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NH3
Cp Constant
A
Tb (K)
Tc (K)
Hvap
Hf
(kJ/kmol) (kJ/kmol)
###
239.65
405.6
23362
-45900
N2
31.150
2.68E-05
###
63.25
126.2
5581
H2
27.143 9.27E-03
###
7.65E-09
20.35
33.2
904
###
Stream 3
Stream 1
Stream 2
M-1
Operating condition :
Stream
1
2
3
18
298.15
298.15
250.34
231.30
60.00
60.00
59.97
59.97
Phase
Vapor
Vapor
Vapor
Vapor
Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
Stream
Component
(inlet)
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
HV
(kJ/hr)
N2
380.1200
0.0000
0.0000
H2
1140.3000
0.0000
0.0000
18
NH3
46.0400
-2313.3687
-45900
-2219743.4957
N2
849.6100
-1954.0110
-1660147.3229
H2
2572.0000
-1923.3943
-4946970.2288
Total
-8826861.0474
Stream
Component
(outlet)
3
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
HV
(kJ/hr)
NH3
46.0400
-1668.1522
-45900
-2190037.7270
N2
1230.5000
-1396.4576
-1718341.0159
H2
3712.4000
-1377.1397
-5112493.2706
Total
-9020872.0135
T (K)
31.150
-1.356E-02
2.679E-05
-1.168E-08
298.1500
27.143
9.27E-03
-1.38E-05
7.65E-09
298.1500
27.315
2.38E-02
1.71E-05
-1.18E-08
231.2950
31.150
-1.36E-02
2.68E-05
-1.17E-08
231.2950
27.143
9.27E-03
-1.38E-05
7.65E-09
231.2950
T (K)
27.315
2.38E-02
1.71E-05
-1.18E-08
250.3400
31.150
-1.36E-02
2.68E-05
-1.17E-08
250.3400
27.143
9.27E-03
-1.38E-05
7.65E-09
250.3400
To (K)
298.15
298.15
298.15
298.15
298.15
To (K)
298.15
298.15
298.15
Stream 3
Stream 4
Operating condition :
Stream
3
4
C-2
Temperature Temperature
(C)
(K)
-22.81
108.15
E-1
250.34
381.30
Pressure
2 (atm)
Phase
59.97
172.74
Vapor
Vapor
Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
CpdT
Hf
(kJ/kmole) (kJ/kmole)
HV
(kJ/hr)
Stream
(inlet)
Component
Flowrate
(kmole/hr)
NH3
46.0400
-1668.1522
-45900
-2190037.7270
N2
1230.5000
-1396.4576
-1718341.0159
H2
3712.4000
-1377.1397
-5112493.2706
Total
-9020872.0135
CpdT
Hf
(kJ/kmole) (kJ/kmole)
HV
(kJ/hr)
Stream
(outlet)
Component
Flowrate
(kmole/hr)
NH3
46.0400
3069.8481
-45900
-1971900.1954
N2
1230.5000
2426.8046
2986183.0846
H2
3712.4000
2411.0888
8950925.9232
Total
9965208.8123
T (K)
27.315
2.38E-02
1.71E-05
-1.18E-08
250.3400
31.150
-1.36E-02
2.68E-05
-1.17E-08
250.3400
27.143
9.27E-03
-1.38E-05
7.65E-09
250.3400
T (K)
27.315
2.38E-02
1.71E-05
-1.18E-08
381.3000
31.150
-1.36E-02
2.68E-05
-1.17E-08
381.3000
27.143
9.27E-03
-1.38E-05
7.65E-09
381.3000
To (K)
298.15
298.15
298.15
To (K)
298.15
298.15
298.15
E-13-02
Stream 4
Stream 5
X-3
Operating condition :
Stream
Temperature
(C)
Temperature
X-1 (K)
Pressure
(atm)
Phase
F
E
960.00
380.00
1233.15
653.15
44.00
44.00
Vapor
Vapor
Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
CpdT
Hf
(kJ/kmole) (kJ/kmole)
Stream
(inlet)
Component
Flowrate
(kmole/hr)
E-13-20
all vapor
CH4
N2
442.5204
3057.8185
29197.5995
-45900
0
H2
H20
CO
CO2
7083.5874
32436.2726
2361.1958
427.64331048
27917.5582
35957.0056
29523.0589
46440.8344
0
-242000
-110620
-393770
O2
30899.5404
0
Total
Stream
(outlet)
E-13-20
all vapor
Component
CH4
N2
H2
H20
CO
CO2
O2
Flowrate
(kmole/hr)
442.5204
3057.8185
7083.5874
32436.2726305561
2361.1958035839
427.64331048
0
CpdT
Hf
(kJ/kmole) (kJ/kmole)
16149.5545 -45900
10511.7756
0
10374.4796
0
12501.6925 -242000
10579.2619 -110620
15465.6845 -393770
10980.8273
0
Total
kJ/hr
(kJ/hr)
-20311686.4133
89280959.4453
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
197756463.6329
-6683266741.1123
-191485757.1109
-148532994.2070
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.60E-005
0.0000
-6756559755.7652
28.106
-3.68E-006 1.746E-005
HV
(kJ/hr)
-13165179.0830
32143101.7277
73488532.8203
-7444069670.6570
-236215771.0849
-161779309.8534
0.0000
-7749598296.1302
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
27.143
9.27E-03
-1.38E-05
32.243
30.869
19.795
28.106
0.001924
-0.01285
0.073436
-4E-006
1.1E-005
2.8E-005
-6E-005
1.7E-005
T (K)
To (K)
1233.1500
-1.17E-08 1233.1500
298.15
298.15
1233.1500
-3.60E-09 1233.1500
-1.27E-008 1233.1500
1.715E-008 1233.1500
298.15
298.15
298.15
298.15
1233.1500
298.15
-1.13E-08
7.65E-09
-1.07E-008
T (K)
653.1500
-1.17E-08 653.1500
7.65E-09 653.1500
-4E-009 653.1500
-1E-008 653.1500
1.7E-008 653.1500
-1E-008 653.1500
-1.13E-08
To (K)
298.15
298.15
298.15
298.15
298.15
298.15
298.15
Stream 5
Stream 6
R-4
Operating condition :
Stream
5
6
Temperature
1 Temperature (K)
2
R-1
(C)
380.00
430.00
653.15
703.15
Pressure
(atm)
Phase
44.00
44.00
Vapor
Vapor
Note that the heat of reaction is automatically incuded in calculating the stream enthalpy
Assumption :
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
Stream
(inlet)
Component
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
E-13-20
all vapor
CH4
N2
442.5204
3057.8185
16149.5545
10511.7756
0
0
H2
H20
CO
CO2
7083.5874
32436.2726
2361.1958
427.64331048
12501.6925
10579.2619
15465.6845
0
-242000
-110620
-393770
O2
10980.8273
Stream
(Outlet)
R-14-01
all vapor
Component
CH4
N2
Flowrate
(kmole/hr)
44.2520
3057.8185
0
Total
CpdT
Hf
(kJ/kmole) (kJ/kmole)
12043.4070
0
11847.9631
0
H2
H20
CO
CO2
O2
8736.4245
30783.4356
708.3587
2080.480372989
0
14365.7384
12130.0295
17924.5785
12621.3452
0.0000
kJ/hr
0
-242000
-110620
-393770
0
Total
(kJ/hr)
7146507.3303
32143101.7277
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
0.0000
-7444069670.6570
-236215771.0849
-161779309.8534
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.602E-005
0.0000
-7802775142.5372
28.106
HV
(kJ/hr)
532945.3297
36228920.5205
-3.680E-006 1.746E-005
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
27.143
9.27E-03
-1.38E-05
125505188.2085
-7076187427.3938
-65661612.0481
-792972295.5381
0.0000
-7772554280.9214
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.602E-005
28.106
-3.680E-006 1.746E-005
T (K)
To (K)
-1.13E-08
653.1500
653.1500
298.15
298.15
1.715E-008
653.1500
653.1500
653.1500
653.1500
298.15
298.15
298.15
298.15
-1.065E-008
653.1500
298.15
T (K)
To (K)
-1.13E-08
703.1500
703.1500
703.1500
298.15
298.15
298.15
-1.17E-08
7.65E-09
-3.60E-09
-1.272E-008
-1.17E-08
7.65E-09
-3.60E-09
-1.272E-008
1.715E-008
-1.065E-008
703.1500
703.1500
703.1500
703.1500
298.15
298.15
298.15
298.15
Input
Output
E-14-01
Operating condition :
Stream
Input
Output
Temperature
Temperature (K)
(C)
430.00
215.00
703.15
488.15
E-1
Pressure
(atm)
Phase
44.00
44.00
Vapor
Vapor
Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
Stream
(Inlet)
Component
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
R-14-01
all vapor
CH4
N2
44.2520
3057.8185
18978.2663
12043.4070
0
0
H2
H20
CO
CO2
8736.4245
30783.4356
708.3587
2080.4803729887
11847.9631
14365.7384
12130.0295
17924.5785
0
-242000
-110620
-393770
O2
12621.3452
0
Total
Stream
(Outlet)
R-14-01
Component
CH4
Flowrate
(kmole/hr)
44.2520
CpdT
Hf
(kJ/kmole) (kJ/kmole)
7771.5860
0
all vapor
N2
3057.8185
5564.9317
H2
8736.4245
30783.4356
708.3587
2080.4803729887
0
5530.1093
6541.9409
5584.8619
7779.0204
5732.4316
0
-242000
-110620
-393770
0
Total
H20
CO
CO2
O2
kJ/hr
(kJ/hr)
839827.0035
36826552.5660
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
103508834.5676
-7007364626.1915
-69766231.5459
-781939022.6231
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.60E-005
0.0000
-7717894666.2235
28.106
HV
(kJ/hr)
343908.5339
-3.68E-006 1.746E-005
19.251
5.21E-02
1.20E-05
17016551.0839
31.150
-1.36E-02
2.68E-05
48313382.3524
-7248207991.4365
-74402558.2032
-803046657.1676
0.0000
-8059983364.8370
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.60E-005
28.106
-3.68E-006 1.746E-005
T (K)
To (K)
703.1500
-1.17E-08 703.1500
298.15
298.15
703.1500
-3.60E-09 703.1500
-1.27E-008 703.1500
1.715E-008 703.1500
298.15
298.15
298.15
298.15
-1.07E-008
703.1500
298.15
T (K)
To (K)
-1.13E-08
488.1500
298.15
-1.13E-08
7.65E-09
-1.17E-08
488.1500
298.15
7.65E-09
488.1500
488.1500
488.1500
488.1500
488.1500
298.15
298.15
298.15
298.15
298.15
-3.60E-09
-1.27E-008
1.715E-008
-1.07E-008
Input
Output
X-6
Operating condition :
Stream
Input
Output
Temperature
Temperature (K)
(C)
215.00
230.00
488.15
503.15
Pressure
(atm)
Phase
44.00
44.00
Vapor
Vapor
Assumption :
1. Reference temperature : 25 C
2. Estimated = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(Inlet)
Component
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
R-14-01
all vapor
CH4
N2
44.2520
3057.8185
7771.5860
5564.9317
0
0
H2
H20
CO
CO2
8736.4245
30783.4356
708.3587
2080.480372989
5530.1093
6541.9409
5584.8619
7779.0204
0
-242000
-110620
-393770
O2
5732.4316
0
Total
Stream
(Ounlet)
R-14-01
all vapor
Component
CH4
N2
Flowrate
(kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
44.2520
8471.3421
3057.8185
6008.7578
H20
CO
CO2
O2
9373.9473
30145.9127
70.8359
2718.003239956
0
5969.3061
7072.2178
6031.9129
8446.8093
6198.8796
0
-242000
-110620
-393770
0
Total
Heat Duty =
-2142791.3419
kJ/hr
H2
HV
(kJ/hr)
343908.5339
17016551.0839
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
48313382.3524
-7248207991.4365
-74402558.2032
-803046657.1676
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
0.0000
-8059983364.8370
28.106
HV
(kJ/hr)
374874.1722
19.251
5.21E-02
1.20E-05
-1.13E-08
18373690.8234
31.150
-1.36E-02
2.68E-05
-1.17E-08
55955960.9754
-7082112412.7591
-7408588.5694
-1047309680.8215
0.0000
-8062126156.1789
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
28.106
44.25204
30145.91
70.83587
9373.947
2718.003
0
3057.818
CH4
H2O
CO
H2
CO2
O2
N2
T (K)
To (K)
488.1500
488.1500
298.15
298.15
488.1500
488.1500
488.1500
488.1500
298.15
298.15
298.15
298.15
488.1500
298.15
T (K)
To (K)
503.1500
298.15
503.1500
298.15
503.1500
503.1500
503.1500
503.1500
503.1500
298.15
298.15
298.15
298.15
298.15
Stream 11
Stream 12
E-9
Operating condition :
Stream
Temperature
(C)
11
12
230.00
99.00
Temperature (K)
Pressure
(atm)
Phase
503.15
372.15
44.00
44.00
Vapor
Mixture
E-1
Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 C
3. Estimated = 0.38
4. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(Ounlet)
R-14-01
all vapor
Stream
(outlet)
CpdT
(kJ/kmole)
Hf
(kJ/kmole)
CH4
N2
44.2520
3057.8185
8471.3421
6008.7578
0
0
H2
H20
CO
9373.9473
30145.9127
70.8359
5969.3061
7072.2178
6031.9129
0
-242000
-110620
CO2
O2
2718.0032399564
0
8446.8093
6198.8796
-393770
0
Total
Component
Flowrate (kmole/hr)
CpdT
(kJ/kmole)
Stream
(outlet)
Component
Component
CH4
N2
H2
Liquid
Vapor
CpdT
(kJ/kmole)
0.0000
44.2520
8471.3421
0.0000
3057.8185 6008.7578
0.0000
9373.9473 5969.3061
29542.9944470581 602.918254 7072.2178
0
70.83587411 6031.9129
0
2080.480373 8446.8093
0
6198.8796
Hvap(Tb)
(kJ/kmole)
8185
5581
Hvap(T)
(kJ/kmole)
-11231.6471
-10314.9061
HL
(kJ/hr)
0
0
H20
CO
CO2
O2
904
40683
6046
17166
6824
Heat Duty=
-926912639.4517
-3134.9945
0
40739.3272 -8.1E+009
-10857.9594
0
-14316.8804
0
-10834.4473
0
Total
-8.1E+009
HV
(kJ/hr)
374874.1722
18373690.8234
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
55955960.9754
-7082112412.7591
-7408588.5694
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005
-1.272E-008
-1047309680.8215
0.0000
-8062126156.1789
19.795
0.073436
-5.602E-005 1.7153E-008
Hf (kJ/kmole)
28.106
-3.680E-006 1.746E-005
-1.065E-008
Hf (kJ/kmole)
19.251
5.21E-02
1.20E-05
-1.13E-08
0
0
-242000
-110620
-393770
31.150
-1.36E-02
2.68E-05
-1.17E-08
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005
-1.272E-008
19.795
0.073436
-5.602E-005 1.7153E-008
28.106
HV
(kJ/hr)
-3.680E-006 1.746E-005
-1.065E-008
flowrate
liquid
0.0000
0.0000
Tb (K)
Tc (K)
T (K)
31371605.771484
18373690.823439
111.65
77.35
190.6
126.2
372.1500
372.1500
55955960.975368
-141642248.25518
-7408588.569384
-801657335.56119
0
-845006914.81547
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
372.1500
0.0000
372.1500 29542.9944
372.1500
0
372.1500
0
372.1500
0
T (K)
To (K)
503.1500
503.1500
298.15
298.15
503.1500
503.1500
503.1500
298.15
298.15
298.15
503.1500
503.1500
298.15
298.15
T (K)
To (K)
503.1500
298.15
503.1500
503.1500
503.1500
503.1500
503.1500
298.15
298.15
298.15
298.15
298.15
503.1500
298.15
flowrate
Cp
vapor
3703.263 8471.342
3057.818 6008.758
9373.947
602.9183
70.83587
2080.48
0
5969.306
7072.218
6031.913
8446.809
6198.88
Hf
0
0
0
-242000
-110620
-393770
0
Stream 9
Stream 11
X-8
Operating condition :
Stream
9
11
Temperature Temperature
(C)
(K)
99.0000
99.0000
372.1500
372.1500
Pressure
(atm)
X-1
Phase
44.0000
44.0000
Mixture
Mixture
Assumption :
1. Reference temperature : 25 C
2. Estimated = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(inlet)
0
Component
CH4
N2
H2
H20
CO
CO2
O2
Flowrate (kmole/hr)
Liquid
0.0000
0.0000
Vapor
44.2520
3057.8185
0.0000
9373.9473
29542.99445 602.918254
0
70.83587411
0
2080.480373
0
CpdT
(kJ/kmole)
2.79E+03
2.16E+03
2.14E+03
2.51E+03
2.16E+03
2.87E+03
2.20E+03
Hvap(Tb)
(kJ/kmole)
Hvap(T)
(kJ/kmole)
HL (kJ/hr)
CH4
N2
8185
-11231.6471
5581
-10314.9061
H2
904
40683
6046
17166
6824
-3134.9945
40739.3272
-10857.9594
-14316.8804
-10834.4473
Total
0
-8278764856
0
0
0
-8278764856
Component
H20
CO
CO2
O2
Stream
(outlet)
0
Component
CH4
N2
H2
H20
CO
CO2
O2
Component
CH4
N2
H2
H20
CO
CO2
O2
Flowrate (kmole/hr)
Liquid
Vapor
0.0000
44.2520
0.0000
3057.8185
0.0000
9373.9473
29542.99445 602.918254
0
70.83587411
0
2080.480373
0
0
Hvap(Tb)
(kJ/kmole)
8185
5581
Hvap(T)
(kJ/kmole)
-11231.6471
-10314.9061
904
40683
6046
17166
6824
-3134.9945
40739.3272
-10857.9594
-14316.8804
-10834.4473
Total
Heat Duty =
197236945
CpdT
(kJ/kmole)
8471.3421405
6008.757846
5969.3060932
7072.2178166
6031.9129223
8446.8092748
6198.879581
HL (kJ/hr)
0
0
0
-8144031881
0
0
0
-8144031881
Stream 11
Hf (kJ/kmole)
0
0
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
0
-242000
-110620
-393770
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
28.106
HV
(kJ/hr)
Tb (K)
Tc (K)
T (K)
123258.299362448
111.65
190.6
372.1500
6603199.80444289
77.35
126.2
372.1500
20106617.9001382
-144391900.81766
-7682679.8816589
-813266111.178249
0
-938507615.87362
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
372.1500
372.1500
372.1500
372.1500
372.1500
0
0
19.251
5.21E-02
1.20E-05
31.150
-1.36E-02
2.68E-05
0
-242000
-110620
-393770
0
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
30.869
-0.01285
2.789E-005
19.795
0.073436
-5.60E-005
Hf (kJ/kmole)
HV
(kJ/hr)
28.106
-3.68E-006 1.746E-005
Tb (K)
Tc (K)
T (K)
374874.172238171
18373690.8234388
111.65
77.35
190.6
126.2
372.1500
372.1500
55955960.9753684
-141642248.25518
-7408588.569384
-801657335.56119
0
-876003646.41471
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
372.1500
372.1500
372.1500
372.1500
372.1500
T (K)
To (K)
372.1500
372.1500
298.15
298.15
372.1500
372.1500
372.1500
372.1500
298.15
298.15
298.15
298.15
372.1500
298.15
flowrate
liquid
vapor
Cp
Hf
0.0000
44.2520
2785.37
0.0000
3057.818 2159.448
T (K)
To (K)
503.1500
-1.17E-08 503.1500
298.15
298.15
503.1500
503.1500
503.1500
503.1500
503.1500
298.15
298.15
298.15
298.15
298.15
-1.13E-08
7.65E-09
-3.60E-09
-1.27E-008
1.715E-008
-1.07E-008
flowrate
Cp
liquid
vapor
0.0000
44.2520 8471.342
0.0000 3057.818 6008.758
Hf
0
0
Stream 8
F-7
Stream 10
Operating condition :
F-1
Temperature Temperature
Stream
(C)
(K)
8
99.00
372.15
9
65.00
338.15
10
65.00
338.15
Pressure (atm)
Phase
44.00
44.00
44.00
Vapor
Vapor
Vapor
Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
Component
(inlet)
0
CH4
N2
H2
H20
Flowrate (kmole/hr)
Liquid
0.0000
0.0000
Vapor
44.2520
3057.8185
0.0000
0
9373.9473
602.9182540216
CpdT
Hf
(kJ/kmole) (kJ/kmole)
2.79E+03
2.16E+03
0
0
2.14E+03
2.51E+03
0
-242000
CO
CO2
O2
0
0
0
70.8358741075 2.16E+03
2080.4803729887 2.87E+03
0
2.20E+03
-110620
-393770
0
Total
Flowrate (kmole/hr)
Liquid
Vapor
CpdT
Hf
(kJ/kmole) (kJ/kmole)
CH4
N2
0.0000
44.2520
1467.3003
0.0000
3057.8185
1166.9404
H2
0.0000
0
0
0
0
9373.9473
602.9182540216
70.8358741075
2080.4803729887
0
1157.6681
1352.343
1167.8585
1521.4177
1181.2012
0
-242000
-110620
-393770
0
Hvap(Tb)
(kJ/kmole)
8185
5581
Hvap(T)
(kJ/kmole)
-10380.5837
-9747.9252
HL
(kJ/hr)
0
0
HV
(kJ/hr)
64931.03
3568292
904
40683
6046
17166
6824
-3011.5642
42583.5389
-10243.5874
-10998.5522
-10156.8953
Total
0
0
0
0
0
0
10851919
-1.5E+008
-7753138
-8.2E+008
0
-9.5E+008
Heat Duty=
-15916721.9476
Stream
Component
(outlet)
H20
CO
CO2
O2
Component
CH4
N2
H2
H20
CO
CO2
O2
HV
(kJ/hr)
To (K)
123258.2994
6603199.8044
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
372.1500
-1.17E-08 372.1500
298.15
298.15
20106617.9001
-144391900.8177
27.143
9.27E-03
-1.38E-05
32.243
1.92E-03
1.06E-05
372.1500
-3.60E-09 372.1500
298.15
298.15
7.65E-09
T (K)
-7682679.8817
-813266111.1782
0.0000
-938507615.8736
30.869
19.795
28.106
372.1500
0.073436 -5.60E-005 1.715E-008 372.1500
-3.68E-006 1.746E-005 -1.07E-008 372.1500
-0.01285
2.789E-005 -1.27E-008
298.15
298.15
298.15
T (K)
19.251
5.21E-02
1.20E-05
-1.13E-08
338.1500
31.150
-1.36E-02
2.68E-05
-1.17E-08
338.1500
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
338.1500
338.1500
338.1500
338.1500
338.1500
28.106
Tb (K)
Tc (K)
T (K)
111.65
77.35
190.6
126.2
338.1500
338.1500
flowrate
liquid
vapor
0.0000 44.25204
0.0000 3057.818
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
338.1500
338.1500
338.1500
338.1500
338.1500
0.0000
0
0
0
0
9373.947
602.9183
70.83587
2080.48
0
To (K)
298.15
298.15
298.15
298.15
298.15
298.15
298.15
Cp
Hf
1467.3
1166.94
0
0
1157.668
0
1352.343 -242000
1167.859 -110620
1521.418 -393770
1181.201
0
Stream 12
F-10
Stream 14
Operating condition :
1
Temperature
Stream
(C)
12
65.00
13
35.00
14
35.00
F-1
2
Temperature (K) 3Pressure (atm)
338.15
308.15
308.15
44.00
43.97
43.97
Phase
Vapor
Mixture
vapor
Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
CH4
N2
44.2520
3057.8185
CpdT
(kJ/kmole)
1467.3003
1166.9404
H2
9373.9473
1157.6681
Stream
Component Flowrate (kmole/hr)
(inlet)
R-14-01
all vapor
Hf
(kJ/kmole)
0
0
0
HV
(kJ/hr)
64931.0304
3568291.8506
10851919.4116
H20
CO
CO2
O2
Stream
Component
(outlet)
=
602.9182540216
70.8358741075
2038.870765529
0
1352.3430
1167.8585
1521.4177
1181.2012
Flowrate (kmole/hr)
-242000
-110620
-393770
0
Total
-145090865.1726
-7753138.1142
-799744167.2905
0.0000
-938103028.2847
CpdT
(kJ/kmole)
Hf (kJ/kmole)
358.38051
291.76021
0
0
Liquid
0.0000
0.0000
Vapor
44.2520
3057.8185
H20
CO
CO2
0.0000
602.9182540216
0
0
9373.9473
0
70.835874108
2038.8707655
288.9882
336.96082
291.82559
373.86426
0
-242000
-110620
-393770
O2
294.12727
Hvap(T)
(kJ/kmole)
-9521.5899
-9198.6749
HL
(kJ/hr)
0
0
15859.0689087537
892149.76820625
-2895.3539
44108.9102
-9646.6056
-4856.4990
-9490.9403
Total
0
-1.7E+008
0
0
0
-1.7E+008
2708960.12583864
0
-7815192.67314669
-802083880.427255
0
-806282104.137448
CH4
N2
H2
8185
5581
H2
H20
CO
CO2
O2
904
40683
6046
17166
6824
Heat Duty=
-40476200.6199
HV
(kJ/hr)
T (K)
To (K)
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
338.1500
338.1500
298.15
298.15
27.143
9.27E-03
-1.38E-05
7.65E-09
338.1500
298.15
32.243
1.92E-03
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
28.106
1.06E-05
-3.60E-09
338.1500
338.1500
338.1500
338.1500
298.15
298.15
298.15
298.15
T (K)
To (K)
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
308.1500
308.1500
298.15
298.15
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
308.1500
308.1500
308.1500
308.1500
298.15
298.15
298.15
298.15
308.1500
298.15
28.106
flowrate
liquid
vapor
0.0000
44.2520
0.0000
3057.8185
Tb (K)
Tc (K)
T (K)
Cp
111.65
77.35
190.6
126.2
308.1500
308.1500
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
308.1500 0.0000
9373.9473 288.9882
308.1500 602.9183
0
336.9608
308.1500
0
70.83587411 291.8256
308.1500
0
2038.870766 373.8643
308.1500
0
0
294.1273
358.3805
291.7602
Hf
0
0
0
-242000
-110620
-393770
0
Stream 14
Stream 15
Stream 10
M-11
Operating condition :
Temperature Temperature
2
Stream
(C)
(K)
M-1
10
35.00
308.15
14
35.00
308.15
15
-23.29
249.86
Pressure
(atm)
44.00
43.97
59.97
Phase
Vapor
vapor
Mixture
Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
Component
(inlet)
Operating conditionCH4
:
N2
H2
H20
Flowrate (kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
Liquid
Vapor
0.0000
44.2520 358.38051
0
0.0000
3057.8185 291.76021 -45900
0.0000
602.918254
9373.9473 288.9882
0
336.96082
0
-242000
CO
70.8358741 291.82559
-110620
CO2
O2
0
0
2038.87077 373.86426
0
294.12727
-393770
0
Component
Hvap(Tb)
(kJ/kmole)
Hvap(T)
(kJ/kmole)
HL
(kJ/hr)
HV
(kJ/hr)
CH4
N2
8185
-9521.5899
15859.069
5581
-9198.6749
892149.77
H2
904
40683
6046
17166
6824
-2895.3539
0
2708960
44108.9102 -1.7E+008
0
-9646.6056
0
-7815193
-4856.4990
0
-8.0E+008
-9490.9403
0
0
Total
-1.7E+008 -8.1E+008
H20
CO
CO2
O2
Stream
Component
(inlet)
0
CH4
N2
H2
H20
CO
CO2
O2
Component
CH4
N2
H2
H20
CO
CO2
O2
Flowrate (kmole/hr)
CpdT
Hf
Liquid
Vapor
(kJ/kmole) (kJ/kmole)
0.0000
44.2520 358.38051
0
0.0000
3057.8185 291.76021
0
0.0000
9373.9473 288.9882
602.918254
0
336.96082
0
70.8358741 291.82559
0
2038.87077 373.86426
0
0
294.12727
Hvap(Tb)
(kJ/kmole)
8185
5581
904
40683
6046
17166
6824
Hvap(T)
(kJ/kmole)
-9521.5899
-9198.6749
HL
(kJ/hr)
0
0
0
-242000
-110620
-393770
0
HV
(kJ/hr)
15859.069
892149.77
-2895.3539
0
2708960
44108.9102 -1.7E+008
0
-9646.6056
0
-7815193
-4856.4990
0
-8.0E+008
-9490.9403
0
0
Total
-1.7E+008 -8.1E+008
Heat Duty =
T (K)
To (K)
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
308.1500
308.1500
298.15
298.15
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
308.1500
308.1500
298.15
298.15
30.869
-0.01285
2.789E-005 -1.27E-008
308.1500
298.15
19.795
0.073436
-5.60E-005 1.715E-008
308.1500
308.1500
298.15
298.15
28.106
flowrate
liquid
vapor
Tb (K)
Tc (K)
T (K)
111.65
190.6
308.1500
0.0000
77.35
126.2
308.1500
0.0000
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
T (K)
To (K)
19.251
5.21E-02
1.20E-05
-1.13E-08
31.150
-1.36E-02
2.68E-05
-1.17E-08
308.1500
308.1500
298.15
298.15
27.143
9.27E-03
-1.38E-05
7.65E-09
32.243
1.92E-03
1.06E-05
-3.60E-09
30.869
-0.01285
2.789E-005 -1.27E-008
19.795
0.073436
-5.60E-005 1.715E-008
308.1500
308.1500
308.1500
308.1500
308.1500
298.15
298.15
298.15
298.15
298.15
28.106
Cp
Hf
358.3805
3057.8185 291.7602
44.2520
flowrate
Cp
liquid
vapor
0.0000
44.2520 358.3805
0.0000 3057.8185 291.7602
Tb (K)
Tc (K)
T (K)
Hf
111.65
77.35
190.6
126.2
308.1500
308.1500
20.35
373.15
81.65
194.65
90.15
33.2
647.3
132.9
304.2
154.6
0
0
Stream
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Manual
(kJ/hr)
0
0
-9020872.01350509
9965208.8123242
-7444069670.65697
#REF!
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Simulation
(kJ/hr)
178430
1128300
-2649300
17961000
68530000
62200000
50548000
-19635000
-2472700
-17162000
-3326900
-5461400
-4395500
-1065900
-18228000
-269.06
-18228000
-3956000
-439550
Error (%)
100
100
-240.50021
44.5175168
10962.4977
#REF!
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