ethane / propane mixture

82.06
1.9872

MW Ethane
Tc
Pc

30.07
305.5
48.2

K
atm

a=
b=

97495552
45.0936

MW Propane
Tc
Pc

44.09
370
42

K
atm

a=
b=

180617084
62.6763

T
P
342.4833 27.21661799

ethane
T0
propane
T0
Mixture V
T0

T ( R)
P (bar)
T (K)
P (atm)

R
Rgas

cm3atm/(mol-K)

h cal/g-mol
0.0000

150

Cv

200

342.48
ethane
propane
sum

Cv

yi/xi
0.0170
0.9830
1

h cal/g-mol
-107.6002

h total
-107.6002
-4.4167
-193.6789

Cv_a_E

Cv_b_E

Cv_c_E

Cv_d_E

-0.3392

0.04124

-0.0000153

1.74E-009

Cv_a_P

Cv_b_P

Cv_c_P

Cv_d_P

-2.9532

0.07279

-0.00003755

7.58E-009

Cv

Cv_a
Cv_b
Cv_c
Cv_d
-2.9086888 0.072252767 -3.71711E-005 7.481E-009

Cv

Cv_a
Cv_b
Cv_c
Cv_d
-2.9280186 0.072495334 -3.73388E-005 7.524E-009

composition fixed

Mixture L
ethane
propane
sum

0.0099
0.9903
1.0002

Iterations here

616.47
27.579
342.4833
27.21662

RK-EOS

iterate to find v
v (cm3/gmol) 636.123731

4.304 lb/ft3

eq (8-11)
-2.805E-007
Fugacity coefficient term by term

Fugacity coefficient calculations

cal/g-mol
Btu/lb
Btu/lb-mol

Dew-point calculations

a_E
RK-EOS

97495552
a_P

RK-EOS

Ethane
Propane

180617084

45.0936

s0

4067.66881 5.5412019
h0

b_P
62.6763

s0

4576.62465 2.9448348

RK-EOS

a
178988914

b
62.3769

MW
43.8513

RK-EOS

a
179758005

b
62.5176

MW
43.9620

RK-EOS

-0.277577
-0.385809

Ethane
Propane

h0

b_E

0.5876576283
0.5876576283

iterate to find v
v (cm3/gmol) 131.01058

20.948 lb/ft3

eq (8-11)
2.0933E-007

Fugacity coefficient term by term

Fugacity coefficient calculations

Ethane
Propane

2.7131140203
2.7131140203

Dew-point calculations

-0.629782
-0.875343

Ethane
Propane

ethane
propane
Sum 2

New xi
0.009915
0.990334
1.000249

Fugacity Coefficient
Sum
-0.388694 -0.078614 0.924397
-0.518294 -0.316445 0.728735

Fugacity Vapor
0.428407 atm
19.49598 atm

Fugacity Coefficient
Sum

-1.621142 0.46219 1.587547

-2.161678 -0.323907 0.723318

Fugacity Liquid
0.428407 atm
19.49598 atm