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AB A1
J AZ
AB A1
Flux, J AZ
if C = P/RT
z 2 z1
RT z 2 z1
Substitute in values:
J AX
82.0572980.2
kgmol/m2s
Equimolar Counterdiffusion
J AZ
II
d
PCO2 =
456 mmHg
PCO2 =
76 mmHg
P = 1.0132x105 Pa
z2 z1 = 0.10 m
R = 8314.3 m3 Pa/kgmol K
PB 2 PB1 1 0 1 0.0231
0.988 atm
PB 2
1 0
ln
ln
P
1 0.0231
B1
D AB P
PA1 PA2
NA
RT z 2 z1 PBM
PBM
NA
0.250 10 1.0
4
82.0572930.15240.988
We can assume a pseudo-steady state condition because the level drops slowly. Now, both NA
and z are variables.
DAB P
PA1 PA2
NA
RT z2 z1 PBM
Assuming a cross-sectional area of 1 m2, the level drops dt in dz seconds, and the leftover kgmol
of A is PAdz/MA:
dz 1
N A 1 A
M A dt
Rearranging and integrating:
tF
A zF
D P
zdz AB PA1 PA2 dt
0
M A z0
RTPBM
tF
A z F2 z 02 RTPBM
2M A D AB PPA1 PA2
4 r1 r2
RT
P p A, 2
where
N A is the molar rate of material A leaving
R is the ideal gas constant
the drop
T is the system temperature
r1 and r2 are two radial points away from
pA,1 is the partial pressure of A at point 1
the sphere center
pA,2 is the partial pressure of A at point 2
DAB is the diffusion coefficient P is the total
system pressure
Starting with this equation, derive the following approximate equation for the molar flux at the particle
surface, NA,1
2 DAB
cA,1 cA,2
N A,1
D1
where
D1 is the diameter of the spherical drop
cA,1 is the molar concentration of material A at the surface of the drop
cA,2 is the molar concentration of material A far from the drop
Assume point 1 is at the drops surface
Assume point 2 is very far away from the drop, so r2 >> r1
N A 1 1 D AB P P PA2
N
D P P PA2
A AB ln
ln
4 r1 r2
RT
4r1
RT
P PA1
P PA1
Now multiply the equation by 1/r1, rewrite the radius as 2/D on the right
side, substitute for surface flux, NAs, and PBM:
Stagnant B
r2
r1
Diffusing
A
PB 2 PB1
PA1 PA2
N
and N AS A 2
P
ln P PA2
4r1
ln B 2
P
P
P
B1
A1
2 D AB PA1 PA2
So we rewrite the equation as: N AS
DRT
PBM
PBM
Assume low vapor pressure, so PA1, PA2 << P and use a Taylor Series approximation ln(x) = x-1:
P PA2 P PA2
P PA2
1
is approaching 1, so ln
P PA1 P PA1
P PA1
P PA2 P PA1 PA1 PA2 PA1 PA2
P PA1
P PA1
P
Lastly, PA1 = CA1RT and PA2 = CA2RT:
Now,
so PBM P.
2 D AB P
2 D AB
2 D AB
PA1 PA2
C A1 RT C A2 RT
C A1 C A2
RTD PBM
RTD
D
where CA1 = concentration at surface of the drop and CA2 = concentration far from the drop 0
N AS
PBM
1.0129 10 5 Pa
5
P
1.01325 10 0
ln
ln B 2
5
1.01325 10 74
PB1
NA
D AB P
6.92 10 6 1.01325 10 5
PA1 PA2
9.68 10 8 kgmol A/m2s
RT r1 r0 PBM
8314.33180.002 1.0129 105
T
DAB(52.6C) = DAB(0C) 2
T1
2
m /s
Now solve for N A :
P2
= (5.16 x 10-6 m2/s)(325.75/273.15)1.75 = 7.023 x 10-6
P1
N A 1 1 DAB P P PA2
ln
4 r1 r2
RT
P
P
A1
N A DAB P P PA2
ln
4r1
RT
P
P
A1
NA
7.023 10 6 1.01325 10 5 1.01325 105 133.322
= 4.34736 x 10-11 kgmol/s
ln
5
8314325.75
4 0.1
1.01325 10 0
Now solve for NA = N A /A = (4.34736 x 10-11 kgmol/s)/(4r12) = 3.46 x 10-8 kgmol/m2s
NA
D P P PA2
AB A1
2
RTr
PBM
4r
and
NA
A dV
M A dt
dV
Volume of the sphere, V 4 r 3 so the derivative of volume is:
4r 2
3
dr
Plug this volume derivative into molar flux equation for dV:
A 4r 2 dr
NA
M A dt
A 4r 2 dr
D P P PA2
1
AB A1
2
M A dt
RTr
PBM
4r
Separate variables and integrate both sides:
t
r
A RT PBM
A r 2 RT PBM
dt
rdr
t
PA1 = 3840 Pa
PA2 = 0 Pa
P = 1.01325 x 105 Pa
MA = 92.14 kg/kgmol
Solve for PBM:
PBM
tevap =
PA1 PA2
= 99392.6 Pa
A
2
ln
P PA1
uniformly to 0.0305m at the right end. Calculate the molar flux of ammonia. The diffusivity is DAB = 0.230 x
10-4 m2/s.
.061m
.0305m
1.22m
2
RT dL
A
RT dL
0.000271 L - 0.001321 L 0.001611
NA
DAB
dL
2
RT
0.000271 L - 0.001321 L 0.001611
PA 2
PA1
dPA
R = 8314 m3 Pa/kgmol K
T = 298.15 K
N A 1514.8
N A = 1.24 x 10-10
8314298.15
RT
kgmol/s
Now solve for NA:
1.24 10 10
NA = N A /A =
at any point along the length, L
1 0.025L 0.06102 tan 60
4
1 = 972.8 kg/m3
2 = 988.1 kg/m3
Meth =46.05
Mwater = 18.02
93.2
46.05
18.02
46.05
18.02
X B1 1 X A1 1 0.0732 0.9268
X B 2 1 X A2 1 0.0277 0.9723
Now calculate the molecular weight:
100kg
100kg
M1
20.07 kg/kgmol
M1
18.75 kg/kgmol
16.8
6.8
83.2
93.2
46.05
18.02
46.05
18.02
Now calculate CAvg:
/ M 1 2 / M 2 972.8 / 20.07 988.1 / 18.75
C avg 1
50.6 kgmol/m3
2
2
X X B1 0.9723 0.9268
X BM B 2
0.949
X B2
0.9268
ln
ln
0.9723
X B1
NA
D AB C avg
z 2 z1 x BM
9
x A1 x A2 0.740 10 50.60.0732 0.0277 8.99 10 7 kgmol/m2s
0.0020.949
C avg
1 991.7
1 1
961.7
3
54.435 kgmol/m
2 M 1 M 2 2 17.9806 17.9031
Calculate XBM:
Xw1 = 1-0.02 = 0.98
Xw2 = 1-0.1 = 0.9
X BM
X B 2 X B1
0.9 0.98
0.939432
ln X B 2 X B1 ln 0.9 / 0.98
1/ 2
1/ 2
D AB 1.173 10 16 M B
T
298
1/ 2
1.173 10 16 2.6 18.02
1.277 10 9 m2/s
0.6
0.6
BV A
0.89370.0740
For 50C:
D AB 1.173 10 16 M B
T
323
1/ 2
1.173 10 16 2.6 18.02
2.251 10 9 m2/s
0.6
0.6
BV A
0.54940.0740
D AB
8.928 10 10 T
8.928 10 10 298
1 / 1 /
1 / 73.5 1 / 76.3
(b) To change the temperature, we use a simple correction factor:
T = 18.5C = 291.7K
From Table A.2-4, w = 1.042 cP
T
291.7
D AB 18.5 D AB 25
1.993 10 5
1.671 10 5 cm2/s
334 w
1.042
(c) From Table 6.3-3, + (Ca2+/2) = 59.5 and - (Cl-) = 76.3, n+ = 2 and n- = 1:
59.5
DCa2 2.662 10 7 2.662 10 7
0.792 10 5 cm2/s
n
2
D AB
76.3
2.031 10 5 cm2/s
n
1
n n
2 1
1.335 10 5 cm2/s
5
5
n / D n / D 2 / 0.792 10 1 / 2.031 10
DCl 2.662 10 7
2.662 10 7
7.70 10 11 m2/s
1/ 3
1/ 3
3
M A
0.8937 10 67500
This value is different from the experimental value because the shape of the molecule differs greatly from a
sphere.
NA
D AB C A1 C A2 0.727 10 9 0.2 0
3.63 10 9 kgmol/m2s
z 2 z1
0.04
2.480 10 10 kgmol/m2s
22.414z 2 z1
22.4140.00015
P1 = 2.0 atm
P2 = 0 atm
PN2/Ny = 0.152 x 10-12 m2/s atm
PN2/Poly = 1.52 x 10-12 m2/s atm
Diffusion of gas through a solid:
2.0 atm
NA
DAB C A1 C A2
z2 z1
S PA
where S is the solubility
22.414
PA1 PA2
1
NA
L
L
22.414
1
2
PM 1 PM 2
1
2.0 0
22.414
0.001
0.008
12
1.52 10 12
0.0152 10
1.256 10 12 kmole/m2s
0 atm
NA
7.01 10 9 kgmol/m2s
z 2 z1
4.0
0.002
8.3142761.871.25 0
RT z 2 z1
N A 1.609 106 mol/m2s
1.25m
P2 = 0 Pa
On Figure 5.3-5 Unsteady State Conduction in a Large Flat Plate when X = 0.685, m = 0, n = 0
c
c = 0.0275 kgmol/m3
Y 0.275
0.1
On Figure 5.3-5, when X = 0.658, m = 0, n = 0.00254/0.00508 = 0.5: (n is not 0 now because not at center)
c
c = 0.0172 kgmol/m3
Y 0.172
0.1
(b)
If the thickness is halved, X becomes:
10
D t
X AB 2 4.72 10 36000
2.632
X1
0.002542
Relative position, n = 0, m = 0
c
Y 0.0020
c = 0.0002 kgmol/m3
0.1
7.1-5 Unsteady State Diffusion in a Cylinder of Agar Gel Radially and Axially
A wet cylinder of agar gel at 278K containing a uniform concentration of urea of 0.1 kgmol/m3 has a
diameter of 30.48mm and is 38.1mm long with flat parallel ends. The diffusivity is 4.72 x 10-10 m2/s.
Calculate the concentration at the midpoint of the cylinder after 100h for the following cases if the cylinder
is suddenly immersed in turbulent pure water.
(a) For radial diffusion only
(b) Diffusion occurs radially and axially
Assume surface resistance is negligible; assume k = 1.0 because properties are similar
T = 278 K
C0 = 0.1 kgmol/m3
C1 = 0 for pure water
D = 4.72 x 10-10 m/s
Time, t = 100h = 360000 seconds
c k c
0 1.0 c
c
Y 1
0.731601
0.01524
r12
Relative position at midpoint of the cylinder, n = 0/0.1524 = 0
Relative resistance, m 0 because kc is assumed to be very large
X
t = 3000 seconds
DAB = 4x10-9 m2/s
C0 = 0.01 kgmol.m3
Kk c
D AB
D AB t
2.02 10 7
4 10
4 10 3000 1.095
9
For x = 0.01:
0.01
0.457
2 4 10 -9 3000
From the chart 5.3-3 Unsteady State Heat Conducted in a Semi-Infinite Solid with Surface Convection:
C C0
C 0.01
C = 2.04x10-2 kgmol/m3
1Y
0.26
C1 / K C0 0.1 / 2 0.01
For x = 0
x
0
0
2 D AB t 2 4 10 -9 3000
From the chart 5.3-3 Unsteady State Heat Conducted in a Semi-Infinite Solid with Surface Convection:
C C0
C 0.01
C = 3.48x10-2 kgmol/m3
1Y
0.62
C1 / K C0 0.1 / 2 0.01
This is the same value as Ci. To calculate CLi:
C Li KCi 2.03.48 10 2 6.96 10 2 kgmol/m3
2 D AB t
0.2
c1 k c0 0.5 1.0 0.3
DAB t 3.72 10 6 t
0.005766t
x12
0.254 2
k y y BM k y'
y BM
ky
k y'
y BM
y B 2 y B1
1 0.9
0.95
ln y B 2 y B1 ln 1.0 / 0.9
6.78 10 5
7.138 10 5
3.569 10 5 kgmol/m2 s atm
P
2.0
Now we can calculate the vaporization rate, NA:
N A k y y A1 y A2 7.138 10 5 0.10 0 7.138 10 6 kgmol/m2s
or
5
N A k G PA1 PA2 3.569 10 0.2 0 7.138 10 6 kgmol/m2s
k G y BM P k y y BM
kG
ky
A value of kG was experimentally determined to be 1.08 lbmol/h ft2 atm for A diffusing through stagnant B.
For the same flow and concentrations it is desired to predict kG and the flux of A for equimolar
counterdiffusion. The partial pressures are PA1 = 0.20 atm, PA2 = 0.05 atm, P = 1.0 atm abs total. Use
English and SI Units.
kG' P kG PBM
Solve for PBM:
P PA2
0.2 0.05
PBM A1
0.872853 atm
P PA2
1 0.05
ln
ln 1 0.2
P PA1
Plug into equation:
kG (1.0 atm) = (1.08 lbmol/h ft2 atm)(0.872853 atm)
kG(1.01x105Pa) = (1.08lbmol/hft2atm)(.872853atm)(1hr/3600sec)(1ft2/.0929 m2)(.453kgmol/lbmol)
kG = 0.9427 lbmol/h ft2 atm
kG = 1.262 x 10-8 kgmol/s m2 Pa
Now solve for flux:
PA1 = 0.2 atm = 20265 Pa
PA2 = 0.05 atm = 5066.25 Pa
NA = 0.1414 lbmol/ft2h
NA = 1.92 x 10-4 kgmol/m2s
X B 2 X B1 1 0 1 0.65
0.619
X B2
1 0
ln
ln
1 0.65
X B1
k x'
X A1 X A2 0.20 0.65 0 0.210 lbmol/ft2 hr
X BM
0.619
To find the ratios, set up the following:
k x kc
1
1
'
1.616
'
k x k c X BM 0.619
NA
k x0 k c0 1 X A1 1 0.65
'
0.565
X BM
0.619
k x'
kc
kc' P
kG' P
RT
k G'
9.567 10 4
3.846 10 5 kgmol/m2s atm
3
82.057 10 303.15
PAi = 74.0 Pa
air = 1.932x10-5 Pa s from Appendix A
= 1.114 kg/m3
R = 8314 m3 Pa/kgmol K
1.932 10 5
N Sc
2.506
D AB 1.114 6.92 10 6
Calculate the Reynolds number:
D 0.020.801.114
N Re
922.6
1.932 10 5
Hence, the flow is laminar. We will use Figure 7.3-2 for laminar flow streamlines:
D
0.02
N Re N Sc
922.62.506
33.02
L 4
1.10 4
Using Figure 7.3-2 with rodlike flow:
C A C A0
0.55
C Ai C A0
If CA0 = 0,
C A C A0
CA 0
0.55
7.3-7 Mass Transfer from a Pipe and Log Mean Driving Force
Use the same physical conditions as in problem 7.3-2, but the velocity in the pipe is now 3.05
m/s. Do as follows:
(a) Predict the mass transfer coefficient kc (Is this turbulent flow?).
(b) Calculate the average benzoic acid concentration at the outlet. [ Note: in this case,
Eqs. (7.3-42) and (7.3-43) must be used with the log mean driving force, where A is
the surface area of the pipe.]
(c) Calculate the total kgmol of benzoic acid dissolved per second.
1.829 m
Pure Water
T = 26.1C
v = 3.05m/s
0.00635 m
1.22 m
= 996 kg/m3
= 8.71 x 10-4 Pa s
T = 26.1C
DAB = 1.245x10-9 m2/s
8.71 10 4
N Sc
702.408
D AB 996 1.245 10 9
Calculate the Reynolds number:
D 0.006353.05996
N Re
22147
8.71 10 4
Calculate the Sherwood number:
0.83
0.33
N Sh 0.23N Re N Sc 0.000049487
Now calculate kc:
k ' 1.245 10 9
k' D
0.000049487 c
N Sh c
0.00635
D AB
(b)
CA1 = 0
CAi = 0.02948 (solubility)
CA2 = ?
So now we plug this into the log mean driving force equation:
C A2 C A1
vC A2 C A1 A K C
C C A1
ln Ai
C Ai C A2
CA1 = 0, so it cancels out of the equation:
vC A2 A K C
C A2
C Ai
ln
C Ai C A2
C A2
0.02948
ln
0.02948 C A2
1.11 10 7
2
A
0.003175
Because the solution is dilute, we can use the properties of water for the solution:
= 996 kg/m3
= 8.71 x 10-4 Pa s
Calculate the Schmidt Number:
N Sc
Calculate the Reynolds number:
N Re
Now calculate JD:
D AB
D
8.71 10 4
702
996 1.245 10 9
0.240.061996 17000
8.71 10 4
0.5
J D 0.99 N Re,
L 0.9917000
0.5
0.00758
kc:
JD
k c'
N Sc 2 / 3
In this case, A is diffusing through stagnant B. We use the solubility for CA1 and CA2 = 0. Also, since the
solution is dilute, xBM 1:
k'
5.85 10 6
0.02948 0 1.726 10 7 kgmol/m2s
N A c C A1 C A2
X BM
1.0
N Sc
Calculate the Reynolds number:
N Re
Now find the Sherwood number:
D AB
D
1.93 10 5
2.505
1.113 6.92 10 6
0.02540.3051.113 446
1.93 10 5
N Sh 2 0.552N Re
0.53
D
D AB
k c' N sh
N Sc 1/ 3 21.0
D AB
6.92 10 6
21.0
5.72 10 3 m/s
D
0.0254
k c'
5.72 10 3
k
2.163 10 9 kgmol/s m2 Pa
RT 8314318
Since the gas is dilute, k G kG. Using that we can solve for the flux:
N A k G PA1 PA2 2.163 10 9 73 0 1.599 10 7 kgmol/m2 s
'
G
Mw = 18 kg/kgmol
CA1 = 0.02948 kgmol/m3
= 8.71 x 10-9 Pa s
0.999734
1 X A2
X B2
1.0
ln
ln
ln
0.999468
1
X
X
A1
B1
Calculate Schmidt Number:
N SC
Calculate Reynolds Number:
N Re
D AB
Calculate
Kc:
8.71 10 4
702
996 1.245 10 9
0.1370.152996 23812.5
Calculate JD:
J D 0.99 N Re
0.5
8.71 10 9
0.9923812.5
0.5
2 / 3
K C' J DN SC
0.064160.152702
2 / 3
Calculate Flux:
NA
0.06416
1.2346 10 5 m/s
3.641 10 7 kgmol/m2s
X BM
0.999734
0.152 m
P = 202600 Pa
R = 8314.34 m3 Pa/kgmol K
T = 325.6 K
Mw = 28.8 kg/kgmol
Correct DAB:
T
D AB 325.6 K ,202.6kPa o
T
Calculate and :
1.75
P
o
P
T
325.6
o 0.0171cP
T
273
325.6
273
N Re
0.1521.5242.155 25495.5
1.958 10 5
0.2
JD
'
C
2/3
N SC
3.51182 10 6 m2/s
0.2
J D 0.036 N Re
0.036 25495.5
N SC
M wP
28.8202600 2.155 kg/m3
8314.34325.6
RT
(a)
Calculate NRe:
202.6
101.3
0.768
1.75
D AB
0.004732
1.958 10
2.58722
2.155 3.51182 10 6
'
C
K
2.587222 / 3
KC = 0.003827 m/s
1.524
'
K
0.003827
KG C
1.41366 10 9 kgmol/m2 Pa s
RT 8314.34325.6
0.004732
(b)
Dp = 0.0127 m
Calculate Reynolds and Schmidt Numbers:
D p 0.0127 1.5242.155
N Re
2130.21
1.958 10 5
1.958 10 5
N SC
2.58722
D AB 2.155 3.51182 10 6
N SH
K C' D p
D AB
KG
46.0164
K C' 0.0127
3.51182 10 6
KC = 0.012725 m/s
K C'
0.012735
4.70 10 9 kgmol/m2 Pa s
RT 8314.34325.6
3
298 0.8718 10
Told new
Calculate the area of the column:
A D 2 0.0667 3.494 10 3 m2
4
4
Now use the area and volumetric flow to find the velocity:
v V / A 5.514 10 7 / 3.494 10 3 1.578 10 4 m/s
Calculate the Schmidt Number:
8.71 10 4
N Sc
702.6
D AB 996.7 1.245 10 9
Calculate Reynolds number:
D p 0.006375 1.578 10 4 996.7
N Re
1.150
8.71 10 4
Calculate JD:
1.09
N Re 2 / 3 1.09 1.1502 / 3 2.277
JD
.436
4
v
1.578 10
Now set the log mean driving force equation can be set equal to the material balance equation on
the bulk stream:
C C A1 C Ai C A2
Ak c Ai
V C A2 C A1
C Ai C A1
ln
C Ai C A2
where CAi = 0.02948 (the solubility)
CA1 = 0
A = 0.01198 m2 (the surface area of the bed)
V = 5.514x10-7 m3/s
CA2 = 2.842 x 10-3 kgmol/m3
Pure water at 26.1C is flowing at a rate of 0.0701ft3/h through a packed bed of 0.251-in.
benzoic acid spheres having a total surface area of 0.129 ft2. The solubility of benzoic acid in
water is 0.00184 lbmol benzoic acid/ft3 solution. The outlet concentration is cA2 is 1.80 x 10-4
lbmol/ft3. Calculate the mass transfer coefficient kc. Assume dilute solution.
= 0.8718 x 10-3 Pa s
= 996.7 kg/m3
= 0.0701 ft3/hr
A = 0.129
C A2 C A1
C C A1
ln Ai
C Ai C A2
where CA1 is the inlet bulk flow concentration, CA2 is the outlet bulk flow concentration, and CAi is the
concentration at the surface of the solid (which in this case equals the solubility)
C Ai C A2
CA1 = 0, so it cancels out of the equation:
C A2
vC A2 A K C
C Ai
ln
C Ai C A2
We can now plug in given numbers:
1.80 10 4
0.0701 1.80 10 4 0.129K C
0.00184
ln
4
0.00184 1.80 10
KC = 0.0559 ft/hr
N Sc
c
c D AB
6.947 10 4
215
994 3.25 10 9
Now calculate k L:
2 D AB
2 / 3 c g
k
0.31N Sc
2
Dp
c
1/ 3
'
L
4
9.806 2.29 10 4 m/s
2 3.25 10 9
2 / 3 994 1.13 6.947 10
0
.
31
215
4
2
1 10
994
1/ 3
A A A B B B 0
A A B B A B 0
A B B and A B
A A B B A A B B 0
A A B B A A B B 0
NA
CD AB
1 X A1
4.062 10 2 0.15 10 4 1 1.0
ln
ln
2.112 10 4 kgmol A/m2s
1 X A2
0.002
1 0
(b)
Substitute X A2
NA
in for XA2:
k1' C
NA
NA
0.002
4.062 10 0.15 10 ln
CD AB
ln
1 X A1
N
1 A '
k1C
1 1.0
N
1 A
5.63 10 3 4.062 10 2
2
4
1.004 10 kgmol A/m s
CA 1
k1'
k1'
2 exp z
k i t 1 2 exp z
ki t
erf
erf
C
D AB
D AB
2 tD AB
2 tD AB
For z1=0m:
CA 1
2 exp 0 erf 1 10 4 1 10 5 1 2 exp 0 erf 1 10 4 1 10 5
1.0
C A 1 2 exp 0 2 1 2 exp 0 0 1.0 kgmol/m3
For z2=0.004m
CA
1.0
1 10
1 10
erf
0.004
1 10 1 10
2 1 10 1 10
erf
0.004
1 10 1 10
2 1 10 1 10
1 10 4
exp
0
.
004
2
1 10 9
4
5
exp
0
.
004
2
9
5
9
1104
1
1
C A 1 2 exp 0.004
2
2
9
9
1
10
For z2=0.01m
CA 1
1 10 4
0.01
2 exp 0.01
erf
1 10 4 1 10 5
9
1.0
1 10
2 1 10 5 1 10 9
1 10 4
0.01
4
5
1 exp 0.01
erf
10
1
10
2
1 10 9
2 1 10 5 1 10 9
1 10 4
1 10 4
1
1
C A 2 exp 0.01
1.9998 2 exp 0.01
0 1 2 0.0423291.9998
9
9
1
10
1
10
3
C A 0.0.0423 kgmol/m
1
(b)
The total amount, Q, of A absorbed up to time t is represented by:
D AB ' 1
k ' t k 't
'
Q c A0
e
k t 2 erf k t
k '
Q 1
110
9
4 '
Q 0.0332 kgmol/m
1
2
110 4 1105
Gas A diffuses from point 1 to a catalyst surface at point 2, where it reacts as follows: 2A B. Gas B
diffuses back a distance to point 1.
(c) Derive an equation for NA for a slow first-order reaction where k1 is the reaction velocity constant.
(d) Calculate NA and xA2 for part (c) where k1 0.53 x 10-2 m/s.
(c)
Begin with the convective diffusion equation:
dC A C A
N A N B where: x A C A ,
N A D AB
dz
C
C
Plugging in:
N B 12 N A
A2
dx A
dx
x A 12 N A
N A dz CD AB
dz
1 xA 2
0
x A1
x
N A CD AB
1 x A2 2
ln
1 x A1 2
N
For a slow reaction, x A2 ' A . Plugging into the flux equation and replacing C with P/RT:
k1 C
NA
2CD AB
NA
2 PD AB 1 N A RT 2k1' P
ln
RT
1 x A1 2
(d)
Plugging in the values, we get:
2 1.01325 10 5 0.2 10 4 1 N A 8.314298 2 0.53 10 2 1.01325 10 5
NA
ln
8.3142980.0013
1 0.97 2
2
4
N A 1.76 10 kgmol/m s
For unsteady-state diffusion through a spherical geometry where we are looking at average temperature and
time, Figure 5.3-13 (page 377) can be used. So, to find the radius, r, we need to find Y, and X, where:
C C ave 0 0.001
Y 1
0.025
C1 C0
0 004
Because A reacts instantly, we know that C1=0. From the graph for a sphere at Y, X=0.32
Solving for r:
D t
7.5 10 9 2
X 0.32 AB2
r 0.000217 m
r1
r12
kt = (35s-1)(0.010s) = 0.350
CA0 = Solubility*Pressure = (2.961x10-7 kgmol/m3 Pa)( 101.32 kPa) = 3.00x10-2 kgmol CO2/m3
Q 3.00 10 2 1.5 10 9 / 35 .350 12 erf 0.350 0.350 / e 0.350 1.458 10 7 kgmol CO2/m2
XB
0.4
0.667
1 X A 1 0.4
XB
0.6
At point 2: X B'
0.667
1 X A 1 0.1
XC
0.2
X C'
0.333
1 X A 1 0.4
1
1
D AM '
2.635 10 5 m2/s
'
0.667
X
XB
0.333
C
2.02 10 5
6.75 10 5
D AB
D AC
Calculate PiM:
Pi1 P PA1 1.0 0.4 0.6 atm
Pi 2 P PA2 1.0 0.1 0.9 atm
At point 1: X B'
PiM
Pi 2 Pi1
0.9 0.4
0.740 atm
Pi 2 ln 0.9
ln
0.4
Pi1
1.9878 10 5
xC1
0.15
0.05
x B1
5
5
D AB 1 x A1 D AC 1 x A1 1.64 10 1 08 5.456 10 1 0.8
Calculate CAM:
P
202.6 10 3
C
68.0647 mol/m3
RT 8314358
C A1 Cx A1 68.0647 0.8 54.45 mol/m3
C A2 Cx A2 68.0647 0.2 13.61 mol/m3
C AM
C C A1 C C A2
C C A1
ln
C C A2
68.0647 13.61
N A 4.68 10 4 kgmole/m2s
1.01325x105 Pa and 373K. The pore radius is 60 A (angstrom). Calculate the Knudsen diffusivity, DKA, of
H2.
P = 1.01325x105 Pa
T = 373K
r = 60 angstroms = 6.0x10-9
MA(H2) = 2.016
DKA
97.0r
MA
97.0 60 10
373
2.016
7.92 10 6 m2/s
XA2 = 0.2
DAB = 6.98x10-5 m2/s
MA = 28.02 kg/kgmol
MB = 4.003 kg/kgmol
R = 8314.3 m3 Pa/kgmol K
(a)
1
T 2
273 2
2
4
97.0 2.5 10 6
DKA 97.0r
7.91 10 m /s
M
28
.
02
A
In an open system with no chemical reaction, the ratio of NA/NB is constant:
NB
MA
28.02
2.645
NA
MB
4.003
Now we can solve for the flux factor, :
N
1 B 1 2.645 1.645
NA
Now we can solve for the transition region NA:
D P 1 x A2 D AB / DKA
N A AB ln
RTL 1 x A1 D AB / DKA
6.98 10 1.013 10
(b) If we estimate that equimolar counterdiffusion is taking place at steady state, = 1-1 = 0. We can
estimate the diffusivity, DNA:
1
1
'
DNA
3.708 10 4 m2/s
1
1
1
1
D AB
DKA
6.98 10 5
7.91 10 4
Now we can solve for the approximate flux:
D' P
3.708 10 4 1.013 10 4
0.8 0.2 9.10 10 5 kgmol/m2s
N A NA X A1 X A2
83142980.010
RTL
DK 97.0r
M
A
DKA 97.0 5 10
DKB 97.0 5 10
2
298
2
0.001582 m /s
28.02
2
298
2
0.004185 m /s
4.003
(b)
For the transition region, flux is calculated using:
D P 1 x A2 DAB DKA
N A AB ln
RTL 1 x A1 DAB DKA
For P = 0.001:
1 1.6457 0 6.98 10 2 0.001582
6.98 10 2 0.001
2
7
NA
ln
6.21 10 kgmol/m s
2
1.64570.0821572980.1 1 1.64571 6.98 10 0.001582
For P = 0.1:
1 1.6457 0 6.98 10 2 0.001582
6.98 10 2 0.1
2
5
NA
ln
1.321 10 kgmol/m s
2
1.64570.0821572980.1 1 1.64571 6.98 10 0.001582
For P = 10:
1 1.6457 0 6.98 10 2 0.001582
6.98 10 2 10
2
5
NA
ln
1.68 10 kgmol/m s
2
1.64570.0821572980.1 1 1.64571 6.98 10 0.001582
(c)
Lower limit is representative of Knudsen diffusion and the upper limit is representative of molecular
diffusion.
0.02226
28.97 P p As 28.97101.3 2.76
H
0.01742
H p 100
100
78.3%
Hs
0.02226
For part (c)
p
2.76
H R 100 A 100
78.9%
p As
3.50
1.037 kg/m3
0.974
The mass velocity G is
G v 6.136001.037 22770 kg/h
Using Eq. 9.6-9
0.8
h 0.0204G 0.8 0.020422770 62.45 W/m2K
At TW = 28.9C, W = 2433 kJ/kg from the steam tables. Substituting into Eq. 9.6-8:
h
T TW 3600 62.45 65.6 28.93600 3.39 kg/m2h
RC
W
2433 1000
The total evaporation rate for a surface area of 0.457 by 0.457 m2 is
RC A 3.390.457 0.457 0.708 kg H2O / h
X
0.195
0.150
0.100
0.065
0.050
0.040
R
1/R
X (1/R)avg (X)( 1/R)avg
1.51 0.663 0.045 0.745
0.0335
1.21 0.826 0.050 0.969
0.0485
0.9 1.11 0.035 1.260
0.0441
0.71 1.41 0.015 2.055
0.0308
0.37 2.70 0.010 3.203
0.0320
0.27 3.70
-Total =
0.1889
X
A 2 R 18.58
The total time is 2.63 + 4.06 = 6.69 hours.
4
x A1 1.41 10 , y A1 0.20
4
0.142 10 x A1
x A1
0
0.2
80
300
80
300
4
0
.
142
10
x
1 0
1 0.2
1 x A1
A1
300kgmol / hr V1
100kgmol / hr
4
1 y A1 1 0.20
1 x A1 1 1.41 10
x A0 0
VN 1 30.0kgmol / h
L0 90.0kgmol / hr
0.030
0.00101
29.73
0.27
0.00300
90.27
*Since the liquid flow does not vary significantly, the operating line is assumed to be straight.
Plot the operating line and equilibrium line and step off stages. 5.2 theoretical stages required.
x A0 0
VN 1 30.0kgmol / h
L0 90.0kgmol / hr
0.030
0.00101
29.73
0.27
0.00300
90.27
L
L
90.0
0
1.20
mV mV1 2.53 29.73
A A1 A2 1.20(1.19) 1.195
LN
90.27
AN
1.19
A A
y1 mx0
0.00101 2.53(0) 1.195 1.195
N
5.04 stages
ln A
ln 1.195
A1
(1 x A ) iM 1
k x' /(1 x A ) iM
k y' /(1 y A ) iM
1.967 10 3 / 1.0
1.342
1.465 10 3 / 1.0
Plotting this, we get yAi=0.183 and xAi=0.247. Use these new values to re-estimate slope:
(1 y Ai ) (1 y AG )
(1 0.183) (1 0.380)
0.715
ln[(1 y Ai ) /(1 y AG )] ln[(1 0.183) /(1 0.380)]
(1 x AL ) (1 x Ai )
(1 0.100) (1 0.247)
0.825
ln[(1 x AL ) /(1 x Ai )] ln[(1 0.100) /(1 0.247)]
(1 y A ) iM
(1 x A ) iM
slope
k x' /(1 x A ) iM
k y' /(1 y A ) iM
1.967 10 3 / 0.825
1.163
1.465 10 3 / 0.715
Plotting this, we get yAi=0.197 and xAi=0.257. Use these new values to re-estimate slope:
(1 y Ai ) (1 y AG )
(1 0.197) (1 0.380)
0.709
ln[(1 y Ai ) /(1 y AG )] ln[(1 0.197) /(1 0.380)]
(1 x AL ) (1 x Ai )
(1 0.100) (1 0.257)
0.820
ln[(1 x AL ) /(1 x Ai )] ln[(1 0.100) /(1 0.257)]
(1 y A ) iM
(1 x A ) iM
k x' /(1 x A ) iM
1.967 10 3 / 0.820
1.160
k y' /(1 y A ) iM
1.465 10 3 / 0.709
This is essentially the same slope so use the interfacial values obtained before.
slope
k x'
1.967 10 3
NA
( x Ai x AL )
(0.257 0.100) 3.78 10 4 kgmol / sm 2
(1 x A ) iM
0.820
xAL=0.10,
yAG=0.380,
y Ai y *A 0.197 0.052
m'
0.923
x Ai x AL 0.257 0.100
From the previous example:
k y'
1.465 10 3
and
1 y A iM
0.709
(1 y *A ) (1 y AG )
yAi=0.197,
xAi=0.257
k x'
1.967 10 3
1 x A iM
0.820
(1 0.052) (1 0.380)
0.733
ln[(1 y ) /(1 y AG )] ln[(1 0.052) /(1 0.380)]
1
1
1
'
'
'
K y /(1 y A ) *M k y /(1 y A ) iM k x /(1 x A ) iM
(1 y A ) *M
*
A
1
1
0.923
K y' 8.90 10 4
3
3
K / 0.773 1.465 10 / 0.709 1.967 10 / 0.820
'
y
K y'
(1 y A ) *M
( y AG y *A )
8.90 10 4
(0.380 0.052) 3.78 10 4 kgmol / sm 2
0.773
492 28.64
0.07309lbm / ft 3
460
77
359
L 0.99708(62.43) 62.25lbm / ft 3
v / 0.8937 / 0.99708 0.8963 centistokes
From Table 10.6-1 for 1-in Pall Rings: Fp=56ft-1.
Pflood 0.115Fp0.7 0.115(56) 0.7 1.925H 2 O / ft packing height
For Figure 10.6-5 for Random Packing: (GL / GG )( G / G ) 0.5 (2.0)(0.07309 / 62.25) 0.5 0.06853
From Figure 10.6-5 for 0.06853 and 1.925, the ordinate=1.7.
Capacity parameter equation from ordinate: (To find volumetric flow)
0.5
1.7 vG [ G /( L G )] F v
0.5
0.5
p
0.05
0.07309
vG
(56) 0.5 (0.8963) 0.05
(62.25 0.07309)
vG 6.663 ft / s
GG vG G 6.663(0.07309) 0.4870lbm /( sft 2 )
50% Flooding:
GG 0.5GG 0.2435lbm and for the liquid: GL 2.0(0.2435) 0.4870lbm / sft 2
New capacity parameter: 0.5(1.7) 0.85
From Figure 10.6-5 for Random Packing at 0.85 and 0.06853: 0.18 inches of water/ft
feedrate
1140
1
lb / s
lb m /( sft 2 ) 1.6427 ft 2
gas flow rate 3600
0.2435
2
2
AC 1.6427 ft ( / 4) D
D 1.446 ft
xN
0.02
0
0.2
5.18
333
5.18
333
1 0
1 0.2
1 0.02
1 xN
x N 0.00355
For a portion of the tower:
y n 1
x
0.02
0
333 n 5.18
333
5.18
1 0
1 0.02
1 y n 1
1 xn
Choose several y points arbitrarily and plot the operating line.
Plot the equilibrium data from Appendix A.3.
Step off trays from bottom to top: 2.4 theoretical trays
Number of trays with 25% efficiency =0.25(2.4)= 9.6 trays
10.6-3 Minimum Liquid Flow Rate and Analytical Determination of Number of Trays
A tray tower is absorbing ethyl alcohol from an inert gas stream using pure water at 303K and 101.3 kPa.
The inlet gas stream flow rate is 100.0 kgmol/h and it contains 2.2 mol% alcohol. It is desired to recover
90% of the alcohol. The equilibrium relationship is y=mx=0.68x for this dilute stream. Using 1.5 times the
minimum liquid flow rate, determine the number of trays needed. Do this graphically and also using the
analytical equations.
Given:
y1 0.022
V1 100.00 kgmol / h
x2 0
m 0.68
0
0.22
0.03235
0.002244
'
L'min
L'min 59.24kgmol / hr
97.8
Lmin
97.8
0
1
0
.
22
1
0
.
03235
1
0
.
002244
x1
0
0.22
0.002244
97.8
88.86
x1 0.0218
97.8
88.86
1 0
1 0.22
1 0.002244
1 x1
Plot the operating line with several points. The solution is dilute, so the line is straight.
Step off trays: 4 trays.
Flow Rates:
V1 100.0
L2 L' 8886
A A1 A2 1.355
Calculate N:
y mx2
0.022 0
1
1
(1 1 / A) 1 / A
N
ln 1
ln
(1 1 / 1.335) 1 / 1.335 4.04
ln A y 2 mx2
ln 1.335 0.002244 0
Acetone is being absorbed by water in a packed tower having a cross-sectional area of 0.186 m2 at 293K
and 101.32 kPa (1 atm). The inlet air contains 2.6 mol% acetone and outlet 0.5%. The gas flow is
13.65kgmol inert air/h. The pure water inlet flow is 45.36 kgmol water/h. Film coefficients for the given
flows in the tower are: k y' a 3.78 10 2 kgmol/sm3molfrac and k x' a 6.16 10 2 kgmol/sm3molfrac.
Equilibrium data are given in Appendix A.3.
a) Calculate the tower height using kya.
b) Repeat using kxa
c) Calculate Kya and the tower height.
Given:
y1 0.026
L' 45.36kgmol / h
y 2 0.005
V ' 13.65kgmol / h
x2 0
From Appendix A.3 for acetone-water and xA=0.0333 mol frac: p A 30.760 0.0395atm
y 0.0395
Equilibrium line: y A mx A
0.0395 m(0.0333)
y 1.186 x
Plot:
x
L' 2
1 x2
y
y
V ' 1 L' 1, V ' 2
1 y1
1 y2
1 x1
x1
0
0.026
0.0055
13.65
45.36
x1 0.00648
13.65
45.36
1 0
1 0.026
1 0.0055
1 x1
Plot the operating line.
Approximate the slope at y1 and x1 using trial and error:
k x' a /(1 x) iM
k x' a /(1 x1 ) i 6.16 10 2 /(1 0.00648) i
slope '
'
1.60
k y a /(1 y) iM
k y a /(1 y1 )
3.78 10 2 /(1 0.026)
y1*=0.0077
Using new points yi1=0.0154 and xi1=0.0130 continue trial and error:
(1 y Ai ) (1 y AG )
(1 0.0154) (1 0.026)
(1 y A ) iM
0.979
ln[(1 y Ai ) /(1 y AG )] ln[(1 0.0154) /(1 0.026)]
(1 x AL ) (1 x Ai )
(1 0.00648) (1 0.0130)
(1 x A ) iM
0.993
ln[(1 x AL ) /(1 x Ai )] ln[(1 0.00648) /(1 0.0130)]
Recalculate the slope: slope
k x' a /(1 x) iM
k y' a /(1 y ) iM
6.16 10 2 / 0.993i
3.78 10 2 / 0.929
1.61
1.62
k y a /(1 y) iM
k y a /(1 y1 )
3.78 10 2 /(1 0.005)
The slope changes very little. Plotting this line we get: y2*=0.0, yi2=0.0020, and xi2=0.0018
Using the interfacial concentrations:
( y y i1 ) ( y 2 y i 2 )
(0.026 0.0154) (0.005 0.002)
( y yi ) M
0.00602
ln[( y1 y i1 ) /( y 2 y i 2 )] ln[(0.026 0.0154) /( 0.005 0.002)]
Calculate the flow rates:
V'
13.65 / 3600
V1
3.893 10 3 kgmol / s
1 y1
1 0.026
V1 V2
V Av
V'
13.65 / 3600
2
V2
3.811 10 3 kgmol / s
1 y2
1 0.005
VAv
a)
V
3.852 10 3
( y1 y 2 ) k y' az ( y y i ) M
b) ( xi x) M
( xi1 x1 ) ( xi 2 x 2 )
(0.0130 0.00648) (0.0018 0)
0.00368
ln[( xi1 x1 ) /( xi 2 x 2 )] ln[(0.0130 0.00648) /( 0.0018 0)]
L
1.260 10 2
( x1 x 2 ) k x' az ( xi x) M
(1 y1* ) (1 y1 )
(1 0.0077) (1 0.026)
c) (1 y) *M
0.983
*
ln[(1 y1 ) /(1 y1 )] ln[(1 0.0077) /(1 0.026)]
1
1
m'
1
1
1.186
'
'
'
'
2
K y a /(1 y ) *M k y a /(1 y ) iM k x a /(1 x) iM
K y a / 0.983 3.78 10 / 0.979 1.16 10 2 / 0.993
K y' a 2.183 10 2 kgmol / sm 3 molfrac
(y y )M
*
( y1 y1* ) ( y 2 y 2* )
(0.026 0.0077) (0.005 0)
0.01025
*
*
ln[( y1 y1 ) /( y 2 y 2 )] ln[(0.026 0.0077) /( 0.005 0)]
V
3.852 10 3
( y1 y 2 ) K y' az ( y y * ) M
y1 0.20
y 2 0.02
x2 0
x1
0
0.02
4 0.2
2
6.53 10 4
4.2 10 2
x1 0.00355
6.53 10
4.20 10
1 0
1 0.2
1 0.02
1 x1
Operating Line:
y
x
4 0.2
2 0.00355
4
4.2 10 2
6.53 10
4.20 10
6.53 10
1
y
1 x
1 0.2
1 0.00355
8.16 10 4
1 y1
1 0.2
Gy
0.2
6.53 10 4 29kgair / s
64.1kgSO2 / s
1 0.2
Gy
0.3164kg / sm 2
2
0.0929m
Similarly for liquid flow:
0.00355
4.20 10 2 18
64.1
2
L'
4.2 10 '
1 0.00355
Gx
8.241
L1
0.04215
2
1 x1 1 0.00355
0.0929m
k x' a 0.152G x0.82 0.152(8.241) 0.82 0.857 , k y' a 0.0594G y0.7 G x0.25 0.0594(0.3164) 0.7 (8.241) 025 0.04496
Interface Compositions: Estimate the slope of PM by trial and error: Final yi=0.1685 and xi =000565
(1 y A ) iM
slope
(1 y Ai ) (1 y AG )
0.816
ln[(1 y Ai ) /(1 y AG )]
(1 x A ) iM
(1 x AL ) (1 x Ai )
0.995
ln[(1 x AL ) /(1 x Ai )]
k x' a /(1 x) iM
15.6
k y' a /(1 y ) iM
Calculate (1-y), (1-y)iM, and (y-yi)
V
8.16 10 4
Integrate: f ( y )
6.33
0.04496(0.0929)
k y' aS
(0.8)(0.0315)
(1 y )( y y i )
0.816
(1 y ) iM
After repeating for each y value from y1 to y2, numerically integrate to get z=1.588m.
303
4
2
Correct the diffusivity to 303K: D AB 0.142 10
0.167 10 m / s
276.2
1.866 10 5
0.958
Calculate the Schmidt No: N Sc
D (1.166)(0.1670 10 4 )
From Table 10.6-1 for 1 in metal Pall rings to 1 in. Raschig rings: f p 1.34
4
HG H y
f 0.660 6.782 0.678
p
0.35
HG H y
f 0.660 6.782 0.678
p
3
From Appendix A.2-4 for water at 303K: 0.8007 10 kg / ms and 995.68kg / m 3
At 298K: 0.8937 10 3 kg / ms
0.35
0.8937 10 3 303
9
2
0.8007 10 5
354.3
Calculate the Schmidt No: N Sc
D (995.68)(2.27 10 4 )
9
0.3
0.357 N Sc 0.5
Gx /
HL Hx
f 372 6.782 / 0.8937 10 3
p
0.3
4.069 / 0.8007 10 3
0.2306m
3
6
.
782
/
0
.
8937
10
1.34 372
0.5