UNIVERSIDADNACIONALAUTNOMADEHONDURAS

FacultaddeIngeniera
DepartamentodeIngenieraQumica

CURVAS DE VALORACIN CIDO BASE

QQ-225 Qumica Analtica Cuantitativa I Periodo 2015

Profesor:Ing.JavierMadrid
Seccin:0701

PresentadoPor:
mbarA.Rodrguez

20111004665

HortenciaMaraMedina

20122302298

KennyEnriqueReyes

20123002243

KevinRolandoAndino

20131006620

ManuelArmandoRamos

20121000010

OscarEduardoPosadas

20111004628

WilmerEnriqueAguilar

20111012605

4DEMARZODE2015
TEGUCIGALPAM.D.C
Honduras

ValoracinBFAF
BF

Titulado

NaOH

AF

Titulante

HCl

VolumenTitulado(ml)

ValoracinBaseFuerteconcidoFuerte

N
14.00

0.1
0.01
0.001
0.1
0.01
0.001
50.0

12.00
10.00
8.00

pH

Reactivo

7.00
6.00

Inicio:

4.00

AntesEsteq.

2.00

Estequiomtrico

0.00
0.00

10.00

20.00

N=0.1

N=0.1

1
2
3
4
5
6

7
8

mlHCl
megNaOH
Gastado
sinneut.
0.00
5.00
10.00
4.00
25.00
2.50
35.00
1.50
49.00
0.10
50.00
0.00
megHCl
exceso
51.00
0.10
60.00
1.00

40.00

50.00

60.00

HClGastado(ml)

DespuesEsteq.

Pto

30.00

[OH]
1.00E01
6.67E02
3.33E02
1.76E02
1.01E03
1.00E07

N=0.01
pH
13.00
12.82
12.52
12.25
11.00
7.00

[H+]
9.90E04
9.09E03

N=0.01

3.00
2.04

megNaOH
sinneut.2
0.50
0.40
0.25
0.15
0.01
0.00
megHCl
exceso
0.01
0.10

[OH]2
1.00E02
6.67E03
3.33E03
1.76E03
1.01E04
1.00E07

N=0.001
pH2
12.00
11.82
11.52
11.25
10.00
7.00

[H+]
9.90E05
9.09E04

N=0.001

4.00
3.04

megNaOH
sinneut.3
0.05
0.04
0.03
0.02
0.00
0.00
megHCl
exceso
0.00
0.01

[OH]3
1.00E03
6.67E04
3.33E04
1.76E04
1.01E05
1.00E07

pH3
11.00
10.82
10.52
10.25
9.00
7.00

[H+]
9.90E06
9.09E05

5.00
4.04

70.00

ValoracinAFBF
BF

Titulante

NaOH

AF

Titulado

HCl

VolumenTitulado(ml)

ValoracincidoFuerteconBaseFuerte

N
0.1
0.01
0.001
0.1
0.01
0.001
50.0

14.00
12.00
10.00
8.00

pH

Reactivo

7.00
6.00

Inicio:

4.00

AntesEsteq.

2.00
0.00

Estequiomtrico

0.00

10.00

20.00

DespuesEsteq.
N=0.1

N=0.1
Pto
1
2
3
4
5
6

7
8

mlNaOH megHClsin
Gastado
neut.
0.00
5.00
10.00
4.00
25.00
2.50
35.00
1.50
49.00
0.10
50.00
0.00
megNaOH
exceso
51.00
0.10
60.00
1.00

30.00

40.00

50.00

60.00

NaOHGastado(ml)

[H+]
1.00E01
6.67E02
3.33E02
1.76E02
1.01E03
1.00E07

N=0.01
pH
1.00
1.18
1.48
1.75
3.00
7.00

[OH]
9.90E04
9.09E03

N=0.01

11.00
11.96

megHClsin
neut.2
0.50
0.40
0.25
0.15
0.01
0.00
megNaOH
exceso
0.01
0.10

[H+]2
1.00E02
6.67E03
3.33E03
1.76E03
1.01E04
1.00E07

N=0.001
pH2
2.00
2.18
2.48
2.75
4.00
7.00

[OH]
9.90E05
9.09E04

N=0.001

10.00
10.96

megHClsin
neut.3
0.05
0.04
0.03
0.02
0.00
0.00
megNaOH
exceso
0.00
0.01

[H+]3
1.00E03
6.67E04
3.33E04
1.76E04
1.01E05
1.00E07

pH3
3.00
3.18
3.48
3.75
5.00
7.00

[OH]
9.90E06
9.09E05

9.00
9.96

70.00

ValoracinBDAF
AF
BD

Reactivo
Kb
Titulante
HCl

Amonaco
1.80E05
Titulados
Etilamina
5.60E04
Quinolena
1.00E09
VolumenTitulado(ml)

ValoracinBaseDbilconcidoFuerte

N
0.1

14.00

0.1

12.00
10.00

50.0

8.00

pH

Inicio:

6.00

AntesPuntoEsteq.

6.02
5.28

4.00
3.15
2.00

Estequiomtrico
0.00
0.0

10.0

20.0

Amonaco

Pto
1
2
3
4
5
6
7
8

40.0

50.0

60.0

70.0

HClGastado(ml)

DespuesPuntoEsteq.

ValoracinBaseDbil0.1NconHCl0.1N
mlHCl
megB
megBOH
[B+]
Gastado
Aadido
sinneut.
formado
0.0
0.00
5.00
0.0000
10.0
1.00
4.00
0.0167
25.0
2.50
2.50
0.0333
35.0
3.50
1.50
0.0412
45.0
4.50
0.50
0.0474
50.0
5.00
0.00
0.0500
55.0
5.50
0.00
0.0048
60.0
6.00
0.00
0.0182

30.0

0.1000
0.0667
0.0333
0.0176
0.0053
0.0000
0.0000
0.0000

[OH]
1.34E03
7.20E05
1.80E05
7.71E06
2.00E06
1.90E09
2.10E12
5.50E13

Quinolena

Etilamina

Amonaco
[BOH]

Etilamina

pH
11.13
9.86
9.26
8.89
8.30
5.28
2.32
1.74

[OH]2
7.48E03
2.24E03
5.60E04
2.40E04
6.22E05
1.06E08
2.10E12
5.50E13

Quinolena

pH2
11.87
11.35
10.75
10.38
9.79
6.02
2.32
1.74

[OH]3
1.00E05
4.00E09
1.00E09
4.29E10
1.11E10
1.41E11
2.10E12
5.50E13

pH3
9.00
5.60
5.00
4.63
4.05
3.15
2.32
1.74

ValoracinADBF
BF
AD

Reactivo
Ka
Titulante
NaOH

Actico
1.80E05
Titulados
Brico
6.00E10
Fluorhdrico
2.40E04
VolumenTitulado(ml)

ValoracincidoDbilconBaseFuerte

N
0.1

14.00

0.1

12.00
10.96
10.00

50.0

8.72
8.16

8.00

pH

Inicio:

6.00

AntesPuntoEsteq.

4.00
2.00

Estequiomtrico
0.00
0.0

10.0

20.0

c.Actico

Pto
1
2
3
4
5
6
7
8

40.0

50.0

60.0

70.0

NaOHGastado(ml)

DespuesPuntoEsteq.

ValoracincidoDbil0.1NconNaOH0.1N
mlNaoH
megAc megHAcsin
[Ac]
Gastado
Aadido
neut.
formado
0.0
0.00
5.00
0.0000
10.0
1.00
4.00
0.0167
25.0
2.50
2.50
0.0333
35.0
3.50
1.50
0.0412
45.0
4.50
0.50
0.0474
50.0
5.00
0.00
0.0500
55.0
5.50
0.00
0.0048
60.0
6.00
0.00
0.0182

30.0

0.1000
0.0667
0.0333
0.0176
0.0053
0.0000
0.0000
0.0000

[H+]
1.34E03
7.20E05
1.80E05
7.71E06
2.00E06
1.90E09
2.10E12
5.50E13

c.Fluorhdrico

c.Brico

c.Actico
[HAc]

c.Brico

pH
2.87
4.14
4.74
5.11
5.70
8.72
11.68
12.26

[H+]2
7.75E06
2.40E09
6.00E10
2.57E10
6.67E11
1.10E11
2.10E12
5.50E13

c.Fluorhdrico

pH2
5.11
8.62
9.22
9.59
10.18
10.96
11.68
12.26

[H+]3
4.90E03
9.60E04
2.40E04
1.03E04
2.67E05
6.93E09
2.10E12
5.50E13

pH3
2.31
3.02
3.62
3.99
4.57
8.16
11.68
12.26