•

ed. Cak:ul or

low •

, .

an vtrY ~ of yo"

-caJc

folhMlng :

" 1

~ 1, Cia, 0 ,. • 23. AJ - 1&"7 Mil

Cr • S~, - I 08 • Cu-

• 1 It. Pb - 20'1.

,;. 55, Fe· •• Zn - 05. •

:. ~. 1 ....

. I.p ,.

...... ;1 ~.

... .. ..

BCTI2f 6

Al~'- ali _, t ~ . en

• , I

. -~-.

, , .

.. tlon from this s~ton •

, .

I.

h oJ ttl followl,. pelr. of .u, • .tenc .. , wrlte WI e tlar, to

show ho t p,e'r ~t. to form • cc:r'\j t ... c::Jd-b ... p Ir.

te 'on d hyG-oxlde Ion

(.-1; Blc...oonal~ 1 ar, ar\d w t .. utn C.-bonle-ecid U\d w .... (Ivt C.-bon ,. Ion .nd w ....

~'f; W t 'S tht e~.1Ion ar hy~lumlon., [~OJ t Of

• , .3 buffwo ao.Iutlon ttl I cantet 0.1 mole of e hYrocY."tc Id 0iCtd.net 0.89. mol.,of aodlwn c:y.nl.'

.,-oe" ,..

(U) If O. t mol. 01 e,yct.-oc:tdorle ac.Id (Hel), i. ~ ,10 the buH

, .~I.~, on.!n r:»(1)~. _!W'* ~1I~;t~,.. l"lOj ,

'(lOP OIlculatet'the pH of t bUff.,. '.Otuua,iln b(l) iIbove. tf O.~

, ~ Ie of •• OCStUm hyGooxt d4a .0 1* add ~ II.

,.:. ~J)- Th. Aufb' Prlnefpl

(1) The,HaI"""g Pr.noipl of unc talnty

, •.•• ~ ._. • ..... ,.4 ••.. ·_ .:"'".

(III) The "'Ortca8llnga of Boh'-l. l"Mcry.

: I ", ~

fb) c:IIC-9 .. tlo.. lUed from ,.adl~ tw.w • .., ....-gy of •• 8 M.v.

_, , t '.'de '- rog I. vel.,jth' • .

Ccl

Tfie"'w;c' iainty In .;." ~ ''''''t~''~ gn) em -I. Find the .ccwoecy -Ntth

d ~ lned. '

partlel. 1.3.3 '0- 6 leh Its poslllon C*n b.

(a) With the d of chemfcal u Uon (st. br'.tly deecr'*,,- th' prOC ....

wi ru.Ur\g of Iron.

) Glven the .tandard electrode potential. I UoC as

_eov
'Z.nZ+ /Zn -0.76
.2+/F. -0.4.
!in"" 15ft -0.14 (0 ."... ct wtilch co 'tlng pretect. iJro" more .rl-fecllve'Y wen

.wt..... co ling h .. b 'n br~ to expo t Jr-m..!

(II) WNch o,'t~'- tW,g:'met"l.;'·Z.~ ;,; Tin, '1_ nor lIy ",Met 10

~otect the JI' Ide Of food c." d Why 7

(.) I "brIefly • t. m t by
(r) I onl ~. it on en 'IV
(II) ato .. dz don SlY
.
JII' IqI SY
(b) b 10 , .c.lcul 'a th • ~ ule. energy of .6H ~Mo -
K(a) + 2m - 395.9
K( } K (g)1II' 10.8·

K K (a) .1

8r (I) (a) U,. ,
•
(sa) -~) - a -)45.-
,r of 'M I lIlea la Sli s KF

K~I

'71 0'· o

. .. ... _.

9

~ KI

B
•
(I, II
z
~ .. !:!... L •

lion.

I

Arllon

)

0) 'h pare

og .from y-aoll w

of . O. • lot I e. C. of

Ilf calculata,

b . ur.ilotil ~ lh ' 011 a.einpla.

·,Of\"'th"m;. "\n''7~''~''th 10 '1.011

: .. _,

(.a) lion F<::)l.A (.) ad".,.ac"

pr ttc...

(I) crop r"olaUon

(H) k ng

) How do I follow. CW'oc: ., 'pH!

(I) cr~l.l "vlly

(II) i, ng

'of

of

conlf'lbut to th ch

51n

(0)

•

Au t.

•• Y. count

,.. ... may

UII)

,

I. formed when tWlllin lor'_ lua on.

their c:hIClf"ld
(I ,.0Jd •
' .. ( «. ~'I .. , '
Iy aaln th8 ~ s:
.
.
(I) me (II) n (u'" t ilv)
) f n • of
ec} :, Ilt .'
o. he t.ncy. , and~u. ,

(cO

- 5 -

·AU

• at I ....

,(a)."., ~ f~ l foUo :

(tt In It.... U 0fU, a~r._IA. s1A> at ilUC I on.

(II) On nlu- lion. enllino prodUct ••

nly'

lie:

. ,

Ina) 81

• ,"I I • 01

(0) C.'aIYI C t-.y Ogw\ Llan 0' ,C 5'l. 8

CW\ C alytlc:.lly ~ ted

0)

0'. If a ~1Mir",ac~. oa.~1 I • -\11IIIIIIII'"

• .etod produCl"

.wn t str tur of c~OWlod S

';4 •

-O-C-C-C-OH.

" I ,

o H OM

I

pi

) te .Id

I) phOlphorcva pentacnkJrld (Pc ) II)

...

!v) pot .tlll'l dictlr t

Lilhi ,,_.,tum hydr-I de (L'A.'H,,)

. .

Of •

0)

of pt"odUr;ts At Bt C

• ~ reactions.

Din

o~

A+a

3

e

___ 3 ............... 0

(t

It. down, Indlc.tlng r-

ot I fotlowi e t" I

and condl tI ens. the

tion

Propeno'

.,tem -.) - on •

- 45 -

... educ:ed lO cGlftOOU"d a of ~ boIU Ow

Give. bfotef account for the .bow r . .,

P could pro In &.bor wy.

t how