Sdeld - yaem Odelaitle Algal! GY gat! ile dle ‘ge Transformations liées a des réactions é acido - basiques dans une solution aqueuse AzLI ALL eles 2 etl taal < Aout y ile ght pH Gy at pla by Sle at aw ty em BAe ay aly sem Cty wpa [inetd de yo AK Ad ead i Ge st ater [Bdetd le 92 8 a as Bsc — jaar Jotél O51 pl dB ae ADACU. gaer ele iy pi PKA My pH J) Dy sane [SAU de 52 7h cpeagll g yol aye lens Jeli lg paki Land i PSN rm ud y PH pled stl p d460 gf saa dpb [PIS Adal De O ple SIS jhe! jai aps ptlolWee eo yt GS ges ATS cane pala ee pH II els OV 67,5 9 65 ct nee SLM Gee pH le But os ISD US a Sligo PHD CS | OLS all 3 AM cae 4 B33 ppt LN TL Le pyel $BaclS —peom OLY 2 eS i sigs ale Saar /BielS A> 9350 just aS -Byglall ottp jLoaif iz ciuSy Suc - aa Spalet (alee calsaN EE shell cigs clint eel SHU sigan floc -1-4 (25 Cae Th Lab lB J ya pH 25 °C sis ap 5 H8O* pg pS yI Ugh le all lll og ans 023) [HsO*]=1077 mob.L-": 5» Sells! all) 2 HsO7 Gli agey ules Sey aS 6 AW JD Gyn! Jou! Jos (RI Do yp! Laem HO" (aq) /H2O(0) a 42 p05) 565 2 HO Lad! + H2O(¢)/HO™ (aq) «HeO suctatly HoO gaantt ony JeLact aisles cs! « e100 HO“ pug sglt Gligaly Hs pgcigusg¥ Cligal se lgh le © walla SEL pa pa oll a V= Themed duets 25 Caie ae AAELERN (ig? Gilgit! pak Zyad @TLI pu Py Os te $25 °Cote eid el gs a asa P=1G.CM*s ole aeeoo AES: tans ell gape cmH Ogg a Sldsl Kew HO" 633 -SMOglo Se HO ASy Apo y lata HeO(e)/HO™ (aq) Beep Atl oy ab Sem cad ial gg elle els all fols Grtmw 003] § Hs" (aq) /Hz2O(0) ar 52 hh 9 Geld» 995 PLM nm cai doe 2 ll Bey S99 dee go jl) oem oy Bele H20(¢)+H:0(¢) = Hs0*(aq) +HO"(aa) 21 JS2) La FA yh fons (1) geal Joi a eae MNF HOM tS gt OU gly HsO* pgs Sg aU gf wel y3 Of 6 _ a ASI BA Sein oad co 2 a! ‘Tautoprotolyse Bote Qe Ire te (Kae ABV pads y 0 jh ll Ae Xy, felis paw Ld + || couple : de gee 2H,0(0) = H:0"(aq) + HO"(aq) ska constante —: at post | aegentiane équilibre 8 ons n(He j ah - ale (H:0) ° ° ° ata ampholyte edad i BX, Xe Xe Xq | cotance masse volumique : Kame US Fp OjT A ee Jeli pA OS «aL ye VEIL pet Ect Xeq= Meq(H2O*) =[HsO*],, .V (25°C 2:6) Xeq= 107.1 = 1077 mol zai i sgBU Spe D510 cone SMeUidY iy Metal? 5 Fup gl LeapWV pene aT BM(Hs0)~ BM(H20) eV ee Xn = 200710110 — 98 mol : al gl 150 [0,11.10"| 0 peaeiowd 140 |1,00.10") 25 pa MRT HB, O107 5 fly pail Li 055 3] le LoD og gio pal sl Of de Jy Mines toe ll ode O} “gorbeg!l bi gly HsO¥ pd SSW Si gl pe bphae Jor aS Ll -HO- At Ala iL Dl tees bg Ape HsO* ot ySt of ch ash JIB JS J LU SIG gig gl Jn Suto oP aly SUM OLS Ul ASU! A are 9 deel ys HOT Ob yy 5 GUS LU SG sig al fle Molec ty AlN O jf ll SG log a” celal 5 pM eldh! geuiy + Ke =[Hs0°],,.[HO-],, log 1=0 3 log 10=1 cab meter i ieee a Ans Weyl MI oles aes LIAN > tee yay lad Ke anh hes -Ke=1,0.10°" ang) Ke ab L6G 25 °C ue i © BROBEIGGIKE) nt) pKe tt) lar GLY WAS Joes (Megara Bel ee SUNY ails oll pKe Hy) Ke hy) pS ey 9 yl Ke YS lye | Ladle 9S Cg! Whe of Juss a = Sp 5 J BI te 0 i AgGML) STL 2 ae M6qrA LAY! Ge Gini Mint) os i aad 133 |5,50.10°"| 50 25 °C5j) Dix yo eB yA cdgle Le 5 [HO-] =4,3.10-% mol.L': yaa ddA g HOM SU AM SF pHs=9,2 : BJ 441 pH bode Aas Ue I DU leet Slane Ads) pH * BU gba BHO SU pI 5S 5° dail 4 tae pall ene PH=—log[HsO*] awl, gl Jes pH oF Ke=[HsO*]. [HOT] : yl Ll 5 nM lath oe pay = POSS cdl pgle LEAL 1 le fas WL ololt Slabs pH =pKe+log[HO-] 1 2B °C ase clad A J heal Hal pH=pke+log[HO"] oussia wiaaniste [HO™]= 108-9" | Bayne ops LBA PH 31 gland ILE SoS gland 25115 [HO™ | 5 31 Jott! DH 2800 (54 18>tlas! [HOT] :log[HO™]=pH—pke ; 25 °C ue cbgS [HO]: ae J Lar Yh Je oS 5 de esos [HoO"] 3 U5 LEI 3b Gps [HsO"] > Ke ; | [Hs0"]'>[H0"]{HO-] [Hs0°]>[HO-] | aucoan ys —log[H:0']'<—logke : ji log[HsO*}">logke : oi gi PH<>pKe :dWky 2pH Jpke rad Ugils aa aa eda fll y Ble Ne 12 Sa A Ae ley 8,0. hee Sue BAngajtduaa @ aya -1.2 6,3.10°" 5 3,1.10-° 50 Regalia salah pat: 20 yam By Liao BYa,NH NHS i : i j | | ! i i i E | QI HEN) 5) JU toe se VK A aaa a5 lest Y PKa=—logKa : aiptaly HA/AM a 90 PKs salt lis 5 seh ole B biel cies Mei Aig Meant 5 Bae gh Be he ei gt eet)7) tee p te HAV AT le yo laa PK a tol 05 3) ptt any NT as] 225°C iat 0 |Hs0"(aq)/H.0(¢) : Uigah < [8,5 e542 04l] 1.9 | SOs (aa) S03 (aa) (BH eed) fold UL 55 BH /B i joj G Desshoyi jar | 2.1 |HoPOd(aq)/HePOs(0a) -BH*(aq)+H:0(6) = B (aq) +Hs0"(aq): S21 de ell ae Sinus a | 35 [AP (00) (0a) ‘yisll jar 8.8 | HCOcH( aq) /HCOz(aq) i PBN BH/B te yo poll antl al ge pa Disha | 42 | CoHisCOs F(a) /OsHs CO; eq) Kaz BL{He0" 8 | CHsGOsH (eq) (GH.CO; (aq) [BH"] 6.4 |CO.,H:O/HO05(aa) + Ka ducgont! AialSg pH 3 Cys 2Bdal! +202 _ | pete? oall 72 | HePOz (aa) HPOE (aa) A aes Coa ste —s ie mon Seo rosMiogh [02 |NA(ea)INHfee) | OSes caters mera 10,3] HCO3 (aq) /CO3 ~(aq) be has cde sé gl DI ot JLal, 21] HPOF(=)POT—e) | BH cotealel pKa to[th0"] tool 14,0] HO (€)/HO (aq) 1 yi Jesse pedye poten jalPKagS am lp A | well cle gajt Amend! 1S -3.2 2 a [AEB cee gaye B fea badd gy oll :HsO*(aq)/HeO() dagazall dalle << AUB SiclS/ an aga JSI Mealy Oj) pll Hs" (aq) /H20 (0) a 92 pl Ka ayant tal of tell en HsO* oad Joli dale tty iat) Hs0*(aq) +H: 0(¢) = H20(¢)+HsO*(aq) H30* rol St PBK oat a ye pa pKA.=0 : af gh i +HzO(€)/HO (aq) dpgajall dually mt 4a a HeO(aa)/HO™ (ax: 93 yall Kar tad aa of ey eas : tll geHleO aad) Joli Males 3g All aad a eon ", _ HxO(¢)+H:0(¢) = HO-(aq) + Hs0*(aq) BY KAr Lead al ye pas | 25°C ue pKae= 14; of cel Kaz=[Ho0°],[HO-]=Ke sBaold aor Solas ig Gilgit! AIS 4.2 RIB er jal) gall As jaad Seb — faa oll ad Ac/Bo dx 49 zal) Aarti Be Suelily ia + B2(aq) = Bi(aq) + A2(aq) HLOMHO™ esate SLI Bie coer ENeLSL Ain Wet adit F8n0 oSREE Ser HAS Jolie lin Wala ty All Oj1 ll aU ye pw ge ens [H30"] 3 Ly pill Gas [BL[HsO"] [ad] K= x— 1a] _ A Bz].[HsO™ (oa) + Bs(aq) = B (aq) + As(aa) LS Testleior ; a BuslAs Teed AU de pe Na 3 Gas [Ay [Bi] Te) yeSi elk) en Abela php pasa! + ges Jglne Ula GAT Hvar Ka pasts welll HA (ag) 20d) Joli SIE Ball Le glad putas J yr goth A(ag) + H:O# Blaq) + HsO"%(aq)| Jeter arsine Gabel Olees pasty | Agent te n(A) ae | 0 ° 0 | assay ni(A)—xq | tae | He |X yg | aebenranin vax | am | = | x Koa OV gta , [Al=o st Semmes Sat jane saga padpttte- lls 475 | pKa [H.0"]=[B]=22 == Cir Le a ae Vv Boge Bee Dobe ys Sgt A ni nee cV—cV.T Oi tae nee [aja tee = NNT (12) oly By A Ka Qaeda DL ode b ggls SNK Oj Saal oe aw rglls aot! \ oe sgl Biss cpar EMeUSL Ai, MEN nit SimoE Kee) c(1—t) OB Tr Te CAS 13) 603) TI Qaela dis Ka of Dyes 5 NB tga param Gus Jol dual i ts Hs" Hs Ode gaz Steldy (A]=c(1-7) ‘ : [B]=[H.0°|=er J PRA=—logKa ual opKa, Kaz Re [B]|H.07) ' AKA S Stall pull al fe ie ISU jane fbe lll a ole VI ae Jol OS Lys Uy Wl en leglelis gdh puis as of huis HsO*(aq)+C8 (aq) 2 spect Dag Spl pay Li, -HsO*(aq)+NO3(aq) , voile Soles 2 selgat glu Ziylas -2.3 1G Je gs) pA ad CHS LS cans 5S A cy ll ; + PBC see C= 1010? MOL sas 5S SL BSe Si cal Le peas KA 63.107 Sts YI J gle 2S +Kie=2.10" cal fate Sole Se PHe= 11,4 )pHi= 10,6 5 tm (25 °C ue oA pin pH ya 2 abslall no Ul a Bela Jetis B (aq) + H20(¢) = BH" (aq) + HO” (aq) led pail 5 00 jt oe pra alHO7) v sof t= CVE somata) PLS Bite cour MUI A, Meter: 5 Sap gh Bey es ee ead e jot| 7 p | 2% 4% © | | 20.10" | 6,3.10°*| Ka || t07 92 | pKa le Gp AyD Age gh: 6S yax A NOI0 mel” 5S pied ge” ' cole lll AA” Sucld Jol alee ss ' «ea | | -A-(aq) + H:0(¢) = AH (aq) +HO-(aq) | biangal Jala Kee 2 eas H.0(0)/HO"(2q) gAH(aa)/A~(eq) AH aan 5e5 53 —_— Loe A> susan igh 2253 AD Suclally AH yaaeod! 598 pola AH(aq)/A~ (aa) angaptipKa aris | BHA/B dengajtl Buel ony Sola Qeatly | Bg OIHO™ angst gaan 9 {B]=e(1—t) [BH"]=[Ho-]=cr all H20'] jet fa aS or ie ade SIT Als 6554 pH J) ots LUS ol pH SIV T pe cree Andi 3S ANY HE APA KA aad aay jaar Stel de 9054 IS jad BAAR ACIS WS dad yo OSS TI 6d gad 9 Wi gall Ry pel lel ond 208) ae Sa A ae J + Gacli Jglne ls GA THY Ks puss 10 gB (aq) Susi Jotis JD Gall teas a (LES J yer pots Halal leas (| agente n(B) ae ° ° 0 | austen n(B)—x,,| ae a. Xi | Xq | tener 2 e pees [Hs0°] op plat bt) ope _[BH"},[HO-].[H:0°] _ Ke. ~ [B}Ho*] Ka Ka teeth gl Go slie yo Cue — oY [B].[Hs0°} 2 QUIS gle pais as WY K jt NAA ge pee __(ry’ Kec —t) iT Shae Do O53) ae crt Ke Fike : Jtdky K= ters Ka 2 Sial Se oo rep Sol DB butels -pbar CMeUSL 55, WN eH pail 2 5840 gSfal Ka ott pps sins PRar>DKas = July KayeKay: 3b Te Te cals i i] + digal /sscs Berge tecll Ue aa gies PH=pKa+ tog 2) ; i | ' [A] i ~ ' Ee oO clog Blo oi pH =p wis) ppl ke ke Ks a [A] [A] | 25°C ase NHi( aq) NHs( a0) : B] i B) eer , fal OS soars? lePH[B] [B]>[A]. [A]>[B] i BEANS A ad ab sts gl pH dl JLe (5 JK) Sylar ' (6 JS) (PKA=9,2) NH/NHs ae youll apache PH< 9,2: ois isyNHi aad nage PH> 9,2 : ois NH Sued age +O Galea -2.4 BABA arG yA aed de gy LL Viglen A i : ae ey Dal Se 3 ads co ed epee he: 7)Ka a ‘CH.COOH (1) /CH5600" (2) a(A 2) =a] Maal ele J Sela as alli a, «CHsCOOH/CH;COO™ Be gpje ce 3 (TJS) uj gll bles fee Ll Dine ober eelidh iy He tentl2 5 Sangh Hey© By Abie na te oJ BI pH DY telly eer) on gill oe) poe eel «a(A)=a(B), Ct as ea F ils poe a AaglL aay) ULe -3.4 i BETS) Gacy ogy ELE : ttle atlas 100-82 | 76-60 | 44-31 | sv Idi pote hil jot y gl Gest SOI pa: ZU per t = UN Hn ce Oj) that Sone cam | Rte be 92 p03 peer Jee i Hin(aq)+H20(¢) == In"(aq)-+Hs0"(aq):astlt, J J Le 3 cal i i © pKa atl, jealt i iL gD peel fareey AN OS gHIN Oy aap Lee WOU Bly dane ct Lk [Hin] =[in“] 5 pH=pKar @ JXsy ott In 60 gl GES) Se OW ge J lA ogial asf >t0 OF I> pH> pKa +1: Justo ft ob (03) cla OS [Hin] (oy G36 aw 09 wdadlogal wwe LT] 1 oieiye {Hin} ~ 10 pH Joli HA Lam ys HA (aq) + H20(¢) = A-(aq) +H:0*(aq) HA (aq) aot 2 HOT (ag) ite, 4 sles Yad ot Sg tl of pew 5 GUS DL oda 5 5 glee JS fetish dale 55 HA (aq) + HO“ (aq) —- A“(aq)+H20(¢) + GUS a slall fetid o 5 yl ab 5G [a] = [A] [Hs] [HA][HO-] [HA] [HO-] [Hs0°] OF gh 10* 5 SAK OSS Jide, 10" 5 Si Kaul Gb We AUS 0S AUS AIL ode 3. pla Jol Aagaph Quan! ALS OgSS Le Ne 2107” ya siHA/A | By cols By LIS Jel yaa f 4 kK, AOS eye psi aStslany Zigpatl ole! K=go ralgl K= ] Le Jolene 2 Sucl5 dples -4.5 Sh geM jaar Je «| AeA de ple SD gle paar SE | Gar rs wen | HaO°(2q) ath Up gles Jets dale ob alll eo US Jolis Sie Oats Lil 4 a WS SS Be SY Gane Jolt BOE oye (25 °C ue) K=10" as HO-(aq)+Hs0°(aq) —~ 2H20(¢) ADU ples Joli dake OU cll eo Ly pe Jolie’ B(aq) sued Cals li]e i dels SS H20%(aa) | K=—— «& B(aq)+HsO*(aq) — BH’ (aq) +H:0(¢) i pS OS ty Byalatl GdleLait Qilgitl pugitl Au 5.5 aN psa gi DucalsyN pglatl it Lines old) J ABH PH sol (ye DU pe pall ted he Sty tale) aa cu Joti! ESTERS 25S Fes saa Jolt oe Va= 20,0 ML Lime oS 3 aisie = Cx=10,0 mmol. SF papell eS ght Jolt ow Vo= 5,0 ML Lin 43] = Co=20,0 mmol. CJS) pH = 4,80 : m3 LI pH ly bee | (ge WLS ue LIB pH AS 11S | DIN ae Ui perl S pple | i 125 °Cae | | comportement / syletint! 2 pA Je gots folie) Sly pis es Medd oe sep Sle Bisel bas CMeUN Ay WOM path: SoeSalt) Sleas (Ha) a(Ho) | ° ° (HA) — xr |n(HO™) i]s « |] ser | 1i(HA) = Ca Va= 10,0.10-*.20, 0.107 1i(HO~) = cs Ve=20,0.10"*.5,0.10-*= 1,0.10~ 70S SL HO™(aq) yo WL oie J adh Joti 05) Xwax=ni(HO-), 10~* mot x:=n(HO-)—ni(HO-) shal pail Jgatee = MQ(HOR-) testy [HOT], ud oy atid pH Jaa Mi(HO~)=[HO],.(Vat Ve) any [HO], = 10-9 ne(HO-)=10-".(Va+Va) : of cf ni(HO~) = 10°*-*.(20,0+5,0).10-°= 1,6.10-" mot x1=m(HO-)—ni(HO-) = 1,0.10-*—1,6.10-"= 1,0.10-* mot x Ma ptt S| Glas Ve gon OF Uf mallee peas (SE CEM Mle plall Joli alec tsy all 0 J hag Lie asty (1) CH; COOH (aq) + HO" (aq) —- CH. COO" (aq) +H0(¢) ___[CHsc00-] [cH COO] [Hs0"] [CHsCOOH][HO-] ” [CH.COOH][HO-][H.0"] HE =10%-=1,6.10" 25°C ue K= PSC) Jota OF Sy Le cal po doe Lead ade 0) Bukola poem 5pilesvinisSF asl gare Sse go Va=20,0 mL Lane «pl aie . Ca= 12,4 mmol.L- tat all eS he lt oe Va Lene ee teal ee i -Cs=20,0 mmol.L* 055 5 BLS JS ts oat) Jolt pH cH — pH daly tie + Glu dyad § aba al seh BNI eee Sole « stp ASy pts Sle «)) /12,0/11,0/10,0] 9.0] 8,0] 60/40) 2,.0/ 1,0) 0 ol) 62/56/54) 52/50) 47) 44/41/38 | 33 '20,0| 18,0] 16,0] 15,0] 14,0] 13,5] 13,0) 12,6| 12,4| 12,2. 16/15/13] 112] 1 | 108) 106] 101] 8.3 | 65 jhe! es 2 SSS pill Joli dates Go f= CHsCOOH(aq) + HO-(aq) —~ CH: COO“(aq) + H20(¢) | Veprtiay Jytipet yas sta joa | Sat JIANG hl Ua JA pH st (12S) ign Je f Sag edi Lal p> pa) i TE Sia Biol tap AD oye ead oul 9 Se pHe=8,3 oie 12,4mL | glall Jotictl OY Ob pH JI pi: c= (0 13mL) PQ. Li oad Le Sn tn dy bap (HOM seta) lal ¢ yh of ash = CHsCOOH (204) yo stl ¢ pill jlo y BM) caleba og fa yS pooh Ie A) ace PIES le pad a i CaVa=Ce Vee any Mi(CHsCOOH)=ne(HO-) (lll, Cae Vee= "5 =12,4mL : ol gl Mees 12,4ML goed oye gah etl peabl he ily sda YI old (DH =f (Va) cael) GUleai! dlads) 5 joes alaal of kee PHL portal! all ily IG oly cpil5GI Gilt (PHe, Vee) oo spl Spl Bisel core Melis Ain BoM pat Soap pSper yye aes 0; Om Veep s eae 21,0.10°? mo8.L"* Ae SE BLS! JS ey PH II ti SAI a 3 te pH II ae gat yOa= 1.4107 mol.L-" 255 JHsO°(aq) + C0 (aq), Ss QM Dyatt g ahad atl 295.5 NHo(aa) Sls pS Je gs 11,0] 9,0 | 7,0] 5.0] 3.0] 2,0] 1,0) 0 8,7 | 9,0 | 9,2 | 9,5 | 9,8 | 10,0} 10,3] 10,6} 20,0) 18,0] 17,0] 16,0] 15,0] 14,5] 14,0] 13,0 73 ryletiut 2 GUS spall [oS Dole 5G o NH, (aq) +H;0*(aq) —~ NHi(aq)+H20(¢) Spl pone aN pH I ys 2 19 JS2 A Stall pant ea tatll a3 IS lt Va geen DY pH) gla (13, JS2) gol ice PE pS abs uot lal PHe=5,6 , Ve=14,4mL ie ie ese lal Jeti OY OL pH JI nie Gee « (0 16mL) PQ. tI + Pend Lf tee te fyb de (H20" eat) ple oe Fa NHs dell atl g gl ley Aa) cpleli og fayS pel ae jl] te IS le Spat oe o i pVe=CaVee Siduy mi(NHs)=ne(HsO*) : of cei (abally pay LI Binet vban eelisl i, Medal: 5iaeS DegBy BSL 5 MN OF 60d) ee coll oo eh et pd Wa ily = PHL gertitl scl Ayliogl! wlids del5 - yarem Silas eo5 mw Je Si THF (V) ath pe ale I obits Selb — oar Byles ad (14 JSS) GLAM V gent DY J glo! O ale gli ght NIA cya og Ul bls BIS ily FASiame wuss B (PH A) Raid Vorbis | p55 Eo 3G «PH A La ite — 2am 5 pl a JE Atl Jelell pid tsi WS) Gall ent § Je gay -Crubel! Aza plo -1.8 PHS (Vo) sorta celts Lagi Lad ceil ge Tey Th rendins pero DS JS3) pH Le gli sic any JB tle a ee eT ae (6 JS) pH=f (Ve) lle T pel Qh EA Sine “GLAM jini! Aasyb -2.8 PH Le arti picll [53 tL PH (Vs) gree TL Li nie PB gait Ng) K a gl! tall ye ga _PH(B)—pH(A) _ ApH Vo(B)—Ve(A) Ve Va(A) poo! La) sce J 8 pH 5 PH(A) o> (B) ptt Lz] ue J 4! pH 4» PH(B) 5 de er fell Lis 5 oT Se, Ve Shall pe te pid El shea PHS (Ve) goal! pled onl dl of yt K= SPs Joey dips dl ce PH=f (Ve) Dal di PH=f (Vo) col pal a gl ll Jee SP GV) aa 28 oak me TiN Cp on fi STitrAB 9f TittEdit el eye te H _ (Ve) 16 JSS) soul pens Kee ee 16/524 BEW DIAD gente geyy Shall geld on reBU Spl? Bisel char Melly Ay ME nth 2 Soar g/lgale < 5 SalI THCAB f Tinlit gty Jameel, 9P = G(Va) a pe, oe haptic ac-besanconsciences_physiques/ressources buptlwwwnirele.frsp/media_chimasp Se = cree ees F Biot 5 ple De gb Va Vor Sly Lis 5 op Gy = 9(Va) a +17 JS) jane laa SPH 9 (V) ginal alpine $811 ane Gly Aagltl aaigSH Sloat! -3.8 8 SEIS eee tact gle Laas Joi aso BSA tated Oli) GH Jie! TE cot gl OSs jean (HUMINT) aan [Bset8 de yo po ga 0 lll HIS) sgl Jol Oli Ob J Lg IN”, HIN -HIn(aq) o 4) Jt) ish pHpKatt gis ia), [in] =pH—log 6,2—4,2| 5,0 | sanpaot phate °9 [rin] BAe aa 5 lal At yitSS aed ONS BIS Slanted (Se S22 pee BY PH RAM ND ont pny 4,4—3,1] 3,6 | ccauug 7,0-6,0 | 6,4 | usin pina 762601 72 | ail ae Uplae Bulet hese ilgelS! Gee Gil Baylall Gi i | deetoaaatt sighs AIS SLeniunls pgusqual! ty gytab Jgloves Hhagilis¥! feta=7/0}|Eevoml nasil Blasi! adlais 2 delat) 2 Juamett PH=f (Vs) cleat ote paws! © + (8 Sgt) AUG) Zaglth asigsst 10—8,1 | 9,5. | cnustca Jyinani dalanny Bgl) Gti S same BU ye A CNL Joa = aol GUS GRIN) poe tyke Aighed) LASIgSI! ole JLeatul (Ser Ja © Sie Spssrgsall suSeytno Jglrey ALyiLY) yaar Ugine dulae ares algal “dérivé se | tangente sgletint fonction ON pall fans Head Ogle GIS SLanaly Beli — Jam Byles acl _ indicateur 3 BS AU DAN Lo i ati od cai ple tes Sl J LAI J Oth GIS Le | coloré 4 Ogle oA J Yet tial oh ob 8 gs sig aie Laie y Le Oh Fa [Epes we eve OB Ue die LL aaybl Se of ay Ld Ol) LSI Ke [Ena i i BIS pnd lane BLL emt Ugly Bisel oar helt Sy Mes acl? Sap WN ZepLES) 65:9 pall AS y phat J plone the gle! 2am J ple 5 ples JE = PHe=8,3 yo 5153) ue «J gl pH 05 2 a pel OY Bgl odig! OLD calls Udy Jy SU) peat Ob ll OLS O31 Og wit Ce 3 GIES ae SB pH pid Lge JS Glas! athe SNS pe Adres Daas SEY Delle « 51S I Spe gl fd castlbell (18 JS) (PHe iat Y aibtel aalans) of JS Ml a, PH as 18 JSS A Oates ae es ela 55 a5 @ Seager | rake jet (19 JS2) PH=f (Ve) conill panic 2 Oa Sh o5S Fu sta eatSe Sle op Va=10,0ML par plese a= Ca= 10 mmol LJ sil 055 5 ¢ 2 pall deny yhag) So J gle, Fhe gtAM eat Sle J ple yWa= 10, 0ML gene 5 glee o =0,10 mmol” Jf i 9555 62 pall deny ptegl S'0 J gle Biever tse) = 24NA = 10mL 3 + OT neal Jd ca "o=0) Spl gly ae Say Se il gle pH cad { sOlelae Wad petal illantl dilate OY 1 goull) SYS ple eye SU pode fp\Scll ase PHE, J} pr alaasl abate OY 62 rail) GI 3 LU DL pS yey all Guile i152 ase DHE Jaa © AA Cplaly gall) OV A OS Late ISS Ok AST ge PH I ail Bo fS1 Ogle GES Alaa 9 BED gee at OS DU oe 3 SF -(20 JR) a ge Natta pode mela ZAV Lat pnd 12) BS) SAV’ Glatt AV te pase asl aL GULP Gt HOOS by Spey phe obigs 1,65. — 2COs,HsO thy 5 jaae 0,085 g.L-? — PDL aU) pH Le 103) Se pH=pKa-tlog HOO] [CO.,H.0] Aslan Slee Be eluasstt + oot Sa Aa Mell faced 1S JEU glie Coe Ake UI g Ol lay OIL oy) Coe ee Gil! SAN celal gi lo pall go SM ol yal tle Jace! eal o ate ON shee oh May cay AS) yf (peat! “embryon larve ‘déboucheur canalisation détartrant 2 giily bl ¢ Pagan as © N ALRG el dil pe ge Se yah sol of ole DH Ald oie AU calacal Goats Anaad jai vol, dual plasty jas Be Obs) PH = 6 ye Syl pe GLI) LL pH oS, aed) che Glad tal ge stl oy SU 4s yh sll 4CO2,H2O (aq) 1s) oy SIN uss Bi Jolie HrO* ogg SGM Sb fh (G1 294> J) pH Dates il i Vc feted Lis of YY hal lent a ll (ey chs ae sels Fall obs YAS oe te ols Bale Sd NO sy 51 stens gl fold EG Law eal ll cule a A gop Bell 802 a TLS BLyNOe y YGB iy ae OU de Raat! Le Jai ols 135 or el le eed plot) opt ge Lal Y] Gai opal 3 Slee heel) Sel place YI elie! (pH J) slits! Guy AUD ae pe Jee LS Cobia) toy ENT IS GE Sep cee SQM Sid bho yeas sol ged ode Batt Raa Ua tle ate PH. Gi % — wey 4 aubaisae) z So My oie sls asta PH we SHI Suk CO2,H2O (aq) cy oye! folidl ay all Dotti 1 ally RIA Et gS 5ST AK O5) pH Ao Le 5 pl bel Oj) ae PA Go| pH = 6 oe jbl Le pH ans of 21s ® Oj) ae felis) ey Ash 2am felis SI dole 51 @ AW 9 Hh SS) aa sb IY Siac coer Meld diy Me pactlt Shae gl epS gh Joe ge 5 125 Cue 8,9 tn,al od gel fei La alee tg All 25) AUF eel gb ally ths gb ane ou Jeisl dtabes 1 Qo Cae ee @ apd not OD S J pltl J CHsGOOH (2g) (CHsCOO™ (aa) im y2 jal peel ll Ley oe ay AN lL GA SD ope JS Hy S SB Eh Gi Og ge O pk,(CHsCOOH/CHsCOO-)= 4,8: das (170 tail Jal) old J pill Upad pagal Baily ool CH; COOH (aq) +20 = CHsCOO (eq) + Hs0" (aa) OD] oj Dat ns Bp eu< [CH.COO"]|H.0*] “Bi gS) 5S IK [eH.cOOH] PAL JoUsI gl Oj A eal ge pe CH COOH (2a) /CHs COO (aq) ax 42 jo Ka gaat) 296 alls K fet -K=1,58.10°° of gl K=Ka=10°%%= 10°“? Gal Sete oy [CHsCOOH] 2Yx, Jee uta oe well SO) sips tia ye a AL [CHsCOO™] 2p 55 AVY «3 CHsCOO 7] : z Fon CH:COO-]=[H;0*]=10-* 1 fetid) alee am ela * pH 1,26.107 — :aigi T= «3 [CHsCOO-] Ka [CH:COO7][H:0"] J of ees Ka Kt Solera 5 eee [H:0°] [CHs COOH] aos [CH»COO™] _1,58.10-* et GB ol Uk Ue sceee ad eee es ralgl [cHcoon}~ ao 7°" ae fe) Sauce [CHsCOOH]>[CHsCOO-] BY [CHsCOOH] > «03 «anal! l rJdtiicl O Cth owl) de OM Dead yal poe | Bad hl Log gre JA 0S seats J oo US gle 3 SseU- oder oheliSl Aig OV gail 2 5Bu0 ghTOOL 225 cys ty has tle ye « NgHAL Alan pile 2 pgs dgucll beg eg) UisKll dual ayes e2OML 1OML 48 os OU, Ler lol « Buel. ae Slee jails | ee ea NIL Gf forte ol ill Mae Le ¢ ge nal leo | eo 1aJidl bled i eee + 20% 6:9 yall dn S'y ylag! 1 gl Kel w i SS 2a. i 2 1, 2H of Clit pla o | Spy egllind) cisaell ee ered Sy pee ESI f OLaSy 4,2 BUEN 5 20% ¢ 22 pal Sth So ad pall g bes Jjlati 3 Na"(aq)-+ HO (aq) 6 mol. yi hyde) oe dyes Ve pent ne! @ Sm hl A= 0, 108. 95-55 HsO*(aq) + CL (aq) ell oe Bhd HL fs 4 10,0ML 5 sid dlc Bi glall oe 514] Cay ISU pd 5450 Soo jon Jl! Gite, 00L came SYyle ns @ SIM pad gs IS Sy pl ae Byala jlo} 2245 Jy PH=10 63 he ile dla Ze — pH Il god « jail tl 6Cm 05S Chey AN cane le oe ply nll Jas w AN NB tell AEN LM ge leo A en cpio PUN Gs pee bai cas JAG US, S Jol8l op Vo= 10M ty Lae tol deal y Sb ale SAAN Bij pate 29 SON ened A oye GL IS Bl Bais S J lA 9 fe — pH toy SI) as Neer ab Uy lal J alee Zale th 1S fone J gle Solel lel Gs 9S lA PH a 22S PHN ol p55 ena PH =f (Va) mel Lik fey SOLD Spt 3 thet! ailll Ojai e LLNS af oUell Da pp ely SHALE Te odes PA ps2 pal LoS otal SoU 5S cl gee SHAS OAM 62 pal deny peel Ll 55 II ot @ Sod BSS pre O35 «SN SY bal AU La] YB Sos jbo IA 3 2 pall LS y rg) ALS a sll Ad) gf @| Sle De oe Lal) JUAN al gs Si asl atl fv © SLT SIE SAS MN 9 yey IY Lek chi SU a fle spl A ple Bice cons eel iy MEN allteines! pH>— /fogKe : os 13} act Jie o,Ss-l pK Adpaiah | alt HA da Ogle pH bs ll BYall SS i JS ge HA (ag) /A“(a9) tego jal Ode op Vee= 14,8 ML pb! Ls] tee ESI Je jaar perpall dS gba | 25°C PUstlajlaiey> | {ASS xb OY pull ix dad! OeUél Sihya,SII OLLI ST | A fgg SLs kas gil Boll Lely sally Stl) slr oy oke=pH+lonfale t ce ¥ is i i Indah Syby jl fl ts Soorl pl SLL } CH.CHOECOOH(aq) » _ CH:COOH(aq) I SEA Shit oder de pH OSI“ ge} (p 0=1,0.10-* mot.L* HF (aq) _3 CsHsCOOH(aq) (0) tea dahl | they pll dar dels cil3k Cy By A LEG de fans | ay sslysl dar yHCOOH the gil dar y CoH>COOH dndé 5 Ay lll g CoHsCOOH 4) gil dl PH Su wll ye Me yt JS oS els JSVTLLIT Bill pall A ne 34 .3,1 .2,1 :pH i 0,125 , 0,079 0,087 :t i pK a(CcHs COOHIC.HsCOO”) i pKa(HCOOH/HCOO”) = 3, 75 pK a(C2HsCOOH/C:HsCOO”) Ka tender dally 1 055 JHA dar OE Vi gar 5 pl rend Ce 85S 5 pdpall dS glad Ogle | Oil pl Ba6 ed bel yf ptall Jolis Dates SI _1 5 plall oda iS ye 2 | $ ESN se gts Say IID als 3. | 20 sys | Co 058 F(BH'IB in ya BiseU UEVe pr bale ins | Cass Ft yds JS ghar Syne | i bly Splall Jos Dole Sl _1 | N goals oe yo jal Apa (gS nb JOU All ela NH> SLi yl ole Bg ge a JF Wh ye I Uglied Co pS all dred adel perl gp OL alll pan 4] diy Vo= 20,0 mb. Fag a8 Fel SI dar Ogee Al ed Fahl wel thst Sey ol yp c1= 5.0.10 mol. 2,0 ML grat La} ue SSI las al aa 323 20; Clad daw bef 1 | PHY oil Sl 6 . co=3 mmol. =e PUI Bisel cone Nell ay)| fOsAI da gCsHsOHICsHs O” de 59 all arp ll sale f 1.0 [CFs OH] {25°C ue Jeli lia Uke GypAll ojlell aU iadoue—- | Ke=10"" < pKa(CsHsOH/CsH-O-)= 10,0: ant Few [oor re PH> pKat1 oy 2 ont eglladtyel | k=fe=10 _ HEI Be) [Ay | Geol dper ye oel tryst a ll eal e tel | ipKa= 8, 82 Selly 8 jell (HePOZ/HPOS Jolin ye | 7A pice pall PHOS 37°C slslirjeae | H.PO;] . pig Elta | = [HPO%=]=0,275 mot." gis 13} [HzPOs] asset _: IbCaHsOs Bis Ul dar 540,085 mol Jeli acy 3 | { pul ea JS | i Sb gM) ASU) gar ony Saves gill Jotésl Dales 1 : ; HPO; = Heop IS 5S Foe JS Jolla ol lid | 72 ct hy 5 maa pall DH ad ol 3 GE gS HPOF” | [HaPo; 0723 mol. -2 , 0,268 -1 ea | HPO? 085 mof.L*- i fy | de (laHA sd pl CoHiO. Ler SoMl dar Combi) | lsh Ss | algal Lia go ge 5 $C cll US yada 3 M= 176g. mol 2 tha SY aad Ill aS ae Ae Spam Ng chy Bley goal good Glall eda 5B | V=100,0mL dame SUye | biol Sanaty Va=10,0mL lgune ine SUdl ys Jot es ASS} i US yal ll BO ML 4 as ,19 mob .L- « [HaPOx] = | sgl gab Js ogy 5 LI1 ong sex DH | cB papell Ole Oley haya gan Oe od | HOOO"(aa) 9 sale yl -4 A SAN TA Nt hadi Vig gS et cot eh ele 0a oo JS de yl. C= 1,0.10-* mol.L* Tt ekg] 56 PH oi A aad gle tel A gis ge IS at fad S NH.CC aps 24 yy41F (NACE ayy > pat! gals «NAOH ap.3all dS yssua 7 _1 ried mM=0,78g « Co=5.10-* mof.L-! _3.2 Xen 1,0 mmol 1A gS Joust =0,1(1 3 [CHINHE) gem 8M Kee 9g [CHsNH3] Xe Kiq =I mmot (p= 108 ) pits 403% K=5,0.10" 44 gs Jou v= 13.4 2,0.10°* :demll 2.5 CHaNH:(S) ne adel lee ner) ened fe ye m aS ch O.10-* m0." 9555 apap deaS gyn Ogle | MLB) JS ww PHI iiy =f (Ve) nye Le 5 dla atell (Se ns Syl) thy So der Ly Jeli Dale GST 1 HO” apes gong BN gre Hales Ss BS SSI wi bel 2 j HEL sang Jae fetal ine 3 | SOgEl J NL thy So phar 5p emel 4- hill go 2d IS Stl Soll paar US gal 5 (ITB dea) BU et SI aa dls fone Jlseady —6 Spall oa 51M aH lll ASL gh AAI ne C= 2,8.10* mol.L*_4 +E (14mL; 8,2) _2:dryel m=0,499 2g & daneSe Dye de Jpanll 25°C sue ball lh eo wlall 55° V=500mL Henly la gly Vo= 50, OML gare dag So Ugly Je be 9 asda ISI pda Se ge step pH) old daly 3) [Hs0°],=1,0.107 mat." HL JS SI DH =F (Va) goed ae gp asl itl oS oe sq pl Biscb— ober Ned) 2p MEU nl: Soe gS