sn015 Titrations + Overview + Basic terms + Titration end point + End point indicators + End point detection + Equivalence point calculation + Titration curve calculation + Titration calculation * Back titration + Sample & titrant volume + Volumetric glassware + Volumetric glass cleaning + Glassware calibration + Standard substances * Sources of errors Fi ezencom Fundamentals of Analytical Chemistry by Douglas A, Skoog and others Complete list of books ipshwww tvalion infrback-raton Back tivation Titration » Back titration Sometimes it is not possible to use standard titration methods. For example the reaction between determined substance and titrant can be too slow, or there can be a problem with end point Balancer and stoichiometry calculator determination, operating systems: Windows 9x, 2000, In such situations we can often use a XP, Vista, 7 technique called back titration. In back titration we use two reagents - one, that reacts with the original sample (lets call it A), and second (lets call it B), that reacts with the first reagent. How do we proceed? We add precisely measured ‘amount of reagent A to sample and once the reaction ends we titrate excess reagent & left with reagent 8, Knowing Buy initial amount of reagent A and amount that was left after the reaction (from Now! titration) we can easily calculate how much reagent A was used for the first download 30-day reaction. free trial! 30-day money back guarantee! single user license price: €24,95 - approximately $33 1.435 g sample of dry CaCO and CaCl, mixture was dissolved in 25.00 mL of 0.9892 M HCI solution. What was CaCl, percentage in original sample, if 21.48 mL of 0.09312 M NaOH was used to titrate excess HCI? During titration 21.48%0.09312=2.000 mmole HCI was neutralized Initially there was 25.00x0.9892=24,73 mmole of HCI used, so during CaCO; dissolution 24.73-2,000=22.73 mmole of acid reacted. As calcium carbonate reacts with hydrochloric acid 1:2 (2 moles of acid per 1 mole of carbonate), original sample contained 22.73/2=11.37 mmole of CaCO3, or 1.137 g (assuming molar mass of CaCO; is 100.0 g). So original sample contained 1.137/1.435x100%=79.27% CaCO3 and 100.0- 72.27%=20.73% CaCl. Direct complexometric AI3+ determination is wesn015 ipshwww tvalion infrback-raton Back tivation difficult, as Al3*+ reacts with EDTA very slowly. To solution containing some unknown amount of Al>* cations 50.00 mL of 0.05000 M EDTA solution was added. After 30 minutes excess EDTA was titrated with 0.04875 M Zn2* solution. What was the amount of Al>* if 17.58 mL of titrant was used? EDTA reacts with both Al?* and Zn?* in 1:1 ratio. There was 50,00%0,05000=2,500 mmole of EDTA used, and 17.58x0,04875=0.8569 mmole was found to be left, Thus there was 2.500-0.8569=1.643 mmole of Al?* in the sample. {36 people Ike this. Be the fst of your frends. Page was last modified on July 19 2009, 10:31:43. 22