CL 459 - Design Project

Compound Phthalic Anhydride C6H4(CO)2O

Date - 19/02/2015
Group No. - 6
1) Yash Khemka (110020010)
2) Amit Bhadoriya (110020056)
3) Ajay Kumar (110020060)
4) Nachiket Kuntla (110020014)
5) Jaydeep Panchal (11D020010)

Reaction Path
Catalytic oxidation of o-xylene to phthalic anhydride

EVALUATION STAGE 2

Assumptions
Feed:
95% by weight o-xylene feed
Filtered air (approximately 23% oxygen and 77% nitrogen gas)
Sulphur dioxide (0.5-2.5% by weight of xylene)
Note:
Only o-xylene can form PAN
PAN plant production capacity is 90,000 metric tons per year
Weight ratio of air to xylenes is 25, equivalently 1 mole % xylene (<1.5)

Assumptions
Conversion in Reactor:
All are with respect to 1 kg of 95% o-xylene feed
1.01 kg of PAN (Theoretical max = 1.03)
0.08 kg of Maleic Anhydride
0.007 kg of Benzoic Acid
0.5 kg of Carbon Dioxide
0.15 kg of Carbon Monoxide
Mass balance will give you amount of Water produced
Data taken from literature, based on actual BASF plant operation

Assumptions
Purification in Pretreatment tank:
Exhaust from Tank contains (wrt input of same component)
0.5% of PAN - lost in exhaust
5% of Maleic Anhydride
100% of Water
Purification in Stripper:
Liquid output from bottom of Stripper contains (wrt input of same component)
99.5% of PAN - retained
5% of Maleic Anhydride

Assumptions
Purification in Rectifier:
Condensed Output from top of Rectifier contains (wrt input of same component)
99.9% of PAN - retained
Note:
All other particulate impurities are removed here
No Maleic Anhydride is lost in this stage
Final purity is 99.8% PAN (0.2% by weight of Maleic Anhydride)

Mass Balance-MANUAL
Compounds

Reactor Feed
(4)

Reactor
Product (5)

Input to
Condensor (6)

Sulphur Dioxide

421989.2

421989.2

Carbon Monoxide

Carbon Dioxide

Crude
Product (7)

Condensor
off-gas (8')

Scrubber
Feed (8)

421989.2

421989.2

421989.2

13561817.3

13561817.3

13561817.3

13561817.3

46834614.2

46834614.2

46834614.2

46834614.2

1743184193.1

1743184193.1

406138003.5

406138003.5

Nitrogen

1743611132

1743611132

1743611132

Oxygen

529702877.7

406138003.5

406138003.5

Phthalic Anhydride

93031913.4

93031913.4

90961567.5

2070345.9

2070345.9

90961567.5

Maleic Anhydride

7323554.6

7323554.6

3420463.8

3903090.8

3903090.8

3420463.8

Benzoic Acid

641027.6

641027.6

388576.6

252451.0

252451.0

388576.6

421989.2

421989.2

421989.2

o-Xylene

87845529.9

m- & p-Xylene

4140691.7

Particulate

426939.2

Pretreatment
Tank Feed (11)

426939.2

421989.2

Water

24710499.8

78446679.5

78446679.5

26999884.1

51446795.4

78446679.5

26999884.1

Total (kg/hr)

2390432721

2390432721

2390432721

122619420.4

2267813300

2294813184

122619420.4

Mass Balance
Compounds

Pretreament
Exhaust (12)

Pretreament
Crude (13)

Stripper
Feed (13)

Stripper waste
to Incinerator

Rectifier
Feed (16)

Rectifier waste to
Incinerator (19)

Refined
PAN (20)

90363.9

90000000

Sulphur Dioxide

Carbon Monoxide

Carbon Dioxide

Nitrogen

426939.2

Oxygen

Phthalic Anhydride

393526.6

90568040.9

90568040.9

477676.9

90090364.0

Maleic Anhydride

180675.7

3239788.1

3239788.1

3077798.7

161989.4

388576.57

388576.57

388576.57

421989.2

421989.2

94618394.8

94618394.8

Benzoic Acid

161989.4

o-Xylene

m- & p-Xylene

Particulate

Water

26999884.1

Total (kg/hr)

28001025.6

3944052.2

421989.2

421989.205

90674342.6

512327.07

90162016

ASPEN FLOWSHEET

DSTWU-RADFRAC COLUMN-DISTILL-1

DSTWU-RADFRAC COLUMN-DISTILL-1

TEMPERATURE V/S STAGE FOR DISTILL-1

TEMPERATURE V/S STAGE FOR DISTILL-2

VAPOUR COMPOSITION V/S STAGE FOR DISTILL-1

LIQUID COMPOSITION V/S STAGE FOR DISTILL-1

VAPOUR COMPOSITION V/S STAGE FOR DISTILL-2

LIQUID COMPOSITION V/S STAGE FOR DISTILL-2

Units
1
2
3
4
5
6
7
8
9
10
From
COMP1
HEATER1
MIX-1
REACT1
COOLER1
FLASH1
FLASH1
COOLER2
To
COMP1
HEATER1
MIX-1
MIX-1
REACT1
COOLER1
FLASH1
COOLER2
MIX-2
FLASH2
Substream: MIXED
Phase:
Vapor
Liquid
Vapor
Vapor
Vapor
Vapor
Vapor
Vapor
Liquid
Mixed
Component Mole Flow
WATER
KMOL/HR
0.00
0.00
0.00
0.00
0.00
347.09
347.09
345.50
1.59
345.50
O-XYL-01 KMOL/HR
0.00
99.17
0.00
99.17
99.17
0.00
0.00
0.00
0.00
0.00
OXYGE-01 KMOL/HR
471.06
0.00
471.06
0.00
471.06
0.00
0.00
0.00
0.00
0.00
CARBO-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
39.67
39.67
39.67
0.00
39.67
MALEI-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
9.92
9.92
8.53
1.39
8.53
PHTHA-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
69.42
69.42
20.37
49.05
20.37
CARBO-02 KMOL/HR
0.00
0.00
0.00
0.00
0.00
158.67
158.67
158.65
0.02
158.65
BENZE-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
NITRO-01 KMOL/HR
1884.22
0.00
1884.22
0.00
1884.22
1884.22
1884.22
1884.19
0.04
1884.19
M-XYL-01 KMOL/HR
0.00
2.61
0.00
2.61
2.61
2.61
2.61
2.58
0.03
2.58
P-XYL-01 KMOL/HR
0.00
2.61
0.00
2.61
2.61
2.61
2.61
2.58
0.03
2.58
TOLUE-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ETHYL-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
BENZO-01 KMOL/HR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
PHTHA-02 KMOL/HR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Mole FlowKMOL/HR
2355.28
104.39
2355.28
104.39
2459.67
2514.21
2514.21
2462.06
52.15
2462.06
Mass FlowKG/HR
67856.85
11082.72
67856.85
11082.72
78939.57
78939.57
78939.57
71501.79
7437.78
71501.79
Volume Flow
L/MIN
969062.00
210.52
563606.00
33388.57
641740.00
989624.00
731262.00
503410.00
105.14
646283.00
Temperature
C
24.85
24.85
141.17
300.00
178.73
380.00
210.00
170.00
170.00
110.00
Pressure BAR
1.00
1.00
2.40
2.40
2.40
2.30
2.30
3.00
3.00
2.00
Vapor Fraction
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.99
Liquid Fraction
0.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.01
Solid Fraction
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Molar Enthalpy
CAL/MOL
-2.97
-5621.38
810.75
16455.83
1474.74
-14109.88
-15623.74
-14537.10
-99871.09
-15166.74
Mass Enthalpy
CAL/GM
-0.10
-52.95
28.14
155.00
45.95
-449.40
-497.61
-500.56
-700.22
-522.25
Enthalpy Flow
CAL/SEC
-1942.27
-163000.00
530431.00
477169.00
1007600.00
-9854200.00
-10912000.00
-9942000.00
-1446700.00
-10373000.00
Molar Entropy
CAL/MOL-K
1.00
-106.80
1.58
-56.03
-0.43
3.89
1.21
0.63
-67.89
-0.09
Mass Entropy
CAL/GM-K
0.03
-1.01
0.05
-0.53
-0.01
0.12
0.04
0.02
-0.48
0.00
Molar Density
MOL/CC
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
Mass Density
GM/CC
0.00
0.88
0.00
0.01
0.00
0.00
0.00
0.00
1.18
0.00
Average Molecular Weight 28.81
106.17
28.81
106.17
32.09
31.40
31.40
29.04
142.63
29.04

Units
11
From
FLASH2
To
MIX-2
Substream: MIXED
Phase:
Liquid
Component Mole Flow
WATER
KMOL/HR
2.00
O-XYL-01 KMOL/HR
0.00
OXYGE-01 KMOL/HR
0.00
CARBO-01 KMOL/HR
0.00
MALEI-01 KMOL/HR
3.08
PHTHA-01 KMOL/HR
19.26
CARBO-02 KMOL/HR
0.01
BENZE-01 KMOL/HR
0.00
NITRO-01 KMOL/HR
0.01
M-XYL-01 KMOL/HR
0.03
P-XYL-01 KMOL/HR
0.03
TOLUE-01 KMOL/HR
0.00
ETHYL-01 KMOL/HR
0.00
BENZO-01 KMOL/HR
0.00
PHTHA-02 KMOL/HR
0.00
Mole FlowKMOL/HR
24.42
Mass FlowKG/HR
3197.71
Volume Flow
L/MIN
43.01
Temperature
C
110.00
Pressure BAR
2.00
Vapor Fraction
0.00
Liquid Fraction
1.00
Solid Fraction
0.00
Molar Enthalpy
CAL/MOL ########
Mass Enthalpy
CAL/GM
-772.32
Enthalpy Flow
CAL/SEC
########
Molar Entropy
CAL/MOL-K
-70.29
Mass Entropy
CAL/GM-K
-0.54
Molar Density
MOL/CC
0.01
Mass Density
GM/CC
1.24
Average Molecular Weight
130.95

12
13
14
FLASH2
MIX-2
HEATER2 DIST1
HEATER2 DIST1
Vapor

Mixed

Mixed

Vapor

15

18

19

20

21

DIST1

DIST1
DIST2

DIST2

DIST2

Liquid

Liquid

Liquid

Liquid

343.50
3.60
3.60
3.53
0.07
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
39.67
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.45
4.47
4.47
2.41
1.46
0.60
0.54
0.06
1.11
68.31
68.31
0.00
0.00
68.31
2.00
66.30
158.64
0.03
0.03
0.03
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1884.18
0.04
0.04
0.04
0.00
0.00
0.00
0.00
2.55
0.06
0.06
0.06
0.00
0.00
0.00
0.00
2.55
0.05
0.05
0.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2437.64
76.57
76.57
6.13
1.53
68.91
2.55
66.36
68304.08 10635.49 10635.49
314.35
144.43 10176.71
350.39
9826.32
########
155.14
172.77
3753.70
2.04
160.47
5.23
150.73
110.00
151.96
190.00
174.02
174.02
279.76
221.81
255.02
2.00
2.00
2.00
1.00
1.00
1.00
0.50
0.50
1.00
0.00
0.00
1.00
0.00
0.00
0.00
0.00
0.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-14305.55 ######## -98202.98 -68500.90 ######## -94485.42 -98687.45 -96057.55
-510.54
-721.90
-706.99
-1334.79
-1076.15
-639.80
-718.13
-648.72
######## ######## ######## ######## -43174.96 ######## -69895.76 ########
0.61
-68.49
-63.83
-12.44
-48.09
-56.61
-58.54
-59.79
0.02
-0.49
-0.46
-0.24
-0.51
-0.38
-0.43
-0.40
0.00
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.00
1.14
1.03
0.00
1.18
1.06
1.12
1.09
28.02
138.90
138.90
51.32
94.32
147.68
137.42
148.07

MOLAR FLOW RATE V/S TEMPERATURE

FLASH-1
MAL-V

PTH-L

70

MOLAR FLOW RATE

60
50
40
30
20
10
0
0

50

100

150
TEMPERATURE(C)

200

250

MOLAR FLOW RATE V/S TEMPERATURE

Flash-2
25

Molar Flow

20

15

MAL-V
PTH-L

10

0
0

20

40

60

80

Temperature

100

120

140

SENSITIVITY W.R.T PRESSURE DISTILL-1

Row/Case
Status
VARY 1
DIST1

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

stream 18
MAVAP

PAVAP

stream 19
MALIQ
PALIQ

stream15
MAVAP1 PAVAP1

1
P-SPEC PRES
BAR
KMOL/HR
KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR
0.2
1.49165342 1.39E-14
0.60483 68.30635 2.375104 1.23E-15
0.328571429
1.48330447 7.68E-14 0.604829 68.30635 2.383453 7.86E-15
0.457142857
1.47679637 2.48E-13 0.604829 68.30635 2.389961 2.80E-14
0.585714286
1.47133548 6.10E-13 0.604829 68.30635 2.395422 7.43E-14
0.714285714
1.46656806 1.27E-12 0.604829 68.30635
2.40019 1.65E-13
0.842857143
1.4623006 2.38E-12 0.604829 68.30635 2.404457 3.24E-13
0.971428571
1.45841412 4.10E-12 0.604829 68.30635 2.408344 5.84E-13
1
1.45759105 4.59E-12 0.604829 68.30635 2.409167 6.60E-13
1.1
1.45482964 6.64E-12 0.604828 68.30635 2.411929 9.86E-13
1.22857143
1.45149163 1.03E-11 0.604828 68.30635 2.415267 1.58E-12
1.35714286
1.4483597 1.53E-11 0.604827 68.30635
2.4184 2.43E-12
1.48571429
1.44540227 2.21E-11 0.604827 68.30635 2.421358 3.61E-12
1.61428571
1.44259599 3.10E-11 0.604826 68.30635 2.424165 5.22E-12
1.74285714
1.43992158 4.27E-11 0.604826 68.30635
2.42684 7.36E-12
1.87142857
1.4373634 5.76E-11 0.604825 68.30635 2.429399 1.02E-11
2
1.4349087 7.64E-11 0.604824 68.30635 2.431854 1.38E-11

SENSITIVITY W.R.T PRESSURE DISTILL-1

SENSITIVITY W.R.T REFLUX RATIO DISTILL-1

Row/Case Status
VARY 1
DIST1
COL-SPEC
MOLE-RR
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

0.2
0.614286
1.028571
1.442857
1.779
1.857143
2.271429
2.685714
3.1
3.514286
3.928571
4.342857
4.757143
5.171429
5.585714
6

stream18
MAVAP
PAVAP

stream 19
MALIQ
PALIQ

stream15
MAVAP1 PAVAP1

KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR

0.748687 0.732838 1.527923 67.38325 2.194976 0.190264
1.375287
0.08544 0.703049 68.20813
2.39325 0.012783
1.457591 6.76E-11 0.604827 68.30635 2.409168 9.74E-12
1.457593 1.07E-11 0.604828 68.30635 2.409165 1.55E-12
1.457593 4.58E-12 0.604829 68.30635 2.409165 6.59E-13
1.457593 3.92E-12 0.604829 68.30635 2.409165 5.64E-13
1.457593 2.01E-12 0.604829 68.30635 2.409165 2.90E-13
1.457593 1.24E-12 0.604829 68.30635 2.409165 1.78E-13
1.457593 8.47E-13 0.604829 68.30635 2.409164 1.22E-13
1.457593 6.24E-13 0.604829 68.30635 2.409164 8.98E-14
1.457593 4.83E-13 0.604829 68.30635 2.409164 6.96E-14
1.457593 3.89E-13 0.604829 68.30635 2.409164 5.59E-14
1.457593 3.22E-13 0.604829 68.30635 2.409164 4.63E-14
1.457593 2.72E-13 0.604829 68.30635 2.409164 3.92E-14
1.457593 2.35E-13 0.604829 68.30635 2.409164 3.38E-14
1.457593 2.05E-13 0.604829 68.30635 2.409164 2.95E-14

SENSITIVITY W.R.T REFLUX RATIO DISTILL-1

SENSITIVITY W.R.T FEED STAGE DISTILL-1

Row/Case Status

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

Stream18
PAVAP
MAVAP

Stream19
PALIQ
MALIQ

stream 15
MAVAP1 PAVAP1

VARY 1
DIST1
14
FEEDS STAGE
KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR
2.31754 0.077593
2 1.056122 0.415502 1.097925 67.81325
3 1.375441 0.085281 0.702869 68.20831 2.393277 0.012759
4 1.445206 0.012868 0.619559 68.29162 2.406822 0.001862
5 1.455911 0.001747 0.606829 68.30435 2.408847 0.000252
3.35E-05
6 1.457371 0.000233 0.605096 68.30608 2.409121
4.44E-06
3.08E-05 0.604865 68.30631 2.409158
7 1.457564
5.88E-07
4.08E-06 0.604834 68.30634 2.409163
8 1.457589
7.79E-08
0.60483 68.30635 2.409164
5.41E-07
9 1.457593
1.04E-08
0.60483 68.30635 2.409164
7.20E-08
10 1.457593
1.38E-09
0.60483 68.30635 2.409164
9.61E-09
11 1.457593
1.87E-10
0.60483 68.30635 2.409164
1.30E-09
12 1.457593
2.60E-11
0.60483 68.30635 2.409164
1.81E-10
13 1.457593
3.86E-12
2.68E-11 0.604829 68.30635 2.409164
14 1.457593
6.59E-13
4.58E-12 0.604829 68.30635 2.409165
15 1.457593
1.48E-13
1.03E-12 0.604822 68.30635 2.409172
16 1.457593
5.94E-14
4.13E-13 0.604759 68.30635 2.409233
17 1.457596
18 1.421642 0.037375 0.646849 68.26351 2.403095 0.005468
19 1.060632 0.411247 1.080893 67.81816 2.330061 0.076947

SENSITIVITY W.R.T FEED STAGE DISTILL-1

SENSITIVITY W.R.T THEORETICAL STAGES DISTILL-1

Row/Case Status
VARY 1
DIST1
PARAM
NSTAGE
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

Stream18
MAVAP
PAVAP

Stream19
MALIQ
PALIQ

stream 15
MAVAP1 PAVAP1

KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR

0.366795
1.13125 2.147829 66.55261 1.956963 0.622487
0.438994
1.05673 1.953396 66.75027 2.079196
0.49935
0.456787 1.038371 1.910106 66.79414 2.104693 0.473836
0.459985 1.035086 1.902419 66.80192 2.109183 0.469343
0.460625 1.034394
1.90108 66.80329 2.109882 0.468666
0.460682 1.034353 1.900843 66.80353 2.110062 0.468469
0.460695
1.03434 1.900813 66.80356 2.110079 0.468453
0.460697 1.034337 1.900806 66.80356 2.110083 0.468448
0.460698 1.034336 1.900804 66.80357 2.110085 0.468446
0.460698 1.034337 1.900804 66.80357 2.110085 0.468447
0.460698 1.034337 1.900804 66.80357 2.110085 0.468447
0.460698 1.034336 1.900804 66.80357 2.110085 0.468446
0.460698 1.034337 1.900804 66.80357 2.110085 0.468447
1.060493 0.411366 1.081062 67.81799 2.330032 0.076996
1.421638 0.037379 0.646854
68.2635 2.403095 0.005469
1.457596 2.36E-11 0.604759 68.30635 2.409233 3.39E-12
1.457593 7.78E-12 0.604822 68.30635 2.409172 1.12E-12
1.457593 4.58E-12 0.604829 68.30635 2.409165 6.60E-13

SENSITIVITY W.R.T THEORETICAL STAGES DISTILL-1

SENSITIVITY W.R.T REFLUX RATIO DISTILL-2

Row/Case Status

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

Reflux ratio variation

VARY 1 PTHIN
MALIN
MALD
DIST2
COL-SPEC
MOLE-RR
KMOL/HR KMOL/HR KMOL/HR
2 68.30635 0.604829 0.261921
2.928571 68.30635 0.604829 0.341472
3.857143 68.30635 0.604829 0.421331
4.785714 68.30635 0.604829 0.499026
5.43 68.30635 0.604829 0.544676
5.714286 68.30635 0.604829 0.560422
6.642857 68.30635 0.604829 0.590454
7.571429 68.30635 0.604829 0.600299
8.5 68.30635 0.604829 0.603266
9.428571 68.30635 0.604829 0.604225
10.35714 68.30635 0.604829
0.60457
11.28571 68.30635 0.604829 0.604707
12.21429 68.30635 0.604829 0.604767
13.14286 68.30635 0.604829 0.604795
14.07143 68.30635 0.604829 0.604809
15 68.30635 0.604829 0.604817

PTHD

PTHB

MALB

KMOL/HR
2.287792
2.20824
2.128382
2.050687
2.005036
1.98929
1.959259
1.949413
1.946447
1.945488
1.945143
1.945006
1.944946
1.944917
1.944903
1.944896

KMOL/HR
66.01856
66.09811
66.17797
66.25566
66.30131
66.31706
6.63E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01
6.64E+01

KMOL/HR
0.342907
0.263356
0.183498
0.105803
0.060152
0.044406
0.014375
0.004529
0.001562
0.000604
0.000259
0.000122
6.17E-05
3.34E-05
1.91E-05
1.15E-05

PTHB/(MA
LB+PTHB)

0.994832734
0.99603149
0.997234872
0.998405656
0.999093567
0.999330842
0.999783388
0.999931749
0.999976455
0.999990904
0.999996098
0.999998168
0.99999907
0.999999496
0.999999712
0.999999826

SENSITIVITY W.R.T REFLUX RATIO DISTILL-2

SENSITIVITY W.R.T FEED STAGE DISTILL-2

Row/Case Status

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

FEEDS STAGE Vary

VARY 1 PTHIN
MALIN
MALD
PTHD
PTHB
MALB
PTHB/(MA
DIST2
LB+PTHB)
19
FEEDS STAGE
KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR KMOL/HR
5 68.30635 0.604829 0.555713 1.993999 6.63E+01 0.049115
6 68.30635 0.604829 0.556206 1.993507 66.31284 0.048623
7 68.30635 0.604829 0.556193
1.99352 66.31283 0.048636
8 68.30635 0.604829 0.556101 1.993611 66.31274 0.048727
9 68.30635 0.604829
0.55598 1.993733 66.31262 0.048849
10 68.30635 0.604829 0.555842 1.993871 66.31248 0.048987
11 68.30635 0.604829 0.555677 1.994036 66.31231 0.049152
12 68.30635 0.604829 0.555478 1.994235 66.31211
0.04935
13 68.30635 0.604829 0.555242
1.99447 66.31188 0.049586
14 68.30635 0.604829 0.554963 1.994749
66.3116 0.049865
15 68.30635 0.604829 0.554634 1.995079 66.31127 0.050195
16 68.30635 0.604829 0.554243
1.99547 66.31088 0.050586
17 68.30635 0.604829
0.55378 1.995933 66.31042 0.051049
18 68.30635 0.604829 0.553229 1.996483 66.30987 0.051599
19 68.30635 0.604829 0.552576 1.997136 66.30921 0.052252
20 68.30635 0.604829 0.551796 1.997917 66.30843 0.053033
21 68.30635 0.604829 0.550866 1.998847
66.3075 0.053963
22 68.30635 0.604829 0.549747 1.999966 66.30638 0.055082
23 68.30635 0.604829 0.548402 2.001311 66.30504 0.056427
24 68.30635 0.604829 0.546766 2.002946
66.3034 0.058062
25 68.30635 0.604829 0.544775 2.004938 66.30141 0.060054
26 68.30635 0.604829 0.542312 2.007401 66.29895 0.062517
27 68.30635 0.604829 0.539248 2.010465 66.29588
0.06558
28 68.30635 0.604829 0.535356 2.014357 66.29199 0.069473
29 68.30635 0.604829 0.530341 2.019371 66.28698 0.074487
30 68.30635 0.604829
0.52359 2.026123 66.28023 0.081239
31 68.30635 0.604829 0.514429 2.035284 66.27107
0.0904
32 68.30635 0.604829
0.50125 2.048463 66.25789 0.103579

MALD/MAL
IN

0.999259883
0.999267304
0.999267105
0.99926573
0.999263902
0.999261818
0.999259331
0.999256338
0.999252785
0.999248584
0.999243617
0.999237721
0.99923075
0.999222452
0.999212613
0.999200852
0.999186836
0.999169972
0.999149706
0.999125063
0.999095051
0.999057939
0.999011769
0.998953112
0.99887755
0.998775814
0.998637767
0.998439169

0.918794788
0.919608937
0.919587193
0.919436271
0.919235643
0.919007062
0.918734207
0.9184058
0.918015993
0.917555023
0.917010037
0.916363151
0.915598306
0.914687814
0.913608278
0.91231789
0.910780097
0.908929779
0.906706199
0.904002367
0.900709445
0.896637583
0.891571803
0.885136007
0.876845429
0.865682974
0.850536491
0.828746492

SENSITIVITY W.R.T FEED STAGE DISTILL-2

SENSITIVITY W.R.T THEORETICAL STAGES DISTILL-2

Row/Case

Status
VARY 1
DIST2
PARAM
NSTAGE
1 OK
2 OK
3 OK
4 OK
5 OK
6 OK
7 OK
8 OK
9 OK
10 OK
11 OK
12 OK
13 OK
14 OK
15 OK
16 OK
17 OK
18 OK
19 OK
20 OK
21 OK
22 OK
23 OK
24 OK
25 OK
26 OK

PTHIN

10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35

MALIN

No of theo stages
MALD

PTHD

PTHB

MALB

KMOL/HR
KMOL/HR
KMOL/HR
KMOL/HR
KMOL/HR
KMOL/HR
68.30635
0.604829
0.371011
2.178702
66.12765
0.233818
68.30635
0.604829
0.370987
2.178726
66.12762
0.233842
68.30635
0.604829
0.370992
2.17872
66.12763
0.233836
68.30635
0.604829
0.370991
2.178722
66.12763
0.233838
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178721
66.12763
0.233837
68.30635
0.604829
0.370991
2.178721
66.12763
0.233837
68.30635
0.604829
0.370991
2.178721
66.12763
0.233837
68.30635
0.604829
0.370991
2.178721
66.12763
0.233837
68.30635
0.604829
0.370991
2.178721
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.370991
2.178722
66.12763
0.233837
68.30635
0.604829
0.445639
2.104073
66.20228
0.159189
68.30635
0.604829
0.480881
2.068831
66.23752
0.123947
68.30635
0.604829
0.5013
2.048412
66.25794
0.103528
68.30635
0.604829
0.514471
2.035242
66.27111
0.090358
68.30635
0.604829
0.523624
2.026088
66.28026
0.081204
68.30635
0.604829
0.530287
2.019425
66.28692
0.074541
68.30635
0.604829
0.535318
2.014394
66.29195
0.06951
68.30635
0.604829
0.539128
2.010585
66.29576
0.065701
68.30635
0.604829
0.542218
2.007495
66.29885
0.06261
68.30635
0.604829
0.544694
2.005019
66.30133
0.060135

PTHB/(MA
LB+PTHB)

MALD/MAL
IN

0.996476604
0.99647624
0.996476328
0.996476303
0.996476307
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.996476308
0.997601182
0.998132239
0.998439935
0.998638398
0.998776334
0.998876737
0.99895255
0.999009954
0.999056524
0.999093833

0.61341492
0.61337491
0.613384538
0.613381794
0.613382286
0.613382428
0.613382427
0.613382398
0.613382399
0.613382401
0.613382384
0.61338237
0.613382358
0.613382345
0.613382331
0.613382317
0.736802978
0.795070304
0.828830554
0.850605785
0.865740034
0.876756146
0.885074291
0.89137269
0.89648226
0.900575849

SENSITIVITY W.R.T THEORETICAL STAGES DISTILL-2

THANK YOU