DISTILLATION

Tiwala lang
RELATIVE VOLATILITY
*Use geometric mean of volatilies in case is not given.

SI!"LE #AT$% DISTILLATION
&RAYLEI'%(S E)UATION*
+ is t,e amo-nt of fee. an. / is t,e amo-nt of li0-i. still left in t,e resi.-e.
1 an. 2 are in e0-ili3ri-m.
T,e e45ression of 2 can 3e given 32 Henrys Law or t,ro-g, t,e -se of t,e
relative volatility relationship.

SI!"LE #AT$% DISTILLATION
&RAYLEI'%(S E)UATION*
%enr2(s Law &2 6 m4*7
Relative volatilit2 &see 5revio-s sli.e*7
&Integrate na lang sa calc- ,a,a,a,-,-*

!$$A#E8T%IELE !ET%OD
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Rectif2ing section7

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Stri55ing section7

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+ENS9E E)UATION
!inim-m n-m3er of stages is given 32 t,e +ens:e
e0-ation. T,is ta:es 5lace .-ring total re;-4 &no .istillate
wit,.rawal*7

!INI!U! RE+LU1
!inim-m re;-4 res-lts to in<nite stages. It can 3e
.etermine. mat,ematicall2 from t,e en.5oints of t,e
rectif2ing line at minim-m re;-47
T,e over,ea. 5ro.-ct com5osition 5oint is &4D= 2D* an. t,e 5oint of
intersection of t,e fee. line an. e0-ili3ri-m c-rve &4>= 2>*.

"RO#LE! ?
A mi4t-re of com5onents A an. # wit, @.A mole fraction of
A is .istille. in a sim5le 3atc, .istillation col-mn. T,e
e0-ili3ri-m relation is 2 6 B4. T,e fee. is ?CC moles an.
BD.CE .istille.. +in. t,e .istillate com5osition.
"RO#LE! B
A mi4t-re of com5onents A an. # wit, @.A mole fraction of
A an. relative volatilit2 of B.@ is .istille. in a sim5le 3atc,
.istillation col-mn. T,e fee. is ?CC moles an. BD.CE
.istille.. +in. t,e .istillate com5osition.
"RO#LE! C
A .istillation col-mn receives a fee. t,at is F@ molE n8
5entane an. A@ molE n8,e4ane. +ee. is sat-rate. wit, a
;ow rate of BG@@ l3molH,r. A .istillate of D@ molE n8
5entane is .esire.. A total con.enser is -se.. Re;-4 is
sat-rate. li0-i.. #ottoms from t,e re3oiler is DI molE n8
,e4ane. Determine t,e minim-m n-m3er of e0-ili3ri-m
tra2s.

"RO#LE! F
A55ro4imate t,e minim-m n-m3er of stages for a 3inar2
s2stem wit, relative volatilit2 of B.CG= fractionall2 to 2iel.
com5ositions of @.DI in t,e .istillate an. @.@FG in t,e
3ottoms.