1. Anionic compound has a unit cell consisting of Aions at the comers of a cube and B ions on the centres of faces of the cube. The empirical formula of the compound would be (a) AB (b) AB © ABs @ A.B . Acetylene hydrocarbons are acidic because (a) acetylene contains least hydrogen atoms (©) acetylene belongs to with formula C,H,» (@) sigma electron density of C—H bond in acetylene is nearer a carbon which has 50% s-character ma) l G ce 3. Which of the following does not contain —COOH group? (a) Aspirin (b) Benzoic acid (c) Picric acid (d) All have —COOH group 4, Only an aldehyde having ... can undergoes the aldo! condensation. vast one alphas atdvh ft 5. When sodium is added to ethanol, (@) no action occurs (b) H, is formed (©) NaOC;H, and 0, are formed (@ NaOC;H, and H, are formedZ 8. 9. 10. 1. 12. . The gold number of some colloidal solutions are given below Colloidal solution | Gold number ees ee A | oor B | 2s rs | 20 The protective nature of these colloidal solutions follows the order (@) C>B>A (b) A>B>C (© A=B=C (@) B>A>C CHy ‘The reaction of HBr with CHy— the presence of peroxide will give (a) ciieoecil, 8) CHC CHB CH; CH, Hy in cH, | (© CH,—CHCH,Br (4) CH,CH,CHCH, ‘The alcohol manufactured from water gas is a) ethanol (©) isobutan The iodoform (2) CHLAHCH, IsCCH,CHs 9 (© CH,CH,OH @ caer, dence, When 3,3-dimethyl-2-butanol is heated with H,SO,, the major product obtained is (@) 2,2-dimethyl-1-butene (b) 2,3-dimethyl-1-butene (© 2,3-dimethyl-2-butene (@) cis and trans isomers of 2,3-dimethyl-2- butene ‘The correct order of basicity of amines in water is (@) (CHg)NH> CHNHp > (CH)3N (b) CH,NH, > (CH,),NH> (CH),N (© (CH,),N> (CH,),NH> CH,NH, (@) None of the above ‘The number of nodes present in radial wave function of 3d orbital is (@1 ©) 2 0 @3 13. 14. 7. P lhigh 18. 19. 21. Which of the following has largest negative electron gain enthalpy? @F @) cl (© Br @t Bromine belongs to period (@) third (b) fourth (© fifth @) second . PCI; molecule has the following geometry (@) trigonal bipyramidal (b) octahedral (©) square planar (@) planar triangular . In an octahedral structure, the pair of d-orbitals involved in d?sp* hybridisation is @ do ) das dee ide © dandy @ ds jada For the electrode reaction, M™ (aq) + ne" —> MGs) Nernst equation is RT ig (a) E=E°+ ‘Two liquids A and B boil at 145°C and 190°C respectively. At 80°C which of them has higher ‘vapour pressure? (a) Liquid A (b) Liquid B (© Both have equal vapour pressure (@) None of the above ‘What is the effect of carbon dioxide in water on corrosion? (@) Increase rusting of iron (b) Decrease rusting of iron (© Does not affect (@) None of the above Delocalised electrons are present in (@) 1,3-butadiene —_(b) Cole (© 1,3,S-hexatriene (4) All of these ‘The chemical name of isoprene is (a) 2-methyl-1,3-butadiene (b) 2-chloro-1,3-butadiene (©) 2-methoxypropene (A) None of the above22. 25. 26. Assertion/Reason Type Question Answer Codes (@ Both Assertion (A) and Reason (R) are correct and (R) is the correct explanation of (A) ii) Both (A) and (R) are correct but (R) is not the correct explanation of (A) (i) (A) is correct but (R) is incorrect iv) (A) is incorrect but (R) is correct Assertion (A) Methyl cyanide on reaction with LiAIH., does not form ethyl amine. Reason (R) Acidic hydrolysis of RCN forms RCOOH. @ @ © Gi) (b) Gi) @ Gv) . The Birch reduction of toluene gives (an {on © C\-on @ Given below is the out a process. wr CH Pap Fresh water} |container + Piston Sea water container SPM Name the process occurring in the above plant. (a) Reverse osmosis (b) Osmosis (©) Diffusion (d) None of these Inareaction between A and B, the initial rate of reaction (r,) was measured for different initial concentrations of A and B as given below Beet aa on ‘ArmolL* | 020 020 | 0. Se ah Bimal | 030 0.10 | 0.05, 5.07 x10 5.07 x10 1.43 x10 Ld Tol, mol L's" What is the order of the reaction with respect to Aand B? {@) 25,10 (b) 15,0 © 25,0 @ 15,1 ‘The most stable conformation of 1,2-diphenyl ethane is Gotts CoH: Celt Is @** Oy Cells Ho WOR H Cots Gotts H i @ fe Ms s iia Colts 27. According to nuclear reaction, aBe+fHe —> Bo+}n, the mass number of Be atom is (@) 4 (b) 8 6 @9 28, Formula of asbestos is (a) (Mg,Si,0,oH),], (b) CayMgs(Si,0;1)(OH), (© CaMg( (@) Ca,Si,0, 29. Which of the following gggonating structures is a2 30. At 25°C, 3 g of a solute A in 100 mL of an aqueous solution gave an osmotic pressure of 2.5 atmosphere. What is the molar mass of solute? (@) 293 (b) 239 (© 392 (d) 932 31. ‘The correct IUPAC name of CH,CH,CH(CH,)CH(C,H,), is (a) 4-ethyl-3-methylhexane (b) 3-ethyl-4-methylhexane (©) 3-methyl-4-ethylhexane (@) 3-iso-pentylpropane 32. Reduction of carbonyl compounds to alkanes with NHjNH and NaOH is called (a) Ponndrof verley reduction (b) Clemmensen's reduction (© Wurtz reaction (@) Wolff-Kishner reduction 33, General formula of alkynes is (@) CoHy (b) CHays 2 (©) Con, Hy (@) CHa, 234. 35. 36. 37. 38. 39. 41. 42. 43. Alkaline KMnO, oxidises acetylene to (a) acetic acid (b) ethyl alcohol (© ethylene glycol (4) oxalic acid Dehydration of alcohol is an example of (a) redox reaction (b) elimination reaction (© substitution reaction (@) addition reaction Gun metal is (@) Cu, Zn, Sn (b) Cu, Zn, Ni (© Cu, Zn, P @ GN, Fe How many moles of nitrogen are needed to produce 8.2 moles of ammonia by reaction with hydrogen? @ 21 (b) 3.1 © 32 @ 41 ‘The temperature of a gas in a closed container is 27°C. If the temperature is raised to 327°C, the pressure exerted is, (a) reduced to half 45. 47. Inert pair effect is predominant in (@) Si (b) Pb © Ge (@) Sn How many o and x bonds are there in the molecule of tetracyanoethene? (NO),C=C(CN), (@) 90,7" (b) 50, 9x (© So, 8x (@) 96, 9x Baeyer's reagent is (a) aqueous KMn0, (b) neutral KMnO, (©) alkaline KMnO, (@ aqueous bromine water Percentage of lead in lead pencile is (@) zero (b) 20 (© 80 @ 60 Low spin complex is formed by (a) sp*d? hybridisation (b) sp*d hybridisation (© d?sp® hybridisation ES eee eee @) cannot sntral oxygen atom in ether is acm ee. Sbighgat’s: specific heat c: ope @ x Oh 2 Ba 50, Clemmensen reduction of a ketone is carried (©) 5.078 i) 110.4 For the water gas reaction, C(s) + HO) > COG) + H,0() the standard Gibbs energy at 1000 K is -8.1 kJmol”!. Whatis its equilibrium constant? (@) 2.60 (b) 4.62 (© 2.64 (@) None of these For the reaction, 2NOG)+Cl(g) = 2NOCKE) Which is true? (@) Kp =Ko xT () Kp =Ke RT? @ Kp Oxidation number of Mn in Mn03 ion is @ +1 (b) -7 @-1 @ +7 Which of the following is not alkali metal? (a) Na (b) Fr (© Ca @K 51. 52. 53. out in the presence of (a) LiAIH, in ether (b) Zn-Hg with HCL (©) alycol with KOH (@) H, with Pd as catalyst ‘The electrophile involved in the nitration of benzene is (a) NO (b) Nog © No, @ NO} In the reaction, CgHs—N"==NCL + HPO, + 0 —> ? the product formed will be (@) CoH,OH (©) CoH, © CoH (@ Cos —Colts Amylopectin is a polymer of (a) B-D-glucose (b) o-D-glucose (©) BD-fructose (@) «D-mannose54, Across the lanthanide series, the basicity of the 55. When st jum and chlorine ion react, energy is lanthanide hydroxides (a) released and ionic bonds are formed (a) increases (b) released and covalent bonds are formed (b) decreases (©) absorbed and ionic bonds are formed (©) first increases and then decreases (d) absorbed and covalent bonds are formed (@) first decreases and then increases