Scribd Logo
Importer

Bienvenue sur Scribd !

  • Kramers - Kronig Trasnform

    Transféré par

    komposto
    34 vues5 pages
    The document discusses the Kramers-Kronig (K-K) transform and its use in validating electrochemical impedance spectroscopy (EIS) data. The K-K transform relates the phase and magnitude of a system's response based on the criteria that the system is linear, stable, and causal. Applying the K-K transform to EIS data involves calculating the magnitude from the experimental phase or vice versa. If the calculated and experimental values match, the data is valid. A mismatch suggests the system is not linear, stable, or causal, and features that fail to transform should be considered artifacts. The document provides examples of the K-K transform applied to valid and invalid EIS data sets.

    Description originale:

    K-K transforms

    Titre original

    kramers - kronig trasnform

    Copyright

    © © All Rights Reserved

    Formats disponibles

    PDF, TXT ou lisez en ligne sur Scribd

    Avez-vous trouvé ce document utile ?

    Ce contenu est-il inapproprié ?

    Signaler ce document
    The document discusses the Kramers-Kronig (K-K) transform and its use in validating electrochemical impedance spectroscopy (EIS) data. The K-K transform relates the phase and magnitude of a system's response based on the criteria that the system is linear, stable, and causal. Applying the K-K transform to EIS data involves calculating the magnitude from the experimental phase or vice versa. If the calculated and experimental values match, the data is valid. A mismatch suggests the system is not linear, stable, or causal, and features that fail to transform should be considered artifacts. The document provides examples of the K-K transform applied to valid and invalid EIS data sets.

    Droits d'auteur :

    © All Rights Reserved
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    34 vues5 pages

    Kramers - Kronig Trasnform

    Transféré par

    komposto
    The document discusses the Kramers-Kronig (K-K) transform and its use in validating electrochemical impedance spectroscopy (EIS) data. The K-K transform relates the phase and magnitude of a system's response based on the criteria that the system is linear, stable, and causal. Applying the K-K transform to EIS data involves calculating the magnitude from the experimental phase or vice versa. If the calculated and experimental values match, the data is valid. A mismatch suggests the system is not linear, stable, or causal, and features that fail to transform should be considered artifacts. The document provides examples of the K-K transform applied to valid and invalid EIS data sets.

    Droits d'auteur :

    © All Rights Reserved
    Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 5

    27.5.

    2014

    Kramers-Kronig Transform
    Burak lgt, PhD

    Criteria For Valid EIS


    Linear: The system obeys Ohms Law, E = iZ.
    The value of Z is independent of the magnitude
    of the perturbation. If linear, no harmonics are
    generated during the experiment.
    Stable: The system does not change with time
    and returns to its original state after the
    perturbation is removed.
    Causal: The response of the system is due only
    to the applied perturbation.

    27.5.2014

    Kramers-Kronig Transform
    The K-K Transform states that the phase and magnitude in a
    real (linear, stable, and causal) system are related.
    Apply the Transform to the EIS data. Calculate the magnitude
    from the experimental phase. If the calculated magnitudes
    match the experimental magnitudes, then you can have some
    confidence in the data. The converse is also true.
    If the values do not match, then the probability is high that your
    system is not linear, not stable, or not causal.
    The K-K Transform as a validator of the data is not accepted by
    all of the electrochemical community.

    Mathematically
    Theoretically, it is possible to calculate the
    imaginary part from the real part (or vice
    versa)
    However, one would need the entire set of
    data from f=- to f=

    27.5.2014

    What can we do?


    We can take the most generic component
    that is K-K transformable and use that to fit
    the data piecewise.
    Voight element
    R/CPE in parallel with the CPE exponent
    varying from -1 to 1.

    Standard Randles Data

    27.5.2014

    K-K Transform

    Another Data Set

    27.5.2014

    Bad K-K

    K-K shows that the data below 1Hz is


    unusable.
    This is a coating that developed a bad
    defect during the experiment

    To sum up
    Do a K-K transform every time you have a
    new data set you are working on.
    Any feature in the data that is not
    transformable is either an instrumental or
    an experimental artifact and does not
    contain actual usable information.

    Vous aimerez peut-être aussi