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10 \fs30 \cf0 Air dan air limbah \par}{\phpg\posx3159\pvpg\posy7323\absw6788\absh1041 \sl-390 \b \f10 \fs30 \cf0
Bagian 13: Cara uji kalsium (Ca) dengan
\par}{\phpg\posx3159\pvpg\posy7323\absw6788\absh1041 \sl-388 \b \f10 \fs30 \cf0
\fi1890 metode titrimetri \par
}
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\cf0 ICS 13.060.50 \par
}
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{\phpg\posx8676\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx5904\pvpg\posy1607\absw1007\absh226 \b \f10 \fs20 \cf0 \b \f10 \fs20
\cf0 Daftar Isi \par
}
{\phpg\posx2118\pvpg\posy2624\absw8892\absh528 \f10 \fs18 \cf0 \f10 \fs18 \cf0 D
aftar isi.......................................................................
..............................................................i
\par}{\phpg\posx2118\pvpg\posy2624\absw8892\absh528 \sl-356 \f10 \fs18 \cf0 Prak
ata. ...........................................................................
.........................................................ii \par
}
{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \f10 \fs18 \cf0 \f10 \fs18 \cf0 1
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 2
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 3
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 3.1
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 3.2
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 3.3
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 3.4
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 3.5
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 3.6
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 3.7
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 4
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-356 \f10 \fs18 \cf0 4.1
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 4.2
\par}{\phpg\posx2118\pvpg\posy3338\absw342\absh4384 \sl-357 \f10 \fs18 \cf0 5 \p
ar
}
{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \f10 \fs18 \cf0 \fi29 \f10 \fs18
\cf0 Ruang lingkup ............................................................

....................................................... 1
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
29 Istilah dan definisi.........................................................
..................................................... 1
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 \fi
29 Cara uji.....................................................................
......................................................... 1
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 \fi
172 Prinsip.....................................................................
........................................................ 1
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
172 Bahan ......................................................................
....................................................... 1
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
172 Peralatan ..................................................................
...................................................... 3
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 \fi
172 Gangguan....................................................................
................................................... 4
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 \fi
172 Persiapan contoh uji .......................................................
................................................ 4
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
172 Prosedur ...................................................................
...................................................... 5
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
172 Perhitungan ................................................................
.................................................... 5
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 Jam
inan mutu dan pengendalian mutu.................................................
............................. 6
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-356 \f10 \fs18 \cf0 \fi
172 Jaminan mutu ...............................................................
.................................................. 6
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 \fi
172 Pengendalian mutu...........................................................
.............................................. 6
\par}{\phpg\posx2463\pvpg\posy3338\absw8550\absh4384 \sl-357 \f10 \fs18 \cf0 Rek
omendasi........................................................................
............................................. 6 \par
}
{\phpg\posx2118\pvpg\posy8336\absw8868\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 L
ampiran A Pelaporan.............................................................
................................................ 8 \par
}
{\phpg\posx6360\pvpg\posy14932\absw55\absh189 \b \f10 \fs17 \cf0 \b \f10 \fs17 \
cf0 i \par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx2118\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx5978\pvpg\posy1607\absw942\absh226 \b \f10 \fs20 \cf0 \b \f10 \fs20 \
cf0 Prakata \par
}
{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Dalam rangka menyeragamkan teknik pengujian kualitas air dan air limbah
sebagaimana
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \f10 \fs18 \cf0 tel

ah ditetapkan dalam Peraturan Pemerintah Nomor 82 Tahun 2001 tentang P

engelolaan
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 Kua
litas Air, Keputusan Menteri Negara Lingkungan Hidup Nomor 02 Tahun 19
88 tentang
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 Bak
u Mutu Air dan Nomor 37 Tahun 2003 tentang Metode Analisis Pengujian
Kualitas air
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 Per
mukaan dan Pengambilan Contoh Air Permukaan, maka dibuatlah Standar Nas
ional
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \f10 \fs18 \cf0 Ind
onesia (SNI) untuk pengujian parameter-parameter kualitas air dan
air limbah
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 seb
agaimana yang tercantum didalam Keputusan Menteri tersebut.
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \par\f10 \fs18 \cf0
Metode ini merupakan hasil kaji ulang dari SNI yang telah kadaluarsa dan telah
melalui uji
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \f10 \fs18 \cf0 cob
a di laboratorium pengujian dalam rangka validasi dan verifikasi
metode serta
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 dik
onsensuskan oleh Subpanitia Teknis Kualitas Air, Panitia Teknis
207S, Bidang
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \f10 \fs18 \cf0 Man
ajemen Lingkungan dengan para pihak terkait.
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \par\f10 \fs18 \cf0
Standar ini telah disepakati dan disetujui dalam rapat konsensus dengan peserta
rapat yang
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-236 \f10 \fs18 \cf0 mew
akili produsen, konsumen, ilmuwan, instansi teknis, pemerintah ter
kait dari pusat
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \f10 \fs18 \cf0 mau
pun daerah pada tanggal 31 Januari 2004 di Serpong, Tangerang - Banten.
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-238 \par\f10 \fs18 \cf0
Metode ini berjudul{\i Air}{\i dan}{\i air}{\i limbah}{\i -}{\i B
agian}{\i 13:}{\i Cara}{\i uji}{\i kalsium}{\i (Ca)}{\i dengan}{\i
metode }
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 {\i
titrimetri} yang merupakan revisi dari SNI 06-2429-1991 dengan judul{\i
Metode}{\i pengujian }
\par}{\phpg\posx2118\pvpg\posy2580\absw8967\absh4276 \sl-237 \f10 \fs18 \cf0 {\i
kalsium}{\i dalam}{\i air}{\i dengan}{\i titrimetrik}{\i EDTA. }\par
}
{\phpg\posx6345\pvpg\posy14932\absw105\absh189 \f10 \fs17 \cf0 \f10 \fs17 \cf0 i
i \par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx8676\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx3589\pvpg\posy1607\absw5931\absh460 \b \f10 \fs20 \cf0 \b \f10 \fs20
\cf0 Air dan air limbah - Bagian 13: Cara uji kalsium (Ca)
\par}{\phpg\posx3589\pvpg\posy1607\absw5931\absh460 \sl-259 \b \f10 \fs20 \cf0 \
fi1474 dengan metode titrimetri \par
}
{\phpg\posx2118\pvpg\posy2839\absw146\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 1 \par

}
{\phpg\posx2651\pvpg\posy2839\absw1527\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 Ruang lingkup \par
}
{\phpg\posx2118\pvpg\posy3315\absw8890\absh850 \f10 \fs18 \cf0 \f10 \fs18 \cf0 M
etode ini digunakan untuk penentuan kadar kalsium (Ca) dalam air dan air limbah
dengan
\par}{\phpg\posx2118\pvpg\posy3315\absw8890\absh850 \sl-237 \f10 \fs18 \cf0 meto
de titrimetri EDTA pada kisaran kadar Ca 100 mg/L sampai dengan 200 mg/L.
\par}{\phpg\posx2118\pvpg\posy3315\absw8890\absh850 \sl-238 \par\f10 \fs18 \cf0
Metode ini digunakan untuk contoh uji air yang tidak berwarna. \par
}
{\phpg\posx2118\pvpg\posy4743\absw342\absh636 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 2
\par}{\phpg\posx2118\pvpg\posy4743\absw342\absh636 \sl-238 \par\b \f10 \fs18 \cf
0 2.1 \par
}
{\phpg\posx2652\pvpg\posy4743\absw1915\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 Istilah dan definisi \par
}
{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 larutan baku kalsium, Ca
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-238 \b \f10 \fs18 \cf0
{\b0 larutan}{\b0 yang}{\b0 mempunyai}{\b0 kadar}{\b0 kalsium,}{\b0 Ca}{\b0
yang}{\b0 diencerkan}{\b0 dengan}{\b0 air}{\b0 suling}{\b0 sampai}{\b0 k
adar }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-237 \b \f10 \fs18 \cf0
{\b0 tertentu }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-237 \par\b \f10 \fs18 \
cf0 2.2
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-239 \b \f10 \fs18 \cf0
{\i blind}{\i sample }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-236 \b \f10 \fs18 \cf0
{\b0 larutan}{\b0 baku}{\b0 dengan}{\b0 kadar}{\b0 tertentu }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-237 \par\b \f10 \fs18 \
cf0 2.3
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-239 \b \f10 \fs18 \cf0
{\i spike}{\i matrix }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-236 \b \f10 \fs18 \cf0
{\b0 contoh}{\b0 uji}{\b0 yang}{\b0 diperkaya}{\b0 menggunakan}{\b0 larutan
}{\b0 baku}{\b0 dengan}{\b0 kadar}{\b0 tertentu }
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-238 \par\b \f10 \fs18 \
cf0 2.4
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-236 \b \f10 \fs18 \cf0
{\i Certified}{\i Reference}{\i Material} (CRM)
\par}{\phpg\posx2118\pvpg\posy5457\absw8957\absh3206 \sl-238 \b \f10 \fs18 \cf0
{\b0 bahan}{\b0 standar}{\b0 bersertifikat}{\b0 yang}{\b0 tertelusur}{\b0 k
e}{\b0 sistem}{\b0 nasional}{\b0 atau}{\b0 internasional }\par
}
{\phpg\posx2118\pvpg\posy9504\absw342\absh635 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 3
\par}{\phpg\posx2118\pvpg\posy9504\absw342\absh635 \sl-237 \par\b \f10 \fs18 \cf
0 3.1 \par
}
{\phpg\posx2636\pvpg\posy9504\absw883\absh635 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 Cara uji
\par}{\phpg\posx2636\pvpg\posy9504\absw883\absh635 \sl-237 \par\b \f10 \fs18 \cf
0 Prinsip \par
}
{\phpg\posx2118\pvpg\posy10455\absw8971\absh1063 \f10 \fs18 \cf0 \f10 \fs18 \cf0

Pada pH contoh uji cukup tinggi (12 sampai dengan 13), magnesium aka
n mengendap
\par}{\phpg\posx2118\pvpg\posy10455\absw8971\absh1063 \sl-238 \f10 \fs18 \cf0 se
bagai magnesium hidroksida maka EDTA hanya akan bereaksi dengan kalsium
. Pada
\par}{\phpg\posx2118\pvpg\posy10455\absw8971\absh1063 \sl-237 \f10 \fs18 \cf0 aw
alnya indikator mureksid bereaksi dengan ion kalsium sehingga larutan berwarna m
erah
\par}{\phpg\posx2118\pvpg\posy10455\absw8971\absh1063 \sl-237 \f10 \fs18 \cf0 mu
da. Pada titik akhir titrasi dengan EDTA, indikator akan lepas kembali dan larut
an menjadi
\par}{\phpg\posx2118\pvpg\posy10455\absw8971\absh1063 \sl-237 \f10 \fs18 \cf0 be
rwarna ungu. \par
}
{\phpg\posx2118\pvpg\posy11883\absw342\absh636 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 3.2
\par}{\phpg\posx2118\pvpg\posy11883\absw342\absh636 \sl-238 \par\b \f10 \fs18 \c
f0 {\b0 a) }\par
}
{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \b \f10 \fs18 \cf0 \fi53 \b \f1
0 \fs18 \cf0 Bahan
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-168 \par\par\b \f10 \f
s18 \cf0 \fi68 {\b0 Indikator}{\b0 mureksid}{\b0 (C }{\b0\dn006 \fs11 8}{\b0
H }{\b0\dn006 \fs11 8}{\b0 N }{\b0\dn006 \fs11 6}{\b0 O }{\b0\dn006 \fs11 6}{
\b0 ) }
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-223 \par\b \f10 \fs18
\cf0 {\b0 1)}{\b0
Timbang}{\b0 200}{\b0 mg}{\b0 mureksid}{\b0 dan}{\b
0 100}{\b0 g}{\b0 kristal}{\b0 natrium}{\b0 klorida}{\b0 (NaCl),}{\b
0 kemudian }
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-237 \b \f10 \fs18 \cf0
\fi334 {\b0 dicampur. }
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-313 \b \f10 \fs18 \cf0
{\b0 2)}{\b0
Gerus}{\b0 campuran}{\b0 tersebut}{\b0 hingga}{\b0 memp
unyai}{\b0 ukuran}{\b0 40}{\b0 mesh}{\b0 sampai}{\b0 dengan}{\b0 50
}
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-237 \b \f10 \fs18 \cf0
\fi334 {\b0 mesh. }
\par}{\phpg\posx2583\pvpg\posy11883\absw8512\absh2057 \sl-314 \b \f10 \fs18 \cf0
{\b0 3)}{\b0
Simpan}{\b0 dalam}{\b0 botol}{\b0 yang}{\b0 tertutup}{\b0
rapat. }\par
}
{\phpg\posx6057\pvpg\posy14932\absw694\absh189 \b \f10 \fs17 \cf0 \b \f10 \fs17
\cf0 1 dari 8 \par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx2118\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2118\pvpg\posy1607\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 b)
\par
}
{\phpg\posx2118\pvpg\posy3498\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 c)
\par
}
{\phpg\posx2118\pvpg\posy4764\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 d)
\par
}
{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Indikator Eriochrome Black T (EBT = C {\dn006 \fs11 20}H{\dn006 \fs11 12}N {\

dn006 \fs11 3}NaO{\dn006 \fs11 7}S)

\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-223 \par\f10 \fs18 \cf
0 1)
Timbang 200 mg EBT dan 100 mg kristal NaCl, kemudian di campur
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-314 \f10 \fs18 \cf0 2)
Gerus campuran tersebut, hingga mempunyai ukuran 40 mesh sampai dengan 50
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-236 \f10 \fs18 \cf0 \f
i400 mesh
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-314 \f10 \fs18 \cf0 3)
Simpan dalam botol yang tertutup rapat.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-275 \par\f10 \fs18 \cf
0 Larutan natrium hidroksida (NaOH) 1 N
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \par\f10 \fs18 \cf
0 1)
Timbang 40 g NaOH, larutkan dengan 50 mL air suling.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-313 \f10 \fs18 \cf0 2)
Encerkan dengan air suling hingga volumenya menjadi 1000 mL.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \par\f10 \fs18 \cf
0 Larutan penyangga pH 10 {\ul +} 0,1
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \par\f10 \fs18 \cf
0 Larutan penyangga yang digunakan bisa dipilih dari salah satu di bawah ini:
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-237 \par\f10 \fs18 \cf
0 1)
Cara I
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-266 \f10 \fs18 \cf0 \f
i400 a)
Larutkan 16,9 g amonium klorida (NH{\dn006 \fs11 4}Cl) d
alam 143 mL ammonium
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-237 \f10 \fs18 \cf0 \f
i800 hidroksida (NH {\dn006 \fs11 4}OH) pekat.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-284 \f10 \fs18 \cf0 \f
i400 b)
Tambahkan 1,25 g magnesium etilendiamin tetra asetat (Mg-EDTA).
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-314 \f10 \fs18 \cf0 \f
i400 c)
Encerkan dengan air suling hingga volumenya menjadi 250,0 mL.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-237 \par\f10 \fs18 \cf
0 2)
Cara II
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-266 \f10 \fs18 \cf0 \f
i400 a)
Larutkan 1,179 g Na{\dn006 \fs11 2}EDTA dihidrat dan 780 mg
magnesium sulfat hepta
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \f10 \fs18 \cf0 \f
i800 hidrat
(MgSO{\dn006 \fs11 4}.7H {\dn006 \fs11 2}O)
atau
644
m
g
magnesium
klorida
heksa
hidrat
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-237 \f10 \fs18 \cf0 \f
i800 (MgCl {\dn006 \fs11 2}.6H{\dn006 \fs11 2}O) dalam 50 mL air suling.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-156 \par\f10 \fs18 \cf
0 \fi400 b)
Tambahkan larutan tersebut ke dalam 16,9 g NH {\dn006 \fs1
1 4}Cl dan 143 mL NH {\dn006 \fs11 4}OH
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-209 \f10 \fs18 \cf0 \f
i800 pekat, sambil dilakukan pengadukan.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-313 \f10 \fs18 \cf0 \f
i400 c)
Encerkan dengan air suling hingga volumenya menjadi 250,0 mL.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-228 \par\f10 \fs18 \cf
0 \fi400 {\fs17 CATATAN}{\fs17 1}{\fs17 Simpan}{\fs17 larutan}{\fs17 pen
yangga}{\fs17 pH}{\fs17 10}{\fs17 {\ul +}}{\fs17 0,1}{\fs17 pada}{\fs1
7 nomor}{\fs17 3.2.c.1)}{\fs17 atau}{\fs17 3.2.c.2) }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-217 \f10 \fs18 \cf0 \f
i1600 {\fs17 tersebut}{\fs17 pada}{\fs17 wadah}{\fs17 plastik}{\fs17 atau}{\
fs17 gelas}{\fs17 borosilikat}{\fs17 bertutup}{\fs17 plastik. }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-291 \f10 \fs18 \cf0 \f
i400 {\fs17 CATATAN}{\fs17 2}{\fs17
Botol}{\fs17 penyimpan}{\fs17 larut
an}{\fs17 ditutup}{\fs17 rapat}{\fs17 untuk}{\fs17 mencegah}{\fs17 keh
ilangan}{\fs17 amonia }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-244 \f10 \fs18 \cf0 \f
i1600 {\fs17 (NH }{\dn006 \fs11 3}{\fs17 )}{\fs17 atau}{\fs17 penyerapan}{\fs

17 karbon}{\fs17 dioksida}{\fs17 (CO}{\dn006 \fs11 2}{\fs17 )}{\fs17 dari}{

\fs17 udara. }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-262 \f10 \fs18 \cf0 \f
i400 {\fs17 CATATAN}{\fs17 3}{\fs17
Waktu}{\fs17 penyimpanan}{\fs17 tidak
}{\fs17 boleh}{\fs17 lebih}{\fs17 1}{\fs17 bulan. }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-292 \f10 \fs18 \cf0 \f
i400 {\fs17 CATATAN}{\fs17 4}{\fs17
Buang}{\fs17 larutan}{\fs17 penyang
ga}{\fs17 jika}{\fs17 1}{\fs17 mL}{\fs17 sampai}{\fs17 dengan}{\fs17
2}{\fs17 mL}{\fs17 larutan}{\fs17 tersebut }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-214 \f10 \fs18 \cf0 \f
i1600 {\fs17 ditambahkan}{\fs17 ke}{\fs17 dalam}{\fs17 larutan}{\fs17 co
ntoh}{\fs17 uji}{\fs17 tidak}{\fs17 menghasilkan}{\fs17 pH}{\fs17 10}{
\fs17 {\ul +}}{\fs17 0,1 }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-217 \f10 \fs18 \cf0 \f
i1600 {\fs17 pada}{\fs17 titik}{\fs17 akhir}{\fs17 titrasi. }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-239 \par\f10 \fs18 \cf
0 Larutan standar kalsium karbonat (CaCO {\dn006 \fs11 3} 0,01 M)
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \par\f10 \fs18 \cf
0 1)
Timbang 1,0 g CaCO{\dn006 \fs11 3}, masukkan ke dalam labu Erlenmeyer 5
00 mL.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-284 \f10 \fs18 \cf0 2)
Larutkan dengan sedikit asam klorida (HCl) 1 : 1, tambah dengan 2
00 mL air
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-238 \f10 \fs18 \cf0 \f
i400 suling.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-171 \par\f10 \fs18 \cf
0 3)
Didihkan beberapa menit, untuk menghilangkan CO {\dn006 \fs11 2}, kemud
ian dinginkan.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-284 \f10 \fs18 \cf0 4)
Setelah dingin, tambahkan beberapa tetes indikator metil merah.
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-171 \par\f10 \fs18 \cf
0 5)
Tambahkan NH{\dn006 \fs11 4}OH 3 N atau HCl 1 : 1 sampai terbentuk warn
a{\i orange. }
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-284 \f10 \fs18 \cf0 6)
Pindahkan secara kuantitatif ke dalam labu ukur 1000 mL, kemudian
tepatkan
\par}{\phpg\posx2651\pvpg\posy1607\absw8446\absh11397 \sl-237 \f10 \fs18 \cf0 \f
i400 sampai tanda tera. \par
}
{\phpg\posx2118\pvpg\posy11521\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 e
) \par
}
{\phpg\posx6057\pvpg\posy14932\absw692\absh189 \f10 \fs17 \cf0 \f10 \fs17 \cf0 2
{\b dari}{\b 8 }\par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx8676\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2118\pvpg\posy1607\absw158\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 f)
\par
}
{\phpg\posx2118\pvpg\posy3033\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 g)
\par
}
{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Larutan baku dinatrium etilendiamin tetra asetat dihidrat (Na{\dn006 \fs1
1 2}EDTA 2H{\dn006 \fs11 2}O = C{\dn006 \fs11 10}H {\dn006 \fs11 14}N{\fs
11 2 }

\par}{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \sl-236 \f10 \fs18 \cf0 Na{

\dn006 \fs11 2}O{\dn006 \fs11 8}.2H {\dn006 \fs11 2}O) 0,01 M
\par}{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \sl-238 \par\f10 \fs18 \cf0
Larutkan 3,723 g Na{\dn006 \fs11 2}EDTA dihidrat dengan air suling di
dalam labu ukur 1000 mL,
\par}{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \sl-209 \f10 \fs18 \cf0 tep
atkan sampai tanda tera.
\par}{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \sl-252 \par\f10 \fs18 \cf0
Pembakuan larutan Na{\dn006 \fs11 2}EDTA + 0,01 M
\par}{\phpg\posx2651\pvpg\posy1607\absw8381\absh1969 \sl-238 \par\f10 \fs18 \cf0
1)
Pipet 10 mL larutan standar CaCO {\dn006 \fs11 3} 0,01 M, masukkan ke da
lam labu erlenmeyer \par
}
{\phpg\posx3051\pvpg\posy3749\absw858\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 25
0 mL. \par
}
{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \f10 \fs18 \cf0 \f10 \fs18 \cf0
2)
Tambah 40 mL air suling dan 1 mL larutan penyangga pH 10 {\ul +} 0,1.
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-314 \f10 \fs18 \cf0 3)
Tambahkan seujung spatula 30 mg sampai dengan 50 mg indikator EBT.
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-170 \par\f10 \fs18 \cf0
4)
Titrasi dengan larutan Na{\dn006 \fs11 2}EDTA 0,01 M sampai terja
di perubahan warna dari
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-209 \f10 \fs18 \cf0 \fi
399 merah keunguan menjadi biru.
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-171 \par\f10 \fs18 \cf0
5)
Catat volume larutan Na{\dn006 \fs11 2}EDTA yang digunakan.
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-313 \f10 \fs18 \cf0 6)
Ulangi titrasi tersebut 3 kali, kemudian volume Na{\dn006 \fs11 2}EDTA yan
g digunakan dirata\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-209 \f10 \fs18 \cf0 \fi
399 ratakan.
\par}{\phpg\posx2651\pvpg\posy4061\absw8354\absh2089 \sl-170 \par\f10 \fs18 \cf0
7)
Hitung molaritas larutan baku Na{\dn006 \fs11 2}EDTA dengan menggu
nakan rumus sebagai \par
}
{\phpg\posx3051\pvpg\posy6342\absw1260\absh676 \f10 \fs18 \cf0 \f10 \fs18 \cf0 b
erikut:
\par}{\phpg\posx3051\pvpg\posy6342\absw1260\absh676 \sl-257 \par\f10 \fs18 \cf0
\fi456 {\f20 \fs20 M}{\dn006 \f20 \fs16 EDTA }\par
}
{\phpg\posx4326\pvpg\posy6760\absw165\absh249 \f40 \fs20 \cf0 \f40 \fs20 \cf0 =
\par
}
{\phpg\posx4513\pvpg\posy6588\absw751\absh276 \f20 \fs20 \cf0 \f20 \fs20 \cf0 M{
\dn006 \fs16 CaCO }\par
}
{\phpg\posx5217\pvpg\posy6588\absw895\absh310 \f20 \fs16 \cf0 \f20 \fs16 \cf0 3{
\fs20 .}{\fs20 V}{\dn006 CaCO }\par
}
{\phpg\posx6077\pvpg\posy6724\absw110\absh187 \f20 \fs16 \cf0 \f20 \fs16 \cf0 3
\par
}
{\phpg\posx6333\pvpg\posy6801\absw1151\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 (
mmol/mL) \par
}
{\phpg\posx4987\pvpg\posy6963\absw720\absh276 \f20 \fs20 \cf0 \f20 \fs20 \cf0 V{
\dn006 \fs16 EDTA }\par
}
{\phpg\posx3051\pvpg\posy7513\absw1915\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 d

engan pengertian : \par

}
{\phpg\posx3064\pvpg\posy7770\absw875\absh1208 \f20 \fs20 \cf0 \fi20 \f20 \fs20
\cf0 M{\dn006 \fs16 EDTA }
\par}{\phpg\posx3064\pvpg\posy7770\absw875\absh1208 \sl-320 \f20 \fs20 \cf0 {\i
V}{\i\dn006 \fs11 EDTA }
\par}{\phpg\posx3064\pvpg\posy7770\absw875\absh1208 \sl-319 \f20 \fs20 \cf0 {\i
\fs20 V}{\i\dn006 \fs11 CaCO }
\par}{\phpg\posx3064\pvpg\posy7770\absw875\absh1208 \sl-202 \par\f20 \fs20 \cf0
\fi20 {\fs20 M}{\dn006 \fs16 CaCO}{\fs16 3 }\par
}
{\phpg\posx3532\pvpg\posy8617\absw55\absh110 \f20 \fs8 \cf0 \f20 \fs8 \cf0 3 \pa
r
}
{\phpg\posx4119\pvpg\posy7784\absw5911\absh1138 \f10 \fs18 \cf0 \f10 \fs18 \cf0
adalah molaritas larutan baku Na{\dn006 \fs11 2}EDTA (mmol/mL);
\par}{\phpg\posx4119\pvpg\posy7784\absw5911\absh1138 \sl-320 \f10 \fs18 \cf0 ada
lah volume rata-rata larutan baku Na{\dn006 \fs11 2}EDTA (mL);
\par}{\phpg\posx4119\pvpg\posy7784\absw5911\absh1138 \sl-319 \f10 \fs18 \cf0 ada
lah volume rata-rata larutan CaCO {\dn006 \fs11 3} yang digunakan (mL);
\par}{\phpg\posx4119\pvpg\posy7784\absw5911\absh1138 \sl-178 \par\f10 \fs18 \cf0
adalah molaritas larutan CaCO{\dn006 \fs11 3} yang digunakan (mmol/mL). \par
}
{\phpg\posx2118\pvpg\posy9363\absw228\absh650 \f10 \fs18 \cf0 \f10 \fs18 \cf0 h)
\par}{\phpg\posx2118\pvpg\posy9363\absw228\absh650 \sl-245 \par\f10 \fs18 \cf0 i
) \par
}
{\phpg\posx2118\pvpg\posy10585\absw342\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 3.3 \par
}
{\phpg\posx2651\pvpg\posy9363\absw8426\absh1306 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Serbuk kalium sianida (KCN).
\par}{\phpg\posx2651\pvpg\posy9363\absw8426\absh1306 \sl-245 \par\f10 \fs18 \cf0
Air suling atau air bebas mineral yang mempunyai daya hantar listrik (DHL) 0,5{
\f40 }S/cm
\par}{\phpg\posx2651\pvpg\posy9363\absw8426\absh1306 \sl-253 \f10 \fs18 \cf0 sam
pai dengan 2{\f40 }S/cm.
\par}{\phpg\posx2651\pvpg\posy9363\absw8426\absh1306 \sl-238 \par\f10 \fs18 \cf0
\fi172 {\b Peralatan }\par
}
{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \f10 \fs18 \cf0 \f10 \fs18 \cf0
a)
buret 50 mL atau alat titrasi lain dengan skala yang jelas;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-311 \f10 \fs18 \cf0 b)
labu Erlenmeyer 250 mL dan 500 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-314 \f10 \fs18 \cf0 c)
labu ukur 250 mL dan 1000 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-311 \f10 \fs18 \cf0 d)
gelas ukur 100 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-314 \f10 \fs18 \cf0 e)
pipet volume 10 mL dan 50 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-311 \f10 \fs18 \cf0 f)
pipet ukur 10 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-314 \f10 \fs18 \cf0 g)
gelas piala 50 mL, 250 mL dan 1000 mL;
\par}{\phpg\posx2118\pvpg\posy11061\absw5866\absh2180 \sl-313 \f10 \fs18 \cf0 h)
spatula; \par
}
{\phpg\posx2118\pvpg\posy13567\absw210\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0
i)

\par}{\phpg\posx2118\pvpg\posy13567\absw210\absh1053 \sl-313 \f10 \fs18 \cf0 j)

\par}{\phpg\posx2118\pvpg\posy13567\absw210\absh1053 \sl-313 \f10 \fs18 \cf0 k)
\par}{\phpg\posx2118\pvpg\posy13567\absw210\absh1053 \sl-313 \f10 \fs18 \cf0 l)
\par
}
{\phpg\posx2518\pvpg\posy13567\absw1797\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0
alat pengukur pH;
\par}{\phpg\posx2518\pvpg\posy13567\absw1797\absh1053 \sl-313 \f10 \fs18 \cf0 pe
ngaduk gelas;
\par}{\phpg\posx2518\pvpg\posy13567\absw1797\absh1053 \sl-313 \f10 \fs18 \cf0 pe
manas listrik;
\par}{\phpg\posx2518\pvpg\posy13567\absw1797\absh1053 \sl-313 \f10 \fs18 \cf0 ti
mbangan analitik; \par
}
{\phpg\posx6057\pvpg\posy14932\absw694\absh189 \b \f10 \fs16 \cf0 \b \f10 \fs16
\cf0 3 dari 8 \par
}
{\shp\shpfhdr0\shpbxpage\shpbypage\shpfblwtxt1\shpz0
\shpleft4498\shptop6931\shpright6231\shpbottom6931
{\*\shpinst {\sp{\sn shapeType}{\sv 20}}
{\sp{\sn fFlipH}{\sv 0}}{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn LineWidth}{\sv
9}}
{\sp{\sn fBehindDocument}{\sv 1}}{\sp{\sn lineColor}{\sv
0}}}}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx2118\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \f10 \fs18 \cf0 \f10 \fs18 \cf0
m) gelas arloji;
\par}{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \sl-313 \f10 \fs18 \cf0 n)
mortar dan alu;
\par}{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \sl-311 \f10 \fs18 \cf0 o)
botol borosilikat tutup asah;
\par}{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \sl-314 \f10 \fs18 \cf0 p)
botol borosilikat tutup karet.
\par}{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \sl-238 \par\f10 \fs18 \cf0
{\b 3.4}{\b
Gangguan }
\par}{\phpg\posx2118\pvpg\posy1607\absw3294\absh1909 \sl-237 \par\f10 \fs18 \cf0
Jika konsentrasi ion-ion berikut ini: \par
}
{\phpg\posx2218\pvpg\posy4012\absw333\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 Cu
\par
}
{\phpg\posx2218\pvpg\posy4326\absw298\absh489 \f10 \fs18 \cf0 \f10 \fs18 \cf0 Fe
\par}{\phpg\posx2218\pvpg\posy4326\absw298\absh489
ar
}
{\phpg\posx2482\pvpg\posy3986\absw158\absh132 \f10
\par
}
{\phpg\posx5097\pvpg\posy4013\absw281\absh207 \f10
\par
}
{\phpg\posx2460\pvpg\posy4298\absw158\absh415 \f10

\sl-313 \f10 \fs18 \cf0 Fe \p

\fs11 \cf0 \f10 \fs11 \cf0 2+
\fs18 \cf0 \f10 \fs18 \cf0 Zn
\fs11 \cf0 \f10 \fs11 \cf0 2+

\par}{\phpg\posx2460\pvpg\posy4298\absw158\absh415 \sl-157 \par\f10 \fs11 \cf0 +

3 \par
}

{\phpg\posx2218\pvpg\posy4952\absw333\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 Mn

\par
}
{\phpg\posx2505\pvpg\posy4926\absw158\absh132 \f10 \fs11 \cf0 \f10 \fs11 \cf0 2+
\par
}
{\phpg\posx2895\pvpg\posy4013\absw1051\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0
> 2 mg/L
\par}{\phpg\posx2895\pvpg\posy4013\absw1051\absh1053 \sl-313 \f10 \fs18 \cf0 > 2
0 mg/L
\par}{\phpg\posx2895\pvpg\posy4013\absw1051\absh1053 \sl-313 \f10 \fs18 \cf0 > 2
0 mg/L
\par}{\phpg\posx2895\pvpg\posy4013\absw1051\absh1053 \sl-313 \f10 \fs18 \cf0 > 1
0 mg/L \par
}
{\phpg\posx5338\pvpg\posy3986\absw158\absh132 \f10 \fs11 \cf0 \f10 \fs11 \cf0 2+
\par
}
{\phpg\posx5097\pvpg\posy4326\absw316\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 Pb
\par
}
{\phpg\posx5350\pvpg\posy4298\absw158\absh132 \f10 \fs11 \cf0 \f10 \fs11 \cf0 2+
\par
}
{\phpg\posx5097\pvpg\posy4613\absw340\absh231 \f10 \fs11 \cf0 \fi182 \f10 \fs11
\cf0 3+
\par}{\phpg\posx5097\pvpg\posy4613\absw340\absh231 \sl-187 \f10 \fs11 \cf0 {\fs1
8 Al }\par
}
{\phpg\posx5097\pvpg\posy4952\absw316\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 Sn
\par
}
{\phpg\posx5350\pvpg\posy4926\absw158\absh132 \f10 \fs11 \cf0 \f10 \fs11 \cf0 4+
\par
}
{\phpg\posx5774\pvpg\posy4013\absw938\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0 >
5 mg/L
\par}{\phpg\posx5774\pvpg\posy4013\absw938\absh1053 \sl-313 \f10 \fs18 \cf0 > 5
mg/L
\par}{\phpg\posx5774\pvpg\posy4013\absw938\absh1053 \sl-313 \f10 \fs18 \cf0 > 5
mg/L
\par}{\phpg\posx5774\pvpg\posy4013\absw938\absh1053 \sl-313 \f10 \fs18 \cf0 > 5
mg/L \par
}
{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Akan mengganggu pengujian. Ortofosfat akan mengendapkan kalsium pada pH 12 sampa
i
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-236 \f10 \fs18 \cf0 den
gan pH 13. Strontium dan Barium akan mengganggu pengujian ini, jika kalinitas co
ntoh
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-238 \f10 \fs18 \cf0 uji
lebih besar dari 300 mg/L dapat menyebabkan warna titik akhir titrasi tidak jel
as.
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-238 \par\f10 \fs18 \cf0
{\b 3.5}{\b
Persiapan}{\b contoh}{\b uji }
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-237 \par\f10 \fs18 \cf0
a) Gunakan 50 mL contoh uji air atau jumLah yang sesuai dan diencerkan dengan
air suling
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-238 \f10 \fs18 \cf0 \fi
319 hingga volume 50 mL (kandungan kalsium 5 mg/L sampai dengan 10 mg/L), masukk

an
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-237 \f10 \fs18 \cf0 \fi
319 ke dalam labu Erlenmeyer 250 mL.
\par}{\phpg\posx2118\pvpg\posy5466\absw8969\absh2272 \sl-171 \par\f10 \fs18 \cf0
b) Apabila tidak dapat segera dianalisis, awetkan contoh uji dengan H
NO{\dn006 \fs11 3} sampai pH 2. \par
}
{\phpg\posx2118\pvpg\posy7920\absw5917\absh490 \f10 \fs18 \cf0 \fi319 \f10 \fs18
\cf0 Waktu simpan contoh uji tidak lebih dari 6 bulan.
\par}{\phpg\posx2118\pvpg\posy7920\absw5917\absh490 \sl-314 \f10 \fs18 \cf0 c)
Perlakuan awal ({\i pre}{\i treatment}) contoh uji atau limbah cair \par
}
{\phpg\posx2456\pvpg\posy8546\absw8586\absh502 \f10 \fs18 \cf0 \f10 \fs18 \cf0 J
ika contoh uji memerlukan digesti awal, lakukan digesti dengan asam nitrat (HNO{
\dn006 \fs11 3}) atau
\par}{\phpg\posx2456\pvpg\posy8546\absw8586\absh502 \sl-237 \f10 \fs18 \cf0 deng
an asam nitrat - asam perklorat - asam fluorida (HNO {\dn006 \fs11 3} - HClO{\d
n006 \fs11 4} - HF), dengan cara \par
}
{\phpg\posx2456\pvpg\posy9023\absw3105\absh674 \f10 \fs18 \cf0 \f10 \fs18 \cf0 s
ebagai berikut:
\par}{\phpg\posx2456\pvpg\posy9023\absw3105\absh674 \sl-252 \par\f10 \fs18 \cf0
{\b 1)}{\b
Digesti}{\b asam}{\b nitrat}{\b (HNO}{\b\dn006 \fs11 3}{\b ) }
\par
}
{\phpg\posx2795\pvpg\posy9812\absw308\absh1481 \f10 \fs18 \cf0 \f10 \fs18 \cf0 (
a)
\par}{\phpg\posx2795\pvpg\posy9812\absw308\absh1481 \sl-275 \par\f10 \fs18 \cf0
(b)
\par}{\phpg\posx2795\pvpg\posy9812\absw308\absh1481 \sl-314 \f10 \fs18 \cf0 (c)
\par}{\phpg\posx2795\pvpg\posy9812\absw308\absh1481 \sl-275 \par\f10 \fs18 \cf0
(d) \par
}
{\phpg\posx2796\pvpg\posy12017\absw308\absh1481 \f10 \fs18 \cf0 \f10 \fs18 \cf0
(e)
\par}{\phpg\posx2796\pvpg\posy12017\absw308\absh1481 \sl-314 \f10 \fs18 \cf0 (f)
\par}{\phpg\posx2796\pvpg\posy12017\absw308\absh1481 \sl-275 \par\f10 \fs18 \cf0
(g)
\par}{\phpg\posx2796\pvpg\posy12017\absw308\absh1481 \sl-275 \par\f10 \fs18 \cf0
(h) \par
}
{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Campur contoh uji dan pindahkan sejumLah volume yang sesuai (50 mL
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-238 \f10 \fs18 \cf0 sam
pai dengan 100 mL) ke dalam labu alas bulat atau erlenmeyer 125 mL.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-170 \par\f10 \fs18 \cf0
Tambahkan 5 mL HNO{\dn006 \fs11 3} pekat dan beberapa batu didih atau butiran
gelas.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-285 \f10 \fs18 \cf0 Did
ihkan perlahan-lahan dan uapkan pada{\i hot}{\i plate} hingga volume
contoh uji
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-237 \f10 \fs18 \cf0 men
jadi yang mungkin kira-kira 10 mL -20 mL.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-170 \par\f10 \fs18 \cf0
Lanjutkan pemanasan dan tambahkan HNO{\dn006 \fs11 3} pekat sesuai kepe
rluan hingga
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-209 \f10 \fs18 \cf0 dig
esti sempurna yang terlihat dari larutan jernih-berwarna. Hindari contoh
uji

\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-238 \f10 \fs18 \cf0 men

jadi kering selama digesti.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-311 \f10 \fs18 \cf0 Bil
as dinding labu erlenmeyer dengan air suling dan saring jika perlu.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-314 \f10 \fs18 \cf0 Pin
dahkan filtrat ke dalam labu ukur 100 mL bilas beker dengan bantuan 5 mL
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-238 \f10 \fs18 \cf0 air
suling (sebanyak 2 kali), tambahkan hasil cucian ini ke dalam labu ukur.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-311 \f10 \fs18 \cf0 Din
ginkan, encerkan dengan air suling hingga tanda tera, dan campurkan
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-238 \f10 \fs18 \cf0 sam
pai homogen.
\par}{\phpg\posx3303\pvpg\posy9812\absw7712\absh3465 \sl-311 \f10 \fs18 \cf0 Amb
il sebagian dari larutran ini untuk keperluan penentuan kalsium. \par
}
{\phpg\posx2456\pvpg\posy13909\absw3235\absh251 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 2) Digesti HNO {\dn006 \fs11 3} - HClO {\dn006 \fs11 4} - HF \par
}
{\phpg\posx2796\pvpg\posy14222\absw308\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 (
a) \par
}
{\phpg\posx3303\pvpg\posy14222\absw7728\absh828 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Campurkan contoh uji dan ukur sejumLah volume yang sesuai ke dalam beker
\par}{\phpg\posx3303\pvpg\posy14222\absw7728\absh828 \sl-237 \f10 \fs18 \cf0 tef
lon (TFE) volume 250 mL.
\par}{\phpg\posx3303\pvpg\posy14222\absw7728\absh828 \sl-228 \par\f10 \fs18 \cf0
\fi2754 {\fs17 4}{\b \fs17 dari}{\b \fs17 8 }\par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx8676\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \f10 \fs18 \cf0 \f10 \fs18 \cf0 (
b)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-313 \f10 \fs18 \cf0 (c)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-311 \f10 \fs18 \cf0 (d)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-276 \par\f10 \fs18 \cf0
(e)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-275 \par\f10 \fs18 \cf0
(f)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-314 \f10 \fs18 \cf0 (g)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-275 \par\f10 \fs18 \cf0
(h)
\par}{\phpg\posx2796\pvpg\posy1607\absw308\absh3037 \sl-275 \par\f10 \fs18 \cf0
(i) \par
}
{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Tambahkan beberapa butir batu didih dan didihkan perlahan-lahan.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-313 \f10 \fs18 \cf0 Uap
kan dengan menggunakan{\i hot}{\i plate}, hingga volumenya 15 mL - 20 mL.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-170 \par\f10 \fs18 \cf0
Tambah 12 mL HNO{\dn006 \fs11 3} pekat, dan uapkan hingga hamp
ir kering. Ulangi
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-237 \f10 \fs18 \cf0 pen
ambahan HNO{\dn006 \fs11 3} dan uapkan, kemudian didinginkan.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-314 \f10 \fs18 \cf0 Tam
bahkan 20 mL HClO{\dn006 \fs11 4} dan 1 mL HF, didihkan sampai laruta
n jernih dan
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-237 \f10 \fs18 \cf0 tim

bul asap putih HClO {\dn006 \fs11 4}, kemudian didinginkan.

\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-284 \f10 \fs18 \cf0 Tam
bahkan air suling {\ul +} 50 mL dan disaring.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-314 \f10 \fs18 \cf0 Pin
dahkan filtrat ke dalam labu ukur 100 mL bilas beker dengan bantuan 5 mL
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-237 \f10 \fs18 \cf0 air
suling (sebanyak 2 kali), tambahkan hasil cucian ini ke dalam labu ukur.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-313 \f10 \fs18 \cf0 Din
ginkan, encerkan dengan air suling hingga tanda tera, dan campurkan
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-238 \f10 \fs18 \cf0 sam
pai homogen.
\par}{\phpg\posx3303\pvpg\posy1607\absw7672\absh3037 \sl-311 \f10 \fs18 \cf0 Amb
il sebagian dari larutran ini untuk keperluan penentuan kalsium. \par
}
{\phpg\posx2118\pvpg\posy7551\absw342\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 3.6 \par
}
{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \f10 \fs17 \cf0 \fi159 \f10 \fs1
7 \cf0 CATATAN
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-160 \par\f10 \fs17 \cf0
\fi159 Pemanasan campuran HClO{\dn006 \fs11 4} dan bahan organik dapat
meledak kuat. Hindarkan bahaya ini
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-188 \f10 \fs17 \cf0 \fi
159 dengan mengikuti prosedur berikut:
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-159 \par\f10 \fs17 \cf0
\fi159 1.
Jangan menambahkan HClO{\dn006 \fs11 4} pada larutan panas yang m
engandung bahan organik
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-262 \f10 \fs17 \cf0 \fi
159 2.
Lakukan{\i pretreatment} (perlakuan awal) contoh uji yang mengandung
bahan organik
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-292 \f10 \fs17 \cf0 \fi
159 3.
Digesti dilakukan di dalam ruang asam yang telah dikon
disikan oleh digesti dengan
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-215 \f10 \fs17 \cf0 \fi
497 menggunakan asam HClO4
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-159 \par\f10 \fs17 \cf0
\fi159 4.
Hindari contoh uji yang di digesti dengan HClO {\dn006 \fs11 4} m
enguap sampai kering
\par}{\phpg\posx2636\pvpg\posy5204\absw8064\absh2320 \sl-222 \par\f10 \fs17 \cf0
{\b \fs18 Prosedur }\par
}
{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \f10 \fs18 \cf0 \f10 \fs18 \cf0
a) Ambil 50,0 mL contoh uji secara duplo, masukkan ke dalam labu Erlenmeyer 25
0 mL.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-313 \f10 \fs18 \cf0 b)
Tambahkan 2 mL larutan NaOH 1 N (secukupnya) sampai dicapai pH 12-13.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-314 \f10 \fs18 \cf0 c)
Apabila contoh uji keruh, tambahkan 1mL sampai dengan 2 mL larutan KCN 10%.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-311 \f10 \fs18 \cf0 d)
Tambahkan seujung spatula atau setara dengan 30 mg - 50 mg indikator mureksid.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-171 \par\f10 \fs18 \cf0
e) Lakukan titrasi dengan larutan baku Na{\dn006 \fs11 2}EDTA 0,01 M
sampai terjadi perubahan warna
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-208 \f10 \fs18 \cf0 \fi
319 merah muda menjadi ungu.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-171 \par\f10 \fs18 \cf0
f)
Catat volume larutan baku Na{\dn006 \fs11 2}EDTA yang digunakan.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-313 \f10 \fs18 \cf0 g)
Apabila larutan Na{\dn006 \fs11 2}EDTA yang dibutuhkan untuk titrasi lebih da

ri 15 mL, encerkan contoh

\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-209 \f10 \fs18 \cf0 \fi
319 uji dengan air suling dan ulangi langkah 3.6.a). s/d 3.6.f) dari 3.6.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-171 \par\f10 \fs18 \cf0
h) Ulangi titrasi tersebut 2 kali, kemudian volume Na{\dn006 \fs11 2}EDTA y
ang digunakan dirata-ratakan.
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-284 \f10 \fs18 \cf0 i)
Jika{\i spike}{\i matrix} digunakan sebagai control mutu, lakukan dengan ca
ra sebagai berikut:
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-314 \f10 \fs18 \cf0 \fi
338 Ambil 15 mL contoh uji, tambahkan 10 mL larutan standar kalsium karbonat 0,0
1 M dan
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-237 \f10 \fs18 \cf0 \fi
338 encerkan dengan air suling hingga volumenya 50 mL, masukkan ke dal
am erlenmeyer
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-237 \f10 \fs18 \cf0 \fi
338 250 mL. Lakukan langkah 3.6 b) sampai dengan 3.6 h).
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-218 \par\f10 \fs18 \cf0
{\fs17 CATATAN}{\fs17
Tidak}{\fs17
terjadinya}{\fs17
perubahan}{\fs1
7
warna}{\fs17
pada}{\fs17
titik}{\fs17
akhir}{\fs17
titrasi}{\fs
17
yang}{\fs17
jelas}{\fs17
biasanya}{\fs17
harus }
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-215 \f10 \fs18 \cf0 {\f
s17 ditambahkan}{\fs17 inhibitor}{\fs17 pada}{\fs17 tahap}{\fs17 ini,}{\fs17
atau}{\fs17 mungkin}{\fs17 indikator}{\fs17 telah}{\fs17 mengalami}{\fs17
kerusakan. }
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-236 \par\f10 \fs18 \cf0
{\b 3.7}{\b
Perhitungan }
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-238 \par\f10 \fs18 \cf0
{\b 3.7.1}{\b
Kadar}{\b kalsium,}{\b Ca }
\par}{\phpg\posx2117\pvpg\posy8048\absw8974\absh5509 \sl-251 \par\f10 \fs18 \cf0
Hitung kadar kalsium sebagai CaCO{\dn006 \fs11 3} dalam contoh uji dengan meng
gunakan rumus sebagai \par
}
{\phpg\posx2118\pvpg\posy14135\absw698\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 b
erikut \par
}
{\phpg\posx6057\pvpg\posy14932\absw694\absh189 \b \f10 \fs17 \cf0 \b \f10 \fs17
\cf0 5 dari 8 \par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\shp\shpfhdr0\shpbxpage\shpbypage\shpfblwtxt1\shpz0
\shpleft4743\shptop1902\shpright5288\shpbottom1902
{\*\shpinst {\sp{\sn shapeType}{\sv 20}}
{\sp{\sn fFlipH}{\sv 0}}{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn LineWidth}{\sv
9}}
{\sp{\sn fBehindDocument}{\sv 1}}{\sp{\sn lineColor}{\sv
0}}}}
{\shp\shpfhdr0\shpbxpage\shpbypage\shpfblwtxt1\shpz0
\shpleft3794\shptop5637\shpright4332\shpbottom5637
{\*\shpinst {\sp{\sn shapeType}{\sv 20}}
{\sp{\sn fFlipH}{\sv 0}}{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn LineWidth}{\sv
9}}
{\sp{\sn fBehindDocument}{\sv 1}}{\sp{\sn lineColor}{\sv
0}}}}
{\phpg\posx2118\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2118\pvpg\posy1731\absw2723\absh705 \f10 \fs18 \cf0 \f10 \fs18 \cf0 K
adar kalsium (mg Ca/L){\f40 \fs20
= }
\par}{\phpg\posx2118\pvpg\posy1731\absw2723\absh705 \sl-256 \par\f10 \fs18 \cf0
dengan pengertian : \par

}
{\phpg\posx2251\pvpg\posy2539\absw1042\absh1428 \f20 \fs20 \cf0 \f20 \fs20 \cf0
V{\fs17 C }{\fs17 .}{\fs17 u}{\fs17 . }
\par}{\phpg\posx2251\pvpg\posy2539\absw1042\absh1428 \sl-367 \f20 \fs20 \cf0 {\f
s20 V}{\fs16 EDTA}{\f40 \fs22 (}{\fs16 a}{\f40 \fs22 ) }
\par}{\phpg\posx2251\pvpg\posy2539\absw1042\absh1428 \sl-292 \par\f20 \fs20 \cf0
{\fs20 M}{\dn006 \fs16 EDTA }
\par}{\phpg\posx2251\pvpg\posy2539\absw1042\absh1428 \sl-320 \f20 \fs20 \cf0 {\d
n006 \fs20 V}{\fs17 EDTA}{\f40 \fs23 [}{\fs17 b}{\f40 \fs23 ] }\par
}
{\phpg\posx3404\pvpg\posy2521\absw705\absh1353 \f10 \fs18 \cf0 \f10 \fs18 \cf0 a
dalah
\par}{\phpg\posx3404\pvpg\posy2521\absw705\absh1353 \sl-338 \f10 \fs18 \cf0 adal
ah
\par}{\phpg\posx3404\pvpg\posy2521\absw705\absh1353 \sl-307 \par\f10 \fs18 \cf0
adalah
\par}{\phpg\posx3404\pvpg\posy2521\absw705\absh1353 \sl-320 \f10 \fs18 \cf0 adal
ah \par
}
{\phpg\posx4759\pvpg\posy1615\absw561\absh554 \f20 \fs20 \cf0 \fi22 \f20 \fs20 \
cf0 1000
\par}{\phpg\posx4759\pvpg\posy1615\absw561\absh554 \sl-187 \par\f20 \fs20 \cf0 V
{\fs17 C }{\fs17 .}{\fs17 u}{\fs17 . }\par
}
{\phpg\posx5331\pvpg\posy1757\absw1186\absh279 \f20 \fs20 \cf0 \f20 \fs20 \cf0 x
V
\par}{\phpg\posx5331\pvpg\posy1757\absw1186\absh279 \sl-224 \f20 \fs20 \cf0 \fi3
34 {\fs17 EDTA}{\f40 \fs22 (}{\fs17 b}{\f40 \fs22 ) }\par
}
{\phpg\posx6483\pvpg\posy1757\absw436\absh225 \f20 \fs20 \cf0 \f20 \fs20 \cf0 x
M \par
}
{\phpg\posx6886\pvpg\posy1757\absw1001\absh276 \f20 \fs17 \cf0 \f20 \fs17 \cf0 E
DTA{\fs20 x}{\fs20 40 }\par
}
{\phpg\posx4249\pvpg\posy2521\absw6299\absh1392 \f10 \fs18 \cf0 \f10 \fs18 \cf0
volume larutan contoh uji (mL)
\par}{\phpg\posx4249\pvpg\posy2521\absw6299\absh1392 \sl-183 \par\f10 \fs18 \cf0
volume rata-rata larutan baku Na{\dn006 \fs11 2}EDTA untuk titrasi kesa
dahan
\par}{\phpg\posx4249\pvpg\posy2521\absw6299\absh1392 \sl-209 \f10 \fs18 \cf0 tot
al (mL).
\par}{\phpg\posx4249\pvpg\posy2521\absw6299\absh1392 \sl-202 \par\f10 \fs18 \cf0
molaritas larutan baku Na{\dn006 \fs11 2}EDTA untuk titrasi (mmol/mL).
\par}{\phpg\posx4249\pvpg\posy2521\absw6299\absh1392 \sl-320 \f10 \fs18 \cf0 vol
ume rata-rata larutan baku Na{\dn006 \fs11 2}EDTA untuk titrasi kalsium (mL) \p
ar
}
{\phpg\posx2117\pvpg\posy4389\absw7102\absh636 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 3.7.2
Persen temu balik{\b0 (%}{\b0\i Recovery}{\b0 ,}{\b0 %}{\b0 R)
}
\par}{\phpg\posx2117\pvpg\posy4389\absw7102\absh636 \sl-238 \par\b \f10 \fs18 \c
f0 {\b0 Persen}{\b0 temu}{\b0 balik}{\b0 dihitung}{\b0 dengan}{\b0 mengguna
kan}{\b0 rumus}{\b0 sebagai}{\b0 berikut}{\b0 : }\par
}
{\phpg\posx3165\pvpg\posy5466\absw653\absh249 \f20 \fs20 \cf0 \f20 \fs20 \cf0 %
R{\f40 = }\par
}
{\phpg\posx3810\pvpg\posy5324\absw575\absh535 \f20 \fs20 \cf0 \f20 \fs20 \cf0 A{
\f40 {\field{\*\fldinst SYMBOL 45 \\f Symbol }}} B

\par}{\phpg\posx3810\pvpg\posy5324\absw575\absh535 \sl-317 \f20 \fs20 \cf0 \fi17

8 C \par
}
{\phpg\posx4393\pvpg\posy5492\absw804\absh225 \f20 \fs20 \cf0 \f20 \fs20 \cf0 x
100 % \par
}
{\phpg\posx2117\pvpg\posy6163\absw1857\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 d
engan pengertian: \par
}
{\phpg\posx2117\pvpg\posy6477\absw201\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0 R
\par}{\phpg\posx2117\pvpg\posy6477\absw201\absh1053 \sl-311 \f10 \fs18 \cf0 A
\par}{\phpg\posx2117\pvpg\posy6477\absw201\absh1053 \sl-313 \f10 \fs18 \cf0 B
\par}{\phpg\posx2117\pvpg\posy6477\absw201\absh1053 \sl-314 \f10 \fs18 \cf0 C \p
ar
}
{\phpg\posx2518\pvpg\posy6477\absw5612\absh1481 \f10 \fs18 \cf0 \f10 \fs18 \cf0
adalah{\i recovery};
\par}{\phpg\posx2518\pvpg\posy6477\absw5612\absh1481 \sl-311 \f10 \fs18 \cf0 ada
lah kadar contoh uji yang di{\i spike} (mg/L);
\par}{\phpg\posx2518\pvpg\posy6477\absw5612\absh1481 \sl-313 \f10 \fs18 \cf0 ada
lah kadar contoh uji yang tidak di{\i spike} (mg/L);
\par}{\phpg\posx2518\pvpg\posy6477\absw5612\absh1481 \sl-314 \f10 \fs18 \cf0 ada
lah kadar standar yang diperoleh ({\i target}{\i value}) (mg/L).
\par}{\phpg\posx2518\pvpg\posy6477\absw5612\absh1481 \sl-238 \par\f10 \fs18 \cf0
\fi277 dimana, \par
}
{\phpg\posx2830\pvpg\posy8253\absw451\absh247 \f20 \fs20 \cf0 \f20 \fs20 \cf0 C{
\f40 = }\par
}
{\phpg\posx3294\pvpg\posy8135\absw660\absh510 \f20 \fs20 \cf0 \f20 \fs20 \cf0 Y
x Z
\par}{\phpg\posx3294\pvpg\posy8135\absw660\absh510 \sl-319 \f20 \fs20 \cf0 \fi21
5 V \par
}
{\phpg\posx2795\pvpg\posy8709\absw4816\absh1053 \f10 \fs18 \cf0 \f10 \fs18 \cf0
dengan pengertian:
\par}{\phpg\posx2795\pvpg\posy8709\absw4816\absh1053 \sl-311 \f10 \fs18 \cf0 Y a
dalah volume standar yang ditambahkan (mL);
\par}{\phpg\posx2795\pvpg\posy8709\absw4816\absh1053 \sl-314 \f10 \fs18 \cf0 Z a
dalah kadar kalsium yang ditambahkan (mg/L);
\par}{\phpg\posx2795\pvpg\posy8709\absw4816\absh1053 \sl-313 \f10 \fs18 \cf0 V a
dalah volume akhir (mL). \par
}
{\phpg\posx2117\pvpg\posy10363\absw146\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 4 \par
}
{\phpg\posx2626\pvpg\posy10363\absw3982\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 Jaminan mutu dan pengendalian mutu \par
}
{\phpg\posx2117\pvpg\posy10838\absw1973\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 4.1
Jaminan mutu \par
}
{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \f10 \fs18 \cf0 \f10 \fs18 \cf0
a)
\par}{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \sl-314 \f10 \fs18 \cf0 b)
\par}{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \sl-311 \f10 \fs18 \cf0 c)
\par}{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \sl-314 \f10 \fs18 \cf0 d)
\par}{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \sl-313 \f10 \fs18 \cf0 e)
\par}{\phpg\posx2117\pvpg\posy11314\absw228\absh1616 \sl-311 \f10 \fs18 \cf0 f)

\par
}
{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Gunakan bahan kimia berderajat pro analisis (p.a.).
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-314 \f10 \fs18 \cf0 Gu
nakan alat gelas bebas kontaminan.
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-311 \f10 \fs18 \cf0 Gu
nakan alat ukur yang terkalibrasi atau terverifikasi.
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-314 \f10 \fs18 \cf0 Gu
nakan air suling untuk pembuatan semua pereaksi dan larutan kerja.
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-313 \f10 \fs18 \cf0 Di
kerjakan oleh analis/penguji yang berkompeten.
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-311 \f10 \fs18 \cf0 La
kukan uji dalam jangka waktu yang tidak melampaui waktu simpan maksimu
m
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-238 \f10 \fs18 \cf0 ({
\i holding}{\i time}) yaitu 6 bulan setelah diasamkan dengan asam nitrat hingga
pH kurang
\par}{\phpg\posx2651\pvpg\posy11314\absw8398\absh2045 \sl-237 \f10 \fs18 \cf0 da
ri 2. \par
}
{\phpg\posx6057\pvpg\posy14932\absw692\absh189 \f10 \fs17 \cf0 \f10 \fs17 \cf0 6
{\b dari}{\b 8 }\par
}
{\shp\shpfhdr0\shpbxpage\shpbypage\shpfblwtxt1\shpz0
\shpleft3277\shptop8422\shpright3925\shpbottom8422
{\*\shpinst {\sp{\sn shapeType}{\sv 20}}
{\sp{\sn fFlipH}{\sv 0}}{\sp{\sn fFlipV}{\sv 0}}
{\sp{\sn LineWidth}{\sv
9}}
{\sp{\sn fBehindDocument}{\sv 1}}{\sp{\sn lineColor}{\sv
0}}}}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx8676\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx2118\pvpg\posy1628\absw8575\absh706 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 4.2
Pengendalian mutu
\par}{\phpg\posx2118\pvpg\posy1628\absw8575\absh706 \sl-252 \par\b \f10 \fs18 \c
f0 {\b0 Lakukan}{\b0 uji}{\b0 secara}{\b0 duplo}{\b0 untuk}{\b0 kontrol}{\b
0 ketelitian.}{\b0 Perbedaan}{\b0 pemakaian}{\b0 larutan}{\b0 Na}{\b0\dn006
\fs11 2}{\b0 EDTA }\par
}
{\phpg\posx2118\pvpg\posy2341\absw4794\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 s
ecara duplo tidak boleh lebih besar dari 0,10 mL. \par
}
{\phpg\posx2118\pvpg\posy3056\absw146\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 5 \par
}
{\phpg\posx2626\pvpg\posy3056\absw1440\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18
\cf0 Rekomendasi \par
}
{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Lakukan kontrol akursi dengan salah satu cara dibawah ini:
\par}{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \sl-238 \par\f10 \fs18 \cf0
a)
Analisis CRM
\par}{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \sl-313 \f10 \fs18 \cf0 \fi
400 Lakukan analisis{\i Certified}{\i Reference}{\i Material} (CRM) unt
uk kontrol akurasi. Larutan
\par}{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \sl-237 \f10 \fs18 \cf0 \fi
400 pekat CRM diencerkan dengan air suling sampai konsentrasi 1,0 mg/L.

Kemudian
\par}{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \sl-238 \f10 \fs18 \cf0 \fi
400 lakukan langkah 3.5 b) dan 3.5.g) dari 3.5.
\par}{\phpg\posx2118\pvpg\posy3531\absw8930\absh1627 \sl-311 \f10 \fs18 \cf0 b)
Lakukan uji{\i blind}{\i sample. }\par
}
{\phpg\posx2118\pvpg\posy5424\absw228\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 c)
\par
}
{\phpg\posx2518\pvpg\posy5424\absw8520\absh421 \f10 \fs18 \cf0 \f10 \fs18 \cf0 K
isaran persen temu balik adalah 85% sampai dengan 115% atau sesuai de
ngan
\par}{\phpg\posx2518\pvpg\posy5424\absw8520\absh421 \sl-237 \f10 \fs18 \cf0 krit
eria dalam sertifikat CRM. \par
}
{\phpg\posx2118\pvpg\posy5974\absw8939\absh703 \f10 \fs18 \cf0 \f10 \fs18 \cf0 d
)
Untuk kontrol gangguan matriks lakukan uji{\i spike}{\i matrix}.
Kisaran persen temu balik
\par}{\phpg\posx2118\pvpg\posy5974\absw8939\absh703 \sl-238 \f10 \fs18 \cf0 \fi4
00 adalah 85% sampai dengan 115%.
\par}{\phpg\posx2118\pvpg\posy5974\absw8939\absh703 \sl-311 \f10 \fs18 \cf0 e)
Buat kartu kendali ({\i control}{\i chart}) untuk akurasi pengujian. \par
}
{\phpg\posx6057\pvpg\posy14932\absw694\absh189 \b \f10 \fs17 \cf0 \b \f10 \fs17
\cf0 7 dari 8 \par
}
\sect\sectd\pard\plain
\pgwsxn12240\pghsxn15840
{\phpg\posx2118\pvpg\posy806\absw2082\absh207 \b \f10 \fs18 \cf0 \b \f10 \fs18 \
cf0 SNI 06-6989.13-2004 \par
}
{\phpg\posx5764\pvpg\posy1607\absw1322\absh876 \b \f10 \fs20 \cf0 \b \f10 \fs20
\cf0 Lampiran A
\par}{\phpg\posx5764\pvpg\posy1607\absw1322\absh876 \sl-353 \b \f10 \fs20 \cf0 \
fi127 {\b0 \fs18 (informatif) }
\par}{\phpg\posx5764\pvpg\posy1607\absw1322\absh876 \sl-368 \b \f10 \fs20 \cf0 \
fi75 Pelaporan \par
}
{\phpg\posx2118\pvpg\posy3303\absw4394\absh207 \f10 \fs18 \cf0 \f10 \fs18 \cf0 C
atat pada buku kerja hal-hal sebagai berikut: \par
}
{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \f10 \fs18 \cf0 \f10 \fs18 \cf0 1
)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-314 \f10 \fs18 \cf0 2)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-311 \f10 \fs18 \cf0 3)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-314 \f10 \fs18 \cf0 4)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-313 \f10 \fs18 \cf0 5)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-313 \f10 \fs18 \cf0 6)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-313 \f10 \fs18 \cf0 7)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-313 \f10 \fs18 \cf0 8)
\par}{\phpg\posx2118\pvpg\posy3779\absw228\absh2463 \sl-313 \f10 \fs18 \cf0 9) \
par
}
{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \f10 \fs18 \cf0 \f10 \fs18 \cf0
Parameter yang dianalisis.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-314 \f10 \fs18 \cf0 Nam
a dan tanda tangan/ analis.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-311 \f10 \fs18 \cf0 Tan
ggal analisis.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-314 \f10 \fs18 \cf0 Rek

aman volume titrasi

\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-313 \f10 \fs18 \cf0 Nom
or contoh uji.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-313 \f10 \fs18 \cf0 Tan
ggal penerimaan contoh uji.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-313 \f10 \fs18 \cf0 Per
hitungan.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-313 \f10 \fs18 \cf0 Has
il pengukuran duplo.
\par}{\phpg\posx2626\pvpg\posy3779\absw3065\absh2463 \sl-313 \f10 \fs18 \cf0 Has
il pengukuran blanko. \par
}
{\phpg\posx2118\pvpg\posy6598\absw7101\absh489 \f10 \fs18 \cf0 \f10 \fs18 \cf0 1
0)
Hasil pengukuran persen{\i spike}{\i matrix} dan CRM atau{\i blind}{\
i sample. }
\par}{\phpg\posx2118\pvpg\posy6598\absw7101\absh489 \sl-313 \f10 \fs18 \cf0 11)
Kadar kalsium dalam contoh uji. \par
}
{\phpg\posx6057\pvpg\posy14932\absw692\absh189 \f10 \fs17 \cf0 \f10 \fs17 \cf0 8
{\b dari}{\b 8 }\par
}
\sect\sectd\pard\plain
}