7.4: Analysing neutralisation 1. Neutasatin isthe reaction between am acid an bso frm 1, ample HCl + NaOH NaCl + HO 2HNO; + MgO Manoj, + HO Complete the equation cus HS, POH, + HNO) > calom, + HL Kon + H+ Neo +1480. 5. ar neurasation point, all Hons fom the seid are neutralised by OFF ons from the alkali or vice-versa. pH ofthe tration product 97 (acute, ls. Titration process is.@ A mead io de ation between 5. the procedure for neutralisation: |. The volume of alkali fed, putin conical a 1. Added a few drops of indicator. ‘i, Another solution of aid is dropped rom a burette unt {he end-point ts reached (9 Using an indicator (i) Using electric conductivity = we OE 1 i Eee an (0) Use pipet daw op Doce of ‘edn [NrOH sluon io a conic Iroc, NAOH wlon. Pk A to ce drops Penola Inia volume ns sae nner Sedan 4 ior Meecha (© Fila bree wit (4) Aa seo ai, HCI HCl ‘op by drop ino the ala ‘Recodo bares reading, _Solucom. Swi the coments Pe ake Final ‘lame = Newraed cious) (6) Commas ang yrohlone sek, CT unt te inane ‘ange car Record Sl ‘ree ding. where M, =molarity of volume of acid In an experiment, 25.0 cm of a sodium hydroxide solution of unknown concentration required 26.50 cm* of 1.0 mol dm sulphuric acid for complete reaction in titration, Calculate the molarity of sodium hydroxide. Example 2 What is the volume of 1.5 mol dm aqueous ammonia required to completely neutralise 30.0 cm? of 0.5 mol dm sulphuric acid? Example 3 Calculate the volume (cm') of 2.0 mol dm* hydrochloric acid that is required to react completely with 2.65 g of sodium carbonate. [Relative atomic mass: C, 12; O, 16; Na, 23] Examole 4 15 cm’ of an acid with the formula H,X of 0.1 mol dm required 30 cm’ of 0.15 mol dm* sodium hydroxide solution for complete neutralisation. Calculate the value of a and hence determine the basicity of the acid. 1 Complete the blanks in the equations below: (a) 2HCl+Mg—> + (b) HO, + Zn(OH), > + (© (____]+ NaOH = CH,COONa + H,O @ + — CaSO, + 2H,0 v Nitric acid reacts with magnesium hydroxide solution to produce magnesium nitrate, Mg(NO,), and water. (a) Write a balanced equation for the reaction between nitric acid and magnesium hydroxide. (b) 10.0 cm? of nitric acid is required to neutralise 0.001 mol of magnesium hydroxide. Calculate the concentration of the nitric acid in mol dm-*. w Sodium carbonate reacts with hydrochloric acid as represented by the equation below: Na,CO,(s) + 2HCI(aq) > 2NaCI(aq) + H,0(1) + CO,(@) Calculate the volume (cm*) of 1.25 mol dm? hydrochloric acid that is required to react completely with 25.0 cm} of 1.0 mol dry sodium carbonate. 15.0 cmé of sulphuric acid neutralises 25.0 cm* of 2.0 mol dm-® aqueous ammonia. Calculate the molarity of the sulphuric acid used. 2