] [

. 50C

.
:
P.V.C
: .

( )

:

Naaq HOaq C4 H 8O2( ) C2 H 6 O() CH 3CO2( aq) Naaq

:
20C :Na+

3
5,0.10
) ( S .m 2 .mol 1

HO2,0.10 2

CH3CO24,1.10 3

M 88 ( g.mol 1 ) :

0,90 ( g.ml ) :3
1
) V0 200 (mL C 0 1,00 .10 mol .L .
1

) t 0(min ) V1 1,0(mL .
S .
. 20C
-1 n 0 . V 0

-2 n1 V1
-3 .
-4 V1 V 0 V . S
1-4 0 t = 0 f . C 0
2-4 t = 0 .
2-4 t t
x
) t 0 (CH 3CO2 HO
V
-5 S
) - x f (t
1-5
t = 12 min t = 4 min

2-5 . t1 / 2
3-5 t1 / 2
-6
40C . t '1 / 2
. t '1 / 2 t1 / 2