Vapor

ethane
R
Tc
Pc

82.06
305.5
48.2

RK-EOS
h and s
T
P
281.6506 26.87641

cm3atm/(mol-K)
K
atm

a=
b=

h cal/g-mol
1032.9005

T ( R)
P (bar)
T (K)
P (atm)

97495552
45.0936

h cal/g-mol
40.9014

h total
5141.4707
307.7677
9254.5733

You will not need anything below this line - below row 13 is data from Reynolds (1979) and the fit for ho and so
Solution Vapor Phase ethane RK-EOS to allow check with data from Reynolds
T0
Rgas

150
1.9872

T (K)
340
420
580
340
420
580
340
420
580

P (atm)
9.869233
9.869233
9.869233
39.47693
39.47693
39.47693
98.69233
98.69233
98.69233

Cv

Cv_a

Cv_b

Cv_c

Cv_d

-0.3392

0.04124

-0.0000153

1.74E-009

h cal/g-mol
Cv dT
1677.6289
2734.5134
5397.9098
1677.6289
2734.5134
5397.9098
1677.6289
2734.5134
5397.9098

h cal/g-mol
RK-EOS
570.5312
763.8768
1114.3054
182.6920
537.6765
999.3731
-1079.5588
45.5494
788.2894

ethane Vapor Phase Data from Reynolds (1979)

MW
T (K)
340
420
580
340
420
580
340
420
580

P(Mpa)
1
1
1
4
4
4
10
10
10

P (atm)
9.869233
9.869233
9.869233
39.47693
39.47693
39.47693
98.69233
98.69233
98.69233

T (K)
340
420
580

P(Mpa)
1
1
1

P (atm)
9.869233
9.869233
9.869233

h total
6315.8290
7566.0589
10579.8841
5927.9897
7339.8587
10464.9518
4665.7390
6847.7316
10253.8680

Everything below is data from Reynolds

30.07
v (m3/kg)
0.08926
0.1133
0.1593
0.01813
0.02614
0.03904
0.00397
0.00892
0.01523

v cm3/kg
89260
113300
159300
18130
26140
39040
3970
8920
15230

v cm3/g
89.26
113.3
159.3
18.13
26.14
39.04
3.97
8.92
15.23

h (kJ/kg)
h (kcal/kg)
h(cal/g-mol)
823.910
196.919
5921.361
996.870
238.258
7164.407
1413.550
337.847
10159.046

v cm3/gmol
2684.0482
3406.931
4790.151
545.1691
786.0298
1173.9328
119.3779
268.2244
457.9661

340
420
580
340
420
580

4
4
4
10
10
10

39.47693
39.47693
39.47693
98.69233
98.69233
98.69233

766.560
965.160
1398.370
589.900
894.940
1369.250

183.212
230.679
334.218
140.989
213.896
327.259

5509.192
6936.511
10049.949
4239.554
6431.847
9840.666

506.971
27.234
281.650556
26.8764103

cal/g-mol
Btu/lb
Btu/lb-mole

RK-EOS

iterate to find v
v (cm3/gmol) 591.283

3.175 lb/ft3

eq (8-11)
-2.605E-007
s cal/g-mol-K
4.7918

s cal/g-mol-K
12.1182

s total
22.4512 cal/g-mol-K
0.7466 Btu/lb-R

and the fit for ho and so

a
RK-EOS

97495552
s cal/g-mol-K
Cv/T dT
6.8667
9.6492
14.9843
6.8667
9.6492
14.9843
6.8667
9.6492
14.9843

s(kJ/kg-K)
3.5345
3.9904
4.8257

h0

s0

4067.66881

5.541202

b
45.0936

s cal/g-mol-K
RK-EOS
15.5859
16.0966
16.8038
12.0181
12.9616
13.8973
7.2225
10.2737
11.7932

s (kcal/kg-K) s(cal/g-mol-K)
0.8448
25.4021
0.9537
28.6786
1.1534
34.6818

s total
27.9937
31.2870
37.3293
24.4260
28.1520
34.4228
19.6304
25.4641
32.3187

3.0271
3.5520
4.4218
2.3579
3.1719
4.1279

0.7235
0.8489
1.0568
0.5636
0.7581
0.9866

21.7555
25.5279
31.7790
16.9460
22.7961
29.6668