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4/17/2015

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Question1.
250mLofxMsolutionand500mLofyMsolutionofasolutearemixedanddilutedto2Ltoproduceatsolutionhavingconcentration1.6M.
Ifx:y=5:4,thenx+yis:
[A]
[B]
[C]
[D]

8.06
8.86
9.8
12.6

Question2.
Onelitreof
[A]
[B]

0.6litreCO
0.8litre

[C]
[D]

0.6litre

ispassedoverhotcoke.Thevolumebecomes1.4litre.Thepercentcompositionofproductsis:

and0.8litreCO

noneofthese

Question3.
Thepressureofarealgasislessthanthepressureofanidealgasbecauseof:
[A]
[B]
[C]
[D]

increaseinthenumberofcollisions
finitesizeofthemolecules
increaseinthekineticenergy
intermolecularforces

Question4.
Photoelectricemissionisobservedfromasurfaceforfrequencies

and

oftheincidentradiation

kineticenergiesofthephotoelectronsinthetwocasesareintheratio1:kthenthethresholdfrequency

Ifthemaximum
isgivenby:

[A]
[B]
[C]
[D]

Question5.
Ifproton,electronand

particlehaveequalkineticenergy,theirdeBrogliewavelengthswouldbeintheorder:

[A]
[B]
[C]
[D]

Question6.
Changeinentropyisnegativefor:
[A]
[B]

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[C]
[D]

Question7.
Inconversionoflimestonetolime,
thevalueof
and
are+179.1kJmol1and160.2J/Krespectivelyat298Kand1bar.Assumingthat
donotchangewithtemperature.Temperatureabovewhichconversionoflimestonetolimewillbespontaneousis:
[A]
[B]
[C]
[D]

and

1008K
1200K
845K
1118K

Question8.
atconstantpressureis18500calat25oC.Theheatofreactionat

Theheatofformationofmethane
constantvolumewouldbe:
[A]
[B]
[C]
[D]

19096cal
18798cal
18202cal
17904cal

Question9.
Lechatelier'sprincipleisnotapplicableto:
[A]
[B]
[C]
[D]

Question10.
WhichactsbothasLowryBronstedacidandbase?
[A]
[B]
[C]
[D]

Question11.
Theprecipitateof

isobtainedwhenequalvolumesofthefollowingaremixed:

[A]
[B]
[C]
[D]

Question12.
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If50mLof0.2MKOHisaddedto40mLof0.5MHCOOH,thepHoftheresultingsolutionis:
[A]
[B]
[C]
[D]

3.75
5.6
7.5
3.4

Question13.
AccordingtoMOtheory,
[A]

isparamagneticandbondordergreaterthanO 2

[B]

isparamagneticandbondorderlessthanO 2

[C]

isdiamagneticandbondorderislessthanO 2

[D]

isdiamagneticandbondorderismorethanO 2

Question14.
IdentifytheIUPACnameoffollowingcompound.

[A]
[B]
[C]
[D]

2Hydroxy4ketohexanoicacid
Hexan2ol4on1oicacid
3Keto5hydroxyhexan1oicacid
4Keto2hydroxyhexan1oicacid

Question15.
IdentifytheIUPACnameofthefollowingcompound:

[A]
[B]
[C]
[D]

Ethyl2methylpentanoate
Ethyl1methylbutanoate
2Methylethylpentanoate
Ethyl1methylpentanoate

Question16.
Whichrepresentsthedisproportionationreaction?
[A]
[B]
[C]
[D]

Allofthese

Question17.
Selectthecorrectstatements:
[A]
[B]
[C]
[D]

H2O 2isimmisciblewithH2O
InpurestateH2O 2isdeepbluecoloured
H2O 2hasanonplanarstructure
H2O 2canonlyactasanoxidizingagent.

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Question18.
WhichoffollowingcarbonateuponheatingwillgiveCO 2.
[A]
[B]
[C]
[D]

Li2CO 3
Na2CO 3
K2CO 3
CsCO 3

Question19.
Whichonerepresentsanimpossiblearrangement?
[A]
[B]
[C]
[D]

nlms
3221/2
4001/2
3231/2
5301/2

Question20.
Agasabsorbsaphotonof355nmandemitstwowavelengths.Ifoneoftheemissionisat680nm,theotherisat:
[A]
[B]
[C]
[D]

1035nm
325nm
743nm
518nm

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