ORG./INO.

CHEMISTRY

TARGET : JEE (Main) 2017

NO. 20

Course : AADHAAR(EB)

This DPP is to be discussed in the week (28-09-2015 to 03-10-2015)

DPP No. # 20 (Revision DPP)

Total Marks : 63
Single choice Objective (1 negative marking) Q.1 to Q.21

1.

(3 marks, 2 min.)

Max. Time : 42 min.

[63, 42]

Which of the following conditions is required for the formation of hydrogen bond :

gkbMkstu ca/k cukus ds fy, fuEu esa ls dkSulh ifjfLFkfr;k vko';d gSa %

(1) Hydrogen atom should be bonded to a highly electronegative atom.

gkbMkstu ijek.kq] mPp fo|qr_.kh; ijek.kq ls caf/kr gksuk pkfg,A

(2) The size of electronegative atom should be small.

fo|qr_.kh; ijek.kq dk vkdkj NksVk gksuk pkfg,A

(3) There should be a lone pair of electron on the electronegative atom.

fo|qr_.kh; ijek.kq ij ,d ,dkdh bysDVkWu ;qXe mifLFkr gksuk pkfg;sA

(4*) All of the above.

mijksDr lHkhA

Sol.

Conditions for Hbonding :

(1) Positive charge density on Hatom should be high.
(2) Availability of lone pair of EN atom should be high.
(3) Size of EN atom should be small.

Sol.

gkbMkstu ca/k ds fy, ifjfLFkfr;k

(1) Hijek.kq ij /kukRed vkos'k ?kuRo mPp gksrk gSA
(2) fo|qr_.kh; ijek.kq ij ,dkdh bysDVkWu ;qXe dh mifLFkfr mPp gksuh pkfg,A
(3) fo|qr _.kh; ijek.kq dk vkdkj NksVk gksuk pkfg,A

2.

How many of the following molecules are polar?

fuEu esa ls fdrus v.kq /kqzoh; gSa\

(i) CO2

(ii) SO2

(iii) NO2

(iv) SOCl2

(v) COCl2

(vi) BeCl2(g)

(vii) TeCl4

(viii) CCl4

(2*) 6

(3) 7

(4) 8

(ix) ClO2
(1) 5

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PAGE NO.- 1

Sol.

CO2

NO2

3.

O= C=O

= 0

=O

SO2

SO2

SOCl2

COCl2

BeCl2

TeCl4

CCl4

ClO2

= 0

Cl Be Cl

How many among the following species contain PP bond(s) :

fuEu esa ls fdruh Lih'kht esa PP cU/k mifLFkr gS %
(i) P (red) yky

(ii) H4P2O5

3 3

(1) 2

Sol.

sp

3 2

(iii) H4P2O7

(iv) (PO )

(v) (PO )

(vi) P4O10

(vii) P4S3

(viii) P4O6

(ix) P4

(2*) 3

(3) 4

(i)

(4) 5

(ii)

(iii)

O
O

O
(iv)

OP O

(vi) O P

(v)

(vii)

4.

(viii)

(ix)

How many species have bond order more than one but less than three

fuEu esa ls fdruh iztkfr;k ,d ls vf/kd ysfdu rhu ls de cU/k e j[krs gSaA
O2, O2 , N2, N2 , N2 , N22 , B2, H2, B 2 , C2, C22
(1) 5
Sol.

(2) 6

(3*) 7

(4) 8

O2, O2 , N2 , N2 , N22 , B2, C2

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5.

How many of these species are paramagentic ?

fuEu esa ls fdruh Lih'kht vuqpqEcdh; gS \

O2, O2+, O2, O22, C2, B2, Be2,Li2
(1) 2

(2) 3

(3*) 4

(4) 5

Sol.

O2, O2+, O2, B2

6.

In which of the following species, the OO bond length is expected to be longest ?

fuEu esa ls fdl iztkfr esa] OO cak yEckbZ lokZf/kd gksxh \
(1*) K2O2
(2) RbO2
(3) O2
(4) O2[PF6]

Sol.

O22(M.O.T)1s 2 1s2 2s 2 2s 2 (2p)2 (2p)4(*2p)4

Bond order (cak

e) (O22) =

1
(10 8) = 1
2
1
(10 7) = 1.5
2

Similarly (blh

izdkj), Bond order (cak e) (O2) =

Similarly (blh

izdkj), Bond order (cak e) (O2) =

Similarly (blh

izdkj), Bond order (cak e) (O2+) =

1
(10 6) = 2
2
1
(10 5) = 2.5
2

1
( Bond order Bond length )
(
7.

cak e cak yEckbZ )

Which of the following leads to bonding?

s-orbital

p-orbital
+

(1)
p-orbital

p-orbital

(3)

(2*)

(4)

fuEufyf[kr esa ls dkSu ca/k cukus ds i{k esa gS&

8.

(1)

(2*)

(3)

(4)

How many of the following are planar ?

XeF2, ClF3, H2O, [XeF5], I3, BCl3, XeF4, SF4, PCl5, SF6, IF7.

fuEu esa ls fdruh Lih'kht leryh; gSa \

XeF2, ClF3, H2O, [XeF5], I3, BCl3, XeF4, SF4, PCl5, SF6, IF7.

(1) 5

(2) 6

(3*) 7

(4) 8

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PAGE NO.- 3

Sol.

gy-

(i) Planar molecules : XeF2, ClF3, H2O, [XeF5], I3, BCl3, XeF4.
(ii)
SF4 See - Saw shape
PCl5 Trigonal bipyramidal
SF6 Square bipyramidal
IF7 Pentagonal bipyramidal
(i) leryh; v.kq : XeF2, ClF3, H2O, [XeF5], I3, BCl3, XeF4.
(ii)
SF4 lh&lkW vkd`fr
PCl5 f=kdks.kh; f}fijkfefM;
SF6 oxkZdkj f}fijkfefM;
IF7 iapdks.kh; f}fijkfefM;

9.

Match list l with List II and select the correct answer using the codes given below the lists.
List I
List II
(Compound)
(Shape)
(a) CS2
1. Bent
(b) SO2
2. Linear
(c) BF3
3. Trigonal planer
(d) NH3
4. Tetrahedral
5. Trigonal pyramidal
lwph l rFkk lwph lI dks lqesfyr dhft, rFkk lwph ds uhps fn, x;s dwVksa dk mi;ksx dj lgh mkj pqfu;sA
lwph I
lwph II
(;kSf xd )
(vkd` fr )
(a) CS2
1. eqMk gqvk
(b) SO2
2. js[kh;
(c) BF3
3. lery f=kdks.kh;
(d) NH3
4. prq"Qydh;
5. f=kdks.kh; fijkfeMh;
dwV :
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
(1*)
2
1
3
5
(2)
1
2
3
5
(3)
2
1
5
4
(4)
1
2
5
4

Sol.

(1) S C S (linear )

(2)

(bent)

(4)

(trigonal pyramidal)

sp

(3)

gy %

(trigonal planar)

(1) S C S ( js[kh; )

(2)

sp

(3)

(lery

f=kdks.kh;)

(4)

(eqM+k

gqvk)

(f=kdks.kh;

fijkfeMh;)

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PAGE NO.- 4

10.

Sol.

Select the incorrect order(s).

(1*) PH3 < AsH3 < NH3 < SbH3 bond angle
(3) CO < CO2 < CO32 bond length

xyr e vFkok eksa dk p;u dhft;s %

(1*) PH3 < AsH3 < NH3 < SbH3 ca/k dks.k
(2) Cl2O > F2O rFkk F2O < H2O ca/k dks.k
2
+
(3) CO < CO2 < CO3 ca/k yEckbZ
(4) NH4 > NH3 > NH2 ca/k dks.k
(1) NH3 > PH3 > AsH3 > SbH3 bond angle
(2) Cl2O > F2O rFkk F2O < H2O
111 102
102 104

(3) C

Sol.

(2) Cl2O > F2O and F2O < H2O bond angle
(4) NH4+ > NH3 > NH2 bond angle

O < O=C=O <

triple bond double bond

partial double bond character due to resonance
(1) NH3 > PH3 > AsH3 > SbH3 ca/k dks.k
(2) Cl2O > F2O rFkk
F 2 O < H2 O
111 102
102 104

(3) C

O < O=C=O <

f=kca/k
11.

f}ca/k

vuqukn ds dkj.k vkaf'kd f}ca/k vfHky{k.k

Among the following molecular orbitals, how many have only one nodal plane?

fuEu esa ls fdrus vkf.od d{kdksa esa dsoy ,d uksMy ry gSS \

1s,2s, *1s, 2px , *2py,2py
(1) 2

Sol.

(2*) 3

(4) 5

*1s

2px or 2py

12.

(3) 4

uksMy ry

*2px or *2py uksMy ry

How many antibonding electrons are there in O2+ ?

O2+ esa fdrus izfr vkca/kh bysDVkWu mifLFkr gSA
(1) 2

(2) 3

(3) 4

(4*) 5

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PAGE NO.- 5

13

How many of the following species have all bonds of equal length ?

fuEu esa ls fdruh iztkfr;ksa ds fy, lHkh cU/kksa dh yEckbZ leku gksrh gS\
(a) ClO4

(b) NO3

(1) 2
14.

(c) AsO43

(2) 3

(d) CO2

(e) SO32

(3) 4

The shape of SO24 ion is :

(1) Square planar
(2*) Tetrahedral

(4*) 5

(3) Trigonal bipyramidal (4) Hexagonal

SO24

vk;u dh vkfr gS %
(1) oxZ leryh;
(2*) prq"Qydh;
15.

(3) f=kHkqth;

f}fijkfeMh;

(4) "kV~dks.kh;

IUPAC name of the following compound is

fuEu ;kSfxd dk IUPAC uke gS

(1) 3-(Prop-2-ynl)hexe-1,3,5-triene
(3) 4-Ethenylhexa-4, 6-dien-1-yne
(1) 3-(izksi-2-vkbZfuy)gsDl-1,3,5-VkbZbu
(3) 4-,sfFkukbygsDlk-4, 6-MkbZu-1-vkbu

(2*) 4-Ethenylhepta-1, 3-dien-6-yne

(4) 4-(Prop-2-ynyl) hexa-1,3,5-triene
(2*) 4-,sfFkukbygsIVk-1, 3-MkbZu-6-vkbu
(4) 4-(izksi-2-vkbZfuy)gsDlk-1,3,5-VkbZbu
Z

Sol.

16.

The IUPAC name of the

is :

(1) 1Ethyl4chlorocyclopent1,3diene (2) 1Chloro4ethylcyclopent1,3diene

(3) 1Ethyl4chlorocyclopenta1,3diene
(4*) 1Chloro4ethylcyclopenta1,3diene

dk IUPAC uke gS %
(1) 1,fFky 4DyksjkslkbDyksisUV1,3MkbbZu
(3) 1,fFky4DyksjkslkbDyksiUs Vk1,3MkbbZu

17.

IUPAC name of

is

(1) N-Deutero-N-formylbenzenamine
(3*) N-Deutero-N-phenylmethanamide

;kSfxd

(2) N-Phenylamino-N-deuteromethanal
(4) N-Deuterobenzene carboxamide

dk IUPAC uke gS

(1) N-M~;wfVfj;ks-N-QkfeZycsUthuvehu
(3*) N-M~;wfVfj;ks-N-QsfuyesFksukekbM

Sol.

(2) 1Dyksjks4,fFkylkbDyksiUs V1,3MkbbZu

(4*) 1Dyksjks4,fFkylkbDyksiUs Vk1,3MkbbZu

(2) N-Qsfuyvehuks-N-M~;wfVfj;kseFs ksusy

(4) N-M~;wfVfj;kscSUthu dkcksZDlkekbM

D
|
H C N Ph
||
O
N-Deutero-N-phenylmethanamide.
N-M~;wfVfj;ks-N-QsfuyesFksukekbM
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PAGE NO.- 6

18.

The IUPAC name of following compounds is HOOC CH2 CH CH2 CH2 COOH
|

COOH

(1) 3-Carboxyhexane -1,6- dioic acid

(3) 4-Carboxyhexane-1,6-dioic acid

(2*) Butane-1,2, 4-tricarboxylic acid

(4) 1, 2-Dicarboxypentanoic acid

HOOC CH2 CH CH2 CH2 COOH dk IUPAC uke

|

fuEufyf[kr esa gSA

COOH

(1) 3-dkcksZfDlgsDlsu-1,6-MkbvkWbd
19.

vEy
(3) 4-dkcksZfDl gsDlsu-1,6-MkbvkWbd vEy

(2*) C;qVsu-1,2, 4-VkbZdkcksZlsfyd

The total number of lone pairs in chlorate ion is :

vEy
(4) 1, 2-MkbdkcksZfDlisUVsukWbZd vEy

DyksjsV vk;u esa dqy ,dkdh bySDVkWu ;qXeksa dh la[;k gS %

(1) 5

(2) 6

(3) 7

(4*) 8

Sol.
20.

In how many of the following species the central atoms have two lone pairs of electrons ?

fuEu esas ls fdruh Lih'kht esa] dsUnzh; ijek.kq ij nks ,dkdh bysDVkWu ;qXe mifLFkr gSa \
XeF4
ICl4

ClF3
SCl2

XeF3+

F2SeO2
XeOF2

(1) 5

(2) 6

NH2

(3*) 7

ClOF3
(4) 8

Sol.

XeF4

ClF3

F
|
Xe F
|
F

XeF3+

F2SeO2

+
NH2

ClOF3

Cl
I

ICl4
Cl

21.

Cl

SCl2
Cl

XeOF2

S
Cl

Cl

In how many of the given species there is no any lone pair on the central atom.

fn;s x;s ;kSfxdksa esa fdrus ij dsfU; ijek.kq ij ,dkdh bysDVkWu ;qXe ugh gSaA
(i) XeF4
(vi) XeOF4
(1*) 5

(ii) NH3
(vii) ICl3
(2) 6

(iii) SO2
(viii) IF7

(iv) NO3
(ix) SO42

(3) 7

(v) O3
(x) XeO3
(4) 8

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PAGE NO.- 7

Sol.

(i) XeF4

(ii) NH3

(iv) NO3

(iii) SO2

(v) O3

(vi) XeOF4

(vii) ICl3

(ix) SO42

(x) XeO3

(viii) IF7

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PAGE NO.- 8