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QuestionRevision

Question1.
Selectthepairofmetamers:
[A]
[B]
[C]

[D]

Question2.
Ifx,yandzarebondordersthenwhatwouldbethecorrectorder?

[A]
[B]
[C]
[D]

x>y>z
y>z>x
z>x>y
z>y>x

Question3.
If

aretherotationalbarriersaboutthebridgeddoublebondthen:

[A]
[B]
[C]
[D]

Question4.
ThefoursparinglysolublesaltsAX(I),BX2(II),CX3(III)andDX4(IV)havesamesolubilityproductsatagiventemperature.Boilingpoints
oftheirsaturatedsolutionwillbeintheorderof:
[A]
[B]
[C]
[D]

I<III<IV<II
IV<III<I<II
I<II<IV<III
I<II<III<IV

Question5.
pHofa0.1Mmonobasicacidisfoundtobe2.Hence,itsosmoticpressureatagiventemperatureTis:
[A]

0.1RT

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[B]
[C]
[D]

QuestionRevision

0.11RT
1.1RT
0.01RT

Question6.
StructurehavingallCCbondlengthequalare:

[A]

[B]

[C]
[D]

Question7.
AcompoundXhasthemolecularformulaC6H10.Compoundisopticallyactivebutunabletoshowdifferentgeometricalisomers.
HoweveronhydrogenationwithH2/Ni,itlosesitsopticalactivity.Whatcouldbethepossiblestructuresofgivencompound?
[A]

[B]

[C]

[D]

Question8.
Identifythepairofidenticalcompounds

[A]

[B]

[C]

[D]

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Question9.
Inwhichofthefollowingpairsofsolutionswillthevaluesofthevan'tHofffactorbethesame?(Assume100%dissociation)
[A]
[B]
[C]
[D]

0.05mK4[Fe(CN) 6]and0.10MFeSO 4
0.10MK4[Fe(CN) 6]and0.05MFeSO 4.(NH4) 2SO 4.5H2O
0.20MNaCland0.10MBaCl2
0.05MFeSO 4.(NH4) 2SO 4.6H2Oand0.02MKCl.MgCl2.6H2O

Question10.
Dryairisfirstpassedthrougha0.1MsolutionofNaClinwaterandthenthrough5MNaClsolution.Asairispassedthroughthese
solutions:
[A]
[B]
[C]
[D]

dilutesolutionwillshowlossinweight
dilutesolutionwillshowgaininweight
changeinweightofdilutesolutionisproportionaltoitsvapourpressure
conc.solutionwillshowgaininweight

Question11.
To20mLof0.1Mbariumchloridesolution0.2mLof3MchromiumsulphateisaddedBaSO 4formedisdissociated(Changeinvolumeis
ignored).Then
[A]
[B]
[C]
[D]

vapourpressureisincreased
boilingpointislowered
osmoticpressureisincreased
freezingpointisincreased

Question12.
Equalvolumesof0.1MsolutionofNaCland0.5MsolutionofNaClarekeptinaclosedvessel(seefigure)andtemperatureismaintained
constant.Afterequilibriumhasbeenestablished,assumingthatvolumesareadditive,whichofthefollowingis(are)true?

[A]
[B]
[C]
[D]

Volumeof0.1Msolutionislesserthanitsoriginalvolume
Volumeof0.1Msolutionisgreaterthanitsoriginalvolume
Volumeof0.5Msolutionislesserthanitsoriginalvolume
Volumeof0.5Msolutionisgreaterthanitsoriginalvolume

Question13.
Whichofthefollowingcontainallspecieshaving
[A]

backbond?

P2O 5,N2O 5,SO 3

[B]
[C]
[D]

Question14.
WhichofthefollowingisacorrectIUPACnameoftheopticallyactivecompound?
[A]
[B]
[C]
[D]

2Bromo3chloropent3ene
2,3Dibromobut1ene
Trans1Ethyl2methylcyclohexane
Cis1,2Dimethylcyclopentane

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Question15.
Whichofthefollowingcanshowopticalaswellasgeometricalisomerism
[A]

[B]

[C]

[D]

Question16.
15mLofanaqueoussolutionofKClwasfoundtorequired20mLofa1.0MAgNO 3solutionwhentitratedusingofK2CrO 4asindicator.
DepressioninfreezingpointofKClsolution(Assumingittobe100%ionizedandmolarity=molality)willbe________C(approx)(Kf =
1.86)

Question17.
VapourpressureofavolatileliquidAis60torrat

.VapourpressureofanothervolatileliquidBis42torrat

molesofBshouldbeaddedto4molesofAinordertobringdownthevapourpressureofsolutionby

at

.Howmany
?

Question18.
Forthegivencompound.Ifnoofopticallyactiveisomersisxandthatofinactiveisy,findxy

Question19.
Howmanyofthefollowingcompounds/speciescontainadelocalizedlonepairof

Question20.
Howmanyofthefollowingcarbocationsaremorestablethanbenzylcation

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Question21.
Fourpointcharges,each
,arefixedatthecornersofasquareofside'a'.Anotherpointchargeq0isplacedaheight'h'vertically
abovethecentreofthesquare,assumingthesquaretobeinahorizontalplane.Magnitudeofforceexperiencedbyq0is:
[A]

[B]

[C]
[D]

Zero

Question22.
AchargedparticleofchargeQisheldfixedandanotherchargedparticleofmassmandchargeq(ofthesamesign)isreleasedfroma
distancer.TheimpulseoftheforceexertedbytheexternalagentonthefixedchargebythetimedistancebetweenQandqbecomes2r
is:
[A]

[B]

[C]

[D]

Question23.
ThearcABwiththecenterCandtheinfinitelylongwirehavinglinearchargedensity
bedonetomoveapointcharge

arelyinginsameplane.Theamountofworkto

frompointAtoBthroughacircularpathABofradiusaisequalto:

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[A]

[B]

[C]

[D]

Question24.
Anonconductingspherewithradiusaisconcentricwithandsurroundedbyaconductingsphericalshellwithinnerradiusbandouter
radiusc.Theinnerspherehasanegativechargeuniformlydistributedthroughoutitsvolume,whilethesphericalshellhasnonetcharge.
ThepotentialV(r)asafunctionofdistancefromthecentreisgivenby:

[A]

[B]

[C]

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[D]

Question25.
Aunitpositivepointchargeofmassmisprojectedwithavelocityvinsidethetunnelasshown.Thetunnelhasbeenmadeinsidea
uniformlychargednonconductingspherehavingpositivechargeofdensity
.Theminimumvelocitywithwhichthepointcharge
shouldbeprojectedsuchitcanitreachtheoppositeendofthetunnel,isequalto:

[A]
[B]
[C]
[D]

zerobecausetheinitialandthefinalpointsareatsamepotential

Question26.
AthinmetallicsphericalshellcontainsachargeQoverit.Apointcharge+qisplacedinsidetheshellatpointTseparatedfromthecentre
bydistance'a'.Anotherpointchargeq1isplacedoutsidetheshellatadistancebfromthecentreasshownintheadjacentfig.Now
selectthecorrectstatementsfromthefollowing.

[A]

Electricfieldatthecentreduetochargeoveroutersurfaceoftheshelliszero

[B]

Electricfieldatthecentreduetochargeoveroutersurfaceoftheshellis

[C]

Electricpotentialatthecentreduetoallchargesinspaceis

[D]

Electricpotentialatthecentreduetoallchargesinspaceis

Question27.
Apointchargeqisplacedatorigin.Let

betheelectricfieldatthreepointsA(1,2,3),B(1,1,1)andC(2,2,2)due

tochargeq.Then
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[A]
[B]
[C]
[D]

Question28.
Adistanceof5cmand10cmoutwardsfromthesurfaceofauniformlychargedsolidsphere,thepotentialare100Vand75V
respectively.Then:
[A]
[B]
[C]
[D]

potentialatitssurfaceis150V.
thechargeonthesphereis
Theelectricfieldonthesurfaceis1500V/m
Theelectricpotentialatitscentreis225V

Question29.
AnunchargedthinconductingsphericalshellAofradius'a'isplacedconcentricallywithathickconductingsphericalshellBofinner
radius2aandouterradius3aasshowninthefigure.IftheshellBisgivenatotalcharge+Q,andshellAisearthedthen:

[A]

ChargeonshellAwillbe

[B]

ChargeonshellAwillbe

[C]

ChargeonoutersurfaceofshellBwillbe

[D]

ChargeonoutersurfaceofshellBwillbe

Question30.
Asmallchargedbeadcanslideonacircularfrictionless,insulatingwireframe.Apointlikedipoleisfixedatthecentreofcircle,dipole
momentis
.Initiallythebeadisontheplaneofsymmetryofthedipole.Beadisreleasedfromrest.Ignoretheeffectofgravity.Select
thecorrectoptions:

[A]

Magnitudeofvelocityofbeadasfunctionofitsangularpositionis

[B]
[C]
[D]

Normalforceexertedbytheframeonbeadiszero.
Ifthewireframewerenotpresentbeadexecutescircularmotionandreturnstoinitialpointaftertracingacompletecircle
Beadwouldmovealongacircularpathuntilitreachedoppositetoitsstartingpositionandthenexecutesperiodicmotion.

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Question31.
Forthesituationshowninthefigure,selectthecorrectstatement(s):

[A]

Potentialoftheconductoris

[B]

Potentialoftheconductoris

[C]

Potentialoftheconductorcan'tbedeterminedasnatureofdistributionofinducedchargesisnotknow.

[D]

PotentialatpointBduetoinducedchargesis

Question32.
AconductingsphereAofradiusa,withchargeQisplacedconcentricallyinsideaneutralconductingshellBofradiusb.BisearthedCis
thecommoncentreoftheAandB:]

[A]

ThefieldatdistancerfromCwhere

[B]

ThepotentialatadistancerfromC,where

[C]

ThepotentialdifferencebetweenAandBis

[D]

ThepotentialatadistancerfromC,where

is

is

Question33.
Ahollow,insulatingsphericalshellhasasurfacechargedistributionplaceduponit,suchthattheupperhemispherehasauniform
surfacechargedensity
,whilethelowerhemispherehasauniformsurfacechargedensity
,asshowninthefigure.Their
interfaceliesinxyplane.Whichofthefollowingstatement(s)is/arecorrect?

[A]
[B]
[C]
[D]

Thefieldatallpointsofxyplanewithinthespherepointsinthevezdirection
Allpointsofthexyplanewithinthesphereareequipotentialpoints
Thefieldatallpointsonzaxisoutsidethespherepointalongpositivezdirection
Thefieldatpointsonzaxiswhichareoneithersideoforiginoutsidethesphereinoppositedirections.

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Question34.
AthicksphericalshellwithitscentreatOandhavinginnerradius'a'andouterradius'3a'carriesuniformlydistributedpositivechargeas
showninthefigure.IfVreferstothepotentialthen:
(TakeOB=2a,OC=4a)

[A]
[B]
[C]
[D]

Question35.
Averylonguniformlychargedcircularcylinder(radiusR)hasasurfacechargedensity
(linearchargedensity
)isplacedalongthecylinderaxis.
[A]

Forelectricfieldoutsidecylindertobezero,

[B]

Forelectricfieldoutsidecylindertobezero,

[C]

Electricfieldinsidecylinderatdistancerfromaxisis

[D]

Electricfieldinsidecylinderatdistancerfromaxisis

.Averylonguniformlychargedlinecharge

Question36.
Awheelhavingmassmhascharges+qandqondiametricallyoppositepoints.Itremainsinequilibriumonaroughinclinedplaneinthe
presenceofuniformverticalelectricfield

.ThevalueofKis_____________:

Question37.
ThediagramshowsauniformlychargedhemisphereofradiusR.Ithasvolumechargedensity
distanceaboveitscentreisEthentheelectricfieldatthepointwhichis2Rbelowitscentrewillbe

.Iftheelectricfieldatapoint2R
.Thevalueof

is

_____________:

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Question38.
Auniformelectricfieldexistsin

plane.ThepotentialofpointsA(2m,2m),B(

)andC(2m,4m)are4V,16Vand12V

respectively.Themagnitudeofelectricfield(inN/C)is___________:

Question39.
Considerasemicircularrodhavingwithauniformlydistributedchargeq,placedasshowninfigure.RadiusofthewireisRandtheinfinite
lineofchargehavinglinearchargedensity
ispassingthroughitscentreandperpendiculartotheplaneofwire.Thevalueofnet
forceexperiencedbysemicircularrodis

thenofKis_____________:

Question40.
AmetalballofradiusRisplacedconcentricallyinsideahollowmetalsphereofinnerradius2Randouterradius3R.Theballisgivena
charge+2Qandthehollowsphereatotalcharge

.Theelectrostaticpotentialenergyofthissystemis

thenvalueofn

is_____________:

Question41.
Thedomainoff(x)is(0,1).Thenthedomainof

is:

[A]
[B]
[C]
[D]

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Question42.
If
[A]

,thenthepointswhere

isnondifferentiableare:

{0,1}

[B]
[C]
[D]

Noneofthese

Question43.
is(where[.]representsthegreatestintegerfunction):

[A]
[B]
[C]
[D]

1
0
Doesnotexist

Question44.
Thelargestvalueofthenonnegativeintegeraforwhich

is

[A]
[B]
[C]
[D]

Noneofthese

Question45.
Thelocusofthefootofperpendiculardrawnfromthecentreoftheellipse

onanytangenttoitis:

[A]
[B]
[C]
[D]

Question46.

Letf:

beacontinuousfunctionandg:

bedefinedas

Then,
[A]
[B]

g(x)iscontinuousbutnotdifferentiableata
g(x)iscontinuousonR

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[C]
[D]

QuestionRevision

g(x)iscontinuousbutnotdifferentiableatb
g(x)iscontinuousanddifferentiableateitheraorbbutnotboth

Question47.
Letf:
[A]
[B]

beafunctionsuchthat
f(x)isdifferentiableonlyinafiniteintervalcontainingzero
f(x)isdifferentiable
isdifferentiable

[C]
[D]

.Iff(x)isdifferentiableatx=0,then:

f(x)isdifferentiableexceptatfinitelymanypoints

Question48.
Let

.IfLisfinite,then:

[A]
[B]
[C]
[D]

Question49.
Letf:
[A]
[B]
[C]
[D]

begivenby

.Then,

f(x)isanoddfunction
f(x)isaoneonefunction
f(x)isanontofunction
f(x)isanevenfunction

Question50.
Foreveryintegern,let

and

berealnumbers.Letfunctionf:

begivenby:

,forallintegersn.

Iffiscontinuous,thenwhichofthefollowinghold(s)foralln?
[A]
[B]
[C]
[D]

Question51.
Lettheeccentricityofthehyperbola

bereciprocaltothatoftheellipse

.Ifthehyperbolapasses

throughafocioftheellipse,then

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[A]

QuestionRevision

theequationofthehyperbolais

[B]

afocusofthehyperbolais(2,0)

[C]

theeccentricityofthehyperbolais

[D]

theequationofthehyperbolais

Question52.
Tangentaredrawntothehyperbola

,paralleltothestraightline

.Thepointsofcontactsofthetangents

onthehyperbolaare:
[A]

[B]
[C]
[D]

Question53.
LetLbeanormaltotheparabola

.IfLpassesthroughthepoint(9,6),thenLisgivenby:

[A]
[B]
[C]
[D]

Question54.
If

and

and

isdiscontinuousat

exactlyonepoint,thenwhichofthefollowingvaluesofaandbarepossible?
[A]
[B]
[C]
[D]

Question55.
If

and

areinA.P.forallx,yand

,then:

[A]
[B]
[C]
[D]
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Question56.
Iff(x)isanoddfunction,

and

,thenthevalueoff(3)is_________.

Question57.
If

existsandisfiniteandnonzeroandif

,thenthevalueof

is

________.

Question58.
Iff(x)isacontinuousfunction,
function,iscontinuous

andf(x)

,where[.]denotesthegreatestinteger

,thentheleastpositiveintegralvalueofais________.

Question59.
Adifferentiablefunctionfissatisfyingtherelation

and

.Thenthevalueof[f(2)]is________.(where[x]representsthegreatestintegerfunction)

Question60.
Considertheparabola

.Let

ontheparabolaand

rectum.Then

betheareaofthetriangleformedbytheendpointsofitslatusrectumandthepoint
betheareaofthetriangleformedbydrawingtangentsatPandattheendpointsofthelatus

is__________.

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