1. Sn** + 26° 2 Be 4 e980 E°=0.13V ez @* Br +2 —> 2Br E°= 1.08 KK, K Calculate K,q for the cell reaction for the cell 43. Half-life of radioactive element is 16 h. What formed by two electrodes. time it will take for 75% disintegration ? (@) 10% (b) 10% (a) 32 days ®) 32h © 10 @ 10% © 4h @ 16h 42. Consider the reaction, ‘4. Friedel-Craft acylation can be given by 1 NO, —= 5N2 +02; K Cx At or NO, 2N0,; Ky Give the equilibrium constant for the xis formation of N;O, from N, and 03. @k-G—a WRG R et++ of 3 mk aE © ao (@) R—O—R45. Which of the following is having maximum acidic strength ? 6 6. 6 6 46. For the reaction, Na,CO, + 2HCl—» NaCl+H,0 + CO, equivalent weight of Na;COs is @ M2 ®) M © 2M @ M/A 47. Excited state configuration of Mn?" is @ ©) the Othe @ he 48. Which of the following is thermosetting polymer ? (@) Nylon-6 (b) Bakelite (© Nylon66 (4) SBR 49. x AaXO44 Yellow or white ppt Which of the following cannot be X ? Br @ CO () (CH,),CH! ‘CH.Br Nic oy oC 50. Rate of a reaction can be expressed by following rate expression Rate = kA]? (BJ, if concentration of A is increased by 3 times and concentration of B is increased by 2 times, how many times rate of reaction increases ? (a) 9 times (© 18 times (b) 27 times (a) 8 times 51. 55. 56. 37. HC. . Sat—on 8, What is the reason for unusual high b.p. of water ? (@) Due to presence of H* and OH” ions in water (b) Due to dipole-dipole interactions (©) Due to London forces (@) Strong London forces, Shine at freshly cut sodium is {@) due to oscillation of free electrons (b) due to weak metallic bonding (©) due to absorption of light in crystal lattice (@) due to presence of free valency at the surface ‘Most acidic oxide among the following is @ co; @) co © dp; @ ap, x, xis CHy (@) CH,—CH— CH, —CH, a ©) eae —cHy CHs He: CHy © Daren’ HC CH, cu, I (@) CH; —CH—CH, CH,CH, Which of the following statements is wrong ? (@) Metals are more than non-metals (b) There are only few metalloids (© Hydrogen can be placed with alkali metals as well as with halogen in periodic table (d) Non-metals are more than metals ‘What volume of M/10 NaOH is added in SO mL M/I0 acetic acid solution to get a buffer solution having highest buffer capacity ? (@) 50 mL (b) 25 mL © 10mL @ 40 mL Monomer of nucleic acid is (a) nucleotide (b) nucleoside (© amino acid (@) carboxylic acid61. 62. 64. . If volume containing gas is compressed to half, how many moles of gas remained in the vessel? (a) just double () just half © same (@ more than double ‘At same temperature, calculate the ratio of average velocity of SO, to CH,. @ 2:3 3:4 © 1:2 @1:6 ). IF temperature of 1 mole of gas is increased by 50°C, calculate the change in kinetic energy of the system. (@) 623.253 —(b) 6.2355 (©) 623.55 @ 6235.05 Give name of the complex, name should sped the postion of ligands ? d | (@ bis iridium (1) ) is i om (© carbonylchlorobistransphosphineiridium (1) (@ chlorocarbonyibistransphosphineiticium (1) CHO. Ozonolysis produets of an eS and CH,CHO | + Olefin is CH,CHO @ Q ) oO © Co @ (1 |. A bubble of volume V, is in the bottom of a pond at 15°C and 1.5 atm pressure. When it ‘comes at the surface it observes a pressure of 1 atm at 25°C and have volume V;, give 4 A (@) 155 ©) 0.85 (© 1550 (@) 155 Volume of 0.6 M NaOH required to neutralize 30 em? of 0.4 M HCl is (@) 20cm? (b) 40 cm? (© 45cm? (@) 30cm? 65. The orbital angular momentum of an electron in 3s orbital is h Oe @ zero 66. Decomposition of H,0; is prevented by (a) KOH (b) MnO, (©) acetanilide (@) oxalic acid 67. The bad smelling substance formed by the action of alcoholic caustic potash on chloroform and aniline is (a) nitrobenzene (b) phenyl isocyanide (©) phenyl cyanide (4) phenyl isocynate 68. What is the EAN of nickel in Ni(CO), ? @ 38 () 20 © 36 @ 32 69, P+ 3NGOH+ 3HO—> A+ 3NAH,PO, here Ais + @ NHy ) PH, O,H,PO4 @ H,PO, 70. If solubility of calcium hydroxide is V3, then its solubility product will be @ 27 © 3 @9 @) 12/3 71. Which of the following compounds is optically active ? (@ (CH,),CHCH,OH () CH,CH,OH (© CCAP, (@ CH,CHOHC,H, 72. Which compound is soluble in water ? @ cs, (©) C,H,0H ca, @ cid, 173. In a cubi¢ structure of diamond which is made from X and Y, X atoms are atthe comers ofthe ‘cube and ¥ at the face centres of the cube. The ‘molecular formula of the compound is @ XY ©) XY © x, (@) 2% 174. Bithional is an example of (@) disinfectant (b) antiseptic (©) antibiotic (4) analgesic75. Aand B in the following reactions are CH, CH LH g, RK 0H i i R—C—R'—— 5 A-4, C. (@) [« x” Sexignt, fH fe nN 78. Ry N—CH = CH, #5 product (@) ARR'ICC B= LiALH, ae wee ‘OH Predominant product is OH R3N—CH—cH, (b) A=RR'C. x a GEN —a i Br (b) R3N—CH, —CH,—Br 28 (© CH, =CH—NR, Br (@) A=RR'CH,CN, B = NaOH (@) No reaction 76. Structure of XeFS ion is 79. Mark out the enthalpy of formation of carbon (@) trigonal bipyramidal monoxide (CO). (b) square pyramidal Given, C(s) + 0.2(g¢) —+ CO2(g); (©) octahedral AH =~ 393.3 kJ/mol (@) pentagonal 1 : 77. Mark out the most unlike form of COG Peco polymerisation of CH, =CH——CH—CH, AH =~ 282.8 kJ/mol H Pee (2) =110.5 ks/mol @ Deel (@) 676.1 d/mol cHy 1H (© = 2828 kJ/mol H na (@) ~ 300.0 k/mol BS ae 80. The magnetic moment of a transition metal ion >) jpn is 3.87 BM. The number of unpaired electrons ch, ‘cH,), present in it, is @2 &) 3 Gach cic, ©4 @s5 © fondue In Answer — Key au_b [4 b [43 b [44 a [45 a [46 a [47 b [48% b [4% a [50 c b a d © d b a © © a a c d a d c b c b a d b d b a b d 5 a b