Material Balance on Mixer

101

Stream 2

732
kg / hr
92.8934 kmole/hr

Stream 3

25000
301.51

M-

kg / hr
kmole/hr
Stream 3

n C4

Molecular
Mass
58.00

Mass
Fraction
0.0267

Mass Flow
Rate
667.50

nC5

72.00

0.1673

4182.50

nC6

86.00

0.1589

3971.25

n C7

100.00

0.0929

2321.75

iC5
2 MP
3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH

72.00
86.00
86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00

0.1077
0.0750
0.0482
0.0056
0.0121
0.0373
0.0373
0.0027
0.0112
0.0057
0.0018
0.0028
0.0253
0.0288
0.0118
0.0400
0.0387
0.0028
0.0598
1.00

2693.25
1875.25
1204.25
138.75
301.75
931.65
931.40
68.40
279.15
141.65
43.93
69.90
632.50
719.25
295.50
998.75
967.25
70.00
1494.50
25000.08

Components

Total

Stream 2

Compone
Molecular Mass
nts
H2
2

volume
fraction
0.78

Mole
Fraction
0.780

Mass
1.56

C1

16

0.099

0.099

1.58

C2

30

0.064

0.064

1.92

C3

44

0.038

0.038

1.67

n-C4

58

0.008

0.008

0.46

i-C4

58

0.008

0.008

0.46

n-C5

72

0.002

0.002

0.14

i-C5

72

0.001
1.00

0.001
1.00

0.07
7.88

Mass
Fraction
0.0056

Mole
Fraction

H2

Molecular
Mass
2.00

C1

16.00

0.0057

0.0233

C2

30.00

0.0069

0.0151

C3

44.00

0.0060

0.0090

n C4

58.00

0.0276

0.0311

nC5

72.00

0.1631

0.1478

nC6

86.00

0.1543

0.1171

n C7

100.00

0.0902

0.0589

i-C4

58.00

0.0017

0.0019

iC5
2 MP
3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6

72.00
86.00
86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00

0.1049
0.0729
0.0468
0.0054
0.0117
0.0362
0.0362
0.0027
0.0108
0.0055
0.0017
0.0027
0.0246

0.0951
0.0553
0.0355
0.0041
0.0089
0.0236
0.0236
0.0017
0.0071
0.0036
0.0011
0.0018

Total
Stream 4

Components

0.1837

0.0206

C7H8
CP
MCP
CH
ECP
MCH

92.00
70.00
84.00
84.00
98.00
98.00
Total

0.0280
0.0115
0.0388
0.0376
0.0027
0.0581
1.00

0.0198
0.0107
0.0301
0.0292
0.0018
0.0387
1.00

M-

Stream 4

Molar Flow
Rate
11.51
58.09
46.18
23.22
37.41
21.81
14.00
1.61
3.51
9.32
9.31
0.68
2.79
1.42
0.44
0.70
8.11
7.82
4.22
11.89
11.51
0.71
15.25
301.51

25732.08
394.40

kg / hr
kmole/hr

Molar Flow
Rate

0.1980

Mass Flow
Rate
144.91

0.2010

147.14

9.1964

0.2437

178.36

5.9452

0.2122

155.32

3.5299

0.0589

43.10

0.7431

0.0589

43.10

0.7431

0.0183

13.38

0.1858

0.0091
1.00

6.69
732.00

0.0929

Mass Flow Rate

Molar Flow
Rate

144.91

72.4569

147.14

9.1964

178.36

5.9452

155.32

3.5299

710.60

12.2518

4195.88

58.2761

3971.25

46.1773

2321.75

23.2175

43.10

0.7431

2699.94
1875.25
1204.25
138.75
301.75
931.65
931.40
68.40
279.15
141.65
43.93
69.90
632.50

37.4991

Mass Fraction

21.8052
14.0029
1.6134
3.5087
9.3165
9.3140
0.6840
2.7915
1.4165
0.4393
0.6990
8.1090

72.4569

92.8934

719.25
295.50
998.75
967.25
70.00
1494.50
25732.08

7.8179
4.2214
11.8899
11.5149
0.7143
15.2500
394.40

Material Balance Around Reactor

R-101
Stream 8

Stream 7

25732.08 kg / hr
394.40 kmole/hr
25
Stream 7

Molecular
Mass

Mass
Fraction

Mole Fraction

H2

2.00

0.0056

0.1837

C1

16.00

0.0057

0.0233

C2

30.00

0.0069

0.0151

C3

44.00

0.0060

0.0090

n C4

58.00

0.0276

0.0311

nC5

72.00

0.1631

0.1478

nC6

86.00

0.1543

0.1171

n C7

100.00

0.0902

0.0589

i-C4

58.00

0.0017

0.0019

iC5
2 MP

72.00
86.00

0.1049
0.0729

0.0951
0.0553

Components

3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
H2O
C2Cl4

86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
18.00
94.00

0.0468
0.0054
0.0117
0.0362
0.0362
0.0027
0.0108
0.0055
0.0017
0.0027
0.0246
0.0280
0.0115
0.0388
0.0376
0.0027
0.0581
0.0000
3.000E-06
1.00

Molecular
Mass

Mass
Fraction

Mole Fraction

H2

2.00

0.0013

0.0482

C1

16.00

0.0057

0.0272

C2

30.00

0.0070

0.0177

C3

44.00

0.0062

0.0107

n C4

58.00

0.0137

0.0180

nC5

72.00

0.0394

0.0416

nC6

86.00

0.0362

0.0320

n C7

100.00

0.0072

0.0055

i-C4

58.00

0.0154

0.0202

iC5
2 MP
3 MP
2,2 DMB
2,3DMB
2 MH

72.00
86.00
86.00
86.00
86.00
100.00

0.2321
0.1192
0.0730
0.0455
0.0287
0.0600

0.2451
0.1054
0.0646
0.0403
0.0254
0.0457

Total

0.0355
0.0041
0.0089
0.0236
0.0236
0.0017
0.0071
0.0036
0.0011
0.0018
0.0206
0.0198
0.0107
0.0301
0.0292
0.0018
0.0387
0.0000
0.0000
1.00

Stream 8

Components

3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
2,2,3 TMB
H2O
C2Cl4
HCL
Total

100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
100.00
18.00
94.00
36.50

0.0497
0.0162
0.0307
0.0136
0.0116
0.0045
0.0000
0.0000
0.0080
0.0252
0.0663
0.0027
0.0733
0.0072
0.0000

1.00E-06
2.30E-05
1.00

0.0378
0.0123
0.0233
0.0104
0.0088
0.0034
0.0000
0.0000
0.0087
0.0228
0.0601
0.0021
0.0569
0.0055
0.0000
0.0000
0.0000
1.0000

ctor
25732.08
338.32

kg / hr
kmole/hr

Chlorine Injection
kg / hr

Mass Flow
Rate

Molar
Flow Rate

144.91

72.4569

147.14

9.1964

178.36

5.9452

155.32

3.5299

710.60

12.2518

4195.88

58.2761

3971.25

46.1773

2321.75

23.2175

43.10

0.7431

2699.94
1875.25

37.4991
21.8052

1204.25
138.75
301.75
931.65
931.40
68.40
279.15
141.65
43.93
69.90
632.50
719.25
295.50
998.75
967.25
70.00
1494.50
0.00
7.50E-05
25732.08

14.0029
1.6134
3.5087
9.3165
9.3140
0.6840
2.7915
1.4165
0.4393
0.6990
8.1090
7.8179
4.2214
11.8899
11.5149
0.7143
15.2500
0.0000
7.98E-07
394.40

Mass Flow
Rate

Molar
Flow Rate

32.6411

16.3205

147.4071

9.2129

179.3759

5.9792

159.0078

3.6138

353.4739

6.0944

1013.8848

14.0817

932.4828

10.8428

185.7398

1.8574

396.9166

6.8434

5971.2138
3066.6213
1879.3603
1171.2736
738.5866
1545.0732

82.9335
35.6584
21.8530
13.6195
8.5882
15.4507

1279.6610
416.6620
789.9341
350.6071
299.3171
116.3349
0.6325
0.7192
206.8498
649.1867
1707.1082
69.9999
1886.2642
185.7398
0.0000
0.0257
0.5918
25732.69

12.7966
4.1666
7.8993
3.5061
2.9932
1.1633
0.0081
0.0078
2.9550
7.7284
20.3227
0.7143
19.2476
1.8574
0.0000
0.0003
0.0162
338.32

Material Balance Around Reactor

R-102
Stream 10

Stream 9

25732.08 kg / hr
338.32 kmole/hr

Stream 9
Molecular
Mass

Mass
Fraction

Mole
Fraction

H2

2.00

0.0013

0.0482

C1

16.00

0.0057

0.0272

C2

30.00

0.0070

0.0177

C3

44.00

0.0062

0.0107

n C4

58.00

0.0137

0.0180

nC5

72.00

0.0394

0.0416

nC6

86.00

0.0362

0.0320

n C7

100.00

0.0072

0.0055

i-C4

58.00

0.0154

0.0202

iC5

72.00

0.2321

0.2451

Components

2 MP
3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
2,2,3 TMB
H2O
C2Cl4
HCL
Total

86.00
86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
100.00
18.00
94.00
36.50

0.1192
0.0730
0.0455
0.0287
0.0600
0.0497
0.0162
0.0307
0.0136
0.0116
0.0045
0.0000
0.0000
0.0080
0.0252
0.0663
0.0027
0.0733
0.0072
0.0000
1.00E-06
2.30E-05
1.00

0.1054
0.0646
0.0403
0.0254
0.0457
0.0378
0.0123
0.0233
0.0104
0.0088
0.0034

Molecular
Mass

Mass
Fraction

Mole
Fraction

H2

2.00

0.0013

0.0479

C1

16.00

0.0057

0.0272

C2

30.00

0.0069

0.0176

C3

44.00

0.0060

0.0104

n C4

58.00

0.0041

0.0054

nC5

72.00

0.0079

0.0083

nC6

86.00

0.0029

0.0026

n C7

100.00

0.0004

0.0003

i-C4

58.00

0.0251

0.0330

iC5
2 MP

72.00
86.00

0.2637
0.1293

0.2787
0.1144

0.0000
0.0000
0.0087
0.0228
0.0601
0.0021
0.0569
0.0055
0.0000
0.0000
0.0000
1.0000

Stream 10

Components

3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
2,2,3 TMB
H2O
C2Cl4
HCL
Total

86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
100.00
18.00
94.00
36.50

0.0781
0.0600
0.0323
0.0605
0.0510
0.0173
0.0325
0.0142
0.0124
0.0049
0.0000
0.0000
0.0080
0.0252
0.0663
0.0027
0.0733
0.0077
0.0000

1.00E-06
2.30E-05
1.00

0.0691
0.0531
0.0286
0.0460
0.0388
0.0132
0.0247
0.0108
0.0094
0.0037
0.0000
0.0000
0.0087
0.0229
0.0601
0.0021
0.0569
0.0059
0.0000
0.0000
0.0000
1.0000

Hydrogen to Hydrocarbon Ratio at the outlet of R-102 Should be 0.05

H2 : HC Ratio

0.05

ctor
25732.08
338.14

kg / hr
kmole/hr

Mass Flow
Rate

Molar
Flow Rate

32.6411

16.3205

147.4071

9.2129

179.3759

5.9792

159.0078

3.6138

353.4739

6.0944

1013.8848

14.0817

932.4828

10.8428

185.7398

1.8574

396.9166

6.8434

5971.2138

82.9335

3066.6213
1879.3603
1171.2736
738.5866
1545.0732
1279.6610
416.6620
789.9341
350.6071
299.3171
116.3349
0.6325
0.7192
206.8498
649.1867
1707.1082
69.9999
1886.2642
185.7398
0.0000
2.57E-02
5.92E-01
25732.69

35.6584
21.8530
13.6195
8.5882
15.4507
12.7966
4.1666
7.8993
3.5061
2.9932
1.1633
0.0081
0.0078
2.9550
7.7284
20.3227
0.7143
19.2476
1.8574
0.0000
2.74E-04
1.62E-02
338.32

Mass Flow
Rate

Molar
Flow Rate

32.3827

16.1914

147.1509

9.1969

178.3647

5.9455

155.3259

3.5301

106.5960

1.8379

202.8658

2.8176

74.6026

0.8675

9.2875

0.0929

647.1486

11.1577

6784.4979
3327.8947

94.2291
38.6965

2010.0155
1544.3494
831.8794
1556.3009
1313.1645
446.4043
836.4138
365.4858
317.9081
125.6286
0.0019
0.0026
206.8608
649.2215
1707.1996
70.0037
1886.3652
198.7522
0.0000
0.0257
0.5918
25732.69
Should be 0.05

23.3723
17.9576
9.6730
15.5630
13.1316
4.4640
8.3641
3.6549
3.1791
1.2563
0.0000
0.0000
2.9552
7.7288
20.3238
0.7143
19.2486
1.9875
0.0000
0.0003
0.0162
338.14

321.9459

Material Balance Around Stabilizer

T-101
Stream 13

Stream 11
25732.08
338.14

kg / hr
kmole/hr

Stream 14

Stream 11
Mass
Fraction
0.0013

Mole
Fraction

H2

Molecular
Mass
2.00

0.0479

Mass Flow
Rate
32.3835

C1

16.00

0.0057

0.0272

147.1544

C2

30.00

0.0069

0.0176

178.3689

C3

44.00

0.0060

0.0104

155.3296

n C4

58.00

0.0041

0.0054

106.5985

nC5

72.00

0.0079

0.0083

202.8706

nC6

86.00

0.0029

0.0026

74.6044

n C7

100.00

0.0004

0.0003

9.2877

i-C4

58.00

0.0251

0.0330

647.1641

iC5
2 MP
3 MP

72.00
86.00
86.00

0.2637
0.1293
0.0781

0.2787
0.1144
0.0691

6784.6607
3327.9746
2010.0637

Components

2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
2,2,3 TMB
H2O
C2Cl4
HCL
Total

86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
100.00
18.00
94.00
36.50

0.0600
0.0323
0.0605
0.0510
0.0173
0.0325
0.0142
0.0124
0.0049
0.0000
0.0000
0.0080
0.0252
0.0663
0.0027
0.0733
0.0077
0.0000
1.000E-06
2.300E-05
1.00

0.0531
0.0286
0.0460
0.0388
0.0132
0.0247
0.0108
0.0094
0.0037
0.0000
0.0000
0.0087
0.0229
0.0601
0.0021
0.0569
0.0059
0.0000
8.096E-07
4.795E-05
1.0000

1544.3865
831.8994
1556.3382
1313.1960
446.4150
836.4339
365.4946
317.9158
125.6316
0.0019
0.0026
206.8658
649.2371
1707.2405
70.0053
1886.4105
198.7570
0.0000
2.573E-02
5.919E-01
25733.31

Stream 13
Mass
Fraction
0.0245

Mole
Fraction

H2

Molecular
Mass
2.00

0.3332

Mass Flow
Rate
32.6412

C1

16.00

0.1105

0.1881

147.4076

C2

30.00

0.1344

0.1221

179.3766

C3

44.00

0.1191

0.0738

159.0084

n C4

58.00

0.0779

0.0366

103.9217

i-C4

58.00

0.4828

0.2268

644.3509

iC5
C2Cl4
HCL

72.00
94.00
36.50

0.0508
1.000E-06
2.300E-05
1.00

0.0192
8.970E-07
5.313E-05
1.00

67.8235
2.440E-02
5.611E-01
1335.12

Components

Total

Stream 14

Mass
Fraction
0.0001

Mole
Fraction

n C4

Molecular
Mass
58.00

0.0001

Mass Flow
Rate
2.1210

nC5

72.00

0.0083

0.0097

202.7881

nC6

86.00

0.0031

0.0030

74.6027

n C7

100.00

0.0004

0.0003

9.2875

72.00
86.00
86.00
86.00
86.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
78.00
92.00
70.00
84.00
84.00
98.00
98.00
100.00
18.00

0.2752
0.1364
0.0824
0.0633
0.0341
0.0638
0.0538
0.0183
0.0343
0.0150
0.0130
0.0051
0.0000
0.0000
0.0085
0.0266
0.0700
0.0029
0.0773
0.0081
0.000E+00
1.00

0.3223
0.1337
0.0808
0.0621
0.0334
0.0538
0.0454
0.0154
0.0289
0.0126
0.0110
0.0043

6714.8678
3327.8996
2010.0184
1544.3517
831.8807
1556.3032
1313.1664
446.4049
836.4150
365.4864
317.9086
125.6288
0.0019
0.0026
206.8611
649.2224
1707.2021
70.0038
1886.3680
198.7525
0.0000
24397.55

Components

iC5
2 MP
3 MP
2,2 DMB
2,3DMB
2 MH
3 MH
2,2 DMP
2,3 DMP
2,4 DMP
3,3 DMP
3 EP
C6H6
C7H8
CP
MCP
CH
ECP
MCH
2,2,3 TMB
H2O
Total

0.0000
0.0000
0.0102
0.0267
0.0702
0.0025
0.0665
0.0069
0.0000
1.00

izer

1334.53
48.75

kg / hr
kmole/hr

24397.55
289.39

kg / hr
kmole/hr

Molar Flow
Rate
16.1917
9.1971
5.9456
3.5302
1.8379
2.8176
0.8675
0.0929
11.1580
94.2314
38.6974
23.3728

17.9580
9.6732
15.5634
13.1320
4.4641
8.3643
3.6549
3.1792
1.2563
0.0000
0.0000
2.9552
7.7290
20.3243
0.7143
19.2491
1.9876
0.0000
2.738E-04
1.622E-02
338.15

Molar Flow
Rate
16.3206
9.2130
5.9792
3.6138
1.7918
11.1095
0.9420
2.595E-04
1.537E-02
48.99

Molar Flow
Rate
0.0366
2.8165
0.8675
0.0929
93.2621
38.6965
23.3723
17.9576
9.6730
15.5630
13.1317
4.4640
8.3642
3.6549
3.1791
1.2563
0.0000
0.0000
2.9552
7.7288
20.3238
0.7143
19.2487
1.9875
0.0000
289.35

Material Balance Around Scrubber

T-102

Stream 16

0.59
0.02

Stream 13

kg / hr
kmole/hr

1334.53
48.75

kg / hr
kmole/hr

Stream 13

Molecular
Mass

Mass
Fraction

Mole
Fraction

Mass Flow
Rate

H2

2.00

0.0245

0.3332

32.6412

C1

16.00

0.1105

0.1881

147.4076

C2

30.00

0.1344

0.1221

179.3766

C3

44.00

0.1191

0.0738

159.0084

n C4

58.00

0.0779

0.0366

103.9217

i-C4

58.00

0.4828

0.2268

644.3509

iC5

72.00

0.0508

0.0192

67.8235

Components

C2Cl4
HCL

94.00
36.50

1.000E-06
2.300E-05
1.00

8.970E-07
5.313E-05
1.00

2.440E-02
5.611E-01
1335.12

Mass
Fraction
0.0245

Mole
Fraction

H2

Molecular
Mass
2.00

0.3332

Mass Flow
Rate
32.6412

C1

16.00

0.1105

0.1881

147.4076

C2

30.00

0.1344

0.1221

179.3766

C3

44.00

0.1191

0.0738

159.0084

n C4

58.00

0.0779

0.0366

103.9217

i-C4

58.00

0.4828

0.2268

644.3509

iC5
C2Cl4
HCL
NaCl

72.00
94.00
36.50
40.00

0.0508
0.0000
0.0000
2.400E-05
1.00

0.0192
0.0000
0.0000
5.403E-05
1.00

67.8235
0.0000
0.0000
5.855E-01
1335.12

Total

Stream 15

Components

Total

bber

Stream 15

Molar Flow
Rate
16.3206
9.2130
5.9792
3.6138
1.7918
11.1095
0.9420

1334.53 kg / hr
48.75 kmole/hr

2.595E-04
1.537E-02
48.99

Molar Flow
Rate
16.3206
9.2130
5.9792
3.6138
1.7918
11.1095
0.9420
0.0000
0.0000
1.563E-02
48.99