MaRS Enviro Research & Engineering Services Privat

F/CEMCHEM/01,Issue No.1
GRAVEMETRIC METHOD (IS :4032-1985, Reaffirmed 20

Sample ID :- 1
Sr. No.

Parameters

Test Start
Date

Test End Weight(W)

Initial
Final
Date
of
Weight(W1) Weight(W2)
Sample of Crucible (g) of Crucible
(g)
After Ignition
(g)

Loss on
Ignition

1.0

Silica
Cao
Mgo
Insoluble
Residue

0.5
0.5
0.5
1.0

Sulphuric
Anhydride

1.0

35.5958

35.6076

30.9305
35.5958
35.5958

31.0319
35.9068
35.6136

30.9305

30.9488

32.4032

32.4586

TITRIMETRIC METHOD(IS :4032-1985, Reaffirmed 200

Sr. No.

Parameters

Test Start
Date

Test End Weight(W) Titrant(V)

Date
of
(ml)
Sample
(g)

Formula

Ferric Oxide
1

Aluminium
Oxide
Chloride

Tested By:-

(0.7985*V)/W
0.5

2.3

0.5
2

7.2
1.4

(V3*E)];

V1= Total EDTA

(Z*0.03546*0.025*100)/Mass
of Sample;

MaRS Enviro Research & Engineering Services Privat

F/CEMCHEM/01,Issue No.1
GRAVEMETRIC METHOD (IS :4032-1985, Reaffirmed 20

Sample ID :- 2

Sr. No.

Parameters

Test Start
Date

Test End Weight(W)

Initial
Final
Date
of
Weight(W1) Weight(W2)
Sample of Crucible (g) of Crucible
(g)
After Ignition
(g)

Loss on
Ignition

1.0

Silica
Cao
Mgo
Insoluble
Residue

0.5
0.5
0.5
1.0

Sulphuric
Anhydride

1.0

30.9305

30.9416

32.4066
30.9305
30.9305

32.5063
31.2413
30.9522

32.4076

32.4262

30.9115

30.9675

TITRIMETRIC METHOD(IS :4032-1985, Reaffirmed 200

Sr. No.

Parameters

Test Start
Date

Test End Weight(W) Titrant(V)

Date
of
(ml)
Sample
(g)

Formula

Ferric Oxide
1

(0.7985*V)/W

Aluminium
Oxide
Chloride

0.5

2.35

0.5
2

7.28
1.4

Tested By:-

(V3*E)];

V1= Total EDTA

(Z*0.03546*0.025*100)/Mass
of Sample;

MaRS Enviro Research & Engineering Services Privat

F/CEMCHEM/01,Issue No.1
GRAVEMETRIC METHOD (IS :4032-1985, Reaffirmed 20

Sample ID :- 3
Sr. No.

Parameters

Loss on
Ignition

Test Start
Date

Test End Weight(W)

Initial
Final
Date
of
Weight(W1) Weight(W2)
Sample of Crucible (g) of Crucible
(g)
After Ignition
(g)
1.0

32.4076

35.6076

Silica
Cao
Mgo
Insoluble
Residue

0.5
0.5
0.5
1.0

Sulphuric
Anhydride

1.0

30.9115
32.4076
32.4076

31.0129
32.7182
32.4292

32.4032

32.4216

32.4032

32.4563

TITRIMETRIC METHOD(IS :4032-1985, Reaffirmed 200

Sr. No.

Parameters

Test Start
Date

Test End Weight(W) Titrant(V)

Date
of
(ml)
Sample
(g)

Formula

Ferric Oxide
1

(0.7985*V)/W

Aluminium
Oxide
Chloride

0.5

2.35

0.5
2

7.08
1.4

Tested By:-

(V3*E)];

V1= Total EDTA

(Z*0.03546*0.025*100)/Mass
of Sample;

MaRS Enviro Research & Engineering Services Privat

F/CEMCHEM/01,Issue No.1
GRAVEMETRIC METHOD (IS :4032-1985, Reaffirmed 20

Sample ID :- 4
Sr. No.

Parameters

Test Start
Date

Test End Weight(W)

Initial
Final
Date
of
Weight(W1) Weight(W2)
Sample of Crucible (g) of Crucible
(g)
After Ignition
(g)

Loss on
Ignition

1.0

Silica
R2o3
Cao
Mgo

0.5
0.5
0.5
0.5

30.9374

30.9041

32.3935
30.9358
32.3969
30.9399

32.4922
30.9816
32.698
30.9841

Insoluble
Residue

1.0

Sulphuric
Anhydride

1.0

32.3985

32.4035

33.4073

33.4811

TITRIMETRIC METHOD(IS :4032-1985, Reaffirmed 200

Sr. No.

Parameters

Test Start
Date

Test End Weight(W) Titrant(V)

Date
of
(ml)
Sample
(g)

Formula

Ferric Oxide

(0.7985*V)/W
0.5

Aluminium
Oxide
Chloride
na
k

Tested By:-

2.60

(0.5098*V)/W

[V=V1-V2
(V3*E)];

0.5
2

0.4

V1= Total EDTA

volume;V2= EDTA used for iron;V3= Volume o
bismuth nitrate;e= equivalence of 1 ml
(Z*0.03546*0.025*100)/Mass
bismuth nitrate solution (0.08)

of Sample;

Services Private Limited

No.1
85, Reaffirmed 2009)
Formula

Calculation

Result
(%)

Loss in
Weight*100

1.18

Weight of Residue*200
Weight of Residue*200
Weight of Residue*72.4
Weight of
residue*100/W
eight of
sample

20.29
62.20
1.29
1.83

Weight of Residue*34.3

1.90

5, Reaffirmed 2009)
Formula

Calculation

Result

(0.7985*V)/W
3.67
[V=V1-V2-

7.34
0.06

V1= Total EDTA

.03546*0.025*100)/Mass
ample;
Z=[10-

Checked By:-

Services Private Limited

No.1
85, Reaffirmed 2009)

Formula

Calculation

Result
(%)

Loss in
Weight*100

1.11

Weight of Residue*200
Weight of Residue*200
Weight of Residue*72.4
Weight of
residue*100/W
eight of
sample

19.94
62.16
1.57
1.86

Weight of Residue*34.3

1.92

5, Reaffirmed 2009)
Formula

Calculation

Result

(0.7985*V)/W
3.75
[V=V1-V2-

7.42
0.06

V1= Total EDTA

.03546*0.025*100)/Mass
ample;
Z=[10-

Checked By:-

Services Private Limited

No.1
85, Reaffirmed 2009)
Formula

Loss in
Weight*100

Calculation

Result
(%)

1.11

Weight of Residue*200
Weight of Residue*200
Weight of Residue*72.4
Weight of
residue*100/W
eight of
sample

19.94
62.12
1.56
1.84

Weight of Residue*34.3

1.82

5, Reaffirmed 2009)
Formula

Calculation

Result

(0.7985*V)/W
3.75
[V=V1-V2-

7.22
0.06

V1= Total EDTA

.03546*0.025*100)/Mass
ample;
Z=[10-

Checked By:-

Services Private Limited

No.1
85, Reaffirmed 2009)
Formula

Calculation

Loss in
Weight*100
Weight of Residue*200
Weight of Residue*200
Weight of Residue*72.4

Result
(%)

3.33
19.74
9.16
60.22
3.20

Weight of
residue*100/W
eight of
sample

0.50

Weight of Residue*34.3

2.53

5, Reaffirmed 2009)
Formula

Calculation

Result

(0.7985*V)/W
4.15

98*V)/W
[V=V1-V2-

V1= Total EDTA

V2= EDTA used for iron;V3= Volume of
muth nitrate;e= equivalence of 1 ml
.03546*0.025*100)/Mass
bismuth nitrate solution (0.08)
ample;
Z=[10-

subtractionof
fe2o3 from r2o3

5.01
0.017
0.22
0.46

Checked By:-

Na2O result

total sum

wt difference

3.33
19.74
9.16
60.22
3.20

multiplying
factor

0.0333
0.0987
0.0458
0.3011
0.0442

100
200
200
200
72.4

0.50

0.0050

100

2.53

0.0738

34.3

0.02

0.22
0.46

99.38
A/F RATIO
1.2072289157
LSF

CaO - 0.7*so3
2.8*sio2+1.2al2o3+0.65fe2o3

na

meter reading* 100*100/10^6*wt. of sample

result *10^6*wt of sample/10^4

58.449
63.9815

Result

3.33
19.74
9.16
60.22
3.20

0.5
2.53

Result of lsf
0.9135296922