:

 E 5 MJ )

 I  : Qr

: (1
   $ "!  :

& ('.

67 ] 5 [X 3& 2 0 (/ /  X. mol / !+,-

(2 :
&( 8 2 1 2. 3 Qr 456 ./  ) , $ &(  
+  )( % &  ) #$ (
G/  (&2
: 8 2  DE 456 > ?. &(   .456
 
:+

(3:+H 
IJ
( + 9  $ " 5( ?  @("(1) :> :

 II  ( , :
: (1

( , 0B /  6"+ :$+,7,+ ?7 "E 705  , 6
2 ./F
8 + (2  O5 456    
:
(  $7E,:
1
 Q
8 P,  
 + PJ 

R

= O5 2J G:
+  S SO G ).(, 
 TM G

S

+J  S U J (, UO5 2 UV  
(:

. S .m 1 E P,  Y$ 
J &J PJ 
X 
+.
 PJ8 Z
.  
  2J  T. 
6 .3


J D G - 
+

G = .

M + X   &(  
+ :Q

( :HE+
2

Q M. 
+J 
J [ + ()J Y.I  O5 c = 5 10 mol / T +  25C1
Q 
8  
 ( . = 343S .cm 1 :
( E  T  .^ 
6  ) , $&(  
+ _ + JO5 .
( 8  Q  O5 Qr ,'q 456.

. CH COO = 4,09mS .m 2 .mo 1 H O = 35mS .m 2 .mo 1 :E

( ,K ,$:

-----------------------------------------------------------------

[H O ] = [CH COO ] = Vx
+

= ( H O + CH COO ).

:!(

[H O ] = [CH COO ]
+

=
q

[CH COO ] [H O ]

Qr ,q =

VS

: ,(

n x ni
x
= i
=

= c H 3O +
VS
V S VS

x
343106 102 S / m
=
=
= 0,877mol / m3 = 8,77 104 mol /
3
2
VS H O+ + CH COO (35 + 4,09) 10 S.m / mo
3

[CH 3COOH ]q

xq

[CH 3COOH ]q

= 5 10 2 8,77 10 4 = 4,9 10 2 mol /

[H O ]
=
c [H O ]
2

q
+

. O5 Qr ,'q 456 8 (

(8,77 10 4 ) 2
1,57 10 5
2
4,9 10

: " $"  NIII

.` E  O5 Qr ,q 456 8 (1
.5 M
 )2 +? .  `  O5 456 8 , OJ E  O5  1 ? O

: ( ` 2

. K," 'H/+ >  ,- ," ,$ K " N

.PJ D+OJ (& ,J 456   . J ` a& 456 X 2GO bc   : >+
J

C + D

A + B

: / @(" &65

: ,(  ,$+ @ :/ " N , ?  N+VI
: )2 +` b (1
:  ,$+ ,K Q R767S T- + 

ni (

CH 3COOH )

= x max

: / ,   ,( :U2V ,$ :/ U

 c 2 = 5 10 3 mol / c1 = 5 10 2 mol /  T Y.I [ + P)J P

+  2GO ( M(
: ,

. 2  O5   2G. ?.

 66XJ
+ 
  U. P2 $( c
O5   2G. ?.
 d T? .
 ,& 5 M
 )2 +  O5 456   2G.  Q _

.2

A+ B

( aq )

:( ,$ @ :/ " N NW+(1

C+ D

( aq )

( aq )

:( 456 2.

( aq )

. ( n( A) O = n( B) O
A

( aq

( aq

"
no(B)
no(B)-xq

no(A)
no(A)-xq

aq

eG IJ  1 P2O

(c, 0 X  &Y"

: /7  Z7  ,$+ ,K
+
D

( aq
)

 
,$

0
0
0
,
xq
xq
xq
 .   0]? 7 ,^" ,^( 
:_ > -&(
=

xq

x q = .x max

x max
x q = .n ( A ) O

:( M D
5 4:+.
+  ZME D
5 xq:[  H"@ M     &( f   G 

( aq

( aq

"
c

c .c

aq

 
0

c
c .c

.c
K=

(=

1
1+

(1 ) 2

aq



,$
0

.c

.c


,
 -

: `U7 " N +

) ." 6" H/+ ,(  ,$+ @ ? 7 

.+ ( ,$ @ a /"   N a /

SBIRO Abdelkrim

Bonne chance
(Lyce Agricole Oulad-Taima rgion dAgadir Maroc)
Pour toute observation contacter mon mail
sbiabdou@yahoo.fr