T

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22

P/kPa
x1
y1
x2
68.728
0
0
1
72.278
0.0287
0.0647
0.9713
75.279
0.057
0.1295
0.943
77.524
0.0858
0.1848
0.9142
78.951
0.1046
0.219
0.8954
82.528
0.2694
0.8548
0.1452
86.762
0.3633
0.7827
0.2173
90.088
0.4184
0.7213
0.2787
93.206
0.4779
0.6421
0.3579
95.017
0.5135
0.595
0.405
96.365
0.5512
0.552
0.448
97.646
0.5844
0.4948
0.5052
98.462
0.5174
0.4568
0.5432
99.811
0.6772
0.3668
0.6332
99.95
0.6926
0.3395
0.6605
100.278
0.7124
0.3055
0.6945
100.467
0.7383
0.2673
0.7327
100.99
0.7729
0.2248
0.7752
101.059
0.7876
0.2078
0.7922
99.877
0.8959
0.092
0.908
99.779
0.9336
0.056
0.944
96.885
1
0
1

A12
A21
y2
1
0.9353
0.8705
0.8152
0.781
0.7306
0.6367
0.5816
0.5221
0.4865
0.4488
0.4156
0.4826
0.3228
0.3074
0.2876
0.2617
0.2271
0.2124
0.1041
0.0664
0

0.65048
55
0.62665
328.15
1
2
1.91647
1
1.84484 1.00055
1.77896 1.00218
1.7164 1.00495
1.67787 1.00735
1.60038 1.01417
1.48016 1.03185
1.39308 1.05269
1.29843 1.08784
1.25039 1.11342
1.2113 1.14003
1.16574 1.18052
1.13921 1.21086
1.08704 1.29468
1.07395 1.32372
1.05931 1.36244
1.04496 1.40953
1.03149
1.4667
1.02681 1.49106
1.00515 1.68247
1.0019 1.75209
1 1.87133

A
B
C
P1 sat
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238

acetone methanol
14.3916
16.5938
2795.82
3644.3
-43.15
-33.39
P2 sat
Pcalculation
68.7297 68.72974957
68.7297 71.96611227
68.7297 74.85861027
68.7297 77.52872781
68.7297 79.13639661
68.7297 82.28127521
68.7297 86.92609207
68.7297 90.11140288
68.7297 93.40072848
68.7297 94.99873462
68.7297
96.2592089
68.7297
97.6742065
68.7297 98.46225017
68.7297 99.87381623
68.7297
100.176728
68.7297 100.4700895
68.7297 100.6838918
68.7297 100.7678835
68.7297 100.7528893
68.7297 99.78971087
68.7297 99.12951073
68.7297 97.68082377

delta P
y1 calc
deltay*100
3.061E-06 0.70362 70.3616
0.09727396 0.70805
0.17672753 0.70936
120
2.2352E-05 0.70789
0.0343719 0.70555
110
0.06087312 0.69715
0.02692621
0.6726
100
0.00054769 0.64381
0.03791918 0.59828
0.00033362 0.56754
90
0.01119176 0.53745
0.00079561 0.49473
80
6.2583E-08
0.4648
0.00394588 0.38925
0.05140561 0.36505
70
0.03689839 0.33405
0.04704204 0.29804
60
0.04933575
0.2564
0
0.09370376 0.23925
0.00761939 0.11359
0.42183631 0.07083
0.63333548
0
1.79210867

0.2

0.4

0.6

0.8

x1 exp vs P exp
y1 exp vs P exp
Series3
Series4

0.8

1.2

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22

P/kPa
x1
y1
x2
68.728
0
0
1
72.278
0.0287
0.0647
0.9713
75.279
0.057
0.1295
0.943
77.524
0.0858
0.1848
0.9142
78.951
0.1046
0.219
0.8954
82.528
0.2694
0.8548
0.1452
86.762
0.3633
0.7827
0.2173
90.088
0.4184
0.7213
0.2787
93.206
0.4779
0.6421
0.3579
95.017
0.5135
0.595
0.405
96.365
0.5512
0.552
0.448
97.646
0.5844
0.4948
0.5052
98.462
0.5174
0.4568
0.5432
99.811
0.6772
0.3668
0.6332
99.95
0.6926
0.3395
0.6605
100.278
0.7124
0.3055
0.6945
100.467
0.7383
0.2673
0.7327
100.99
0.7729
0.2248
0.7752
101.059
0.7876
0.2078
0.7922
99.877
0.8959
0.092
0.908
99.779
0.9336
0.056
0.944
96.885
1
0
1

A12
A21
y2
1
0.9353
0.8705
0.8152
0.781
0.7306
0.6367
0.5816
0.5221
0.4865
0.4488
0.4156
0.4826
0.3228
0.3074
0.2876
0.2617
0.2271
0.2124
0.1041
0.0664
0

0.65048
55
0.62665
328.15
1
2
1.91647
1
1.84475 1.00056
1.77881 1.00219
1.71621 1.00495
1.67765 1.00736
1.60014 1.01418
1.47993 1.03186
1.39287 1.05269
1.29827 1.08783
1.25026
1.1134
1.21121 1.13999
1.16568 1.18045
1.13916 1.21076
1.08703 1.29452
1.07395 1.32354
1.05932 1.36225
1.04497 1.40932
1.0315 1.46647
1.02682 1.49083
1.00516 1.68228
1.0019 1.75195
1 1.87133

A
B
C
P1 sat
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238

acetone methanol
14.3916
16.5938
2795.82
3644.3
-43.15
-33.39
P2 sat
Pcalculation
68.7297 68.72974957
68.7297 71.96591388
68.7297 74.85792946
68.7297 77.52739041
68.7297 79.13458675
68.7297 82.27843094
68.7297 86.92167734
68.7297 90.10610927
68.7297 93.39494062
68.7297 94.99293254
68.7297 96.25352887
68.7297 97.66883285
68.7297 98.45714509
68.7297 99.86949195
68.7297 100.1726764
68.7297 100.4664025
68.7297 100.6806508
68.7297 100.7651876
68.7297 100.7504257
68.7297 99.78892625
68.7297 99.12917025
68.7297 97.68082377

delta P
y1 calc
deltay*100
3.061E-06 0.70362 70.3616
0.09739774 0.70805
0.1773004 0.70935
120
1.1495E-05 0.70788
0.0337041 0.70553
110
0.06228472 0.69712
0.02549685 0.67255
100
0.00032795 0.64375
0.03569856 0.59822
0.00057924 0.56748
90
0.01242581 0.53739
0.00052134 0.49468
80
2.357E-05 0.46475
0.00342131 0.38921
0.0495848 0.36501
70
0.03549552 0.33402
0.04564667 0.29801
60
0.05054061 0.25638
0
0.09521811 0.23922
0.00775699 0.11358
0.42227871 0.07083
0.63333548
0
1.78905302

0.2

0.4

0.6

0.8

x1 exp vs P exp
y1 exp vs P exp
Series3
Series4

0.8

1.2

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22

P/kPa
x1
y1
x2
68.728
0
0
1
72.278
0.0287
0.0647
0.9713
75.279
0.057
0.1295
0.943
77.524
0.0858
0.1848
0.9142
78.951
0.1046
0.219
0.8954
82.528
0.2694
0.8548
0.1452
86.762
0.3633
0.7827
0.2173
90.088
0.4184
0.7213
0.2787
93.206
0.4779
0.6421
0.3579
95.017
0.5135
0.595
0.405
96.365
0.5512
0.552
0.448
97.646
0.5844
0.4948
0.5052
98.462
0.5174
0.4568
0.5432
99.811
0.6772
0.3668
0.6332
99.95
0.6926
0.3395
0.6605
100.278
0.7124
0.3055
0.6945
100.467
0.7383
0.2673
0.7327
100.99
0.7729
0.2248
0.7752
101.059
0.7876
0.2078
0.7922
99.877
0.8959
0.092
0.908
99.779
0.9336
0.056
0.944
96.885
1
0
1

A12
A21
y2
1
0.9353
0.8705
0.8152
0.781
0.7306
0.6367
0.5816
0.5221
0.4865
0.4488
0.4156
0.4826
0.3228
0.3074
0.2876
0.2617
0.2271
0.2124
0.1041
0.0664
0

1.08165
55
0.68367
328.15
1
2
1.26851
1
1.25478 1.01825
1.24155
1.0364
1.22841 1.05504
1.22001 1.06729
1.20234 1.09393
1.17257 1.14181
1.14886 1.18296
1.12053 1.23623
1.10492 1.26782
1.09148 1.29647
1.07486 1.33412
1.06462 1.35871
1.04302 1.41506
1.03724 1.43147
1.03056 1.45136
1.02376 1.47287
1.01711 1.49562
1.01473 1.50433
1.00305 1.55656
1.00115 1.56983
1 1.58713

A
B
C
P1 sat
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238
97.6808238

acetone methanol
14.3916
16.5938
2795.82
3644.3
-43.15
-33.39
P2 sat
Pcalculation
68.7297 68.72974957
68.7297 71.49293648
68.7297 74.08428143
68.7297 76.58648809
68.7297 78.14694776
68.7297 81.32195955
68.7297 86.31225882
68.7297 89.92100732
68.7297 93.73010133
68.7297 95.55762687
68.7297 96.95089001
68.7297 98.41246729
68.7297 99.14670681
68.7297 100.1863122
68.7297
100.322371
68.7297 100.3863122
68.7297 100.3298426
68.7297 100.1256126
68.7297 100.0072717
68.7297 98.80678458
68.7297 98.35877525
68.7297 97.68082377
OF

delta P
y1 calc
deltay*100
3.061E-06 0.70362 70.3616
0.61632473
0.7032
1.42735246 0.70143
120
0.87892857 0.69825
0.6465 0.69542
110
1.45453357 0.68733
0.20226713 0.66632
100
0.02788655 0.64186
0.2746822 0.60165
0.29227741 0.57326
90
0.34326711 0.54453
0.58747211 0.50229
80
0.46882342 0.47181
0.14085924 0.39245
0.13866016 0.36654
70
0.01173153
0.3332
0.01881215 0.29442
60
0.74716553 0.24983
0
1.10613249 0.23162
1.14536105 0.10353
2.01703834 0.06294
0.63333548
0
13.1794143

0.2

0.4

0.6

0.8

x1 exp vs P exp
y1 exp vs P exp
Series3
Series4

0.8

1.2