FC FG4 4)W9 =`> )(. _7
" '" o I
1 I
 D .q%
 . C=1,0.10-2mol/l
 D D S1  h e "fg  D D S2  h
" . e
,H '  h 0 e "fg K1=1,6.10-5 :
,H '  h
0 e "f . K2=1,6.10-4 :
"
  
D S1 I
 D : 43 
/ S2

1 = 153S.cm 1 2 = 510S.cm1
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D  


C 
" B -    I S1 I
 D S2
2  " 4   '3 C o/

H O+ = 35, 0mS.m2 .mol1

3

CH COO = 4, 09mS.m2 .mol1

3

HCOO = 5, 46mS.m2 .mol1

: gJ,
7 )1d x4) @F  FG4 x4)W9 =`> @(. B

Page 4