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FULL TEST II
Paper 1
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FIITJEE
Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part is further divided into three sections: Section-A, Section-B & Section-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
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Useful Data
PHYSICS
2
g = 10 m/s
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
me = 9.1 1031 kg
Density of water
Atmospheric pressure
Pa = 105 N/m2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
Atomic No:
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
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Physics
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
PART I
SECTION A
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
Which of the following is the most accurate instrument for measuring length?
(A) vernier calipers having 20 divisions on the sliding scale which coincide with 19 divisions on
the main millimeter scale
(B) a screw gauge having pitch 1 mm and 50 divisions on the circular scale
(C) a vernier scale of least count 0.01 mm
(D) a screw gauge of least count 0.001 mm
2.
3.
2m
450
(B) 0.20
(D) 0.33
A small ball thrown with an initial velocity u directed at an angle = 37 above the horizontal
collides inelastically (e = 1/4) with a vertical massive wall moving with a uniform horizontal
velocity u/5 towards ball. After collision with the wall, the ball returns to the point from where it
was thrown. Neglect friction between ball and wall. The time t from beginning of motion of the ball
till the moment of its impact with the wall is (tan37 = 3/4)
3u
18u
(A)
(B)
5g
25 g
(C)
54u
125 g
(D)
54u
25 g
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4.
A cube of side l and mass M is placed on rough horizontal surface and the friction is sufficient so
that it will not move, if a constant force F = Mg is applied horizontally l/4 above the surface. Then
the torque due to normal force about center of the cube is equal to
Mgl
Mgl
(A)
(B)
2
4
Mgl
(C)
(D) zero
8
5.
6.
Magnetic field
v0
q,m
Liquid
D
2
air
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1
B
kg is connected
2
by a massless inextensible string and kept on
k= 0.2
horizontal surface. Coefficient of friction between block
s= 0.2
and surface is shown in figure. A force F kt (where
k = 1 N/s and t is time in second) applied on A. Then
(g = 10 m/s2)
(A) work done by friction force on block B is zero in time interval t = 0 to t = 3s.
(B) work done by friction force on block A is zero in time interval t = 0 to t = 3s.
(C) work done by tension on B is also zero in time interval t = 0 to t = 3s.
(D) speed of blocks at t = 10s is 27.5 m/s.
F=kt
A
k= 0.2
s= 0.4
8.
A particle starts SHM at time t 0. Its amplitude is A and angular frequency is . At time t 0 its
E
kinetic energy is
, where E is total energy. Assuming potential energy to be zero at mean
4
position, the displacement-time equation of the particle can be written as
(A) x A cos t
(B) x A sin t
6
3
(C) x A sin t
(D) x A cos t
3
6
9.
2F
4F
+
20C +
+
+
+
+
C
S
10V
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Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraph 2 multiple choice questions and based
on the other paragraphs 3 multiple choice questions have to be answered. Each of these questions has
four choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 10 and 11
A massive disc of radius R is mounted on a light axle with the axle held horizontal, the disc is made to
spin with angular speed 0. It is then lowered gently on to a level table and released as soon as its rim
makes contact with the table top. The disc begins to move along the table, skidding and picking up speed
as it goes.
10.
If k is the coefficient of kinetic friction between the rim of the disc and table top, disc will continue
to skid for a time
R0
R0
(A)
(B)
3 k g
2 k g
R0
3R0
(C)
(D)
k g
k g
11.
If initial kinetic energy of the disc is K, then the kinetic energy of the disc after it stars pure rolling
will be
2
1
(A) K
(B) K
3
2
1
3
(C) K
(D) K
3
4
Space for Rough work
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13.
14.
(B) 4 R2
(D) 4 R2
(B) unstable
(D) cant say
E0
+ +
C
+
+
+ +
If ring is slightly disturb from given position, find the angular speed of ring when it rotate by /2.
E0
E0
(A) 2
(B)
m
m
8 E 0
(C)
(D) none
m
Space for Rough work
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AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
SECTION B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
Three sound sources of same frequency f are arranged as shown in figure. S2 moves towards left
v
2v
with speed , S3 moves on a circular path of radius R with constant speed
, and S1 performs
n
n
100v 1
S.H.M. with frequency
s and amplitude 1 cm. (n > 12 and v is speed of sound)
n
S1
S
2
(A)
Column I
Beat frequency heard by S1 may be
(p)
(B)
(q)
(C)
(D)
(r)
(s)
S3
Column II
f
n
2f
n 1
zero
2f
n 1
(t)
Space for Rough work
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2.
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
Column I
The voltage applied to X-ray tube is increased.
In photo electric effect work function of the
target is increased.
Stopping potential decreased by
Wavelength of K , X-ray increased by
(p)
(q)
(r)
(s)
Column II
Average K.E. of the electrons
decreases
Average K.E. of the electrons
increases
Cut off wavelength decreases
Atomic number of target
material decreases
(t)
SECTION C
(One Integer Value Correct Type)
This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
v (m/s)
10
37
45
2.
t(s)
O
F
1 kg
=0.2
Figure (a)
2 m/s
2N
1
Figure
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3.
4.
10
6V,3
6V,2
5.
S
Q ; S 3 103 years
Starting with number of atoms of R and S in the ratio of 2 : 1, find the ratio after the lapse of three
half lives of R..
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11
Chemistry
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
PART II
SECTION A
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
(C) ( SiO )
2.
2n
3 n
(D) ( SiO )
Which of the following equations must be used for the exact calculation of [H+] of an aqueous HCl
solution at any concentration CHCl . [ K w 1014 M 2 ]
(A) [H+] CHCl
K
(C) H C HCl W
H
(B) H CHCl K w
Kw
(D) H C HCl
H
3.
Which of the following salts give different result by the action of heat?
(A) Li2CO3 and CaCO3
(B) NaHCO3 and KHCO3
(C) Hydrated MgCl2 and hydrated Na2SO4
(D) Li2SO4 and MgSO4
4.
High P & T
A
3 B C is a first order reaction. If A is strong mono protic acid and B is strong
diprotic acid and reaction kinetic is studied by using a standard solution of NaOH required to
neutralise reaction mixture at different instants of time. When initially we had taken same
concentration of A in each case.
Now it was observer that volume required after 971 sec was double that required initially, then the
half life of reaction is:
(A) 485 sec
(B) 1942 sec
(C) 3010 sec
(D) 971 sec
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AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
5.
III
II
Which of reduction potential the following is the correct decreasing order of E values:
(A) I II III
(B) III II I
(C) I III II
(D) II I III
6.
Compound A and B, both were treated with NaOH , producing a single compound C:
O
O
CH3
CH
3
HO
C.Compound C is :
heat
+
OH
(A)
OH
(B)
CH3
(C)
(D)
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1
3
N 2 g H 2 g . If Kp of the above reaction is 78.1 at 400C
For the reaction NH 3 g
2
2
which is not correct:
1/2
3 3P
(A) At pressure P degree of dissociation of NH 3 is 1
4 k p
8.
on an alkyl halide R X NH 3
RNH 3 X
(B) Increasing solvent polarity causes a large decrease in the rate of the S N 2 attack by hydroxide
ion on trimethyl sulphonium ion.
HO (CH 3 )3 S
CH 3 OH (CH 3 ) 2 S
Trimethyl sulphonium ion
DMS
(C) Increasing solvent polarity causes a small decrease in the rate of the S N 2 attack by trimethyl
amine on trimethyl sulphonium ion
(CH 3 )3 N (CH 3 )3 S
CH 3 N (CH 3 )3 (CH 3 ) 2 S
(D) All are incorrect.
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9.
20 mL of KOH solution was titrated with 0.20 mol L-1 H2SO4 solution in a conductively cell. The
data obtained were plotted to give the graph shown below:
100
Relative conductivity
80
60
40
20
0
15
45
30
-1
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraph 2 multiple choice questions and based
on the other paragraphs 3 multiple choice questions have to be answered. Each of these questions has
four choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 10 and 11
G (kJmol-1) of O2(g)
The Ellingham diagram for the reduction of haematite and that of cuprous oxide given below;
4Cu O2 2Cu2O
100
300
2CO O2 2CO2
500
700
2C O2 2CO
900
500K
1073K
TemperatureinK
On the basis of the above plot, answer the following two questions:
Space for Rough work
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10.
11.
Dolacaine, a local anesthetic, is a compound with molecular formula, C13 H 20 O 2 N 2 . It is insoluble in water
and dilute NaOH, but soluble in dil. HCl. Upon treatment with NaNO 2 and HCl and then with -naphthol,
a highly coloured solid is formed. When Novocaine is boiled with aqueous NaOH , it slowly dissolves.
The alkaline solution is shaken with ether and layers are separated.
Acidification of the aqueous layer causes the precipitation of white solid A; continued addition of acid
causes A to redissolve. Upon isolation A is found to have melting point of 185 -186 C and the formula
C7 H 7 O 2 N :
Evaporation of ether layer leaves a liquid B of formula C6 H15 ON. with acetic anhydride gives
'C', C8 H17 O 2 N which is insoluble in water and dilute bases, but soluble in dilute HCl.
B is found to be identical to the compound formed by the action of diethylamine on ethylene oxide.
12.
When compound B is treated with p nitrobenzoyl chloride followed by moderate reduction with
Ni/H 2 ; the compound formed is:
(A)
O
NH2
(B)
OCH2NH2
O
NH2
(C)
CH2CH2N(CH2CH3)2
O
NH2
COCH2NH2OH
NO 2
CH 2OH
(D)
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13.
NaNO2 , HCl
naphthol
Dolacaine
Product
O
OCH2CH2N(CH2CH3)2
(A)
(B)
N
OH
OH
(C)
O
N
(D)
COCH2CH2N(CH2CH3) 2
OH
CH2CH2N(CH2CH3)2
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17
14.
Compound B is having:
(A) 3 amine
(C) acid group
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
[ Use log1.8 0.26, ka of formic acid 1.8 10 4 for acetic acid 1.8 105 , Ka of NH3 1.8 10 5 Ka1 ,
of H2S = 10 7 and Ka2 of H 2 S 1014 ]
Match the entries of column II for which the equality or inequality given in the column I is valid:
Column I
Column II
5
(A)
(p)
(degree
of dissociation of
10 M HCl solution> 0.1M H 2 S solution
water
water)
(B)
(q) _
CH 3 COOH solution at pH equal to
O H
4.74 NH 4 OH solution at pH equal to 9.26
(C)
(r) electrolyte (degree of dissociation
0.1M CH 3 COOH solution 1.0M HCOOH
solution
of weak electrolytes)
pH
(D)
(s)
0.1M of a weak acid HA K c 10 5 solution
0.01M of a weak acid HA2 K a 10 8
solution
(t)
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2.
(C)
Hg
Hg2 Cl2
1.1 V
(D)
Cl 0.1M
Ag / Ag
(q)
0.414V
0.118 V
(s)
0.327V
(t)
Ag
SECTION C
(One Integer Value Correct Type)
This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
compound
2.
Gold number of starch is 25. The amount of 0.3125 a gm of starch is required to prevent
coagulation of 100 ml of gold sol adding 10 ml of 10% NaCl solution? Value of a is
3.
Dimethyl gloyoxime is added to aqueous solution of nickel chloride, made alkaline, by adding
NH 4 OH solution, a brilliant red ppt is obtained. The number of Ni N bonds in red ppt
is..?
Space for Rough work
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4.
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
A coordination compound has empirical formula PdF3 . What is oxidation number of central atom?
Comprehension (Question No. 5)
The cell given below consists of three compartments separated by porous barriers. The first contains a
cobalt electrode in 5 L of 0.1 M Co(NO3)2; the second contains 5 L of 0.1 M KNO3; the third contains a
silver electrode in 5 L of 0.1 M AgNO3. Assume that the current within in the cell is carried equally by the
positive and negative ions(does not depend on the size) if there is a passage of 0.1 mole of electrons.
Co
Ag
II
III
ECo
0.28 V
2
/ Co
E Ag
0.8 V
/ Ag
5.
x
M, then the x will be:
1000
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Mathematics
20
PART III
SECTION A
Straight Objective Type
This section contains 6 multiple choice questions numbered 1 to 6. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
sin 1 x tan 1 x
is equal to
x0
x3
1
(A)
6
lim
(B)
(C) 2
2.
(D)
(A)
3.
1
2
x
c
y2
x2
xy 2 c
3
y
1
2
1
3
1, the tangent at P (2, ) and the line x 1 is
x
2
5
(B) n3
4
5
(D) n 2
8
dy 3x 2 y 4 2 xy
2
is
dx
x 2 x3 y3
(B) x3 y 2
x2
c
y
(D) x3 y 2
x2
c
y
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4.
5.
A number is selected at random from the set of natural numbers. The probability that the sum of
the digits of its square is 39 is
1
(A)
(B) 0
6
1
1
(C)
(D)
10
9
6.
A B
(A)
(C)
1
3
2
3
(B)
3
2
(D)
1
2
7.
(B) (1, 3)
(D) (3, 15)
Space for Rough work
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8.
22
1 0
The square roots of the matrix
are
0 1
1 0
(A)
0 1
1 0
(C)
0 1
9.
1 0
(B)
0 1
1 1
(D)
1 1
1 | x |
contains
2 | x |
(B) [1, 2)
(D) (2, )
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraph 2 multiple choice questions and based
on the other paragraphs 3 multiple choice questions have to be answered. Each of these questions has
four choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 10 and 11
a, b, c, d is an A.P. with integer terms and d a 2 b 2 c 2 .
10.
11.
(B) 2
(D) none
The value of a 2b 3c 4 d is
(A) 0
(C) 100
(B) 10
(D) none of these
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13.
14.
AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
(B) 30
(D) none of these
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
Column I
Length of side of equilateral triangle with vertex at
origin and inscribed in the parabola y 2 12 x is
(p)
Column II
18 3
(q)
24 3
(r)
7 5
(s)
12 2
(t)
15 5
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AITS-FT-II-(Paper-1)-PCM-JEE(Advanced)/16
2.
24
p 185
(r)
(D)
p 80
(s)
(t)
SECTION C
(One Integer Value Correct Type)
This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
2.
. The value of k is
k
3.
4.
5.
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