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Unit 9 Test 0.

0 Stoichiometry II

Name:

____________________
Class:
Benchmark 9.1 - Gas Stoich: Students can use gas laws to solve
stoichiometric problems using molar ratios (BCA tables) at various
conditions.

1. 10.8g of magnesium is reacted with excess phosphoric acid to


produce hydrogen gas and an ionic compound. The pressure at sea
level (in Singapore) is 101.3kPa, the temperature of the reaction is
32OC.
a) Determine the theoretical volume of hydrogen gas
produced.
3 Mg(s) +
2 H3PO4(aq)
Mg3(PO4)2(s) + 3 H2(g)

b) Calculate the percent yield if 2.30L are actually collected.

2. 14.8g of ethane gas(C2H6) is burned with 33.22L of oxygen. The


reaction occurs at 2.31atm and 45.7OC.
a) Find the volume of carbon dioxide produced.

b) Find the moles of excess reactant leftover.

Benchmark 9.2 - Solution Stoich: Students can use


solution calculations to solve stoichiometric problems
using molar ratios (BCA tables) at various conditions.

1. 40.0mL of 2.00M hydrochloric acid is reacted with 3.00M barium


hydroxide. Determine the volume of barium hydroxide solution
required for the complete reaction.
2 HCl(aq) + Ba(OH)2(aq)
BaCl2(aq)
+ 2 H2O(l)

2. 32.2mL of 2.50M silver fluoride reacts with 15.0mL of 6.0M


aluminum chloride.

a) Find the mass of precipitate formed.

b) Determine the concentration of the leftover solution.

Benchmark 9.3 - Energy Stoich: Students can integrate energy


concepts into quantitative stoichiometric problems using molar ratios
(BCA tables) at various conditions.

1. For the reaction below, write the balanced chemical equation,


including the energy term. Then represent the energy storage and
transfer using the bar graphs.
When you heated sodium hydrogen carbonate, you decomposed
it into sodium carbonate, water vapor, and gaseous carbon
dioxide.

2 Mg(s)

2. Find the energy transferred when 12.15g of magnesium is burned.


+
O2(g)

2 MgO(s)
H=-668.0kJ

3. How many grams of carbon dioxide are produced when the


combustion of methane (H=-891kJ) produces 1200kJ.

Cumulative Section
In the apparatus shown (picture to follow), 0.14g of magnesium
ribbon is reacted with 10.0mL of 6.00M sulfurous acid. The acid
solution is inverted in an additional 200.0mL of water, the
temperature change and gas volume are observed. The waters
temperature was initially at SATP and rose to 38.0OC and the gas
recovered was 155mL.

a) Find the percent yield of gas.

b) Calculate the energy produced by this experiment.

c) Determine the molar enthalpy (H) of this reaction.

d) Find the mass of excess reactant leftover.

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