Vous êtes sur la page 1sur 16

1

FIITJEE

JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(PAPER-1)

ALL INDIA TEST SERIES

FIITJEE Students From Classroom / Integrated School Programs have secured to 2 Zonal, 6 State & 18 City Topper Ranks. 33 in Top 100, 78 in Top 200 and 205 in Top
500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.

AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

Q. No.

PHYSICS

CHEMISTRY

MATHEMATICS

1.
2.

C
C

D
D

B
C

3.

4.

5.

6.

7.
8.

B
C

A
A, B, C

C
A, B, D

9.

A, B, C, D

A, B, C

10.

A, B, C

B, C

B, C

11.

A, B, C

A, C

A, B

12.
13.

A
B

C
B

C
D

14.

15.

16.

A
(A) s, (B) pt,
(C) q, (D) pr
(A) pqt, (B) prt,
(C) s, (D) qr
3

1.
2.
1.
2.

D
(A) r, (B) pt,
(C) qs, (D) qs
(A) pqs, (B) q,
(C) rt, (D) q
4

A
(A) prt, (B) q,
(C) t, (D) s
(A) qt, (B) q,
(C) prs, (D) t
1

3.

5
9

7
3

2
1

4.

5.

6.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

2
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

Physics

PART I
SECTION A

1.

C
1

tan1 tan
e

vertical component after collision eucos


& Horizontal component u sin
tan

2.

u sin
1

tan1 tan
eucos
e

C
Zero
T f 2a

Ring

T
a

TR fR 2R

a R
f 0.

3.

B
I1

V t /RC1
V
e
& I2 e t /RC2
R
R
t

I1
eR C1 C2
I2

I1
e RC1
I2

4.

B
f

1
2 LC

f 50

1
2 LC / K

50 100
f 50

K
K 1 2
1

f 10 4
f

K 1.01

5.

r1 2R sin30o , r2 2R sin 60o R 3 R

i
BD B AC BCB 0 sin 60o 0 sin30 o
4

r
4

1
2

0 i
BD
4 R 3

r2

r1
30o
30o

30

30 o

6.

i
o

C
Beats

V
V
V

4 4 4

V
4 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

3
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

7.

B
3
sin60o sin90o
2
3 3
,
2 2
3 3

8.

C
13.6 10.2 3.4eV
1st collision
& 3.4 15 11.6eV 2nd collision.

9.

A, B, C, D
V

1
n
1
r

P.E.
T r 3/ 2
T.E.

10.

1
r

A, B, C
2

Vs2 3 8 4 25 Vs 5 volt
Vs
5
I
VR 3 1 R R 3

R 3
0.6
Z 5
VL VC I lags V.
P.F.

11.

A, B, C
1 1 1
v v
1
f v u
f u
since m is positive in the graph,

v
v

u
u

v
v

m 1
u
f

int ercept on m axis 1 & tan

12.

1
f

A
V
, OP x 2 y 2
R
origin is ins tan taneous centre of rotation

VP r OP

V 2
x y2
R

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

4
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

13.

a R

a R 2a

ac

V2
V
ac 2R R
R
R
2a

anet

ac
1
2a
45o
tan

14.

C
Q 300

15J / o C
T
20

Thermal heat capacity, C


15.

D
Specific heat capacity, S

16.

Q
300

600J / kg o C
m T 0.025 20

A
Molar heat capacity
Q
300

nT 25

20
50
30J / mol o C

SECTION B
1.

(A s) (B p, t) (C q) (D p, r)
In wrist watch spring force is not dependent on gravity.
T 2

m
K

2.

(A p, q, t) (B p, r, t) (C s) (D q, r)
In nuclear reactions energy, charge, mass and momentum remain conserved.

1.

SECTION C
for Rmax , 45o Hmax

20

sin2 45o

2 10

10m

Hmax allowed 5m,


5

20

Rmax

2.

sin2

2 10

20

30o

sin60o

10

m 20 3m.

5
1
3R3 R2
2
2
22

Msphere R3 , Isphere R3 R2
3
53

29 5
Iremaining portion Icylinder 2 Isphere
R .
30

Mcylinder R2 3R . Icylinder

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

5
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

3.

9
18 sin30o r 1
9 m / s.

18 sin 30o

18 m/s
18cos 30o

1m

60o
0.5m

4.

1 1 1

F f1 f2

1
1
1 1
1 2
1

24 4
20 20 4
20 20

5
1 2 .
9

5.

2
2

V 200
V 2 200
I
2.5A & P

500 watt
R
80
R
80
When the wire is divided into two equal parts and connected in parallel we get maximum power.
Re sis tance of each part 40

Imax 5A
2

Pmax

6.

200
V2

2000W 2kw.
Req
20

4
Q
Q
, VPB
3
6
Q Q
12 Q 24C
3 6
24
VAP
8
3
VA VP 8 VP 4volt.
VAP

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

6
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

Chemistry

PART II
SECTION A

1.

D
H
H

H
B

CH3

B 2 H6

CH3
CH3

CH3

2.

methylation

D
H
OH

OH

+
+

CH2

H+

ring. exp

-H2 O

HO

HO

HO

HO
OH

HO

OH

OH

H /excess
similar repetation
HO
HO

3.

A
At nodal surface, = 0
r

4.

2 2
= 1
z z

C
+2

Co ordination no of Fe in D is 6
-

Na

Fe

+2

(a sandwhich compound)

C
-

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

7
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

5.

C
O

O
+

Zn(Hg)
HCl

AlCl3

O
O

SOCl2

HO

HO

Cl

AlCl3
Br

NaBH4

H2SO4

NBS/CCl4

OH

ONa
OH
heat

6.

C
O

O
H

(a)

OH

OH

+ OH
O-D

D - OD

(b)

D - OD

DO-

DO

D - OD

D
D

H
DO - D

DO-

OD

O
D

D
D

O-D D
H

D - OD

DO - D

O
D

Repeat last two step

D
D

D
D

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

8
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16
O

H
H

(d)
OH

OH

7.

OH

HO - H

A
Synergic bonding.

8.

9.

A, B, C
log

K2
Ho T2 T1

K1 & K 2 are eq. cons tan t


K1 2.303R T1T2

log

K2
Ea T2 T1

K1 & K 2 are rate cons tan t


K1 2.303R T1T2

B
H3C

Me
N

H3C
H3C

Me

CH3

OH

CH3

H2C
CH3
(Major product)

Due to greater probability of losing -H (9 : 3 ratio).


10.

B, C
(b) conjugate base of H2PO4 is HPO24
(c) pH of 0.1 M NaCl (aqueous solution) =

11.

1
pK w
2

A, C
A 3 3e Al

Number of moles of Al produced

4.5
0.166
27

Number of moles of electrons used 3 0.166


1
H e H2
2

Number of moles of H2 produced

1
3 0.166
2

Volume of H2 produced 1.5 0.166 22.4 5.57 5.6


12.

C
2nd step is r.d.s. in sulphonation reaction.

13.

B
2nd step is fast step in nitration.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

9
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

14.

A
a

P V b RT
V

on converting into virial equation from, we get

b
2
3

2
RT b b ....... to higher power of n
PV RT
2
4
V

V
V

(i)

For Boyles temperature, 2nd virial co-efficient becomes zero


b

RT 2
a
TB
Rb
a
TB2
RB
2a
Ti
Ti 2TB2
Rb

15.

A
Let Boyles temperature, TB'
TB
TB'

16.

a
Rb
8a
a
2
2TB
R 2b
Rb

D
b2 = 0.04
b = 0.2 lit/mol
Vreal = 4 22.4 + 4 0.2 = 90.4 lit

SECTION B
1.

A r ,B p,t , C q,s D q,s .


(A) Sic covalent carbide (Not hydrolysed)
(B) Al4 C3 12H2O 4Al OH3 3CH4
(C) Cal2 2H2 O Ca OH2 H C C H
(D) Mg2 C3 4H2 O 2Mg OH 2 CH3 C CH

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

10
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

2.

A p,q,s , B q , C r,t D q .
Al2 SO4 3 2Al3 3SO 4
0.2M

0.3M

AlPO 4 Al PO
0.1M

3
4

0.1M

Urea
Urea
0.1M
MgCl2 Mg2 2Cl
0.1M 0.2M

SECTION C
1.

4
Based on fact

2.

7
OH
B
2Na

O
HO

O
O
B

OH 8H2O

OH

3.

3
OHC

CHO

CHO

,
NO2

Cl

C
N

4.

3
OCH3

,
H3CO

H3CO

OCH3

NH2

OCH3

OCH3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

11
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

5.

2
1
1 100
n100; t 90 n
K
K
10
n100 2

2
n10
1

t 99
t 99
t 90

hence x 2

6.

3
S

H
Cl

H
C

S
H
0

C C

, Cl

H
0

O
H
0

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

12
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

Mathematics

PART III
SECTION A

1.

PQ r 2 1 2r cos r 2 1 r
3

& AT r 2 1 2r cos
Where 'Q ' is the angle between

OA and OT.
2
2
now, PQ 4 AT

1 r r 4 r 1 2r cos
2

P
A

3r r 3
3r r 3
1
1; r 0
8r
8r
7 13 7 13
r
,
.
6
6

cos

2.

C
Here two balls are drawn and the result is known that the two balls are white, therefore Bayess
theorem should be used.
Required probability =

3.

1
.1
1
4

1
1 6 1 3 1 1
2
.1 . . .
4
4 10 4 10 4 10

D
Let Q x f x g x in x0 x
By LMVT,
Q x Q x 0 Q' x Q' x 0 for some C x 0 ,x
Q x 0 0, Q' C f ' C g' C 0

Q x Q x0 Q x
F' C g' C x x0 0
Q x 0 f x g x .

4.

A
A

AP = 23

(-3, 4)

5
5

13

P
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

13
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

5.

D
Sn

5
2n 5

4 2 n 1 n 2

6.

5
4

A
Equation of tan gent at 'P ' is
Y y m X x
Now,

y mx

1 m2

y 2 x 2 dy

2xy
dx

putting y vx

Solving Differential equation


x 2 y 2 Cx
It passes through 1,2 C 5
Equation of curve x 2 y 2 5x 0

7.

C
x cos y sin

1
3
2
x 0, y 2cos ec,

chord A 'P;
y

2 sin
x 3
3 cos 1

x 0, OM

2 sin
cos
1

Now, OQ2 MQ2 OQ2 OQ OM

2 OM OQ OM2
OM 2OQ OM
2 sin

cos 1 sin

2 sin
1 cos

2sin 4 4 cos 2 sin 2

1 cos

sin

4 sin 2 2cos 1 cos2

1 cos

sin

8.

A, B, D
f x 0 x 3 x 2 x 1 x 2 x 1 2 0
x 3 1

2
x2 x 1
-2

-1

1
2

x3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

14
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

9.

A, B, C
Take f x x and g x x and proceed.

10.

B, C
cos 2x

1
I tan1
dx tan tan x dx
4
1 sin 2x

x dx
4

11.

x2

x2
x
C gx x .
4
2
4
2

A, B

2 4 4 a2 1

1 a, 1 a
2
f 1 a 0 & f 1 a 0

1
a ,1
4

12.

C
The value of K1 & K2 decide the opening of parabola
A max Area OBCO
A min Area OACO

Y
c
A

X'

Y'

14.

1
4
1
K1
8

K1

(1,0)

(2, 0)

K2

1 K2 = -1
4

D
Area BFEC Area ABC AFE

or AOB BOC COA AFE


1 2
R sin 2C sin 2A sin 2B sin 2A
2
1
R2 sin2B sin 2C
2

2R
co
sA

13.

2A

E
H

O
C

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

15
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

15.

B
AE R, AF 2Rcos A
EF R

16.

3
AFE is equilateral
AFE

R 3
9
sum of square of altitudes 3
R2 .
2
4

SECTION B
1.

(A
p, r, t) (B
q) (C
t) (D
s)

A tan 1 2 3 4 0 1 2 3 4 2n
2

B x 2

4 t 2 2, TR is diameter 6

2
TR 9
4

Area of circle

C 6
D y A yB yC
2.

(A
q, t) (B
q) (C
p, r, s) (D
t)

SECTION C
1.

1
D.C' s of OP are,

1 1

,
,
3 3
1
D.C' s of AL
,
3

3
1 1
,

3 3

C (o, o, a)

cos
cosy

mn

3
mn
3

,cos

,cos

P (a, a, a)

(o, a, a)

1
1 1
D.C's of BM
,
,

3 3
3
1 1
1
D.C' s of CN
,
,

3
3
3

Let D.C' s of required line be ,m,n

M(a, o, a)

A (a, o, o)

B
(o, a, o)

N (a, a, o)

m n

3
mn
3

4 2
4
m2 n 2
3
3
4
2
2
2
2
cos cos cos y cos 1.
3
2

Hence, cos cos cos y cos2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

16
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

2.

2
The gives equation is x 1 y 2 4

XY 4
Equationof tan gent is,

4
4
2 x t
t
t
8
A 0, & B 2t1 0
t

P t1 t
B

1 8
2t 8
2 t
4K 8 k 2.
Area

3.

1
2

2 3 25
CE a b

DE
16
16
C2
CE

1
DE
4.

5
10 1

f K 1 x dx f x dx f x 1 dx.......... f x 9
K 1 0

putting x 1 t, x 2 t............ x 9 t
1

10

f x dx f x dx f x dx.......... f x dx
0

10

f x dx 5.
0

5.

7
Every ball have two options
4 balls can be put in 24 ways.
Arrangement among themselves in 2!
1
24 23
2!
But, above count also includes the one case in which all the balls are put in one box,
Required number of ways = 23 1 = 7.

6.

2
3

K 1 K 2 K 3
K 1 K 2 K 3
1
K 2

K 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com