Table 1.

Thermodynamic Relationships of Borax for Trial 1 in the First

Attempt
[B4O5(OH)4
1/T
Temperature
Vol. titrant
^2-]
Ksp
(1/K)
lnKsp
(K)
(mL)
328

34.15

0.683

1.274447
948

0.0030
49

0.2425
13

318

33.80

0.676

1.235663
104

0.0031
45

0.2116
08

308

33.60

0.672

1.213857
792

0.0032
47

0.1938
04

0.0033
11

0.7168
64

302
40.00
0.8
2.048000
y= -245.27x + 0.987
H= 2.0385928kJ/mol and S=25.50J/mol.K

The sample calculations below were taken from table 1 at 328 K:

N1V1=N2V2
where N2=M*2 => N2/2=M2
M2= N1V1/2V2
= (0.2 N HCl*34.15 mL)/ 2*5mL
= 0.683 M
Ksp= 4[B3O5(OH)42-]3
(
= 4*
0.683) 3
=1.274447948
1/T= 1/328 K
= 0.003049
lnKsp= ln(1.274447948)
= 0.242513
H = (-245.27)*(-8.314 J/mol)*(1kJ/1000J)
=2.0385928 kJ/mol
S= (0.987)* 8.314 J/mol.K
=25.50J/mol.K
G = H-TS
= 2.0385928 kJ/mol- [(328 K)*(25.50J/mol.K)*(1kJ/1000J)
=-6.3250 kJ/mol

G
6.325
0
6.070
1
5.815
1
5.662
1