:

prof : Zegrir. derradji

www.mentouri.forumactif.com

-*1
:1
-*1 t = 0 100 ml ) (2K +S2O
C2= 0.036 mol / L 100 mL
) ( K+ + I- . C1 = 0.4 mol / L
. ) (1 Ox / Red I2 / I , S2O82- / SO42- :
).(1 ) n(I2 ). x(t -*2 t V= 10 ml
50 ml .
) ( 2Na+ + S2O32- . C3 = 0.02 mol / L
. ) .Veq
(. :
)t (min
0
3
6
9
12
16
20
30
40
50
60
Veq(mmo 0.0 2.5 5.1 7.1 8.4 10.6 11.4 14.1 15.6 16. 16.4
)l
1
2
8

. . ). (2 Ox / Red I2 / I- , S4O62- / S2 O32- : .

).(2 ) n0 (I2 V= 10 ml . Veq ) n (I2 V= 200 ml Veq. ) x(t . Veq
:)t (min
0
3
6
9
12
16
20
30
40
50
60
)X(m moL
1Cm0.5mmoL :.
1Cm10min
- ) . X=f(t

)X(m moL
)t (min

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 -*2
:2

1mL -2 -2 )(CH3)3C-Cl(aq
. RCl :
)(CH3)3C-Cl(aq) + 2H2O(L) = (CH3)3C- OH(aq) + H3O+(aq) + Cl-(aq
)R-Cl(aq) + 2H2O(L) = R-OH(aq) + H3O+(aq) + Cl-(aq
) H3O+(aq ) Cl-(aq
) (.
) ( Sonde
-1 -
t=0

:

-1 -
31
1.95

28
1.95

0
3
6
9
13
16
19
22
25
0 0.49 0.98 1.27 1.46 1.66 1.76 1.85 1.90

)t(min
) (s.m-1

.+
- ) (t ) x(t ) O

(H )(Cl-

V . ) x(t )V (t

+
) O

(H). (Cl-

f ) n0 (RCL V ) (t f) x(t. n0
:0
3
6
9
13
16
19
22
25
28
31
0 0.49 0.98 1.27 1.46 1.66 1.76 1.85 1.90
1.95 1.95
) X= f(t . : = 0.85 g/ml : RCl

+
) O

(Cl-) (H

)t(min
) (s.m-1
)X(m moL

Zegrir derradji

Lyce Ahmed Cherif

mentouri .ain mlila
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