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TABLE 2 Composition of Reaction Mixture 2

Sample 1
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
60
240
420
600
780
960
1140
1320
1500
1680
1860
2040
2220
2430
2580
2760
2940
3120
3300
3510
3660
3840
4020
4200

40
2.0
2.5
0.5

Absorbance
0.372
0.357
0.345
0.333
0.324
0.313
0.304
0.295
0.286
0.277
0.269
0.26
0.253
0.244
0.237
0.23
0.223
0.216
0.209
0.202
0.197
0.191
0.184
0.179

313.15 Kelvin

Time
60
240
420
600
780
960
1140
1320
1500
1680
1860
2040
2220
2430
2580
2760
2940
3120
3300
3510
3660
3840
4020
4200

Abs
4.0E-01

ln(absorbance) Slope
Time
-0.9888614247 -0.0001740253
-1.0300194972
-1.064210862
-1.099612789
-1.1270117632
-1.1615520884
-1.1907275776
-1.2207799226
-1.2517634682
-1.2837377728
-1.3130438994
-1.347073648
-1.3743657903
-1.4105870537
-1.4396951378
-1.4696759701
-1.5005835075
-1.5324768713
-1.565421027
-1.5994875816
-1.6245515502
-1.6554818509
-1.6928195214
-1.7203694731

1/(absorbance)
60
240
420
600
780
960
1140
1320
1500
1680
1860
2040
2220
2430
2580
2760
2940
3120
3300
3510
3660
3840
4020
4200

2.688172043
2.8011204482
2.8985507246
3.003003003
3.0864197531
3.1948881789
3.2894736842
3.3898305085
3.4965034965
3.6101083032
3.717472119
3.8461538462
3.95256917
4.0983606557
4.2194092827
4.347826087
4.4843049327
4.6296296296
4.7846889952
4.9504950495
5.076142132
5.2356020942
5.4347826087
5.5865921788

f
R

3.0E-01
2.0E-01

Absorbance

1.0E-01
0.0E+00
0

ln(ab

0.0E+00

-5.0E-01
ln(absorbance)

-1.0E+00

-1.5E+00

-2.0E+00

1/(ab
6.0E+00
5.0E+00
4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00

1/(ab
6.0E+00
5.0E+00
4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00

Absorbance vs. Time


4.0E-01
f(x) = - 4.53105489060825E-005x + 0.3591247455
R = 0.989159552

3.0E-01
2.0E-01

Absorbance

1.0E-01
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000 4500

Time (seconds)

ln(absorbance) vs. Time


0.0E+00
0

500 1000 1500 2000 2500 3000 3500 4000 4500

-5.0E-01
ln(absorbance)

-1.0E+00
-1.5E+00

f(x) = - 0.0001740253x - 0.9898872347


R = 0.9997886364

-2.0E+00

Time (seconds)

1/(absorbance) vs. Time


6.0E+00
5.0E+00
4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00

f(x) = 0.0006876632x + 2.5261457274


R = 0.9910975231

1/(absorbance) vs. Time


6.0E+00
5.0E+00

f(x) = 0.0006876632x + 2.5261457274


R = 0.9910975231

4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00
0

500 1000 1500 2000 2500 3000 3500 4000 4500

Time (seconds)

Sample 2
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

45
2.0
2.5
0.5

Absorbance
0.257
0.241
0.23
0.2
0.212
0.206
0.2
0.194
0.188
0.184
0.179
0.173
0.168
0.163
0.158
0.155
0.152
0.148
0.146
0.143
0.14
0.137
0.133
0.13
0.127
0.124
0.12
0.117
0.115
0.113
0.111

318.15 Kelvin

Time
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

ln(absorbance) Slope
Time
-1.3586791941 -0.00021224
-1.4229583455
-1.4696759701
-1.6094379124
-1.5511690043
-1.5798791102
-1.6094379124
-1.6398971199
-1.6713133162
-1.6928195214
-1.7203694731
-1.7544636845
-1.7837912996
-1.8140050782
-1.845160246
-1.8643301621
-1.8838747581
-1.9105430052
-1.9241486573
-1.9449106487
-1.9661128564
-1.9877743532
-2.0174061508
-2.0402208285
-2.0635681925
-2.0874737134
-2.1202635362
-2.1455813442
-2.1628231506
-2.1803674603
-2.1982250777

1/(absorbance)
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

3.8910505837
4.1493775934
4.347826087
5
4.7169811321
4.854368932
5
5.1546391753
5.3191489362
5.4347826087
5.5865921788
5.7803468208
5.9523809524
6.1349693252
6.3291139241
6.4516129032
6.5789473684
6.7567567568
6.8493150685
6.993006993
7.1428571429
7.299270073
7.5187969925
7.6923076923
7.874015748
8.064516129
8.3333333333
8.547008547
8.6956521739
8.8495575221
9.009009009

3.0E-01

2.5E-01

2.0E-01

1.5E-01

Absorbance

1.0E-01

5.0E-02

0.0E+00

ln(a

0.0E

-5.0
ln(absorbance)

-1.0E

-1.5E

-2.0E

-2.5E

1/(a

1.0E+

8.0E+

6.0E+

1/(a

1.0E+

8.0E+

6.0E+
1/(absorbance)

4.0E+

2.0E+

0.0E+

Absorbance vs. Time


3.0E-01
2.5E-01
2.0E-01

f(x) = - 3.50511512165695E-005x + 0.2302460034


R = 0.9578160975

1.5E-01

Absorbance

1.0E-01
5.0E-02
0.0E+00
0

500

1000

1500

2000

2500

3000

3500

4000

Time (seconds)

ln(absorbance) vs. Time


0.0E+00
-5.0E-01
ln(absorbance)

500

1000 1500 2000 2500 3000 3500 4000

-1.0E+00
-1.5E+00
-2.0E+00

f(x) = - 0.0002122363x - 1.4343478819


R = 0.9896932439

-2.5E+00

Time (seconds)

1/(absorbance) vs. Time


1.0E+01
8.0E+00
6.0E+00

f(x) = 0.0013314827x + 3.9205491169


R = 0.9938109157

1/(absorbance) vs. Time


1.0E+01
8.0E+00

f(x) = 0.0013314827x + 3.9205491169


R = 0.9938109157

6.0E+00
1/(absorbance)

4.0E+00
2.0E+00
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

Time (seconds)

Sample 3
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2670
2850
3030
3210
3390

50
2.0
2.5
0.5

Absorbance
0.428
0.390
0.364
0.345
0.327
0.312
0.300
0.287
0.276
0.266
0.255
0.246
0.236
0.228
0.220
0.214
0.204
0.198
0.191
0.184

313.15 Kelvin

Time
0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2670
2850
3030
3210
3390

0.2692549033

0.214

0.6931471806 0.38845271
1.308988764

0.107

ln(absorbance) Slope
Time
-0.8486320834 -0.0002330157
-0.9416085399
-1.0106014113
-1.064210862
-1.1177951081
-1.1647520912
-1.2039728043
-1.2482730632
-1.2873544133
-1.3242589702
-1.3664917338
-1.402423743
-1.443923474
-1.47840965
-1.5141277326
-1.541779264
-1.5896352851
-1.6194882483
-1.6554818509
-1.6928195214

1/(absorbance)
0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2670
2850
3030
3210
3390

2.3364485981
2.5641025641
2.7472527473
2.8985507246
3.0581039755
3.2051282051
3.3333333333
3.4843205575
3.6231884058
3.7593984962
3.9215686275
4.0650406504
4.2372881356
4.3859649123
4.5454545455
4.6728971963
4.9019607843
5.0505050505
5.2356020942
5.4347826087

Absorbance vs. Time


5.0E-01
4.0E-01
f(x) = - 6.44742396027312E-005x + 0.3833173929
R = 0.9516536527

3.0E-01
Absorbance

2.0E-01
1.0E-01
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

Time (seconds)

ln(absorbance) vs. Time


0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

-5.0E-01
ln(absorbance)

-1.0E+00

f(x) = - 0.0002330157x - 0.9290928058


R = 0.9890719944

-1.5E+00
-2.0E+00

Time (seconds)

1/(absorbance) vs. Time


6.0E+00
5.0E+00

f(x) = 0.0008740485x + 2.384977106


R = 0.997926969

4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

6.0E+00
5.0E+00

f(x) = 0.0008740485x + 2.384977106


R = 0.997926969

4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

Time (seconds)

Determining Ea
1/temperature versus ln(k)

1/Temperature

ln(k)
0.0031933578 -8.65634032
0.0031431715 -8.45798133
0.0030945381 -8.3644721

1/Temperature versus ln(k)


-8.2
0.00308
-8.25

0.0031

0.00312

0.00314

0.00316

0.00318

-8.3
-8.35
-8.4

1/Temperature (1/K)

f(x) = - 2958.8582655419x + 0.8087993392


R = 0.9622898996

-8.45
-8.5
-8.55
-8.6
-8.65
-8.7
ln(k)

n(k)

0.00316

0.00318

19x + 0.8087993392

0.0032