Cch xc nh ch s Axit v ch s Hydroxyl

I-

Xc nh ch s Axit:
-

Cn khong 2-10 g mu, ly chnh xc ti 0.1 g vo bnh

tht c.

Cht ch th Phenolphthalein: 1g phenolphthalein + 100 ml

etanol 96%, 2-3 git

Cht chun KOH 0,1N.

Dung mi :

Etanol

Etanol 96% + DE ( diethyl ether) , V =1/1. (

Nu mu khng ha tan ht trong dung mi Etanol).
Cch tin hnh:

II-

Cn 2-10 g mu (chnh xc ti 0,1 g) vo bnh nn.

Thm vo bnh nn 50 ml dung mi chun , v 2-3 git

phenolphthalein trn.

M nt puret dung dch chun KOH 0,1N chy xung

bnh nn, sau lc u. (Cn xem xt mu chun
oligoeste c ng c nhit thng ko , nu c cn
s dng nhit ).

Lc u bnh nn, cho ti khi dung dch chuyn sang mu

hng th dng li.

Ta ghi c th tch KOH 0,1N dng.

p dng cng thc :

Xc nh ch s Hydroxyl.
-

Cn khong 2-10 g cht cn chun , vo bnh nn 250

ml.

Cho tip vo bnh nn dung dch chun ( 200 ml

Toluen, 40 ml pyridin, 60 ml anhydrit axetic, lm m trong
chu nc cho ti khi dung dch ha tan hon ton. Sau
un nng hn hp ln 60 C trong 30 pht.

Thm 25ml nc ct vo bnh nn, y np, lc mnh trong

vi giy( thy phn anhidrit cn d).

Chun dung dch vi KOH 0,1 N, s dng

phenolphthalein ( 1% ethanol) lm cht ch th ( A ml).

Lc mnh bnh nn cho ti khi c mu hng xut hin.

Lp li th nghim trn, nhng KHNG DNG MU. TA

S C B ml ca ch th phenolphthalein.

Gi tr HV c tnh theo cng thc:

Vi N l nng phn mol ca KOH

W khi lng mu.